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EP2083974B1 - Materiau leger a base de bois - Google Patents

Materiau leger a base de bois Download PDF

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Publication number
EP2083974B1
EP2083974B1 EP07821530.8A EP07821530A EP2083974B1 EP 2083974 B1 EP2083974 B1 EP 2083974B1 EP 07821530 A EP07821530 A EP 07821530A EP 2083974 B1 EP2083974 B1 EP 2083974B1
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EP
European Patent Office
Prior art keywords
wood
base material
filler
density
weight
Prior art date
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Application number
EP07821530.8A
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German (de)
English (en)
Other versions
EP2083974A2 (fr
Inventor
Lionel Gehringer
Stephan WEINKÖTZ
Günter Scherr
Frank Braun
Maxim Peretolchin
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BASF SE
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BASF SE
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Application filed by BASF SE filed Critical BASF SE
Priority to EP20110152229 priority Critical patent/EP2319670A1/fr
Priority to EP07821530.8A priority patent/EP2083974B1/fr
Priority to PL07821530T priority patent/PL2083974T3/pl
Publication of EP2083974A2 publication Critical patent/EP2083974A2/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/005—Manufacture of substantially flat articles, e.g. boards, from particles or fibres and foam
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249971—Preformed hollow element-containing
    • Y10T428/249972—Resin or rubber element
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/253—Cellulosic [e.g., wood, paper, cork, rayon, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254—Polymeric or resinous material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31895—Paper or wood
    • Y10T428/31899—Addition polymer of hydrocarbon[s] only
    • Y10T428/31902—Monoethylenically unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31975—Of cellulosic next to another carbohydrate
    • Y10T428/31978—Cellulosic next to another cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31975—Of cellulosic next to another carbohydrate
    • Y10T428/31978—Cellulosic next to another cellulosic
    • Y10T428/31982—Wood or paper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31989—Of wood

Definitions

  • the present invention relates to light wood materials containing 30 to 95 wt .-%, based on the wood material, wood particles, wherein the wood particles have a mean density of 0.4 to 0.85 g / cm 3 , 2.5 to 20 wt. %, based on the wood material, polystyrene and / or styrene copolymer as filler, wherein the filler has a bulk density of 30 to 100 kg / m 3 , and 2.5 to 50 wt .-%, based on the wood material, binder, wherein the average density of the light wood material is less than or equal to 600 kg / m 3 .
  • Wood-based panels are a cost-effective and resource-saving alternative to solid wood and have gained great importance in particular in furniture construction, laminate flooring and as building materials.
  • Starting materials serve wood particles of different strengths, eg. As wood chips or wood fibers from different woods.
  • wood particles are usually pressed with natural and / or synthetic binders and optionally with the addition of further additives to plate or strand-shaped wood materials.
  • chipboard comes mainly used in the manufacture of doors as an inner layer.
  • a disadvantage of these materials is the too low screw extraction resistance, the difficulty attaching fittings and the difficulties in edging.
  • CH 370229 is a light wood material, according to the preamble of claim 1 discloses, in particular lightweight and pressure-resistant molding materials are described which consist of wood chips or fibers, a binder and serving as a filler porous plastic. To produce the molding materials, the wood chips or fibers are mixed with binder and foamable or partially foamable plastics, and the resulting mixture is pressed at elevated temperature.
  • binders all conventional binders suitable for the gluing of wood, such as urea-formaldehyde resins, are useful.
  • Suitable fillers are foamable or already foamed plastic particles, preferably expandable thermoplastics such as styrene polymers.
  • the particle size of the plastics used is generally in prefoamed plastics 0.6 to 10 mm.
  • the plastics are used in an amount of 0.5 to 5 weight percent, based on the wood chips.
  • the plates described in the examples have a thickness of 18 to 21 mm, a density of 220 kg / m 3 to 430 kg / m 3 and an average bending strength of 3.6 N / mm 2 to 17.7 N / mm 2 on.
  • the transverse tensile strengths are not specified in the examples.
  • WO 02/38676 describes a process for the preparation of light products, in which 5 to 40 wt .-% foamable or already foamed polystyrene having a particle size of less than 1 mm, 60 to 95 wt .-% lignocellulosic material and binder mixed and at elevated temperature and elevated pressure be pressed into the finished product, wherein the polystyrene melts and on the one hand impregnates the lignocellulosic material and on the other hand by the migration to the surface of the product forms a hard, water-resistant skin.
  • urea-formaldehyde resin or melamine-formaldehyde resin may be used as the binder.
  • the example describes a product with a thickness of 4.5 mm and a density of 1200 kg / m 3 .
  • US 2005/0019548 describes lightweight OSB boards using low density fillers.
  • binder polymeric binders such as 4,4-diphenylmethane diisocyanate resin are described.
  • the fillers described are glass, ceramics, perlite or polymeric materials.
  • the polymeric material is used in an amount of 0.8 to 20 wt .-% based on the OSB board.
  • the polymeric material used in the examples is the material Dualite, which consists of polypropylene, polyvinylidene chloride or polyacrylonitrile. A weight reduction of 5% is described.
  • OSB boards having a density of 607 to 677 kg / m 3 and a transverse tensile strength of 0.31 to 0.59 N / mm 2 are described.
  • US 2003/24443 discloses a material consisting of wood chips, binders and fillers. Fillers include polymers based on styrene. The volume ratio between the wood chips and the binder is advantageously 1: 1. There are also described prior art plates in which the volume ratio of binder to wood shavings is 90:10. These prior art plates have a density of 948 kg / m 3 . As binders among other thermosetting resins are described. In the examples according to the invention plates with a volume ratio of binder to wood chips of 45:55 are described which have a density of 887 kg / m 3 .
  • JP 06031708 describes light wood materials, wherein for the middle layer of a three-layer chipboard, a mixture of 100 parts by weight of wood particles and 5 to 30 parts by weight of particles of synthetic resin foam are used, said resin particles having a specific gravity of not more than 0.3 g / cm 3 and have a compressive strength of at least 30 kg / cm 2 . Further, it is described that the specific gravity of the wood particles should not exceed 0.5 g / cm 3 .
  • a mechanical strength of the produced wood materials of 4.7 to 4.9 kg / cm 3 is achieved using wood particles from the Japanese cedar with a density of 0.35 g / cm 3 .
  • Lauan and Kapur wood particles with an average density of 0.6 g / cm 3 only a mechanical strength of the produced wood materials of 3.7 kg / cm 3 could be achieved.
  • the disadvantage of the prior art is summarized in that on the one hand, the described light (wood) materials for furniture manufacturing too low mechanical strength, such as too low a screw pull-out resistance, have. On the other hand, the wood materials described in the prior art still have a high density of over 600 kg / m 3 . Furthermore, in the prior art for the production of lightweight wood-based materials, woods with an unusually light density of less than 0.5 g / cm 3 are employed for the European market.
  • Too low mechanical strength for example, lead to breaking or cracking of the components. Furthermore, these components tend during drilling or sawing to additional flaking of further wood material. Fastening hardware is difficult with these materials.
  • the object of the present invention was therefore to show light wood materials, which in comparison to the commercial wood materials by 5 bis 40% lower density with the same good mechanical strength.
  • the mechanical strength can be determined, for example, by measuring the transverse tensile strength.
  • these lightweight wood-based materials should be manufacturable using native, European woods. Consequently, the lightweight wood-based materials using heavy woods with a density greater than or equal to 0.5 g / cm 3 should have comparable low densities and comparable high mechanical strengths as the wood-based materials according to JP 06031708 made using light woods. Furthermore, the swelling and water absorption of the light wood materials should not be affected by the reduced density.
  • the weight of the binder refers to the solids content of the binder.
  • the average density of the wood particles refers to a wood moisture content of 12%. Furthermore, the average density of the wood particles refers to an average density over all wood particles used.
  • the wood-base materials according to the invention have an average density of 200 to 600 kg / m 3 , preferably 200 to 575 kg / m 3 , particularly preferably 250 to 550 kg / m 3 , in particular 300 to 500 kg / m 3 .
  • the transverse tensile strength of the wood-base materials according to the invention is advantageously greater than 0.3 N / mm 2 , preferably greater than 0.4 N / mm 2 , particularly preferably greater than 0.5 and in particular greater than 0.6 N / mm 2 .
  • the determination of the transverse tensile strength is in accordance with EN 319.
  • Wood-based materials are all materials which are made of wood veneers with an average density of 0.4 to 0.85 g / cm 3 , such as veneer sheets or plywood sheets, of wood chips with a mean density of 0.4 to 0.85 g / cm 3 produced wood materials, such as chipboard or OSB boards, and wood fiber materials such as LDF, MDF and HDF boards. Particleboard and fiberboard, in particular chipboard, are preferred.
  • the average density of the wood particles is advantageously 0.4 to 0.8 g / cm 3 , preferably 0.4 to 0.75 g / cm 3 , in particular 0.4 to 0.6 g / cm 3 .
  • spruce for example, spruce, beech, pine, larch or fir wood is used, preferably spruce and / or beech wood, in particular spruce wood.
  • the filler polystyrene and / or styrene copolymer can be prepared by all polymerization processes known to those skilled in the art [see, for example, US Pat. Ullmann's Encyclopedia, Sixth Edition, 2000 Electronic Release]. For example, the preparation is carried out in a conventional manner by suspension polymerization or by extrusion.
  • styrene In the suspension polymerization, styrene, optionally with the addition of further comonomers in aqueous suspension, is polymerized in the presence of a customary suspension stabilizer by means of free-radical-forming catalysts.
  • the blowing agent and, if appropriate, further additives may be introduced during the polymerization or may be added to the batch in the course of the polymerization or after the end of the polymerization.
  • the resulting bead-shaped optionally expandable styrene polymers are separated from the aqueous phase after the end of the polymerization, washed, dried and sieved.
  • the blowing agent is mixed for example via an extruder in the polymer, conveyed through a nozzle plate and granulated into particles or strands.
  • the filler polystyrene or styrene copolymer is particularly preferably expandable.
  • blowing agents are all blowing agents known to those skilled in the art, for example C 3 to C 6 hydrocarbons, such as propane, n-butane, isobutane, n-pentane, isopentane, neopentane and / or hexane, alcohols, ketones, ethers or halogenated hydrocarbons , Preferably, a commercially available pentane isomer mixture is used.
  • the styrenic polymers may contain additives, nucleating agents, plasticizers, flame retardants, soluble and insoluble inorganic and / or organic dyes and pigments, e.g. IR absorber, such as carbon black, graphite or aluminum powder, are added together or spatially separated as additives.
  • additives e.g. IR absorber, such as carbon black, graphite or aluminum powder, are added together or spatially separated as additives.
  • styrene copolymers these styrene copolymers advantageously have at least 50% by weight, preferably at least 80% by weight, of copolymerized polystyrene.
  • comonomers come z. B. ⁇ -methylstyrene, ring-halogenated styrenes, acrylonitrile, esters of acrylic or methacrylic acid of Alcohols having 1 to 8 carbon atoms, N-vinylcarbazole, maleic acid (anhydride), (meth) acrylamides and / or vinyl acetate into consideration.
  • the polystyrene and / or styrene copolymer may contain in copolymerized form a small amount of a chain splitter, i. a compound having more than one, preferably two, double bonds, such as divinylbenzene, butadiene and / or butanediol diacrylate.
  • the branching agent is generally used in amounts of from 0.005 to 0.05 mol%, based on styrene.
  • styrene (co) polymers having molecular weights and molecular weight distributions as described in US Pat EP-B 106 129 and in DE-A 39 21 148 are described. Preference is given to using styrene (co) polymers having a molecular weight in the range from 190,000 to 400,000 g / mol.
  • Mixtures of different styrene (co) polymers can also be used.
  • styrene polymers to glassy polystyrene (GPPS), toughened polystyrene (HIPS), anionically polymerized polystyrene or toughened polystyrene (A-IPS), styrene- ⁇ -methylstyrene copolymers, acrylonitrile-butadiene-styrene polymers (ABS), styrene-acrylonitrile (SAN), Acrylonitrile-styrene-acrylic ester (ASA), methyl acrylate-butadiene-styrene (MBS), methyl methacrylate-acrylonitrile-butadiene-styrene (MABS) polymers or mixtures thereof or used with polyphenylene ether (PPE).
  • GPPS glassy polystyrene
  • HIPS toughened polystyrene
  • A-IPS anionically polymerized polystyrene or toughened polystyrene
  • polystyrene Styropor®, Neopor® and / or Peripor® from BASF Aktiengesellschaft is particularly preferably used.
  • Pre-expanded polystyrene and / or styrene copolymers are advantageously used.
  • the prefoamed polystyrene can be prepared by all methods known to the person skilled in the art (for example DE 845264 ).
  • the expandable styrene polymers are expanded in a known manner by heating to temperatures above their softening point, for example with hot air or preferably steam.
  • the prefoamed polystyrene or styrene copolymer is used in the form of spheres or beads having an average diameter of advantageously 0.25 to 10 mm, preferably 0.5 to 5 mm, in particular 0.75 to 3 mm.
  • the prefoamed polystyrene or styrene copolymer spheres advantageously have a small surface area per volume, for example in the form of a spherical or elliptical particle.
  • the prefoamed polystyrene or styrene copolymer spheres are advantageously closed-celled.
  • the open cell density according to DIN-ISO 4590 is less than 30%.
  • antistatic agents the usual and common in the art substances can be used. Examples are N, N-bis (2-hydroxyethyl) -C 12 -C 18 -alkylamines, fatty acid diethanolamides, choline ester chlorides of fatty acids, C 12 -C 20 -alkyl sulfonates, ammonium salts.
  • Suitable ammonium salts are present on the nitrogen in addition to alkyl groups 1 to 3 hydroxyl-containing organic radicals.
  • Suitable quaternary ammonium salts are, for example, those having on the nitrogen cation 1 to 3, preferably 2, identical or different alkyl radicals having 1 to 12, preferably 1 to 10 carbon atoms, and 1 to 3, preferably 2 identical or different hydroxyalkyl or hydroxyalkylpolyoxyalkylene Radicals bound with any anion, such as chloride, bromide, acetate, methyl sulfate or p-toluenesulfonate.
  • hydroxyalkyl and hydroxyalkyl-polyoxyalkylene radicals are those which are formed by oxyalkylation of a nitrogen-bonded hydrogen atom and are derived from 1 to 10 oxyalkylene radicals, in particular oxyethylene and oxypropylene radicals.
  • An antistatic agent which is particularly preferred is a quaternary ammonium salt or an alkali metal salt, in particular the sodium salt of a C 12 -C 20 alkanesulfonate, eg. B emulsifier K30 from Bayer AG, or mixtures thereof.
  • the antistatic agents can generally be added both as a pure substance and in the form of an aqueous solution.
  • the antistatic agent can be added in the process for the preparation of polystyrene or styrene copolymer analogously to the customary additives or applied after the preparation of the polystyrene particles as a coating.
  • the antistatic agent is advantageously used in an amount of 0.05 to 6 wt .-%, preferably 0.1 to 4 wt .-%, based on the polystyrene or styrene copolymer.
  • the filler polystyrene and / or styrene copolymer is advantageously present evenly distributed in the wood material according to the invention.
  • the filler balls are advantageously present after pressing to the wood material in an unmelted state. Optionally, however, it may come to a melting of the filler balls, which are located on the surface of the wood material.
  • binders it is possible to use all binders known to the person skilled in the art for the production of wood-based materials.
  • Formaldehyde-containing adhesives are advantageously used as binders, for example urea-formaldehyde resins or melamine-containing urea-formaldehyde resins. Preference is given to using urea-formaldehyde resins.
  • Kaurit® glue from BASF Aktiengesellschaft is used as the binder.
  • the solids content of the binder is usually from 25 to 100% by weight, in particular from 50 to 70% by weight.
  • the lightweight wood-base materials according to the invention advantageously contain 55 to 92.5% by weight, preferably 60 to 90% by weight, in particular 70 to 85% by weight, based on the wood material, of wood particles, the wood particles having an average density of 0, 4 to 0.85 g / cm 3 , preferably 0.4 to 0.75 g / cm 3 , in particular 0.4 to 0.6 g / cm 3 , 5 to 15 wt .-%, preferably 8 to 12 wt .-% based on the wood material, polystyrene and / or styrene copolymer filler, wherein the filler has a bulk density of 30 to 100 kg / m 3 , and 2.5 to 40 wt .-%, preferably 5 to 25 wt .-% , in particular 5 to 15 wt .-%, based on the wood material, binder, wherein the average density of the light wood material is less than or equal to 600 kg / m 3 , preferably less than
  • the thickness of the wood materials varies with the field of application and is usually in the range of 0.5 to 50 mm.
  • the transverse tensile strength of the lightweight wood-base materials according to the invention having a density of 200 to 650 kg / m 3 is advantageously greater than (0.002 ⁇ D - 0.55) N / mm 2 , preferably greater than (0.002 ⁇ D - 0.45) N / mm 2 , in particular greater than (0.0022 x D - 0.45) N / mm 2 .
  • the swelling values are advantageously 10% smaller, preferably 20% smaller, in particular 30% smaller than the swelling values of a plate of the same density without filler.
  • the present invention relates to a process for the production of lightweight wood-based materials, as defined in claim 1.
  • the wood particle cake is cold pre-sealed before pressing.
  • the pressing can be carried out by all methods known to the person skilled in the art. Usually, the wood particle cake is pressed at a press temperature of 150 ° C to 230 ° C to the desired thickness. The pressing time is normally 3 to 15 seconds per mm plate thickness.
  • the present invention relates to the use of the wood-based materials according to the invention for the production of furniture, of packaging materials, in house building or interior work.
  • the advantages of the present invention are the low density of the wood-based materials according to the invention with good mechanical stability. Furthermore, the inventive easily produce wood-based materials; There is no need to retrofit the existing plants for the production of wood-based materials according to the invention.
  • Foamable polystyrene was such.
  • EP 981 574 described prepared. The addition of an antistatic agent during or after production was omitted.
  • the polystyrene particles obtained according to Example A1 were treated with steam in a continuous prefoamer.
  • the bulk density of the prefoamed polystyrene beads was adjusted by varying the vapor pressure and the steaming time.
  • Extruded PS foam available from BASF as Styrodur® (bulk density about 30 kg / m 3 ) was ground in a Pallmann impact mill type PP to an average particle diameter of 0.2 to 2 mm.
  • the glued chips or fibers were cold precompressed in a 30x30 cm mold. It was then pressed in a hot press (pressing temperature 190 ° C, pressing time 210 s). The nominal thickness of the plate was 16 mm in each case.
  • the density was determined 24 hours after preparation according to EN 1058.
  • the determination of the transverse tensile strength is in accordance with EN 319.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Laminated Bodies (AREA)
  • Rod-Shaped Construction Members (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Claims (9)

  1. Matériau léger à base de bois, contenant
    30 à 92,5% en poids, par rapport au matériau à base de bois, de particules de bois, les particules de bois présentant une densité moyenne de 0,4 à 0,85 g/cm3,
    2,5 à 20% en poids, par rapport au matériau à base de bois, de polystyrène et/ou de copolymère de styrène comme charge, la charge présentant une densité apparente de 30 à 100 kg/m3, et
    5 à 50% en poids, par rapport au matériau à base de bois, de liant, la densité moyenne du matériau léger à base de bois étant inférieure à 600 kg/m3,
    caractérisé en ce que dans lequel on utilise, comme charge, des perles ou des billes prémoussées de charge, qui présentent un diamètre de 0,25 à 10 mm et
    dans lequel les perles ou les billes de charge présentent un revêtement antistatique.
  2. Matériau léger à base de bois selon la revendication 1, les particules de bois présentant une densité moyenne de 0,4 à 0,75 g/cm3.
  3. Matériau léger à base de bois selon les revendications 1 ou 2, la résistance à la traction transversale du matériau à base de bois étant supérieure à 0,4 N/mm2.
  4. Matériau léger à base de bois selon les revendications 1 à 3, la densité du matériau à base de bois étant de 250 à 550 kg/m3.
  5. Matériau léger à base de bois selon les revendications 1 à 4, contenant 55 un 92,5% en poids, par rapport au matériau à base de bois, de particules de bois, les particules de bois présentant une densité moyenne de 0,4 à 0,6 g/cm3, et 5 à 15% en poids, par rapport au matériau à base de bois, de polystyrène et/ou de copolymère de styrène comme charge, la charge présentant une densité apparente de 15 à 80 kg/m3, 2,5 à 40% en poids, par rapport au matériau à base de bois, de liant, la densité moyenne du matériau léger à base de bois étant inférieure à 550 kg/m3.
  6. Matériau composite qui contient au moins trois couches de matériau à base de bois, la ou les couches centrales présentant des matériaux à base de bois selon les revendications 1 à 5 ou 9 et les couches externes de recouvrement ne présentant pas de charge.
  7. Procédé pour la fabrication de matériaux légers à base de bois tels que définis dans la revendication 1, caractérisé en ce qu'on mélange 2,5 à 20% en poids, par rapport au matériau à base de bois, de polystyrène et/ou de copolymère de styrène prémoussé, présentant une densité apparente de 30 à 100 kg/m3, 5 à 50% en poids, par rapport au matériau à base de bois, de liant et 30 à 92,5% en poids, par rapport au matériau à base de bois, de particules de bois présentant une densité moyenne de 0,4 à 0,85 g/cm3 et on comprime ensuite en un matériau à base de bois tel que défini dans la revendication 1 sous température élevée et pression élevée, caractérisé en ce que dans lequel on utilise, comme charge, des perles ou des billes prémoussées de charge, qui présentent un diamètre de 0,25 à 10 mm et dans lequel les perles ou les billes de charge présentent un revêtement antistatique.
  8. Utilisation du matériau léger à base de bois selon les revendications 1 à 5 ou 9 ou du matériau composite selon la revendication 6 pour la fabrication de meubles, de matériaux d'emballage, dans la construction de maisons ou dans l'aménagement intérieur.
  9. Matériau léger à base de bois selon les revendications 1 à 5, le matériau à base de bois étant un matériau à base de fibres de bois.
EP07821530.8A 2006-10-19 2007-10-18 Materiau leger a base de bois Active EP2083974B1 (fr)

Priority Applications (3)

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EP20110152229 EP2319670A1 (fr) 2006-10-19 2007-10-18 Matériau léger à base de bois
EP07821530.8A EP2083974B1 (fr) 2006-10-19 2007-10-18 Materiau leger a base de bois
PL07821530T PL2083974T3 (pl) 2006-10-19 2007-10-18 Lekkie tworzywa drzewne

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Application Number Priority Date Filing Date Title
EP06122557.9A EP1914052B1 (fr) 2006-10-19 2006-10-19 Materiau léger a base de bois
EP07821530.8A EP2083974B1 (fr) 2006-10-19 2007-10-18 Materiau leger a base de bois
PCT/EP2007/061165 WO2008046890A2 (fr) 2006-10-19 2007-10-18 Matériaux légers dérivés du bois

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EP2083974A2 EP2083974A2 (fr) 2009-08-05
EP2083974B1 true EP2083974B1 (fr) 2017-01-18

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EP06122557.9A Active EP1914052B1 (fr) 2006-10-19 2006-10-19 Materiau léger a base de bois
EP20110152229 Withdrawn EP2319670A1 (fr) 2006-10-19 2007-10-18 Matériau léger à base de bois
EP20070821531 Active EP2083975B1 (fr) 2006-10-19 2007-10-18 Matériaux légers dérivés du bois présentant de bonnes propriétés mécaniques et leur methode de production
EP07821530.8A Active EP2083974B1 (fr) 2006-10-19 2007-10-18 Materiau leger a base de bois
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EP20110152229 Withdrawn EP2319670A1 (fr) 2006-10-19 2007-10-18 Matériau léger à base de bois
EP20070821531 Active EP2083975B1 (fr) 2006-10-19 2007-10-18 Matériaux légers dérivés du bois présentant de bonnes propriétés mécaniques et leur methode de production

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EP (5) EP1914052B1 (fr)
JP (2) JP5300728B2 (fr)
CN (2) CN101553348B (fr)
AT (1) ATE493247T1 (fr)
AU (2) AU2007312218B2 (fr)
BR (2) BRPI0717434A2 (fr)
CA (2) CA2666454A1 (fr)
DE (2) DE202006020503U1 (fr)
EA (2) EA013665B1 (fr)
ES (3) ES2641263T3 (fr)
MY (2) MY148865A (fr)
NO (3) NO20091516L (fr)
NZ (2) NZ576323A (fr)
PL (3) PL1914052T3 (fr)
PT (3) PT1914052T (fr)
UA (2) UA94123C2 (fr)
WO (3) WO2008046890A2 (fr)

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PT2083974T (pt) 2017-03-31
US20110003136A1 (en) 2011-01-06
DE502007006137D1 (de) 2011-02-10
ES2622883T3 (es) 2017-07-07
EA013666B1 (ru) 2010-06-30
EP2319670A1 (fr) 2011-05-11
NO20091522L (no) 2009-05-18
WO2008046892A2 (fr) 2008-04-24
PL2083975T3 (pl) 2011-05-31
BRPI0717436A2 (pt) 2013-11-12
PL2083974T3 (pl) 2017-07-31
NZ576323A (en) 2012-03-30
WO2008046891A1 (fr) 2008-04-24
EP2083975B1 (fr) 2010-12-29
JP2010506757A (ja) 2010-03-04
AU2007312220A1 (en) 2008-04-24
JP5150638B2 (ja) 2013-02-20
CN101553348A (zh) 2009-10-07
PT2083975E (pt) 2011-02-03
EP2083976A2 (fr) 2009-08-05
CN101553348B (zh) 2013-08-14
CN101541488B (zh) 2014-01-15
MY148871A (en) 2013-06-14
US9089991B2 (en) 2015-07-28
WO2008046890A2 (fr) 2008-04-24
NZ576290A (en) 2012-02-24
NO20091516L (no) 2009-05-14
CA2666447A1 (fr) 2008-04-24
NO20091523L (no) 2009-04-30
ATE493247T1 (de) 2011-01-15
EA200900550A1 (ru) 2009-10-30
DE202006020503U1 (de) 2008-10-09
EP2083975A1 (fr) 2009-08-05
EP1914052B1 (fr) 2017-06-28
CN101541488A (zh) 2009-09-23
PT1914052T (pt) 2017-10-04
ES2641263T3 (es) 2017-11-08
CA2666454A1 (fr) 2008-04-24
MY148865A (en) 2013-06-14
AU2007312220B2 (en) 2012-05-03
AU2007312218B2 (en) 2012-02-09
PL1914052T3 (pl) 2017-12-29
WO2008046892A3 (fr) 2008-08-21
JP2010506758A (ja) 2010-03-04
UA96612C2 (ru) 2011-11-25
US20100297425A1 (en) 2010-11-25
JP5300728B2 (ja) 2013-09-25
BRPI0717434A2 (pt) 2013-11-12
WO2008046890A3 (fr) 2008-06-12
EP1914052A1 (fr) 2008-04-23
EA013665B1 (ru) 2010-06-30
US8304069B2 (en) 2012-11-06
ES2357574T3 (es) 2011-04-27
UA94123C2 (ru) 2011-04-11
AU2007312218A1 (en) 2008-04-24
EP2083974A2 (fr) 2009-08-05
EA200900551A1 (ru) 2009-10-30

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