EP1649074A1 - Revetement de protection contre l'usure et piece comportant un revetement de protection contre l'usure - Google Patents
Revetement de protection contre l'usure et piece comportant un revetement de protection contre l'usureInfo
- Publication number
- EP1649074A1 EP1649074A1 EP04802981A EP04802981A EP1649074A1 EP 1649074 A1 EP1649074 A1 EP 1649074A1 EP 04802981 A EP04802981 A EP 04802981A EP 04802981 A EP04802981 A EP 04802981A EP 1649074 A1 EP1649074 A1 EP 1649074A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- component
- protection coating
- multilayer system
- wear protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 14
- 230000003628 erosive effect Effects 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000000956 alloy Substances 0.000 claims abstract description 10
- 239000007769 metal material Substances 0.000 claims abstract description 7
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims description 59
- 239000011248 coating agent Substances 0.000 claims description 56
- 239000000463 material Substances 0.000 claims description 43
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 239000010936 titanium Substances 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001120 nichrome Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910000838 Al alloy Inorganic materials 0.000 claims 1
- 229910000531 Co alloy Inorganic materials 0.000 claims 1
- 229910000640 Fe alloy Inorganic materials 0.000 claims 1
- 229910000990 Ni alloy Inorganic materials 0.000 claims 1
- 229910001069 Ti alloy Inorganic materials 0.000 claims 1
- 238000005259 measurement Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 66
- 239000000758 substrate Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 2
- 229910018487 Ni—Cr Inorganic materials 0.000 description 2
- 229910033181 TiB2 Inorganic materials 0.000 description 2
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 2
- 229910010169 TiCr Inorganic materials 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- CXOWYMLTGOFURZ-UHFFFAOYSA-N azanylidynechromium Chemical compound [Cr]#N CXOWYMLTGOFURZ-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/347—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with layers adapted for cutting tools or wear applications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/36—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including layers graded in composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/40—Coatings including alternating layers following a pattern, a periodic or defined repetition
- C23C28/42—Coatings including alternating layers following a pattern, a periodic or defined repetition characterized by the composition of the alternating layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/286—Particular treatment of blades, e.g. to increase durability or resistance against corrosion or erosion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/30—Manufacture with deposition of material
- F05D2230/31—Layer deposition
- F05D2230/313—Layer deposition by physical vapour deposition
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/90—Coating; Surface treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/611—Coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12542—More than one such component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12576—Boride, carbide or nitride component
Definitions
- the invention relates to a wear protection coating, in particular an erosion protection coating, preferably for gas turbine components, according to the preamble of patent claim 1. Furthermore, the invention relates to a component with such a wear protection coating according to the preamble of patent claim 13.
- Fluid mechanically loaded components such as gas turbine components
- Erosion is a process of wear and tear that is caused by solid substances moving in the gas flow.
- wear protection coatings are required which protect the components against wear, in particular against erosion, corrosion and oxidation.
- EP 0 674 020 B1 discloses a multi-layer, erosion-resistant coating for the surfaces of substrates.
- the erosion-resistant coating disclosed there provides a wear protection coating which consists of a plurality of multilayer systems applied in repetition to the substrate to be coated.
- the multilayer systems applied in repetition are each formed from two different layers, namely on the one hand from a layer of a metallic material and on the other hand from a layer of titanium diboride. Since, in the case of the erosion protection coating according to EP 0 674 020 B1, the multilayer systems applied repeatedly are formed from only two layers, layers of metallic material and layers of titanium diboride are alternately arranged in the erosion protection coating disclosed there.
- EP 0 366 289 A1 discloses a further erosion-resistant and corrosion-resistant coating for a substrate.
- the wear protection coating is formed from a plurality of multilayer systems applied in repetition to the substrate to be coated, each multilayer system again consists of two different layers, namely a metallic layer, for example made of titanium, and a ceramic layer, for example made of titanium nitride.
- EP 0 562 108 B1 Another erosion-resistant and abrasion-resistant wear protection coating is known from EP 0 562 108 B1.
- the wear protection coating disclosed there is in turn formed from a plurality of multilayer systems which are applied repeatedly on a substrate to be coated.
- 4 of EP 0 562 108 B1 discloses a wear protection coating formed from a plurality of multilayer systems applied in repetition, each multilayer system consisting of four layers, namely a ductile layer made of tungsten or a tungsten alloy and three hard layers, the three being distinguish hard layers with regard to an additional element content.
- the present invention is based on the problem of creating a novel wear protection coating and a component with such a wear protection coating.
- each of the multilayer systems applied in repetition has at least four different layers.
- a first layer of each multilayer system facing the surface to be coated is formed from a metal material adapted to the composition of the component surface to be coated.
- a second layer of each multilayer system applied to the first layer is formed from a metal alloy material adapted to the composition of the component surface to be coated.
- a third layer of each multilayer system applied to the second layer is made of a graded metal-ceramic material and a fourth layer of each multilayer system applied to the third layer is made of a nanostructured ceramic material.
- the wear protection coating according to the invention ensures very good erosion resistance and oxidation resistance and has an extremely low influence on the vibration resistance of the coated component. It is particularly suitable for coating complex components, such as guide vanes, rotor blades, guide vane segments, rotor blade segments and integrally bladed rotors.
- a number of such multilayer systems are applied repeatedly to the surface of the component stressed by fluid mechanics, an adhesion-promoting layer preferably being applied between the surface of the component and the first multilayer system adjoining the surface.
- Figure 1 is a highly schematic representation of a blade of a gas turbine having an anti-wear coating according to the invention.
- FIG. 2 shows a highly schematic cross section through an anti-wear coating according to the invention according to a first exemplary embodiment of the invention
- FIG. 3 shows a highly schematic cross section through a wear protection coating according to the invention according to a second exemplary embodiment of the invention.
- Fig. 4 shows a highly schematic cross section through an anti-wear coating according to the invention according to a third embodiment of the invention.
- FIG. 1 shows a blade of a gas turbine in perspective View bearing a wear protection coating according to the invention.
- 2 to 4 show schematic cross sections through the blade, each with different wear protection coatings according to the invention.
- FIG. 1 shows a blade 10 of a gas turbine with an airfoil 11 and a blade root 12.
- the entire blade 10 namely a surface thereof to be protected, is coated with a wear protection coating 13.
- the entire blade 10 is coated with the wear protection coating 13
- the blade 10 it is also possible for the blade 10 to have the wear protection coating 13 only in sections, that is to say only in the region of the blade leaf 11 or in parts thereof or in the region of the blade root 12 .
- Other gas turbine components such as, for example, housings or integrally bladed rotors such as blisks (B
- the component to be coated is identified by reference number 10.
- the wear protection coating 13 according to the invention is applied to a surface 14 of the component 10 to be coated.
- the wear protection coating 13 consists of two multilayer systems 15 and 16 applied repeatedly on the surface 14.
- Each of the two multilayer systems 15 and 16 consists of four different layers, a first layer 17 facing the surface 14 to be coated each Multi-layer system 15 and 16 is formed from a metal material adapted to the composition of the component 10 to be coated.
- a second layer 18 of each multilayer system 15 and 16 applied to the first layer 17 is formed from a metal alloy material adapted to the composition of the component 10 to be coated.
- a third layer 19 of each multilayer system 15 and 16 applied to the second layer 18 is made of a graded metal-ceramic material and a fourth layer 20 of each multilayer system 15 and 16 applied to the third layer 19 is formed from a ceramic material.
- the graded metal-ceramic material within the layer 19 forms a transition between the second layer 18 and the fourth layer 20, namely from the metal alloy of the second layer 18 to the ceramic material of the fourth layer 20.
- a further multilayer system 21 is applied to the multilayer systems 15 and 16 described above, which corresponds to the multilayer systems 15 and 16 with regard to the design of the individual layers 17 to 20.
- Four, five or a greater number of such multilayer systems 15, 16 or 21 can also be arranged one above the other in repetition in order to form a wear protection coating 13 according to the invention.
- the multilayer systems can also be composed or formed from more than four layers.
- an adhesion-promoting layer 22 is applied between the surface 14 of the component 10 to be coated and the first multilayer system 15 adjoining the surface 14.
- the adhesive layer 22 enables better contact between the wear protection coating 13 according to the invention and the component 10 to be coated.
- the first layer 17 is preferably designed as a nickel layer (Ni layer).
- a second layer 18 (NiCr layer) formed from a nickel-chromium material is then applied to such a Ni layer 17.
- the second layer 18 made of the nickel-chromium material is then joined as a third layer 19 by a graded metal-ceramic layer, which is preferably formed from a CrN ⁇ -x material (CrN] -x layer).
- the fourth layer 20 is formed from a ceramic material, namely chromium nitride (CrN layer).
- the component 10 to be coated is formed from a titanium base material.
- the first layer 17 is preferably formed from titanium, palladium or platinum.
- the third layer 19 is in turn followed by a grading layer, which either consists of a CrAIN ⁇ . x material or a TiAIN ⁇ -x material is formed.
- a CrAIN layer follows as the fourth layer 20 as the ceramic layer.
- the fourth layer 20 is preferably formed from titanium aluminum nitride (TiAIN).
- TiAIN titanium aluminum nitride
- a TiAISiN material or AlTiN material or TiN / AIN material can also be used as the ceramic material for the fourth layer 20 in this case.
- the wear protection coating 13 according to the invention is applied to the component 11 to be coated in the sense of the present invention by means of a PVD coating process.
- the layer thickness of a multilayer system of the wear protection coating according to the invention is preferably less than 15 ⁇ m.
- the wear protection coating according to the invention is preferably used in complex, three-dimensional, fluid mechanically stressed components, such as, for example, housing elements, guide vane segments, rotor blade segments, integrally bladed rotors or also individual blades for aircraft engines.
- the anti-wear coating according to the invention on the one hand the entire component to be coated and on the other hand only a region thereof can be coated.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Laminated Bodies (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004001392A DE102004001392A1 (de) | 2004-01-09 | 2004-01-09 | Verschleißschutzbeschichtung und Bauteil mit einer Verschleißschutzbeschichtung |
| PCT/DE2004/002800 WO2005066384A1 (fr) | 2004-01-09 | 2004-12-22 | Revetement de protection contre l'usure et piece comportant un revetement de protection contre l'usure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1649074A1 true EP1649074A1 (fr) | 2006-04-26 |
| EP1649074B1 EP1649074B1 (fr) | 2010-02-10 |
Family
ID=34716391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04802981A Expired - Lifetime EP1649074B1 (fr) | 2004-01-09 | 2004-12-22 | Revetement de protection contre l'usure et piece comportant un revetement de protection contre l'usure |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7927709B2 (fr) |
| EP (1) | EP1649074B1 (fr) |
| CA (1) | CA2537205A1 (fr) |
| DE (2) | DE102004001392A1 (fr) |
| RU (1) | RU2374075C2 (fr) |
| WO (1) | WO2005066384A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102017219639A1 (de) * | 2017-11-06 | 2019-05-09 | Siemens Aktiengesellschaft | Schichtsystem mit harten und weichen Schichten und Schaufel |
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| DE102004050474A1 (de) * | 2004-10-16 | 2006-04-20 | Mtu Aero Engines Gmbh | Verfahren zur Herstellung eines mit einer Verschleißschutzbeschichtung beschichteten Bauteils |
| DE102005030266A1 (de) * | 2005-06-29 | 2007-01-18 | Mtu Aero Engines Gmbh | Schaufel einer Turbomaschine mit einer Schaufelspitzenpanzerung |
| DE102005049249B4 (de) * | 2005-10-14 | 2018-03-29 | MTU Aero Engines AG | Verfahren zur Entschichtung eines Gasturbinenbauteils |
| DE102006001864A1 (de) * | 2006-01-13 | 2007-07-19 | Mtu Aero Engines Gmbh | Verschleißschutzbeschichtung |
| US8893405B2 (en) * | 2006-05-25 | 2014-11-25 | Nike, Inc. | Article of footwear incorporating tensile strands with an elongated cross-sectional shape |
| DE102006051813A1 (de) | 2006-11-03 | 2008-05-08 | Mtu Aero Engines Gmbh | Schaufel für einen Verdichter oder eine Turbine eines Flugtriebwerks, Flugtriebwerk mit einer solchen Schaufel sowie Verfahren zum Beschichten einer Schaufel eines Flugtriebwerks |
| DE102007005755A1 (de) * | 2007-02-06 | 2008-08-07 | Mtu Aero Engines Gmbh | Vorrichtung zum Schutz von Bauteilen mit brennbarer Titanlegierung vor Titanfeuer und Verfahren zu deren Herstellung |
| DE102007022832A1 (de) * | 2007-05-15 | 2008-11-20 | Mtu Aero Engines Gmbh | Verfahren zur Entschichtung eines Bauteils |
| DE102007027335A1 (de) | 2007-06-14 | 2008-12-18 | Mtu Aero Engines Gmbh | Verschleißschutzbeschichtung und Bauteil mit einer Verschleißschutzbeschichtung |
| DE102008019891A1 (de) * | 2008-04-21 | 2009-10-22 | Mtu Aero Engines Gmbh | Erosionsschutzbeschichtung |
| DE102008023591A1 (de) | 2008-05-14 | 2009-11-19 | Mtu Aero Engines Gmbh | Schutzschicht und Verfahren zum Aufbringen einer Schutzschicht |
| DE102008023590A1 (de) * | 2008-05-14 | 2009-11-19 | Mtu Aero Engines Gmbh | Schutzschicht und Verfahren zum Herstellen einer Schutzschicht |
| DE102009010110B4 (de) | 2009-02-21 | 2014-08-28 | MTU Aero Engines AG | Erosionsschutz-Beschichtungssystem für Gasturbinenbauteile |
| DE102009013129A1 (de) | 2009-03-13 | 2010-09-16 | Mtu Aero Engines Gmbh | Kunststoffbauteil mit Erosionsschutzschicht für Anwendungen mit erosiver Beanspruchung |
| US20100304107A1 (en) * | 2009-05-27 | 2010-12-02 | United Technologies Corporation | Layered coating for erosion protection |
| BR112012016892A2 (pt) * | 2010-01-14 | 2018-03-27 | Saab Ab | lâmina de turbina eólica tendo uma superfície externa com propriedades aperfeiçoadas. |
| DE102010060152A1 (de) | 2010-10-25 | 2012-04-26 | Max-Planck-Institut für Plasmaphysik | Verschleißschutzbeschichtung |
| TWI477619B (zh) * | 2010-12-29 | 2015-03-21 | Hon Hai Prec Ind Co Ltd | 硬質薄膜、具備該硬質薄膜之產品、該產品之製作方法 |
| RU2449053C1 (ru) * | 2011-04-05 | 2012-04-27 | Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) | Способ нанесения износостойкого покрытия на титановые сплавы |
| US9291062B2 (en) | 2012-09-07 | 2016-03-22 | General Electric Company | Methods of forming blades and method for rendering a blade resistant to erosion |
| EP3199821B1 (fr) * | 2014-12-25 | 2023-08-30 | IHI Corporation | Pale de compresseur pour moteur |
| US9834835B2 (en) | 2015-02-18 | 2017-12-05 | United Technologies Corporation | Fire containment coating system for titanium |
| JP2016196820A (ja) * | 2015-04-02 | 2016-11-24 | 株式会社Ihi | エンジン用圧縮機翼 |
| US10017844B2 (en) | 2015-12-18 | 2018-07-10 | General Electric Company | Coated articles and method for making |
| EP3246430B1 (fr) | 2016-05-20 | 2021-12-08 | MTU Aero Engines AG | Procédé de fabrication d'aubes ou de système d'aubes d'une turbomachine comprenant des couches de protection contre l'érosion et composant ainsi fabriqué |
| DE102016222296A1 (de) * | 2016-11-14 | 2018-05-17 | Siemens Aktiengesellschaft | Mehrlagige aluminiumhaltige Schutzbeschichtung und Bauteil |
| JP6735299B2 (ja) * | 2018-03-09 | 2020-08-05 | 三菱重工業株式会社 | 複合材翼、前縁金属カバー形成ユニット、複合材翼の製造方法 |
| DE102019210880A1 (de) * | 2019-07-23 | 2021-01-28 | MTU Aero Engines AG | Laufschaufel für eine strömungsmaschine |
| DE102020206202A1 (de) | 2020-05-18 | 2021-11-18 | MTU Aero Engines AG | Schaufel für eine Strömungsmaschine mit Schaufelspitzenpanzerung und Erosionsschutzschicht und Verfahren zur Herstellung Derselben |
| RU2749171C1 (ru) * | 2020-08-28 | 2021-06-07 | Федеральное государственное унитарное предприятие "Центральный аэрогидродинамический институт имени профессора Н.Е. Жуковского" (ФГУП "ЦАГИ") | Теплозащитное покрытие летательного аппарата |
| US20230184117A1 (en) * | 2021-12-14 | 2023-06-15 | General Electric Company | Airfoil vibration damping apparatus |
| EP4245963B1 (fr) * | 2022-03-16 | 2025-09-10 | Rolls-Royce Deutschland Ltd & Co KG | Moteur à turbine à gaz et procédé de fabrication d'une aube de rotor |
| CN115094382B (zh) * | 2022-07-07 | 2023-08-15 | 佛山科学技术学院 | 一种用于金属或合金表面的复合薄膜、其制备方法及应用 |
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| SU49238A1 (ru) * | 1935-03-07 | 1936-08-31 | А.А. Абиндер | Способ термического наращивани из газовой фары на поверхность металлических изделий твердых сплавов |
| US4481237A (en) * | 1981-12-14 | 1984-11-06 | United Technologies Corporation | Method of applying ceramic coatings on a metallic substrate |
| US4761346A (en) * | 1984-11-19 | 1988-08-02 | Avco Corporation | Erosion-resistant coating system |
| US4904542A (en) * | 1988-10-11 | 1990-02-27 | Midwest Research Technologies, Inc. | Multi-layer wear resistant coatings |
| DE68925937T2 (de) * | 1988-10-12 | 1996-10-02 | Detector Electronics | Erkennung und Verarbeitung von Wellenformen |
| DE69216218T2 (de) | 1991-10-14 | 1997-06-19 | Commissariat Energie Atomique | Erosionsbeständiges und abrasionsbeständiges Mehrschichtenmaterial |
| US5384367A (en) * | 1993-04-19 | 1995-01-24 | Ppg Industries, Inc. | Carbamate urea or urethane-functional epoxy acrylic with polyacid |
| GB9405744D0 (en) * | 1994-03-23 | 1994-05-11 | Rolls Royce Plc | A multilayer erosion resistant coating and a method for its production |
| EP1029101B1 (fr) * | 1997-11-03 | 2001-09-12 | Siemens Aktiengesellschaft | Produit, en particulier composant d'une turbine a gaz, a couche thermo-isolante en ceramique, et procede pour obtenir ladit produit |
| CA2327031C (fr) * | 1999-11-29 | 2007-07-03 | Vladimir Gorokhovsky | Revetements composites deposes par evaporation sous vide et procede afferent |
| JP3996809B2 (ja) | 2002-07-11 | 2007-10-24 | 住友電工ハードメタル株式会社 | 被覆切削工具 |
| US6858333B2 (en) * | 2002-10-09 | 2005-02-22 | Kennametal Inc. | Tool with wear resistant low friction coating and method of making the same |
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2004
- 2004-01-09 DE DE102004001392A patent/DE102004001392A1/de not_active Withdrawn
- 2004-12-22 WO PCT/DE2004/002800 patent/WO2005066384A1/fr not_active Ceased
- 2004-12-22 RU RU2006115794/02A patent/RU2374075C2/ru not_active IP Right Cessation
- 2004-12-22 CA CA002537205A patent/CA2537205A1/fr not_active Abandoned
- 2004-12-22 US US10/568,697 patent/US7927709B2/en not_active Expired - Fee Related
- 2004-12-22 EP EP04802981A patent/EP1649074B1/fr not_active Expired - Lifetime
- 2004-12-22 DE DE502004010743T patent/DE502004010743D1/de not_active Expired - Lifetime
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102017219639A1 (de) * | 2017-11-06 | 2019-05-09 | Siemens Aktiengesellschaft | Schichtsystem mit harten und weichen Schichten und Schaufel |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2537205A1 (fr) | 2005-07-21 |
| US20070190351A1 (en) | 2007-08-16 |
| EP1649074B1 (fr) | 2010-02-10 |
| US7927709B2 (en) | 2011-04-19 |
| RU2374075C2 (ru) | 2009-11-27 |
| WO2005066384A8 (fr) | 2006-04-20 |
| DE502004010743D1 (de) | 2010-03-25 |
| DE102004001392A1 (de) | 2005-08-04 |
| RU2006115794A (ru) | 2008-05-20 |
| WO2005066384A1 (fr) | 2005-07-21 |
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