EP1890775A1 - Preparations cosmetiques presentant une certaine teneur en extrait aqueux d'anis et en agents emulsifiants non ioniques specifiques - Google Patents
Preparations cosmetiques presentant une certaine teneur en extrait aqueux d'anis et en agents emulsifiants non ioniques specifiquesInfo
- Publication number
- EP1890775A1 EP1890775A1 EP06763110A EP06763110A EP1890775A1 EP 1890775 A1 EP1890775 A1 EP 1890775A1 EP 06763110 A EP06763110 A EP 06763110A EP 06763110 A EP06763110 A EP 06763110A EP 1890775 A1 EP1890775 A1 EP 1890775A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- preparation according
- acid
- skin
- fruit extract
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 52
- 239000002537 cosmetic Substances 0.000 title claims abstract description 23
- 239000000284 extract Substances 0.000 title claims abstract description 21
- 240000004760 Pimpinella anisum Species 0.000 title claims abstract description 16
- 235000013399 edible fruits Nutrition 0.000 title claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 7
- NKEQOUMMGPBKMM-UHFFFAOYSA-N 2-hydroxy-2-[2-(2-hydroxy-3-octadecanoyloxypropoxy)-2-oxoethyl]butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CC(O)(C(O)=O)CC(O)=O NKEQOUMMGPBKMM-UHFFFAOYSA-N 0.000 claims abstract description 4
- ICIDSZQHPUZUHC-UHFFFAOYSA-N 2-octadecoxyethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCO ICIDSZQHPUZUHC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940073669 ceteareth 20 Drugs 0.000 claims abstract description 4
- 229940100460 peg-100 stearate Drugs 0.000 claims abstract description 4
- 229940100458 steareth-21 Drugs 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 9
- 230000037303 wrinkles Effects 0.000 claims description 9
- 235000012550 Pimpinella anisum Nutrition 0.000 claims description 8
- 235000007265 Myrrhis odorata Nutrition 0.000 claims description 7
- 229940061720 alpha hydroxy acid Drugs 0.000 claims description 6
- 150000001280 alpha hydroxy acids Chemical class 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 239000001023 inorganic pigment Substances 0.000 claims description 4
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 3
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 230000037394 skin elasticity Effects 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 244000068689 Pimpinella saxifraga Species 0.000 abstract 1
- -1 3- (4- (2,2-bisethoxycarbonyl-vinyl) -phenoxy) -propenyl Chemical group 0.000 description 27
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 22
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 19
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 17
- 239000000203 mixture Substances 0.000 description 16
- 239000004205 dimethyl polysiloxane Substances 0.000 description 14
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229920001971 elastomer Polymers 0.000 description 11
- 239000000806 elastomer Substances 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 229920002545 silicone oil Polymers 0.000 description 11
- 239000003963 antioxidant agent Substances 0.000 description 10
- 235000006708 antioxidants Nutrition 0.000 description 10
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000004904 UV filter Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 229940008099 dimethicone Drugs 0.000 description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
- 206010040954 Skin wrinkling Diseases 0.000 description 8
- 239000000499 gel Substances 0.000 description 8
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 8
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 8
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 7
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 125000004122 cyclic group Chemical group 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 4
- 240000004064 Poterium sanguisorba Species 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- CVSVTCORWBXHQV-UHFFFAOYSA-N creatine Chemical compound NC(=[NH2+])N(C)CC([O-])=O CVSVTCORWBXHQV-UHFFFAOYSA-N 0.000 description 4
- DDRJAANPRJIHGJ-UHFFFAOYSA-N creatinine Chemical compound CN1CC(=O)NC1=N DDRJAANPRJIHGJ-UHFFFAOYSA-N 0.000 description 4
- 229920006037 cross link polymer Polymers 0.000 description 4
- UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical class N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- ACTIUHUUMQJHFO-UHFFFAOYSA-N Coenzym Q10 Natural products COC1=C(OC)C(=O)C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UHFFFAOYSA-N 0.000 description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 3
- 235000010469 Glycine max Nutrition 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 208000012641 Pigmentation disease Diseases 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229930003268 Vitamin C Natural products 0.000 description 3
- 229930003427 Vitamin E Natural products 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- UBNYRXMKIIGMKK-RMKNXTFCSA-N amiloxate Chemical compound COC1=CC=C(\C=C\C(=O)OCCC(C)C)C=C1 UBNYRXMKIIGMKK-RMKNXTFCSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
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- 235000017471 coenzyme Q10 Nutrition 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000000416 hydrocolloid Substances 0.000 description 3
- BJRNKVDFDLYUGJ-RMPHRYRLSA-N hydroquinone O-beta-D-glucopyranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-RMPHRYRLSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
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- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
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- OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical class CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 description 2
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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- GYBINGQBXROMRS-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethylamino)butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)NC(C([O-])=O)CC([O-])=O GYBINGQBXROMRS-UHFFFAOYSA-J 0.000 description 1
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- QNTNKSLOFHEFPK-UPTCCGCDSA-N ubiquinol-10 Chemical compound COC1=C(O)C(C)=C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)C(O)=C1OC QNTNKSLOFHEFPK-UPTCCGCDSA-N 0.000 description 1
- 229940035936 ubiquinone Drugs 0.000 description 1
- PLSAJKYPRJGMHO-UHFFFAOYSA-N ursolic acid Natural products CC1CCC2(CCC3(C)C(C=CC4C5(C)CCC(O)C(C)(C)C5CCC34C)C2C1C)C(=O)O PLSAJKYPRJGMHO-UHFFFAOYSA-N 0.000 description 1
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- VHBFFQKBGNRLFZ-UHFFFAOYSA-N vitamin p Natural products O1C2=CC=CC=C2C(=O)C=C1C1=CC=CC=C1 VHBFFQKBGNRLFZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9771—Ginkgophyta, e.g. Ginkgoaceae [Ginkgo family]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
Definitions
- the present invention relates to cosmetic preparations containing an aqueous extract from anise (Pimpinella anis fruit extract), available under the trade name Bioxilift from SILAB, St. Viance, France, and one or more emulsifiers.
- anise Pimpinella anis fruit extract
- a very important for the consumer, but it is difficult to quantitatively measurable property of cosmetic products is a certain invigorating and / or smooth skin feel and the suppleness of the skin after its application.
- a rosy skin color (such as is available by staying in the open air) is considered by consumers to be healthy and therefore desirable, whereas a pale complexion is generally not as desirable. It is an object of the present invention to provide skincare preparations and preparations for the care of naturally aged skin, wherein the preparations are intended to nourish and beautify the external appearance of the body and at the same time reduce wrinkles and eliminate cellulites.
- a cosmetic preparation containing (a) an aqueous extract from anise (Pimpinella anis fruit extract), available under the trade name Bioxilift from SILAB, St. Viance, France, and (b) one or more several emulsifiers selected from the group glyceryl stearate citrate, polyglyceryl-3-methylglucose distearate, PEG-40 stearate, PEG-100 stearate, ceteareth-20 and steareth-21 from the disadvantages of the prior art.
- an aqueous extract from anise Pimpinella anis fruit extract
- emulsifiers selected from the group glyceryl stearate citrate, polyglyceryl-3-methylglucose distearate, PEG-40 stearate, PEG-100 stearate, ceteareth-20 and steareth-21 from the disadvantages of the prior art.
- Such a preparation has the substantial advantage over prior art formulations that it has a significantly higher long-term physicochemical stability than conventional emulsions prepared, for example, with stearic acid as an emulsifier, since the salts contained in the aqueous fruit extract of anise lead to W emulsions in a few weeks to a phase separation of the emulsion under conventional storage conditions (temperature range from -10 0 C to 40 0 C).
- such preparation has the following additional benefits: It promotes the natural regeneration process and cell metabolism of the skin, activates skin protection systems and makes the skin more resistant to stressors, counteracts (first) signs of aging, reducing lines and facial lines, refining pores and
- the skin is visibly tightened and smoothed, deeply activates the skin's own production of components of connective tissue such as collagens, elastic fibers and proteoglycans (including hyaluronic acids), counteracts the formation of new wrinkles sustainably, the energy depots / reserves filled and the skin / cell regeneration improves, rejuvenates the skin's internal structure by improving the epidermal-dermal (papillae), thereby refining and tightening facial and skin contours, firming the skin palpably and visibly and improving skin elasticity.
- connective tissue such as collagens, elastic fibers and proteoglycans (including hyaluronic acids)
- anise fruit extracts with one or more emulsifiers selected from the group glyceryl stearate citrate, polyglyceryl-3-methyl glucose distearate, PEG-40 Stearate, PEG-100 Stearate, Ceteareth-20 and Steareth-21 will produce a stable O / W emulsion in line with the market, making the extracts particularly suitable for use in cosmetic preparations and the requirements for Stability, compatibility and effectiveness.
- one or more emulsifiers selected from the group glyceryl stearate citrate, polyglyceryl-3-methyl glucose distearate, PEG-40 Stearate, PEG-100 Stearate, Ceteareth-20 and Steareth-21 will produce a stable O / W emulsion in line with the market, making the extracts particularly suitable for use in cosmetic preparations and the requirements for Stability, compatibility and effectiveness.
- Bioxilift is an aqueous fruit extract from anise (Pimpinella anis fruit extract).
- the extract has an amber-like color and has a characteristic anise smell.
- the extract is rich in inorganic minerals such as sodium and magnesium ions, but especially in potassium ions.
- the recorded spectra do not deliver
- the specific composition is:
- the extract is preserved with butylene glycol 0.36% and parabens 0.14% and is in
- the aniseed fruits are solubilized in water and hydrolyzed enzymatically.
- the ratio of raw material to extract is V 2 .
- Soluble and insoluble phases are separated and then filtered or filtered sterile thereafter.
- Bioxilift is offered by the company SILAB, France.
- UV protective substances it is also advantageous in the context of the present invention to prepare cosmetic preparations whose main purpose is not protection against sunlight, but which nevertheless contain a content of further UV protective substances.
- cosmetic preparations that are in the form of a sunscreen.
- the preparations according to the present invention preferably contain at least one further UV-A, UV-B and / or broad-spectrum filter substance.
- the formulations may, although not necessary, optionally also contain one or more organic and / or inorganic pigments as UV filter substances, which may be present in the water and / or the oil phase.
- the preparations according to the present invention can also advantageously be in the form of so-called oil-free cosmetic emulsions which contain a water phase and at least one UV filter substance which is liquid at room temperature as a further phase and which, in particular, can also be free of further oil components.
- UV filter substances in the context of the present invention are also:
- Heliopan AP is available from Symrise
- 2-phenylbenzimidazole-5-sulfonic acid such as its sodium, potassium or its ethanolamine ammonium salt, and also the sulfonic acid itself with the INCI name phenylbenzimidazole sulfonic acid (CAS No. 27503-81-7), which, for example, under the trade name Eusolex 232 is available from Merck or from Neo Heliopan Hydro from Symrise;
- Sulfonic acid derivatives of 3-Benzylidencamphers such as. B. 4- (2-oxo-3-bomyliden- methyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and salts thereof.
- Benzoxazole derivatives such as.
- Hydroxybenzophenones e.g. B. 2- (4'-diethylamino-2 1 -hydoxybenzoyl) -benzoeklare- hexyl ester (also: aminobenzophenone), which is available under the trade name Uvinul A Plus from BASF.
- Triazine derivatives such as. B.
- 4-aminobenzoic acid derivatives preferably (2- ethylhexyl) 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
- Esters of benzalmalonic acid preferably di-2-ethylhexyl 4-methoxybenzalmalonate;
- Esters of cinnamic acid preferably 4-methoxycinnamic acid (2-ethylhexyl) ester, 4-methoxycinnamic acid isopentyl ester;
- benzophenone preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy- 1- methoxy-1'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, and
- Ethylhexyl 2-cyano-3,3-diphenylacrylate (octocrylene), which is available from BASF under the name Uvinul N 539 T.
- Particularly advantageous preparations in the sense of the present invention which are distinguished by a high or very high UV-A protection, preferably contain further UV-A and / or broadband filters, in particular dibenzoylmethane derivatives, in addition to the filter substance (s) according to the invention.
- UV filters which can be used in the context of the present invention is of course not intended to be limiting.
- the total amount of the filter substances is from the range of 0.1 to 30 wt .-%, preferably 0.5 to 10 wt .-%, in particular 1, 0 to 6.0 wt .-% - each based on the total weight of the preparations - chosen to provide cosmetic preparations that protect the hair or the skin from the entire range of ultraviolet radiation. It is further preferred if the preparation additionally contains inorganic pigments, preferably coated titanium dioxide.
- Inorganic pigments within the meaning of the invention are metal oxides and / or other sparingly water-soluble or insoluble metal compounds, in particular oxides of titanium (TiO 2 ), zinc (ZnO), iron (eg Fe 2 O 3 ), zirconium (ZrO 2 ) , Silicon (SiO 2 ), manganese (for example MnO), aluminum (Al 2 O 3 ), cerium (for example Ce 2 O 3 ), mixed oxides of the corresponding metals and mixtures of such oxides and also the sulfate of barium (BaSO 4 ).
- the pigments can also be used advantageously in the form of commercially available oily or aqueous predispersions. Dispersants and / or solubilization agents may advantageously be added to these predispersions.
- the pigments may advantageously be surface-treated ("coated"), whereby, for example, a hydrophilic, amphiphilic or hydrophobic character is to be formed or retained.
- This surface treatment may consist in using a thin hydrophilic and hydrophilic pigment according to methods known per se
- the various surface coatings may also comprise water .
- Inorganic surface coatings in the sense of the present invention may consist of aluminum oxide (Al 2 O 3 ), aluminum hydroxide Al (OH) 3 , or alumina hydrate (also: alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO 3 J 6 , sodium metaphosphate (NaPO 3 J n , silicon dioxide (SiO 2 ) (also: silica, CAS no.
- Organic surface coatings for the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length of 200 to 350 dimethylsiloxane Units and silica gel) or alginic acid.
- Suitable titanium dioxide particles and predispersions of titanium dioxide particles are available from the following companies under the following trade names:
- Zinc oxide particles which are suitable according to the invention and predispersions of zinc oxide particles are obtainable from the following companies under the following commercial names:
- alpha-hydroxy acids are additionally present in the preparation. It is further preferred if the preparation additionally contains glycerol. It is further preferred if the preparation is an emulsion, preferably an O / W emulsion or an O / W hydrodispersion. It is further preferred if substances having a particle diameter of 10 to 250 nm, preferably 10 to 100 nm, are selected as the coated titanium dioxide. It is further preferred if the alpha-hydroxy acid is lactic acid, citric acid, malic acid or tartaric acid. It is further preferred if the preparation has a pH of from 3 to 10, preferably from 4 to 8.
- the invention also encompasses the use of a preparation according to the invention against wrinkles and / or for increasing skin elasticity.
- the emulsions may also contain hydrocolloids (also referred to as thickeners or gel formers) which can stabilize the preparations.
- Agar-agar, carrageenan, tragacanth, gum arabic, alginates, xanthan gum, pectins, polyoses, guar flour, locust bean gum, starch, dextrins, cellulose ethers, hydroxyethyl and -propyl cellulose derivatives, vinyl polymers, polycarboxylic acids are advantageous hydrocolloids which are advantageous according to the invention .
- Polyethers, polyimines, polyamides, polysilicic acids, clay minerals, zeolites, silicic acids are advantageous hydrocolloids which are advantageous according to the invention .
- Further advantageous gelling agents are for example copolymers of Ci-3 o O-alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or esters thereof.
- the INCI name for such compounds is "Acrylates / C 10-30 Alkyl Acrylate Crosspolymer.”
- Particularly advantageous are the Pemulen® types TR 1, TR 2 and TRZ from Goodrich (Noveon).
- Carbopols are also advantageous gelling agents for such preparations.
- Carbopols are polymers of acrylic acid, especially acrylate-alkyl acrylate copolymers.
- advantageous carbopols are the types 980, 981, 984 1342, 1382, 2984 and 5984.
- R can represent a hydrogen or a methyl group.
- the cellulose mixed ethers which are generally also referred to as methylcelluloses and which, in addition to a dominating content of methyl, additionally contain 2-hydroxyethyl, 2-hydroxypropyl or 2-hydroxybutyl groups.
- Particularly preferred are (hydroxypropyl) methylcelluloses, for example those available under the trade name Methocel E4M from Dow Chemical Comp.
- copolymers of polyvinylpyrrolidone for example the PVP hexadecene copolymer and the PVP eicosene copolymer, which are available under the trade names Antaron V216 and Antaron V220 from the GAF Chemicals Cooperation, as well as the Tricontayl PVP and the like.
- the binding ability of the UV filter in or on the skin is of great importance for the water resistance of the formulation. It is understood that oil-soluble UV filters are better bound to the (lipophilic) surface of the skin or are more difficult to wash off this than water-soluble UV filters.
- the cosmetic preparations according to the invention may contain cosmetic adjuvants, such as are commonly used in such preparations, for.
- preservatives preservatives, complexing agents, bactericides, perfumes, substances to increase the foaming, dyes, pigments that have a coloring effect, thickeners, moisturizing and / or moisturizing substances, fillers that improve the feel on the skin, fats, oils, waxes or other common ingredients of a cosmetic formulation, such as alcohols, polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.
- Advantageous preservatives for the purposes of the present invention are, for example, iodopropyl butylcarbamates (for example those available under the trade names Glycacil-L, Glycacil-S from Lonza and / or Dekaben LMB from Jan Dekker), parabens (ie p-hydroxybenzoic acid alkyl esters, such as Methyl, ethyl, propyl and / or butylparaben), phenoxyethanol, ethanol, benzoic acid and the like.
- the preservation system according to the invention also advantageously also preserving aids, such as octoxyglycerol, glycine soy etc.
- Advantageous complexing agents for the purposes of the present invention are, for example, EDTA, [S, S] -ethylenediamine disuccinate (EDDS), which is obtainable, for example, under the trade name Octaquest from the company Octel, pentasodium-ethylenediamine tetramethylenephosphonate, which is obtained, for example.
- EDDS ethylenediamine disuccinate
- B. under the trade name Dequest 2046 from the company.
- Monsanto is available and / or iminodisuccinic which u. a. from Bayer AG under the trade names Iminodisuccinat VP OC 370 (about 30% solution) and Baypure CX 100 is permanently available.
- compositions are also obtained when antioxidants are used as additives or active ingredients.
- the preparations advantageously contain one or more antioxidants.
- antioxidants all suitable or common for cosmetic applications antioxidants can be used.
- water-soluble antioxidants can be used, such as vitamins.
- Further preferred antioxidants are vitamin C and its derivatives, vitamin E and its derivatives, and vitamin A and its derivatives.
- the amount of the antioxidants (one or more compounds) in the preparations is preferably 0.001 to 30 wt .-%, particularly preferably 0.05 to 20 wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.
- vitamin E and / or its derivatives represent the antioxidant (s)
- vitamin A or vitamin A derivatives or carotenes or their derivatives represent the antioxidant (s)
- active ingredients to be used in the context of the present invention are those which have a positive effect on the condition of the skin, in particular active ingredients for positively influencing the aging skin, which reduce the development of wrinkles or even existing wrinkles.
- biochinones in particular ubiquinone (Q10) and ubiquinol, folic acid and its derivatives (in particular tetrahydrofolic acid and dihydrofolic acid), niacin and its derivatives (in particular niacinamide), creatine and creatinine, camitin, biotin, isoflavone and its derivatives, lipoic acid, ginkgo Extracts, hops and hops malt extracts.
- agents that promote the restructuring of connective tissue such as natural and / or synthetic isoflavonoids and isoflavonoid-containing plant extracts - such.
- soy and clover extracts - can be used very well in the formulations of the invention.
- the formulations are particularly suitable as active ingredients for supporting the skin functions in dry skin (such as, for example, vitamin C, biotin, camitin, propionic acid, green tea extracts, eucalyptus oil, urea and mineral salts (such as, for example, NaCl, Marine minerals) as well as osmolytes (such as inositol, betaine, quaternary ammonium compounds)).
- active ingredients for alleviating or positively affecting irritative skin conditions be it on sensitive skin in general or by Noxa irritated skin (UV light, chemicals), as beneficial.
- agents such as sericosides, various extracts of licorice, licochalcone, especially licochalcone A, dexpanthenol, inhibitors of prostaglandin metabolism, in particular cyclooxygenase and leukotriene metabolism, especially the 5-lipoxygenase, but also the 5-lipoxevase inhibitor protein, FLAP.
- creatine and creatinine are suitable active ingredients to create and / or renew an (energy) depot and to activate the repair of various cellular structures, in particular the DNA.
- modulators of pigmentation also proved to be advantageous.
- agents that reduce the pigmentation of the skin and thus lead to a cosmetically desired lightening of the skin and / or reduce the occurrence of age spots and / or lighten existing age spots include tyrosine sulfate, dioic acid (8-hexadecene-1,16-dicarboxylic acid) and various extracts of licorice, arbutin, alpha-arbutin, deoxyarbutin, fruit acids, especially alpha-hydroxy acids (AHAs), Bearberry (Uvae ursi), Ursolic acid, ascorbic acid, pyridoxamine, niacinamide,
- Inventive formulations which z. B. known anti-wrinkle active ingredients such as flavone glycosides (especially ⁇ -glycosyl rutin), coenzyme Q10, vitamin C and / or derivatives, vitamin E and / or derivatives and the like, are particularly advantageous for the prophylaxis and treatment of cosmetic or dermatological skin changes, as they are z. B. occur during skin aging (such as dryness,
- Moisturizers are substances or mixtures of substances which give cosmetic preparations the property, after application or distribution on the skin surface, to reduce the moisture release of the hom layer (also called transepidermal water loss (TEWL)) and / or to positively influence the hydration of the initial layer , Overall, the skin's barrier function is normalized, the skin is noticeably refreshed and invigorated, and the skin appears smoother. The deep-acting increase in moisture visibly reduces swelling and dark circles, stimulates the formation of skin's own lipids and stimulates the skin's natural anti-aging functions and the overall performance of the skin.
- TEWL transepidermal water loss
- moisturizers for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccharide gum-1, glycine soya, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid, panthenol and urea.
- the oil phase of the preparations according to the present invention advantageously contains nonpolar, for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane, polyolefins, hydrogenated polyisobutenes and isohexadecane.
- nonpolar for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane, polyolefins, hydrogenated polyisobutenes and isohexadecane.
- polyolefins polydecenes are the preferred substances.
- the oil phase can also have a content of cyclic or linear silicone oils or consist entirely of such oils, although it is preferred to use an additional content of other oil phase components in addition to the silicone oil or silicone oils.
- Silicone oils are synthetic compounds in which silicon atoms via oxygen atoms chain and / or net-like linked and the remaining valences of silicon by hydrocarbon radicals (usually methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated , Systematically, the silicone oils are called polyorganosiloxanes.
- the methyl-substituted polyorganosiloxanes which are the quantitative represent the most important compounds of this group and are distinguished by the following structural formula
- Dimethicones are available in different chain lengths or with different molecular weights.
- cyclomethicone octamethylcyclotetrasiloxane
- silicone oils are also advantageous for the purposes of the present invention, for example hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).
- Particularly advantageous polyorganosiloxanes in the context of the present invention are, for example, dimethylpolysiloxanes [poly (dimethylsiloxane)], which are obtainable, for example, under the trade names Abil 10 to 10 000 from Th. Goldschmidt.
- phenylmethylpolysiloxanes INCI: phenyl dimethicone, phenylmethicone
- cyclic silicones octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane
- cyclomethicones amino-modified silicones (INCI: amodimethicones) and silicone waxes, z.
- polysiloxane-polyalkylene copolymers (INCI: stearyl dimethicone and cetyl dimethicone) and dialkoxydimethyl polysiloxanes (stearoxy dimethicones and behenoxy stearyl dimethicone), which are available as various Abil-Wax types from Th. Goldschmidt.
- other silicone oils are also advantageous for the purposes of the present invention, for example cetyl dimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).
- the preparations according to the present invention may also advantageously contain one or more substances from the following group of siloxane elastomers, for example in order to increase the water resistance and / or the sun protection factor of the products: (a) Siloxane elastomers which contain the units R 2 SiO and RSiOi, 5 and / or R 3 SiO 0 , 5 and / or SiO 2 , wherein the individual radicals R are each independently hydrogen, Ci -24 -alkyl (as for example, methyl, ethyl, propyl) or aryl (such as phenyl or ToIyI), alkenyl (such as vinyl) and the weight ratio of the units R 2 SiO to RSiOi, 5 is selected from the range of 1: 1 to 30: 1;
- Siloxane elastomers which are insoluble and swellable in silicone oil obtainable by the addition reaction of an organopolysiloxane (1) containing silicon-bonded hydrogen with an organopolysiloxane (2) containing unsaturated aliphatic groups, the proportions used being such be such that the amount of hydrogen of the organopolysiloxane (1) or the unsaturated aliphatic groups of the organopolysiloxane (2)
- the siloxane elastomer (s) are in the form of spherical powders or in the form of gels.
- siloxane elastomers are those with the INCI name dimethicone / vinyl dimethicone crosspolymer, for example that available from DOW CORNING under the trade names DOW CORNING 9506 Powder available.
- siloxane elastomer is used in combination with oils of hydrocarbons of animal and / or vegetable origin, synthetic oils, synthetic esters, synthetic ethers or mixtures thereof.
- siloxane elastomer is used in combination with unbranched silicone oils or cyclic silicone oils or mixtures thereof which are liquid or pasty at room temperature.
- organopolysiloxane elastomers with the INCI name dimethicone / polysilicone-11, completely especially the Gransil types available from Grant Industries Inc. GCM, GCM-5, DMG-6, CSE gel, PM-GeI, LTX, ININ gel, AM-18 gel and / or DMCM-5.
- the siloxane elastomer is used in the form of a gel of siloxane elastomer and a lipid phase, the content of the silicone elastomer in the gel being 1 to 80% by weight, preferably 0.1 to 60% by weight , in each case based on the total weight of the gel.
- the total amount of siloxane elastomers from the range of 0.01 to 10 wt .-%, preferably from 0.1 to 5 wt .-%, each based on the total weight of Formulation, to choose.
- Bioxylift was used as Pimpinella anis fruit extract.
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Abstract
L'invention concerne une préparation cosmétique contenant (a) un extrait aqueux d'anis (extrait d'anis vert), en vente sous le nom commercial de Bioxilift de la société SILAB, St. Viance, France, et (b) un ou plusieurs agents émulsifiants sélectionnés dans le groupe constitué par le citrate de stéarate de glycéryle, le distéarate de polyglycéryle-3-méthylglucose, PEG-40-stéarate, PEG-100-stéarate, cétéareth-20 et stéareth-21.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005026005A DE102005026005A1 (de) | 2005-06-03 | 2005-06-03 | Kosmetische Zubereitungen mit einem Gehalt an einem besonderen Anisfruchtextrakt und bestimmten Emulgatoren |
| PCT/EP2006/062195 WO2006128779A1 (fr) | 2005-06-03 | 2006-05-10 | Preparations cosmetiques presentant une certaine teneur en extrait aqueux d'anis et en agents emulsifiants non ioniques specifiques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1890775A1 true EP1890775A1 (fr) | 2008-02-27 |
Family
ID=36818350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06763110A Ceased EP1890775A1 (fr) | 2005-06-03 | 2006-05-10 | Preparations cosmetiques presentant une certaine teneur en extrait aqueux d'anis et en agents emulsifiants non ioniques specifiques |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1890775A1 (fr) |
| DE (1) | DE102005026005A1 (fr) |
| WO (1) | WO2006128779A1 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007052536A1 (de) * | 2007-11-01 | 2009-05-07 | Beiersdorf Ag | Wirkstoffkombinationen aus Anisfruchtextrakt und Weißen Teeextrakt |
| DE102007062691A1 (de) * | 2007-12-21 | 2009-06-25 | Beiersdorf Ag | Wirkstoffkombinationen aus Anisfruchtextrakt und einem oder mehreren 2,3-Dibenzylbutyrolactonen |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3818674B2 (ja) * | 1992-06-02 | 2006-09-06 | 三省製薬株式会社 | 皮膚外用剤 |
| DE19922385A1 (de) * | 1999-05-14 | 2000-11-16 | Arnold Zajonz | Schönheits-Elixier |
| TW555566B (en) * | 1999-11-16 | 2003-10-01 | Unilever Nv | Cosmetic compositions containing anise extract and retinoids |
| DE10141472A1 (de) * | 2001-08-29 | 2003-03-20 | Beiersdorf Ag | Stabililsierung oxidations- und/oder UV-empfindlicher Wirkstoffe |
| EP1310261A1 (fr) * | 2001-11-09 | 2003-05-14 | Cognis France S.A. | Utilisation d'un extrait de Vigna aconitifolia dans une composition cosmétique et/ou dermopharmaceutique |
| US20040018244A1 (en) * | 2002-03-12 | 2004-01-29 | Playtex Products, Inc. | Lotion compositions |
| FR2839618B1 (fr) * | 2002-05-15 | 2004-07-16 | Dominique Gagnant | Composition de plantes medicinales pour la perte de poids et de la cellulite |
| US20040126449A1 (en) * | 2002-12-30 | 2004-07-01 | Gopa Majmudar | Topical composition and methods for treatment of aged or environmentally damaged skin |
| DE10301632A1 (de) * | 2003-01-17 | 2004-07-29 | Beiersdorf Ag | Kosmetische oder dermatologische Zubereitungen mit einem Gehalt an Kreatin, Kreatinin und/oder seinen Derivaten in Kombination mit Sojabohnenkeimextrakten |
| DE10333029A1 (de) * | 2003-07-21 | 2005-02-17 | Merck Patent Gmbh | Nanopartikuläres UV-Schutzmittel |
| DE10356864A1 (de) * | 2003-12-03 | 2005-07-07 | Beiersdorf Ag | Kosmetische und dermatologische Zubereitungen mit einem Gehalt an Licochalcon A und Sojabohnenkeimextrakten |
| FR2863164B1 (fr) * | 2003-12-04 | 2006-02-24 | Silab Sa | Procede d'obtention d'un principe actif a partir de pimpinella anisum, principe actif obtenu et application cosmetique |
| DE102004054926B3 (de) * | 2004-11-10 | 2005-12-08 | Lancaster Group Gmbh | Kosmetisches Hautmattierungsmittel |
| CA2588560A1 (fr) * | 2004-12-29 | 2006-07-06 | Labo Cosprophar Ag | Composition cosmetique a application cutanee appropriee pour detendre des rides d'expression |
-
2005
- 2005-06-03 DE DE102005026005A patent/DE102005026005A1/de not_active Withdrawn
-
2006
- 2006-05-10 WO PCT/EP2006/062195 patent/WO2006128779A1/fr not_active Ceased
- 2006-05-10 EP EP06763110A patent/EP1890775A1/fr not_active Ceased
Non-Patent Citations (3)
| Title |
|---|
| DATABASE GNPD [online] MINTEL; 1 February 2005 (2005-02-01), CARITA: "Progressif Anti-Rides Cream for Eyes", Database accession no. 342344 * |
| DATABASE GNPD [online] MINTEL; 1 October 2004 (2004-10-01), POLLENA MALWA: "Botox System Anti-Wrinkle Night Cream", Database accession no. 309826 * |
| See also references of WO2006128779A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006128779A1 (fr) | 2006-12-07 |
| DE102005026005A1 (de) | 2006-12-07 |
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