EP1917372B1 - Aluminium casting alloy - Google Patents
Aluminium casting alloy Download PDFInfo
- Publication number
- EP1917372B1 EP1917372B1 EP06791332A EP06791332A EP1917372B1 EP 1917372 B1 EP1917372 B1 EP 1917372B1 EP 06791332 A EP06791332 A EP 06791332A EP 06791332 A EP06791332 A EP 06791332A EP 1917372 B1 EP1917372 B1 EP 1917372B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- parts
- alloys
- casting
- casting alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 229910045601 alloy Inorganic materials 0.000 title claims description 27
- 239000000956 alloy Substances 0.000 title claims description 27
- 238000005266 casting Methods 0.000 title claims description 13
- 229910052782 aluminium Inorganic materials 0.000 title description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title description 2
- 239000004411 aluminium Substances 0.000 title 1
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910021364 Al-Si alloy Inorganic materials 0.000 description 1
- 229910016570 AlCu Inorganic materials 0.000 description 1
- 229910017073 AlLi Inorganic materials 0.000 description 1
- 229910016943 AlZn Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- AHLBNYSZXLDEJQ-FWEHEUNISA-N orlistat Chemical compound CCCCCCCCCCC[C@H](OC(=O)[C@H](CC(C)C)NC=O)C[C@@H]1OC(=O)[C@H]1CCCCCC AHLBNYSZXLDEJQ-FWEHEUNISA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
- C22C21/04—Modified aluminium-silicon alloys
Definitions
- the invention relates to aluminum casting alloys, in particular for chassis applications.
- AlSi7Mg or AlSi11 Mg e.g. AlSi7Mg or AlSi11 Mg.
- AlSi (Mg, Cu) alloys are also used, but due to their corrosive properties they can only find niche applications.
- AlCu (Ti, Mg) alloys which offer the highest strengths among common alloys.
- niche applications in the chassis area are the AlMg alloys.
- the components made from the above alloys are subjected to a two-stage heat treatment to obtain the desired properties.
- JP 0710953T A is an Al-Si alloy with a chemical composition in wt.% 3.3-5.5 Si, 0.2-0.7% Mg, 0.01-0.2% Ti, 0.0001-0.01% B, max. 0.2% Fe, max. 0.005% P, max. 0.005% Ca, optionally one or several of the elements 0.02-0.5% Mn, 0.01-0.3% Cr, 0.01-0.2% Zr and 0.2-0.5% Cu and furthermore optionally max. 0.03% Sb, 0.001-0.01% Na and 0.001-0.05% Sr.
- the object of the invention to develop an alloy which has properties which still have sufficiently high elongation at fracture values, in particular for automotive applications.
- This combination of properties is necessary, for example, in chassis applications, in order to be able to survive cases of abuse.
- the alloy has to be sufficiently castable and, owing to its composition, should not impose excessive demands on the melting process and the metal circulation.
- Al casting alloys contain alloy components listed below: Si: 2.7 to 3.1% by weight mg: 0.3 to 0.6% by weight Fe: 0.05 to 0.16% by weight Mn: ⁇ 0.5, preferably 0.05 to 0.4 wt .-% Ti: 0.01 to 0.08% by weight Sr: 0.01 to 0.03% by weight other: ⁇ 0.1% by weight and in each case added to 100 wt .-% with Al.
- production-related impurities for example Pb, Ni, Zn, etc.
- production-related impurities for example Pb, Ni, Zn, etc.
- the alloys of the present invention have a strength-strain ratio that is not achievable with conventional Al casting alloys under the requirement of Cu freedom. Especially in pressure-assisted casting processes, e.g. Low pressure - back pressure - Kogillenguss - result from the good cast structure better mechanical technological properties.
- the alloy is grain-fined.
- the cast components are heat-treated, in particular with the following parameters: solution annealing 490 to 540 ° C for 1 to 10h start 150 to 200 ° C for 1 to 10h
- T4 one-stage tempering treatment
- the castability allows one of large defects, known as voids, to be free cast, and on the other hand, the microstructure is positively influenced in such a manner that the number of internal grooves which reduce the elongation at break is minimized.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Body Structure For Vehicles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Materials For Medical Uses (AREA)
- Electroplating Methods And Accessories (AREA)
- Dental Preparations (AREA)
- Continuous Casting (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Powder Metallurgy (AREA)
Description
Die Erfindung bezieht sich auf Aluminium-Gusslegierungen, insbesondere für Fahrwerksanwendungen. Hierfür werden im Allgemeinen primär erschmolzene untereutektische AlSi-Legierungen angewendet, die zur Festigkeitssteigerung mit geringen Gehalten an Mg legiert sind, z.B. AlSi7Mg oder AlSi11 Mg. Vereinzelt werden auch AlSi(Mg,Cu)-Legierungen verwendet, die aber aufgrund der korrosiven Eigenschaften nur Nischenanwendungen finden können. Gleiches gilt für die Familie der AlCu(Ti,Mg)-Legierungen, die unter den gängigen Legierungen die höchsten Festigkeiten bieten. Ebenfalls Nischenanwendungen im Fahrwerksbereich bilden die AlMg-Legierungen. Andere Legierungsfamilien, wie AlZn oder AlLi, spielen im Fahrwerk keine Rolle.The invention relates to aluminum casting alloys, in particular for chassis applications. For this purpose, generally primarily melted hypoeutectic AlSi alloys are used, which are alloyed with low levels of Mg for strength enhancement, e.g. AlSi7Mg or AlSi11 Mg. Occasionally AlSi (Mg, Cu) alloys are also used, but due to their corrosive properties they can only find niche applications. The same applies to the family of AlCu (Ti, Mg) alloys, which offer the highest strengths among common alloys. Also niche applications in the chassis area are the AlMg alloys. Other alloy families, such as AlZn or AlLi, play no role in the chassis.
Üblicherweise werden die Bauteile, die aus den oben genannten Legierungen hergestellt werden, einer zweistufigen Wärmebehandlung zur Erzielung der gewünschten Eigenschaften unterzogen.Usually, the components made from the above alloys are subjected to a two-stage heat treatment to obtain the desired properties.
Generell weisen die bestehenden Legierungsfamilien den Nachteil auf, dass damit nur ein eingeschränktes Festigkeits-Dehnungsverhältnis erreichbar ist. Die zuvor genannten höherfesten Legierungen mit Cu-Zugabe scheiden aufgrund der korrosiven Eigenschaften häufig aus. AlMg-Legierungen sind deutlich schwerer vergießbar und daher in der Anwendung (Bauteilgeometrie) limitiert.In general, the existing alloy families have the disadvantage that only a limited strength-strain ratio can be achieved. The above-mentioned high-strength alloys with Cu addition are often eliminated due to the corrosive properties. AlMg alloys are significantly heavier castable and therefore limited in application (component geometry).
Aus der Zusammenfassung der
Demgemäß lag der Erfindung die Aufgabe zugrunde, eine Legierung zu entwickeln, welche Eigenschaften aufweist, die insbesondere für Anwendungen Im Automobilbau, bei hohen Materialfestigkeiten noch ausreichend hohe Bruchdehnungswerte aufweist Diese Eigenschaftskombination ist beispielsweise bei Fahrwerksanwendungen notwendig, um auch Missbrauchsfälle überstehen zu können. Gleichzeitig muss die Legierung hinreichend gut vergießbar sein und soll aufgrund ihrer Zusammensetzung keine überhöhten Anforderungen an den Schmelzprozess und den Metallkreislauf stellen.Accordingly, it was the object of the invention to develop an alloy which has properties which still have sufficiently high elongation at fracture values, in particular for automotive applications. This combination of properties is necessary, for example, in chassis applications, in order to be able to survive cases of abuse. At the same time, the alloy has to be sufficiently castable and, owing to its composition, should not impose excessive demands on the melting process and the metal circulation.
Dies wird gemäß der Erfindung dadurch erzielt, dass Al-Gussiegierungen nachfolgend angeführte Legierungsbestandteile enthalten:
Gegebenenfalls sind herstellungsbedingte Verunreinigungen, z.B. Pb, Ni , Zn etc., enthalten, wie sie dem Fachmann allgemein bekannt sind.Optionally, production-related impurities, for example Pb, Ni, Zn, etc., are included, as are generally known to the person skilled in the art.
Die erfindungsgemäßen Legierungen weisen ein Festigkeits-Dehnungsverhältnis auf, welches mit herkömmlichen Al-Gusslegierungen unter der Anforderung von Cu-Freiheit nicht erreichbar ist. Insbesondere bei druckunterstützten Gießverfahren, z.B. Niederdruck - Gegendruck-Kogillenguss - ergeben sich aus dem guten Gussgefüge bessere mechanisch technologische Eigenschaften.The alloys of the present invention have a strength-strain ratio that is not achievable with conventional Al casting alloys under the requirement of Cu freedom. Especially in pressure-assisted casting processes, e.g. Low pressure - back pressure - Kogillenguss - result from the good cast structure better mechanical technological properties.
Es kann weiterhin vorteilhaft sein, wenn die Legierung korngefeint ist.It may also be advantageous if the alloy is grain-fined.
Um die oben genannten Vorteile zu erzielen oder noch weiter zu entwickeln, ist es vorteilhaft, wenn die gegossenen Bauteile wärmebehandelt werden, insbesondere mit folgenden Parametern:
Für manche Anwendungsfälle kann es aber auch vorteilhaft sein, lediglich eine einstufige Anlassbehandlung vorzunehmen, allgemein bekannt als beispielsweise T4, T5 oder 0For some applications, however, it may also be advantageous to carry out only one-stage tempering treatment, generally known as T4, T5 or 0, for example
Neben den bereits genannten Vorteilen, die Bauteile aus Legierungen gemäß der Erfindung aufweisen, kommt noch hinzu, dass wegen der fehlenden Legierungsbestandteile Cu und Zn die Korrosionsbeständigkeit bedeutend erhöht wird. Das Produkt ist auch relativ preiswert, weil keine dasselbe verteuernden Legierungszusätze, wie z.B. SE-Metalle, verwendet werden, es kann die übliche Schmelzbehandlung angewendet werden und es bedarf keines besonderen Aufwandes zur Kreislauftrennung.In addition to the advantages already mentioned, which have components made of alloys according to the invention, there is also the fact that, because of the missing alloy constituents Cu and Zn, the corrosion resistance is significantly increased. The product is also relatively inexpensive because no use is made of the same expensive alloying additives, such as SE metals, the usual melt treatment can be used, and there is no need for a special separation process.
Es ist auch ein vorzügliches Festigkeits-Dehnungsverhältnis bei vorzüglicher Gießbarkeit vorhanden. Die Gießbarkeit ermöglicht zum einen ein von großen Fehlern, bekannt als Lunkern, freies Gußstück, zum anderen wird die Mikrosturktur in einer solchen Weise positiv beeinflußt, daß die Anzahl innerer Kerben, die die Bruchdehnung verringern, möglichst gering gehalten wird.There is also an excellent strength-elongation ratio with excellent castability. On the one hand, the castability allows one of large defects, known as voids, to be free cast, and on the other hand, the microstructure is positively influenced in such a manner that the number of internal grooves which reduce the elongation at break is minimized.
Als beispielhafte Werte sind anzuführen:
Claims (7)
- An Al casting alloy, containing the alloy components listed hereafter:
and in each case completed with Al to 100 wt%.Si: 2.7 to 3.1 wt% Mg: 0.3 to 0.6 wt% Fe: 0.05 to 0.16 wt% Mn: < 0.5, preferably 0.05 to 0.4 wt% Ti: 0.01 to 0.08 wt% Sr: 0.01 to 0.03 wt% other: < 0.1 wt% - The Al casting alloy according to Claim 1, characterised in that the alloy is grain-refined.
- A use of Al casting alloys according to one of the preceding claims for work pieces, component parts or parts for or of chassis parts of motor vehicles.
- A cast part made from an Al casting alloy according to claim 1 or 2.
- The cast part according to claim 4, characterised in that the cast part is solution-annealed between 490 to 540°C for 1 to 10h.
- The cast part according to claim 4 or 5, characterised in that the cast part is tempered between 150 to 200°C for 1 to 10h.
- A use of cast parts according to one of claims 4 to 6 for work pieces, component parts or parts for or of chassis parts of motor vehicles.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005041188 | 2005-08-31 | ||
| DE102006010131 | 2006-03-06 | ||
| PCT/DE2006/001525 WO2007025528A2 (en) | 2005-08-31 | 2006-08-30 | Aluminium casting alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1917372A2 EP1917372A2 (en) | 2008-05-07 |
| EP1917372B1 true EP1917372B1 (en) | 2012-10-17 |
Family
ID=37517275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06791332A Not-in-force EP1917372B1 (en) | 2005-08-31 | 2006-08-30 | Aluminium casting alloy |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20100163137A1 (en) |
| EP (1) | EP1917372B1 (en) |
| JP (1) | JP2009506215A (en) |
| DE (1) | DE112006002779A5 (en) |
| FR (2) | FR2890082B1 (en) |
| IT (1) | ITMI20061659A1 (en) |
| WO (1) | WO2007025528A2 (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE202008017274U1 (en) | 2007-11-08 | 2009-04-16 | Ksm Castings Gmbh | Front axle, especially for motor vehicles |
| CN101855125B (en) | 2007-11-08 | 2013-11-06 | Ksm铸造集团有限公司 | Front axle brackets for motor vehicles |
| DE102008055928A1 (en) | 2007-11-08 | 2009-08-27 | Ksm Castings Gmbh | Al-cast alloys |
| DE102009048364A1 (en) | 2008-10-09 | 2010-04-15 | Ksm Castings Gmbh | Front powered axle support for motor vehicle, has rear and front housings remote from each other in longitudinal direction, and housings respectively fixing gear-box and stabilizer, where housings integrated to chassis of support by bars |
| WO2013053354A2 (en) | 2011-10-11 | 2013-04-18 | Ksm Castings Group Gmbh | Cast part |
| DE102013108127A1 (en) | 2012-08-23 | 2014-02-27 | Ksm Castings Group Gmbh | Al-cast alloy |
| CN102979937B (en) * | 2012-11-13 | 2015-06-03 | 安徽春辉仪表线缆集团有限公司 | Check valve body aluminum alloy casting method |
| CN104968817A (en) * | 2013-02-06 | 2015-10-07 | Ksm铸造集团有限公司 | Aluminium casting alloy |
| WO2018161311A1 (en) | 2017-03-09 | 2018-09-13 | GM Global Technology Operations LLC | Aluminum alloys |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3335732B2 (en) | 1993-10-12 | 2002-10-21 | 日本軽金属株式会社 | Hypoeutectic Al-Si alloy and casting method thereof |
| JPH07109536A (en) * | 1993-10-12 | 1995-04-25 | Nippon Light Metal Co Ltd | Aluminum alloy for forging and its heat treatment |
| JPH09272941A (en) * | 1996-04-04 | 1997-10-21 | Nissan Motor Co Ltd | Aluminum-based alloy used for product forging after casting into a product preform and its casting and forging method |
| JP3835629B2 (en) * | 1996-09-24 | 2006-10-18 | 住友軽金属工業株式会社 | Wear-resistant aluminum alloy material with excellent machinability and corrosion resistance |
| EP1218561B1 (en) * | 1999-09-24 | 2003-12-03 | Honsel Guss GmbH | Method for the heat treatment of structure castings from an aluminium alloy to be used therefor |
| FR2818288B1 (en) * | 2000-12-14 | 2003-07-25 | Pechiney Aluminium | PROCESS FOR MANUFACTURING A SECURITY PART IN AL-Si ALLOY |
| FR2827306B1 (en) * | 2001-07-10 | 2004-10-22 | Pechiney Aluminium | HIGH DUCTILITY ALUMINUM ALLOY FOR PRESSURE CASTING |
| US20030143102A1 (en) * | 2001-07-25 | 2003-07-31 | Showa Denko K.K. | Aluminum alloy excellent in cutting ability, aluminum alloy materials and manufacturing method thereof |
| JP4227014B2 (en) * | 2001-07-25 | 2009-02-18 | 昭和電工株式会社 | Aluminum alloy material excellent in machinability and manufacturing method thereof |
| JP2003170263A (en) * | 2001-12-10 | 2003-06-17 | Hitachi Metals Ltd | Method for casting vehicle wheel under low pressure |
| FR2841164B1 (en) * | 2002-06-25 | 2004-07-30 | Pechiney Aluminium | ALLOY MOLDING WITH HIGH FLUID RESISTANCE |
| DE102004022817A1 (en) * | 2004-05-08 | 2005-12-01 | Erbslöh Ag | Decorative anodizable, easily deformable, mechanically highly loadable aluminum alloy, process for its production and aluminum product made from this alloy |
| US8403347B2 (en) * | 2005-09-13 | 2013-03-26 | Ksm Castings Group Gmbh | Front-axle bracket, in particular for motor vehicles |
-
2006
- 2006-08-30 EP EP06791332A patent/EP1917372B1/en not_active Not-in-force
- 2006-08-30 DE DE112006002779T patent/DE112006002779A5/en not_active Withdrawn
- 2006-08-30 JP JP2008528333A patent/JP2009506215A/en active Pending
- 2006-08-30 IT IT001659A patent/ITMI20061659A1/en unknown
- 2006-08-30 WO PCT/DE2006/001525 patent/WO2007025528A2/en not_active Ceased
- 2006-08-30 US US11/990,098 patent/US20100163137A1/en not_active Abandoned
- 2006-08-30 FR FR0607610A patent/FR2890082B1/en not_active Expired - Fee Related
-
2009
- 2009-10-21 FR FR0957389A patent/FR2939149B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20100163137A1 (en) | 2010-07-01 |
| DE112006002779A5 (en) | 2008-09-04 |
| WO2007025528A2 (en) | 2007-03-08 |
| FR2890082A1 (en) | 2007-03-02 |
| ITMI20061659A1 (en) | 2007-03-01 |
| JP2009506215A (en) | 2009-02-12 |
| FR2939149B1 (en) | 2011-04-22 |
| EP1917372A2 (en) | 2008-05-07 |
| FR2939149A1 (en) | 2010-06-04 |
| FR2890082B1 (en) | 2009-12-04 |
| WO2007025528A3 (en) | 2007-05-03 |
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