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EP1718541B1 - Dual or multi-chamber tube - Google Patents

Dual or multi-chamber tube Download PDF

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Publication number
EP1718541B1
EP1718541B1 EP05707592A EP05707592A EP1718541B1 EP 1718541 B1 EP1718541 B1 EP 1718541B1 EP 05707592 A EP05707592 A EP 05707592A EP 05707592 A EP05707592 A EP 05707592A EP 1718541 B1 EP1718541 B1 EP 1718541B1
Authority
EP
European Patent Office
Prior art keywords
tube
chamber
preparation
passage channel
mouth edge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP05707592A
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German (de)
French (fr)
Other versions
EP1718541A1 (en
Inventor
Theodor Park
Beate Zirn
Susanne Bietz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1718541A1 publication Critical patent/EP1718541A1/en
Application granted granted Critical
Publication of EP1718541B1 publication Critical patent/EP1718541B1/en
Anticipated expiration legal-status Critical
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/22Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with two or more compartments
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/05Details of containers
    • A45D2200/058Means for mixing different substances prior to application

Definitions

  • the present invention relates to a multi-chamber tube according to the preamble of claim 1.
  • This is particularly a two-chamber tube, comprising an outer tube tube (tube jacket) with a tube neck mounted on a tube shoulder, which opens into an outlet, wherein a first chamber with a first preparation and another Chamber is filled with a second preparation, wherein in the tube neck provided for the passage of the first preparation of the first passageway and a second passage provided for the passage of the second passage are arranged, the passageways open in the outlet, wherein in the outlet, the first preparation and the second preparation to a common strand come together.
  • Two-chamber or multi-chamber tubes are already known in the prior art, wherein in principle two relationssforrrien are familiar.
  • two tubular tubes are inserted into one another, the inner tube with its tube head being inserted in the passageway of the outer tube.
  • the two tubes of this "tube-in-tube” are welded or folded together at their end.
  • the two tubes define an inner and an outer chamber, with the chambers opening into the common head or exit region.
  • a tubular tube is divided by a dividing wall into two adjacent chambers ("side-by-side").
  • the through channels are designed so that the two separate in the chambers compositions come together only in the mouth area at the end of the tube neck.
  • the two preparations emerge together from the tube as soon as pressure is exerted on the outer tube.
  • the design of the outlet determines in which striped pattern the preparations emerge from the tube.
  • known commercially available tubes have the same partial volumes of the various chambers and form this ratio in a corresponding mixing ratio, in particular of 50:50, in the outlet.
  • the tubes are provided with a tamper-evident closure, such as a peelable foil, which suppresses mixing prior to first use. At least after the first use, however, the mixing of the two components can hardly be prevented by the known screw caps. This mixing initially adversely affects the aesthetic impression of the product. If the two components have different colors, as is known, for example, from toothpastes, a smudged beginning always appears on the toothbrush first, before the stripes in the toothpaste strand stand out in color. Another problem is that the compositions chemically contaminate each other, which has unpleasant consequences for aggressive components.
  • a generic tube is from the US 2003/0106905 known.
  • the object of the present invention is first to provide a multi-chamber tube, which is simple and inexpensive to produce and which is suitable as a reliable and storable dispenser for two-phase products. It is also the object of the invention to provide such a multi-chamber tube, which has any but fixed mixing ratio. Regardless, it is a further object of the invention to modify the multi-chamber tube so that the risk of mixing the components in the outlet area and the diffusion is reduced from chamber to chamber.
  • a first basic idea is to provide the volumes of the individual chambers in a ratio that differs from the previously known uniform distribution.
  • the invention is intended to include any unequal distribution of volumes that has a significant difference.
  • the exit area is designed accordingly.
  • the ratio of the chamber volumes is reflected in the cross sections of the through channels, which open in the outlet.
  • a through-channel can be divided into one or more parallel branch channels.
  • the cross sections of the branch channels added to the cross section of the passageway. It should be noted that it is advantageous for the function of the multi-chamber tubes if the different components present in the chambers each have approximately the same viscosity.
  • the advantage of the design according to the invention is that the chambers filled with different volumes can now be expressed relatively evenly until emptying of the residue and the product expressed has the same mixing ratio almost constant.
  • such tubes can be relatively easily finished and filled with the known methods. It can serve as a safe and comfortable container for a sensitive multi-component product.
  • a particularly preferred field of application of such two-chamber tubes is the range of colorants and / or tinting agents for keratinic fibers, in particular for human hair. Because of their chemical formulations, these agents require mixing ratios that differ from the uniform distribution. Especially for these two-component agent, the two preparations can be assembled separately from each other in a two-chamber tube according to the invention. At this point will be the registrations DE 103 59 538.4 . DE 103 59 557.0 and DE 103 59 539.2 , all of which originate from the applicant of this application and all have the filing date of 17.12.2003. These documents describe fillings for two-chambered tubes, the preparation intended for one chamber containing at least one substantive dye and / or at least one precursor of a naturally-analogous dye, while the preparation intended for filling the second chamber contains at least one care substance.
  • a preparation with at least one oxidation dye precursor and for the filling of the second chamber a preparation with at least one oxidizing agent or a care substance is described as filling for the one chamber, wherein the ratio of the volumes and thus the outlet for the preparations in a range between greater than 1 : 1 and 3: 1.
  • geometries of the tube openings are advantageous, which have a mixing ratio not equal to 50:50, namely from 80:20 to 60:40, preferably from 75:25.
  • the ratio of 75:25 from outside tube to inside tube is advantageous in the case of a color pigmented phase and a conditioner at a volume of 100 ml.
  • the outer tube and / or the inner tube can be made transparent.
  • the proportion of the color preparation about 75% and the proportion of care preparation can make up about 25% and therefore the color preparation in the case of a "tube-in-tube" is advantageously introduced into the outer tube with the larger volume . It is particularly advantageous if the shoulder region of the outer tube is reinforced with rounds, which have particularly good barrier properties. Thus, a diffusion of the dye can be excluded from the shoulder area. In order to prevent the diffusion as effectively as possible, it is advantageous to incorporate into the material of the tube shoulder aluminum or a suitable plastic, such as PTB.
  • a general problem of multi-chamber tubes is that the components mix in the exit area and that components diffuse into one another via the common exit area, so that mixing occurs in the chambers.
  • the discharge opening with a tamper-evident closure such as aluminum - or plastic film, to be sealed by the consumer before the first use Will get removed.
  • a tamper-evident closure is, as stated, difficult to assemble and also can not prevent the components from mixing after the first use.
  • the dyes mentioned here have a relatively high creep or diffusibility.
  • the problem of unwanted mixing is by no means limited to the multi-chamber tubes with different chamber volumes, but occurs in all multi-chamber tubes, even those with the same volume.
  • another general idea of the invention is to make the closure region of the multi-chamber tubes so that the risk of mixing is drastically reduced.
  • This problem is solved by the fact that the mouth edge of the first passage channel opposite to the mouth edge of the second passage channel on a different level.
  • one of the orifice edges is above or behind the other with respect to the exiting strand and forms a barrier to the composition that is in the lower-lying orifice-edge chamber.
  • the level created by the raised mouth edge can hardly be overcome by the composition. It thus acts as a kind of "diffusion brake".
  • This advantage initially pays off in the storage of the multicomponent products, the packaged products being characterized by a high storage stability in terms of mixing and / or diffusion.
  • the aesthetic requirements of consumers can be met, which in the case of differently colored components now at the first use and even after the first use can perceive a clear separation of colors.
  • the unsightly smearing of the components in the region of the tube head remains largely spared them.
  • the chemical reactivity of advantage to avoid the mixing. This is particularly true when the two components react together to form a possibly less stable, volatile or aggressive end product.
  • a particularly simple and thus advantageous type of implementation is to form the separate chambers as separate tubes, each with its own passage.
  • the through-channels are designed in different lengths.
  • the tubes are then collected in the tube neck by placing them side by side in a common holder, as is known from “side-by-side” tubes, or simply plugged into each other as in “tube-in-tube” tubes, then results in a difference in level of the mouth edges because of the different length of the through channels.
  • the through-channel of the inner tube is arranged coaxially with the through-channel of the outer tube and protrudes somewhat further.
  • the two individual chambers are arranged side by side in an outer shell, while the o.g. "tube in tube” has an inner tube which is completely surrounded by an outer tube.
  • This embodiment is characterized by a constant dosage of the two preparations.
  • the composition whose diffusion is to be avoided for example the component mixed with intense color pigments, is provided in the chamber whose mouth edge is at a lower level.
  • a level difference is greater than the usual in the manufacturing process tolerances, which can make up a size of one tenth of a millimeter.
  • Differences in level according to the invention have a size of at least 0.3 millimeters, preferably more than 0.5 millimeters and more preferably more than 1.0 millimeters.
  • a diffusion-inhibiting level difference can be ensured.
  • a level difference of about 1.5 millimeters can form.
  • Level differences of more than about 3 millimeters prove to be impractical especially in the present multiple tubes.
  • the two-chamber tube according to the invention is preferably made of a material that is suitable for the packaging of tinting and coloring agents of this type. It should be noted that due to the oxidation properties of the product, the barrier properties of commercially available plastic tubes are only limited sufficient.
  • a material is suitable for the direct dyes or their precursors, as well as for oxidizing agents and oxidation dye precursors, an aluminum laminate or pure aluminum, with pure aluminum tubes are only partially used because of their mechanical properties.
  • Aluminum laminate is understood here as an aluminum layer coated with multilayer plastic.
  • a tube has proven in which both the inner tube and the outer tube are made of aluminum laminate.
  • tubes made of plastic laminate (PE, PET, PP) or Kunststoffxextrulves (PE, PET, PP) with barrier layers, such as EVOH conceivable.
  • the material of the inner tube can be selected independently of the material of the outer tube. As already mentioned, it may be advantageous for reasons of an attractive design to manufacture the outer tube but also the inner tube made of transparent plastic.
  • a special significance attaches to the closure.
  • This is designed as a screw cap, the inner sleeve, as known from such screw caps, the outlet seals.
  • a seal is applied, which has a thickness of several, for example 3 millimeters and which consists essentially of a foam. This is covered against the outlet with glued paper and then an aluminum foil.
  • This seal is suitable for the mouth edges to press into the material so that the through channels are sealed.
  • the torque with which the cap is screwed on is limited.
  • an edge is provided on the inner diameter of the sleeve, which protrudes above the internal thread. When the cap is screwed on, this edge rests on a shoulder which surrounds the outlet at the front.
  • the invention should in principle not be restricted in any way with regard to this exit pattern, it may be preferred according to the invention if the first preparation exits as the main strand and the second preparation forms a plurality of colored strips running along this main strand. Also with regard to the number of strips, the invention should not be limited. A number of two to four stripes may be particularly preferred according to the invention for application or optical reasons. With the strips, the product can be aesthetically enhanced. In this case, in a first embodiment, the first preparation form the strips, while the second preparation forms the main strand and in a second embodiment the second preparation form the strips, while the first preparation forms the main strand. Advantageously, however, it is too Make sure that the colored preparation is stored in the chamber with the mouth edge at the lower level.
  • the two preparations may be preferred for the two preparations to form, in particular proportionally, the main strand together next to one another.
  • the outlet strand can consist of an inner region, formed from a first preparation, and an outer region, formed from the second preparation, wherein the preparations also form the outlet strand according to their arrangement in the tube.
  • FIG. 1 shows a section through the upper part of a two-chamber tube.
  • the two-chamber tube has an outer tube tube 1 with a tube shoulder 2 formed thereon and an outer through-channel 3.
  • the outer tube tube 1 forms as outer tube a first chamber 21 for a preparation A.
  • This first outer chamber 21 coaxially surrounds a tubular réelletube 4, which forms a further chamber 22 for a preparation B, wherein the réelletube 4 in turn has an inner tube shoulder 5 with a corresponding inner passageway 6.
  • the mecanical tube 4 is inserted into the outer tube tube 1 and held on not shown locking lugs in the outer passage 3.
  • Webs 7 form a stop when inserting and ensure the distance of the tube shoulders 2 and 5, so that a passage to the passage channel 3 remains.
  • the passageways 3 and 6 open into a common outlet.
  • outer tube and inner tube are formed by tubes, which are closed at their rear end by means of a common fold.
  • the outer wall 6a of the inner passage channel 6 is formed star-shaped. Different geometries for the walls of the inner through-channel 6 are in FIGS. 2a to 2i shown.
  • the cross-sectional area 9 of the star which may have three or four points, defines the size of the partial flow for the preparation B located in the inner tube (hatched).
  • the gussets 11 remaining between the outer wall 8 of the inner through-channel and the round outer wall 10 of the outer through-channel define the branch streams for the preparation located in the outer tube.
  • the size of the partial stream for the second preparation A is determined by the sum of the branch streams.
  • the two chambers 21 and 22 have different volumes, which are in a predetermined relationship to each other.
  • the through channels produce two partial streams with at least almost the same ratio, wherein one of the partial streams, such as, for example, according to 2 a or 2 c can be divided into a plurality of parallel branch streams.
  • one of the partial streams such as, for example, according to 2 a or 2 c can be divided into a plurality of parallel branch streams.
  • the embodiment according to FIG. 2c is particularly preferable.
  • orifice variants can be produced which form mixing ratios of at least 60:40 and preferably 75:25. The maximum achievable difference is around 80:20.
  • FIG. 3 shows a plan view of the head of a two-chamber tube, wherein clearly the cross-sectional geometry can be seen in the exit region in front of the discharge opening.
  • Shown is a Ronde made of plastic, which forms a tube shoulder 16, on which the neck 17 is formed. On the edge 18, in particular made of aluminum laminate outer tube tube is welded.
  • FIG. 4 shows a section through the Ronde after FIG. 3 , To recognize the tube head 12 of the inner tube, which is firmly inserted into the tube head 13 of the outer tube. In this example, the mouth edge 19 of the outer tube is at the level of the mouth edge 20 of the inner tube.
  • the passageways 3 and 6 are clearly visible.
  • FIG. 5 shows a view from below through the Ronde FIG. 3 and FIG. 4 , Evident are the webs 7, which bear against the shoulder 16 from the inside.
  • FIG. 6 It is shown how can be adjusted by modification of the outer wall 8 of the inner passage channel on the one hand, the mixing ratio and on the other hand, the width of the strip and thus the visual impression.
  • an outer wall 8 is shown in star shape, wherein the star has three peaks each.
  • the width of the tips 14 defines the width of the strips in the expressed strand.
  • a mixing ratio of 60:40 results in the three-part cross-sectional area 11 of the outer passageway to the cross-sectional area 9 of the inner passageway.
  • the tube head according to FIG. 6b has a mixing ratio of about 75:25 with relatively narrow strips.
  • 6c shows deeper curves of the walls 8, whereby wider stripes are nevertheless produced at a smaller mixing ratio of about 73:27.
  • the latter two conditions are suitable for two-chamber tubes, which serve as a donor for a tinting agent with about 75% color content and 25% care content.
  • the embodiment according to FIG. 6d shows a tube head, which realizes a cylindrical inner strand 15 within the likewise cylindrical outer strand 25.
  • the mixing ratio can be set arbitrarily over the diameter of the inner strand.
  • This embodiment is particularly suitable if the outer strand 23 is formed by a transparent preparation, while the inner strand forming preparation is colored.
  • FIG. 7 now is a section through an open two-chamber tube with a difference in level of the mouth edges shown. It is a "tube-in-tube", as described above.
  • the first passage 24 of the tube has a mouth edge 26 and the second passage 27 a mouth edge 28. It can be seen that the level of the mouth edge 26 with respect to the tube shoulder 30 is well below the level of the mouth edge 28.
  • the level difference is designated 29.
  • the double tube shown in this figure is particularly suitable for the exception of colored tinting agents. In this case, the component mixed with color pigments is stored in the chamber 31 formed by the outer tube.
  • the level difference 29 is sufficient to prevent the diffusion of the color pigments from the passage 24 through the exit area into the passageway 27.
  • the inner tube forms the chamber 32 and contains a care substance.
  • the tube head of the outer tube is in turn formed by a head piece 33 to which the tube 34 of the outer tube is attached.
  • the shoulder area is reinforced with an inlay 35.
  • the mecanictube in turn has a head piece 36, the geometry of the Through channels forms.
  • the tube 37 of the inner tube is formed.
  • the hoses 34 and 37 are sealed together at the end, not shown, and thus closed.
  • the head piece 36 is inserted into the through-channel 24 and latched via locking lugs 38 which engage in a groove 39. Webs 40 in turn ensure the distance.
  • Attention is drawn to the paragraph 41 which is provided at the upper end of the neck and on which an in the screw cap located edge hangs when screwing the cap.
  • FIG. 8 now shows the multi-chamber tube according to the invention in the form of a "tube-in-tube” FIG. 7 but with screwed-on screw cap 42.
  • the screwing of the screw cap 42 is made possible by a thread of the known type.
  • an inner sleeve 43 is provided, which seals the outlet.
  • a gasket 44 having a thickness of several millimeters and consisting essentially of a foam which is covered against the outlet with live paper and thereon an aluminum foil. It can be seen that the mouth edge 28 presses into the seal 44, while the seal 44 rests on the mouth edge 26. So the passageways are tightly closed.
  • an edge 45 is provided, which protrudes above the internal thread. This edge 45 settles when screwing the cap on the shoulder 41 ( FIG. 7 ), which surrounds the outlet end face. So a limitation of the torque is given. In addition, it is ensured that the skirt 46 of the screw cap 42 is not pressed onto the tube shoulder.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Tubes (AREA)
  • Package Specialized In Special Use (AREA)
  • External Artificial Organs (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)

Abstract

A multi-chamber tube package which comprises a first tube chamber having a tube nozzle channel extending from a tube shoulder and terminating in an outlet, and a second tube chamber having a tube nozzle channel terminating in an outlet adjoining the first outlet. The tube nozzle channels enable the dispensing of the multiple preparations from the chambers. The nozzle channels lead to an outlet where the first preparation and the second preparation meet and coalesce to form a common strand. The two channels and the chambers associated with them have a defined ratio to each other. One nozzle channel may be subdivided into one or more parallel branches and/or the nozzle channels may have orifice rims or edges which lie on different planes.

Description

Die vorliegende Erfindung betrifft eine Mehrkammertube gemäß Oberbegriff des Anspruchs 1. Diese ist insbesondere eine Zweikammertube, aufweisend ein äußeres Tubenrohr (Tubenmantel) mit einem auf einer Tubenschulter aufsitzenden Tubenhals, der in einem Auslass mündet, wobei eine erste Kammer mit einer ersten Zubereitung und eine weitere Kammer mit einer zweiten Zubereitung befüllbar ist, wobei im Tubenhals ein für den Durchgang der ersten Zubereitung vorgesehener erster Durchgangskanal und ein für den Durchgang der zweiten Zubereitung vorgesehener zweiter Durchgangskanal angeordnet sind, wobei die Durchgangskanäle im Auslass münden, wobei im Auslass die erste Zubereitung und die zweite Zubereitung zu einem gemeinsamen Strang zusammenkommen.The present invention relates to a multi-chamber tube according to the preamble of claim 1. This is particularly a two-chamber tube, comprising an outer tube tube (tube jacket) with a tube neck mounted on a tube shoulder, which opens into an outlet, wherein a first chamber with a first preparation and another Chamber is filled with a second preparation, wherein in the tube neck provided for the passage of the first preparation of the first passageway and a second passage provided for the passage of the second passage are arranged, the passageways open in the outlet, wherein in the outlet, the first preparation and the second preparation to a common strand come together.

Zwei- oder Mehrkammertuben sind bereits im Stand der Technik bekannt, wobei prinzipiell zwei Ausführungsforrrien geläufig sind. In der ersten besonders einfachen Ausführungsform sind zwei schlauchförmige Tuben ineinander gesteckt, wobei die Innentube mit ihrem Tubenkopf im Durchgangskanal der Außentube einsteckt. Die beiden Tuben dieser "tube-in-tube" sind an ihrem Ende gemeinsam verschweißt oder gefalzt. Die beiden Tuben definieren eine innere und eine äußere Kammer, wobei die Kammern in dem gemeinsamen Kopf- oder Austrittsbereich münden. In einer anderen Ausführungsform ist eine schlauchförmige Tube durch eine Trennwand in zwei nebeneinanderliegende Kammern ("side-by-side") geteilt. Auch in dieser Form sind die Durchgangskanäle so konzipiert, dass die beiden getrennt in den Kammern befindlichen Zusammensetzungen erst im Mündungsbereich am Ende des Tubenhalses zusammenkommen. Die beiden Zubereitungen treten gemeinsam aus der Tube aus, sobald Druck auf die Außentube ausgeübt wird. Die Gestaltung des Auslass bestimmt, in welchem Streifenmuster die Zubereitungen aus der Tube austreten. Dabei haben bekannte handelsübliche Tuben gleiche Teilvolumina der verschiedenen Kammern und bilden dieses Verhältnis in einem entsprechendem Mischungsverhältnis, insbesondere von 50 : 50, im Auslass ab.Two-chamber or multi-chamber tubes are already known in the prior art, wherein in principle two Ausführungsforrrien are familiar. In the first particularly simple embodiment, two tubular tubes are inserted into one another, the inner tube with its tube head being inserted in the passageway of the outer tube. The two tubes of this "tube-in-tube" are welded or folded together at their end. The two tubes define an inner and an outer chamber, with the chambers opening into the common head or exit region. In another embodiment, a tubular tube is divided by a dividing wall into two adjacent chambers ("side-by-side"). Also in this form, the through channels are designed so that the two separate in the chambers compositions come together only in the mouth area at the end of the tube neck. The two preparations emerge together from the tube as soon as pressure is exerted on the outer tube. The design of the outlet determines in which striped pattern the preparations emerge from the tube. In this case, known commercially available tubes have the same partial volumes of the various chambers and form this ratio in a corresponding mixing ratio, in particular of 50:50, in the outlet.

Für Produkte, deren zwei Phasen getrennt aufbewahrt werden müssen und deren Mischungsverhältnis von dem herkömmlichen Wert von 50 : 50 abweicht, sind die bekannten Tuben nicht tauglich. Auch wenn mitunter schon Mehrkammertuben mit unterschiedlichen Kammervolumina bekannt wurden, so war es damit bislang kaum möglich, das Mischungsverhältnis auch im ausgedrückten Strang zu reproduzieren. Somit werden mehrkomponentige Produkte nach wie vor in getrennten Behältnissen angeboten, wenn die Komponenten in einem ungleichen Verhältnis gemischt werden sollen. Das macht die Handhabung des Produktes für den Anwender verhältnismäßig unkomfortabel.For products whose two phases must be stored separately and whose mixing ratio differs from the conventional value of 50:50, the known tubes are not suitable. Although sometimes even multi-chamber tubes were known with different chamber volumes, so it was so far hardly possible to reproduce the mixing ratio in the expressed strand. Thus, multicomponent products are still offered in separate containers when the components are to be mixed in an unequal ratio. This makes handling the product relatively uncomfortable for the user.

Ein weiterer Nachteil der bekannten Tuben ist, dass sich die Zubereitungen im Austrittsbereich ungewollt vermischen, ohne dass der Nutzer auf die Tube drückt. Mitunter sind die Tuben mit einem Originalitätsverschluss, beispielsweise einem abziehbaren Folie, versehen, die ein Mischen vor dem ersten Gebrauch unterdrückt. Spätestens nach dem ersten Gebrauch lässt sich das Vermischen der beiden Komponenten jedoch durch die bekannten Schraubverschlüsse kaum verhindern. Dabei wirkt sich dieses Mischen zunächst nachteilig auf den ästhetischen Eindruck des Produktes aus. Wenn die beiden Komponenten unterschiedliche Farben aufweisen, wie es beispielsweise von Zahnpasten bekannt ist, darin erscheint auf der Zahnbürste immer zunächst ein verschmierter Anfang, bevor sich die Streifen im Zahnpastastrang farblich voneinander abheben. Ein anderes Problem liegt darin, dass sich die Zusammensetzungen gegenseitig chemisch verunreinigen, was gerade bei aggressiven Komponenten unangenehme Folgen hat.Another disadvantage of the known tubes is that the preparations unintentionally mix in the exit area without the user pressing on the tube. Occasionally, the tubes are provided with a tamper-evident closure, such as a peelable foil, which suppresses mixing prior to first use. At least after the first use, however, the mixing of the two components can hardly be prevented by the known screw caps. This mixing initially adversely affects the aesthetic impression of the product. If the two components have different colors, as is known, for example, from toothpastes, a smudged beginning always appears on the toothbrush first, before the stripes in the toothpaste strand stand out in color. Another problem is that the compositions chemically contaminate each other, which has unpleasant consequences for aggressive components.

Dabei hängt das Problem des Vermischens stark von der Beschaffenheit der Komponenten ab. So kann beobachtet werden, dass insbesondere direktziehende Farbstoffe oder Vorstufen naturanaloger Farbstoffe sich durch eine besonders hohe Diffusionsbereitschaft (Kriechfähigkeit) auszeichnen. In solchen Fällen beschränkt sich das Mischen nicht nur auf den Austrittsbereich, sondern es diffundiert der Farbstoff von der einen Kammer in die andere Kammer, so dass die darin enthaltene Zusammensetzung nachhaltig verunreinigt wird. Diese Diffusion lässt sich durch die gebräuchlichen dichtenden Verschlüsse, die auf den Kopf aufgeschraubt werden, auch bei hohem aufgewandten Drehmoment nicht verhindern.The problem of mixing depends strongly on the nature of the components. Thus it can be observed that in particular direct-pulling Dyes or precursors of nature-analogous dyes are characterized by a particularly high degree of diffusion readiness (creep resistance). In such cases, the mixing is not limited to the exit area, but the dye diffuses from one chamber to the other chamber, so that the composition contained therein is permanently contaminated. This diffusion can not be prevented by the usual sealing closures that are screwed onto the head, even at high torque applied.

Durch die Tendenz sich zu vermischen ist zudem die Lagerfähigkeit dieser Produkte stark eingeschränkt. So hat sich herausgestellt, dass bei mehrwöchiger Lagerung eine Diffusion der Komponenten über den gemeinsamen Austrittsbereich trotz fest aufgeschraubten Deckel nicht verhindert werden kann. Dabei sind die bekannten, vor dem ersten Gebrauch abzuziehenden und so als Originalitätsverschluss dienenden Folien bei Mehrkammertuben wegen der Gestaltung des Auslass kaum geeignet, da sie sich nicht zuverlässig dichtend aufbringen lassen.Due to the tendency to mix, the shelf life of these products is also severely limited. Thus, it has been found that with storage for several weeks, a diffusion of the components over the common exit area despite tightly screwed lid can not be prevented. The known, before the first use to be deducted and serving as tamper evident films in multi-chamber tubes because of the design of the outlet are hardly suitable because they can not reliably apply sealing.

Eine gattungsgemäße Tube ist aus der US 2003/0 106 905 bekannt.A generic tube is from the US 2003/0106905 known.

Die Aufgabe der vorliegenden Erfindung liegt zunächst darin, eine Mehrkammertube zu schaffen, die einfach und kostengünstig herstellbar ist und die als zuverlässiger und lagerfähiger Spender für zweiphasige Produkte geeignet ist. Dabei ist es zudem die Aufgabe der Erfindung eine solche Mehrkammertube zu schaffen, die ein beliebiges aber fest eingestelltes Mischungsverhältnis hat. Unabhängig davon ist es eine weitere Aufgabe der Erfindung, die Mehrkammertube so zu modifizieren, dass die Gefahr des Mischens der Komponenten im Austrittsbereich und die Diffusion von Kammer zu Kammer gemindert ist.The object of the present invention is first to provide a multi-chamber tube, which is simple and inexpensive to produce and which is suitable as a reliable and storable dispenser for two-phase products. It is also the object of the invention to provide such a multi-chamber tube, which has any but fixed mixing ratio. Regardless, it is a further object of the invention to modify the multi-chamber tube so that the risk of mixing the components in the outlet area and the diffusion is reduced from chamber to chamber.

Diese Aufgaben werden durch Mehrkammertuben mit den kennzeichnenden Merkmalen des Anspruch 1 gelöst. Besondere Ausführungsformen der Tube sind in den Unteransprüchen beschrieben.These objects are achieved by multi-chamber tubes with the characterizing features of claim 1. Particular embodiments of the tube are described in the subclaims.

Ein erster Grundgedanke liegt darin, die Volumina der einzelnen Kammern in einem Verhältnis vorzusehen, das sich von der bislang bekannten gleichmäßigen Aufteilung unterscheidet. Dabei soll die Erfindung jegliche ungleiche Verteilung der Volumina umfassen, die einen signifikanten Unterschied aufweist. Um eine dem Verhältnis der Kammervolumina entsprechende Mischung im ausgedrückten Strang gewährleisten zu können, wird der Austrittsbereich entsprechend gestaltet. So spiegelt sich das Verhältnis der Kammervolumina auch in den Querschnitten der Durchgangskanäle wieder, die im Auslass münden. Dabei kann ein Durchgangskanal in einen oder mehrere parallele Zweigkanäle aufgeteilt sein kann. Dann addierten sich die Querschnitte der Zweigkanäle zum Querschnitt des Durchgangskanals. Dabei ist anzumerken, dass es für die Funktion der Mehrkammertuben vorteilhaft ist, wenn die in den Kammern vorhandenen unterschiedlichen Komponenten jeweils etwa die gleiche Viskosität aufweisen.A first basic idea is to provide the volumes of the individual chambers in a ratio that differs from the previously known uniform distribution. The invention is intended to include any unequal distribution of volumes that has a significant difference. To ensure a mixture corresponding to the ratio of the chamber volumes in the expressed strand To be able to, the exit area is designed accordingly. Thus, the ratio of the chamber volumes is reflected in the cross sections of the through channels, which open in the outlet. In this case, a through-channel can be divided into one or more parallel branch channels. Then, the cross sections of the branch channels added to the cross section of the passageway. It should be noted that it is advantageous for the function of the multi-chamber tubes if the different components present in the chambers each have approximately the same viscosity.

Der Vorteil der erfindungsgemäßen Gestaltung liegt darin, dass sich die mit unterschiedlichen Volumina befüllten Kammern nun verhältnismäßig gleichmäßig bis zur Restentleerung ausdrücken lassen und das ausgedrückte Produkt dabei nahezu konstant dasselbe Mischungsverhältnis aufweist. Dabei lassen sich derartige Tuben mit den bekannten Verfahren relativ einfach fertigen und befüllen. Sie können damit als sicheres und komfortables Behältnis für ein sensibles mehrkomponentiges Produkt dienen.The advantage of the design according to the invention is that the chambers filled with different volumes can now be expressed relatively evenly until emptying of the residue and the product expressed has the same mixing ratio almost constant. In this case, such tubes can be relatively easily finished and filled with the known methods. It can serve as a safe and comfortable container for a sensitive multi-component product.

Ein besonders bevorzugtes Einsatzgebiet solcher Zweikammertuben ist der Bereich der Färbemittel und/oder Tönungsmittel für keratinische Fasern, insbesondere für menschliches Haar. Diese Mittel machen wegen ihrer chemischen Formulierungen von der Gleichverteilung abweichende Mischungsverhältnisse erforderlich. Gerade für diese Zweikomponentenmittel können die beiden Zubereitungen getrennt voneinander in einer erfindungsgemäßen Zweikammertube konfektioniert werden. An dieser Stelle werden die Anmeldungen DE 103 59 538.4 , DE 103 59 557.0 und DE 103 59 539.2 , die alle von der Anmelderin dieser Anmeldung stammen und alle den 17.12.2003 als Anmeldetag aufweisen, genannt. In diesen Dokumenten werden Befüllungen für Zweikammertuben beschrieben, wobei die für die eine Kammer vorgesehene Zubereitung mindestens einen direktziehenden Farbstoff und/oder mindestens eine Vorstufe eines naturanalogen Farbstoffs enthält, während die für die Befüllung der zweiten Kammer vorgesehene Zubereitung mindestens einen Pflegestoff enthält.A particularly preferred field of application of such two-chamber tubes is the range of colorants and / or tinting agents for keratinic fibers, in particular for human hair. Because of their chemical formulations, these agents require mixing ratios that differ from the uniform distribution. Especially for these two-component agent, the two preparations can be assembled separately from each other in a two-chamber tube according to the invention. At this point will be the registrations DE 103 59 538.4 . DE 103 59 557.0 and DE 103 59 539.2 , all of which originate from the applicant of this application and all have the filing date of 17.12.2003. These documents describe fillings for two-chambered tubes, the preparation intended for one chamber containing at least one substantive dye and / or at least one precursor of a naturally-analogous dye, while the preparation intended for filling the second chamber contains at least one care substance.

Für das Verhältnis der Volumina und damit des Austritts für die Zubereitungen ist ein Bereich zwischen 1 : 2 und 5 : 1, bevorzugt 2 : 1 bis 3 : 1, angegeben, wobei das Verhältnis 1 : 1 ausgeschlossen sein soll. Zudem wird als Befüllung für die eine Kammer eine Zubereitung mit mindestens einem Oxidationsfarbstoffvorprodukt und für die Befüllung der zweiten Kammer eine Zubereitung mit mindestens einem Oxidationsmittel oder einem Pflegestoff beschrieben, wobei das Verhältnis der Volumina und damit des Austritts für die Zubereitungen in einem Bereich zwischen größer 1 : 1 und 3 : 1 liegt.For the ratio of the volumes and thus the outlet for the preparations, a range between 1: 2 and 5: 1, preferably 2: 1 to 3: 1, indicated, wherein the 1: 1 ratio should be excluded. In addition, a preparation with at least one oxidation dye precursor and for the filling of the second chamber a preparation with at least one oxidizing agent or a care substance is described as filling for the one chamber, wherein the ratio of the volumes and thus the outlet for the preparations in a range between greater than 1 : 1 and 3: 1.

Zum Erhalt der rezepturbedingten Mischungsverhältnisse und zum gleichmäßigen Produktaustritt sind Geometrien der Tubenöffnungen vorteilhaft, die ein Mischungsverhältnis ungleich 50:50, nämlich von 80 : 20 bis 60 : 40, vorzugsweise von 75 : 25, aufweisen. Das Verhältnis von 75 : 25 von Außentube zu Innentube ist im Falle einer farbpigmentierten Phase und eines Pflegemittels bei einem Volumen von 100 ml vorteilhaft. Aus ästhetischen Gesichtspunkten kann die äußere Tube und/oder die innere Tube transparent gestaltet sein.To obtain the formulation-related mixing ratios and for even product discharge, geometries of the tube openings are advantageous, which have a mixing ratio not equal to 50:50, namely from 80:20 to 60:40, preferably from 75:25. The ratio of 75:25 from outside tube to inside tube is advantageous in the case of a color pigmented phase and a conditioner at a volume of 100 ml. From an aesthetic point of view, the outer tube and / or the inner tube can be made transparent.

Im Hinblick darauf, dass bei einem Tönungsmittel der Anteil der Farbzubereitung etwa 75% und der Anteil der Pflegezubereitung etwa 25% ausmachen kann und daher die Farbzubereitung im Falle einer "tube-in-tube" vorteilhafter Weise in die Außentube mit dem größeren Volumen eingebracht wird, ist es besonders vorteilhaft, wenn der Schulterbereich der Außentube mit Ronden verstärkt wird, die besonders gute Barriereeigenschaften aufweisen. Damit kann eine Diffusion des Farbstoffs aus dem Schulterbereich ausgeschlossen werden. Um die Diffusion möglichst effektiv zu verhindern ist es vorteilhaft, in das Material der Tubenschulter Aluminium oder einen geeigneten Kunststoff, wie PTB, einzuarbeiten.In view of the fact that for a tinting agent, the proportion of the color preparation about 75% and the proportion of care preparation can make up about 25% and therefore the color preparation in the case of a "tube-in-tube" is advantageously introduced into the outer tube with the larger volume , It is particularly advantageous if the shoulder region of the outer tube is reinforced with rounds, which have particularly good barrier properties. Thus, a diffusion of the dye can be excluded from the shoulder area. In order to prevent the diffusion as effectively as possible, it is advantageous to incorporate into the material of the tube shoulder aluminum or a suitable plastic, such as PTB.

Wie schon angesprochen, liegt ein generelles Problem der Mehrkammertuben darin, dass sich die Komponenten im Austrittsbereich mischen und dass Komponenten über den gemeinsamen Austrittsbereich ineinander diffundieren, so dass es in den Kammern zur Vermischung kommt. Um ein Austreten der Mischung während der Lagerung zu verhindern und dem gegenüber Verbraucher die Unversehrtheit der Tube zu gewährleisten, kann es bei einem Mündungsbereich mit relativ einfacher Geometrie, beispielsweise im Falle zweier koaxialer Zylinder, vorteilhaft sein, die Ausgabeöffnung mit einem Originalitätsverschluss, beispielsweise aus Aluminium- oder Kunststofffolie, zu versiegeln, der vom Verbraucher vor dem ersten Gebrauch entfernt wird. Ein solcher Originalitätsverschluss ist jedoch, wie gesagt, schwierig zu montieren und kann zudem nicht verhindern, dass sich die Komponenten nach dem ersten Gebrauch mischen. Insbesondere die hier angesprochenen Farbstoffe weisen eine verhältnismäßig hohe Kriech- oder Diffusionsfähigkeit auf.As already mentioned, a general problem of multi-chamber tubes is that the components mix in the exit area and that components diffuse into one another via the common exit area, so that mixing occurs in the chambers. In order to prevent leakage of the mixture during storage and to ensure the integrity of the tube to consumers, it may be advantageous at a mouth region with relatively simple geometry, for example in the case of two coaxial cylinders, the discharge opening with a tamper-evident closure, such as aluminum - or plastic film, to be sealed by the consumer before the first use Will get removed. However, such a tamper-evident closure is, as stated, difficult to assemble and also can not prevent the components from mixing after the first use. In particular, the dyes mentioned here have a relatively high creep or diffusibility.

Dabei ist das Problem des ungewollten Vermischens keinesfalls allein auf die Mehrkammertuben mit unterschiedlichen Kammervolumina beschränkt, sondern tritt bei allen Mehrkammertuben auf, auch bei denen mit gleichen Volumina. Insofern liegt ein weiterer genereller Gedanke der Erfindung darin, den Verschlußbereich der Mehrkammertuben so zu gestalten, dass die Gefahr der Vermischung drastisch reduziert wird. Dieses Problem wird dadurch behoben, dass der Mündungsrand des ersten Durchgangskanals gegenüber dem Mündungsrand des zweiten Durchgangskanals auf einem anderen Niveau liegt. Somit befindet sich einer der Mündungsränder in Bezug auf den austretenden Strang über oder hinter dem anderen und bildet eine Sperre für die Zusammensetzung, die in der Kammer mit dem tieferliegenden Mündungsrand ist. Schließlich kann die durch den erhöhten Mündungsrand geschaffene Stufe von der Zusammensetzung kaum überwunden werden. Sie wirkt damit gewissermaßen als "Diffusionsbremse".The problem of unwanted mixing is by no means limited to the multi-chamber tubes with different chamber volumes, but occurs in all multi-chamber tubes, even those with the same volume. In this respect, another general idea of the invention is to make the closure region of the multi-chamber tubes so that the risk of mixing is drastically reduced. This problem is solved by the fact that the mouth edge of the first passage channel opposite to the mouth edge of the second passage channel on a different level. Thus, one of the orifice edges is above or behind the other with respect to the exiting strand and forms a barrier to the composition that is in the lower-lying orifice-edge chamber. Finally, the level created by the raised mouth edge can hardly be overcome by the composition. It thus acts as a kind of "diffusion brake".

Dabei sei auch an dieser Stelle noch einmal ausdrücklich darauf hingewiesen, dass der Gedanke, die Mündungsränder der Durchgangskanäle auf verschiedenes Niveau zu legen, nicht auf Mehrkammertuben mit unterschiedlich großen Kammervolumina beschränkt ist, sondern eine für jegliche Mehrkammertube sinnvolle Erfindung ist. Selbstverständlich können die beiden beschriebenen und eigentlich unabhängigen Gegenstände der Mehrkammertube mit unterschiedlichen Kammervolumina und die Mehrkammertube mit Niveauunterschied der Mündungsränder in beliebiger Weise kombiniert werden.It should also be emphasized at this point once again that the idea of laying the mouth edges of the through-channels to different levels, not limited to multi-chamber tubes with different sized chamber volumes, but is a useful for any Mehrkammertube invention. Of course, the two described and actually independent objects of the multi-chamber tube with different chamber volumes and the multi-chamber tube with level difference of the mouth edges can be combined in any way.

Dies bringt vor allem den Vorteil, dass die Mischung der Komponenten stark gemindert werden kann. Dieser Vorteil zahlt sich zunächst bei der Lagerung der mehrkomponeritigen Produkte aus, wobei die verpackten Produkte sich durch eine hohe Lagerstabilität hinsichtlich der Mischung und/oder der Diffusion auszeichnen. So kann einmal den ästhetischen Ansprüchen der Verbraucher genügt werden, die im Falle unterschiedlich gefärbter Komponenten nunmehr beim ersten Gebrauch und auch noch nach dem ersten Gebrauch eine klare Trennung der Farben wahrnehmen können. Das unansehnliche Verschmieren der Komponenten im Bereich des Tubenkopfes bleibt ihnen weitgehend erspart. Zudem ist mitunter wegen der chemischen Reaktivität von Vorteil, die Vermischung zu vermeiden. Das gilt insbesondere, wenn die beiden Komponenten miteinander zu einem möglicherweise weniger stabilen, flüchtigen oder aggressiven Endprodukt reagieren.This has the particular advantage that the mixture of the components can be greatly reduced. This advantage initially pays off in the storage of the multicomponent products, the packaged products being characterized by a high storage stability in terms of mixing and / or diffusion. Thus, once the aesthetic requirements of consumers can be met, which in the case of differently colored components now at the first use and even after the first use can perceive a clear separation of colors. The unsightly smearing of the components in the region of the tube head remains largely spared them. In addition, sometimes because of the chemical reactivity of advantage, to avoid the mixing. This is particularly true when the two components react together to form a possibly less stable, volatile or aggressive end product.

Dabei konnte die erhöhte Lagerbeständigkeit in Versuchen bestätigt werden. So hat sich erwiesen, dass Farbstoffe nicht wie angenommen durch die Wandung der Innentube diffundieren und dann zu der Verteilung am inneren Tubenrand führen, sondern dass die Diffusion über den gemeinsamen Austrittsbereich stattfindet. Diese Diffusion wird durch die stufig angeordneten Mündungsränder stark reduziert.The increased storage stability could be confirmed in experiments. Thus, it has been found that dyes do not diffuse as assumed through the wall of the inner tube and then lead to the distribution at the inner tube edge, but that the diffusion takes place via the common outlet region. This diffusion is greatly reduced by the staggered muzzle edges.

Dabei gibt es verschiedene konstruktive Möglichkeiten, die stufigen Mündungsränder im Tubenkopf zu realisieren. Eine besonders einfache und damit vorteilhafte Art der Realisierung ist es, die getrennten Kammern als getrennte Tuben mit jeweils einem eigenen Durchgangskanal auszubilden. Ausgehend von der Tubenschulter werden die Durchgangskanäle dabei in unterschiedlicher Länge konzipiert. Wenn die Tuben dann im Tubenhals zusammengefasst werden, indem sie nebeneinander in eine gemeinsame Halterung gesteckt werden, wie es von "side-by-side" Tuben bekannt ist, oder einfach wie bei "tube-in-tube"-Tuben ineinander gesteckt werden, dann ergibt sich wegen der unterschiedlichen Länge der Durchgangskanäle ein Niveauunterschied der Mündungsränder. Dabei ist es vorteilhaft, wenn im Falle der "tube-in-tube" Anordnung der Durchgangskanal der inneren Tube koaxial zum Durchgangskanal der äußeren Tube angeordnet ist und etwas weiter vorragt. So ist die Diffusion in Richtung von der äußeren zu der inneren Tube nahezu unterbunden. Ein Vorteil der Erfindung liegt im Fall der "tube-in-tube"-Tuben darin, dass es auf die Toleranzen, die beim Ineinanderstecken der Tuben zwangsläufig auftreten, nicht mehr ankommt. Vorteilhafterweise wird bei der Konzeption des Niveauunterschiedes darauf geachtet, dass dieser größer als die größt mögliche Toleranz ist.There are various design options to realize the stepped mouth edges in the tube head. A particularly simple and thus advantageous type of implementation is to form the separate chambers as separate tubes, each with its own passage. Starting from the tube shoulder, the through-channels are designed in different lengths. When the tubes are then collected in the tube neck by placing them side by side in a common holder, as is known from "side-by-side" tubes, or simply plugged into each other as in "tube-in-tube" tubes, then results in a difference in level of the mouth edges because of the different length of the through channels. It is advantageous if, in the case of the "tube-in-tube" arrangement, the through-channel of the inner tube is arranged coaxially with the through-channel of the outer tube and protrudes somewhat further. Thus, the diffusion in the direction from the outer to the inner tube is almost suppressed. An advantage of the invention in the case of the "tube-in-tube" tubes is that it no longer matters to the tolerances that inevitably occur when the tubes are inserted one inside the other. Advantageously, care is taken in the design of the level difference that this is greater than the maximum possible tolerance.

Prinzipiell ist jede Art der Verteilung der Kammern innerhalb der gemeinsamen Tube möglich. Bei der "side-by-side" Tube werden die beiden einzelnen Kammern nebeneinander in einer äußeren Hülle angeordnet, während die o.g. "tube in tube" eine innere Tube aufweist, die von einer äußeren Tube vollständig umgeben ist. Diese Ausführungsform zeichnet sich durch eine gleichbleibende Dosierung der beiden Zubereitungen aus.In principle, any kind of distribution of the chambers within the common tube is possible. In the "side-by-side" tube, the two individual chambers are arranged side by side in an outer shell, while the o.g. "tube in tube" has an inner tube which is completely surrounded by an outer tube. This embodiment is characterized by a constant dosage of the two preparations.

Besonders vorteilhaft ist es natürlich, wenn die Zusammensetzung, deren Diffusion vermieden werden soll, beispielsweise die mit intensiven Farbpigmenten versetzte Komponente, in der Kammer vorgesehen ist, deren Mündungsrand auf niedrigerem Niveau liegt.Of course, it is particularly advantageous if the composition whose diffusion is to be avoided, for example the component mixed with intense color pigments, is provided in the chamber whose mouth edge is at a lower level.

Wenn im Rahmen dieser Erfindung von einem Niveauunterschied geredet wird, so ist dieser größer als die beim Fertigungsverfahren üblichen Toleranzen, die durchaus eine Größe von einem zehntel Millimeter ausmachen können. Niveauunterschiede im Sinne der Erfindung haben eine Größe von mindestens 0,3 Millimeter, bevorzugt von mehr als 0,5 Millimeter und besonders bevorzugt von mehr als 1,0 Millimeter. Damit kann trotz der Fertigungstoleranzen ein die Diffusion hemmender Niveauunterschied sichergestellt werden. Im vorliegenden Fall kann sich ein Niveauunterschied von etwa 1,5 Millimeter ausbilden. Niveauunterschiede von mehr als etwa 3 Millimeter erweisen sich speziell bei den hier vorliegenden Mehrfachtuben als unpraktikabel.If in the context of this invention is spoken by a level difference, this is greater than the usual in the manufacturing process tolerances, which can make up a size of one tenth of a millimeter. Differences in level according to the invention have a size of at least 0.3 millimeters, preferably more than 0.5 millimeters and more preferably more than 1.0 millimeters. Thus, despite the manufacturing tolerances, a diffusion-inhibiting level difference can be ensured. In the present case, a level difference of about 1.5 millimeters can form. Level differences of more than about 3 millimeters prove to be impractical especially in the present multiple tubes.

Die erfindungsgemäße Zweikammertube ist vorzugsweise aus einem Material gefertigt, dass zur Verpackung von Tönungs- und Färbemitteln dieser Art geeignet ist. Dabei ist zu beachten, dass aufgrund der Oxidationseigenschaften des Produktes die Barriereeigenschaften handelsüblicher Kunststofftuben nur begrenzt ausreichen. Als Material bietet sich für die direktziehenden Farbstoffe oder deren Vorstufen, sowie für Oxidationsmittel und Oxidationsfarbstoffvorprodukte, ein Aluminiumlaminat oder reines Aluminium an, wobei reine Aluminiumtuben wegen ihrer mechanischen Eigenschaften nur bedingt einsetzbar sind. Unter Aluminiumlaminat wird hier eine mit mehrlagigem Kunststoff beschichtete Aluminiumschicht verstanden. Als erfindungsgemäß ganz besonders bevorzugt hat sich eine Tube erwiesen, bei der sowohl die Innentube als auch die Außentube aus Aluminiumlaminat gefertigt ist. Für die weniger aggressiven Zubereitungen sind auch Tuben aus Kunststofflaminat (PE, PET, PP) oder Kunststoffcoextrudaten (PE, PET, PP) mit Barriereschichten, wie beispielsweise EVOH denkbar. Darüber hinaus kann in einer Ausführungsform das Material der Innentube unabhängig von dem Material der Außentube gewählt werden. Wie schon erwähnt, kann es aus Gründen eines ansprechenden Designs vorteilhaft sein, die Außentube aber auch die Innentube aus transparentem Kunststoff zu fertigen.The two-chamber tube according to the invention is preferably made of a material that is suitable for the packaging of tinting and coloring agents of this type. It should be noted that due to the oxidation properties of the product, the barrier properties of commercially available plastic tubes are only limited sufficient. As a material is suitable for the direct dyes or their precursors, as well as for oxidizing agents and oxidation dye precursors, an aluminum laminate or pure aluminum, with pure aluminum tubes are only partially used because of their mechanical properties. Aluminum laminate is understood here as an aluminum layer coated with multilayer plastic. As very particularly preferred according to the invention, a tube has proven in which both the inner tube and the outer tube are made of aluminum laminate. For the less aggressive preparations, tubes made of plastic laminate (PE, PET, PP) or Kunststoffxextrudaten (PE, PET, PP) with barrier layers, such as EVOH conceivable. Moreover, in one embodiment, the material of the inner tube can be selected independently of the material of the outer tube. As already mentioned, it may be advantageous for reasons of an attractive design to manufacture the outer tube but also the inner tube made of transparent plastic.

Bei der erfindungsgemäß gestalteten Mehrkammertube kommt eine besondere Bedeutung dem Verschluss zu. Dieser wird als Schraubkappe ausgebildet, deren innere Hülse, wie von solchen Schraubkappen bekannten, den Auslass abdichtet. Im vorliegenden Fall ist es vorteilhaft, wenn am Boden der inneren Hülse eine Dichtung anliegt, die eine Stärke von mehreren, beispielsweise 3 Millimetern hat und die im wesentlichen aus einem Schaumstoff besteht. Dieser wird gegen den Auslass mit aufgeklebtem Papier und darauf einer Aluminiumfolie bedeckt. Diese Dichtung ist geeignet, dass sich die Mündungsränder in das Material eindrücken, so dass die Durchgangskanäle dicht verschlossen sind. Um den Anpressdruck zu begrenzen ist es vorteilhaft, wenn das Drehmoment, mit dem die Kappe aufgeschraubt wird, begrenzt ist. Dazu wird am Innendurchmesser der Hülse ein Rand vorgesehen, der oberhalb des Innengewindes vorsteht. Dieser Rand legt sich beim Aufschrauben der Kappe auf einen Absatz auf, der den Auslass stirnseitig umgibt.In the case of the multi-chamber tube designed according to the invention, a special significance attaches to the closure. This is designed as a screw cap, the inner sleeve, as known from such screw caps, the outlet seals. In the present case, it is advantageous if at the bottom of the inner sleeve, a seal is applied, which has a thickness of several, for example 3 millimeters and which consists essentially of a foam. This is covered against the outlet with glued paper and then an aluminum foil. This seal is suitable for the mouth edges to press into the material so that the through channels are sealed. In order to limit the contact pressure, it is advantageous if the torque with which the cap is screwed on is limited. For this purpose, an edge is provided on the inner diameter of the sleeve, which protrudes above the internal thread. When the cap is screwed on, this edge rests on a shoulder which surrounds the outlet at the front.

Obwohl die Erfindung prinzipiell hinsichtlich dieses Austrittsmusters in keiner Weise beschränkt sein soll, kann es erfindungsgemäß bevorzugt sein, wenn die erste Zubereitung als Hauptstrang austritt und die zweite Zubereitung mehrere an diesem Hauptstrang entlanglaufende farbige Streifen bildet. Auch hinsichtlich der Zahl dieser Streifen soll die Erfindung nicht eingeschränkt sein. Eine Zahl von zwei bis vier Streifen kann erfindungsgemäß aus applikationstechnischen oder optischen Gründen besonders bevorzugt sein. Mit den Streifen kann das Produkt ästhetisch aufgewertet werden. Dabei kann in einer ersten Ausgestaltungsform die erste Zubereitung die Streifen bilden, während die zweite Zubereitung den Hauptstrang bildet und in einer zweiten Ausgestaltungsform die zweite Zubereitung die Streifen bilden, während die erste Zubereitung den Hauptstrang bildet. Vorteilhafterweise ist jedoch darauf zu achten, dass die farbige Zubereitung in der Kammer aufbewahrt ist, deren Mündungsrand auf dem niedrigeren Niveau liegt.Although the invention should in principle not be restricted in any way with regard to this exit pattern, it may be preferred according to the invention if the first preparation exits as the main strand and the second preparation forms a plurality of colored strips running along this main strand. Also with regard to the number of strips, the invention should not be limited. A number of two to four stripes may be particularly preferred according to the invention for application or optical reasons. With the strips, the product can be aesthetically enhanced. In this case, in a first embodiment, the first preparation form the strips, while the second preparation forms the main strand and in a second embodiment the second preparation form the strips, while the first preparation forms the main strand. Advantageously, however, it is too Make sure that the colored preparation is stored in the chamber with the mouth edge at the lower level.

In einer weiteren Ausgestaltungsform, kann es bevorzugt sein, wenn die beiden Zubereitungen insbesondere anteilig gemeinsam nebeneinander den Hauptstrang bilden. In einer weiteren Ausgestaltungsform kann der Austrittsstrang aus einem inneren Bereich, gebildet aus einer ersten Zubereitung, und einem äußeren Bereich, gebildet aus der zweiten Zubereitung, bestehen, wobei die Zubereitungen entsprechend ihrer Anordnung in der Tube auch den Austrittsstrang bilden.In a further embodiment, it may be preferred for the two preparations to form, in particular proportionally, the main strand together next to one another. In a further embodiment, the outlet strand can consist of an inner region, formed from a first preparation, and an outer region, formed from the second preparation, wherein the preparations also form the outlet strand according to their arrangement in the tube.

Die Erfindung wird nachfolgend anhand der beiliegenden Figuren 1 bis 8 näher erklärt. Es zeigen:

Figur 1
einen Schnitt durch eine Zweikammertube,
Figur 2
verschiedene Querschnittsgeometrien des Auslass,
Figur 3
eine Draufsicht auf den Kopf einer Zweikammertube,
Figur 4
einen Schnitt durch den Kopf einer Zweikammertube,
Figur 5
einen Ansicht des Kopfes einer Zweikammertube,
Figur 6
Tubenköpfe mit variierenden Mischungsverhältnissen,
Figur 7
eine offene Zweikammertube mit Niveauunterschied der Mündungsränder und
Figur 8
eine erfindungsgemäße geschlossene Zweikammertube mit Niveauunterschied der Mündungsränder.
The invention is described below with reference to the accompanying FIGS. 1 to 8 explained in more detail. Show it:
FIG. 1
a section through a two-chamber tube,
FIG. 2
different cross-sectional geometries of the outlet,
FIG. 3
a top view of the head of a two-chamber tube,
FIG. 4
a section through the head of a bicameral tube,
FIG. 5
a view of the head of a bicameral tube,
FIG. 6
Tube heads with varying mixing ratios,
FIG. 7
an open two - chamber tube with level difference of the muzzle edges and
FIG. 8
a closed two-chamber tube according to the invention with level difference of the mouth edges.

Figur 1 zeigt einen Schnitt durch den oberen Bereich einer Zweikammertube. Diese ist in der Art "tube-in-tube" ausgebildet und geeignet für zwei reaktive Zubereitungen, die in voneinander getrennten Kammern in einer gemeinsamen Tube aufbewahrt werden. Das Mischen, respektive das Zusammenströmen, der beiden Zubereitungen geschieht erst bei der Anwendung. Die Zweikammertube weist ein äußeres Tubenrohr 1 mit einer daran angeformten Tubenschulter 2 und einem äußeren Durchgangskanal 3 auf. Das äußere Tubenrohr 1 bildet als Außentube eine erste Kammer 21 für eine Zubereitung A aus. Diese erste äußere Kammer 21 umgibt koaxial eine rohrförmige Innentube 4, die eine weitere Kammer 22 für eine Zubereitung B bildet, wobei die Innentube 4 ihrerseits eine innere Tubenschulter 5 mit einem entsprechenden inneren Durchgangskanal 6 aufweist. Die Innentube 4 ist in das äußere Tubenrohr 1 eingesteckt und über nicht dargestellte Rastnasen im äußeren Durchgangskanal 3 gehalten. Stege 7 bilden einen Anschlag beim Einstecken und gewährleisten den Abstand der Tubenschultern 2 und 5, so dass ein Durchgang zum Durchgangskanal 3 verbleibt. Die Durchgangskanäle 3 und 6 münden in einem gemeinsamen Auslass. FIG. 1 shows a section through the upper part of a two-chamber tube. This is designed in the manner of "tube-in-tube" and suitable for two reactive preparations, which are stored in separate chambers in a common tube. The mixing, respectively the confluence, of the two preparations happens only at the application. The two-chamber tube has an outer tube tube 1 with a tube shoulder 2 formed thereon and an outer through-channel 3. The outer tube tube 1 forms as outer tube a first chamber 21 for a preparation A. This first outer chamber 21 coaxially surrounds a tubular Innentube 4, which forms a further chamber 22 for a preparation B, wherein the Innentube 4 in turn has an inner tube shoulder 5 with a corresponding inner passageway 6. The Innentube 4 is inserted into the outer tube tube 1 and held on not shown locking lugs in the outer passage 3. Webs 7 form a stop when inserting and ensure the distance of the tube shoulders 2 and 5, so that a passage to the passage channel 3 remains. The passageways 3 and 6 open into a common outlet.

Im Durchgangskanal 3 bildet der darin angeordnete innere Durchgangskanal 6 ein Trennmittel, das bei einem Druck auf die Tube eine zunächst getrennte Förderung der Zubereitungen A und B ermöglicht. Nach der getrennten Förderung vereinigen sich die Zubereitungen im Bereich des Auslasses vor der Ausgabeöffnung und verlassen diese in einem gemeinsamen Strang. In diesem Fall sind Außentube und Innentube von Schläuchen gebildet, die an ihrem hinteren Ende vermittels eines gemeinsamen Falzes verschlossen sind.In the passage 3 of the inner passageway 6 arranged therein forms a release agent, which allows a first separate promotion of the preparations A and B at a pressure on the tube. After the separate promotion, the preparations unite in the area of the outlet before the discharge opening and leave them in a common strand. In this case, outer tube and inner tube are formed by tubes, which are closed at their rear end by means of a common fold.

Schon in der Figur 1 ist zu erkennen, dass die Außenwandung 6a des inneren Durchgangskanals 6 sternförmig ausgebildet ist. Verschiedene Geometrien für die Wandungen des inneren Durchgangskanals 6 sind in Figur 2a bis 2i gezeigt. Bei den Ausführungsformen nach 2a, 2c, 2d, 2h und 2i definiert die Querschnittsfläche 9 des Sternes, der drei oder vier Spitzen haben kann, die Größe des Teilstroms für die in der Innentube befindliche Zubereitung B (schraffiert). Hingegen definieren die zwischen der Außenwandung 8 des inneren Durchgangskanals und der runden Außenwandung 10 des äußeren Durchgangskanals verbleibenden Zwickel 11 die Zweigströme für die in der Außentube befindliche Zubereitung. Die Größe des Teilstroms für die zweite Zubereitung A wird durch die Summe der Zweigströme festgelegt.Already in the FIG. 1 It can be seen that the outer wall 6a of the inner passage channel 6 is formed star-shaped. Different geometries for the walls of the inner through-channel 6 are in FIGS. 2a to 2i shown. In the embodiments according to FIGS. 2a, 2c, 2d, 2h and 2i, the cross-sectional area 9 of the star, which may have three or four points, defines the size of the partial flow for the preparation B located in the inner tube (hatched). On the other hand, the gussets 11 remaining between the outer wall 8 of the inner through-channel and the round outer wall 10 of the outer through-channel define the branch streams for the preparation located in the outer tube. The size of the partial stream for the second preparation A is determined by the sum of the branch streams.

Die beiden Kammern 21 und 22 haben unterschiedliche Volumina, die in einem vorgegebenen Verhältnis zueinander stehen. Erfindungsgemäß erzeugen die Durchgangskanäle zwei Teilströme mit zumindest nahezu demselben Verhältnis, wobei einer der Teilströme, wie beispielsweise nach 2 a oder 2c in mehrere parallele Zweigströme aufgeteilt sein kann. Um eine aus allen Betrachtungswinkeln sichtbare Streifigkeit des ausgetretenen Produktstromes zu erzeugen, ist die Ausführungsform nach 2c besonders zu bevorzugen. Mit den gezeigten Geometrien 2a bis 2i lassen sich Mündungsvarianten herstellen, die Mischungsverhältnisse von mindestens 60 : 40 und bevorzugt 75 :25 bilden. Der maximal erreichbare Unterschied liegt bei etwa 80 : 20.The two chambers 21 and 22 have different volumes, which are in a predetermined relationship to each other. According to the invention, the through channels produce two partial streams with at least almost the same ratio, wherein one of the partial streams, such as, for example, according to 2 a or 2 c can be divided into a plurality of parallel branch streams. In order to produce a visible stripiness of the leaked product stream from all viewing angles, the embodiment according to FIG. 2c is particularly preferable. With the geometries 2a to 2i shown, orifice variants can be produced which form mixing ratios of at least 60:40 and preferably 75:25. The maximum achievable difference is around 80:20.

Figur 3 zeigt eine Draufsicht auf den Kopf einer Zweikammertube, wobei deutlich die Querschnittsgeometrie im Austrittsbereich vor der Ausgabeöffnung zu erkennen ist. Diese entspricht etwa dem Beispiel nach 2c. Gezeigt ist eine Ronde aus Kunststoff, die eine Tubenschulter 16 ausbildet, an der der Hals 17 angeformt ist. Auf den Rand 18 ist das insbesondere aus Aluminiumlaminat gefertigte äußere Tubenrohr verschweißt. Figur 4 zeigt einen Schnitt durch die Ronde nach Figur 3. Zu erkennen sind der Tubenkopf 12 der Innentube, der in den Tubenkopf 13 der Außentube fest eingesteckt ist. In diesem Beispiel liegt der Mündungsrand 19 der Außentube auf dem Niveau des Mündungsrandes 20 der Innentube. Die Durchgangskanäle 3 und 6 sind deutlich zu erkennen. Der Schulterbereich 16 der Außentube ist in diesem Fall durch eine eingearbeitete Kunststoffschicht verstärkt, die besonders gute Barriereeigenschaften gegen die Diffusion von Farbstoffen aufweist. Figur 5 zeigt einen Blick von unten durch die Ronde nach Figur 3 und Figur 4. Zu erkennen sind die Stege 7, die von Innen gegen die Schulter 16 anliegen. FIG. 3 shows a plan view of the head of a two-chamber tube, wherein clearly the cross-sectional geometry can be seen in the exit region in front of the discharge opening. This corresponds approximately to the example according to 2c. Shown is a Ronde made of plastic, which forms a tube shoulder 16, on which the neck 17 is formed. On the edge 18, in particular made of aluminum laminate outer tube tube is welded. FIG. 4 shows a section through the Ronde after FIG. 3 , To recognize the tube head 12 of the inner tube, which is firmly inserted into the tube head 13 of the outer tube. In this example, the mouth edge 19 of the outer tube is at the level of the mouth edge 20 of the inner tube. The passageways 3 and 6 are clearly visible. The shoulder region 16 of the outer tube is reinforced in this case by an incorporated plastic layer, which has particularly good barrier properties against the diffusion of dyes. FIG. 5 shows a view from below through the Ronde FIG. 3 and FIG. 4 , Evident are the webs 7, which bear against the shoulder 16 from the inside.

In Figur 6 wird gezeigt, wie sich durch Modifikation der Außenwandung 8 des inneren Durchgangskanals einerseits das Mischungsverhältnis und andererseits die Breite der Streifen und damit der optische Eindruck einstellen lässt. In den Figuren 6a bis 6c ist jeweils eine Außenwandung 8 in Sternform gezeigt, wobei der Stern jeweils drei Spitzen aufweist. Die Breite der Spitzen 14 definiert dabei die Breite der Streifen im ausgedrückten Strang. Aus der Geometrie des Tubenkopfes nach 6a resultiert ein Mischungsverhältnis von 60 : 40 der aus drei Teilen bestehenden Querschnittsfläche 11 des äußeren Durchgangskanals zu der Querschnittsfläche 9 des inneren Durchgangskanals. Der Tubenkopf nach 6b weist ein Mischungsverhältnis von etwa 75 : 25 bei verhältnismäßig schmalen Streifen auf. Der Kopf nach 6c zeigt tiefere Wölbungen der Wände 8, wodurch bei kleinerem Mischungsverhältnis von etwa 73 : 27 dennoch breitere Streifen erzeugt werden. Die beiden zuletzt genannten Verhältnisse bieten sich an für Zweikammertuben, die als Spender für ein Tönungsmittel mit etwa 75% Farbanteil und 25% Pflegeanteil dienen. Durch Modifikation der Wände sind selbstverständlich beliebige Mischungsverhältnisse und beliebige Streifendesigns darstellbar.In FIG. 6 It is shown how can be adjusted by modification of the outer wall 8 of the inner passage channel on the one hand, the mixing ratio and on the other hand, the width of the strip and thus the visual impression. In the FIGS. 6a to 6c in each case an outer wall 8 is shown in star shape, wherein the star has three peaks each. The width of the tips 14 defines the width of the strips in the expressed strand. From the geometry of the tube head according to FIG. 6 a, a mixing ratio of 60:40 results in the three-part cross-sectional area 11 of the outer passageway to the cross-sectional area 9 of the inner passageway. The tube head according to FIG. 6b has a mixing ratio of about 75:25 with relatively narrow strips. The head of Fig. 6c shows deeper curves of the walls 8, whereby wider stripes are nevertheless produced at a smaller mixing ratio of about 73:27. The latter two conditions are suitable for two-chamber tubes, which serve as a donor for a tinting agent with about 75% color content and 25% care content. By modification of the walls of course any mixing ratios and any strip designs can be displayed.

Die Ausführungsform nach Figur 6d zeigt einen Tubenkopf, der einen zylindrischen Innenstrang 15 innerhalb des ebenfalls zylindrischen Außenstrangs 25 realisiert. Das Mischungsverhältnis lässt sich über den Durchmesser des Innenstrangs beliebig einstellen. Diese Ausführungsform ist besonders geeignet, falls der Außenstrang 23 von einer transparenten Zubereitung gebildet wird, während die den Innenstrang formende Zubereitung farbig ist.The embodiment according to FIG. 6d shows a tube head, which realizes a cylindrical inner strand 15 within the likewise cylindrical outer strand 25. The mixing ratio can be set arbitrarily over the diameter of the inner strand. This embodiment is particularly suitable if the outer strand 23 is formed by a transparent preparation, while the inner strand forming preparation is colored.

In Figur 7 ist nunmehr ein Schnitt durch eine offene Zweikammertube mit einem Niveauunterschied der Mündungsränder gezeigt. Es handelt sich um eine "tube-in-tube", wie oben schon beschrieben. Der erste Durchgangskanal 24 der Tube hat einen Mündungsrand 26 und der zweite Durchgangskanal 27 einen Mündungsrand 28. Zu erkennen ist, dass das Niveau des Mündungsrandes 26 in Bezug auf die Tubenschulter 30 deutlich unterhalb des Niveau des Mündungsrandes 28 liegt. Der Niveauunterschied ist mit 29 bezeichnet. Die in dieser Figur dargestellte Doppeltube ist besonders geeignet zur Ausnahme von farbigen Tönungsmitteln. Dabei ist die mit Farbpigmenten versetzte Komponente in der von der Außentube gebildeten Kammer 31 aufbewahrt. Der Niveauunterschied 29 reicht aus, um die Diffusion der Farbpigmente vom Durchgangskanal 24 über den Austrittsbereich in den Durchgangskanal 27 zu verhindern.In FIG. 7 now is a section through an open two-chamber tube with a difference in level of the mouth edges shown. It is a "tube-in-tube", as described above. The first passage 24 of the tube has a mouth edge 26 and the second passage 27 a mouth edge 28. It can be seen that the level of the mouth edge 26 with respect to the tube shoulder 30 is well below the level of the mouth edge 28. The level difference is designated 29. The double tube shown in this figure is particularly suitable for the exception of colored tinting agents. In this case, the component mixed with color pigments is stored in the chamber 31 formed by the outer tube. The level difference 29 is sufficient to prevent the diffusion of the color pigments from the passage 24 through the exit area into the passageway 27.

Die Innentube bildet die Kammer 32 und enthält einen Pflegestoff. Der Tubenkopf der Außentube wird wiederum von einem Kopfstück 33 gebildet, an der der Schlauch 34 der Außentube angebracht ist. Der Schulterbereich ist mit einem Inlay 35 verstärkt. Die Innentube hat ihrerseits ein Kopfstück 36, das die Geometrie der Durchgangskanäle formt. An das Kopfstück 36 ist der Schlauch 37 der Innentube angeformt. Die Schläuche 34 und 37 sind am nicht dargestellten Ende zusammen versiegelt und damit verschlossen. Das Kopfstück 36 ist in den Durchgangskanal 24 eingesteckt und über Rastnasen 38, die in eine Nut 39 eingreifen verrastet. Stege 40 gewährleisten wiederum den Abstand. Schon an dieser Stelle sei auf den Absatz 41 hingewiesen, der am oberen Ende des Halses vorgesehen ist und auf den sich ein in der Schraubkappe befindlicher Rand beim Aufschrauben der Kappe auflegt.The inner tube forms the chamber 32 and contains a care substance. The tube head of the outer tube is in turn formed by a head piece 33 to which the tube 34 of the outer tube is attached. The shoulder area is reinforced with an inlay 35. The Innentube in turn has a head piece 36, the geometry of the Through channels forms. At the head piece 36, the tube 37 of the inner tube is formed. The hoses 34 and 37 are sealed together at the end, not shown, and thus closed. The head piece 36 is inserted into the through-channel 24 and latched via locking lugs 38 which engage in a groove 39. Webs 40 in turn ensure the distance. Already at this point, attention is drawn to the paragraph 41, which is provided at the upper end of the neck and on which an in the screw cap located edge hangs when screwing the cap.

Figur 8 zeigt nunmehr die erfindungsgemäße Mehrkammertube in Form einer "tube-in-tube" nach Figur 7 jedoch mit aufgeschraubter Schraubkappe 42. Das Aufschrauben der Schraubkappe 42 wird durch ein Gewinde der bekannten Art ermöglicht. Im Inneren der doppelwandigen Schraubkappe 42 ist eine innere Hülse 43 vorgesehen, die den Auslass abdichtet. Am Boden der Hülse liegt eine Dichtung 44 an, die eine Stärke von mehreren Millimetern hat und die im wesentlichen aus einem Schaumstoff besteht, der gegen den Auslass mit aufgelebtem Papier und darauf einer Aluminiumfolie bedeckt ist. Zu erkennen ist, dass sich der Mündungsrand 28 in die Dichtung 44 eindrückt, während die Dichtung 44 auf dem Mündungsrand 26 anliegt. So sind die Durchgangskanäle dicht verschlossen. Am Innendurchmesser der Hülse 43 ist ein Rand 45 vorgesehen, der oberhalb des Innengewindes vorsteht. Dieser Rand 45 legt sich beim Aufschrauben der Kappe auf den Absatz 41 (Figur 7) auf, der den Auslass stirnseitig umgibt. So ist eine Begrenzung des Drehmomentes gegeben. Zudem ist gewährleistet, dass die Schürze 46 der Schraubkappe 42 nicht auf die Tubenschulter gedrückt wird. FIG. 8 now shows the multi-chamber tube according to the invention in the form of a "tube-in-tube" FIG. 7 but with screwed-on screw cap 42. The screwing of the screw cap 42 is made possible by a thread of the known type. Inside the double-walled screw cap 42, an inner sleeve 43 is provided, which seals the outlet. At the bottom of the sleeve is a gasket 44 having a thickness of several millimeters and consisting essentially of a foam which is covered against the outlet with live paper and thereon an aluminum foil. It can be seen that the mouth edge 28 presses into the seal 44, while the seal 44 rests on the mouth edge 26. So the passageways are tightly closed. At the inner diameter of the sleeve 43, an edge 45 is provided, which protrudes above the internal thread. This edge 45 settles when screwing the cap on the shoulder 41 ( FIG. 7 ), which surrounds the outlet end face. So a limitation of the torque is given. In addition, it is ensured that the skirt 46 of the screw cap 42 is not pressed onto the tube shoulder.

Claims (14)

  1. A multi-chamber tube, in particular a dual chamber tube, having an outer tube conduit (1) with a tube neck (17) resting on a tube shoulder (2, 16, 30), which opens into an outlet, wherein a first chamber (21, 31) may be filled with a first preparation (A) and a further chamber (22, 32) may be filled with a second preparation (B), wherein a first passage channel (3, 24) provided for the passage of the first preparation and a second passage channel (6, 27) provided for the passage of the second preparation are arranged in the tube neck (17), wherein the passage channels in the outlet each have a mouth encompassed by a mouth edge (19, 20, 26, 28), where the first preparation and the second preparation converge together into a common strand, with a level difference (29) between the mouth edge (19, 26) of the first passage channel (3, 24) and the mouth edge (20, 28) of the second passage channel (6, 27) with respect to the tube shoulders (2, 16, 30), wherein at least the portion of the mouth edge, which lies between the first and second passage channel, protrudes over the remaining mouth edge, characterized by a screwed plug (42) in which a seal (44) is incorporated wherein the mouth edge (28) is embedded with a higher level into the material of the seal (44) by about the level difference (29), while the seal (44) sealably lies on the mouth edge (26) with a lower level.
  2. The multi-chamber tube according to claim 1, characterized in that the level difference (29) amounts to at least 0.3 millimeter and preferably to more than 0.5 millimeter and more preferably to more than 1.0 millimeter.
  3. The multi-chamber tube according to claim 1 or 2, characterized by an inner tube (4), which is plugged into the passage channel (24) of an outer tube, wherein the passage channel (27) of the inner tube (4) protrudes by the level difference (29) over the mouth edge of the passage channel (24) of the outer tube.
  4. The multi-chamber tube according to any of claims 1 to 3, characterized in that the composition, the diffusion of which should be avoided, in particular the component mixed with intense color pigments, is provided in the chamber (21, 31), the mouth edge (19, 26) of which lies at a lower level.
  5. The multi-chamber tube according to any of claims 1 to 4, characterized in that the volumes of the chambers (21, 22, 31, 32) are different and are in a determined ratio relatively to each other, wherein the cross-sections of the passage channels (3, 6, 24, 27) have an at least almost corresponding ratio, wherein a passage channel (3, 6, 24, 27) may be divided into one or several parallel branch channels.
  6. The multi-chamber tube according to claim 1, characterized in that a stop (41) is provided, which limits the torque upon screwing on the screwed plug (42).
  7. The multi-chamber tube according to any of the preceding claims, characterized in that the outer tube conduit (1) forms an outer tube, which surrounds coaxially a pipe-shaped inner tube (4), wherein the inner tube (4) has an inner passage channel (6), wherein the inner passage channel (6) is plugged into the passage channel (3) and wherein the outer wall (8) of the inner passage channel (6) forms a separator.
  8. The multi-chamber tube according to any of the preceding claims, characterized in that the outer wall (8) of the inner passage channel (6) is formed with the shape of a star, wherein the cross-sectional surface of the star defines the partial current for the preparation located in the inner tube (4) and wherein the remaining crotches (11) between the outer wall (8) of the inner passage channel (6) and the round outer wall (10) of the outer passage channel (3) define branch currents for the preparation located in the outer tube (1).
  9. The multi-chamber tube according to any of the preceding claims, characterized in that the outer tube and inner tube (4) are formed from pipes (1, 4, 34, 37), which are secured at the rear end by means of a common fold.
  10. The multi-chamber tube according to any of the preceding claims, characterized in that the outer tube and/or the inner tube (4) is made out of an aluminium foil coated with plastic, in particular an aluminium laminate or out of plastic laminates.
  11. The multi-chamber tube according to any of the preceding claims, characterized in that the outer tube and/or the inner tube (4) are made out of transparent plastic.
  12. The use of a multi-chamber tube according to any of the preceding claims, in such a way that the preparation (A) provided for filling said one chamber contains at least one substantive dye and/or at least one precursor of nature-analogue dye and the preparation (B) provided for filling the second chamber contains at least one care material.
  13. The use of a multi-chamber tube according to any of the preceding claims 1 to 11, so that the preparation (A) provided for filling said one chamber contains at least one oxidation dye precursor and the preparation (B) provided for filling the second chamber contains at least one oxidation agent.
  14. The use of a multi-chamber tube according to any of the preceding claims 1 to 11, so that the preparation (A) provided for filling said one chamber contains at least one oxidation dye precursor and the preparation (B) provided for filling the second chamber contains at least one care material.
EP05707592A 2004-02-24 2005-02-23 Dual or multi-chamber tube Expired - Lifetime EP1718541B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004009424A DE102004009424A1 (en) 2004-02-24 2004-02-24 Two or more chamber tube
PCT/EP2005/001878 WO2005080215A1 (en) 2004-02-24 2005-02-23 Dual or multi-chamber tube

Publications (2)

Publication Number Publication Date
EP1718541A1 EP1718541A1 (en) 2006-11-08
EP1718541B1 true EP1718541B1 (en) 2009-09-02

Family

ID=34833064

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05707592A Expired - Lifetime EP1718541B1 (en) 2004-02-24 2005-02-23 Dual or multi-chamber tube

Country Status (9)

Country Link
US (1) US20070095702A1 (en)
EP (1) EP1718541B1 (en)
CN (1) CN1922078A (en)
AT (1) ATE441596T1 (en)
AU (1) AU2005215913A1 (en)
CA (1) CA2579912A1 (en)
DE (2) DE102004009424A1 (en)
ES (1) ES2330536T3 (en)
WO (1) WO2005080215A1 (en)

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WO2023023927A1 (en) * 2021-08-24 2023-03-02 The Procter & Gamble Company Package for dispensing dual-phase cosmetic composition

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DE102006061863A1 (en) * 2006-12-21 2008-06-26 Henkel Kgaa Hair conditioning agents with selected cationic polymers and water-soluble silicones
DE102007001008A1 (en) 2007-01-02 2008-07-03 Henkel Kgaa Cosmetic composition useful for protecting hair from oxidative damage comprises an ayurvedic plant extract
DE102007001028A1 (en) 2007-01-02 2008-07-03 Henkel Kgaa Cosmetic preparation, e.g. for care and conditioning of hair after permanent waving or dyeing, contains a synergistic combination of argan oil and shea butter
DE102007001027A1 (en) 2007-01-02 2008-07-03 Henkel Kgaa Cosmetic preparation, e.g. for care and conditioning of hair after permanent waving or dyeing, contains a combination of palmitic, palmitoleic, stearic, oleic and linoleic acids
DE102007001019A1 (en) 2007-01-02 2008-07-03 Henkel Kgaa Cosmetic compositions useful for care and conditioning of keratinic fibers, especially hair, comprise a mineral powder and a cationic, amphoteric or zwitterionic polymer
US8906187B2 (en) * 2008-06-25 2014-12-09 Colgate-Palmolive Company Method of making shoulder/nozzles with film barrier liners
US8622260B2 (en) * 2009-04-13 2014-01-07 The Procter & Gamble Company Multi-phase oral composition dispenser with adjustable flow
CN102502093B (en) * 2011-10-14 2014-01-22 友德塑胶(深圳)有限公司 Cover-lifting double flexible pipes
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CN109689517B (en) * 2016-07-07 2020-07-14 奈特包装有限责任公司 Multi-lumen tube containers and caps
EP3677345A1 (en) * 2019-01-03 2020-07-08 Sulzer Mixpac AG Coaxial cartridge for multi-component materials and method of assembling a coaxial cartridge
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JP2022544693A (en) 2019-08-30 2022-10-20 ザ プロクター アンド ギャンブル カンパニー Packaged hair care composition
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US20230070292A1 (en) * 2021-08-24 2023-03-09 The Procter & Gamble Company Package for dispensing dual-phase cosmetic composition

Also Published As

Publication number Publication date
DE502005008044D1 (en) 2009-10-15
EP1718541A1 (en) 2006-11-08
AU2005215913A1 (en) 2005-09-01
WO2005080215A1 (en) 2005-09-01
ES2330536T3 (en) 2009-12-11
US20070095702A1 (en) 2007-05-03
CN1922078A (en) 2007-02-28
ATE441596T1 (en) 2009-09-15
CA2579912A1 (en) 2005-09-01
DE102004009424A1 (en) 2005-09-08

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