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EP2187864A2 - Compositions contenant des composés quaternaires d'ester de diéthanolamine - Google Patents

Compositions contenant des composés quaternaires d'ester de diéthanolamine

Info

Publication number
EP2187864A2
EP2187864A2 EP08801501A EP08801501A EP2187864A2 EP 2187864 A2 EP2187864 A2 EP 2187864A2 EP 08801501 A EP08801501 A EP 08801501A EP 08801501 A EP08801501 A EP 08801501A EP 2187864 A2 EP2187864 A2 EP 2187864A2
Authority
EP
European Patent Office
Prior art keywords
coo
groups
compounds
formula
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08801501A
Other languages
German (de)
English (en)
Inventor
Matthias Loeffler
Franz-Xaver Scherl
Tom Fricke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Finance BVI Ltd
Original Assignee
Clariant Finance BVI Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102007037018A external-priority patent/DE102007037018A1/de
Priority claimed from DE200810015899 external-priority patent/DE102008015899A1/de
Application filed by Clariant Finance BVI Ltd filed Critical Clariant Finance BVI Ltd
Publication of EP2187864A2 publication Critical patent/EP2187864A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the invention relates to compositions containing diethanolamine ester quats, which are characterized in that the two ester groups carry long-chain acyl chains having 18 to 24 carbons and preferably contain no carbon-carbon double bond, as well as their use for the care of the skin and hair.
  • Skin care and hair care compositions containing quaternary ammonium compounds having at least one long chain alkyl or alkenyl group for example, behenyltrimethylammonium chloride, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, distearyldimethylammonium chloride are known.
  • a disadvantage of this class of compounds is their poor biodegradability.
  • EP 1 117 377 discloses cosmetic preparations containing mono-, di- and / or triester quats whose ester groups are derived from C 8 -C 18 coconut fatty acids.
  • EP 0 614 349 describes hair care compositions containing quaternized fatty acid trialkanolamine ester salts with acyl groups, preferably derived from the octadecene-9-acid having a trans double bond content of 40 to 70% by weight.
  • WO 96/03970 discloses that diester quats whose ester groups are derived from rapeseed oil and contain up to 3 double bonds are particularly advantageous in Hair care products can be used and are characterized by improved conditioning effects and hair combability.
  • esterquats mentioned in the prior art are their insufficient stability, in particular under the influence of light and oxygen.
  • active ingredients for conditioning the skin and the hair which develop a good effect even at low levels of use and are environmentally less burdensome.
  • the aim was thus to remedy or at least reduce the disadvantages of the prior art, and in particular to develop active ingredients which are well formulated, show improved conditioning effects and, in particular, improve the combability of wet and dry hair, reduce static, reduce the grip improve and cause gloss and color protection of the hair.
  • active ingredients which, despite their good biodegradability, have excellent conditioning properties and, moreover, good skin tolerance.
  • the development of active substances should in particular also include the possibility of providing the active ingredients in the form of compositions, which may then already be formulated.
  • Diethanolaminesterquats which are characterized in that the two ester groups carry long-chain saturated acyl radicals having 18 to 24 carbons, or by special compositions containing such
  • Diethanolaminesterquats show improved effects in terms combability, gloss, color protection, anti-static and skin feel.
  • these Diethanolaminesterquats are characterized by a much higher color stability compared to unsaturated esterquats. This stability has a positive effect on the storage of Diethanolaminesterquats, since color and smell does not change even after prolonged storage at a higher temperature.
  • diethanolamine ester quats have better storage stability.
  • effect when used in hair and skin care products have a higher viscosity and thus improved stability of the cosmetic formulation. Despite the good conditioning properties, diethanolamine ester quats are readily biodegradable.
  • compositions comprising one or more compounds of the formula (1)
  • R 1 CO and R 2 CO independently of one another are linear or branched saturated acyl groups having 18 to 24 C atoms and
  • a * is a counterion
  • C 8-23 alkyl-COO-groups preferably the total amount of C 9-23 alkyl-COO-groups, based on all of the groups R 1 COO- and R 2 COO-, 40.0 wt % or more, and preferably 42.0 wt% or more.
  • compositions are spoken of when there is a physical mixture of two or more chemical compounds.
  • the compositions according to the invention may therefore be mixtures of two or more compounds of the formula (1). However, they can also be compositions which contain only one or more compounds of the formula (1) and, in addition, one or more other compounds. These compositions may, for. B. End-use compositions, such as already formulated cosmetic, dermatological or pharmaceutical compositions.
  • R 1 CO and R 2 CO independently of one another are linear or branched saturated acyl groups having 18 to 24 C atoms
  • R 1 and R 2 in formula (1) are independent each other are linear or branched alkyl groups having 17 to 23 carbon atoms.
  • radicals R 1 and R 2 of the compounds of the formula (1) are preferably, independently of one another, linear alkyl groups having 17 to 23 C atoms.
  • the total amount of C 19 alkyl COO, C 2 r alkyl COO and C 2 3 alkyl COO groups based on all groups R 1 COO and R 2 COO-, 40th , 0 wt .-% or more and preferably 42.0 wt .-% or more.
  • the total amount of Cig-alkyl-COO and C2i-alkyl-COO groups based on all groups R 1 COO and R 2 COO-, 40.0 wt .-% or more and preferably 42.0% by weight or more.
  • the total amount of C 2 i-alkyl-COO groups based on all groups R 1 COO and R 2 COO-, 40.0 wt .-% or more and preferably 42.0 wt .-% or more.
  • compositions of the invention are characterized in that a plurality of compounds of the formula (1) are contained therein and the amount of Ci 7 alkyl COO groups of the compounds of formula (1), based on all groups
  • R 1 COO and R 2 COO from 1, 0 to 45.0 wt .-%
  • the amount of Ci 9 alkyl COO groups of the compounds of formula (1), based on all groups R 1 COO - and R 2 is COO-, from 1, 0 to 15.0 wt .-%
  • the amount of C 2 alkylR-COO groups of the compounds of formula (1), based on all groups R 1 COO and R 2 COO-, from 42.0 to 94.0 wt .-% is.
  • compositions according to the invention are characterized in that several
  • Compounds of formula (1) are contained therein and the amount of Ci 7 alkyl COO groups of the compounds of formula (1), based on all groups R 1 COO and R 2 COO-, from 41, 0 to 45, 0 wt .-%, the amount of C 19 alkyl COO groups of the compounds of formula (1), based on all groups R 1 COO and R 2 COO-, from 9.0 to 13.0 wt. -%, and the amount of C 2 i-alkyl-COO groups of the compounds of formula (1), based on all groups R 1 COO and R 2 COO-, from 42.0 to 46.0 wt. % is.
  • compositions of the invention are characterized in that a plurality of compounds of the formula (1) are contained therein and the amount of Ci 7 alkyl COO groups of the compounds of the formula (1), based on all Groups R 1 COO and R 2 COO, from 1, 0 to 6.0 wt .-%, the amount of C 19 alkyl COO groups of the compounds of formula (1), based on all groups R 1 COO and R 2 COO-, from 12.0 to 15.0 wt .-%, and the amount of C 2 i-alkyl-COO groups of the compounds of formula (1), based on all groups R 1 COO - and R 2 COO-, from 79.0 to 84.0 wt .-% is.
  • compositions of the invention are characterized in that a plurality of compounds of formula (1) are contained therein and the amount of C ⁇ alkyl COO groups of the compounds of formula (1), based on all Groups R 1 COO and R 2 COO, from 1, 0 to 6.0 wt .-%, the amount of C 19 alkyl COO groups of the compounds of formula (1), based on all groups R 1 COO and R 2 COO-, from 1, 0 to 6.0 wt .-%, and the amount of C 2 i-alkyl-COO groups of the compounds of formula (1), based on all groups R 1 COO - and R 2 COO-, from 90.0 to 94.0 wt .-% is.
  • the amount of C 23 alkyl COO groups of the compounds of the formula (1), based on all groups R 1 COO and R 2 COO-, in the compositions according to the invention up to 3.0 Wt .-%, preferably from 0.5 to 2.5 wt .-% and particularly preferably from 1, 0 to 2.0 wt .-%.
  • compositions of the invention are characterized in that a plurality of compounds of the formula (1) are contained therein and the amount of Ci 7 alkyl COO groups of the compounds of the formula (1), based on all Groups R 1 COO and R 2 COO, from 1, 0 to 5.0 wt .-%, the amount of Cig-alkyl COO groups of the compounds of formula (1), based on all groups R 1 COO and R 2 is COO-, from 6.0 to 10.0 wt .-%, and the amount of C 2 i-alkyl-COO groups of the compounds of formula (1), based on all groups R 1 COO- and R 2 is COO-, from 86.0 to 90.0 wt%.
  • compositions according to the invention preference is again given to those in which the amount of C 23 -alkyl-COO groups of the compounds of the formula (1), based on all groups R 1 COO- and R 2 COO-, of 1, 0 to 5, 0 wt .-% is.
  • compositions according to the invention comprise one or more compounds of the formula (1) in which R 1 and R 2 are linear or branched, preferably linear, alkyl groups having 21 C atoms.
  • compositions according to the invention comprise one or more compounds of the formula (1) and one or more compounds of the formula (2)
  • R 3 CO and R 4 CO independently of one another are linear or branched saturated acyl groups having 12 to 24 C atoms, preferably having 18 to 24 C atoms, or linear or branched mono- or polyunsaturated acyl groups having 12 to 24 C atoms, preferably with 18 to 24 carbon atoms, wherein at least one of the groups R 3 CO and R 4 CO must be a mono- or polyunsaturated acyl group, and
  • the amount of the compounds of the formula (2) is less than 20.0 wt .-%, preferably less than 10.0 wt .-%, particularly preferably less as 5.0 wt .-% and particularly preferably less than 1, 0 wt .-%, is.
  • compositions according to the invention are those in which no compound of the formula (2) is contained.
  • the counterions A ' or A " and B ' are preferably independently selected from chloride, bromide, methosulfate MeSO 4 ' (where Me is methyl CH 3 ), tosylate, phosphate, Sulfate, hydrogen sulfate, lactate and citrate, more preferably from chloride and methosulfate MeSO 4 ' .
  • Particularly preferred are the counterions A ' or A " and B ' chloride.
  • the quaternary esterquats of formula (1) are characterized by an excellent conditioning effect.
  • the compositions according to the invention contain, based on the total composition, from 0.1 to 10.0 wt .-%, and preferably from 1, 0 to 5.0 wt .-% of the one or more compounds of the formula (1).
  • the compositions of the invention z.
  • cosmetic, dermatological or pharmaceutical compositions As cosmetic, dermatological or pharmaceutical compositions.
  • compositions according to the invention comprising one or more unbranched or branched monoalcohols having an alkyl group having 8 to 22 carbon atoms, and preferably, based on the total composition, of 0.1 to 70.0 wt .-% of one or several of these substances.
  • Preferred such monoalcohols are lauryl alcohol, stearyl alcohol, cetyl alcohol, guerbet alcohol and behenyl alcohol.
  • the composition therefore contains one or more monoalcohols having an alkyl group having 1 to 7 carbon atoms, and preferably, based on the total composition, from 0.1 to 70.0 wt .-% of one or several of these substances.
  • Ethanol, propanol, isopropanol, butanol, isobutanol and t-butanol, particularly preferably isopropanol, are preferably used as monoalcohols.
  • the composition contains one or more polyols having 3 to 12 C atoms, and preferably, based on the total composition, from 0.1 to 70.0 wt .-% of one or more of these substances.
  • polyhydric alcohols i. Polyols, preferably pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, diglycerol, triglycerol, dipropylene glycol, tripropylene glycol, sorbitol, xylitol, mannitol and / or mixtures thereof.
  • Polyols are 1,5-pentanediol, 1, 2-pentanediol, 1, 6-hexanediol, 1, 2-hexanediol, 1, 7-heptanediol, 1, 2-heptanediol, 1, 8-octanediol, 1, 2-octanediol , 1, 9-nonanediol, 1, 2-nonanediol, 1, 10-decanediol, 1, 2-decanediol, 1, 11-undecanediol, 1, 2-undecanediol, 1, 12-dodecanediol, 1, 2-dodecanediol, diglycerol , Triglycerin, dipropylene glycol, tripropylene glycol, sorbitol, xylitol, mannitol and / or mixtures thereof.
  • compositions according to the invention contain diethanolmethylamine and preferably, based on the total composition, from 10 ppm to 1.0% by weight of diethanolmethylamine.
  • small amounts of diethanolmethylamine and small amounts of one or more fatty acids of the formula R 13 COOH and R 23 COOH, wherein R 13 CO and R 23 CO independently of one another linear or branched acyl groups having 18 to 24 carbon atoms and preferably linear or branched saturated acyl groups having 18 to 24 carbon atoms, may be advantageous.
  • the inventive compositions contain one or more fatty acids of the formula R 13 COOH and R 23 COOH, wherein R 13 CO and R 23 CO independently of one another linear or branched acyl groups having 18 to 24 carbon atoms, preferably linear or branched saturated acyl groups having 18 to 24 carbon atoms, are, and preferably, based on the total Composition, from 10 ppm to 1, 0 wt .-% of one or more of these substances.
  • the conditioning effect of the composition according to the invention can be increased by adding N-modified silicones.
  • compositions according to the invention contain alkyl methicones, alkyl dimethicones or one or more amodimethicones.
  • Amodimethicones are siloxanes polymers grafted with amino-functional groups.
  • Amodimethicones are z. B. under the trade name Dow Corning 2-8566 Amino Fluid (Dow Coming Corporation), Mirasil ADME (Rhodia), SilCare ® Silicone SEA (Clariant) or Wacker-Belsil ADM 1100 (Wacker Chemie AG) known, have a molecular weight between 800 and 260000 g / mol and correspond in general to the formula (3)
  • R 5 is -OH or -CH 3
  • X is a linear or branched C 1 -C 6 -alkylene group and each of x, y and z is independently from 1 to 5500, preferably from 50 to 500.
  • compositions according to the invention contain one or more of the abovementioned compounds of the formula (3) and, preferably, based on the whole Composition, 0.1 to 5.0 wt .-% of one or more compounds of formula (3).
  • Compatibility with other ingredients, as well as the skin feel and the antistatic effect of the composition can be achieved by adding one or more compounds of the formula (4)
  • R 10 CO is a linear or branched, preferably a linear, furthermore preferably a saturated, acyl group having 18 to 24 C atoms, preferably having 18 to 22 C atoms, and
  • compositions according to the invention comprise one or more compounds of the formula (4)
  • R 1c CO is a linear or branched, preferably a linear, more preferably a saturated, acyl group, having 18 to 24 carbon atoms, preferably having 18 to 22 carbon atoms, and A 'is a counterion
  • the counterion A "of the formula (4) is preferably selected from chloride, bromide, methosulfate MeSO 4 " , tosylate, phosphate, sulfate, hydrogensulfate, lactate and citrate, and more preferably selected from chloride and methosulfate MeSO 4 " .
  • compositions of the invention may be, for. As to pellets, lozenges, flakes, flakes, extrudates, pastes, compacts, powders, but also to emulsions or dispersions.
  • compositions according to the invention are dispersions.
  • compositions according to the invention comprise one or more nonionic emulsifiers, and preferably, based on the total composition, from 0.1 to 5.0% by weight of one or more nonionic emulsifiers.
  • Suitable nonionic emulsifiers are preferably addition products of from 0 to 30 mol of ethylene oxide and / or from 0 to 5 mol
  • Polyglycerol polyricinoleate and polyglycerol poly-12-hydroxystearate are also preferably suitable.
  • fatty alcohol ethoxylates selected from the group consisting of the ethoxylated stearyl alcohols, isostearyl alcohols, cetyl alcohols, isocetyl alcohols, oleyl alcohols, lauryl alcohols, isolauryl alcohols, cetylstearyl alcohols, in particular polyethylene glycol (13) stearyl ether, polyethylene glycol (14) stearyl ether, polyethylene glycol (15) stearyl ether, polyethylene glycol ( 16) stearyl ether, polyethylene glycol (17) stearyl ether, polyethylene glycol (18) stearyl ether, polyethylene glycol (19) stearyl ether, polyethylene glycol (20) stearyl ether, polyethylene glycol (12) isostearyl ether, polyethylene glycol (13) isostearyl ether, polyethylene glycol (14) isostearyl ether, polyethylene glycol (15) isostearyl ether, polyethylene glycol (15) isoste
  • fatty acid ethoxylates selected from the group consisting of ethoxylated stearates, isostearates and oleates, in particular polyethylene glycol (20) stearate, polyethylene glycol (21) stearate, polyethylene glycol (22) stearate, polyethylene glycol (23) stearate, polyethylene glycol (24) stearate, polyethylene glycol ( 25) stearate,
  • the sodium laureth-11-carboxylate can be advantageously used.
  • polyethylene glycol (60) evening primrose glycerides can be used with advantage.
  • polyethylene glycol glycerol fatty acid esters from the group polyethylene glycol (20) glyceryl laurate,
  • sorbitan esters are polyethylene glycol (20) sorbitan monolaurate, polyethylene glycol (20) sorbitan monostearate, polyethylene glycol (20) sorbitan monoisostearate, Polyethylene glycol (20) sorbitan monopalmitate, polyethylene glycol (20) sorbitan monooleate.
  • glyceryl monostearate glyceryl monooleate, diglyceryl monostearate, glyceryl isostearate, polyglyceryl-3-oleate, polyglyceryl-3-diisostearate, polyglyceryl-4-isostearate, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl-4-dipolyhydroxystearate, PEG-30-dipolyhydroxystearate, diisostearoylpolyglyceryl 3-diisostearate, glycol distearate and polyglyceryl-3-dipolyhydroxystearate, sorbitan monoisostearate, sorbitan stearate, sorbitan oleate, sucrose distearate, lecithin, PEG-7 hydrogenated castor oil, cetyl alcohol, stearyl alcohol, behenyl alcohol, isobehenyl alcohol and
  • compositions according to the invention are cosmetic, dermatological or pharmaceutical compositions.
  • the cosmetic, dermatological or pharmaceutical compositions according to the invention are preferably skin care agents and hair treatment agents.
  • Examples of preferred cosmetic, dermatological or pharmaceutical compositions according to the invention are 2-in-1 shower baths,
  • compositions according to the invention are oil-in-water emulsions, preferably oil-in-water emulsions for the treatment or care of the skin.
  • compositions according to the invention are compositions for the treatment or care of hair, for example shampoos, rinse-off hair conditioners, cream rinses, rinses, hair treatments, hair colorants and hair colorants, permanent waving agents, hair gels, hair conditioners Aerosol, spray and fluid forms.
  • the cosmetic, dermatological and pharmaceutical compositions may contain as further auxiliaries and additives all customary surfactants, oil bodies, cationic polymers, film formers, thickening and gelling agents, superfatting agents, antimicrobial and biogenic agents, moisturizing agents, stabilizers, preservatives, pearlescing agents, dyes and fragrances , contain.
  • surfactants cationic, nonionic, amphoteric and / or zwitterionic surfactants can be used.
  • Preferred cationic surfactants are quaternary ammonium salts, such as di- (Cs-C ⁇ ) -alkyl-dimethylammonium chloride or bromide, preferably di (C 8 -C 22 ) -alkyldimethylammonium chloride or bromide; (C 8 -C 22 ) alkyldimethyl-dimethylammonium chloride or bromide; (C 8 -C 22 ) alkyltrimethylammonium chloride or bromide, preferably cetyltrimethylammonium chloride or bromide, and (C 8 -C 22 ) -alkyl-trimethyl-ammonium chloride or bromide; (C 10 -C 24 ) -alkyldimethylbenzyl-ammonium chloride or bromide, preferably (C 1 -C 8 -alkyl) -dimethylbenzyl-ammonium chloride, (C 8 -C 22 ) -alkyl
  • the amount of cationic surfactants is preferably from 0.1 to 10.0 wt .-%, particularly preferably from 0.5 to 7.0 wt .-% and particularly particularly preferably from 1, 0 to 5.0 wt .-% , based on the finished compositions.
  • Preferred nonionic surfactants are fatty alcohol ethoxylates (alkylpolyethylene glycols); Alkylphenolpolyethylenglykole; Fatty amine ethoxylates (alkylaminopolyethylene glycols); Fatty acid ethoxylates (acyl polyethylene glycols); Polypropylenglykolethoxylate (Pluronics ®); Fatty acid alkanolamides, (fatty acid amide polyethylene glycols); Saccharoseester; Sorbitol esters and sorbitan esters and their polyglycol ethers, and C 8 -C 22 -Alkylpolyglucoside.
  • the amount of nonionic surfactants in the compositions according to the invention is preferably in the range from 1.0 to 20.0% by weight, particularly preferably from 2.0 to 10.0 Wt .-% and particularly preferably from 3.0 to 7.0 wt .-%.
  • compositions of the invention may contain amphoteric surfactants. These may be described as derivatives of long chain secondary or tertiary amines having an alkyl group of 8 to 18 carbon atoms and in which another group is substituted with an anionic group that mediates water solubility, such as. B. with a carboxyl, sulfate or sulfonate group.
  • amphoteric surfactants are N- (C 2 -C 8) alkyl-.beta.-aminopropionates and N- (C 2 -C 8) alkyl-beta-iminodipropionates as alkali metal and mono-, di- and trialkylammonium salts.
  • Suitable further surfactants are also amine oxides. These are oxides of tertiary amines with a long-chain group of 8 to 18 carbon atoms and two mostly short-chain alkyl groups with 1 to 4 carbon atoms.
  • the C- are here, for example, o- t to C 8 alkyl dimethyl, FettTexreamidoalkyl-dimethylamine.
  • betaine surfactants also called zwitterionic surfactants. These contain in the same molecule a cationic group, in particular an ammonium group and an anionic group, which may be a carboxylate group, sulfate group or sulfonate group.
  • Suitable betaines are preferably alkylbetaines such as coco-betaine or fatty acid alkylamidopropylbetaines, for example cocoacylamidopropyldimethylbetaine or the C 12 - bis Ci 8 -Dimethylaminohexanoate or the C 10 - to Ci ⁇ -Acylamidopropandimetylbetaine.
  • the amount of the amphoteric surfactants and / or betaine surfactants is preferably from 0.5 to 20.0 wt .-% and particularly preferably from 1, 0 to 10.0 wt .-%.
  • Preferred surfactants are cocoamidopropyl betaine, alkyl betaines such as coco-betaine, sodium cocoyl glutamate and lauroamphoacetate.
  • Compositions additionally as foam-enhancing agents co-surfactants from the group of Aikylbetaine, Alkylamidobetaine, Aminopropionate, Aminoglycinate, Imidazoliniumbetaine and sulfobetaines, amine oxides, fatty acid alkanolamides and polyhydroxyamides.
  • the oil bodies may advantageously be selected from the groups of triglycerides, natural and synthetic fatty bodies, preferably esters of fatty acids with lower C-number alcohols, e.g. As with isopropanol, propylene glycol or glycerol, or esters of fatty alcohols with alkanoic acids low C number or with fatty acids or from the group of alkyl benzoates, and natural or synthetic hydrocarbon oils.
  • esters of fatty acids with lower C-number alcohols e.g. As with isopropanol, propylene glycol or glycerol, or esters of fatty alcohols with alkanoic acids low C number or with fatty acids or from the group of alkyl benzoates, and natural or synthetic hydrocarbon oils.
  • triglycerides come from linear or branched, saturated or unsaturated, optionally hydroxylated, C 8 -C 3 o-fatty acids, in particular vegetable oils, such as sunflower, corn, soybean, rice, jojoba, Babusscu-, pumpkin , Grape seed, sesame, walnut, apricot, orange, wheat germ, peach kernel, macadamia, avocado, sweet almond, meadowfoam, castor oil, olive oil, peanut oil, rapeseed oil and coconut oil, as well as synthetic triglyceride oils, e.g. As the commercial product Myritol ® 318. Also hardened triglycerides are inventively preferred.
  • oils of animal origin for example beef tallow, perhydrosqualene, lanolin can be used.
  • Another class of oil bodies preferred according to the invention are the benzoic acid esters of linear or branched C ⁇ - 22- alkanols, eg. , The commercial products Finsolv ® SB (isostearyl benzoate), Finsolv ® TN (C 12 -C 15 - alkyl benzoate) and Finsolv EB ® (ethylhexyl).
  • dialkyl ethers having a total of 12 to 36 carbon atoms, in particular having 12 to 24 carbon atoms, such as di-n-octyl ether (Cetiol ® OE), di-n-nonyl ether, di-n-decyl ether, di n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl n-undecyl ether , Di-3-ethyldecyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether
  • branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms for.
  • hydroxycarboxylic acid alkyl esters are full esters of glycolic acid, lactic acid, malic acid, tartaric acid or citric acid. Further basically suitable esters of the hydroxycarboxylic acids are esters of ⁇ -hydroxypropionic acid, tartronic acid, D-gluconic acid, sugar acid, mucic acid or glucuronic acid.
  • esters of Ci 2 -Ci 5 fatty alcohols are particularly preferred. Esters of this type are commercially available, e.g. B. under the trade name Cosmacol ® the EniChem, Augusta Industriale.
  • Another class of the present invention preferred oily substances are dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, such as
  • Di-n-butyl adipate (Cetiol ® B), di- (2-ethylhexyl) adipate and di- (2-ethylhexyl) succinate and diol esters such as ethylene glycol dioleate, ethylene glycol-di-isotridecanoat, propylene glycol di- (2- ethylhexanoate), propylene glycol di-isostearate, propylene glycol di-pelargonat, butanediol di-isostearate and neopentyl glycol dicaprylate and di-isotridecylvestat.
  • diol esters such as ethylene glycol dioleate, ethylene glycol-di-isotridecanoat, propylene glycol di- (2- ethylhexanoate), propylene glycol di-isostearate, propylene glycol di-pelargonat, butaned
  • oil bodies are symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, glycerol carbonate or dicaprylyl carbonate (Cetiol ® CC).
  • Another class of inventively preferred oil bodies are the esters of dimers of unsaturated C 2 -C 22 fatty acids (dimer fatty acids) with monovalent linear, branched or cyclic C 2 -C 8 -alkanols or with polyvalent linear or branched
  • hydrocarbon oils for example those with linear or branched, saturated or unsaturated C 7 -C 4 o-carbon chains, for example Vaseline, dodecane, isododecane, cholesterol, lanolin, synthetic hydrocarbons such as polyolefins, in particular polyisobutene, hydrogenated Polyisobutene, polydecane, and hexadecane, isohexadecane, paraffin oils, isoparaffin oils, e.g. As the commercial products of Permethyl ® series, squalane, squalene, and alicyclic hydrocarbons, eg. Example, the commercial product 1, 3-di- (2-ethyl-hexyl) -cyclohexane (Cetiol ® S), ozokerite, and ceresin.
  • hydrocarbon oils for example those with linear or branched, saturated or unsaturated C 7 -C 4 o-carbon chains, for example Vaseline, dodecane, is
  • Methyl, and x is a number from 2 to 500, for example the dimethicones available under the trade names VICASIL (General Electric Company), DOW CORNING 200, DOW CORNING 225, DOW CORNING 200 (Dow Corning Corporation), and those under SilCare ® Silicone 41M65, SilCare ® Silicone 41 M70, SilCare ® Silicone 41 M80 (Clariant) Dimethicone available, Stearyldimethylpolysiloxan, C 2 ° C 24 alkyl dimethyl polysiloxane, C 24 -C 28 -Ikyl- dimethylpolysiloxane, but also the under SilCare ® Silicone 41 M40, SilCare ® Silicone 41M50 (Clariant) available methicones, furthermore trimethylsiloxysilicate [(CH 2) 3 SiO) 1/2] ⁇ [SiO 2 ] y , where x is a number from 1 to 500 and y is a
  • Suitable cationic polymers are those known by the INCI name "Polyquaternium", in particular Polyquaternium-31, Polyquaternium-16, Polyquaternium-24, Polyquaternium-7, Polyquaternium-22, Polyquaternium-39, Polyquaternium-28, Polyquaternium-2, Polyquaternium -10, Polyquaternium-11, Polyquaternium 37 & mineral oil & PPG trideceth (Salcare SC95), PVP-dimethylaminoethyl methacrylate copolymer, guar hydroxypropyl triammonium chlorides, calcium alginate and ammonium alginate, cationic cellulose derivatives, cationic starch, copolymers of diallyl ammonium salts and acrylamides quaternized vinylpyrrolidone / vinylimidazole polymers; condensation products of polyglycols and amines; quaternized collagen polypeptides; quaternized wheat polypeptides; polyethylenimines;
  • compositions according to the invention may contain one or more of the abovementioned cationic polymers in amounts of from 0.1 to 5.0% by weight, preferably from 0.2 to 3.0% by weight and more preferably from 0.5 to 2, 0 wt .-%, based on the finished compositions.
  • compositions containing film-forming agents according to the invention which are selected depending on the application of salts of phenylbenzimidazolesulfonic acid, water-soluble polyurethanes, for example C l o-Polycarbamylpolyglycerylester, polyvinyl alcohol, Polyvinylpyrrolidoncopolymeren as PVP / Hexandecene or PVP / Eicosene
  • Copolymer for example vinylpyrrolidone / vinyl acetate copolymer, water-soluble acrylic acid polymers / copolymers or their esters or salts, for example partial acrylic / methacrylic acid and polyethylene glycol ethers of fatty alcohols, such as acrylate / steareth-20-methacrylate copolymer, water-soluble cellulose, for example hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, water-soluble Quaterniums, polyquaterniums, carboxyvinyl polymers, such as carbomers and their salts, polysaccharides, for example Polydextrose and glucan, vinyl acetate / crotonate, for example under the trade name Aristoflex ® A 60 (Clariant) available, and polymeric amine oxides, for example under the trade names Diaformer Z-711 , 712, 731, 751 available agents.
  • compositions according to the invention may contain one or more film formers in amounts of from 0.1 to 10.0% by weight, preferably from 0.2 to 5.0% by weight and more preferably from 0.5 to 3.0% by weight. %, based on the finished compositions.
  • the desired viscosity of the compositions can be adjusted by adding thickeners and gelling agents.
  • Cellulose ethers and other cellulose derivatives eg.
  • metal salts of fatty acids preferably of 12 to 22 carbon atoms, for example sodium stearate, sodium palmitate, sodium laurate, sodium arachidates, sodium behenate, potassium stearate, potassium palmitate, sodium myristate, aluminum monostearate, hydroxyfatty acids, for example 12-hydroxystearic acid, 16-hydroxyhexadecanoic acid; fatty acid amides; fatty acid; Dibenzal sorbitol and alcohol-soluble polyamides and polyacrylamides or mixtures thereof.
  • crosslinked and uncrosslinked polyacrylates such as carbomer, sodium polyacrylates or sulfonic acid-containing polymers such as Ammoniumacryloyldimethyltaurate / VP copolymer can be used.
  • compositions according to the invention preferably contain from 0.01 to 20.0% by weight, more preferably from 0.1 to 10.0% by weight, particularly preferably from 0.2 to 3.0% by weight, and very particularly preferably from 0.4 to 2.0 wt .-% of thickeners or gelling agents.
  • Antimicrobial agents include cetyltrimethylammonium chloride, cetylpyridinium chloride, benzethonium chloride, diisobutylethoxyethyldimethylbenzylammonium chloride, sodium N-laurylsarcosinate, sodium N-palmethyl sarcosinate, lauroylsarcosine, N-myristoylglycine, potassium N-laurylsarcosine, trimethylammonium chloride, sodium aluminum chlorohydroxylactate, triethyl citrate,
  • Propylparaben, and their Na salts pentanediol, 1, 2-octanediol, 2-bromo-2-nitropropane-1, 3-diol, ethylhexylglycerol, benzyl alcohol, sorbic acid, benzoic acid, lactic acid, imidazolidinylurea, Diazolidinylhamstoff, Dimethyloldimethylhydantoin (DMDMH), Na -SaIz of hydroxymethylglycinate, hydroxyethylglycine of sorbic acid and combinations of these active substances used.
  • compositions according to the invention preferably contain the antimicrobial agents in amounts of from 0.001 to 5.0% by weight, more preferably from 0.01 to 3.0% by weight and especially preferably from 0.1 to 2.0% by weight. , based on the finished compositions.
  • compositions according to the invention may further comprise biogenic active substances selected from plant extracts, such as aloe vera, as well as local anesthetics, antibiotics, antiphlogistics, antiallergic agents, corticosteroids, and
  • Sebostats bisabolol ®, allantoin ®, phytantriol ®, proteins, vitamins selected from niacin, biotin, vitamin B2, vitamin B3, vitamin B6, vitamin B3 derivatives (salts, acids, esters, amides, alcohols), vitamin C and vitamin C derivatives (Salts, acids, esters, amides, alcohols), preferably as the sodium salt of the monophosphoric acid ester of ascorbic acid or as the magnesium salt of
  • Phosphoric acid esters of ascorbic acid, tocopherol and tocopherol acetate, and vitamin E and / or its derivatives are Phosphoric acid esters of ascorbic acid, tocopherol and tocopherol acetate, and vitamin E and / or its derivatives.
  • compositions according to the invention may contain biogenic active substances preferably in amounts of from 0.001 to 5.0% by weight, particularly preferably from 0.01 to 3.0% by weight and especially preferably from 0.1 to 2.0% by weight, based on the finished compositions.
  • the compositions according to the invention may contain astringents, preferably magnesium oxide, aluminum oxide, titanium dioxide, zirconium dioxide and zinc oxide, oxide hydrates, preferably alumina hydrate (boehmite) and hydroxides, preferably of calcium, magnesium, aluminum, titanium, zirconium or zinc, and aluminum chlorohydrates, preferably in amounts of from 0 to 50 , 0 wt .-%, more preferably in amounts of 0.01 to 10.0 wt .-% and particularly preferably in amounts of 0.1 to 10.0 wt .-%.
  • Preferred deodorants are allantoin and bisabolol. These are preferably used in amounts of 0.0001 to 10.0 wt .-%.
  • isopropyl palmitate, glycerol and / or sorbitol are available as a moisturizing substance.
  • metal salts of fatty acids such as. As magnesium, aluminum and / or zinc stearate, preferably in amounts of 0.1 to 10.0 wt .-%, preferably from 0.5 to 8.0 wt .-% and particularly preferably from 1, 0 to 5.0 wt .-%, based on the finished compositions.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol and sorbic acid.
  • pearlescing component are preferably suitable fatty acid monoalkanolamides, fatty acid dialkanolamides, monoesters or diesters of alkylene glycols, in particular ethylene glycol and / or propylene glycol or its oligomers, with higher fatty acids, such as. As palmitic acid, stearic acid and behenic acid, monoesters or polyesters of glycerol with carboxylic acids, fatty acids and their metal salts, ketosulfones or mixtures of said compounds. Particularly preferred are ethylene glycol distearates and / or polyethylene glycol distearates with an average of 3 glycol units.
  • compositions according to the invention contain pearlescing compounds, these are preferably present in an amount of from 0.1 to 15.0 wt .-% and particularly preferably in an amount of 1, 0 to 10.0 wt .-% in the inventive compositions.
  • fragrance or perfume oils can individual fragrance compounds, eg.
  • ethers, aldehydes, ketones, alcohols and hydrocarbons are used.
  • Fragrance compounds of the ester type are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethylacetate, linalylbenzoate, benzylformate, ethyl-methylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate and benzylsalicylate.
  • the ethers include, for example, benzyl ethyl ether to the aldehydes z.
  • the linear alkanals having 8 to 18 carbon atoms citral, citronellal, citronellyloxyacetaldehyde, cycloalanine, Hydroxycitronellal, Lilial and Bourgeonal, to the ketones z.
  • the alcohols include anethole, citronellol, eugenol, geranion, linalol, phenylethyl alcohol and terpineol
  • the hydrocarbons include mainly the terpenes and balsams.
  • mixtures of different fragrances are used, which together produce an attractive fragrance.
  • Perfume oils may also contain natural fragrance mixtures, such as those available from plant or animal sources, e.g. Pine, citrus, jasmine, lily, rose, or ylang-ylang oil. Also essential oils of lower volatility, which are mostly used as aroma components, are suitable as perfume oils, eg. B. sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon oil, lime blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil and ladanum oil.
  • perfume oils eg. B. sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon oil, lime blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil and ladanum oil.
  • compositions according to the invention are preferably adjusted to a pH in the range from 2 to 12, preferably in the range from 3 to 9.
  • acids or alkalis for pH adjustment preferably mineral acids, in particular HCl, inorganic bases, in particular NaOH or KOH, or organic acids, in particular citric acid, are used.
  • the total amount of auxiliaries and additives in the compositions or in the compositions according to the invention is preferably from 1.0 to 50.0% by weight and more preferably from 5.0 to 40.0% by weight.
  • compositions according to the invention can also be easily formulated in special embodiments.
  • compositions according to the invention may thus z. B. also be ready-to-masses, but also - as already mentioned - produced from these masses pellets or lozenges or flakes or flakes.
  • the inventive compositions provide attachable, preferably pelletisable or pastillierbare or schuppbare or can be converted into flake form, masses represent, which have low stick and melting points of up to 100 0 C.
  • the formable compositions according to the invention are preferably processed into pellets or pellets or flakes. These pellets or flakes or flakes according to the invention preferably also have low sticking and melting points of at most 100 ° C.
  • the ready-to-use compositions according to the invention and the pellets or flakes or flakes according to the invention preferably contain from 45.0 to 70.0% by weight of one or more compounds of the invention Formula (1) and from 30.0 to 55.0 wt .-% of one or more monoalcohols having an unbranched or branched alkyl group having 8 to 22 carbon atoms and particularly preferably from 47.0 to 60.0 wt .-% at one or a plurality of compounds of formula (1) and from 40.0 to 53.0 wt .-% of one or more monoalcohols having an unbranched or branched alkyl group having 8 to 22 carbon atoms.
  • the monoalcohols cetyl alcohol, stearyl alcohol and combinations thereof are preferred.
  • the formable compositions according to the invention and the pellets or flakes or flakes according to the invention are free of monoalcohols having 1 to 7 C atoms and polyols with 3 to 12 carbon atoms.
  • these ready-to-use compositions according to the invention and the pellets or flakes or flakes according to the invention preferably the pellets or flakes or flakes according to the invention, those which are selected from the compounds of the formula (1) and the monoalcohols with a Alkyl group consisting of 8 to 22 carbon atoms.
  • the ready-to-use compositions according to the invention and the pellets or flakes or flakes according to the invention comprise one or more compounds selected from monoalcohols having 1 to 7 C atoms and polyols having 3 to 12 carbon atoms in an amount of up to 10.0 wt .-%, and preferably from 1, 0 to 6.0 wt .-%.
  • Preferred additives are isopropyl alcohol and dipropylene glycol.
  • the short-chain monoalcohols having 1 to 7 carbon atoms can contribute to improving the manufacturability.
  • the pellets or flakes or flakes according to the invention can advantageously be used for the production of cosmetic, dermatological or pharmaceutical compositions or formulations.
  • the compositions according to the invention, in particular the cosmetic, dermatological or pharmaceutical compositions according to the invention, are advantageously suitable for the treatment or care of the skin.
  • a further subject of the present invention is therefore the use of the compositions according to the invention, in particular of the cosmetic, dermatological or pharmaceutical compositions according to the invention, for the treatment or care of the skin.
  • compositions according to the invention in particular the cosmetic, dermatological or pharmaceutical compositions according to the invention, are furthermore advantageously suitable for the treatment or care of hair.
  • a further subject of the present invention is therefore the use of the compositions according to the invention, in particular of the cosmetic, dermatological or pharmaceutical compositions according to the invention, for the treatment or care of hair.
  • the diethanolamine ester quats of formula (1) can be obtained by a variety of relevant methods of preparative organic chemistry. Surveys on this topic are, for example, by R. Puchta et al. in tens. Surf. Det., 30, 186 (1993), M.Brock in Tens. Surf. Det. 30, 394 (1993), R. Lagerman et. al. in J. Am. OiI. Chem. Soc, 71, 97 (1994).
  • the alkylation can alternatively be carried out to methyl chloride with dimethyl sulfate, p-Toluolsulfonklarealkylester etc.
  • methyldiethanolamine dibehenate 307.2 g of methyldiethanolamine dibehenate (0.4 mol) are taken up in isopropanol and placed in a 1 liter glass autoclave. The autoclave is heated to about 70 0 C and 20.2 g of methyl chloride (0.4 mol) was added in portions to constant pressure. Subsequently, the pressure is released, the product is transferred to a flask and distilled off on a rotary evaporator isopropanol. 1.2. Preparation of further compounds of the formula (1)
  • A is ' Cl ' and R 1 is CO and R 2 CO is derived from
  • docosanoic acid didocosoylethyl dimonium chlorides
  • tetracosanoic acid ditetracosoylethyl dimonium chlorides
  • C2 fatty acid 0-22 Dibehenoylethyl Dimonium Chloride
  • the quaternization can take place in isopropanol instead of in one or more monoalcohols with an unbranched or branched alkyl group having 8 to 22 C atoms, preferably in cetyl and / or stearyl alcohol.
  • the compounds of the formula (1) resulting from the reaction, with or without compounds of the formula (2), can easily be melted in a weight ratio of 1: 1 with any mixture of cetyl alcohol and stearyl alcohol below 100 ° C. and pelletized, pasted, be scaled or converted into flake form.
  • the weight ratio of cetyl alcohol to stearyl alcohol is preferably from 1: 3 to 3: 1.
  • Example 11.1 Analogously to Example 11.1. be prepared masses, but instead of 0.2 mol of methyldiethanolamine dibehenate according to Example 1.1. 0.2 mol of the methyldiethanolamine-difatty acid ester, the in 1.2 1.2. mentioned Compounds (1b) and (1d) to (1i) are used. For each of these methyldiethanolamine difatty acid esters, the preparation of the formable compositions is carried out with the mixtures 1-5 from Table 1.
  • the molten ready-to-use mass is applied dropwise to a cooled treadmill so that it solidifies in the form of pellets or pastilles.
  • the molten ready-to-use mass is applied to a cooled treadmill in such a way that a film is formed from the respective meltable mass that can be prepared.
  • the film is allowed to solidify and shredded to flakes with a knife.
  • Example 2 Hair conditioner with vitamins and UV protection, leave on
  • Genamin ® CTAC (Clariant) of 0.50% Cetrimonium chloride wheat starch of 0.50% Belsil DMC 6032 0.80% Dimethicone Copolyol Acetate Dow Corning ® 190 of 0.50% Dimethicone copolyol
  • Example 8 2-Phase Conditioner Spray, leave on
  • Example 11 Hair rinse against greasy hair
  • a diethanolamine ester quat (according to Example 1f), 50% active 3.00% in cetyl alcohol: stearyl alcohol in a weight ratio of 70:30 (Ex 11a), 50:50 (ex 11b) and 30:70 (Ex 11c) as pellets or pastilles
  • PEG-4 polyglyceryl-2-stearate B water ad 100%
  • a Diethanolaminesterquat (according to Example 1g), 50% active 3.00% in cetyl alcohol: stearyl alcohol in a weight ratio of 70:30 (Ex 13a), 50:50 (ex 13b) and 30:70 (ex 13c) as flakes
  • Genagen CAB ® 818 (Clariant) 6.00% Cocamidopropyl Betaine Hostapon ® KCG (Clariant) 8.00% sodium cocoyl
  • Method of preparation I melting the components A at about 75 ° C. and dissolving in B with stirring.
  • Formulation Examples 11 to 13 are readjusted, but instead of the diethanolamine ester quats (1f), (1g) and (1 h), the diethanolamine ester quats (1e) and O
  • Diethanolamine ester quat (according to Table 2), 50% active 2.00% in cetyl alcohol: stearyl alcohol in a weight ratio of 50:50 as pellets or pastilles
  • the hair rinse according to Example 14 containing diethanolamine ester quat 1a represents a comparison formulation.

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Abstract

L'invention concerne des compositions contenant un ou plusieurs composés de formule (1) dans laquelle R1CO et R2CO représentent indépendamment l'un de l'autre des groupes acyles saturés linéaires ou ramifiés ayant 18 à 24 atomes C et A- représente un contre-ion et la quantité totale de groupes C18-23-alkyl-COO-, par rapport à tous les groupes R1COO- et R2COO- est de 40,0 % en poids ou plus. Les compositions sont par exemple des compositions cosmétiques, dermatologiques ou pharmaceutiques.
EP08801501A 2007-08-06 2008-07-31 Compositions contenant des composés quaternaires d'ester de diéthanolamine Withdrawn EP2187864A2 (fr)

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DE102007037018A DE102007037018A1 (de) 2007-08-06 2007-08-06 Zusammensetzungen enthaltend Diethanolaminesterquats
DE200810015899 DE102008015899A1 (de) 2008-03-27 2008-03-27 Zusammensetzungen enthaltend Diethanolaminesterquats
PCT/EP2008/006293 WO2009018955A2 (fr) 2007-08-06 2008-07-31 Compositions contenant des composés quaternaires d'ester de diéthanolamine

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US8361953B2 (en) 2008-02-08 2013-01-29 Evonik Goldschmidt Corporation Rinse aid compositions with improved characteristics
WO2011120822A1 (fr) 2010-04-01 2011-10-06 Evonik Degussa Gmbh Composition active d'adoucissant pour étoffe
MX2012011005A (es) * 2010-04-01 2012-10-15 Evonik Degussa Gmbh Composicion activa suavizante de tela.
CN102869757B (zh) 2010-04-28 2015-12-02 赢创德固赛有限公司 织物柔软组合物
DE102010029610B4 (de) * 2010-06-02 2013-02-21 Evonik Goldschmidt Gmbh Quartäre Dialkanolaminester
DE102010029606B4 (de) * 2010-06-02 2013-02-21 Evonik Goldschmidt Gmbh Quartäre Dialkanolaminester
US8507425B2 (en) 2010-06-29 2013-08-13 Evonik Degussa Gmbh Particulate fabric softener comprising ethylenediamine fatty acid amides and method of making
DE102011086924A1 (de) * 2011-11-23 2013-05-23 Henkel Ag & Co. Kgaa Haarkonditionierende Mittel
WO2013113453A1 (fr) 2012-01-30 2013-08-08 Evonik Industries Ag Composition active d'assouplissant pour textile
PL2847307T3 (pl) 2012-05-07 2016-10-31 Aktywna kompozycja do zmiękczania tkanin i sposób jej wytwarzania
US9265714B2 (en) 2013-09-26 2016-02-23 Colgate-Palmolive Company Cleansing composition comprising a cationic and nonionic surfactant mixture
BR102014025172B1 (pt) 2013-11-05 2020-03-03 Evonik Degussa Gmbh Método para fabricação de um éster de ácido graxo de metisulfato de tris-(2-hidroxietil)-metilamônio, e composição ativa de amaciante de roupa
UA119182C2 (uk) 2014-10-08 2019-05-10 Евонік Дегусса Гмбх Активна композиція для пом'якшувача тканини
WO2019177716A1 (fr) * 2018-03-13 2019-09-19 The Procter & Gamble Company Compositions de produits de consommation comprenant des microcapsules
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