EP1377635A2 - Composition ignifuge anti-abrasive - Google Patents
Composition ignifuge anti-abrasiveInfo
- Publication number
- EP1377635A2 EP1377635A2 EP02721203A EP02721203A EP1377635A2 EP 1377635 A2 EP1377635 A2 EP 1377635A2 EP 02721203 A EP02721203 A EP 02721203A EP 02721203 A EP02721203 A EP 02721203A EP 1377635 A2 EP1377635 A2 EP 1377635A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- fire retardant
- abrasive
- weight percent
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 129
- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- 229920001944 Plastisol Polymers 0.000 claims abstract description 22
- 239000004999 plastisol Substances 0.000 claims abstract description 22
- 239000000919 ceramic Substances 0.000 claims abstract description 21
- 239000004014 plasticizer Substances 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010439 graphite Substances 0.000 claims abstract description 13
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 13
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 7
- 239000010452 phosphate Substances 0.000 claims abstract description 7
- -1 phosphate ester Chemical class 0.000 claims abstract description 7
- 238000005299 abrasion Methods 0.000 claims description 20
- 229920006311 Urethane elastomer Polymers 0.000 claims description 17
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims description 10
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 10
- 229910000765 intermetallic Inorganic materials 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 3
- 238000009472 formulation Methods 0.000 abstract description 39
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract description 19
- 239000011230 binding agent Substances 0.000 abstract description 15
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 229920002635 polyurethane Polymers 0.000 abstract description 4
- 239000004814 polyurethane Substances 0.000 abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052593 corundum Inorganic materials 0.000 abstract description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 32
- 229920005862 polyol Polymers 0.000 description 22
- 150000003077 polyols Chemical class 0.000 description 22
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 13
- 230000008033 biological extinction Effects 0.000 description 13
- 239000002994 raw material Substances 0.000 description 13
- 230000006870 function Effects 0.000 description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 description 10
- 230000005484 gravity Effects 0.000 description 10
- 239000000779 smoke Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 239000007770 graphite material Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- 239000012948 isocyanate Substances 0.000 description 5
- 150000002513 isocyanates Chemical class 0.000 description 5
- 238000011056 performance test Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229910010293 ceramic material Inorganic materials 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 4
- 229910000760 Hardened steel Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910021538 borax Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000979 retarding effect Effects 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 235000010339 sodium tetraborate Nutrition 0.000 description 3
- 238000007655 standard test method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000013022 formulation composition Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 230000036284 oxygen consumption Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 101100508413 Caenorhabditis elegans ifc-1 gene Proteins 0.000 description 1
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
- C04B2235/425—Graphite
Definitions
- FIGS. 2A-2C depict heat release rate, specific extinction area, and carbon monoxide, respectively, as a function of time for the urethane 5.2 control
- FIGS. 3A-3C depict heat release rate, specific extinction area, and carbon monoxide, respectively, as a function of time for the ultra high molecular weight polyethylene control
- composition designations include about approximately the same mass of PVC resin.
- preferred compositions as evidenced by the performance test results, is that of IFC 21/21C.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Cette invention se rapporte à plusieurs modes de réalisation généraux d'une composition ignifuge anti-abrasive, notamment ceux qui comprennent un liant au plastisol, un liant ou un système de plastisol modifié par polyuréthane ou un système d'uréthane pur modifié pour produire un effet ignifuge. Ces compositions se caractérisent de préférence en ce qu'elles contiennent un plastifiant à l'ester de phosphate et éventuellement, seuls ou associés entre eux, des composés métalliques ou des flocons de graphite intumescents. On prévoit également d'inclure/incorporer (par exemple par liaison) des éclats de céramique (Al2O3) dans les formulations de base faisant l'objet de cette invention, pour améliorer considérablement le caractère abrasif de la composition qui en résulte ou des panneaux fabriqués avec cette composition.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US27147701P | 2001-02-26 | 2001-02-26 | |
| US271477P | 2001-02-26 | ||
| PCT/US2002/006012 WO2002068061A2 (fr) | 2001-02-26 | 2002-02-26 | Composition ignifuge anti-abrasive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1377635A2 true EP1377635A2 (fr) | 2004-01-07 |
| EP1377635A4 EP1377635A4 (fr) | 2005-06-01 |
Family
ID=23035747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02721203A Withdrawn EP1377635A4 (fr) | 2001-02-26 | 2002-02-26 | Composition ignifuge anti-abrasive |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1377635A4 (fr) |
| AU (1) | AU2002252145A1 (fr) |
| WO (1) | WO2002068061A2 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007061503A1 (de) * | 2007-12-18 | 2009-06-25 | Henkel Ag & Co. Kgaa | Flammfeste Plastisole enthaltend Blähgraphit |
| WO2010034109A1 (fr) * | 2008-09-26 | 2010-04-01 | Quantum Technical Services Ltd. | Revêtement ignifuge |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2547555A1 (de) * | 1975-10-23 | 1977-04-28 | Kz Vnii Sintetitscheskoyo Kaut | Thermostabile urethanelastomere und mischungen auf deren basis |
| US4206102A (en) * | 1976-09-15 | 1980-06-03 | Mobay Chemical Corporation | Method of producing polyurethanes with increased resistance to abrasion |
| DE3113385A1 (de) * | 1981-04-02 | 1982-10-21 | Bayer Ag, 5090 Leverkusen | Halogenarmes, thermoplastisches polyurethanelastomer verbesserter flammbestaendigkeit durch zusatz einer 4-stoff-additiv-kombination, seine herstellung und seine verwendung |
| US4342682A (en) * | 1981-09-18 | 1982-08-03 | Borg-Warner Chemicals, Inc. | Intumescent flame retardant thermoplastic polyurethane elastomer compositions |
| US4572862A (en) * | 1984-04-25 | 1986-02-25 | Delphic Research Laboratories, Inc. | Fire barrier coating composition containing magnesium oxychlorides and high alumina calcium aluminate cements or magnesium oxysulphate |
| EP0384354B1 (fr) * | 1989-02-20 | 1995-01-04 | Canon Kabushiki Kaisha | Lame de nettoyage et appareil électrophotographique l'utilisant |
| US5045635A (en) * | 1989-06-16 | 1991-09-03 | Schlegel Corporation | Conductive gasket with flame and abrasion resistant conductive coating |
| US5942561A (en) * | 1995-03-03 | 1999-08-24 | Tosoh Corporation | Fire-retardant polymer composition |
| US6228433B1 (en) * | 1997-05-02 | 2001-05-08 | Permagrain Products, Inc. | Abrasion resistant urethane coatings |
-
2002
- 2002-02-26 EP EP02721203A patent/EP1377635A4/fr not_active Withdrawn
- 2002-02-26 WO PCT/US2002/006012 patent/WO2002068061A2/fr not_active Ceased
- 2002-02-26 AU AU2002252145A patent/AU2002252145A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002068061A2 (fr) | 2002-09-06 |
| AU2002252145A1 (en) | 2002-09-12 |
| EP1377635A4 (fr) | 2005-06-01 |
| WO2002068061A3 (fr) | 2002-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20030826 |
|
| AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
| RIC1 | Information provided on ipc code assigned before grant |
Ipc: 7C 08L 27/06 B Ipc: 7C 08K 3/22 B Ipc: 7C 08L 75/04 B Ipc: 7C 08K 5/521 B Ipc: 7C 08K 3/04 A |
|
| A4 | Supplementary search report drawn up and despatched |
Effective date: 20050419 |
|
| 17Q | First examination report despatched |
Effective date: 20070612 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20070829 |