EP1367323A1 - Four de fusion de gazeification - Google Patents
Four de fusion de gazeification Download PDFInfo
- Publication number
- EP1367323A1 EP1367323A1 EP02710493A EP02710493A EP1367323A1 EP 1367323 A1 EP1367323 A1 EP 1367323A1 EP 02710493 A EP02710493 A EP 02710493A EP 02710493 A EP02710493 A EP 02710493A EP 1367323 A1 EP1367323 A1 EP 1367323A1
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- EP
- European Patent Office
- Prior art keywords
- furnace
- combustible wastes
- gasification
- ashes
- exhaust gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/24—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0276—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/085—High-temperature heating means, e.g. plasma, for partly melting the waste
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/12—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating using gaseous or liquid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/10—Combustion in two or more stages
- F23G2202/106—Combustion in two or more stages with recirculation of unburned solid or gaseous matter into combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/20—Combustion to temperatures melting waste
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2204/00—Supplementary heating arrangements
- F23G2204/10—Supplementary heating arrangements using auxiliary fuel
- F23G2204/101—Supplementary heating arrangements using auxiliary fuel solid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2204/00—Supplementary heating arrangements
- F23G2204/20—Supplementary heating arrangements using electric energy
- F23G2204/201—Plasma
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/00001—Exhaust gas recirculation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/30—Halogen; Compounds thereof
- F23J2215/301—Dioxins; Furans
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2217/00—Intercepting solids
- F23J2217/10—Intercepting solids by filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2217/00—Intercepting solids
- F23J2217/20—Intercepting solids by baffles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/30—Sorption devices using carbon, e.g. coke
Definitions
- the present invention relates to a gasification-melting furnace and a gasification-melting method for gasifying combustible wastes and/or ashes by combustion and discharging their residue as molten slag, a plasma torch used in the gasification-melting furnace, and an electrode holder for the plasma torch.
- Gasification-melting furnaces for drying, thermally decomposing, burning and melting combustible wastes and/or ashes are divided to kiln-type furnaces, fluid bed-type furnaces and shaft furnaces.
- the kiln-type furnaces and the fluid bed-type furnaces utilise the amount of heat of combustible wastes and/or ashes themselves without using an auxiliary fuel such as coke to melt the combustible wastes and/or the ashes, so that they need only small operation cost.
- the complicated treatment flow disadvantageously requires a lot of operators skilled in operation and maintenance.
- the shaft furnaces require an auxiliary fuel such as coke, they are advantageous in requiring no pretreatment such as crushing, drying, etc., and having a relatively simple treatment flow. Because the shaft furnaces have simple structures, their operation and maintenance are easy.
- a top charge-type shaft furnace of shaft furnace in which combustible wastes and/or ashes and coke are supplied from a top of a furnace body 2 as shown in Fig. 1
- a side charge-type shaft furnace in which combustible wastes and/or ashes and coke are supplied from a side of a furnace body 2 as shown in Fig. 2.
- a supply port 5 mounted to the top of the furnace body 2 is connected to a pusher 6, to which a feeder 7 for combustible wastes and/or ashes and a coke feeder 8 are connected.
- the pusher 6, the feeder 7 for combustible wastes and/or ashes and the coke feeder 8 constitute a feeding mechanism 60.
- the furnace body 2 is provided, in a furnace bottom portion 22, with an molten slag outlet 23 communicating with the furnace body 2, and a slag trough 15 and a slag-cooling water tank 16 are connected to the molten slag outlet 23.
- An exhaust gas outlet 9 arranged in an upper portion of the furnace body 2 is connected to a secondary combustion furnace 10 via an exhaust gas-introducing pipe 28.
- a primary cooling tower 11 Connected to the secondary combustion furnace 10 are a primary cooling tower 11, a heat exchanger 12, a secondary cooling tower 13 and a dust collector 14 in this order.
- An inducing draft fan 18 and an exhaust gas tower 19 are connected to the downstream side of the dust collector 14. Air from the fan 17 is heated in the heat exchanger 12 and sent to air supply means 3, 4.
- the top charge-type shaft furnace comprises the feeding mechanism 60 at a high position
- a building for containing the furnace should have a high roof
- large transporting facilities such as conveyers, cranes, etc. are needed to convey them to the feeding mechanism 60.
- the secondary combustion furnace 10 is built at a position adjacent to the furnace body 2, and the top of the furnace body 2 is connected to the secondary combustion furnace 10 via the horizontal exhaust gas-introducing pipe 28.
- the supply port 5 for combustible wastes and/or ashes and coke is disposed at a position at which a combustion gas flow is horizontal, dust contained in combustible wastes and/or ashes flows into the secondary combustion furnace 10 together with the combustion gas. Part of the dust is melted to form clinker in the secondary combustion furnace 10, and adheres to the wall of the secondary combustion furnace 10. Further, some of the dust flows into the primary cooling tower 11, thereby adversely affecting treatment in the primary cooling tower 11 and subsequent towers.
- the side charge-type shaft furnace is provided with a feeding mechanism 60 at a relatively low position, a building for containing the shaft furnace need not have a high roof, and large transporting facilities such as conveyers, cranes, etc. are not required.
- a supply port 5 is disposed at such a position that a combustion gas flow becomes upward, there is extremely less likelihood that small pieces having small specific gravities such as dust, etc. in the combustible wastes and/or the ashes supplied flow into the secondary combustion furnace 10 together with the combustion gas.
- the side charge-type shaft furnace is more preferable from the above-mentioned aspects.
- the supply port 5 opens on a wall surface of the furnace body 2 having a circular cross section in the case of the side charge-type shaft furnace, the combustible wastes and/or the ashes and the coke are accumulated higher as closer to the supply port 5, and the accumulation tends to decrease by the angle of repose as separating from the supply port 5.
- a high-temperature gas flowing upward from a heat source is subjected to non-uniform resistance while passing through a layer of the combustible wastes and/or the ashes and the coke.
- the high-temperature gas is subjected to a biased flow that a larger amount of the high-temperature gas passes through a low-resistance zone in the layer of the combustible wastes and/or the ashes and the coke, while a smaller amount of the high-temperature gas passes through a high-resistance zone therein.
- the gasification-melting furnaces described in JP 56-2243 B and JP 60-11766 B burn coke and combustible wastes and/or ashes for a heat source, supply an oxygen-rich air to burn them, and intermittently discharge a molten slag.
- these gasification-melting furnaces need additional means for producing an oxygen-rich air, and the operation of opening and closing an exit to intermittently discharge a molten slag.
- the gasification-melting furnaces described in JP 2-298717 A and JP 4-124515 A utilise the combustion of coke and a hot air from a plasma torch for a heat source.
- these gasification-melting furnaces do not have additional air supply means for blowing air into the furnaces to burn combustible wastes, etc., almost failing to utilise the heat of combustion of the combustible wastes. Therefore, they should disadvantageously have large additional heat sources such as coke, electric power to the plasma torch, etc.
- the lower calorific value of city wastes (calorific value in an undried state) has relatively large variations.
- the variations of the lower calorific value of city wastes include long-range variations due to such seasonal factors that for instance, the lower calorific value is low in the summer season by increase in wet refuse (garbage), while it is high in the winter season by increase in plastic wastes, and short-range variations (changing with time) that the lower calorific value is low in a certain time range because the combustible wastes are wet, while it is high in another time range because the combustible wastes are dry.
- the gasification-melting methods of combustible wastes described in JP 56-2243 B and JP 60-11766 B use coke other than combustible wastes as a heat source, thereby making it possible to keep the overall calorific value constant by controlling the amount of coke supplied depending on the variations of the lower calorific value of combustible wastes.
- controlling with the amount of coke supplied is effective only for the long-range variations of the calorific value, because it is difficult to properly control the amount of coke intermittently supplied depending on the short-range variations of the lower calorific value of combustible wastes, and because there is a time lag from the start of burning coke to sufficient heat generation.
- JP 10-192815 A describes a method for extending the life of a landfill comprising digging up buried ashes, melting them in a melting furnace, and burying the resultant slag or utilising it as civil engineering materials and soil improvers.
- JP 10-192815 A suggests that a plasma-type melting furnace can be used as a furnace for melting ashes, however, it fails to teach its specifics at all.
- JP 10-192815 A describes the use of burner-type melting furnaces and plasma-type melting furnaces for melting ashes.
- Japanese Patent 3,012,665 discloses that wastes dug out from wastes landfills are melted in a coke bed-type shaft furnace provided with a plasma torch, and continuously discharged as a glassy slag from the furnace.
- Japanese Patent 3,012,665 fails to teach the structure of the shaft furnace and its operation conditions suitable for continuously discharging the slag.
- the temperature of a hot gas discharged from a furnace top is 200°C to 300°C.
- the accumulation height H of combustible wastes and/or ashes is too larger than the inner diameter D of a furnace body, so that so-called "bridging" easily occurs, in which resins, etc. contained in the accumulated layer become partly melted and fused to each other.
- the "bridging” is a phenomenon that combustible wastes and/or ashes form bridges in the furnace for some reasons, the bridges supporting combustible wastes and/or ashes thereabove, thereby preventing the combustible wastes and/or the ashes from shifting toward a furnace bottom portion.
- the bridges collapse explosive combustion occurs in the furnace, thereby being likely to cause damage to the furnace body, etc.
- the internal pressure of a furnace bottom portion becomes a positive pressure as high as about 1,500 mmAq.
- a molten slag is vigorously ejected from a molten slag outlet, causing risk.
- JP 10-8118 A, JP 10-196930 A and JP 11-76753 A disclose methods for treating an exhaust gas comprising subjecting a cooled exhaust gas to a dioxin-adsorbing treatment with activated carbon, and then neutralising an acidic gas.
- the dioxin-adsorbing treatment comprises blowing activated carbon into the cooled exhaust gas, and removing the activated carbon adsorbing dioxin and flying ashes by a dust collector, a bag filter or an activated carbon adsorption tower.
- the neutralisation treatment of an acidic gas comprises adding calcium hydroxide to an exhaust gas deprived of dioxin and flying ashes, causing the exhaust gas to pass through a dust collector or a bag filter to collect powder floating in the exhaust gas, and finally neutralising an acidic gas in the exhaust gas.
- dioxin and heavy metals contained in the used activated carbon and the flying ashes collected by a bag filter should be subjected to a treatment for making them harmless before burying in landfills.
- two bag filters are disposed in series; calcium hydroxide is introduced into an upstream bag filter to remove not only an acidic gas by neutralisation but also smoke dust, and activated carbon is introduced into a downstream bag filter to remove dioxin by adsorption.
- the smoke dust collected in the upstream stage and the used activated carbon collected in the downstream stage are returned to a gasification-melting furnace, in which the dioxin and the activated carbon are decomposed by incineration.
- JP 2001-41429 A In the method for treating an exhaust gas described in JP 2001-41429 A, all of the smoke dust collected in an upstream stage and the used activated carbon collected in a downstream stage are returned to a gasification-melting furnace, in which dioxin and the activated carbon are decomposed by combustion, requiring no treatment for making harmless and no landfill.
- a gasification-melting furnace in which dioxin and the activated carbon are decomposed by combustion
- This incinerator comprises a primary combustion furnace, a substantially cylindrical secondary combustion furnace, and an exhaust gas-introducing pipe for sending the exhaust gas from the primary combustion furnace to the secondary combustion furnace, an opening of the exhaust gas-introducing pipe being biased from a centre line of the secondary combustion furnace, such that the exhaust gas is swirled in the secondary combustion furnace. Also, to efficiently mix the unburned gas with air to completely burn the unburned gas, a path for supplying the air to the secondary combustion furnace opens at a position biased from the centre line of the secondary combustion furnace.
- the incinerator of JP 7-229610 A is disadvantageous in that the direction and speed of the exhaust gas charged into the secondary combustion furnace cannot properly be changed depending on the conditions of combustible wastes. Also, in the presently available secondary combustion furnace generating no swirling flow, the removal of dioxin is insufficient, and a huge cost would be incurred if the exhaust gas-introducing pipe were mounted to the secondary combustion furnace at such a position that the swirling flow of the exhaust gas is generated.
- an object of the present invention is to provide a furnace and a method for the gasification-melting of combustible wastes and/or ashes, which can efficiently subject combustible wastes and/or ashes to an incineration treatment or a melting treatment, and continuously discharge the resultant molten slag.
- Another object of the present invention is to provide a low-cost, shaft furnace-type gasification-melting furnace substantially free from damage to a secondary combustion furnace wall and adverse influence on treatments downstream of a primary cooling tower.
- a further object of the present invention is to provide a shaft furnace-type gasification-melting furnace with a reduced operation cost by decrease in a biased flow of a high-temperature gas in a layer of combustible wastes and/or ashes.
- a still further object of the present invention is to provide a gasification-melting furnace of combustible wastes and/or ashes with suppressed generation of bridging and decreased internal pressure of a furnace bottom portion for preventing the spewing of a molten slag.
- a still further object of the present invention is to provide a gasification-melting method of combustible wastes free from discharging of smoke dust containing dioxin and heavy metals and the accumulation of the reaction products of calcium hydroxide in the system.
- a still further object of the present invention is to provide an incinerator with the suppressed generation of carbon monoxide, dioxin, etc.
- a still further object of the present invention is to provide a long-life electrode holder and a plasma torch comprising it.
- the present invention has been completed based on the above findings.
- the gasification-melting furnace supplies combustible wastes and/or ashes and an auxiliary fuel into a shaft furnace, in an atmosphere containing air in a stoichiometric amount or less relative to them, and thermally decomposes the combustible wastes and/or ashes to discharge the resultant residue as a molten slag from a slag exit, the gasification-melting furnace comprising a plasma torch for blowing a hot air into an auxiliary fuel layer in a furnace bottom portion, which is at a positive pressure of 5 kPa or less on average.
- H/D is 2 or less, wherein H is a height from a furnace bottom to a top surface of a layer of accumulated combustible wastes and/or ashes, and D is an inner diameter of a furnace body in a zone in which there is a top surface of a layer of the combustible wastes and/or ashes.
- the shaft furnace-type gasification-melting furnace supplies combustible wastes and/or ashes and an auxiliary fuel into a furnace, burns the combustible wastes and/or the ashes for gasification by a heat source disposed in a furnace bottom portion, and discharges molten residue from a residue-discharging outlet, supply ports for the combustible wastes and/or the ashes and the auxiliary fuel being mounted to a side surface of the shaft furnace with the lower portions of the supply ports projecting into the furnace.
- the heat source may be a plasma torch and a coke layer.
- the gasification-melting method of combustible wastes comprises using a shaft furnace-type gasification-melting furnace provided with a plasma torch, supplying the combustible wastes and the auxiliary fuel into the shaft furnace, blowing a hot air into an auxiliary fuel layer in a furnace bottom portion by the plasma torch, burning the combustible wastes for gasification in an atmosphere containing a stoichiometric amount or less of air relative to the combustible wastes and the auxiliary fuel, and discharging residue as a molten slag outside the furnace, the amount of electric power supplied to the plasma torch being controlled depending on the variations of a lower calorific value of the combustible wastes.
- the gasification-melting method of combustible wastes comprises using a shaft furnace-type gasification-melting furnace provided with a plasma torch, supplying the combustible wastes and the auxiliary fuel into the shaft furnace, blowing a hot air into an auxiliary fuel layer in a furnace bottom portion by the plasma torch, burning the combustible wastes for gasification in an atmosphere containing a stoichiometric amount or less of air relative to the combustible wastes and the auxiliary fuel, and discharging residue as a molten slag outside the furnace, the amount of electric power supplied to the plasma torch being increased in the short-range decrease of the lower calorific value of the combustible wastes, and decreased in the short-range increase of the lower calorific value of the combustible wastes.
- the gasification-melting method of combustible wastes comprises using a shaft furnace-type gasification-melting furnace provided with a plasma torch, supplying the combustible wastes and the auxiliary fuel into the shaft furnace, blowing a hot air into an auxiliary fuel layer in a furnace bottom portion by the plasma torch, burning the combustible wastes for gasification in an atmosphere containing a stoichiometric amount or less of air relative to the combustible wastes and the auxiliary fuel, and discharging residue as a molten slag outside the furnace, the amount of the auxiliary fuel supplied to the shaft furnace being increased in the long-range decrease of the lower calorific value of the combustible wastes, and decreased in the long-range increase of the lower calorific value of the combustible wastes.
- the gasification-melting method of combustible wastes comprises using a shaft furnace-type gasification-melting furnace provided with a plasma torch, supplying the combustible wastes and the auxiliary fuel into the shaft furnace, blowing a hot air into an auxiliary fuel layer in a furnace bottom portion by the plasma torch, burning the combustible wastes for gasification in an atmosphere containing a stoichiometric amount or less of air relative to the combustible wastes and the auxiliary fuel, and discharging residue as a molten slag outside the furnace, the amount of electric power supplied to the plasma torch being increased in the short-range decrease of the lower calorific value of the combustible wastes, and decreased in the short-range increase of the lower calorific value of the combustible wastes, and the amount of the auxiliary fuel supplied to the shaft furnace being increased in the long-range decrease of the lower calorific value of the combustible wastes, and decreased
- the gasification-melting method of combustible wastes and/or ashes comprises burning a gas generated by thermally decomposing the combustible wastes and/or ashes in a gasification-melting furnace, bringing the resultant exhaust gas into contact with activated carbon, smoke dust containing the activated carbon and flying ashes being removed from the exhaust gas; and returning the smoke dust to the gasification-melting furnace.
- the gasification-melting method of the above combustible wastes and/or ashes comprises using a shaft furnace-type gasification-melting furnace provided with a plasma torch, supplying combustible wastes and/or ashes and an auxiliary fuel into the shaft furnace, blowing a hot air into an auxiliary fuel layer in a furnace bottom portion by the plasma torch, burning the combustible wastes and/or ashes for gasification in an atmosphere containing a stoichiometric amount or less of air relative to the combustible wastes and/or ashes and the auxiliary fuel, discharging the residue outside the furnace as a molten slag, burning a gas generated by thermally decomposing the combustible wastes and/or ashes in the gasification-melting furnace, bringing the resultant exhaust gas into contact with activated carbon, wherein smoke dust containing the activated carbon and flying ashes is removed from the exhaust gas; and returning the smoke dust to the gasification-melting furnace.
- the gasification-melting method of combustible wastes and/or ashes comprises burning a gas generated by thermally decomposing the combustible wastes and/or ashes in the gasification-melting furnace, wherein the resultant primary exhaust gas is brought into contact with activated carbon; wherein smoke dust containing the activated carbon and flying ashes is removed from the exhaust gas; wherein the smoke dust is returned to the gasification-melting furnace; wherein a secondary exhaust gas obtained by removing the smoke dust is brought into contact with a salt-removing agent; and removing the resultant salts from the secondary exhaust gas.
- the gasification-melting method of the above combustible wastes and/or ashes comprises using a shaft furnace-type gasification-melting furnace provided with a plasma torch, supplying combustible wastes and/or ashes and an auxiliary fuel into the shaft furnace, blowing a hot air into an auxiliary fuel layer in a furnace bottom portion by the plasma torch, burning the combustible wastes and/or ashes for gasification in an atmosphere containing a stoichiometric amount or less of air relative to the combustible wastes and/or ashes and the auxiliary fuel, discharging the residue outside the furnace as a molten slag, burning a gas generated by thermally decomposing the combustible wastes and/or ashes in the gasification-melting furnace, wherein the resultant primary exhaust gas is brought into contact with activated carbon; wherein smoke dust containing the activated carbon and flying ashes is removed from the exhaust gas; wherein the smoke dust is returned to the gasification-melting
- the incinerator of combustible wastes and/or ashes comprises a primary combustion furnace for burning combustible wastes and/or ashes, a substantially cylindrical, secondary combustion furnace, and an exhaust gas-introducing pipe connecting the primary combustion furnace and the secondary combustion furnace for introducing an exhaust gas from the primary combustion furnace to the secondary combustion furnace, and a baffle plate mounted to the exhaust gas-introducing pipe for controlling the flow rate and direction of the exhaust gas flowing into the secondary combustion furnace.
- the electrode holder according to a still further embodiment of the present invention is disposed in a plasma torch for fixing at least one of a pair of electrodes to keep a constant distance between both electrodes while keeping electric insulation therebetween, the electrode holder being made of an insulating ceramic having a thermal shock resistance ⁇ T of 400°C or more.
- the plasma torch according to a still further embodiment of the present invention comprises a pair of electrodes, and an electrode holder for fixing at least one of the electrodes, the electrode holder being made of an insulating ceramic having a thermal shock resistance ⁇ T of 400°C or more, whereby both electrodes are kept at a constant distance with electric insulation.
- the gasification-melting furnace of the present invention for combustible wastes (including landfill wastes, etc.) and/or ashes burns a coke layer formed on a bottom of a shaft furnace by a hot air blown from a plasma torch, heating combustible wastes and/or ashes accumulated on the coke layer by this heat and the hot air from the plasma torch to a molten slag, and discharging the molten slag outside the furnace.
- the molten slag is glassy, and its volume is about 1/5 of that of the wastes, with heavy metals, etc. sealed therein so that they do not eluate.
- the hot air injecting from the plasma torch is as hot as 1,800°C to 2,500°C, to heat the coke layer and burn part of the coke layer with oxygen in the hot air and air blown from the air supply means, so that the temperature of the coke layer is stably kept at about 1,500°C.
- an oxygen-rich air is needed to keep the temperature of the coke layer at 1,500°C only with the heat of combustion of coke, air blown from the air supply means need not be an oxygen-rich air, because both the coke layer and the plasma torch are used in the gasification-melting furnace of the present invention.
- the gasification-melting furnace of the present invention comprises, in addition to the plasma torch, an air supply means for blowing a combustion air into the furnace at a position above the plasma torch, at which it faces the coke layer, the temperature of the coke layer can be kept at 1,500°C or higher without lowering the temperature of the hot air from the plasma torch.
- the internal pressure of a furnace bottom portion in which there is the coke layer is kept at a positive pressure of 0.3 to 5 kPa on average.
- the internal pressure of the furnace bottom portion is preferably at least about 0.3 kPa.
- the internal pressure of the furnace bottom portion is more preferably a positive pressure of 0.3 to 2 kPa.
- positive pressure is determined relative to the atmospheric pressure outside the furnace.
- the pressure of the furnace bottom portion always varies depending on the total height and void ratio (air flow resistance ) of the layer 26 of combustible wastes and/or ashes and the coke layer 25 in the shaft furnace 2, the amount of air supplied from the plasma torch 11, the amount of air induced by an inducing fan, etc. Accordingly, the pressure of the furnace bottom portion is expressed by an average value with time.
- the pressure of the furnace bottom portion by adjusting the height of the combustible waste layer 26.
- the increase in the amount of electric power supplied to the plasma torch 11 or the amount of coke charged leads to increase in the melting speed of the combustible wastes, resulting in a lower height of the combustible waste layer 26 and thus a lower pressure of the furnace bottom portion.
- the decrease in the amount of electric power supplied to the plasma torch 11 or the amount of coke charged leads to decrease in the melting speed of the combustible wastes, resulting in a higher height of the combustible waste layer 26 and thus a higher pressure of the furnace bottom portion.
- a plasma torch 11 mounted to the shaft furnace 2 are a plasma torch 11 near the bottom and a first air supply means 3 and a second air supply means 4 above the plasma torch 11.
- two plasma torches 11 are mounted to the furnace body on a periphery of the same height, with the direction of a hot air blown from the plasma torches 11 aligned with the diameter direction of the furnace body and toward the edge of the furnace bottom portion.
- Both of the first air supply means 3 and the second air supply means 4 are similarly provided at six points on the periphery. Air blown from the first air supply means 3 and the second air supply means 4 is at a high temperature by heat exchanging with a high-temperature gas of a secondary combustion furnace in a heat exchanger.
- the furnace body 2 is constituted by an outer shell 201 and a refractory liner layer 202.
- the furnace body 2 has a structure constituted by a combination of a furnace body part 20 and a furnace bottom part 21, the furnace bottom part 21 being suspended from the furnace body part 20. If necessary, the furnace bottom part 21 may be detached onto a carriage (not shown) to move to a predetermined place. Because of this structure, checking and repair are easy in the furnace bottom part 21 and the plasma torch 11 as well as the inside of the furnace body part 20.
- a supply port 5 is mounted to the furnace body 2 in a substantially middle portion in a vertical direction, and a pusher 6 is connected to the supply port 5.
- a combustible waste feeder 7 and a coke feeder 8 are connected to the pusher 6.
- the combustible waste feeder 7 and the coke feeder 8 are provided with double-butterfly valves (not shown), to prevent the outside air from entering.
- Mounted above the supply port 5 is an air supply means 30.
- the furnace body 2 is provided with an exhaust gas exit 9 in an upper portion thereof, and the exhaust gas exit 9 is successively connected to a secondary combustion furnace 10, a primary cooling tower 11, a heat exchanger 12, a secondary cooling tower 13 and a dust collector 14.
- a dust collector 14 Connected downstream of the dust collector 14 are an inducing fan 18 and an exhaust gas tower 19.
- a furnace bottom portion 22 of the furnace body 2 is provided with a molten slag outlet 23 communicating with the furnace body 2, and the molten slag outlet 23 is connected to a slag trough 15 and a slag-cooling water bath 16.
- the combustible wastes are charged into the shaft furnace 2 together with coke and limestone, and the resultant gas is discharged to the secondary combustion chamber 10 via the upper portion of the furnace.
- secondary combustion chamber 10 combustible components contained in this gas are burned in a reducing atmosphere, so that nitrogen compounds are decomposed to N2.
- secondary combustion is carried out such that the combustion temperature is in a range of 1,000°C to 1,200°C, and that the residence time of the resultant gas is 2 seconds or more.
- This combustion gas is cooled to 500°C to 700°C by the primary cooling chamber 11, heat-exchanged by the heat exchanger (air-preheating chamber )12, and then rapidly cooled to 150°C to 200°C by the secondary cooling chamber 13 so that it quickly passes through a dioxin resynthesis temperature range.
- To neutralise toxic gases (chlorine gas, etc.) it passes through the dust collector 14 containing a mixture of activated carbon and calcium hydroxide to make the exhaust gas innocuous, and then discharged to the air.
- dust generated in the secondary combustion chamber 10, the primary cooling chamber 11, the secondary cooling chamber 13 and the heat exchanger 12 are collected and solidified to become reusable.
- the furnace bottom portion 22 is filled with coke to form a coke layer 25, and the plasma torch 11 is then ignited to blow a hot air at 1,000°C to 2,500°C (for instance, about 1,800°C) into the coke layer 25.
- the temperature of the furnace bottom portion 22 and the coke layer 25 is elevated to, for instance, about 1,500°C after about 3 hours by the heat of combustion of the coke with the hot air supplied from the plasma torch 11.
- Supplied into the furnace body 2 in this state are combustible wastes from the combustible waste feeder 7 by the pusher 6 and a mixture of coke and limestone from the coke feeder 8 by the pusher 6.
- a weight ratio of the coke to the combustible wastes is preferably, for instance, 2% by weight.
- a combustible waste layer 26 is formed on the coke layer 25 in substantially alternate layers of the combustible wastes and the coke.
- the air is supplied from the plasma torch 11 and, if necessary, the air supply means 3 into the furnace body 2.
- the total amount of the air is a stoichiometric amount or less to the coke in the furnace body 2; specifically, a ratio of the stoichiometric amount of air to the total amount of air is preferably 1/0.2 to 1/0.9.
- the ashes and the landfill wastes contain more inorganic components and less combustible components as compared with general combustible wastes. Accordingly, the amount of heat for melting them is supplied from the coke or the plasma torch 11. To reduce a running cost, the combustion of the coke should be suppressed as much as possible. However, when the ashes and the landfill wastes, etc. have too small calorific values, the coke should also be a heat source. In this case, air in an amount about 0.2 to 0.9 times the stoichiometric amount of air to the coke is preferably supplied into the furnace body 2. The amount of heat necessary for melting the ashes and the landfill wastes can be supplied from the hot air injected from the plasma torch 11.
- the layer 26 of combustible wastes and/or ashes (referred to simply as “combustible waste layer” hereinafter) accumulated on the heated coke layer 25 is dried.
- Part of the combustible waste layer 26 is burned with the above combustion air, while the other part of the combustible waste layer 26 is gasified because the combustion air is consumed by the above combustion.
- Ashes generated by the combustion of the combustible wastes and char generated by gasification are melted by the hot air from the coke layer 25 heated at about 1,500°C to form a molten slag, which flows down in the coke layer 25 and stored in the furnace bottom portion 22.
- the molten slag residing in the furnace bottom portion 22 is discharged from the molten slag outlet 23 mounted to the furnace bottom to the outside of the furnace.
- the combustible wastes and the coke are accumulated in substantially alternate layers.
- a ratio of the coke to the combustible wastes is about 2% by weight, the combustion of the combustible wastes consumes most of the above combustion air, because the combustion of the combustible wastes is much faster than that of the coke. As a result, it is difficult to burn the coke, resulting in a small amount of the coke consumed.
- an upper portion of the combustible waste layer 26 becomes a wastes-rich layer 261, and an intermediate portion of the combustible waste layer 26 in which the combustion and gasification of the combustible wastes proceed becomes a combustible wastes-coke mixture layer 262.
- the coke layer 25 is continuously formed to a predetermined height in the furnace bottom portion 22, and the coke layer 25 is kept at a height at which the amount of coke consumed and the amount of coke supplied are balanced.
- the molten slag outlet 23 preferably has a structure as short and linear as possible to prevent the molten slag from being solidified and thus clogging it. To prevent the solidification of the molten slag, it is also effective to heat the molten slag outlet 23 by a burner, etc. from outside the furnace body 2.
- a ratio (H/D) of the accumulation height H of the combustible wastes and/or the ashes to the inner diameter D of the shaft furnace 2 at a position of a top surface of the combustible waste layer 26 is preferably 2 or less.
- the shaft furnace 2 of the present invention Even when the resins form large fused bulks, bridges are less likely formed with a large inner diameter D of the furnace body. Accordingly, in the shaft furnace 2 of the present invention, the bridging of the combustible wastes and/or the ashes less likely occurs, and further the flow resistance of air is small, resulting in a small internal pressure in the furnace bottom portion. Namely, even if the injecting pressure of a plasma air and a shroud air from the plasma torch is a positive pressure of 14.7 kPa, the furnace bottom portion having the coke layer is at a positive pressure not exceeding 5 kPa.
- H/D is preferably 0.8 or more, more preferably 1.0 or more.
- a lower portion of the supply port 5 is provided with a ledge 27, which projects inside the furnace from the refractory member 202.
- the extent of projection of the ledge 27 inside the furnace is preferably 20 to 70%, particularly about 1/2, of a radius of the wastes-rich layer 261 in the shaft furnace.
- the combustible wastes and/or the ashes and the coke are accumulated higher at positions closer to the supply port 5, and the amount of their accumulation decreases as separating from the supply port 5 because of the angle of repose.
- the combustible wastes and/or the ashes and the coke in the furnace body 2 becomes non-uniform.
- the shaft furnace provided with the ledge 27 the combustible wastes and/or the ashes and the coke fall down in the furnace body 2 at a position deviated from the supply port 5 by substantially the same distance as the length of the ledge 27 projecting inside the furnace. Accordingly, the accumulation distribution of the combustible wastes and/or the ashes and the coke becomes uniform in the furnace body 2 of a circular cross section.
- Fig. 6 shows a combustion furnace system comprising a primary combustion furnace 2 and a secondary combustion furnace 10.
- the primary combustion furnace 2 per se may be the same as the shaft furnace shown in Fig. 3.
- a combustible gas burned in the shaft furnace 2 is further burned in the secondary combustion furnace 10.
- Air is preferably supplied from a second additional air supply means 36 disposed near a gas inlet of the secondary combustion furnace 10 or near a gas outlet of the shaft furnace 2, to keep the secondary combustion furnace filled with a stoichiometric amount or more of air. This keeps an oxidative atmosphere in the secondary combustion furnace 10, so that the remaining combustible components in the combustible gas are completely burned.
- the amount and temperature of air supplied from the second additional air supply means 36, the percentage of oxygen contained therein, the outlet temperature of the shaft furnace, etc. need only be properly set.
- Figs. 7 and 8 are schematic, lateral, cross-sectional views showing the incinerator of Fig. 6.
- This incinerator comprises the primary combustion furnace 2, the secondary combustion furnace 10 having substantially cylindrical shape with a centre line extending along the vertical direction, and an exhaust gas-introducing pipe 28 connecting the secondary combustion furnace 10 to the primary combustion furnace 2.
- the primary combustion furnace 2 and the secondary combustion furnace 10 may be the same as shown in Fig. 6.
- An exhaust gas generated by the combustion of the combustible wastes is charged into the secondary combustion furnace 10 via the exhaust gas-introducing pipe 28.
- the secondary combustion furnace 10 is provided with a gas-discharging path 10a in its lower portion.
- the substantially cylindrical exhaust gas-introducing pipe 28 is connected to an upper side surface of the secondary combustion furnace 10 in a horizontal diameter direction.
- the exhaust gas-introducing pipe 28 has a baffle plate 38.
- the baffle plate 38 is, as shown in Figs. 7 and 9, mounted near a junction with the secondary combustion furnace 10, such that part of the flow path of the exhaust gas-introducing pipe 28 is shut in a direction substantially along a centreline V of the secondary combustion furnace 10.
- the distance of the baffle plate 38 from a junction of the exhaust gas-introducing pipe 28 and the secondary combustion furnace 10 is preferably smaller than the inner diameter of the exhaust gas-introducing pipe 28.
- the baffle plate 38 is desirably movable such that an area of shutting the flow path of the exhaust gas-introducing pipe 28 can be controlled.
- a zone of the flow path of the exhaust gas-introducing pipe 28 shut by the baffle plate 38 extends substantially in parallel with the centre line V of the secondary combustion furnace 10. Therefore, the baffle plate 38 can bias the direction of an exhaust gas flowing into the secondary combustion furnace 10 from the centre line V of the secondary combustion furnace 10 and change the flow rate of the exhaust gas, thereby generating a swirling flow SF of predetermined strength along a wall surface of the secondary combustion furnace 10.
- the baffle plate 38 movable in a radial direction of the exhaust gas-introducing pipe 28, the throttle area S of the exhaust gas-introducing pipe 28 can be controlled, thereby properly controlling the flow rate and direction of the exhaust gas.
- the distance HB between the baffle plate 38 and an opening of the secondary combustion furnace 10 is smaller than the inner diameter DP of the exhaust gas-introducing pipe 28. If the baffle plate 38 were separated from the opening by this length or more, the exhaust gas throttled by the baffle plate 38 is expanded, failing to generate a sufficient swirling flow SF in the secondary combustion furnace 10 To completely burn the exhaust gas in the secondary combustion furnace 10, a secondary combustion air is supplied. Accordingly, it is preferable that a secondary combustion air supply path 36 is mounted such that its opening is positioned at least at a junction of the exhaust gas-introducing pipe 28 and the secondary combustion furnace 10, and that air is supplied from the secondary combustion air supply path 36 in the same direction as the swirling direction of the exhaust gas in the secondary combustion furnace 10.
- the secondary combustion air supply path 36 may not be mounted to the side wall of the secondary combustion furnace 10, but may be mounted to the exhaust gas-introducing pipe 28 depending on a mounting position of the baffle plate 38.
- the flow rate and direction of the exhaust gas passing through the exhaust gas-introducing pipe 28 are changed by the baffle plate 38, such that the exhaust gas flows into the secondary combustion furnace 10 along its side wall, resulting in swirling as shown in Fig. 8. Further, the exhaust gas is mixed with a secondary air supplied from the secondary air-supplying path 36, resulting in strong swirling. As a result, the exhaust gas flowing into the secondary combustion furnace 10 becomes a strong swirling flow SF involving the secondary air, resulting in substantially complete combustion and thus leading to drastic decrease in carbon monoxide, hydrocarbons, etc., and substantial decomposition of dioxin. The exhaust gas completely burned in the secondary combustion furnace 10 is discharged from an exit 10a.
- the baffle plate 38 preferably has a larger shutting area.
- too large a shutting area of the baffle plate 38 leads to too high the speed of the exhaust gas, resulting in excess wearing in the wall of the secondary combustion furnace 10.
- the shutting area of the baffle plate 38 is preferably about half of the cross section area of the exhaust gas-introducing pipe 28.
- the relation between the shutting area of the baffle plate 38 and the degree of mixing of the exhaust gas and the secondary air was determined by simulation at a position in the secondary combustion furnace 10 shown in Fig. 10. The results are shown in Table 1.
- the degree of mixing was determined by calculating turbulence energy by using heat fluid calculation.
- the turbulence energy is correlated with the change of a flow rate; the larger the turbulence energy (m 2 /sec 2 ), the larger the variations of the flow rate, resulting in higher mixing.
- the inner diameter of the secondary combustion furnace 10 was 1.1 m
- the inner diameter of the exhaust gas-introducing pipe 28 was 0.6 m.
- measurement was carried out at five points A to E in total on the centre line V of the secondary combustion furnace 10.
- the point A is an intersection of the centre line L of the exhaust gas-introducing pipe 28 and the centre line V of the secondary combustion furnace 10, and the points B to E are at positions downward from the point A in this order at a one-meter interval.
- the exhaust gas is completely burned in the secondary combustion furnace 10 is found by observing whether or not the exhaust gas charged from the exhaust gas-introducing pipe 28 is immediately mixed with the secondary air. Namely, it can be determined by observing whether or not there is large turbulence energy at the points A and B. More effectiveness is obtained by the baffle plate 38 having a larger shutting area ratio at this point. On the other hand, the average value of the points A to E indicates that the turbulence energy is lower in the case 2 than in the case of no baffle plate 38. It is thus clear that to achieve a sufficient mixing effect by the baffle plate 38, the cross section area of the baffle plate 38 is preferably 30% or more of the cross section area of the exhaust gas-introducing pipe 28.
- the exhaust gas-introducing pipe 28 may be biased from the centre line V of the secondary combustion furnace 10.
- Fig. 11 shows a further example of the gasification-melting furnace system of the present invention.
- This system is to remove dioxin from the exhaust gas by causing activated carbon to adsorb dioxin in the exhaust gas.
- a dust collector to remove smoke dust containing activated carbon and flying ashes from the exhaust gas.
- a bag filter is particularly suitable because of excellent contact with the exhaust gas and the activated carbon and the accuracy of removing flying ashes.
- a dust collector to remove acidic components from the exhaust gas, from the exhaust gas, a dust collector, a bag filter, etc. may be used.
- the bag filter is particularly suitable because of excellent accuracy of removing the salts.
- the smoke dust collected in the exhaust gas treatment step is returned into the combustible waste layer in the gasification-melting furnace, to melt the smoke dust containing flying ashes and activated carbon while avoiding scattering, and further to expose dioxin in the smoke dust to a high temperature in the gasification-melting furnace for efficient thermal decomposition.
- Dioxin not thermally decomposed in the gasification-melting furnace can be thermally decomposed in the gas combustion furnace.
- the exhaust gas generated by the thermal decomposition of the combustible wastes in the gasification-melting furnace is burned at a dioxin-decomposing temperature in the gas combustion furnace, and then cooled at a speed preventing the resynthesis of dioxin to reduce the concentration of dioxin in the exhaust gas.
- the gas combustion furnace 102 connected to the gasification-melting furnace 2 burns a combustible gas containing hydrocarbons, hydrogen, etc. generated by the thermal decomposition of combustible wastes in the gasification-melting furnace 2 at as high a temperature as 1,000°C to 1,200°C for at least about 2 to 3 seconds, to decompose dioxin.
- the gas cooling tower 103 cools a high-temperature exhaust gas discharged from the gas combustion furnace 2 to such a temperature (for instance, 500°C) that a heat exchanger, etc. disposed downstream are not damaged.
- the first heat exchanger 104 performs heat exchange between the exhaust gas at about 500°C discharged from the gas cooling tower 103 and the air supplied from the fan 141, to heat the air.
- the hot air is sent to the gasification-melting furnace 2.
- the second heat exchanger 105 performs heat exchange between the exhaust gas discharged from the first heat exchanger 104 and the air supplied from the fan 151, to heat the air.
- the hot air is sent to the exhaust gas tower 110, to elevate the temperature of the exhaust gas discharged from the exhaust gas tower 110, thereby preventing white fume.
- the salt-removing tower 106 further lowers the temperature of the exhaust gas whose temperature is lowered by heat exchange with the air, thereby rapidly cooling the exhaust gas in a temperature range of 400°C to 200°C, in which the resynthesis of dioxin is likely to occur, to suppress the resynthesis of dioxin. It also functions to prevent heat damage on the bag filter disposed downstream.
- first bag filter 107 Connected to the downstream of the salt-removing tower 106 are a first bag filter 107 and a second bag filter 108 in this order.
- An inlet of the first bag filter 107 is connected to an air-blowing pipe 172 of an activated carbon reservoir 171, through which activated carbon is introduced.
- the exhaust gas and the activated carbon flow into the first bag filter 107, and the activated carbon dispersed in the exhaust gas adsorbs dioxin.
- the dioxin-adsorbing activated carbon and the dioxin-containing flying ashes are collected by the first bag filter 107.
- an air-blowing pipe 182 connected to the calcium hydroxide reservoir 181 for introducing calcium hydroxide, a salt-removing agent, into the second bag filter 108.
- the exhaust gas and calcium hydroxide flow into the second bag filter 108, and calcium hydroxide neutralises the exhaust gas. Salts generated by a neutralisation reaction and unreacted calcium hydroxide are collected by the second bag filter 108.
- an inducing fan 109 and an exhaust gas tower 110 Connected to the downstream of the second bag filter 108 are an inducing fan 109 and an exhaust gas tower 110 in this order.
- the exhaust gas cleaned by the second bag filter 108 is sent to the exhaust gas tower 110 by the inducing fan 109, and discharged from the exhaust gas tower 110 to the air.
- the bottom portions of the gas combustion furnace 2, the gas cooling tower 103, the salt-removing tower 106 and the first bag filter 107 are air-tightly connected to the dust-collecting conveyer 111, and the dust-collecting conveyer 111 is provided with a flying ash reservoir 112 at its front end.
- the flying ashes and the used activated carbon collected in each apparatus are collected in the flying ash reservoir 112 by the dust-collecting conveyer 111.
- the flying ash reservoir 112 is connected to the gasification-melting furnace 2 via the air-blowing pipe 121, the flying ashes and the used activated carbon stored in the flying ash reservoir 112 are returned to the gasification-melting furnace 2.
- the collected flying ashes contain low-boiling point heavy metals.
- the heavy metals When returned to the gasification-melting furnace 2, the heavy metals are vaporised again and stored in the exhaust gas-treating system. Accordingly, when the concentrations of the heavy metals in the flying ashes reach predetermined levels, it is necessary to discharge the flying ashes from the system.
- the bottom portion of the second bag filter 108 is air-tightly connected to the dust-collecting conveyer 113, and a dust-collecting conveyer 113 is provided with a reservoir 114 at its front end.
- the reaction products (salts) of calcium hydroxide and unreacted calcium hydroxide collected by the second bag filter 108 are sent to reservoir 114 via the dust-collecting conveyer 113, and stored there. They are further sent from the reservoir 114 to a kneading-type moulding machine 115 properly for solidification, and conveyed out from the melting treatment system.
- the activated carbon charged into the inlet of the first bag filter 107 adsorbs dioxin in the exhaust gas, and the activated carbon adsorbing dioxin is collected in the bag filter 107.
- Flying ashes not collected in the gas combustion furnace 2, the gas cooling tower 103 and the salt-removing tower 106 are also collected in the first bag filter 107, and sent to the flying ash reservoir 112 by the dust-collecting conveyer 111. Further, flying ashes collected in the gas combustion furnace 2, the gas cooling tower 103 and the salt-removing tower 106 upstream of the first bag filter 107 are also sent to the flying ash reservoir 112 by the dust-collecting conveyer 111.
- the flying ashes are not conveyed out from the system but returned to the high-temperature gasification-melting furnace 2 together with the used activated carbon.
- the gasification-melting furnace 2 dioxin is decomposed, the activated carbon is melted by incineration, and the flying ashes are melted. As a result, it is possible to prevent dioxin from being discharged outside the system.
- Calcium hydroxide charged into the inlet of the second bag filter 108 absorbs HCl and SOx in the exhaust gas, thereby forming calcium chloride and calcium sulphate, which are collected in the second bag filter 108.
- Calcium chloride and calcium sulphate collected in the second bag filter 108 are conveyed to the reservoir 114 by the dust-collecting conveyer 113. They are properly mixed with cement, etc. and moulded to pellets by the kneading-type moulding machine 115, which are used for landfill, etc.
- salt powder collected in the second bag filter 108 does not substantially contain dioxin and heavy metals. Accordingly, the mouldings of the salt powder would not cause any contamination problem in landfill, and are reusable as building materials, civil engineering materials, etc.
- the plasma torch 11 used for the gasification-melting furnace of the present invention has a structure shown in Fig. 12.
- an electrode holder 202 Disposed in an insert chip 203 is an electrode holder 202 made of an insulating refractory material, whose centre shaft has a hole, through which a tungsten bar electrode 204 penetrates.
- This electrode holder 202 positions the tungsten bar electrode 204 along the centre axis of the insert chip 203.
- a working gas such as Ar, etc. is first caused to flow between the tungsten bar electrode 204 and the insert chip 203.
- a high-frequency generator then applies a high-frequency voltage of 3,000 to 4,000 V at 1 to 2 MHz between the tungsten bar electrode 204 and the insert chip 203.
- a pilot arc power supply supplies a DC pilot current of 10 to 20 A between the tungsten bar electrode 204 and the insert chip 203.
- the electrode holder 202 is simultaneously subjected to overheat and cooling, a large thermal gradient occurs in the member, resulting in breakage in some cases. Though not so remarkable as in the mal-ignition, the electrode holder 202 is likely to be influenced by overheat and cooling simultaneously even in a usual use in which a plasma is normally ejected from the nozzle of the insert chip 203, so that it is sometimes broken by use for a long period of time.
- the plasma torch is provided with the electrode holder 202 for keeping the distance between the tungsten bar electrode 204 and the insert chip 203 constant while electrically insulating these electrodes.
- the electrode holder 202 is made of an insulating ceramic having a thermal shock resistance ⁇ T of 400°C or more.
- Fig. 13 is a schematic, vertical, cross-sectional view showing another plasma torch 11.
- the plasma torch 11 comprises an electrode holder 202 for holding a tungsten bar electrode 204 and an insert chip 203 with a constant distance while electrically insulating these electrodes.
- the electrode holder 202 is made of an insulating ceramic having a thermal shock resistance ⁇ T of 400°C or more.
- Suitable as ceramics for such electrode holder 202 are silicon nitride ceramics and zirconia.
- Sialon may be used as silicon nitride ceramics, and Sialon HCN-10 available from Hitachi Metals, Ltd., for instance, is preferable.
- This Sialon has an electrical resistivity of 1011 ⁇ cm or more and a thermal shock resistance ⁇ T of 710°C.
- the electrode holder 202 of the present invention is subjected to little wearing.
- the working gas passes through the hole of the electrode holder 202 at a high speed, the electrode holder 202 would be worn if a trace amount of dust were contained in the working gas.
- the working gas is supplied between the tungsten bar electrode 204 and the insert chip 203 from the hole of the electrode holder 202 in a swirling flow.
- the electrode holder 202 is worn by dust in the working gas, thereby changing the shape of this hole, resulting in turbulence in the swirling flow.
- the electrode holder 202 is preferably made of ceramics having a wear resistance of 5 mm 3 or less by wear volume.
- This wear volume is defined as volume decrease (slurry wear), when a test piece of 15 mm x 15 mm x 5 mm ground by #400 diamond is rotated with its surface of 15 mm x 15 mm in a peripheral direction in Al 2 O 3 powder (60 mesh) at a peripheral speed of 7 m/s for 1 hour.
- the wear volume of Sialon HCN-10 is 1.4 mm 3
- the wear volume of Zirconia HCZ-40 is 0.8 mm 3 .
- the electrode holder 202 of the present invention needs high dimensional accuracy in inner and outer surfaces, it is preferable that a green body obtained by the rubber-pressing of ceramic powder is first subjected to a predetermined working, and finish-worked again in necessary portions after sintering.
- the properties of ashes used in this Example are as follows; Type of ashes ashes available from a stoker furnace, Moisture content 20% by weight, Content of combustibles 4% by weight, and Ash content 76% by weight.
- the above ashes were gasification-melted under the following conditions; Amount of ashes supplied 200 kg/hour, Amount of coke supplied 35 kg/hour, Amount of limestone supplied 6 kg/hour, Total air volume 250 Nm 3 /hour, Air volume from plasma torch 250 Nm 3 /hour, Total air volume/stoichiometric air volume 0.82, Temperature of hot air supplied from plasma torch about 1,800°C, Temperature of coke layer 25 1,500°C, and Average internal pressure in furnace bottom portion 22 positive pressure of 1.0 kPa.
- the temperature in the furnace body 2 was substantially as constant as about 1,500°C in the coke layer 25, and 500°C to 900°C in an upper space of the ash layer 26. This temperature variation occurs, because every time ashes are supplied at a pace of one batch per 1 minute, water in the ashes is evaporated to remove heat from the furnace. After about 10 minutes passed from starting the supply of ashes, a molten slag started to be discharged. The amount of a molten slag discharged was about 200 kg/hour on average.
- the properties of landfill wastes used in this Example are as follows; Type of landfill wastes dug landfill wastes, Moisture content 33% by weight, Content of combustibles 7% by weight, and Ash content 60% by weight.
- landfill wastes were gasification-melted under the following conditions; Amount of wastes supplied 400 kg/hour, Amount of coke supplied 40 kg/hour, Amount of limestone supplied 10 kg/hour, Total air volume 250 Nm 3 /hour, Air volume from plasma torch 250 Nm 3 /hour, Total air volume/stoichiometric air volume 0.57 Temperature of hot air supplied from plasma torch about 1,800°C, Temperature of coke layer 25 1,500°C, and Average internal pressure in furnace bottom portion 22 positive pressure of 2 kPa.
- the hot air volume from the plasma torch was 250 Nm 3 /hour. However, when the hot air volume was changed to 350 Nm 3 /hour, the temperature in the furnace bottom portion 22 and in the coke layer 25 was lowered, failing to keep 1,500°C, so that the discharging of the molten slag slowed.
- the coke layer 25 is a layer with extremely many voids, the molten slag easily flows down through the voids and is uniformly exposed to a hot air while residing on the furnace bottom, thus free from even partial solidification.
- the coke layer 25 have many voids, it is possible to lower its resistance to air flow to keep the internal pressure in a furnace bottom portion at a proper level for continuously discharging the molten slag, even though it has a higher density than ashes or landfill wastes.
- the entire coke layer 25 can be kept stably and uniformly at a high temperature of about 1,500°C, thereby keeping the molten slag stably in a melting state.
- the pressure of a shroud air introduced through the plasma torch was set at 15 kPa in this Example, the pressure near the furnace bottom portion 22 was about I to 2 kPa because of the air flow resistance in the above coke layer 25 and the combustible waste layer 26. It was, however, sufficient to function as a pressure difference to push the molten slag out through furnace bottom portion 22. Even though the liquid surface of the molten slag is lowered to permit the hot air to eject from the furnace, the hot air' speed is low. Thus, by keeping the internal pressure of the furnace bottom portion 22 properly at a positive pressure, the stable, continuous discharging of the molten slag can be achieved.
- the properties of combustible wastes used in this Example are as follows; Type of combustible wastes general combustible wastes (mainly domestic garbage) Moisture content 46.5% by weight, Lower calorific value 8200 kJ/kg, Ash content 7.9% by weight,
- the above combustible wastes were gasification-melted under the following conditions; Amount of electric power supplied to plasma torch 360 MJ/hr, Amount of coke supplied 30 kg/hr, Amount of combustible wastes and/or ashes supplied 1,000 kg/hr, Total air volume 700 Nm 3 /hr, Air volume from plasma torch 150 Nm 3 /hr, Temperature of hot air supplied from plasma torch about 1,800°C, Temperature of coke layer 25 1,500°C, and Average internal pressure in furnace bottom portion 22 positive pressure of 1.5 kPa.
- the temperature in the furnace body 2 was substantially constant at about 1,500°C in the coke layer 25, and 500°C to 900°C in an upper space of the combustible waste layer 26. Because a hot air is blown from the plasma torch into a lower layer of the coke layer 25, it is possible to keep the entire coke layer 25 uniformly and stably at a high temperature of about 1,500°C, thereby keeping the molten slag stably in a melting state.
- the pressure of a shroud air introduced through the plasma torch was set at 14.7 kPa in this Example, the pressure near the furnace bottom portion 22 was about 1.5 kPa because of the air flow resistance in the coke layer 25 and the combustible waste layer 26. It was, however, sufficient to function as a pressure difference to push the molten slag out through the furnace bottom portion 22. Even though the liquid surface of the molten slag is lowered to permit a hot air to eject from the furnace, the hot air' speed is low. By lowering the internal pressure of the furnace bottom portion 22, the stable, continuous discharging of the molten slag can be achieved.
- Example 3 using combustible wastes with a lower calorific value lower than that of the combustible wastes of Example 3, the amount of electric power supplied to the plasma torch was increased.
- the following combustible wastes were gasification-melted under the same conditions as in Example 3 except for the following conditions.
- the molten slag could be kept stably in a melting state to continuously and stably discharge the molten slag.
- Type of combustible wastes general combustible wastes (mainly domestic garbage) Moisture content 71.3% by weight, Lower calorific value 3,400 kJ/kg, Ash content 14.2% by weight, and Amount of electric power supplied to plasma torch 790 MJ/hr.
- Example 3 using combustible wastes with a lower calorific value higher than that of the combustible wastes of Example 3, the amount of electric power supplied to the plasma torch was decreased to gasification-melt the combustible wastes.
- the gasification-melting of the combustible waste was conducted under the same conditions as in Example 3 except for the following conditions.
- the molten slag could be kept in a melting state stably, to carry out the continuous discharging of the molten slag stably.
- Type of combustible wastes general combustible wastes (mainly domestic garbage), Moisture content 30.1 % by weight, Lower calorific value 12,000 kJ/kg, Ash content 3.5% by weight, and Amount of electric power supplied to plasma torch 290 MJ/hr.
- Example 3 the amount of coke supplied to the following combustible wastes with a high lower calorific value was made smaller than those in Examples 3 to 5, to carry out gasification-melting.
- the gasification-melting conditions of the combustible wastes were the same as in Example 3 except for the following ones.
- the molten slag could be kept in a melting state stably, to carry out the continuous discharging of the molten slag stably.
- Type of combustible wastes general combustible wastes (mainly domestic garbage), Moisture content 29.2% by weight, Lower calorific value 9,800 kJ/kg, Ash content 3.2% by weight, Amount of electric power supplied to plasma torch 330 MJ/hr, and Amount of coke supplied 20 kg/hr.
- Example 6 gasification melting was carried out, with the combustible wastes of Example 6 provided with an increased lower calorific value, and with the decreased amount of electric power supplied to the plasma torch.
- the gasification-melting conditions of the combustible wastes were the same as in Example 6 except for the following ones.
- the molten slag could be kept in a melting state stably, to carry out the continuous discharging of the molten slag stably.
- Type of combustible wastes general combustible wastes (mainly domestic garbage), Moisture content 28.3% by weight, Lower calorific value 11,000 kJ/kg, Ash content 2.9% by weight, and Amount of electric power supplied to plasma torch 300 MJ/hr
- Example 7 using combustible wastes with a lower calorific value higher than that of the combustible wastes of Example 7, gasification melting was carried out with the decreased amount of electric power supplied to the plasma torch.
- the gasification-melting conditions of the combustible wastes were the same as in Example 7 except for the following ones.
- the molten slag could be kept stably in a melting state, to carry out the continuous discharging of the molten slag stably.
- Type of combustible wastes general combustible wastes (mainly domestic garbage), Moisture content 27.1% by weight, Lower calorific value ; 12,000 kJ/kg, Ash content 2.5% by weight, and Amount of electric power supplied to plasma torch 260 MJ/hr.
- Combustible wastes were gasification-melted in the same manner as in Example 5 except for decreasing the amount of electric power supplied to the plasma torch to 210 MJ/hr.
- the temperature in the coke layer was 1,200°C to 1,280°C, which was lower than that in Example 5. Accordingly, because the molten slag was solidified at the molten slag outlet 23 and the slag trough 15, the molten slag was not discharged continuously.
- the amount of coke necessary for continuously and stably gasification-melting 1,000 kg/hr of combustible wastes having a lower calorific value may usually be about 30 kg/hr, and that when the lower calorific value of the combustible wastes is reduced, the amount of electric power supplied to the plasma torch need only be increased.
- Examples 3 to 5 show cases where the short-range lower calorific value of the combustible wastes varies, while Examples 6 to 8 show cases where the long-range lower calorific value of the combustible wastes varies. It is clear that the increase of the long-range lower calorific value requires only the reduction of the amount of coke supplied. On the contrary, the reduction of the long-range lower calorific value requires only the increase of the amount of coke supplied.
- Type of combustible wastes general combustible wastes (mainly domestic garbage), Moisture content 55% by weight, Resin content 12% by weight, Lower calorific value 358 kJ/kg, Amount of combustible wastes supplied 1,000 kg/hr, Amount of coke supplied 20 kg/hr, Total air volume 700 Nm 3 /hr, Air volume from plasma torch 150 Nm 3 /hr, Air pressure from plasma torch 14.7 MPa, and H/D 2.0.
- Type of combustible wastes general combustible wastes (mainly domestic garbage), Moisture content 55% by weight, Resin content 12% by weight, Lower calorific value 358 kJ/kg, Amount of combustible wastes supplied 1,000 kg/hr, Amount of coke supplied 20 kg/hr, Total air volume 700 Nm 3 /hr, Air volume from plasma torch 150 Nm 3 /hr, Air pressure from plasma torch 14.7 MPa, and H/D 2.0.
- Combustible wastes having the same properties as in Example 9 were subjected to a gasification-melting treatment under the following conditions. No bridging of combustible wastes occurred in the gasification-melting furnace.
- the pressure in the furnace bottom portion 22 was a positive pressure of 1.5 kPa on average.
- the temperature in the furnace body 2 was substantially constant at about 1,500°C in the coke layer 25, and 500°C to 900°C in an upper space of the combustible waste layer 26. After passing about 60 minutes from the start of supplying combustible wastes, a molten slag started to be discharged from the molten slag outlet 23. The amount of the molten slag discharged was about 80 kg per 1 hour on average.
- Example 10 though the pressure of a shroud air blown from the plasma torch 11 was set at 14.7 kPa, the pressure in the furnace bottom portion 22 was about 5 kPa to 1.5 kPa because of the air flow resistance in the coke layer 25 and the combustible waste layer 26. It was, however, sufficient as a pressure difference to push the molten slag out from the molten slag outlet 23. Even if the liquid surface of the molten slag was lowered to permit a hot air to eject from the furnace, its speed was so low that there was no vigorous ejection of the molten slag.
- Combustible wastes were subjected to a gasification-melting treatment under the same conditions as in Example 9 except for changing H/D to 2.5.
- the internal pressure of the furnace bottom portion 22 was a positive pressure of 8 kPa on average.
- the gasification-melting furnace of the present invention can continuously gasification-melt combustible wastes and/or ashes and stably discharge the resultant molten slag.
- combustible wastes and/or ashes can be subjected to a gasification-melting treatment, without discharging smoke dust containing dioxin and heavy metals, and without accumulating the reaction products of calcium hydroxide in the system.
- the swirling flow of the exhaust gas can be controlled, thereby completely burning the exhaust gas, by disposing a baffle plate in an exhaust gas-introducing pipe connecting a primary incineration furnace and a secondary incineration furnace. Further, by supplying a secondary air in the same direction as the exhaust gas throttled by the baffle plate, the exhaust gas and the air are more strongly swirled in the secondary combustion furnace, so that the concentrations of carbon monoxide and hydrocarbons in the exhaust gas can effectively be reduced.
- the electrode holder of the present invention and the plasma torch comprising it are resistant to erosion and breakage at the time of mal-ignition or during ordinary use, thereby enjoying a long life.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Gasification And Melting Of Waste (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001031472A JP2002235916A (ja) | 2001-02-07 | 2001-02-07 | 廃棄物の燃焼処理装置 |
| JP2001314472 | 2001-02-07 | ||
| JP2001170983 | 2001-02-10 | ||
| JP2001170983A JP2002364817A (ja) | 2001-06-06 | 2001-06-06 | 塵芥の溶融方法 |
| JP2001249194 | 2001-08-20 | ||
| JP2001249194A JP2003056819A (ja) | 2001-08-20 | 2001-08-20 | 焼却灰或いは埋立てごみの溶融炉 |
| PCT/JP2002/000893 WO2002063213A1 (fr) | 2001-02-07 | 2002-02-04 | Four de fusion de gazeification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1367323A1 true EP1367323A1 (fr) | 2003-12-03 |
Family
ID=27345935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02710493A Withdrawn EP1367323A1 (fr) | 2001-02-07 | 2002-02-04 | Four de fusion de gazeification |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP1367323A1 (fr) |
| WO (1) | WO2002063213A1 (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012112064A1 (fr) * | 2011-02-18 | 2012-08-23 | Крено Инвест Са | Procédé de transformation de déchets solides ou liquides provenant de l'industrie ou de la consommation dans du plasma thermique et installation pour sa mise en oeuvre |
| RU2575719C2 (ru) * | 2011-02-18 | 2016-02-20 | Сергей Александрович Вощинин | Способ переработки твердых и жидких отходов производства и потребления в термической плазме и установка для его осуществления |
| CN107606621A (zh) * | 2017-08-31 | 2018-01-19 | 中国科学院力学研究所 | 一种基于等离子体的离心式固体污染物高温熔融炉 |
| CN115245951A (zh) * | 2021-08-09 | 2022-10-28 | 江苏美东环境科技有限公司 | 提高等离子体气化熔融炉处理危废物热效率的方法 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2001501C2 (nl) * | 2008-04-18 | 2009-10-20 | Dhv B V | Werkwijze voor het vervaardigen van energie en synthetische bouwmaterialen, zoals basalt, grind, bakstenen, tegels enzovoort en dergelijke materialen uit hoogcalorisch afval en minerale reststoffen. |
| CN106594756B (zh) * | 2015-10-15 | 2019-10-08 | 圣堃环保科技（上海）有限公司 | 一种垃圾焚烧炉 |
| CN106082571A (zh) * | 2016-08-04 | 2016-11-09 | 山东奥特高科环保科技有限公司 | 低热值污泥三化处理工艺及装置 |
| CN109404918B (zh) * | 2018-12-06 | 2023-10-31 | 航天神禾(北京)环保有限公司 | 一体化废物热解气化炉 |
| CN111780116B (zh) * | 2020-06-08 | 2021-10-08 | 华中科技大学 | 一种基于等离子体的舰船有机废弃物气化焚烧处理系统 |
| CN113237076A (zh) * | 2021-04-23 | 2021-08-10 | 姚志勇 | 等离子火焰助燃消除高烟固体燃料烟尘的方法 |
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| JPS4836265B1 (fr) * | 1969-12-18 | 1973-11-02 | ||
| JPS5441573A (en) * | 1977-09-08 | 1979-04-02 | Mitsubishi Heavy Ind Ltd | Waste matter treatment device |
| SE451033B (sv) * | 1982-01-18 | 1987-08-24 | Skf Steel Eng Ab | Sett och anordning for omvandling av avfallsmaterial med plasmagenerator |
| JPH03274309A (ja) * | 1990-03-23 | 1991-12-05 | Nippon Puraiburiko Kk | 高分子系焼却物の焼却炉 |
| JPH05106826A (ja) * | 1991-10-14 | 1993-04-27 | Nippon Steel Corp | 廃棄物の溶融炉 |
| JP2768146B2 (ja) * | 1992-06-15 | 1998-06-25 | 日本鋼管株式会社 | 廃棄物溶融炉の操業方法 |
| JPH0996406A (ja) * | 1995-09-29 | 1997-04-08 | Nkk Corp | 給塵方法 |
| JPH10300043A (ja) * | 1997-02-27 | 1998-11-13 | Shin Meiwa Ind Co Ltd | 廃棄物燃料燃焼システム及び廃棄物燃料燃焼システムにおけるバグフィルタ捕集物処理方法 |
| JPH11182826A (ja) * | 1997-12-19 | 1999-07-06 | Research Institute Of Innovative Technology For The Earth | 竪型溶融炉 |
| JPH11201431A (ja) * | 1998-01-08 | 1999-07-30 | Chiyoda Corp | 直接溶融炉 |
| JP3977939B2 (ja) * | 1998-09-30 | 2007-09-19 | 新日鉄エンジニアリング株式会社 | 廃棄物溶融処理方法及び処理設備 |
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2002
- 2002-02-04 EP EP02710493A patent/EP1367323A1/fr not_active Withdrawn
- 2002-02-04 WO PCT/JP2002/000893 patent/WO2002063213A1/fr not_active Ceased
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012112064A1 (fr) * | 2011-02-18 | 2012-08-23 | Крено Инвест Са | Procédé de transformation de déchets solides ou liquides provenant de l'industrie ou de la consommation dans du plasma thermique et installation pour sa mise en oeuvre |
| RU2575719C2 (ru) * | 2011-02-18 | 2016-02-20 | Сергей Александрович Вощинин | Способ переработки твердых и жидких отходов производства и потребления в термической плазме и установка для его осуществления |
| CN107606621A (zh) * | 2017-08-31 | 2018-01-19 | 中国科学院力学研究所 | 一种基于等离子体的离心式固体污染物高温熔融炉 |
| CN115245951A (zh) * | 2021-08-09 | 2022-10-28 | 江苏美东环境科技有限公司 | 提高等离子体气化熔融炉处理危废物热效率的方法 |
| CN115245951B (zh) * | 2021-08-09 | 2024-01-02 | 江苏美东环境科技有限公司 | 提高等离子体气化熔融炉处理危废物热效率的方法 |
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| Publication number | Publication date |
|---|---|
| WO2002063213A1 (fr) | 2002-08-15 |
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