EP1377381B1 - High-gradient magnetic filter and method for the separation of weakly magnetisable particles from fluid media - Google Patents
High-gradient magnetic filter and method for the separation of weakly magnetisable particles from fluid media Download PDFInfo
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- EP1377381B1 EP1377381B1 EP02727286A EP02727286A EP1377381B1 EP 1377381 B1 EP1377381 B1 EP 1377381B1 EP 02727286 A EP02727286 A EP 02727286A EP 02727286 A EP02727286 A EP 02727286A EP 1377381 B1 EP1377381 B1 EP 1377381B1
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- Prior art keywords
- filter
- gradient magnetic
- medium
- magnetic field
- filter according
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/025—High gradient magnetic separators
- B03C1/031—Component parts; Auxiliary operations
- B03C1/033—Component parts; Auxiliary operations characterised by the magnetic circuit
- B03C1/0332—Component parts; Auxiliary operations characterised by the magnetic circuit using permanent magnets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/28—Magnetic plugs and dipsticks
- B03C1/288—Magnetic plugs and dipsticks disposed at the outer circumference of a recipient
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C2201/00—Details of magnetic or electrostatic separation
- B03C2201/18—Magnetic separation whereby the particles are suspended in a liquid
Definitions
- the invention relates to a high-gradient magnetic filter for separating weakly magnetizable particles from liquid media, whose operation is derived from the physical principle of generating field strength gradients by introducing a ferromagnetic structure into a magnetic field.
- the invention further relates to a method for operating the high-gradient magnetic filter.
- Such a device is already in the DE 33 12 207 A1 described.
- This contains fixed chambers which are filled with a magnetizable ferromagnetic filling compound.
- a magnetizable ferromagnetic filling compound For the supply and discharge of a liquid medium nozzles are provided.
- Each pair of chambers has a common magnetization arrangement, the magnetic conductor consists of two opposing parts, which on different sides of a are arranged through the middle of these chambers continuous line.
- Each such part includes a magnet with pole pieces diametrically disposed on the chambers in the direction transverse to the line passing through the centers of the chambers, whereby these two parts, together with the ferromagnetic filter filling masses form a closed magnetic circuit.
- the disadvantage here is the still considerable space of the device and the complicated process for the separation of the ferromagnetic materials from the liquid media.
- a high gradient magnetic separator having a magnetic unit of two poles which together form a space in which a homogeneous magnetic field can be generated, with a matrix frame which is allowed to rotate about an axis and at least partially an annular one by partitions encloses divided into segments interior space, and at least one inflow and a drain line.
- the object of this invention is to increase the path of the fluid within the magnetic field. This is achieved in that the width of the magnetic unit along the interior corresponds to at least the width of two segments and in the region of the gap each segment of the annular interior is connected to its adjacent segments via an opening in each case, wherein the openings alternately at a first and a second, the first non-opposite location are attached.
- the magnetic field is also built up by permanent magnets, which already allow to make the separator smaller and cheaper and to reduce operating costs.
- This device has the disadvantage that the permanent magnets for the required backwashing can not be turned off.
- the arranged in a carousel filter chambers are therefore cyclically rotated after the filtering process in the magnetic field from the magnetic field area and rinsed in the field-free zone. Subsequently, the filter chambers are rotated back into the magnetic field and again charged with the liquid to be cleaned until the filter is added and a further backwashing must be done outside the magnetic field.
- Such a carousel separator requires a structural design that must provide many moving parts and especially numerous seals. This leads to wear and leaks and thus to a considerable maintenance and repair effort, which is e.g. is unacceptable in a municipal sewage plant.
- the invention has for its object to provide a high-gradient magnetic filter for separating weakly magnetizable particles from liquid media, which - using a permanent magnet for generating the magnetic field - is a compact, maintenance and low-repair assembly, the process of separation of the particles simply designed and the permanent magnet for the required backwashing makes ineffective.
- the variety of parts or number should be further reduced and the sealing problem eliminated.
- the method according to the invention for operating the high-gradient magnetic filter is intended to ensure efficient use thereof.
- the invention can be realized functionally in two variants according to claims 6 to 8 or 9.
- the one variant provides to form the permanent magnet as a rotor and rotatably arranged in the correspondingly shaped part of the iron circle.
- the angle of rotation of the rotor is adjustable so that the field strength between the pole pieces from a minimum to a maximum field strength value can be selected in order to adjust the field strength of the different materials of the particles to be separated. It is also possible to adjust the angular position of the rotor, e.g. 90 ° or in other angular steps to lock.
- the other variant of the invention is to form the permanent magnet as a linearly displaceable piece in the correspondingly shaped part of the iron circle.
- the method according to claim 25 can be operated efficiently by the use of a program for controlling the clocks of the advancing and returning medium or flushing medium in operative connection with the magnetic field to be switched on and off and the magnetic field strength to be set, the program also performing the functions according to FIGS Features of claims 26 to 28 includes.
- the high-gradient magnetic filter according to the invention consists in its essential structure of a housing 1, in which a pipe system for guiding a liquid medium 2 (arrows), are separated from the weakly magnetizable particles, with a flow 3 and a Return 4 is provided.
- a pipe system for guiding a liquid medium 2 arrows
- unillustrated means are used, e.g. belonging to the general state of the art valve control blocks that control the respective flow 3 and return 4 of the medium 2 in a mutual circulation.
- an iron circle 5 in which a filter 8, which is flowed through by the medium 2, is located in a filter chamber 7 formed between pole shoes 6 of the iron circle 5.
- a permanent magnet 9 is arranged, which generates a magnetic field between the pole pieces 6 in the state shown in FIG. 1 and thus passes through the filter 8.
- the entire part of the iron circuit 5 is always separated from the liquid medium 2 and thus sealed, wherein the pipe system with the flow 3 and return 4 is space-saving enclosed by the iron circuit 5.
- FIGS. 1 and 2 the variant of the invention is shown with a permanent magnet 9 designed as a rotor 10.
- the rotor 10 is equipped with Einzelpermanentmagneten 12 of FIG. 4.
- Fig. 5 shows the schematic representation of a drive 13 for the rotor 10, with which this shuts off the magnetic field ( Figure 2) and turns on ( Figure 1).
- the rotor 10 is provided with an axle 14 slidably and rotatably received in bearings 15 ( Figure 6).
- the angle of rotation of the rotor 10 can be adjusted so that the acting field strength between the pole pieces 6 from a minimum to a maximum field strength value is selectable. This makes it possible to largely adapt the field strength acting on the different materials of the particles, and the separation effect can be influenced. If it is expedient, the rotor 10 can also be rotated 90 ° or in other angular steps and locked.
- FIG. 7 shows the iron circuit 5 as a rotor 10, wherein throughput and efficiency can be increased by the linearly displaceable piece 11 as a permanent magnet 9, if this corresponds to a correspondingly designed or arranged iron circle 5 and at least two filters 8, each with a magnetic field provided.
- the cycles of the advancing and returning medium 2 or flushing medium can be controlled in the mutual circulation in operative connection with the magnetic field to be switched on and off and the magnetic field strength to be set for all design and process variants.
- the method is tunable with the features described in claims 26 to 28 both complex and variable for different applications.
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- Filtration Of Liquid (AREA)
- Filtering Materials (AREA)
- Centrifugal Separators (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Soft Magnetic Materials (AREA)
Abstract
Description
Die Erfindung betrifft einen Hochgradienten-Magnetfilter zum Abtrennen von schwach magnetisierbaren Partikeln aus flüssigen Medien, dessen Funktionsweise aus dem physikalischen Prinzip der Generierung von Feldstärkengradienten durch das Einbringen einer ferromagnetischen Struktur in ein Magnetfeld abgeleitet ist. Die Erfindung betrifft ferner ein Verfahren zum Betreiben des Hochgradienten-Magnetfilters.The invention relates to a high-gradient magnetic filter for separating weakly magnetizable particles from liquid media, whose operation is derived from the physical principle of generating field strength gradients by introducing a ferromagnetic structure into a magnetic field. The invention further relates to a method for operating the high-gradient magnetic filter.
Es hat sich bei derartigen Filtern durchgesetzt, das erforderliche Magnetfeld durch Permanentmagnete zu erzeugen, um die Baueinheiten raumsparender und kostengünstiger herstellen sowie energiesparender gegenüber den Filtern mit Elektromagneten betreiben zu können.It has prevailed in such filters, to generate the required magnetic field by permanent magnets to produce the units space-saving and cost-effective and to operate more energy efficient compared to the filters with electromagnets.
Eine derartige Einrichtung ist schon in der
Nachteilig sind hierbei der noch erhebliche Bauraum der Einrichtung und der komplizierte Ablauf zur Aussonderung der ferromagnetischen Werkstoffe aus den flüssigen Medien.The disadvantage here is the still considerable space of the device and the complicated process for the separation of the ferromagnetic materials from the liquid media.
Weiterhin ist gemäß der
Das Magnetfeld wird dabei auch von Permanentmagneten aufgebaut, die es schon gestatten, den Separator kleiner und kostengünstiger herzustellen und die Betriebskosten zu senken.The magnetic field is also built up by permanent magnets, which already allow to make the separator smaller and cheaper and to reduce operating costs.
Diese Einrichtung hat den Nachteil, daß sich die Permanentmagnete für den erforderlichen Rückspülvorgang nicht ausschalten lassen. Die in einem Karussell angeordneten Filterkammern werden deswegen nach dem Filtervorgang im Magnetfeld zyklisch aus dem Magnetfeldbereich gedreht und in der feldfreien Zone gespült. Anschließend werden die Filterkammern wieder ins Magnetfeld gedreht und erneut mit der zu reinigenden Flüssigkeit beaufschlagt, bis das Filter zugesetzt ist und ein weiterer Rückspülvorgang außerhalb des Magnetfeldes erfolgen muß.This device has the disadvantage that the permanent magnets for the required backwashing can not be turned off. The arranged in a carousel filter chambers are therefore cyclically rotated after the filtering process in the magnetic field from the magnetic field area and rinsed in the field-free zone. Subsequently, the filter chambers are rotated back into the magnetic field and again charged with the liquid to be cleaned until the filter is added and a further backwashing must be done outside the magnetic field.
Ein solcher Karussellseparator erfordert einen konstruktiven Aufbau, der viele bewegte Teile und vor allem zahlreiche Dichtungen vorsehen muß. Dies führt zu Verschleiß und Undichtigkeiten und damit zu einem erheblichen Wartungs- und Reparaturaufwand, was z.B. in einer kommunalen Abwasseranlage unvertretbar ist.Such a carousel separator requires a structural design that must provide many moving parts and especially numerous seals. This leads to wear and leaks and thus to a considerable maintenance and repair effort, which is e.g. is unacceptable in a municipal sewage plant.
Bei einem weiteren Hochgradienten-Magnetseparator entsprechend dem DE-GM 297 23 852.3 ist zumindest das Dichtungsproblem behoben. Dabei werden nicht die einzelnen Filterkammern in das Magnetfeld hinein- und wieder herausbewegt. Das Filtersystem steht fest, und ein Magnet wird mechanisch hin- und herbewegt, um den Filtervorgang bzw. das Rückspülen einzuleiten. Jedoch sind auch hier viele bewegte Teile erforderlich.In another high-gradient magnetic separator according to DE-GM 297 23 852.3 at least the sealing problem is resolved. In this case, the individual filter chambers are not moved into and out of the magnetic field. The filter system is fixed and a magnet is mechanically reciprocated to initiate the filtering process or backwashing. However, many moving parts are required here as well.
Schließlich bleibt ein neu entwickelter Hochgradienten-Magnetabscheider, wie er in der
Neben dieser als Hochgradienten-Magnetabscheider zu definierenden, relativ neuartigen Gattung sind so genannte ältere Starkfeldscheider bekannt. Ein derartiger Starkfeldscheider ist beispielsweise der
- Die Sieb-/Rostfläche weist quer zu den Magnetsystemen und/oder von einem Magnetsystem zum anderen sich erstreckende Drähte oder Stäbe auf und
- der Eisenquerschnitt ist übersättigt, wobei
- eine gleichmäßige Verteilung der Feldstärke an der Oberfläche des Siebes/Rostes für eine gleichmäßige Abscheidung sorgen soll.
- The sieve / grate surface has wires or rods extending transversely to the magnet systems and / or from one magnet system to another
- the iron cross-section is supersaturated, with
- a uniform distribution of the field strength at the surface of the screen / grid should ensure a uniform deposition.
Allein schon diese Bauart und Charakterisierung lässt eine Verwendung als Hochgradienten-Magnetabscheider nicht zu, weil
- eine hohe Feldkonzentration nicht realisierbar ist,
- die Gefahr einer bleibenden Magnetisierung besteht,
- die zwei Magnetrotoren an den Seiten eine kompakte Bauweise verhindern,
- die Reinigung bestenfalls durch zusätzliche und aufwändige z. B. Brauseeinrichtungen erfolgen soll und
- ein im eigentlichen Sinne ein konsruktiv und technologisch zu integrierendes Spülsystem noch gar nicht angesprochen ist.
- a high field concentration is not feasible,
- the danger of permanent magnetization exists,
- the two magnet rotors on the sides prevent a compact design,
- the cleaning at best by additional and elaborate z. B. shower facilities and should
- a flushing system that is in the true sense a brewing and technologically to be integrated is not even addressed.
Daraus ergibt sich für den Fachmann hinsichtlich der einzuschlagenden Entwicklungsrichtung, daß die aus diesem Stand der Technik sich ergebenden Nachteile, wie
- eine Übersättigung des Eisenquerschnitts ,
- der geschlossene Magnetkreis,
- die unvorteilhafte Verteilung des magnetischen Feldes
- a supersaturation of the iron cross section,
- the closed magnetic circuit,
- the unfavorable distribution of the magnetic field
Der Erfindung liegt die Aufgabe zugrunde, einen Hochgradienten-Magnetfilter zum Abtrennen von schwach magnetisierbaren Partikeln aus flüssigen Medien zu schaffen, der - unter Verwendung eines Permanentmagneten zur Erzeugung des Magnetfeldes - eine kompakte, wartungs- sowie reparaturarme Baueinheit darstellt, den Ablauf der Abtrennung der Partikel einfach gestaltet und den Permanentmagneten für den erforderlichen Rückspülvorgang unwirksam macht. Dabei sollen die Teilevielfalt bzw. -anzahl weiter reduziert und das Dichtungsproblem beseitigt werden. Das erfindungsgemäße Verfahren zum Betreiben des Hochgradienten-Magnetfilters soll eine effiziente Anwendung desselben sichern.The invention has for its object to provide a high-gradient magnetic filter for separating weakly magnetizable particles from liquid media, which - using a permanent magnet for generating the magnetic field - is a compact, maintenance and low-repair assembly, the process of separation of the particles simply designed and the permanent magnet for the required backwashing makes ineffective. The variety of parts or number should be further reduced and the sealing problem eliminated. The method according to the invention for operating the high-gradient magnetic filter is intended to ensure efficient use thereof.
Nach dem Anspruch 1 wird dies dadurch gelöst, daß der Hochgradienten-Magnetfilter entsprechend der Aufgabe umfaßt
- ein den Hochgradienten-Magnetfilter aufnehmendes Gehäuse mit Mitteln zur Führung des flüssigen Mediums in einem Rohrsystem mit Vorlauf und Rücklauf,
- einen den eigentlichen Hochgradienten-Magnetfilter bildenden Eisenkreis, in dem sich in einer, zwischen Polschuhen des Eisenkreises ausgebildeten Filterkammer ein Filter befindet, das von dem zu reinigenden Medium durchströmt wird,
- mindestens einen in dem Eisenkreis angeordneten Permanentmagneten zur Erzeugung des Magnetfeldes zwischen den Polschuhen, wobei dieser Teil des Eisenkreises zu dem flüssigen Medium getrennt und somit abgedichtet ist, und
- das Magnetfeld zwischen den Polschuhen, welches mittels des Permanentmagneten abschaltbar und wieder einschaltbar ist,
- a high-gradient magnetic filter receiving housing with means for guiding the liquid medium in a piping system with flow and return,
- an iron circuit forming the actual high-gradient magnetic filter, in which a filter is located in a filter chamber formed between pole shoes of the iron circuit and through which the medium to be cleaned flows;
- at least one arranged in the iron circle permanent magnet for generating the magnetic field between the pole pieces, said part of the iron circuit is separated and thus sealed to the liquid medium, and
- the magnetic field between the pole shoes, which can be switched off and switched on again by means of the permanent magnet,
Mit den Merkmalen der Ansprüche 2 bis 5 ist das erfindungsgemäße Konzept weiter ausgestaltet.With the features of
Die Erfindung kann gemäß den Ansprüchen 6 bis 8 oder 9 funktionell in zwei Varianten realisiert werden.The invention can be realized functionally in two variants according to
Die eine Variante sieht vor, den Permanentmagneten als Rotor auszubilden und in dem entsprechend ausgeformten Teil des Eisenkreises drehbar anzuordnen. Dabei ist der Drehwinkel des Rotors so einstellbar, daß die Feldstärke zwischen den Polschuhen von einem minimalen bis zu einem maximalen Feldstärkewert gewählt werden kann, um die Feldstärke den unterschiedlichen Materialien der abzutrennenden Partikel anpassen zu können. Es ist auch möglich, die Winkelstellung des Rotors z.B. 90°-weise oder in anderen Winkelschritten zu arretieren.The one variant provides to form the permanent magnet as a rotor and rotatably arranged in the correspondingly shaped part of the iron circle. The angle of rotation of the rotor is adjustable so that the field strength between the pole pieces from a minimum to a maximum field strength value can be selected in order to adjust the field strength of the different materials of the particles to be separated. It is also possible to adjust the angular position of the rotor, e.g. 90 ° or in other angular steps to lock.
Die andere Variante der Erfindung besteht darin, den Permanentmagneten als linear verschiebbares Stück in dem entsprechend ausgeformten Teil des Eisenkreises auszubilden.The other variant of the invention is to form the permanent magnet as a linearly displaceable piece in the correspondingly shaped part of the iron circle.
Für diese Varianten der Erfindung sind die zweckmäßigen Ausführungen den Merkmalen der Ansprüche 10 bis 20 zu entnehmen.For these variants of the invention, the expedient embodiments of the features of
Das erfindungsgemäße Verfahren zum Betreiben des Hochgradienten-Magnetfilters entsprechend den Schritten der Ansprüche 21 oder 22 erfolgt so, daß das Abtrennen der schwach magnetisierbaren Partikel aus dem flüssigen Medium wechselseitig im Rohrsystem aufgabengemäß nach den Schritten
- a) Beaufschlagung des Filters mit dem zu separierenden Medium über das Rohrsystem mit Vorlauf und Rücklauf bei eingeschaltetem Magnetfeld im Eisenkreis zwischen den Polschuhen und Durchsetzung des Magnetfeldes in der vom Medium durchspülten Filterkammer am Filter, wobei sich infolge der hohen Feldgradienten am Filter die magnetisierbaren Partikel anlagern und dabei die Feldstärke entsprechend der Winkelstellung des Permanentmagneten unterschiedlich stark einstellbar ist, danach
- b) Abschalten des Magnetfeldes des Permanentmagneten
realisiert wird, wonach erfindungsgemäß - c) die Entfernung der angelagerten und separierten Partikel vom Filter in einem Spülvorgang als Gegenstromverfahren oder auch als Gleichstromverfahren erfolgt und
- d) eine Wiederholung der Schrittfolge a), b) und c) bis zur Beendigung der Abtrennung der Partikel aus dem flüssigen Medium abläuft.
- a) loading the filter with the medium to be separated via the pipe system with flow and return with the magnetic field in the iron circuit between the pole pieces and enforcement of the magnetic field in the purged by the medium filter chamber on the filter, which accumulate due to the high field gradients on the filter, the magnetizable particles and while the field strength is set to different degrees according to the angular position of the permanent magnet, thereafter
- b) switching off the magnetic field of the permanent magnet
is realized, according to the invention - c) the removal of the accumulated and separated particles from the filter in a flushing process as a countercurrent process or as a DC process and takes place
- d) a repetition of the sequence of steps a), b) and c) until completion of the separation of the particles from the liquid medium takes place.
Das Verfahren ist entsprechend den Merkmalen der Ansprüche 23 oder 24 hinsichtlich des Mediums bzw. der Medien unterschiedlich ausgestaltungsfähig.The method is according to the features of claims 23 or 24 with respect to the medium or the media differently ausgestaltungsfähig.
Weiterhin kann das Verfahren nach Anspruch 25 durch die Verwendung eines Programms zur Steuerung der Takte des vor- und rücklaufenden Mediums bzw. Spülmediums in Wirkverbindung mit dem ein- und auszuschaltenden Magnetfeld und der einzustellenden Magnetfeldstärke effizient betrieben werden, wobei das Programm auch die Funktionen gemäß den Merkmalen der Ansprüche 26 bis 28umfaßt.Furthermore, the method according to claim 25 can be operated efficiently by the use of a program for controlling the clocks of the advancing and returning medium or flushing medium in operative connection with the magnetic field to be switched on and off and the magnetic field strength to be set, the program also performing the functions according to FIGS Features of claims 26 to 28 includes.
Die Erfindung wird an Ausführungsbeispielen erläutert.The invention will be explained with reference to exemplary embodiments.
In den Zeichnungen zeigen
- Fig. 1
- den erfindungsgemäßen Hochgradienten-Magnetfilter in vereinfachter Darstellung im
durch den Rotor 10 eingeschalteten Zustand, - Fig. 2
- den Hochgradienten-Magnetfilter nach Fig. 1 im ausgeschalteten Zustand,
- Fig. 3
- die Erfindungsvariante mit schematischer Darstellung des
Permanentmagneten 9 als linear verschiebbares Stück 11, - Fig.4
- die schematische Darstellung des
Rotors 10mit dem Permanentmagneten 9aus Einzelpermanentmagneten 12, - Fig. 5
- die schematische Darstellung des
Rotors 10mit Antrieb 13, - Fig. 6
- das Prinzip der Lagerung des
Rotors 10 und - Fig. 7
- das Prinzip einer erfindungsgemäßen Doppelausführung
mit zwei Filtern 8 und einemRotor 10.
- Fig. 1
- the high-gradient magnetic filter according to the invention in a simplified representation in the state switched on by the
rotor 10, - Fig. 2
- the high-gradient magnetic filter of Figure 1 in the off state,
- Fig. 3
- the variant of the invention with a schematic representation of the
permanent magnet 9 as a linearlydisplaceable piece 11, - Figure 4
- the schematic representation of the
rotor 10 with thepermanent magnet 9 ofEinzelpermanentmagneten 12, - Fig. 5
- the schematic representation of the
rotor 10 withdrive 13, - Fig. 6
- the principle of storage of the
rotor 10 and - Fig. 7
- the principle of a double embodiment according to the invention with two
filters 8 and a rotor 10th
Entsprechend den Fig. 1 und 2 besteht der erfindungsgemäße Hochgradienten-Magnetfilter in seinem wesentlichen Aufbau aus einem Gehäuse 1, in dem ein Rohrsystem zur Führung eines flüssigen Mediums 2 (Pfeile), aus dem schwach magnetisierbare Partikel abzutrennen sind, mit einem Vorlauf 3 und einem Rücklauf 4 vorgesehen ist. Dazu werden nicht dargestellte Mittel verwendet, wie z.B. zum allgemeinen Stand der Technik gehörende Ventilsteuerblöcke, die den jeweiligen Vorlauf 3 und Rücklauf 4 des Mediums 2 in einem wechselseitigen Umlauf steuern.1 and 2, the high-gradient magnetic filter according to the invention consists in its essential structure of a
Innerhalb des Gehäuses 1 befindet sich ein Eisenkreis 5, in dem sich in einer zwischen Polschuhen 6 des Eisenkreises 5 ausgebildeten Filterkammer 7 ein Filter 8 befindet, das von dem Medium 2 durchströmt wird. In dem Eisenkreis ist ein Permanentmagnet 9 angeordnet, der im gemäß Fig. 1 eingeschalteten Zustand ein Magnetfeld zwischen den Polschuhen 6 erzeugt und damit das Filter 8 durchsetzt.Within the
Der gesamte Teil des Eisenkreises 5 ist zu dem flüssigen Medium 2 stets abgetrennt und somit abgedichtet, wobei das Rohrsystem mit dem Vorlauf 3 und Rücklauf 4 raumsparend durch den Eisenkreis 5 umschlossen wird.The entire part of the
In den Fig. 1 und 2 ist die Erfindungsvariante mit einem als Rotor 10 ausgebildeten Permanentmagneten 9 dargestellt. Der Rotor 10 ist mit Einzelpermanentmagneten 12 gemäß Fig. 4 bestückt. Fig. 5 zeigt die schematische Darstellung eines Antriebs 13 für den Rotor 10, mit dem dieser das Magnetfeld abschaltet (Fig.2) und einschaltet (Fig.1). Zweckmäßigerweise ist der Rotor 10 mit einer Achse 14 versehen, die in Lagern 15 gleitend und drehbar aufgenommen ist (Fig. 6).In FIGS. 1 and 2, the variant of the invention is shown with a
Die Erfindungsvariante mit dem Permanentmagneten 9 als linear verschiebbares Stück 11, welches z. B. gleitend gelagert und über einen nicht dargestellten Antrieb das Magnetfeld ein- und wieder abschaltet, ist in Fig. 3 schematisch dargestellt, wobei die Gestaltung dieses Hochgradienten-Magnetfilters sich in Analogie zu den Fig. 1 und 2 ergeben kann.The variant of the invention with the
Nach diesem konstruktiven Grundaufbau, in welchem das erfindungsgemäße Rohrsystem zum umgekehrt gerichteten Spülen des Filters (8) bei abgeschaltetem Magnetfeld vorgesehen ist, sind vorteilhafte Ausführungen möglich, die je nach Verwendungszweck und Wirkungsgrad realisiert und sich wie folgt darstellen können:According to this constructive basic structure, in which the pipe system according to the invention is provided for reversely purging the filter (8) with the magnetic field switched off, advantageous embodiments are possible, which are realized depending on the intended use and efficiency and can be represented as follows:
Je nach der Beschaffenheit der abzutrennenden, schwachmagnetisierbaren Partikel aus den flüssigen Medien 2, kann der Drehwinkel des Rotors 10 so eingestellt werden, daß die wirkende Feldstärke zwischen den Polschuhen 6 von einem minimalen bis zu einem maximalen Feldstärkewert wählbar ist. Damit ist eine weitgehende Anpassung der auf die unterschiedlichen Materialien der Partikel einwirkenden Feldstärke möglich, und der Trenneffekt ist beeinflußbar. Wenn es zweckmäßig ist, kann der Rotor 10 auch 90°-weise oder in anderen Winkelschritten gedreht und arretiert werden.Depending on the nature of the separated, weakly magnetizable particles from the
Um den Durchsatz und Wirkungsgrad erfindungsgemäßer Hochgradienten-Magnetfilter zu erhöhen sowie den spezifischen Bauaufwand zu senken, wird die Ausbildung gemäß der Fig. 7 vorgeschlagen, bei der der Eisenkreis 5 so gestaltet ist, daß zwei Filter 8 vorgesehen sind, die von einem Permanetmagneten 9 gleichzeitig mit je einem Magnetfeld im eingeschalteten Zustand beaufschlagt oder ausgeschaltet sind. Fig. 7 zeigt dabei den Permanentmagneten 9 als Rotor 10, wobei Durchsatz und Wirkungsgrad auch durch das linear verschiebbare Stück 11 als Permanentmagnet 9 erhöhbar sind, wenn dieses in einem entsprechend gestalteten bzw. angeordneten Eisenkreis 5 korrespondiert und mindestens zwei Filter 8 mit je einem Magnetfeld versorgt.In order to increase the throughput and efficiency of high-gradient magnetic filter according to the invention and to reduce the specific construction cost, the embodiment according to FIG. 7 is proposed in which the
Das erfindungsgemäße Verfahrensprinzip zum Betreiben aller denkbaren, in den Ansprüchen 1 bis 20 erfaßten erfindungsgemäßen Konstruktionsvarianten sieht vor, daß das Abtrennen der schwach magnetisierbaren Partikel aus dem flüssigen Medium 2 wechselseitig im Rohrsystem nach folgenden Schritten entsprechend den Ansprüchen 21 bis 24 abläuft:
- 1. In der ersten Schrittfolge wird
mindestens ein Filter 8 mit dem zu separierenden flüssigen Medium 2 über das Rohrsystem beaufschlagt. Das Rohrsystem ist ineinem Vorlauf 3 und einem Rücklauf 4 wechselseitig anwendbar, wobei in dieser ersten Schrittfolge bei eingeschaltetem Magnetfeldim Eisenkreis 5 zwischen den Polschuhen 6 z. B. gemäß Fig. 1der Vorlauf 3 und der Rücklauf 4 des flüssigen und zu reinigendenMediums 2 dargestellt sind. Dabei durchsetzt das Magnetfeldden vom Medium 2 mittels des Rohrsystems durchspültenFilter 8, welches z.B. aus einem magnetisierbaren Drahtgewebe besteht. Infolge der hohen Feldgradientenam Filter 8 lagern sich die magnetisierbaren Partikel im Drahtgewebe an. Die Feldstärke kann entsprechend der Drehung (Rotor 10) oder Verschiebung (linear verschiebbares Stück 11) desPermanetmagneten 9 unterschiedlich stark eingestellt werden. - 2. Danach wird in der weiteren Schrittfolge das Magnetfeld des Permanentmagneten 9 (
Rotor 10 / linear verschiebbares Stück 11) abgeschaltet. Das oderein Medium 2 mit einem nun umgekehrt gerichteten Vorlauf 3 und Rücklauf 4 (z.B. entsprechend der Fig. 2) entfernt die am Drahtgewebe desFilters 8 angelagerten und separierten Partikel in einem Spülvorgang. Diese Spülung ist in mehreren Variationen durchführbar, indem z.B.- ein zu reinigendes und von den Partikeln zu befreiendes
Medium 2 als Spülmedium oder - ein separates
Medium 2 als Spülmedium
Ventilsteuerung im Vorlauf 3 und Rücklauf 4 verwendet werden. - ein zu reinigendes und von den Partikeln zu befreiendes
- 3. Wiederholung dieser vorbeschriebenen Schrittfolgen im ständigen wechselseitigen Umlauf,
wobei das Filter 8 je nach Zustand oder Verbrauch aus der Filterkammer 7 herausnehmbar oder austauschbar ist, um es z. B. zu ersetzen.
- 1. In the first step sequence, at least one
filter 8 is acted upon by theliquid medium 2 to be separated via the pipe system. The pipe system is in oneFlow 3 and areturn 4 mutually applicable, in this first step sequence when the magnetic field in theiron circuit 5 between the pole pieces 6 z. B. of FIG. 1, theflow 3 and thereturn 4 of the liquid and to be cleaned medium 2 are shown. In this case, the magnetic field passes through the flushed by themedium 2 by means of thepipe system filter 8, which consists for example of a magnetizable wire mesh. As a result of the high field gradients on thefilter 8, the magnetizable particles deposit in the wire mesh. The field strength can be set to different degrees according to the rotation (rotor 10) or displacement (linearly displaceable piece 11) of thepermanent magnet 9. - 2. Thereafter, in the further step sequence, the magnetic field of the permanent magnet 9 (
rotor 10 / linearly displaceable piece 11) is turned off. The or a medium 2 with a now reversely directedflow 3 and return 4 (eg, corresponding to FIG. 2) removes the deposited on the wire cloth of thefilter 8 and separated particles in a rinsing process. This conditioner is feasible in several variations, eg- a to be cleaned and freed from the
particles medium 2 as a flushing medium or - a
separate medium 2 as flushing medium
flow 3 andreturn 4. - a to be cleaned and freed from the
- 3. Repetition of these above-described sequences of steps in the constant mutual circulation, wherein the
filter 8 is removable or replaceable depending on the state or consumption of thefilter chamber 7 to make it z. B. to replace.
Beide Variationen sind im Gegenstrom- (Anspruch 21 b)) oder im Gleichstromverfahren (Anspruch 22) baulich ausführbar.Both variations are structurally executable in Gegenstrom- (claim 21 b)) or in the DC method (claim 22).
Mit einem Programm nach Anspruch 25 können die Takte des vor- und rücklaufenden Mediums 2 bzw. Spülmediums in dem wechselseitigen Umlauf in Wirkverbindung mit dem ein- und abzuschaltenden Magnetfeld und der einzustellenden Magnetfeldstärke für sämtliche Konstruktions- und Verfahrensvarianten gesteuert werden.With a program according to claim 25, the cycles of the advancing and returning medium 2 or flushing medium can be controlled in the mutual circulation in operative connection with the magnetic field to be switched on and off and the magnetic field strength to be set for all design and process variants.
Das Verfahren ist mit den in den Ansprüchen 26 bis 28 beschriebenen Merkmalen sowohl komplex als auch variabel für die unterschiedlichen Anwendungszwecke abstimmbar.The method is tunable with the features described in claims 26 to 28 both complex and variable for different applications.
Das erfindungsgemäße Konstruktions- und Verfahrensprinzip zeichnet sich in seiner gewerblichen Anwendung dadurch aus, daß
- einerseits eine kompakte, wartungs- sowie reparaturarme Baueinheit mit für die Wartung vorteilhaft austauschbaren Baugruppen geschaffen wird und
- andererseits der Ablauf und der Betrieb der Abtrennung der Partikel aus flüssigen Medien einfach sowie kostengünstig durchgeführt werden können, wobei
- schließlich die beschriebenen Nachteile des Standes der Technik beseitigt sind und eine vielfältige Anwendung in verschiedenen einschlägigen Industrien möglich wird.
- on the one hand, a compact, low-maintenance and low-repair assembly with advantageously exchangeable for maintenance assemblies is provided and
- On the other hand, the course and operation of the separation of the particles from liquid media can be carried out simply and inexpensively, wherein
- Finally, the disadvantages of the prior art described are eliminated and a variety of applications in various relevant industries is possible.
- 1 =1 =
- Gehäusecasing
- 2 =2 =
- Flüssiges MediumLiquid medium
- 3 =3 =
- Vorlaufleader
- 4 =4 =
- Rücklaufreturns
- 5 =5 =
- Eisenkreisiron circuit
- 6 =6 =
- Polschuhpole
- 7 =7 =
- Filterkammerfilter chamber
- 8 =8 =
- Filterfilter
- 9 =9 =
- Permanentmagnetpermanent magnet
- 10 =10 =
- Rotorrotor
- 11 =11 =
- linear verschiebbares Stücklinearly displaceable piece
- 12 =12 =
- EinzelperrnanentmagnetEinzelperrnanentmagnet
- 13 =13 =
- Antriebdrive
- 14 =14 =
- Achseaxis
- 15 =15 =
- Lagercamp
- N =N =
- NordpolNorth Pole
- S =S =
- SüdpolSouth Pole
Claims (28)
- A high-gradient magnetic filter for separating weakly magnetisable particles of liquid media (2) in a circulation, comprising- a housing (1) with means for guiding the liquid medium (2) in a pipe system with feed (3) and return (4),- an iron circuit (5), accommodated in the housing (1), in which circuit is located at least one (filter) in a filter chamber (7) formed between pole shoes (6) of the iron circuit (5), through which filter flows the medium (2) to be cleaned, and- at least one permanent magnet (9) arranged in the iron circuit (5) for generating a magnetic field between the pole shoes (6), wherein the iron circuit (5) is separate and therefore sealed from the liquid medium (2),wherein the magnetic field between the pole shoes (6) can be switched off and on again alternately by means of the permanent magnet (9),
characterised by a pipe system for washing the filter (8) in the opposite direction when the magnetic field is switched off. - The high-gradient magnetic filter according to Claim 1, characterised bya) device for feeding the medium (2) acted upon on both sides throughout the length of the filter (8), andb) a closed pipe system (3, 4) which is enclosed by the iron circuit (5).
- The high-gradient magnetic filter 1 or 2, characterised in that the length of the filter (8) is ≤ the length of the pole shoe (6).
- The high-gradient magnetic filter according to one of Claims 1 to 3, characterised in that the cross-sections of the connections of the filters (8) for the medium (2) are designed so that the filter is subjected to uniform flow of the medium (2) and the filter chamber (7) is suitably designed for this.
- The high-gradient magnetic filter according to one of Claims 1 to 4, characterised in that the housing (1) is designed as a frame for receiving a component for the pole system (5, 6) and for receiving a component for the pipe system (3, 4).
- The high-gradient magnetic filter according to one of Claims 1 to 5, characterised in that the permanent magnetic (9) is designed as a rotor (10) and is rotatably arranged in the suitably designed part of the iron circuit (5).
- The high-gradient magnetic filter according to Claim 6, characterised in that the angle of rotation of the rotor (10) can be set from a minimum to a maximum field strength value.
- The high-gradient magnetic filter according to Claim 6 or 7, characterised in that the angle of rotation of the rotor (10) can be set to 90°.
- The high-gradient magnetic filter according to Claim 1 to 5, characterised in that the permanent magnet (9) is designed as a linearly displaceable piece (11) in the suitably designed part of the iron circuit (5).
- The high-gradient magnetic filter according to one of Claims 1 to 9, characterised by such a design of the iron circuit (5) that at least two filters (8) are provided which are switched on or off by a permanent magnet (9) simultaneously or alternately in respect of each magnetic field that can be acted upon.
- The high-gradient magnetic filter according to one of Claims 1 to 10, characterised in that the permanent magnet (9) consists of a plurality of individual permanent magnets (12).
- The high-gradient magnetic filter according to one of Claims 1 to 11, characterised in that the permanent magnet (9) is connected to a drive (13).
- The high-gradient magnetic filter according to Claim 6, characterised in that the rotor (10) is mounted with its shaft (14) in bearings (15).
- The high-gradient magnetic filter according to Claim 9, characterised in that the linearly displaceable piece (11) is mounted in bearings.
- The high-gradient magnetic filter according to one of Claims 1 to 14, characterised in that the filter (8) consists of magnetisable wire fabric or magnetisable steel wool.
- The high-gradient magnetic filter according to one of Claims 1 to 14, characterised in that the filter (8) represents a cage with magnetisable material, such as wire fabric, steel wool or chips, enclosed therein.
- The high-gradient magnetic filter according to Claim 15, characterised in that the filter (8) can be removed from the filter chamber (7) or replaced.
- The high-gradient magnetic filter according to one of Claims 15 to 17, characterised in that the internal arrangement of the filter (8) is designed in such a manner, for optimising the separation, that the medium (2) flowing through it passes through the filter (8) in an alternating direction of flow.
- The high-gradient magnetic filter according to one of Claims 15 to 18, characterised in thata) means are provided in the filter (8) which guarantee the flow of the medium (2) at right angles or transversely to the entire surface of the magnetisable wire fabric, the magnetisable steel wool or chips, andb) the longitudinal axes of the individual components, such as wires of the wire fabric or steel wool, and of the chips, do not run in the direction of the magnetic field.
- The high-gradient magnetic filter according to one of Claims 15 to 19, characterised in that the filter (8) consists of a plurality of individual filters (8).
- A method for operating a high-gradient magnetic filter according to Claim 1, wherein the separation of the weakly magnetisable particles from the liquid medium takes place alternately in the pipe system according to the following steps:a) loading of at least one filter (8) with the liquid medium (2) to be separated via the pipe system in a feed (3) and a return (4) when the magnetic field is switched on in the iron circuit (5) between the pole shoes (6) and dispersion of the magnetic field in the filter chamber (7) of the filter (8) through which the medium (2) flushes, wherein the magnetisable particles are taken up due to the high field gradient on the filter (8), and wherein the field strength can be set to different values according to the rotation or displacement of the permanent magnet (9), thenb) switching off of the magnetic field of the permanent magnet (9)
characterised byc) removal of the particles taken up and separated from the filter (8) in a flushing process as a counterflow with feed (3) and return (4) in the opposite direction, andd) repetition of step sequence a), b) and c) until the end of separation of the particles from the liquid medium (2). - The method according to Claim 21, characterised in that the flushing process takes place in the direct current, wherein the step sequence is determined by- the flushing medium (2) feed- the contaminated flushing medium (2) return.
- The method according to Claim 21 or 22, characterised by the use of the medium (2) to be cleaned and to be released from the particles as flushing medium.
- The method according to Claim 21 or 22, characterised by the use of a separate medium (2) as flushing medium.
- The method according to Claims 13 to 15, characterised by the use of a programme for controlling the cycle of the feeding and returning medium (2) or flushing medium in actuating connection with the magnetic field to be switched on and off and the magnetic field strength to be set.
- The method according to one of Claims 21 to 25, characterised in that before the absorption capacity of the filter (8) is reached it is switched off.
- The method according to one of Claims 21 to 26, characterised in that if a plurality of filters (8) is used, at least one is switched for accumulation of the particles and at least another is switched for the flushing process.
- The method according to one of Claims 21 to 27, characterised in that the control of the cycles is switched as a function of a time and/or a differential pressure.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10117659 | 2001-04-09 | ||
| DE10117659A DE10117659C2 (en) | 2001-04-09 | 2001-04-09 | High gradient magnetic filter and method for separating weakly magnetizable particles from liquid media |
| PCT/DE2002/001225 WO2002081092A1 (en) | 2001-04-09 | 2002-04-04 | High-gradient magnetic filter and method for the separation of weakly magnetisable particles from fluid media |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1377381A1 EP1377381A1 (en) | 2004-01-07 |
| EP1377381B1 true EP1377381B1 (en) | 2007-06-13 |
Family
ID=7680946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02727286A Expired - Lifetime EP1377381B1 (en) | 2001-04-09 | 2002-04-04 | High-gradient magnetic filter and method for the separation of weakly magnetisable particles from fluid media |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7223345B2 (en) |
| EP (1) | EP1377381B1 (en) |
| JP (1) | JP4334230B2 (en) |
| CN (1) | CN100493725C (en) |
| AT (1) | ATE364448T1 (en) |
| DE (2) | DE10117659C2 (en) |
| WO (1) | WO2002081092A1 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10331254B4 (en) * | 2003-07-10 | 2006-05-04 | Chemagen Biopolymer-Technologie Aktiengesellschaft | Apparatus and method for separating magnetic or magnetizable particles from a liquid |
| ES2264899B1 (en) | 2005-07-12 | 2008-01-01 | Centro De Investigacion De Rotacion Y Torque Aplicada, S.L. | FILTER TO CAPTURE POLLUTANT EMISSIONS. |
| US8556843B2 (en) * | 2008-02-02 | 2013-10-15 | AccelDx | Blood purification method and apparatus for the treatment of malaria |
| DE102008035695A1 (en) | 2008-07-30 | 2010-02-04 | Martin Lipsdorf | Particle e.g. sensitive target particle, processing method for use in biotechnology field, involves deflecting magnetic field of permanent magnet between flow paths of magnetic field by impulse at magneto electric control element |
| US9272290B2 (en) * | 2009-07-17 | 2016-03-01 | Koninklijke Philips N.V. | Apparatus for the enrichment of magnetic particles |
| WO2013027818A1 (en) | 2011-08-25 | 2013-02-28 | 宇部興産株式会社 | Mixture separation method and separation device |
| DE112014001626B4 (en) | 2013-03-25 | 2022-05-05 | Sumitomo Heavy Industries, Ltd. | Foreign body attracting structure |
| US10124282B2 (en) * | 2013-11-05 | 2018-11-13 | Eagle Industry Co., Ltd. | Filter device |
| US9387486B2 (en) * | 2014-09-30 | 2016-07-12 | Ut-Battelle, Llc | High-gradient permanent magnet apparatus and its use in particle collection |
| CN104923392A (en) * | 2015-06-18 | 2015-09-23 | 广州粤有研矿物资源科技有限公司 | Reversed type horizontal magnetic field vertical ring high-gradient magnetic separator |
| CN104959225A (en) * | 2015-07-23 | 2015-10-07 | 张甲禄 | Antipodal electromagnetic iron remover |
| CN105665128B (en) * | 2016-04-14 | 2017-10-03 | 河南理工大学 | A kind of permanent magnetism closed magnetic architecture for realizing high background lectromagnetism field |
| CN109842280A (en) * | 2017-11-24 | 2019-06-04 | 彭德正 | Height magnetization high gradient component power supply |
| WO2019221313A1 (en) | 2018-05-16 | 2019-11-21 | 케이퓨전테크놀로지 주식회사 | Underwater plasma generating apparatus |
| CN115069410B (en) * | 2022-06-29 | 2025-05-27 | 盐城象屿环资矿业科技有限公司 | A magnetic separator with high mineral capture capacity using non-uniform magnetic field gradient |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE904041C (en) * | 1952-06-10 | 1954-02-15 | Spodig Heinrich | Permanent magnet separator that can be switched on and off |
| GB796336A (en) | 1955-03-11 | 1958-06-11 | Blending Machine Company Ltd | Improvements relating to magnetic separators for fluent materials |
| DE1177091B (en) * | 1963-04-27 | 1964-09-03 | Kloeckner Humboldt Deutz Ag | Magnetic separator for fine-grained substances |
| DE3312207A1 (en) * | 1983-04-05 | 1984-10-11 | Ukrainskij institut inženerov vodnogo chozjajstva, Rovno | Device for separating ferromagnetic materials from liquid media |
| FR2544224B1 (en) | 1983-04-18 | 1988-01-08 | Uk I Inzh | MAGNETIC SEPARATOR FOR THE PURIFICATION OF FLUIDS CONTAINING FERROMAGNETIC PARTICLES |
| CN2031895U (en) * | 1988-04-22 | 1989-02-01 | 杨光 | Electric heater with water-purifying function |
| FR2655881B1 (en) * | 1989-12-20 | 1992-07-24 | Fives Cail Babcock | HIGH INTENSITY MAGNETIC SEPARATOR WORKING IN WET. |
| DE4314902C2 (en) * | 1993-05-05 | 1997-02-06 | Roesler Roland Oberflaechen | Drum magnetic separator with a fixed magnet system and demagnetizing device |
| DE19626999C1 (en) * | 1996-07-05 | 1997-08-21 | Karlsruhe Forschzent | High gradient magnet separator |
| DE29723852U1 (en) * | 1997-12-04 | 1999-05-20 | Forschungszentrum Karlsruhe GmbH, 76133 Karlsruhe | High gradient magnetic separator |
| DE19934427C1 (en) * | 1999-07-22 | 2000-12-14 | Karlsruhe Forschzent | Magnetic mineral particle separator has circular or elliptical passages improving separation process |
| GB0015304D0 (en) | 2000-06-23 | 2000-08-16 | Cellpath Plc | Improved medical sampler |
-
2001
- 2001-04-09 DE DE10117659A patent/DE10117659C2/en not_active Expired - Fee Related
-
2002
- 2002-04-04 DE DE50210315T patent/DE50210315D1/en not_active Expired - Lifetime
- 2002-04-04 US US10/473,714 patent/US7223345B2/en not_active Expired - Lifetime
- 2002-04-04 AT AT02727286T patent/ATE364448T1/en active
- 2002-04-04 WO PCT/DE2002/001225 patent/WO2002081092A1/en not_active Ceased
- 2002-04-04 EP EP02727286A patent/EP1377381B1/en not_active Expired - Lifetime
- 2002-04-04 CN CNB02807971XA patent/CN100493725C/en not_active Expired - Fee Related
- 2002-04-04 JP JP2002579124A patent/JP4334230B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN100493725C (en) | 2009-06-03 |
| JP4334230B2 (en) | 2009-09-30 |
| ATE364448T1 (en) | 2007-07-15 |
| DE50210315D1 (en) | 2007-07-26 |
| EP1377381A1 (en) | 2004-01-07 |
| WO2002081092A1 (en) | 2002-10-17 |
| DE10117659C2 (en) | 2003-07-17 |
| DE10117659A1 (en) | 2002-10-17 |
| US7223345B2 (en) | 2007-05-29 |
| CN1501843A (en) | 2004-06-02 |
| JP2004533915A (en) | 2004-11-11 |
| US20040159612A1 (en) | 2004-08-19 |
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