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EP1868903B1 - Élément de déversement refermable pour emballages composites carton/plastique - Google Patents

Élément de déversement refermable pour emballages composites carton/plastique Download PDF

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Publication number
EP1868903B1
EP1868903B1 EP07727720A EP07727720A EP1868903B1 EP 1868903 B1 EP1868903 B1 EP 1868903B1 EP 07727720 A EP07727720 A EP 07727720A EP 07727720 A EP07727720 A EP 07727720A EP 1868903 B1 EP1868903 B1 EP 1868903B1
Authority
EP
European Patent Office
Prior art keywords
cutting element
pouring
thread
cutting
shell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP07727720A
Other languages
German (de)
English (en)
Other versions
EP1868903A1 (fr
Inventor
Felix Rigling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SIG Services AG
Original Assignee
SIG Technology AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SIG Technology AG filed Critical SIG Technology AG
Priority to PL07727720T priority Critical patent/PL1868903T3/pl
Publication of EP1868903A1 publication Critical patent/EP1868903A1/fr
Application granted granted Critical
Publication of EP1868903B1 publication Critical patent/EP1868903B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/42Details of containers or of foldable or erectable container blanks
    • B65D5/72Contents-dispensing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/42Details of containers or of foldable or erectable container blanks
    • B65D5/72Contents-dispensing means
    • B65D5/74Spouts
    • B65D5/746Spouts formed separately from the container
    • B65D5/747Spouts formed separately from the container with means for piercing or cutting the container wall or a membrane connected to said wall
    • B65D5/748Spouts formed separately from the container with means for piercing or cutting the container wall or a membrane connected to said wall a major part of the container wall or membrane being left inside the container after the opening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/32Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/42Details of containers or of foldable or erectable container blanks
    • B65D5/72Contents-dispensing means
    • B65D5/74Spouts

Definitions

  • the invention relates to a resealable pouring element for cardboard / plastic composite packages according to the preamble of claim 1.
  • Reclosable pouring spouts for disposable packages have long been known in many designs.
  • versions with screw cap are particularly popular because they ensure a reliable tight reclosure, so that it can be shaken in resealed packaging, without any of the contents can escape.
  • Such spouts are often constructed in three parts, with a peripheral flange equipped with a frame member fixed to the top of the composite package connected is.
  • the actual frame shape is cylindrical, wherein inside the cylinder, a cutting element is arranged, which, actuated by the screw, has the task of opening the composite pack by it when first opening the screw from the frame member inside the Composite package is moved, so that below the pouring a pouring opening is formed.
  • Another three-part pouring element is in the generic EP 1 088 764 B1 described.
  • the frame member has an external thread and the screw on a corresponding internal thread.
  • the cutting element is forced during initial actuation of the screw through corresponding threads in the interior of the frame member or on the outer periphery of the cutting element to push axially into the composite material.
  • There frame member and cutting element are also connected to each other in the production by injection molding, however, the cutting element is connected to the flange of the frame member with this.
  • the present invention has the object, the above-mentioned and described in more detail above pouring element for cardboard / plastic composite packages and further, that while maintaining a simple three-part construction a particularly simple assembly and good cohesion of the preassembled pouring is achieved , Furthermore, a reliable penetration of the the spout opening spanning film to be guaranteed when first opened.
  • the external thread of the cutting element consists of two threaded sections, each extending over about a quarter of the circumference of the cutting element and having a slope which is steeper than the internal thread of the screw cap, which cooperates with the external thread of the frame member in that the cutting element has circumferentially distributed and radially projecting cams extending axially from the upper edge of the cutting element to beyond the outer thread so as to form a stop for the cutting element pushed into the interior of the frame element during assembly ,
  • the invention has recognized that in this way the cutting element is always in a defined position: After removal from the injection mold a plurality of circumferentially distributed radial connecting bridges are provided for connection between the frame member and cutting element, which between the bottom of the cutting element and the upper edge run of the frame element and are destroyed only when nesting. Later, dropping out of the cutting element from the downwardly open frame member during transport or application to the composite package is reliably prevented. Even with the pouring element already applied to the composite packing, no damage can be caused to it lying PE layer of the over-coated pouring opening, since the actual cutting members having cutting element is arranged protected inside the frame member.
  • a simultaneous axial telescoping of the mounted on the unit of cutting element and frame element screw is sufficient to allow the final assembly of the applied to a composite package pouring.
  • the frame member has at least one internal thread, which consists of two threaded portions, each extending over about a quarter of the circumference and having a slope corresponding to the pitch of the external thread of the cutting element.
  • a further preferred embodiment of the invention provides that the external thread of the frame member is kannaka marc.
  • the external thread in a preferred embodiment of the invention from a Plural consists of individual with short interruptions spaced threaded portions.
  • the frame element at its lower inner circumference on a circumferential and downwardly pointing lip. This is manufacturing technology when removing the injection-molded component frame element / cutting element low and further, the lip serves as a stop for the in the frame member when opening turned into cutting element.
  • a further teaching of the invention provides that the cutting element has a plurality of circumferentially arranged radially outwardly directed projections, which cooperate with corresponding inner cam of the frame member to prevent unscrewing of the cutting element from the frame member. When screwing on the screw cap, they release the rotation of the cutting element only in one direction, allowing only one left turn.
  • These projections can be formed either by the cams projecting radially on the outside of the cutting element and / or by respective horizontal extensions of the upper ends of the threaded sections. Particularly preferably, the cams and the threaded sections merge into one another.
  • the cutting element has on its outer side a plurality circumferentially distributed and radially projecting cams, which extend from the upper edge of the cutting element down and in shape correspond to the already described cam of the cutting element.
  • the lower ends of all cams lie in a common, perpendicular to the vertical axis of the cutting element extending plane and thus serve for safe support on the lip at the inner end of the frame member.
  • the screw cap has at least one internal force transmission element, which causes the first movement of the screw through the arranged inside the cutting element projecting cam, the movement of the cutting element.
  • a power transmission element is preferably designed trapezoidal and concentric to the screw cap bent and facilitates the assembly process, the orientation of the screw with respect to the cutting element.
  • An inventive pouring element preferably has a tamper-evident seal. This can be formed by an integrally molded with the screw cap and radially projecting from this flat element, which is firmly connected to the flange of the frame member, wherein the element is connected to at least one destructible material bridge with the screw cap.
  • a preferred embodiment of a pouring element according to the invention is shown to make clear the process steps of its manufacture and its operation during opening.
  • Fig. 1 an inventive pouring element shown in longitudinal section, consisting of a frame member 1, an integrally molded thereon with the frame member 1 cutting element 2 and a screw 3.
  • the frame member 1 has in its cylindrical main body, an external thread 4 and a circumferential flange 5 for attachment to a (not shown) on composite package.
  • a threaded portion 6A Inside the frame member 1 can be seen a threaded portion 6A.
  • the assembly of frame element 1 and cutting element in Fig. 2 shown in perspective.
  • an inwardly projecting cam 9 can be seen at the upper edge of the frame member 1, which serves as a stop for the cutting element 2, which will be discussed in more detail below.
  • Fig. 2 shows that the cutting element has at its upper periphery a plurality of cams, which project radially outward, wherein two opposed cams 10 are each disposed above the threaded portions 7A and 7B. Further cams 11 and 12, of which only the front of the respectively opposite pairs can be seen, are in the illustrated and so far preferred embodiment with a horizontal extension 7D of the threaded portion 7A integrally connected. On the opposite side is also a horizontal extension 7C of the threaded portion 7B can be seen. However, it is also possible to dispense with the cams 12 and the extensions 7C and 7D.
  • teeth 13 of the cutting element 2 can be seen well. These teeth 13 have in the preferred and illustrated embodiment sharp edges.
  • in the upper inner region of the cutting element 2 are in turn radially inwardly projecting cam 14 to recognize, as particularly clear Fig. 2 evident.
  • the frame member 1 is connected to the cutting element 2 via connecting bridges 15, as also out Fig. 2 evident.
  • the screw cap 3 has an internal thread 16 corresponding to the pitch of the external thread 4 of the frame element 1 and an internal trapezoidal force-transmitting element 17 running essentially trapezoidal and concentric with the screw cap.
  • the force transmission element 17 causes the cutting element with the aid of the inwardly projecting cam 14 is rotated during the first opening of the spout along the threaded portions 6 and 7 and thus penetrates axially into the package interior.
  • the screw cap 3 is now first moved over the cutting element 2 protruding from the frame element 1, as in FIG Fig. 3 is shown.
  • the remaining reference numerals in Fig. 3 correspond to those of Fig. 1 and 2 ,
  • Fig. 4 now shows the fully assembled pouring element in vertical section, wherein the axial movement of the applied screw cap 3 and the cutting element 2 has been moved axially into the interior of the frame member 1, without moving in rotation. It can be seen clearly that the tips of the teeth 13 are also arranged at a distance from the lower edge of the frame element 1.
  • Fig. 5 is the finished mounted pouring for clarity again shown in perspective.
  • the pouring element according to the invention also has a tamper-evident seal:
  • a plate 18 is integrally molded onto the screw cap 3, which is connected via connecting bridges 19 with the screw cap 3, as is clear Fig. 5 evident.
  • the plate 18 has on its underside in the present case, two pins 20 which in corresponding recesses 21 (FIG. Fig. 2 ) of the flange 5 engage from the frame member 1 which are caulked to the fixed connection from below.
  • Fig. 6 to 9 finally describe the function of the pouring element according to the invention during the first opening operation of the screw 3.
  • Fig. 6 the mounting position from the Fig. 4 and 5 , but reproduced without screw cap 3.
  • the inner cam 9 with the outside Cam 11 and the end of the integrally connected to the cam 11 extensions 7C and 7D of the threaded portions 7A and 7B cooperate. Unscrewing the cutting element 2 from the frame member 1 upwards is reliably excluded by this locking, since the cutting element 2 can rotate only by turning to the left when unscrewing the screw 3.
  • Fig. 7 now shows a state in which the teeth are just in contact with the film to be pierced (not shown). It can be seen clearly that the lower edges of the cams 10 extend down to the respective threaded section 6A or 6B of the internal thread of the frame element 1. Despite the only one-piece threaded sections 6A, 6B and 7A, 7B, a reliable guidance for the necessary rotary cutting movement is achieved.
  • the 8 and 9 show the cutting element 2 in its end position in which it remains even after further use of the screw 3 by re-screwing or screwing and reliably holds back the opened film from the pouring channel in this way.
  • all cams 10, 11 and 12 arranged diametrically opposite each other ensure that a "falling in" of the cutting element 2 into the interior of the package is reliably ruled out.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Cartons (AREA)
  • Packages (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)

Claims (15)

  1. Organe verseur refermable pour emballages composites en carton/matière synthétique, en particulier emballages pour boisson, constitué d'un élément de base (1) présentant une bordure de fixation (5) périphérique, de même qu'un filetage externe (4) et un filetage interne (6), d'un élément de coupe (2) présentant un filetage externe (7), et d'un bouchon à visser (3) avec un filetage interne (16), dans lequel l'élément de coupe (2) est, à l'état injecté, produit par injection à l'extrémité de l'élément de base (1) opposée à la bordure de fixation (5), et d'une pièce avec celui-ci par l'intermédiaire de traverses de liaison (15), et dans lequel l'élément de coupe (2) est disposé, en position de montage de l'organe verseur, à l'intérieur de l'élément de base (1),
    caractérisé en ce que le filetage externe (7) de l'élément de coupe (2) est constitué de deux sections de filets (7A et 7B), lesquelles s'étendent chacune sur sensiblement un quart de la périphérie de l'élément de coupe (2) et présentent un pas plus raide que le filetage interne (16) du bouchon à visser (3), qui coopère avec le filetage externe (4) de l'élément de base (1), et en ce que le filetage interne (6) de l'élément de base (1) se compose de deux sections de filets (6A et 6B) qui s'étendent chacune sur un quart de la périphérie et présentent un pas qui correspond au pas du filetage externe (7) de l'élément de coupe (2), et en ce que l'élément de coupe (2) présente des bossages (10) disposés à l'écart les uns des autres à la périphérie de sa face externe, et saillant radialement, lesquels s'étendent depuis le bord supérieur de l'élément de coupe (2) jusqu'au-delà du filetage externe (7) de l'élément de coupe (2) de telle sorte que ses bords inférieurs forment avec les sections de filets (6A, respectivement 6B) du filetage interne (6) de l'élément de base (1) une butée pour l'élément de coupe (2) pressé au montage à l'intérieur de l'élément de base (1).
  2. Organe verseur selon la revendication 1,
    caractérisé en ce que le filetage externe (4) de l'élément de base (1) est double.
  3. Organe verseur selon la revendication 1 ou 2,
    caractérisé en ce que le filetage externe (4) est constitué de plusieurs sections de filets distinctes.
  4. Organe verseur selon l'une des revendications 1 à 3,
    caractérisé en ce que l'élément de base (1) présente à sa périphérie interne inférieure une lèvre périphérique (8) dirigée vers le bas.
  5. Organe verseur selon l'une des revendications 1 à 4,
    caractérisé en ce que l'élément de coupe (2) présente plusieurs saillies disposées à la périphérie, dirigées radialement vers l'extérieur, lesquelles coopèrent avec des bossages internes correspondants (9) de l'élément de base (1), pour empêcher l'élément de coupe (2) de sortir en tournant de l'élément de base (1).
  6. Organe verseur selon la revendication 5,
    caractérisé en ce que les saillies sont formées par des bossages (11) saillant radialement, à la face externe de l'élément de coupe (2).
  7. Organe verseur selon la revendication 5,
    caractérisé en ce que les saillies sont chacune formées par des prolongements (7C, 7D) horizontaux des extrémités supérieures des sections de filets (7A et 7B).
  8. Organe verseur selon les revendications 6 et 7,
    caractérisé en ce que les bossages (11) et les sections de filets (7A et 7B) se raccordent.
  9. Organe verseur selon l'une des revendications 1 à 8,
    caractérisé en ce que l'élément de coupe (2) présente à sa face externe plusieurs premiers bossages (12) disposés à l'écart les uns des autres à la périphérie et saillant radialement, lesquels s'étendent vers le bas à partir du bord supérieur de l'élément de coupe (2) et corresponde en forme à des seconds bossages (10 ou 11).
  10. Organe verseur selon la revendication 9,
    caractérisé en ce que les extrémités inférieures des seconds bossages (10 et 11) se situent dans un plan s'étendant globalement perpendiculairement à un axe vertical de l'élément de coupe (2), pour s'appuyer sur la lèvre (8) lorsque l'élément de coupe (2) sort de l'élément de base (1).
  11. Organe verseur selon la revendication 9,
    caractérisé en ce que les extrémités inférieures des premiers bossages (12) se situent dans un plan s'étendant globalement perpendiculairement à un axe vertical de l'élément de coupe (2), pour s'appuyer sur la lèvre (8) lorsque l'élément de coupe (2) sort de l'élément de base (1).
  12. Organe verseur selon l'une des revendications 1 à 11,
    caractérisé en ce que le bouchon à visser (3) présente au moins un élément (17) de transfert de force situé à l'intérieur, lequel produit le déplacement de l'élément de coupe (2) lors de la première rotation d'ouverture du bouchon à visser (3), par l'intermédiaire de bossages (14) disposés à l'intérieur de l'élément de coupe (2).
  13. Organe verseur selon l'une des revendications 1 à 12,
    caractérisé en ce que l'élément (17) de transfert de force au moins présent est réalisé sensiblement en forme de trapèze, et avec un développement concentrique au bouchon à visser (3).
  14. Organe verseur selon l'une des revendications 1 à 13,
    caractérisé en ce que l'organe verseur présente un sceau de garantie.
  15. Organe verseur selon la revendication 9,
    caractérisé en ce qu'une patte plate (18) injectée d'une pièce avec le bouchon à visser et s'écartant radialement de celui-ci, sert de sceau de garantie, et est fixée à la bordure (5) de l'élément de base (1) avant le montage final de l'organe verseur.
EP07727720A 2006-04-04 2007-04-03 Élément de déversement refermable pour emballages composites carton/plastique Active EP1868903B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07727720T PL1868903T3 (pl) 2006-04-04 2007-04-03 Dający się ponownie zamykać element wylewowy dla zespolonych opakowań z kartonu/ tworzywa sztucznego

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006016113A DE102006016113B3 (de) 2006-04-04 2006-04-04 Wiederverschließbares Ausgießelement für Karton/Kunststoff-Verbundpackungen
PCT/EP2007/053249 WO2007115976A1 (fr) 2006-04-04 2007-04-03 Élément de déversement refermable pour emballages composites carton/plastique

Publications (2)

Publication Number Publication Date
EP1868903A1 EP1868903A1 (fr) 2007-12-26
EP1868903B1 true EP1868903B1 (fr) 2009-06-03

Family

ID=38123787

Family Applications (2)

Application Number Title Priority Date Filing Date
EP07727720A Active EP1868903B1 (fr) 2006-04-04 2007-04-03 Élément de déversement refermable pour emballages composites carton/plastique
EP07727724A Active EP1863717B1 (fr) 2006-04-04 2007-04-03 Élément de déversement refermable pour emballages composites carton-plastique

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP07727724A Active EP1863717B1 (fr) 2006-04-04 2007-04-03 Élément de déversement refermable pour emballages composites carton-plastique

Country Status (16)

Country Link
US (2) US20090302037A1 (fr)
EP (2) EP1868903B1 (fr)
KR (2) KR20080114672A (fr)
CN (2) CN101316765A (fr)
AR (1) AR060305A1 (fr)
AT (2) ATE432883T1 (fr)
AU (2) AU2007236004A1 (fr)
BR (2) BRPI0702839A (fr)
CA (2) CA2603111A1 (fr)
DE (3) DE102006016113B3 (fr)
EA (2) EA013781B1 (fr)
ES (2) ES2327974T3 (fr)
MX (2) MX2007015318A (fr)
PL (2) PL1868903T3 (fr)
TW (1) TW200824982A (fr)
WO (2) WO2007115978A1 (fr)

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DE102010040825A1 (de) * 2010-09-15 2012-03-15 Robert Bosch Gmbh Verschlussvorrichtung aus Kunststoff

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DE102007057863A1 (de) * 2007-11-29 2009-06-04 Sig Technology Ag Selbstöffnendes und wiederverschließbares Ausgießelement aus Kunststoff zur Applikation auf einer Packung für Flüssigkeiten
GB0907662D0 (en) * 2009-05-02 2009-06-10 Elopak Systems Improvements in or relating to pour spout fitments
DE102010028518A1 (de) * 2010-05-04 2011-11-10 Robert Bosch Gmbh Verschlussvorrichtung
WO2012034836A1 (fr) * 2010-09-15 2012-03-22 Robert Bosch Gmbh Dispositifs d'ouverture refermables
DE102010048415A1 (de) * 2010-10-15 2012-04-19 Sig Technology Ag Wiederverschließbares Ausgießelement mit Barrierefolie und Stützwand
EP2655202B1 (fr) * 2010-12-21 2017-02-08 Capartis AG Verseur, procédé pour produire un verseur et contenant pourvu d'un tel verseur
DE102011017509A1 (de) 2011-04-26 2012-10-31 Robert Bosch Gmbh Verschluss mit Adapter
ITMI20120063A1 (it) * 2012-01-20 2013-07-21 Ipi Srl Dispositivo di apertura richiudibile per un contenitore di prodotti versabili
DE102012020529A1 (de) * 2012-10-19 2014-04-24 Sig Technology Ag Wiederverschließbares Ausgießelement für eine Verpackung und Dorn eines drehbaren Dornrades einer Verpackungsmaschine zur Aufnahme eines solchen Ausgießelementes und Kombination von Ausgießelement und Dorn
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CN109311560B (zh) * 2016-05-31 2021-03-23 Sig技术股份公司 用于复合包装件的倾倒元件及具有倾倒元件的复合包装件
EP3251965A1 (fr) * 2016-05-31 2017-12-06 SIG Technology AG Bec verseur pour emballage composite et emballage composite doté d'un bec verseur
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KR20080114672A (ko) 2008-12-31
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PL1868903T3 (pl) 2009-11-30
EA200702016A1 (ru) 2009-04-28
BRPI0702839A (pt) 2008-04-01
EA013271B1 (ru) 2010-04-30
MX2007015317A (es) 2008-02-11
EP1863717B1 (fr) 2009-06-03
US20080210745A1 (en) 2008-09-04
WO2007115978A1 (fr) 2007-10-18
EP1868903A1 (fr) 2007-12-26
PL1863717T3 (pl) 2009-11-30
CN101316765A (zh) 2008-12-03
MX2007015318A (es) 2008-02-11
US20090302037A1 (en) 2009-12-10
ATE432883T1 (de) 2009-06-15
KR20080114671A (ko) 2008-12-31
CA2603111A1 (fr) 2007-10-18
DE502007000808D1 (de) 2009-07-16
AU2007221929A1 (en) 2007-11-01
CA2605163A1 (fr) 2007-10-18
ATE432884T1 (de) 2009-06-15
DE102006016113B3 (de) 2007-08-23
TW200824982A (en) 2008-06-16
ES2327975T3 (es) 2009-11-05
CN101316764A (zh) 2008-12-03
ES2327974T3 (es) 2009-11-05
EA013781B1 (ru) 2010-06-30
DE502007000811D1 (de) 2009-07-16
WO2007115976A1 (fr) 2007-10-18
BRPI0702842A (pt) 2008-04-01
AU2007236004A1 (en) 2007-10-18
AR060305A1 (es) 2008-06-04

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