[go: up one dir, main page]

EP1390001A2 - Produits de soins capillaires contenant des huiles naturelles - Google Patents

Produits de soins capillaires contenant des huiles naturelles

Info

Publication number
EP1390001A2
EP1390001A2 EP02730268A EP02730268A EP1390001A2 EP 1390001 A2 EP1390001 A2 EP 1390001A2 EP 02730268 A EP02730268 A EP 02730268A EP 02730268 A EP02730268 A EP 02730268A EP 1390001 A2 EP1390001 A2 EP 1390001A2
Authority
EP
European Patent Office
Prior art keywords
acid
hair
natural oils
weight
tocopherols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02730268A
Other languages
German (de)
English (en)
Inventor
Wolf Eisfeld
Peter Busch
Ulrich Issberner
Petra Biehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis IP Management GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP1390001A2 publication Critical patent/EP1390001A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63—Steroids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/671—Vitamin A; Derivatives thereof, e.g. ester of vitamin A acid, ester of retinol, retinol, retinal
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/678—Tocopherol, i.e. vitamin E
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/006—Antidandruff preparations

Definitions

  • the invention is in the field of cosmetic products and relates to hair care products which contain natural oils with tocopherols and sterols and / or carotenoids and which are used to strengthen the hair and to protect against UV light.
  • sterols as hair growth-strengthening agents are described in US Pat. No. 6,156,296. They are used in combination with alpha-hydroxycarboxylic acids in hair care products.
  • European patent application EP 0 943 313 A2 describes the use of sunflower wax in hair care products in order to counteract damaging environmental influences.
  • the invention relates to hair care products containing natural oils
  • Another object of the invention is the use of natural oils with tocopherols and sterols and / or carotenoids for the production of hair care products.
  • tocopherols, sterols and carotenoids for preventing hair breakage and split ends is much higher if they are used in natural oils in hair care products.
  • the presence of the oils has a nourishing and protective effect against environmental influences and mechanical stress, especially on damaged and dry hair, and on the other hand increases the availability of the active ingredients against damaging UV light influences.
  • the combination of tocopherol with sterols or carotenoids shows an improved effectiveness against hair breakage and split ends.
  • the effectiveness against damaging UV light effects can be further increased.
  • such preparations also prophylactically lead to reduced damage to the hair structure and thus contribute to maintaining the hair structure.
  • Natural oils with tocopherol and sterols and / or carotenoids Natural oils with tocopherol and sterols and / or carotenoids
  • the preparations according to the invention contain 0.1 to 20% by weight, preferably 1 to 10% by weight and particularly preferably 2 to 5% by weight, of the natural oils.
  • Natural oils are to be understood as oils that are of animal or preferably vegetable origin. These are esters of linear C ⁇ -C ⁇ fatty acids with linear C6-C22 fatty alcohols, Esters of branched C ⁇ -Ci3 carboxylic acids with linear C ⁇ -C ⁇ fatty alcohols, such as myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl stearate, cetyl palmitate, cetyl palmitate, cetyl palmitate, cetyl palmitate, cetyl palmitate, cetyl palmitate, cetyl palate Stearylmyristat, stearyl palmitate, stearyl stearate, Stearylisostearat, stearyl oleate, stearyl behenate, Stearylerucat, iso
  • Triglycerides based on Ce-Cio fatty acids and liquid mono- / di- / triglyceride mixtures based on C6-Ci8 fatty acids are also suitable.
  • the tocopherols, sterols and / or carotenoids can be added to these oils, but they are preferably already present in the oil in the native state.
  • Particularly preferred are the commercial products from “ AarhüsOliefäbrik S / S Aärhus Denmark, " known under the name Cremeol® now Cegesoft® (Cognis, Düsseldorf). These include:
  • Cegesoft® previously Cremeol® PS 6, vegetable oil, C18: 1 84%, C18: 2 5%, unsaponifiable matter (mainly phytosterols, e.g.-ß-sitosterol, campesterol) -1.1%, tocopherols 1,400 ppm Cegesoft ® (previously Cremeol®) PS 17, Vegetable oil, C18: 1 72%, C18: 2 11%, unsaponifiable matter (mainly phytosterols, e.g.
  • ß-sitosterol, campesterol 1.5%
  • Passionflower Passiflora Incarnata oil
  • C18: 1 16% C18: 270%
  • unsaponifiable matter phytosterols, e.g. ß-sitosterol, campesterol
  • Cegesoft® previously Cremeol® SBE, Shea butter (Butyrospermum Parkii) extract, C18: 1 63.4%, C18: 2 1.8%, unsaponifiable matter: 30-40%, of which triterpene alcohols 85%, sterols 8%; Tocopherols 1,400 ppm
  • phytosterols are used as sterols.
  • examples include sitosterol, campesterol, brassicasterol, lupenol, stigmasterol, ⁇ -spinasterol and avennasterol, ß-sitosterol, stigmasterol and campesterol are particularly preferred.
  • Tocopherols are understood to mean chroman-6-oles (3,4-dihydro-2H-benzopyran-6-ole) substituted in the 2-position with a 4,8,12, -trimethyltridecyl radical.
  • the plastoquinones, tocopherolquinones, ubiquinones, bovichinones, K vitamins and menaquinones (2-methyl-1, 4-naphthoquinones) belong to the same group of bioquinones, ie to the polyprenylated 1,4-benzo and naphthoquinones.
  • ⁇ -, ⁇ -, ⁇ - and ⁇ -tocopherols come into question.
  • tocopherols their derivatives, in particular esters with carboxylic acids, such as tocopherol acetate or palmitate, are also suitable.
  • Carotenoids are plant substances that give vegetables or fruits the yellow, orange or red color. Chemically speaking, these are 11- to 12-fold unsaturated tetraterpenes with a skeleton with 9 conjugated double bonds, 8 methyl branches (including the possible ring structures) and a ß-ionone ring structure at one end of the molecule while they are in the structure at the other end of the molecule.
  • Typical carotenoids are, for example, ⁇ -carotene or provitamin A, ⁇ -carotene, lutein, cryptoxanthin, zeaxanthin and lycopene. Solubilizates of carotenoids and tocopherols for oral intake are also known from German Offenlegungsschrift DE 19609477 A1. The carotenoids can be used individually or in mixtures.
  • esters is generally understood to mean quaternized fatty acid triethanolamine ester salts. These are known substances which can be obtained by the relevant methods of preparative organic chemistry. In this connection, reference is made to the international patent application WO 91/01295 ( Henkel), according to which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through and then quaternized with dimethyl sulfate or ethylene oxide.
  • R 1 CO represents an acyl radical with 6 to 22 carbon atoms
  • R 2 and R 3 independently of one another for hydrogen or R 1 CO
  • R 4 represents an alkyl radical with 1 to 4 carbon atoms or a (CH2CH2 ⁇ ) q H group
  • m, n and p in total stand for 0 or numbers from 1 to 12
  • q stands for numbers from 1 to 12
  • X stands for halide, alkyl sulfate or alkyl phosphate.
  • ester quats that can be used in the context of the invention are products based on caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, isostearic acid, stearic acid, oleic acid, elaidic acid, arachic acid, behenic acid and erucic acid and their technical mixtures , as they occur, for example, in the pressure splitting of natural fats and oils.
  • Technical C12 / 18- Coconut fatty acids and in particular partially hardened Ci ⁇ / i ⁇ tallow or palm fatty acids as well as elaidic acid-rich Ci6 / 18 fatty acid cuts are used.
  • the fatty acids and the triethanolamine can be used in a molar ratio of 1.1: 1 to 3: 1 to produce the quaternized esters.
  • an application ratio of 1.2: 1 to 2.2: 1, preferably 1.5: 1 to 1.9: 1 has proven to be particularly advantageous.
  • the preferred ester quats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9 and are derived from technical C16 / 18-tallow or palm fatty acid (iodine number 0 to 40) .
  • quaternized fatty acid triethanol amine ester salts of the formula (I) have proven to be particularly advantageous, R 1 GO for an acyl radical having 16 to 18 carbon atoms, R 2 for R 1 CO, R 3 for hydrogen, R 4 represents a methyl group, m, n and p represents 0 and X represents methyl sulfate.
  • quaternized ester salts of fatty acids with diethanolalkylamines of the formula (II) are also suitable as esterquats,
  • R 1 CO for an acyl radical with 6 to 22 carbon atoms
  • R 2 for hydrogen or R 1 CO
  • R 3 and R 4 independently of one another for alkyl radicals with 1 to 4 carbon atoms
  • m and n in total for 0 or numbers from 1 to 12
  • X represents halide, alkyl sulfate or alkyl phosphate.
  • R 1 CO stands for an acyl radical with 6 to 22 carbon atoms
  • R 2 for hydrogen or RICO
  • R 3 , R 4 and R 5 independently of one another for alkyl radicals with 1 to 4 carbon atoms
  • X represents halide, alkyl sulfate or alkyl phosphate.
  • the esterquats usually come on the market in the form of 50 to 90% strength by weight alcoholic solutions, which can be diluted with water if required.
  • Esterquats can be present in the hair care products in amounts of 0 to 10% by weight, preferably 1 to 5% by weight and particularly preferably 1.5 to 3% by weight.
  • Formulations which remain on the hair or the scalp for a long time or which frequently contain aggressive chemicals are particularly suitable for developing the effectiveness against hair breakage, split ends and UV light influences. These include hair treatments, hair packs, hair lotions, hair gels, hair colors, bleaching agents, permanent waving agents, sun and after-sun products for hair. • • The agents are particularly suitable for long-term use with a prophylactic effect. In addition to preventing hair breakage and split ends, the preparations can also be used for intensive care of the scalp, to increase hair shine, improve the feel and to fade the natural hair color and synthetic hair colors.
  • the hair care agents containing natural oils with tocopherols and sterols are in a composition of:
  • the natural oils preferably contain
  • tocopherols 0.03 to 3% by weight of tocopherols and 0.5 to 8% by weight of sterols and particularly preferred
  • tocopherols 0.05 to 2% by weight of tocopherols and 1 to 5% by weight of sterols.
  • the hair care agents containing natural oils with tocopherols and carotenoids are in a composition of:
  • tocopherols 0.01 to 5% by weight of tocopherols and 0.001 to 2% by weight of carotenoids based on the amount of
  • oils Oils, before.
  • the natural oils preferably contain
  • tocopherols 0.03 to 3% by weight of tocopherols and 0.005 to 1% by weight of carotenoids are particularly preferred
  • the hair care agents containing natural oils with tocopherols and sterols and carotenoids are in a composition of:
  • the natural oils preferably contain
  • the hair care products according to the invention can contain, as additional auxiliaries and additives, surfactants, co-emulsifiers, superfatting agents, pearlescent waxes, consistency agents, polymers, silicone compounds, waxes, stabilizers, antidandruff agents, film formers, swelling agents, hydrotropes, preservatives, solubilizers, complexing agents, reducing agents, alkalizing agents, antioxidants Contain perfume oils and the like,
  • anionic and / or amphoteric or zwitterionic surfactants are soaps, alkylbenzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerin ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxymeamide sulfate, hydroxymether sulfates ether) sulfates, mono- and dialkylsulfosuccinates, mono- and dialkylsulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts,
  • anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, amino propionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • the surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, relevant review articles include, for example, J. Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J.
  • the proportion of surfactants in the compositions can be 0.1 to 10 and preferably 0.5 to 5% by weight, based on the preparations.
  • surfactants can also be added to the hair care products as co-emulsifiers, such as: (1) Adducts of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear fatty alcohols with 8 to 22 C atoms, with fatty acids with 12 to 22 C atoms and with alkylphenols with 8 to 15 C atoms in the alkyl group;
  • alkyl mono- and oligoglycosides with 8 to 22 carbon atoms in the alkyl radical and their ethoxy analogs
  • polyol and especially polyglycerol esters such as e.g. Polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimer isostearate. Mixtures of compounds from several of these classes of substances are also suitable;
  • Partial esters based on linear, branched, unsaturated or saturated Ce / 22 fatty acids, ricinoleic acid as well as 12-hydroxystearic acid and glycerin, polyglycerin, pentaerythritol, dipentaerythritol, sugar alcohols (e.g. sorbitol), - alkyl glucosides. (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g. cellulose);
  • the adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or with castor oil are known, commercially available products. These are mixtures of homologs, the middle of which Degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate with which the addition reaction is carried out.
  • C12 / 18 fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 2024051 PS as refatting agents for cosmetic preparations.
  • C ⁇ / 1 8 alkyl mono- and oligoglycosides their preparation and their use are known from the prior art. They are produced in particular by reacting glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms.
  • glycoside residue both Monoglycosides, in which a cyclic sugar residue is glycosidically bound to the fatty alcohol, and also oligomeric glycosides with a degree of oligomerization of up to preferably about 8 are suitable.
  • the degree of oligomerization is a statistical mean value which is based on a homolog distribution customary for such technical products,
  • Zwitterionic surfactants can also be used as emulsifiers.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines, such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylm -hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for
  • Suitable emulsifiers are ampholytic surfactants.
  • Ampholytic surfactants are surface-active compounds -verrise r are the i ⁇ alkyl or acyl group containing -except to a C / in the molecule at least one free amino group and at least one -COOH or -S ⁇ 3H group and are capable of forming inner salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and Ci2 / i8-acylsarcosine.
  • Substances such as, for example, lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Suitable consistency agents are primarily fatty alcohols or hydroxyfatty alcohols with 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferred.
  • Polymeric thickeners such as aerosil types (hydrophilic silicas), polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids are also used.
  • Polyacrylates e.g.
  • surfactants such as ethoxylated fat Acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with a narrow homolog distribution, and electrolytes such as table salt and ammonium chloride.
  • Suitable cationic polymers are, for example, cationic cellulose derivatives, e.g. a quaternized hydroxyethyl cellulose available under the name Polymer JR 400® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrrolidone / vinylimidazole polymers such as e.g.
  • Luviquat® condensation products of polyglycols and amines, quaternized collagen polypeptides, such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L / Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, e.g. Amidomethicones, copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine (Cartaretine ⁇ / Sandoz), copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, e.g.
  • cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline, condensation products from dihaloalkylene, such as e.g. Dibromobutane with bisdialkylamines, e.g. Bis-dimethylamino-1,3-propane, cationic guar gum, e.g. Jaguar® CBS, Jaguar®. C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers, e.g. Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol.
  • dihaloalkylene such as e.g. Dibromobutane with bisdialkylamines, e.g. Bis-dimethylamino-1,3-propane
  • cationic guar gum e.g. Jaguar® CBS, Jaguar®. C-17, Jaguar® C-16 from Celanese
  • quaternized ammonium salt polymers e.g. Mir
  • Anionic, zwitterionic, amphoteric and nonionic polymers include, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone ⁇ inylacrylate copolymers, vinyl acetate / butylmaleate / isobomylacrylate copolymers, methylvinylether / maleic anhydride copolymers and their esters, non-crosslinked acrylamide and polyethylenethacrylate acrylamide and non-crosslinked polyacrylamide acrylamide and with polyols, non-crosslinked polyamide acrylamide and with crosslinked Acrylate copolymers, octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxyproyl methacrylate copolymers, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / dimethylaminoeth
  • Pearlescent waxes are: alkylene glycol esters, especially ethylene glycol distearate; Fatty acid alkanolamides, especially coconut fatty acid diethanolamide; Partial glycerides, especially stearic acid monoglyceride; Esters of polyvalent, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; Fatty substances, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, which have a total of at least 24 carbon atoms, especially lauron and distearyl ether; Fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring opening products of olefin epoxides with 12 to 22 carbon atoms with fatty alcohols with 12 to 22 carbon atoms and / or polyols with 2 to 15 carbon atoms
  • Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones and amino-, fatty acid-, alcohol-, polyether-, epoxy-, fluorine-, glycoside- and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature.
  • Simethicones which are mixtures of dimethicones with an average chain length of 200 to 300 dimethylsiloxane units and hydrogenated silicates, are also suitable.
  • a detailed overview of suitable volatile silicones can also be found by Todd et al. in Cosm.Toil. 91, 27 (1976).
  • waxes can also be contained in the preparations, in particular natural waxes, such as candelilla wax, camauba wax, japan wax, espresso grass wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, ouricury wax, montan wax wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial grease, ceresin, ozokerite (earth wax) rPetrolatum, paraffin wax e MIKROE "awake 'se chemically" modified waxes (hard waxes), such as Montanesterwachse, sasol waxes, hydrogenated jojoba waxes and synthetic waxes such as eg polyalkylene waxes and polyethylene glycol waxes.
  • natural waxes such as candelilla wax, camauba wax, japan wax, espresso grass wax, cork wax, guaruma wax, rice germ oil wax,
  • metal salts of fatty acids e.g. Magnesium, aluminum and / or zinc stearate or ricinoleate are used.
  • Piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4-trimythylpentyl) -2- (IH) -pyridinone monoethanolamine salt), Baypival® (climbazole), Ketoconazol®, (4-acety I- 1 - ⁇ -4- [2- (2.4-dichlorophenyl) r-2- (1H-imidazol-1-ylmethyl) -1, 3-dioxylan-c-4-ylmethoxyphenyl ⁇ piperazine, ketoconazole, elubiol, selenium disulfide, sulfur colloidal , Sulfur polyethylene glycol sorbitan monooleate, sulfur Ricinolpolyehtoxylat, sulfur tar distillates, salicylic acid (or in combination with hexachlorophene), undexylenic acid monoethanolamide sulfosuccinate sodium salt, Lamepon® UD (protein undecylenic acid pyrithione, magnesium
  • hydrotropes such as ethanol, isopropyl alcohol, or polyols
  • polyols which come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups.
  • the polyols can also contain further functional groups, in particular amino groups, or be modified with nitrogen. Typical examples are
  • Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
  • Methyl compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
  • Lower alkyl glucosides in particular those with 1 to 8 carbons in the alkyl radical, such as methyl and butyl glucoside;
  • Sugar alcohols with 5 to 12 carbon atoms such as sorbitol or mannitol,
  • Aminosugar such as gluamine
  • Dialcohol amines such as diethanolamine or 2-amino-1, 3-propanediol.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, para- " bene “ , pentanediol or sorbic acid _ and " the " other classes of substances listed in ⁇ Appendix _ 6rPart " A _ and B of the " Cosmetics Ordinance.
  • Antioxidant-type protective agents are used that interrupt the photochemical reaction chain that is triggered when UV radiation penetrates the skin.
  • Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine) , Chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g.
  • thiols e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, Propyl, amyl, butyl and lauryl, palmitoyl, oleyl, ⁇ -linoleyl, cholesteryl and glyceryl esters
  • salts dilaurylthio dipropionate, distearylthiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids , Nucleotides, nucleosides and salts) as well as sulfoximine compounds (e.g.
  • buthioninsulfoximines homocysteine sulfoximine, butioninsulfones, penta-, hexa-, heptathioninsulfoximine) in very low tolerable dosages (e.g. pmol to ⁇ mol / kg), also (metal) chelators (e.g. ⁇ -hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), ⁇ -hydroxy acids (e.g.
  • citric acid citric acid, lactic acid, malic acid
  • humic acid bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives
  • folic acid and its derivatives ubiquinone and ubiquinol and their derivatives
  • vitamin C and derivatives eg ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate
  • vitamin A and derivatives vitamin A palmitate
  • EDTA EDTA
  • NTA phosphonic acids
  • Triton B Triton B
  • turpinal and phenacetin can be used as complexing agents.
  • Reducing agents such as ascorbic acid, sodium sulfate, sodium thiosulfate and the like may also be included.
  • Ammonia, monoethanolamines, (L) - arginine, AMP etc. can be used as alkalizing agents.
  • Perfume oils include mixtures of natural and synthetic fragrances.
  • Natural fragrances are extracts of flowers (lily, lavender, roses, jasmine, neroli, ylang-ylang), stems -unc leaves- ( ⁇ eranium7H ⁇ tchoulirPetitgrain) rfruits- (Ams7Koriandererr cumin,-juniper) 7 fruit peels (bergamot, lemon, oranges), Roots (Macis, Angelica, Celery, Cardamom, Costus, Iris, Calmus), Woods (Pine, Sandal, Guaiac, Cedar, Rosewood), Herbs and Grasses (Tarragon, Lemongrass, Sage, Thyme), Needles and Twigs (Spruce, fir, pine, mountain pine), resins and balsams (GälbäHüm, Elemi, " Bel ⁇ zöeT " Myi ⁇ h " e7Olibanum, Opoponax) width " animal raw materials, such
  • Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert.-butylcyclohexyl acetate, - linalyl acetate.-dimethylbenzylcarbinylacetate, - phenylethyl acetate, linalyl benzoate, benzyl formate, ethyl methylphenyl glycinate, allyl cyclohexylpropylateylateylateylateylateylateylateylateylateylateylateylateylatepylpropylate.
  • the ethers include, for example, benzyl ethyl ether
  • the aldehydes include, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial and bourgeonal
  • the ketones include, for example, the jonones, oc-isomethylionone and methyl cedryl ketone the alcohols anethol, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol
  • the hydrocarbons mainly include the terpenes and balsams, but preference is given to using mixtures of different fragrances which together produce an appealing fragrance.
  • Essential oils of lower volatility which are mostly used as aroma components, are also suitable as perfume oils, for example sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil, labolanum oil and lavandin oil.
  • the oil phase with the liquid and solid components including Dehyquart® L 80 was melted at 75 - 80 ° C.
  • the water phase likewise heated to 75-80 ° C., was added to the hot oil phase and slowly cooled down to 30 ° C. with stirring.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

L'invention concerne des produits de soins capillaires contenant des huiles naturelles comprenant des tocophérols et des stérols ou des caroténoïdes. L'invention concerne également l'utilisation de ces produits de soins capillaires pour empêcher les cheveux de casser et de fourcher et pour protéger des effets nuisibles de la lumière ultraviolette.
EP02730268A 2001-05-31 2002-05-22 Produits de soins capillaires contenant des huiles naturelles Withdrawn EP1390001A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10126446A DE10126446A1 (de) 2001-05-31 2001-05-31 Haarpflegemittel mit natürlichen Ölen
DE10126446 2001-05-31
PCT/EP2002/005590 WO2002096376A2 (fr) 2001-05-31 2002-05-22 Produits de soins capillaires contenant des huiles naturelles

Publications (1)

Publication Number Publication Date
EP1390001A2 true EP1390001A2 (fr) 2004-02-25

Family

ID=7686710

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02730268A Withdrawn EP1390001A2 (fr) 2001-05-31 2002-05-22 Produits de soins capillaires contenant des huiles naturelles

Country Status (6)

Country Link
US (1) US20040151676A1 (fr)
EP (1) EP1390001A2 (fr)
JP (1) JP2004532255A (fr)
AR (1) AR034063A1 (fr)
DE (1) DE10126446A1 (fr)
WO (1) WO2002096376A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008273874A (ja) * 2007-04-27 2008-11-13 Fuji Chem Ind Co Ltd 頭皮外用剤
US20090041713A1 (en) * 2007-08-10 2009-02-12 Conopco, Inc. D/B/A Unilever Hair Care Composition
US20090044822A1 (en) * 2007-08-10 2009-02-19 Conopco, Inc. D/B/A Unilever Hair care composition
US20090041701A1 (en) * 2007-08-10 2009-02-12 Conopco, Inc. D/B/A Unilever Hair care composition
JP5619409B2 (ja) * 2009-12-10 2014-11-05 株式会社ミルボン 毛髪処理剤
JP6092038B2 (ja) * 2013-08-02 2017-03-08 富士フイルム株式会社 乳化組成物

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB824353A (en) * 1956-10-19 1959-11-25 Berner Osakeyhtio Hair oil
US4172887A (en) * 1973-11-30 1979-10-30 L'oreal Hair conditioning compositions containing crosslinked polyaminopolyamides
JPS56120613A (en) * 1980-02-26 1981-09-22 Kao Corp Preshampoo type hair treatment composition
DE4134137C2 (de) * 1991-10-16 1996-03-28 Scharfe Peter Michael Haarboden-Bioaktivlotion und Verfahren zu ihrer Herstellung
FR2700954B1 (fr) * 1993-01-29 1995-04-28 Eve International Sa Composition cosmétique à action réparatrice et protectrice des cheveux secs et très secs.
DE4308794C1 (de) * 1993-03-18 1994-04-21 Henkel Kgaa Verfahren zur Herstellung von festen Esterquats mit verbesserter Wasserdispergierbarkeit
DE19608775A1 (de) * 1996-03-07 1997-09-11 Beiersdorf Ag Haarkosmetische Zubereitungen auf der Grundlage von Phytosterolen und alpha-Hydroxycarbonsäuren
DE19609477A1 (de) * 1996-03-11 1997-09-18 Basf Ag Stabile wäßrige Solubilisate von Carotinoiden und Vitamine
DE19805703C2 (de) * 1998-02-06 2001-05-03 Cognis Deutschland Gmbh Haarnachbehandlungsmittel
JP2002527367A (ja) * 1998-10-14 2002-08-27 コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング ナノスケールのステロールおよびステロールエステルの使用
US20040013753A1 (en) * 1998-12-23 2004-01-22 Laboratoires Pharmascience Use of unsaponifiable components of vegetable oils for preparing a food additive

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
None *
See also references of WO02096376A3 *

Also Published As

Publication number Publication date
JP2004532255A (ja) 2004-10-21
US20040151676A1 (en) 2004-08-05
DE10126446A1 (de) 2002-12-05
AR034063A1 (es) 2004-01-21
WO2002096376A3 (fr) 2003-04-03
WO2002096376A2 (fr) 2002-12-05

Similar Documents

Publication Publication Date Title
DE19921186C2 (de) Hochkonzentriert fließfähige Perlglanzkonzentrate und Verfahren zu ihrer Herstellung
DE10150727A1 (de) Kosmetische und/oder pharmazeutische Zubereitungen
EP1434559B1 (fr) Preparations cosmetiques et/ou pharmaceutiques
DE10150728A1 (de) Kosmetische und/oder pharmazeutische Zubereitungen
DE19906081A1 (de) Verwendung von Emulsionen als Imprägnier- und Avivagemittel
EP1185235A1 (fr) Preparations colorantes pour les cheveux
DE19929511A1 (de) Hochkonzentriert fließfähige Aniontensidmischungen
EP1392225A2 (fr) Produits de soins capillaires a base d'huiles naturelles
EP1117377B1 (fr) Preparations cosmetiques
DE19851451A1 (de) Kosmetische und/oder pharmazeutische Zubereitungen
EP1390001A2 (fr) Produits de soins capillaires contenant des huiles naturelles
EP1390002A1 (fr) Produits de soins capillaires aux huiles naturelles
DE10044662A1 (de) Kosmetische und/oder pharmazeutische Zubereitungen mit Salicysäure
DE19937293A1 (de) Verwendung von alkoxylierten Carbonsäureestern als Schaumboostern
DE10310381A1 (de) Tensidmischungen
WO2000069410A1 (fr) Preparations cosmetiques et/ou pharmaceutiques
EP1621231A1 (fr) Composition à base de tensioactifs conditionnants
EP1051966A2 (fr) Compositions cosmétiques et/ou pharmaceutiques contenant des alkylglycosides, des glycérides partiels d'acides gras, des esterquats, et du guar hydroxyalkylé comme agent épaississant
EP1301073A1 (fr) Utilisation d'esters quaternaires comme agents microbicides
DE19851430A1 (de) Verwendung von kationaktiven Mischungen
EP1131049A1 (fr) Utilisation de melanges cationiques
EP1128808A1 (fr) Utilisation de melanges cationiques
DE19949281A1 (de) Verwendung von Emulgatormischungen
DE19916209A1 (de) Kosmetische Zubereitungen
WO2000001875A1 (fr) Composition assouplissante

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20031121

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

RBV Designated contracting states (corrected)

Designated state(s): DE ES FR GB IT

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: COGNIS IP MANAGEMENT GMBH

17Q First examination report despatched

Effective date: 20061123

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20061201