EP1390001A2 - Hair care agents containing natural oils - Google Patents

Abstract

The invention relates to hair care agents containing natural oils that comprise tocopherols and sterols and/or carotinoids. The invention further relates to the use of said hair care agents for preventing broken hair and split ends and for protecting the hair against the detrimental effects of UV light.

Description

 Hair care products with natural oils

The invention is in the field of cosmetic products and relates to hair care products which contain natural oils with tocopherols and sterols and / or carotenoids and which are used to strengthen the hair and to protect against UV light.

State of the art

There are already numerous preparations for hair care against split ends and breaking of the hair on the ^" MärkT ^~ Schäά'iglιn ή ^~ dü ^. Remnants of dyeing, bleaching or washing the hair remain on the hair and scalp, or cause frequent and intensive styling to roughen the hair shaft and are also visible macroscopically after a short time. Particularly intense sunshine helps that the hair dries out or fades, which applies to both natural hair color and tinted hair,

Hair treatment agents with different active ingredients against split ends and the damaging influence of UV radiation are already known from many patent applications. In JP 0 1211515 and JP 0 1272513, agents with silicone compounds in combination with antioxidants are used against split ends and exposure to UV light. Antioxidants such as tocopherol and carotenoids are also used against graying of human hair (DE 41 39921 A1). .

International patent application WO 95/17157 discloses a hair care product with a vitamin combination of vitamins B1, B6, B12, C and tocopherol in liposomal form for pretreatment or aftertreatment with light and / or laser radiation.

With the aim of protecting the hair from damaging environmental influences, sterols as hair growth-strengthening agents are described in US Pat. No. 6,156,296. They are used in combination with alpha-hydroxycarboxylic acids in hair care products. Likewise, European patent application EP 0 943 313 A2 describes the use of sunflower wax in hair care products in order to counteract damaging environmental influences.

In order to be effective, it is important that the active ingredients are well absorbed by the hair and scalp. The application concentrations are usually relatively high. Despite many different approaches, there is still a need for effective formulations to overcome the problems described. It is therefore an object of the following invention to provide preparations which have an improved action against broken hair and split ends, and also have environmental influences, in particular in the form of damaging UV radiation.

Furthermore, they should damage the hair less after use, but stabilize it and thus help maintain the hair structure. These forms of preparation should also have good dermatological compatibility and be characterized by good stability when stored at high temperatures.

Description of the invention

The invention relates to hair care products containing natural oils

(a) tocopherols and

(b) sterols and / or

(c) Carotenoids, and the use of these hair care products to prevent hair breakage and split ends and to protect against damaging UV light influences.

Another object of the invention is the use of natural oils with tocopherols and sterols and / or carotenoids for the production of hair care products.

Surprisingly, it was found that the effectiveness of tocopherols, sterols and carotenoids for preventing hair breakage and split ends is much higher if they are used in natural oils in hair care products. The presence of the oils has a nourishing and protective effect against environmental influences and mechanical stress, especially on damaged and dry hair, and on the other hand increases the availability of the active ingredients against damaging UV light influences. The combination of tocopherol with sterols or carotenoids shows an improved effectiveness against hair breakage and split ends. By using the combination of sterols and carotenoids with tocopherol, the effectiveness against damaging UV light effects can be further increased. In addition, such preparations also prophylactically lead to reduced damage to the hair structure and thus contribute to maintaining the hair structure.

Natural oils with tocopherol and sterols and / or carotenoids

The preparations according to the invention contain 0.1 to 20% by weight, preferably 1 to 10% by weight and particularly preferably 2 to 5% by weight, of the natural oils.

Natural oils are to be understood as oils that are of animal or preferably vegetable origin. These are esters of linear Cε-C∑∑ fatty acids with linear C6-C22 fatty alcohols, Esters of branched Cδ-Ci3 carboxylic acids with linear Cβ-C∑∑ fatty alcohols, such as myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl stearate, cetyl palmitate, cetyl palmitate, cetyl palmitate, cetyl palmitate, cetyl palmitate, cetyl palate Stearylmyristat, stearyl palmitate, stearyl stearate, Stearylisostearat, stearyl oleate, stearyl behenate, Stearylerucat, isostearyl, isostearyl palmitate, Isostearylstearat, isostearyl isostearate, Isostearyloleat, isostearyl behenate, Isostearyloleat, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, 0- leyloleat, Oleylbehenat, oleyl erucate, behenyl myristate, behenyl, Behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. Triglycerides based on Ce-Cio fatty acids and liquid mono- / di- / triglyceride mixtures based on C6-Ci8 fatty acids are also suitable. The tocopherols, sterols and / or carotenoids can be added to these oils, but they are preferably already present in the oil in the native state. Particularly preferred are the commercial products from ^" AarhüsOliefäbrik S / S Aärhus Denmark, ^" known under the name Cremeol® now Cegesoft® (Cognis, Düsseldorf). These include:

Cegesoft® (previously Cremeol®) PS 6, vegetable oil, C18: 1 84%, C18: 2 5%, unsaponifiable matter (mainly phytosterols, e.g.-ß-sitosterol, campesterol) -1.1%, tocopherols 1,400 ppm Cegesoft ® (previously Cremeol®) PS 17, Vegetable oil, C18: 1 72%, C18: 2 11%, unsaponifiable matter (mainly phytosterols, e.g. ß-sitosterol, campesterol) 1.5%, tocopherols 2000 ppm Cegesoft® (previously Cremeol®) PFO, Passionflower (Passiflora Incarnata) oil, C18: 1 16%, C18: 270%, unsaponifiable matter (phytosterols, e.g. ß-sitosterol, campesterol) <1 - max. 2.5% (of which ß-sitosterol 49%, stigmasterol 23%, capesterol 11%, other 17%), tocopherols 600 ppm Cegesoft® (previously Cremeol®) GPO, golden palm (Elaeis Guineensis) oil, tocopherols + tocotrienols 1000 ppm, carotenoid 400 ppm

Cegesoft® (previously Cremeol®) SBE, Shea butter (Butyrospermum Parkii) extract, C18: 1 63.4%, C18: 2 1.8%, unsaponifiable matter: 30-40%, of which triterpene alcohols 85%, sterols 8%; Tocopherols 1,400 ppm

Therefore, mainly phytosterols are used as sterols. Examples include sitosterol, campesterol, brassicasterol, lupenol, stigmasterol, α-spinasterol and avennasterol, ß-sitosterol, stigmasterol and campesterol are particularly preferred.

Tocopherols are understood to mean chroman-6-oles (3,4-dihydro-2H-benzopyran-6-ole) substituted in the 2-position with a 4,8,12, -trimethyltridecyl radical. The plastoquinones, tocopherolquinones, ubiquinones, bovichinones, K vitamins and menaquinones (2-methyl-1, 4-naphthoquinones) belong to the same group of bioquinones, ie to the polyprenylated 1,4-benzo and naphthoquinones. In particular, α-, β-, γ- and δ-tocopherols come into question. In addition to the tocopherols, their derivatives, in particular esters with carboxylic acids, such as tocopherol acetate or palmitate, are also suitable. Carotenoids are plant substances that give vegetables or fruits the yellow, orange or red color. Chemically speaking, these are 11- to 12-fold unsaturated tetraterpenes with a skeleton with 9 conjugated double bonds, 8 methyl branches (including the possible ring structures) and a ß-ionone ring structure at one end of the molecule while they are in the structure at the other end of the molecule. Typical carotenoids are, for example, β-carotene or provitamin A, α-carotene, lutein, cryptoxanthin, zeaxanthin and lycopene. Solubilizates of carotenoids and tocopherols for oral intake are also known from German Offenlegungsschrift DE 19609477 A1. The carotenoids can be used individually or in mixtures.

Esterqυats

The term "esterquats" is generally understood to mean quaternized fatty acid triethanolamine ester salts. These are known substances which can be obtained by the relevant methods of preparative organic chemistry. In this connection, reference is made to the international patent application WO 91/01295 ( Henkel), according to which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through and then quaternized with dimethyl sulfate or ethylene oxide. A process for the preparation of solid esterquats is also known from German Patent DE-C1 4308794 (Henkel) to which the quaternization of triethanolamine esters is carried out in the presence of suitable dispersants, preferably fatty alcohols.Overviews on this topic are, for example, by R. Puchta et al. in Tens. Surf.Det., 30, 186 (1993), M.Brock in Tens.Surf.Det. 30, 394 (1993), R. Lagerman et al. in J.Am.Oil. Chem. Soc, 71. 97 ("1994) and I.Shapiro in Cosm.Toil. 109, 77 (1994) appeared. The quaternized fatty acid triethanolamine ester salts follow the formula (I)

I - [RiCO- (OCH ₂ CH2) mOCH2CH2-N ⁺ .CH2CH2θ. (CH2CH ₂ 0) nR ² ] X- (I)

in which R ¹ CO represents an acyl radical with 6 to 22 carbon atoms, R ² and R ³ independently of one another for hydrogen or R ¹ CO, R ^{4 represents} an alkyl radical with 1 to 4 carbon atoms or a (CH2CH2θ) _q H group, m, n and p in total stand for 0 or numbers from 1 to 12, q stands for numbers from 1 to 12 and X stands for halide, alkyl sulfate or alkyl phosphate. Typical examples of ester quats that can be used in the context of the invention are products based on caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, isostearic acid, stearic acid, oleic acid, elaidic acid, arachic acid, behenic acid and erucic acid and their technical mixtures , as they occur, for example, in the pressure splitting of natural fats and oils. Technical C12 / 18- Coconut fatty acids and in particular partially hardened Ciβ / iβ tallow or palm fatty acids as well as elaidic acid-rich Ci6 / 18 fatty acid cuts are used. The fatty acids and the triethanolamine can be used in a molar ratio of 1.1: 1 to 3: 1 to produce the quaternized esters. With regard to the application properties of the ester quats, an application ratio of 1.2: 1 to 2.2: 1, preferably 1.5: 1 to 1.9: 1 has proven to be particularly advantageous. The preferred ester quats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9 and are derived from technical C16 / 18-tallow or palm fatty acid (iodine number 0 to 40) , From an application point of view, quaternized fatty acid triethanol amine ester salts of the formula (I) have proven to be particularly advantageous, R ¹ GO for an acyl radical having 16 to 18 carbon atoms, R ² for R ¹ CO, R ³ for hydrogen, R ^{4 represents} a methyl group, m, n and p represents 0 and X represents methyl sulfate. In addition to the quaternized fatty acid triethanolamine ester salts, quaternized ester salts of fatty acids with diethanolalkylamines of the formula (II) are also suitable as esterquats,

R ⁴

I [R ¹ CO- (OCH ₂ CH2) mOCΗ2CH2-N + -CH2CH2O- (CH ₂ CH2θ) _n R2] X- (II)

-I- -

R ³

in which R ¹ CO for an acyl radical with 6 to 22 carbon atoms, R ² for hydrogen or R ¹ CO, R ³ and R ⁴ independently of one another for alkyl radicals with 1 to 4 carbon atoms, m and n in total for 0 or numbers from 1 to 12 and X represents halide, alkyl sulfate or alkyl phosphate. Finally, the quaternized ester salts of fatty acids with 1,2-dihydroxypropyl dialkylamines of the formula (III) should be mentioned as a further group of suitable ester quats,

R ⁵ O- (CH ₂ CH2θ) mOCRi

I I

[R ⁴ -N ⁺ .CH2CHCH ₂ 0. (CH2CH ₂ 0) nR ² ] X "(III)

IR ³

in which R ¹ CO stands for an acyl radical with 6 to 22 carbon atoms, R ² for hydrogen or RICO, R ³ , R ⁴ and R ⁵ independently of one another for alkyl radicals with 1 to 4 carbon atoms, m and n in total for 0 or numbers of 1 to 12 and X represents halide, alkyl sulfate or alkyl phosphate. With regard to the selection of the preferred fatty acids and the optimal degree of esterification, the examples given for (I) also apply to the esterquats of the formulas (II) and (III). The esterquats usually come on the market in the form of 50 to 90% strength by weight alcoholic solutions, which can be diluted with water if required.

Esterquats can be present in the hair care products in amounts of 0 to 10% by weight, preferably 1 to 5% by weight and particularly preferably 1.5 to 3% by weight. Industrial applicability

Formulations which remain on the hair or the scalp for a long time or which frequently contain aggressive chemicals are particularly suitable for developing the effectiveness against hair breakage, split ends and UV light influences. These include hair treatments, hair packs, hair lotions, hair gels, hair colors, bleaching agents, permanent waving agents, sun and after-sun products for hair. • ^{• The} agents are particularly suitable for long-term use with a prophylactic effect. In addition to preventing hair breakage and split ends, the preparations can also be used for intensive care of the scalp, to increase hair shine, improve the feel and to fade the natural hair color and synthetic hair colors.

Cosmetic and / or pharmaceutical preparations

In a preferred embodiment of the agents according to the invention, the hair care agents containing natural oils with tocopherols and sterols are in a composition of:

0.01 to 5% by weight of tocopherols and 0.01 to 10% by weight of sterols, based on the amount of the oils. The natural oils preferably contain

0.03 to 3% by weight of tocopherols and 0.5 to 8% by weight of sterols and particularly preferred

0.05 to 2% by weight of tocopherols and 1 to 5% by weight of sterols.

In a further embodiment of the agents according to the invention, the hair care agents containing natural oils with tocopherols and carotenoids are in a composition of:

0.01 to 5% by weight of tocopherols and 0.001 to 2% by weight of carotenoids based on the amount of

Oils, before. The natural oils preferably contain

0.03 to 3% by weight of tocopherols and 0.005 to 1% by weight of carotenoids are particularly preferred

0.05 to 2% by weight of tocopherols and 0.01 to 0.5% by weight of carotenoids.

In the embodiment of the agents according to the invention, the hair care agents containing natural oils with tocopherols and sterols and carotenoids are in a composition of:

(a) 0.01 to 5% by weight of tocopherols and

(b) 0.1 to 10% by weight of sterols and

(c) 0.001 to 2% by weight of carotenoids based on the amount of the oils. The natural oils preferably contain

(a) 0.03 to 3% by weight of tocopherols and

(b) 0.5 to 8% by weight of sterols and

(c) 0.005 to 1% by weight of carotenoids is particularly preferred

(a) 0.05 to 2% by weight tocopherols and

(b) 1 to 5% by weight of sterols and

(c) 0.01 to 0.5% by weight of carotenoids.

The hair care products according to the invention can contain, as additional auxiliaries and additives, surfactants, co-emulsifiers, superfatting agents, pearlescent waxes, consistency agents, polymers, silicone compounds, waxes, stabilizers, antidandruff agents, film formers, swelling agents, hydrotropes, preservatives, solubilizers, complexing agents, reducing agents, alkalizing agents, antioxidants Contain perfume oils and the like,

Other preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic surfactants. Typical examples of anionic surfactants are soaps, alkylbenzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerin ether sulfonates, α-methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxymeamide sulfate, hydroxymether sulfates ether) sulfates, mono- and dialkylsulfosuccinates, mono- and dialkylsulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, N-acylamino acids, such as acyl lactamate, acyl glutylate, acyl sulfate acyl acyl aryl asylates, acyl glutamate, acyl sulfate acyl acylate, acyl glutamate, acyl glucosate acyl acyl asylate, acyl sulfate acyl, acyl acyl aspartate, acyl glutylate, acyl glutamate, acyl sulfate , Protein fatty acid condensates (especially vegetable products based on wheat) and alkyl (ether) phosphates. If the anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution. Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, amino propionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, relevant review articles include, for example, J. Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J. Falbe (ed.), " Catalysts, surfactants and mineral oil additives ", Thieme Verlag, Stuttgart, 1978, pp. 123-217. The proportion of surfactants in the compositions can be 0.1 to 10 and preferably 0.5 to 5% by weight, based on the preparations.

In addition, other surfactants can also be added to the hair care products as co-emulsifiers, such as: (1) Adducts of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear fatty alcohols with 8 to 22 C atoms, with fatty acids with 12 to 22 C atoms and with alkylphenols with 8 to 15 C atoms in the alkyl group;

(2) Ci2 / i8 fatty acid monoesters and diesters of adducts of 1 to 30 moles of ethylene oxide with glycerol;

(3) glycerol monoesters and diesters and sorbitan monoesters and diesters of saturated and unsaturated fatty acids having 6 to 22 carbon atoms and their ethylene oxide addition products;

(4) alkyl mono- and oligoglycosides with 8 to 22 carbon atoms in the alkyl radical and their ethoxy analogs;

(5) adducts of 15 to 60 moles of ethylene oxide with castor oil and / or hardened castor oil;

(6) polyol and especially polyglycerol esters such as e.g. Polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimer isostearate. Mixtures of compounds from several of these classes of substances are also suitable;

(7) adducts of 2 to 15 moles of ethylene oxide with castor oil and / or hardened castor oil;

(8) Partial esters based on linear, branched, unsaturated or saturated Ce / 22 fatty acids, ricinoleic acid as well as 12-hydroxystearic acid and glycerin, polyglycerin, pentaerythritol, dipentaerythritol, sugar alcohols (e.g. sorbitol), - alkyl glucosides. (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g. cellulose);

(9) mono-, di- and trialkyl phosphates and mono-, di- and / or tri-PEG-alkyl phosphates and their salts;

(10) wool wax alcohols;

(11) polysiloxane-polyalkyl-polyether copolymers or corresponding derivatives;

(12) mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol according to DE 1165574 PS and / or mixed esters of fatty acids with 6 to 22 carbon atoms, methyl glucose and polyols, preferably glycerol or polyglycerol,

(13) polyalkylene glycols and

(14) Glycerol carbonate.

The adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or with castor oil are known, commercially available products. These are mixtures of homologs, the middle of which Degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate with which the addition reaction is carried out. C12 / 18 fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 2024051 PS as refatting agents for cosmetic preparations.

Cβ / 1 ₈ alkyl mono- and oligoglycosides, their preparation and their use are known from the prior art. They are produced in particular by reacting glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms. Regarding the glycoside residue, both Monoglycosides, in which a cyclic sugar residue is glycosidically bound to the fatty alcohol, and also oligomeric glycosides with a degree of oligomerization of up to preferably about 8 are suitable. The degree of oligomerization is a statistical mean value which is based on a homolog distribution customary for such technical products,

Zwitterionic surfactants can also be used as emulsifiers. Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule. Particularly suitable zwitterionic surfactants are the so-called betaines, such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylm -hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate. The fatty acid amide derivative known under the CTFA name of Cocamidopropyl Betaine is particularly preferred. Suitable emulsifiers are ampholytic surfactants. Ampholytic surfactants are surface-active compounds -verstanden _r are the iβ alkyl or acyl group containing -except to a C / in the molecule at least one free amino group and at least one -COOH or -Sθ3H group and are capable of forming inner salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and Ci2 / i8-acylsarcosine.

Substances such as, for example, lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.

Suitable consistency agents are primarily fatty alcohols or hydroxyfatty alcohols with 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferred.

Polymeric thickeners such as aerosil types (hydrophilic silicas), polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids are also used. Polyacrylates (e.g. Carbopole® from Goodrich or Synthalene® from Sigma), polyacrylamides, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as ethoxylated fat Acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with a narrow homolog distribution, and electrolytes such as table salt and ammonium chloride.

Suitable cationic polymers are, for example, cationic cellulose derivatives, e.g. a quaternized hydroxyethyl cellulose available under the name Polymer JR 400® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrrolidone / vinylimidazole polymers such as e.g. Luviquat® (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides, such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L / Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, e.g. Amidomethicones, copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine (CartaretineΘ / Sandoz), copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, e.g. described in FR 2252840 A and its crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline, condensation products from dihaloalkylene, such as e.g. Dibromobutane with bisdialkylamines, e.g. Bis-dimethylamino-1,3-propane, cationic guar gum, e.g. Jaguar® CBS, Jaguar®. C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers, e.g. Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol.

Anionic, zwitterionic, amphoteric and nonionic polymers include, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidoneΛ inylacrylate copolymers, vinyl acetate / butylmaleate / isobomylacrylate copolymers, methylvinylether / maleic anhydride copolymers and their esters, non-crosslinked acrylamide and polyethylenethacrylate acrylamide and non-crosslinked polyacrylamide acrylamide and with polyols, non-crosslinked polyamide acrylamide and with crosslinked Acrylate copolymers, octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxyproyl methacrylate copolymers, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam terpolymers and, if appropriate, derivatized derivates in cell polymers and questionable silicates.

Pearlescent waxes, for example, are: alkylene glycol esters, especially ethylene glycol distearate; Fatty acid alkanolamides, especially coconut fatty acid diethanolamide; Partial glycerides, especially stearic acid monoglyceride; Esters of polyvalent, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; Fatty substances, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, which have a total of at least 24 carbon atoms, especially lauron and distearyl ether; Fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring opening products of olefin epoxides with 12 to 22 carbon atoms with fatty alcohols with 12 to 22 carbon atoms and / or polyols with 2 to 15 carbon atoms and 2 to 10 hydroxyl groups and mixtures thereof. Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones and amino-, fatty acid-, alcohol-, polyether-, epoxy-, fluorine-, glycoside- and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature. Simethicones, which are mixtures of dimethicones with an average chain length of 200 to 300 dimethylsiloxane units and hydrogenated silicates, are also suitable. A detailed overview of suitable volatile silicones can also be found by Todd et al. in Cosm.Toil. 91, 27 (1976).

In addition to the natural oils used, waxes can also be contained in the preparations, in particular natural waxes, such as candelilla wax, camauba wax, japan wax, espresso grass wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, ouricury wax, montan wax wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial grease, ceresin, ozokerite (earth wax) rPetrolatum, paraffin wax e MIKROE ^{"awake 'se chemically"} modified waxes (hard waxes), such as Montanesterwachse, sasol waxes, hydrogenated jojoba waxes and synthetic waxes such as eg polyalkylene waxes and polyethylene glycol waxes.

As stabilizers, metal salts of fatty acids, e.g. Magnesium, aluminum and / or zinc stearate or ricinoleate are used.

Piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4-trimythylpentyl) -2- (IH) -pyridinone monoethanolamine salt), Baypival® (climbazole), Ketoconazol®, (4-acety I- 1 - {-4- [2- (2.4-dichlorophenyl) r-2- (1H-imidazol-1-ylmethyl) -1, 3-dioxylan-c-4-ylmethoxyphenyl} piperazine, ketoconazole, elubiol, selenium disulfide, sulfur colloidal , Sulfur polyethylene glycol sorbitan monooleate, sulfur Ricinolpolyehtoxylat, sulfur tar distillates, salicylic acid (or in combination with hexachlorophene), undexylenic acid monoethanolamide sulfosuccinate sodium salt, Lamepon® UD (protein undecylenic acid pyrithione, magnesium pyridithione, zinc pyrithione, zinc pyrithione, zinc pyrithione, zinc pyrithione, zinc pyrithione, zinc pyrithione, zinc pyrithione, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, zinc pyridine, Magnesium sulfate in question.

To improve the flow behavior, hydrotropes, such as ethanol, isopropyl alcohol, or polyols can also be used, polyols which come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols can also contain further functional groups, in particular amino groups, or be modified with nitrogen. Typical examples are

• glycerin;

Alkylene glycols, such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;

n Technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10 ^', such as technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight;

• Methyl compounds, such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;

• Lower alkyl glucosides, in particular those with 1 to 8 carbons in the alkyl radical, such as methyl and butyl glucoside;

Sugar alcohols with 5 to 12 carbon atoms, such as sorbitol or mannitol,

• Sugar with 5 to 12 carbon atoms, such as glucose or sucrose;

Aminosugar, such as gluamine

• Dialcohol amines, such as diethanolamine or 2-amino-1, 3-propanediol.

Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, para- ^" bene ^" , pentanediol or sorbic acid ^_ and ^" the ^" other classes of substances listed in ^~ Appendix ^_ 6rPart ^" A ^_ and B of the ^" Cosmetics Ordinance.

In addition to the two aforementioned groups of primary light stabilizers, secondary light stabilizers can also be used. Antioxidant-type protective agents are used that interrupt the photochemical reaction chain that is triggered when UV radiation penetrates the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine) , Chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, Propyl, amyl, butyl and lauryl, palmitoyl, oleyl, γ-linoleyl, cholesteryl and glyceryl esters) and their salts, dilaurylthio dipropionate, distearylthiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids , Nucleotides, nucleosides and salts) as well as sulfoximine compounds (e.g. buthioninsulfoximines, homocysteine sulfoximine, butioninsulfones, penta-, hexa-, heptathioninsulfoximine) in very low tolerable dosages (e.g. pmol to μmol / kg), also (metal) chelators ( e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and derivatives (eg ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), vitamin A and derivatives (vitamin A palmitate) as well as coniferyl benzoate of benzoin, rutinic acid and its derivatives, α-glycosyl rutin, ferulic acid, furfuryloluenyl glucitol, carnifurylolene glucitol , Butylated hydroxyanisole, nordihydroguajak resin acid, nordihydroguajaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (eg ZnO, ZnSθ4) selenium and its derivatives (eg selenium methionine) their derivatives (for example stilbene oxide, trans-stilbene oxide) and the derivatives suitable according to the invention (salts, esters, ethers, zu cker, nucleotides, nucleosides, peptides and lipids) of these active ingredients. EDTA, NTA, phosphonic acids, Triton B, turpinal and phenacetin can be used as complexing agents. Reducing agents such as ascorbic acid, sodium sulfate, sodium thiosulfate and the like may also be included. Ammonia, monoethanolamines, (L) - arginine, AMP etc. can be used as alkalizing agents.

Perfume oils include mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers (lily, lavender, roses, jasmine, neroli, ylang-ylang), stems -unc leaves- (Θeranium7H ^ tchoulirPetitgrain) rfruits- (Ams7Koriandererr cumin,-juniper) 7 fruit peels (bergamot, lemon, oranges), Roots (Macis, Angelica, Celery, Cardamom, Costus, Iris, Calmus), Woods (Pine, Sandal, Guaiac, Cedar, Rosewood), Herbs and Grasses (Tarragon, Lemongrass, Sage, Thyme), Needles and Twigs (Spruce, fir, pine, mountain pine), resins and balsams (GälbäHüm, Elemi, ^" BelτzöeT ^" Myiτh ^" e7Olibanum, Opoponax) width ^" animal raw materials, such as civet and castoreum, come into question. Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert.-butylcyclohexyl acetate, - linalyl acetate.-dimethylbenzylcarbinylacetate, - phenylethyl acetate, linalyl benzoate, benzyl formate, ethyl methylphenyl glycinate, allyl cyclohexylpropylateylateylateylateylateylateylateylateylateylateylateylateylateylateylateylatepylpropylate. The ethers include, for example, benzyl ethyl ether, the aldehydes include, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial and bourgeonal, and the ketones include, for example, the jonones, oc-isomethylionone and methyl cedryl ketone the alcohols anethol, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol, the hydrocarbons mainly include the terpenes and balsams, but preference is given to using mixtures of different fragrances which together produce an appealing fragrance. Essential oils of lower volatility, which are mostly used as aroma components, are also suitable as perfume oils, for example sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil, labolanum oil and lavandin oil. Preferably, bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, -Hexylzimtaldehyd, geraniol, benzyl acetone, cyclamen aldehyde, linalool, Boisambrene Forte, Ambroxan, indole, hedione, Sandelice, lemon oil, mandarin oil, orange oil, allyl amyl glycolate, Cyclovertal, lavandin oil, muscatel are sage oil , ß-Damascone, geranium oil bourbon, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, Evernyl, Iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilllate, irotyl and floramate, alone or in mixtures. Examples

To prepare the hair emulsions, the oil phase with the liquid and solid components including Dehyquart® L 80 was melted at 75 - 80 ° C. The water phase, likewise heated to 75-80 ° C., was added to the hot oil phase and slowly cooled down to 30 ° C. with stirring.

Table 1: Recipes for hair emulsions (amounts in% by weight)

* Cremeol types were obtained from Aarhus Oliefabrik A / S, Aarhus, DK

Claims

claims

1. Hair care products containing natural oils

(a) tocopherols and

(b) sterols and / or

(c) Carotenoids based on the amount of oils.

2. Composition according to claim 1, characterized in that the natural oils contain tocopherols in amounts of 0.01 to 5 wt.%.

3. Agent according to claims 1 and / or 2, characterized in that the natural oils contain sterols in amounts of 0.01 to 10% by weight.

4. Composition according to claims 1 to 3, characterized in that the natural oils contain carotenoids in quantities of 0.01 to 2% by weight.

5. Composition according to claims 1 to 4, characterized in that they contain the natural oils in amounts of 0.1 to 20% by weight.

6. Composition according to claims 1 to 5, characterized in that the natural oils contain unsaturated fatty acids as a further component.

7. Composition according to claims 1 to 6, characterized in that they contain ester quats as a further component.

8. Using natural oils with

(a) tocopherol and

(b) sterols and / or

(c) Carotenoids for the manufacture of hair care products.

9. Use of preparations according to claims 1 to 8 for the prevention of hair breakage and split ends.

10. Use of preparations according to claims 1 to 8 for protecting hair and scalp against exposure to UV light.