EP1210061A1 - Use of salts for improving the absorption qualities of anionic direct dyes - Google Patents
Use of salts for improving the absorption qualities of anionic direct dyesInfo
- Publication number
- EP1210061A1 EP1210061A1 EP01921361A EP01921361A EP1210061A1 EP 1210061 A1 EP1210061 A1 EP 1210061A1 EP 01921361 A EP01921361 A EP 01921361A EP 01921361 A EP01921361 A EP 01921361A EP 1210061 A1 EP1210061 A1 EP 1210061A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- salt
- component
- anionic
- calcium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 43
- 125000000129 anionic group Chemical group 0.000 title claims abstract description 31
- 239000000982 direct dye Substances 0.000 title claims abstract description 19
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 10
- 210000004209 hair Anatomy 0.000 claims abstract description 26
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 102000011782 Keratins Human genes 0.000 claims abstract description 12
- 108010076876 Keratins Proteins 0.000 claims abstract description 12
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 6
- 235000005985 organic acids Nutrition 0.000 claims abstract description 5
- -1 sorbates Chemical class 0.000 claims description 25
- 239000000975 dye Substances 0.000 claims description 17
- 239000003086 colorant Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
- 239000011575 calcium Substances 0.000 claims description 13
- 229910052791 calcium Inorganic materials 0.000 claims description 13
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 12
- 238000004043 dyeing Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 6
- 239000001103 potassium chloride Substances 0.000 claims description 6
- 235000011164 potassium chloride Nutrition 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 235000021317 phosphate Nutrition 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 claims description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 claims description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
- 229940009098 aspartate Drugs 0.000 claims description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-L aspartate group Chemical class N[C@@H](CC(=O)[O-])C(=O)[O-] CKLJMWTZIZZHCS-REOHCLBHSA-L 0.000 claims description 2
- 150000001649 bromium compounds Chemical class 0.000 claims description 2
- 150000001805 chlorine compounds Chemical group 0.000 claims description 2
- 229940001468 citrate Drugs 0.000 claims description 2
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 2
- 229940044170 formate Drugs 0.000 claims description 2
- 150000004675 formic acid derivatives Chemical class 0.000 claims description 2
- 229940050410 gluconate Drugs 0.000 claims description 2
- 229930195712 glutamate Natural products 0.000 claims description 2
- 150000002306 glutamic acid derivatives Chemical class 0.000 claims description 2
- 229940001447 lactate Drugs 0.000 claims description 2
- 150000003893 lactate salts Chemical class 0.000 claims description 2
- 229940049920 malate Drugs 0.000 claims description 2
- 150000004701 malic acid derivatives Chemical class 0.000 claims description 2
- PXQPEWDEAKTCGB-UHFFFAOYSA-N orotic acid Chemical compound OC(=O)C1=CC(=O)NC(=O)N1 PXQPEWDEAKTCGB-UHFFFAOYSA-N 0.000 claims description 2
- 150000003891 oxalate salts Chemical class 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 2
- 239000002453 shampoo Substances 0.000 claims description 2
- 229940075554 sorbate Drugs 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- 150000003892 tartrate salts Chemical class 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-L malate(2-) Chemical compound [O-]C(=O)C(O)CC([O-])=O BJEPYKJPYRNKOW-UHFFFAOYSA-L 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 13
- 238000004040 coloring Methods 0.000 abstract description 5
- 230000001590 oxidative effect Effects 0.000 abstract description 4
- 239000002253 acid Substances 0.000 description 30
- 235000014113 dietary fatty acids Nutrition 0.000 description 27
- 239000000194 fatty acid Substances 0.000 description 27
- 229930195729 fatty acid Natural products 0.000 description 27
- 150000004665 fatty acids Chemical class 0.000 description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 239000006071 cream Substances 0.000 description 11
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 description 7
- 235000013305 food Nutrition 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 description 6
- 235000019233 fast yellow AB Nutrition 0.000 description 6
- AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 5
- 229940081733 cetearyl alcohol Drugs 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- UBHWBODXJBSFLH-UHFFFAOYSA-N hexadecan-1-ol;octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO.CCCCCCCCCCCCCCCCCCO UBHWBODXJBSFLH-UHFFFAOYSA-N 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- FAPWYRCQGJNNSJ-UBKPKTQASA-L calcium D-pantothenic acid Chemical compound [Ca+2].OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O.OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O FAPWYRCQGJNNSJ-UBKPKTQASA-L 0.000 description 3
- 229960002079 calcium pantothenate Drugs 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- CEZCCHQBSQPRMU-UHFFFAOYSA-L chembl174821 Chemical compound [Na+].[Na+].COC1=CC(S([O-])(=O)=O)=C(C)C=C1N=NC1=C(O)C=CC2=CC(S([O-])(=O)=O)=CC=C12 CEZCCHQBSQPRMU-UHFFFAOYSA-L 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
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- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 2
- KKBFCPLWFWQNFB-UHFFFAOYSA-M CI Acid Orange 3 Chemical compound [Na+].[O-][N+](=O)C1=CC([N+](=O)[O-])=CC=C1NC(C=C1S([O-])(=O)=O)=CC=C1NC1=CC=CC=C1 KKBFCPLWFWQNFB-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
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- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
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- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 235000012741 allura red AC Nutrition 0.000 description 1
- 239000004191 allura red AC Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N ammonium carbonate Chemical class N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 239000004161 brilliant blue FCF Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001913 cellulose Chemical class 0.000 description 1
- 229920002678 cellulose Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- OIQPTROHQCGFEF-UHFFFAOYSA-L chembl1371409 Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-UHFFFAOYSA-L 0.000 description 1
- DZCOAQKTFAIFRV-UHFFFAOYSA-N chembl3306827 Chemical compound CC1=CC(C)=C(S(O)(=O)=O)C=C1N=NC1=CC(S(O)(=O)=O)=C(C=CC=C2)C2=C1O DZCOAQKTFAIFRV-UHFFFAOYSA-N 0.000 description 1
- 229940107161 cholesterol Drugs 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 229940096890 d&c violet no. 2 Drugs 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- JFVXEJADITYJHK-UHFFFAOYSA-L disodium 2-(3-hydroxy-5-sulfonato-1H-indol-2-yl)-3-oxoindole-5-sulfonate Chemical compound [Na+].[Na+].Oc1c([nH]c2ccc(cc12)S([O-])(=O)=O)C1=Nc2ccc(cc2C1=O)S([O-])(=O)=O JFVXEJADITYJHK-UHFFFAOYSA-L 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- NJDNXYGOVLYJHP-UHFFFAOYSA-L disodium;2-(3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=CC(=O)C=C2OC2=CC([O-])=CC=C21 NJDNXYGOVLYJHP-UHFFFAOYSA-L 0.000 description 1
- JUOPAVUCOCCTBO-UHFFFAOYSA-L disodium;2-[[4-[ethyl-[(4-sulfonatophenyl)methyl]amino]phenyl]-[4-[ethyl-[(4-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC(=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=C(S([O-])(=O)=O)C=C1 JUOPAVUCOCCTBO-UHFFFAOYSA-L 0.000 description 1
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229940057915 fd&c red no. 4 Drugs 0.000 description 1
- 229940051147 fd&c yellow no. 6 Drugs 0.000 description 1
- YKGGGCXBWXHKIZ-UHFFFAOYSA-N fluorescein (acid form) Chemical compound OC(=O)C1=CC=CC=C1C1=C2C=CC(=O)C=C2OC2=CC(O)=CC=C21 YKGGGCXBWXHKIZ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940055726 pantothenic acid Drugs 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 239000011713 pantothenic acid Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 235000012731 ponceau 4R Nutrition 0.000 description 1
- 239000004175 ponceau 4R Substances 0.000 description 1
- 235000019237 ponceau SX Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 235000012752 quinoline yellow Nutrition 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- FZUOVNMHEAPVBW-UHFFFAOYSA-L quinoline yellow ws Chemical compound [Na+].[Na+].O=C1C2=CC=CC=C2C(=O)C1C1=NC2=C(S([O-])(=O)=O)C=C(S(=O)(=O)[O-])C=C2C=C1 FZUOVNMHEAPVBW-UHFFFAOYSA-L 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- FPSFKBGHBCHTOE-UHFFFAOYSA-M sodium 1-[(3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl)diazenyl]-4-sulfonaphthalen-2-olate Chemical compound [Na+].O=C1C(N=NC=2C3=CC=CC=C3C(=CC=2O)S([O-])(=O)=O)C(C)=NN1C1=CC=CC=C1 FPSFKBGHBCHTOE-UHFFFAOYSA-M 0.000 description 1
- DJDYMAHXZBQZKH-UHFFFAOYSA-M sodium;1-amino-4-(cyclohexylamino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1CCCCC1 DJDYMAHXZBQZKH-UHFFFAOYSA-M 0.000 description 1
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Chemical class 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940100459 steareth-20 Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- YXHBBEQKMVAJOH-UHFFFAOYSA-K trisodium;5-oxido-4-[(4-sulfonatophenyl)diazenyl]-1-(4-sulfophenyl)pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].C1=CC(S(=O)(=O)O)=CC=C1N1C([O-])=C(N=NC=2C=CC(=CC=2)S([O-])(=O)=O)C(C([O-])=O)=N1 YXHBBEQKMVAJOH-UHFFFAOYSA-K 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- OIHZGFWAMWHYPA-UHFFFAOYSA-N xanthylium Chemical compound C1=CC=CC2=CC3=CC=CC=C3[O+]=C21 OIHZGFWAMWHYPA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/673—Vitamin B group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
Definitions
- the present invention relates to the use of physiologically tolerable salts of inorganic or organic acids to improve the absorption behavior of anionic direct dyes, a 2-stage process for dyeing fibers and a multicomponent agent for non-oxidative dyeing of fibers (in particular keratin fibers such as human Hair), one component of which contains a colorant based on anionic direct dyes and the other component of which contains the physiologically tolerable salts.
- Non-ionic and cationic dyes for example from the group of nitro dyes, azo dyes or anthraquinone and triphenylmethane dyes, are preferably used in commercially available non-oxidative colorants (so-called toning agents). Such tints are usually sufficiently gentle on the hair and survive several washes.
- anionic dyes based on anionic dyes are predominantly used. Since keratin is negatively charged, if at all, the anionic dye, which is also negatively charged, can be rejected, which is why with anionic dyes in the acidic pH range, only relatively weak, uneven and poorly washable stains are obtained, while in the neutral and basic milieu these Dyes practically do not stain the keratin fiber at all.
- the build-up behavior can be improved by adding so-called Carriem or penetration accelerators, such as benzyl alcohol or phenoxyethanol, but at the same time the already relatively strong skin tint is significantly enhanced by anionic dyes.
- anionic dyes have currently only gained particular importance in Japan, since none of the usual direct draws for approved hair dyes are included in the Japanese positive list.
- inorganic or organic salts to non-oxidative hair colorants
- the use of these salts for improvement
- the absorption behavior of anionic direct dyes is completely new and, based on the prior art, was also not predictable.
- the present application therefore relates to the use of one or more physiologically tolerable salts of inorganic and / or organic acids to improve the absorption behavior of anionic direct dyes on keratin fibers, such as human hair.
- the salts in particular are the chlorides, bromides, sulfates, lactates, tartrates, citrates, malates, glycolates, glycerophoshates, phantothenates, phosphinates, glutamates, gluconates, phosphates, formates, sorbates, aspartates, orotates, oxalates and acetates of sodium, potassium, magnesium , Calcium, ammonium, aluminum or zinc into consideration, the salts of calcium, magnesium, sodium and potassium, and in particular sodium chloride, potassium chloride, magnesium chloride, calcium chloride and calcium panthotenate and mixtures thereof, being preferred.
- the salts of potassium and calcium are particularly preferred, in particular potassium chloride, calcium chloride and calcium panthotenate.
- the salts can be used both individually and in the form of a mixture of several salts.
- the salts can be formulated both in solid form, the salts being mixed with water or the colorant before use, and in the form of an aqueous preparation.
- the total amount of salt used, based on the aqueous preparation or the colorant, is about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight, in particular 0.2 to 2.5 percent by weight.
- Another object of the present application is a multi-stage process for dyeing keratin fibers, especially human hair, in which the fiber is first pretreated with one or more physiologically tolerable salts of an aqueous and / or organic acid-containing preparation, and then with at least one a dye containing an anionic direct dye is colored.
- an aqueous preparation containing the physiologically acceptable salts is applied to the keratin fiber; for example by spraying an aqueous salt solution.
- the colorant is then applied to the fiber pretreated with the salt, the colorant depending on the desired depth of color for about 5 to 60 minutes, preferably 15 to 30 minutes, at a temperature of about 20 to 50 degrees Celsius, in particular at 30 to 40 degrees Celsius.
- the hair is rinsed with water, optionally washed with a shampoo and dried.
- Another object of the present application is a multi-component kit for carrying out the dyeing process described above, which contains a first component containing at least one physiologically compatible salt of an inorganic or organic acid and a second component containing at least one anionic direct dye.
- the first component can be present both in solid form and in the form of an aqueous preparation and contains at least one physiologically compatible salt of an inorganic or organic acid, preferably a chloride, bromide, sulfate, lactate, tartrate, citrate, malate, Glycolate, glycerophoshate, phantothenate, phosphinate, glutamate, gluconate, phosphate, formate, sorbate, aspartate, orotate, oxalate or acetate of sodium, potassium, magnesium, calcium, ammonium, aluminum or zinc, the salts of calcium and potassium, and in particular the sodium chloride, potassium chloride, magnesium chloride, calcium chloride and calcium panthotenate and mixtures thereof, and optionally additives. If the first component is in solid form, it must be mixed with water before use.
- the salts of potassium and calcium are particularly preferred, in particular potassium chloride, calcium chloride and calcium panthotenate.
- the total amount of salt used in the aqueous preparation is about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight, in particular 0.2 to 2.5 percent by weight.
- the colorant can be in the form of a solution, in particular an aqueous or aqueous-alcoholic solution, a cream, a gel, an aerosol foam or an emulsion, and is a mixture of the dye components with the additives customary for such preparations.
- anionic dyes 6-hydroxy-5 - [(4-sulfophenyl) azo] -2-naphthalenesulfonic acid disodium salt (CM 5985; Food Yellow No. 3; FD&C Yellow No. 6), 2,4-dinitro -1-naphthol-7-sulfonic acid disodium salt (CI10316; Acid Yellow No. 1; Food Yellow No. 1), 2- (indan-1, 3-dion-2-yl) quinolin-x, x-sulfonic acid (mixture from mono- and disulfonic acid) (CI47005; D&C Yellow No. 10; Food Yellow No. 13; Acid Yellow No.
- the substantive dyes are used in the colorant in a total amount of about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight.
- the colorant can, if necessary, contain other customary and suitable synthetic or natural substantive dyes.
- Usual additives in solutions, creams, emulsions, aerosol foams or gels are, for example, solvents such as water, lower aliphatic alcohols, for example ethanol, n-propanol and isopropanol, glycol ethers or glycols such as glycerol and 1,2-propanediol, which are used alone or in combination with one another become.
- solvents such as water, lower aliphatic alcohols, for example ethanol, n-propanol and isopropanol, glycol ethers or glycols such as glycerol and 1,2-propanediol, which are used alone or in combination with one another become.
- the tinting agent for cosmetic agents can be known additives, for example wetting agents or emulsifiers from the classes of anionic, cationic, amphoteric or nonionic surface-active substances, such as fatty alcohol sulfates, oxyethylated fatty alcohol sulfates, alkyl sulfonates, alkylbenzenesulfonates, alkyltrimethylammonium salts, alkylbetaoleols, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids,
- thickeners such as higher fatty alcohols, starch or cellulose derivatives, perfumes, hair pretreatment agents, conditioners, hair swelling agents, preservatives, petroleum jelly, paraffin oil and fatty acids as well as care agents such as cationic resins, lanolin derivatives, cholesterol, pantothenic acid and betaine.
- the ingredients mentioned are in the usual amounts for such purposes used, for example the wetting agents and emulsifiers in concentrations of approximately 0.5 to 30 percent by weight (based on the colorant), the thickeners in an amount of approximately 0.1 to 25 percent by weight (based on the colorant) and the care substances in one concentration from about 0.1 to 5.0 percent by weight (based on the colorant).
- the colorant of the second component additionally contains at least one surface-active compound from the group of anionic, amphoteric and nonionic wetting agents and surfactants, the formulation as non-ionic, anionic or amphoteric cream being particularly preferred.
- the addition of the surface-active compounds results in a particularly low skin coloration.
- the pH of the ready-to-use colorant is about 1 to 9, in particular 2.5 to 8.5.
- the desired pH can be adjusted by adding organic or inorganic acids or alkalizing agents, for example with phosphoric acid, hydrochloric acid, acetic acid, salicylic acid, malonic acid, gluconic acid lactone or ⁇ -hydroxycarboxylic acids such as glycolic acid, lactic acid, tartaric acid, citric acid or malic acid, or alkalizing agents Agents such as alkanolamines, alkylamines, alkali hydroxides, ammonium hydroxide, alkali carbonates, ammonium carbonates or alkali phosphates.
- physiologically compatible inorganic and / or organic salts enable a significant improvement in the absorption behavior of anionic dyes on keratin fibers such as For example, hair, wool or silk, which enables more intensive and long-lasting dyeing to be achieved with a low skin coloration.
- the salts are particularly well suited for improving the absorption behavior of anionic direct dyes on keratin fibers, they can also be used very advantageously in the dyeing of other natural or synthetic fibers, for example cotton, viscose, nylon or cellulose acetate, with anionic direct dyes.
- Bleached hair is first pretreated with a spray solution that contains 1 percent by weight calcium chloride and 1 percent by weight potassium chloride. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After a Exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A brown color is obtained.
- Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A brown color is obtained.
- Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. An orange-red color is obtained.
- Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A violet color is obtained.
- the tinting agents according to Examples 1 to 5 are in each case with and without pretreatment in the manner described in the Examples Coloring hair used and then compared the intensity of the dyeings obtained. The results are summarized in Table 2 below.
- the L * a * b * color measurement values determined in the present examples were determined using a color measuring device from Minolta, type Chromameter II.
- the L-value stands for the brightness (i.e. the lower the L-value, the greater the color intensity)
- the a-value is a measure of the red component (i.e. the larger the a-value, the greater the red component is larger).
- the b-value is a measure of the blue component of the color, the more negative the b-value, the greater the blue component.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the use of physiologically compatible salts of inorganic or organic acids for improving the absorption qualities of anionic direct dyes. Also disclosed is a two-step procedure for colouring fibres, in addition to a multicomponent agent for non-oxidative fibre colouring ( in particular, keratin fibres such as human hair) whereby one component contains a colouring agent based on anionic direct dyes and another component contains physiologically compatible salts.
Description
B e s c h r e i b u n g Description
Verwendung von Salzen zur Verbesserung des Aufziehverhaltens von anionischen direktziehenden FarbstoffenUse of salts to improve the absorption behavior of anionic direct dyes
Gegenstand der vorliegenden Erfindung ist die Verwendung von physiologisch verträglichen Salzen anorganischer oder organischer Säuren zur Verbesserung des Aufziehverhaltens von anionischen direktziehenden Farbstoffen, ein 2-stufiges Verfahren zum Färben von Fasern sowie ein Mehrkomponenten-Mittel zur nicht-oxidativen Färbung von Fasern (insbesondere Keratinfasem wie menschlichen Haaren), dessen eine Komponente ein Färbemittel auf der Basis von anionischen direktziehenden Farbstoffen enthält und dessen andere Komponente die physiologisch verträglichen Salze enthält.The present invention relates to the use of physiologically tolerable salts of inorganic or organic acids to improve the absorption behavior of anionic direct dyes, a 2-stage process for dyeing fibers and a multicomponent agent for non-oxidative dyeing of fibers (in particular keratin fibers such as human Hair), one component of which contains a colorant based on anionic direct dyes and the other component of which contains the physiologically tolerable salts.
In handelsüblichen nicht-oxidativen Färbemitteln (sogenannten Tönungsmitteln) werden vorzugsweise nicht-ionische und kationische Farbstoffe, beispielsweise aus der Gruppe der Nitrofarbstoffe, Azofarbstoffe oder Anthrachinon- und Triphenylmethanfarbstoffe, verwendet. Derartige Tönungen sind in der Regel ausreichend haarschonend und überstehen mehrere Haarwäschen.Non-ionic and cationic dyes, for example from the group of nitro dyes, azo dyes or anthraquinone and triphenylmethane dyes, are preferably used in commercially available non-oxidative colorants (so-called toning agents). Such tints are usually sufficiently gentle on the hair and survive several washes.
Unter bestimmten Umständen (beispielsweise aufgrund der Gesetzgebung) werden jedoch in einigen Ländern trotz der schlechteren färberischen Eigenschaften der anionischen Farbstoffe überwiegend Färbemittel auf der Basis von anionischen Farbstoffe eingesetzt.
Da Keratin, wenn überhaupt, negativ geladen ist, kann es zur Abstossung des ebenfalls negativ geladenen anionischen Farbstoffes kommen, weshalb mit anionischen Farbstoffen im sauren pH-Bereich lediglich relativ schwache, ungleichmässige und wenig waschbeständige Färbungen erhalten werden, während im neutralen und basischen Milieu diese Farbstoffe die Keratinfaser praktisch überhaupt nicht anfärben. Das Aufziehverhalten lässt sich zwar durch den Zusatz von sogenannten Carriem oder Penetrationsbeschleunigern, wie zum Beispiel Benzyl- alkohol oder Phenoxyethanol, verbessern, gleichzeitig wird jedoch die an sich schon relativ starke Hautanfärbung durch anionische Farbstoffe noch deutlich verstärkt. In Anbetracht der vorgenannten Nachteile haben anionische Farbstoffe gegenwärtig nur in Japan eine besondere Bedeutung erlangt, da in der japanischen Positivliste für zugelassene Haarfarbstoffe keine der sonst üblichen Direktzieher enthalten sind.Under certain circumstances (for example due to legislation), however, in some countries, despite the poorer coloring properties of the anionic dyes, dyes based on anionic dyes are predominantly used. Since keratin is negatively charged, if at all, the anionic dye, which is also negatively charged, can be rejected, which is why with anionic dyes in the acidic pH range, only relatively weak, uneven and poorly washable stains are obtained, while in the neutral and basic milieu these Dyes practically do not stain the keratin fiber at all. The build-up behavior can be improved by adding so-called Carriem or penetration accelerators, such as benzyl alcohol or phenoxyethanol, but at the same time the already relatively strong skin tint is significantly enhanced by anionic dyes. In view of the above-mentioned disadvantages, anionic dyes have currently only gained particular importance in Japan, since none of the usual direct draws for approved hair dyes are included in the Japanese positive list.
Die Verbesserung des Aufziehverhaltens von anionischen Farbstoffen bei gleichzeitig akzeptabler Hautanfärbung und gutem Ausgleichsvermögen stellt daher ein bisher ungelöstes Problem dar. Erfindungsgemäß wird diese Aufgabe durch den Einsatz von physiologisch verträglichen Salzen anorganischer oder organischer Säuren gelöst.The improvement in the absorption behavior of anionic dyes with at the same time acceptable skin coloration and good leveling capacity therefore represents a problem that has not yet been solved. According to the invention, this object is achieved by the use of physiologically tolerable salts of inorganic or organic acids.
Der Zusatz von anorganischen oder organischen Salzen zu nicht- oxidativen Haarfärbemitteln ist zwar prinzipiell aus dem Stand der Technik (beispielsweise der EP-OS 0 806 199; DE-PS 19640 792 oder DE-OS 1942 390) bekannt, die Verwendung dieser Salze zur Verbesserung des Aufziehverhaltens von anionischen direktziehenden Farbstoffen ist jedoch völlig neu und war aufgrund des Standes der Technik auch nicht vorhersehbar.
Gegenstand der vorliegenden Anmeldung ist daher die Verwendung eines oder mehrerer physiologisch verträglicher Salze anorganischer und/oder organischer Säuren zur Verbesserung des Aufziehverhaltens von anionischen direktziehenden Farbstoffen auf keratinische Fasern, wie zum Beispiel menschlichen Haaren.The addition of inorganic or organic salts to non-oxidative hair colorants is known in principle from the prior art (for example EP-OS 0 806 199; DE-PS 19640 792 or DE-OS 1942 390), the use of these salts for improvement However, the absorption behavior of anionic direct dyes is completely new and, based on the prior art, was also not predictable. The present application therefore relates to the use of one or more physiologically tolerable salts of inorganic and / or organic acids to improve the absorption behavior of anionic direct dyes on keratin fibers, such as human hair.
Als Salze kommen insbesondere die Chloride, Bromide, Sulfate, Lactate, Tartrate, Citrate, Malate, Glycolate, Glycerophoshate, Phantothenate, Phosphinate, Glutamate, Gluconate, Phosphate, Formiate, Sorbate, Aspartate, Orotate, Oxalate und Acetate des Natriums, Kaliums, Magnesiums, Caiciums, Ammoniums, Aluminiums oder Zinks in Betracht, wobei die Salze des Caiciums, Magnesiums, Natriums und Kaliums, und insbesondere das Natriumchlorid, Kaliumchlorid, Magnesiumchlorid, Calciumchlorid und Calciumpanthotenat sowie deren Mischungen, bevorzugt sind. Besonders bevorzugt sind hierbei die Salze des Kaliums und Caiciums, insbesondere das Kaliumchlorid, Calciumchlorid und Calciumpanthotenat.The salts in particular are the chlorides, bromides, sulfates, lactates, tartrates, citrates, malates, glycolates, glycerophoshates, phantothenates, phosphinates, glutamates, gluconates, phosphates, formates, sorbates, aspartates, orotates, oxalates and acetates of sodium, potassium, magnesium , Calcium, ammonium, aluminum or zinc into consideration, the salts of calcium, magnesium, sodium and potassium, and in particular sodium chloride, potassium chloride, magnesium chloride, calcium chloride and calcium panthotenate and mixtures thereof, being preferred. The salts of potassium and calcium are particularly preferred, in particular potassium chloride, calcium chloride and calcium panthotenate.
Die Salze können sowohl einzeln als auch in Form eines Gemisches mehrerer Salze verwendet werden. Hierbei können die Salze sowohl in fester Form, wobei die Salze vor der Anwendung mit Wasser oder dem Färbemittel vermischt werden, als auch in Form einer wässrigen Zubereitung konfektioniert sein.The salts can be used both individually and in the form of a mixture of several salts. Here, the salts can be formulated both in solid form, the salts being mixed with water or the colorant before use, and in the form of an aqueous preparation.
Die Gesamteinsatzmenge des Salzes beträgt -bezogen auf die wässrige Zubereitung beziehungsweise das Färbemittel- etwa 0,01 bis 10 Gewichtsprozent, vorzugsweise 0,1 bis 5 Gewichtsprozent, insbesondere 0,2 bis 2,5 Gewichtsprozent.
Ein weiterer Gegenstand der vorliegenden Anmeldung ist ein mehrstufiges Verfahren zur Färbung keratinischer Fasern, insbesondere menschlicher Haare, bei dem die Faser zunächst mit einer ein oder mehrere physiologisch verträgliche Salze einer anorganischen und/oder organischen Säure enthaltenden wässrigen Zubereitung vorbehandelt wird, und anschliessend mit einem mindestens einen anionischen direktziehenden Farbstoff enthaltenden Färbemittel gefärbt wird.The total amount of salt used, based on the aqueous preparation or the colorant, is about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight, in particular 0.2 to 2.5 percent by weight. Another object of the present application is a multi-stage process for dyeing keratin fibers, especially human hair, in which the fiber is first pretreated with one or more physiologically tolerable salts of an aqueous and / or organic acid-containing preparation, and then with at least one a dye containing an anionic direct dye is colored.
Zunächst wird eine die physiologisch verträglichen Salze enthaltende wässrige Zubereitung auf die Keratinfaser aufgetragen; beispielsweise durch Aufsprühen einer wässrigen Salzlösung. Anschliessend wird das Färbemittel auf die mit dem Salz vorbehandelte Faser aufgetragen, wobei man das Färbemittel je nach gewünschter Farbtiefe etwa 5 bis 60 Minuten, vorzugsweise 15 bis 30 Minuten, bei einer Temperatur von etwa 20 bis 50 Grad Celsius, insbesondere bei 30 bis 40 Grad Celsius, einwirken lässt. Abschliessend wird das Haar mit Wasser gespült, gegebenenfalls mit einem Shampoo gewaschen und getrocknet.First, an aqueous preparation containing the physiologically acceptable salts is applied to the keratin fiber; for example by spraying an aqueous salt solution. The colorant is then applied to the fiber pretreated with the salt, the colorant depending on the desired depth of color for about 5 to 60 minutes, preferably 15 to 30 minutes, at a temperature of about 20 to 50 degrees Celsius, in particular at 30 to 40 degrees Celsius. Finally, the hair is rinsed with water, optionally washed with a shampoo and dried.
Ein weiterer Gegenstand der vorliegenden Anmeldung ist ein Mehrkomponenten-Kit zur Durchführung des vorstehend beschriebenen Färbeverfahrens, welcher eine mindestens ein physiologisch verträgliches Salz einer anorganischen oder organischen Säure enthaltende 1. Komponente und eine mindestens einen anionischen direktziehenden Farbstoff enthaltende 2. Komponente enthält.Another object of the present application is a multi-component kit for carrying out the dyeing process described above, which contains a first component containing at least one physiologically compatible salt of an inorganic or organic acid and a second component containing at least one anionic direct dye.
Die 1. Komponente kann sowohl in fester Form als auch in Form einer wässrigen Zubereitung vorliegen und enthält mindestens ein physiologisch verträgliches Salz einer anorganischen oder organischen Säure, vorzugsweise ein Chlorid, Bromid, Sulfat, Lactat, Tartrat, Citrat, Malat,
Glycolat, Glycerophoshat, Phantothenat, Phosphinat, Glutamat, Gluconat, Phosphat, Formiat, Sorbat, Aspartat, Orotat, Oxalat oder Acetat des Natriums, Kaliums, Magnesiums, Caiciums, Ammoniums, Aluminiums oder Zinks, wobei die Salze des Caiciums und Kaliums, und insbesondere das Natriumchlorid, Kaliumchlorid, Magnesiumchlorid, Calciumchlorid und Calciumpanthotenat sowie deren Mischungen, und gegebenenfalls Zusatzstoffe. Sofern die 1. Komponente in fester Form vorliegt, muss sie vor der Anwendung mit Wasser vermischt werden. Besonders bevorzugt sind hierbei die Salze des Kaliums und Caiciums, insbesondere das Kaliumchlorid, Calciumchlorid und Calciumpanthotenat.The first component can be present both in solid form and in the form of an aqueous preparation and contains at least one physiologically compatible salt of an inorganic or organic acid, preferably a chloride, bromide, sulfate, lactate, tartrate, citrate, malate, Glycolate, glycerophoshate, phantothenate, phosphinate, glutamate, gluconate, phosphate, formate, sorbate, aspartate, orotate, oxalate or acetate of sodium, potassium, magnesium, calcium, ammonium, aluminum or zinc, the salts of calcium and potassium, and in particular the sodium chloride, potassium chloride, magnesium chloride, calcium chloride and calcium panthotenate and mixtures thereof, and optionally additives. If the first component is in solid form, it must be mixed with water before use. The salts of potassium and calcium are particularly preferred, in particular potassium chloride, calcium chloride and calcium panthotenate.
Die Gesamteinsatzmenge des Salzes beträgt in der wässrigen Zubereitung etwa 0,01 bis 10 Gewichtsprozent, vorzugsweise 0,1 bis 5 Gewichtsprozent, insbesondere 0,2 bis 2,5 Gewichtsprozent.The total amount of salt used in the aqueous preparation is about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight, in particular 0.2 to 2.5 percent by weight.
Das Färbemittel kann in Form einer Lösung, insbesondere einer wässrigen oder wässrig-alkoholischen Lösung, einer Creme, eines Gels, eines Aerosolschaumes oder einer Emulsion vorliegen, und stellt eine Mischung der Farbstoffkomponenten mit den für solche Zubereitungen üblichen Zusätzen dar.The colorant can be in the form of a solution, in particular an aqueous or aqueous-alcoholic solution, a cream, a gel, an aerosol foam or an emulsion, and is a mixture of the dye components with the additives customary for such preparations.
Als anionische Farbstoffe können insbesondere genannt werden: 6-Hydroxy-5-[(4-sulfophenyl)azo]-2-naphthalinsulfonsäure-dinatriumsalz (CM 5985; Food Yellow No. 3; FD&C Yellow No. 6), 2,4-Dinitro-1-naphthol- 7-sulfonsäure-dinatriumsalz (CI10316; Acid Yellow No. 1 ; Food Yellow No. 1), 2-(lndan-1 ,3-dion-2-yl)chinolin-x,x-sulfonsäure (Gemisch aus Mono- und Disulfonsäure) (CI47005;D&C Yellow No. 10; Food Yellow No. 13; Acid Yellow No. 3), 5-Hydroxy-1-(4-sulfophenyl)-4-[(4-sulfophenyl)- azo]-pyrazol-3-carbonsäure-trinatriumsalz (CI19140; Food Yellow No. 4;
Acid Yellow No. 23), 9-(2-Carboxyphenyl)-6-hydroxy-3H-xanthen-3-on (CI45350; Acid Yellow No. 73; D&C Yellow No. 8), 5-[(2,4-Dinitrophenyl)- amino]-2-phenylamino-benzolsulfonsäure-natriumsalz (Cl 10385; Acid Orange No. 3), 4-[(2,4-Dihydroxyphenyl)azo]-benzolsulfonsäure- mononatriumsalz (Cl 14270; Acid Orange No. 6), 4-[(2-Hydroxynaphth-1 - yl)azo]-benzolsulfonsäure-natriumsalz (Cl 15510; Acid Orange No. 7), 4-[(2,4-Dihydroxy-3-[(2,4-dimethylphenyl)azo]-phenyl)azo]-benzolsulfon- säure-natriumsalz (CI20170; Acid Orange No. 24), 4-Hydroxy-3-[(4- sulfonaphth-1-yl)azo]-1-naphthalin-sulfonsäure-dinatriumsalz (Cl 14720; Acid Red No. 14), 6-Hydroxy-5-[(4-sulfonaphth-1-yl)azo]-2,4-naphthalin- disulfonsäure-trinatriumsalz (Cl 16255; Ponceau 4R; Acid Red No. 18), 3-Hydroxy-4-[(4-sulfonaphth-1-yl)azo]-2,7-naphthalin-disulfonsäure- trinatriumsalz (CI16185; Acid Red No. 27), 8-Amino-1-hydroxy-2- (phenylazo)-3,6-naphthalin-disulfonsäure-dinatriumsalz (Cl 17200; Acid Red No. 33), 5-(Acetylamino)-4-hydroxy-3-[(2-methylphenyl)azo]-2,7- naphthalin-disulfonsäure-dinatriumsalz (CM 8065; Acid Red No. 35), 2-(3-Hydroxy-2,4,5,7-tetraiod-dibenzopyran-6-on-9-yl)-benzoesäure- dinatriumsalz (CI45430;Acid Red No. 51 ), N-[6-(Diethylamino)-9-(2,4- disulfophenyl)-3H-xanthen-3-yliden]-N-ethylethanammonium-hydroxid, inneres Salz, Natriumsalz (CI45100; Acid Red No. 52), 8-[(4-(Phenylazo)- phenyl)azo]-7-naphthol-1 ,3-disulfonsäure-dinatriumsalz (CI27290; Acid Red No. 73), 2',4',5,,7,-Tetrabrom-3,,6'-dihydroxyspiro[isobenzofuran- 1(3H),9'-[9H]xanthen]-3-on-dinatriumsalz (CI45380; Acid Red No. 87), 2\4\5\7'-Tetrabrom-4,5,6,7-tetrachlor-3\6'-dihydroxyspiro[isobenzofuran- 1(3H),9'[9H]xanthen]-3-on-dinatriumsalz (CI45410; Acid Red No. 92), 3',6'-Dihydroxy-4',5,-diiodospiro-[isobenzofuran-1(3H),9'(9H)-xanthen]-3- on-dinatriumsalz (CI45425; Acid Red No. 95), (2-Sulfophenyl)di[4-(ethyl- ((4-sulfophenyl)methyl)amino)-phenyl]-carbenium-dinatriumsalz, betain (CI42090; Acid Blue No. 9; FD&C Blue No. 1), 1 ,4-Bis[(2-sulfo-4-methyl-
phenyl)amino]-9,10-anthrachinon-dinatriumsalz (Cl 61570; Acid Green No. 25),Bis[4-(dimethylamino)phenyl]-(3,7-disulfo-2-hydroxynaphth-1-yl) carbenium-inneres Salz, mononatriumsalz (CI44090; Food Green No. 4; Acid Green No. 50), Bis[4-(diethylamino)phenyl](2,4-disulfophenyl)- carbenium-inneres salz, Natriumsalz (2:1) (CI42045; Food Blue No. 3; Acid Blue No. 1), Bis[4-(diethylamino)phenyl](5-hydroxy-2,4-disulfo- phenyl)carbenium-inneres salz, Calciumsalz (2:1) (CI42051 ; Acid Blue No. 3), 1 -Amino-4-(cyclohexylamino)-9,10-anthrachinon-2-sulfonsäure- natriumsalz (CI62045; Acid Blue No. 62), 2-(1 ,3-Dihydro-3-oxo-5-sulfo- 2H-indol-2-yliden)-2,3-dihydro-3-oxo-1H-indol-5-sulfonsäure-dinatriumsalz (CI73015; Acid Blue No. 74), 9-(2-Carboxyphenyl)-3-[(2-methylphenyl)- amino]-6-[(2-methyl-4-sulfophenyl)amino]xanthylium-inneres Salz, mononatriumsalz (CI45190; Acid Violet No. 9), 1-Hydroxy-4-[(4-methyl-2- sulfophenyl)amino]-9,10-anthrachinon-natriumsalz (CI60730; D&C Violett No. 2; Acid Violet No. 43), Bis[3-nitro-4-[(4-phenylamino)-3-suIfo-phenyl- amino]-phenyl]-sulfon (CI10410; Acid Brown No. 13), 5-Amino-4-hydroxy- 6-[(4-nitrophenyl)azo]-3-(phenylazo)-2,7-naphthalin-disulfonsäure- dinatriumsalz (CI20470; Acid Black No. 1), 3-Hydroxy-4-[(2-hydroxy- naphth-1 -yl)azo]-7-nitro-1 -naphthalin-sulfonsäure-chromkomplex (3:2) (CI15711 ; Acid Black No. 52), 3-[(2,4-Dimethyl-5-sulfophenyl)azo]-4- hydroxy-1-naphthalin-sulfonsäure-dinatriumsalz (CI14700; Food Red No. 1 ; Ponceau SX; FD&C Red No. 4), 4-(Acetylamino)-5-hydroxy-6-[(7-sulfo- 4-[(4-sulfophenyl)azo]naphth-1-yl)azo]-1,7-naphthalindisuIfonsäure- tetranatriumsalz (CI28440; Food Black No. 1), 5-[(2-Methoxy-5-methyl-4- sulfophenyl)azo]-6-hydroxy-2-naphthalin-sulfonsäure-dinatriumsalz (CM 6035; Food Red 17; Curry Red; FD&C Red No. 40) und 3-Hydroxy-4- (3-methyl-5-oxo-1 -phenyl-4,5-dihydro-1 H-pyrazol-4-ylazo)-naphthalin-1 - sulfonsäure-natriumsalz, Chrom-Komplex (Acid Red No. 195).
Die direktziehenden Farbstoffe werden in dem Färbemittel in einer Gesamtmenge von etwa 0,01 bis 10 Gewichtsprozent, vorzugsweise 0,1 bis 5 Gewichtsprozent, eingesetzt.The following may be mentioned in particular as anionic dyes: 6-hydroxy-5 - [(4-sulfophenyl) azo] -2-naphthalenesulfonic acid disodium salt (CM 5985; Food Yellow No. 3; FD&C Yellow No. 6), 2,4-dinitro -1-naphthol-7-sulfonic acid disodium salt (CI10316; Acid Yellow No. 1; Food Yellow No. 1), 2- (indan-1, 3-dion-2-yl) quinolin-x, x-sulfonic acid (mixture from mono- and disulfonic acid) (CI47005; D&C Yellow No. 10; Food Yellow No. 13; Acid Yellow No. 3), 5-hydroxy-1- (4-sulfophenyl) -4 - [(4-sulfophenyl) - azo ] -pyrazole-3-carboxylic acid trisodium salt (CI19140; Food Yellow No. 4; Acid Yellow No. 23), 9- (2-Carboxyphenyl) -6-hydroxy-3H-xanthene-3-one (CI45350; Acid Yellow No. 73; D&C Yellow No. 8), 5 - [(2,4-dinitrophenyl) amino ] -2-phenylamino-benzenesulfonic acid sodium salt (Cl 10385; Acid Orange No. 3), 4 - [(2,4-Dihydroxyphenyl) azo] -benzenesulfonic acid monosodium salt (Cl 14270; Acid Orange No. 6), 4- [ (2-Hydroxynaphth-1 - yl) azo] benzenesulfonic acid sodium salt (Cl 15510; Acid Orange No. 7), 4 - [(2,4-dihydroxy-3 - [(2,4-dimethylphenyl) azo] phenyl ) azo] -benzenesulfonic acid sodium salt (CI20170; Acid Orange No. 24), 4-hydroxy-3 - [(4-sulfonaphth-1-yl) azo] -1-naphthalenesulfonic acid disodium salt (Cl 14720; acid Red No. 14), 6-Hydroxy-5 - [(4-sulfonaphth-1-yl) azo] -2,4-naphthalenedisulfonic acid trisodium salt (Cl 16255; Ponceau 4R; Acid Red No. 18), 3- Hydroxy-4 - [(4-sulfonaphth-1-yl) azo] -2,7-naphthalene-disulfonic acid, trisodium salt (CI16185; Acid Red No. 27), 8-amino-1-hydroxy-2- (phenylazo) - 3,6-naphthalene-disulfonic acid disodium salt (Cl 17200; Acid Red No. 33), 5- (acetylamino) -4-hydroxy-3 - [( 2-methylphenyl) azo] -2,7-naphthalene disulfonic acid disodium salt (CM 8065; Acid Red No. 35), 2- (3-Hydroxy-2,4,5,7-tetraiododibenzopyran-6-one-9-yl) benzoic acid disodium salt (CI45430; Acid Red No. 51), N- [6- ( Diethylamino) -9- (2,4-disulfophenyl) -3H-xanthene-3-ylidene] -N-ethylethanammonium hydroxide, inner salt, sodium salt (CI45100; Acid Red No. 52), 8 - [(4- (phenylazo ) - phenyl) azo] -7-naphthol-1, 3-disulfonic acid disodium salt (CI27290; Acid Red No. 73), 2 ', 4', 5, 7, -Tetrabrom-3,, 6'-dihydroxyspiro [ isobenzofuran-1 (3H), 9 '- [9H] xanthene] -3-one-disodium salt (CI45380; Acid Red No. 87), 2 \ 4 \ 5 \ 7'-tetrabromo-4,5,6,7- tetrachloro-3 \ 6'-dihydroxyspiro [isobenzofuran-1 (3H), 9 '[9H] xanthene] -3-one disodium salt (CI45410; Acid Red No. 92), 3', 6'-dihydroxy-4 ', 5 , -diiodospiro- [isobenzofuran-1 (3H), 9 '(9H) -xanthene] -3- on disodium salt (CI45425; Acid Red No. 95), (2-sulfophenyl) di [4- (ethyl- ( (4-sulfophenyl) methyl) amino) phenyl] carbenium disodium salt, betaine (CI42090; Acid Blue No. 9; FD&C Blue No. 1), 1, 4-bis [(2-sulfo-4-methyl- phenyl) amino] -9,10-anthraquinone disodium salt (Cl 61570; Acid Green No. 25), bis [4- (dimethylamino) phenyl] - (3,7-disulfo-2-hydroxynaphth-1-yl) carbenium- inner salt, monosodium salt (CI44090; Food Green No. 4; Acid Green No. 50), bis [4- (diethylamino) phenyl] (2,4-disulfophenyl) carbenium inner salt, sodium salt (2: 1) (CI42045 ; Food Blue No. 3; Acid Blue No. 1), bis [4- (diethylamino) phenyl] (5-hydroxy-2,4-disulfophenyl) carbenium inner salt, calcium salt (2: 1) (CI42051; Acid Blue No. 3), 1 -Amino-4- (cyclohexylamino) -9,10-anthraquinone-2-sulfonic acid sodium salt (CI62045; Acid Blue No. 62), 2- (1, 3-dihydro-3-oxo -5-sulfo-2H-indol-2-ylidene) -2,3-dihydro-3-oxo-1H-indole-5-sulfonic acid disodium salt (CI73015; Acid Blue No. 74), 9- (2-carboxyphenyl) -3 - [(2-methylphenyl) - amino] -6 - [(2-methyl-4-sulfophenyl) amino] xanthylium inner salt, monosodium salt (CI45190; Acid Violet No. 9), 1-hydroxy-4- [ (4-methyl-2-sulfophenyl) amino] -9,10-anthraquinone sodium salt (CI60730; D&C Violet No. 2; Acid Violet N O. 43), bis [3-nitro-4 - [(4-phenylamino) -3-suIfo-phenylamino] phenyl] sulfone (CI10410; Acid Brown No. 13), 5-amino-4-hydroxy-6 - [(4-nitrophenyl) azo] -3- (phenylazo) -2,7-naphthalene-disulfonic acid disodium salt (CI20470; Acid Black No. 1), 3-hydroxy-4 - [(2-hydroxy-naphth-1 -yl) azo] -7-nitro-1-naphthalene-sulfonic acid-chromium complex (3: 2) (CI15711; Acid Black No. 52), 3 - [(2,4-dimethyl-5-sulfophenyl) azo] -4 - Hydroxy-1-naphthalene-sulfonic acid disodium salt (CI14700; Food Red No. 1; Ponceau SX; FD&C Red No. 4), 4- (acetylamino) -5-hydroxy-6 - [(7-sulfo- 4- [ (4-sulfophenyl) azo] naphth-1-yl) azo] -1,7-naphthalenedisulfonic acid tetrasodium salt (CI28440; Food Black No. 1), 5 - [(2-methoxy-5-methyl-4-sulfophenyl) azo ] -6-hydroxy-2-naphthalene-sulfonic acid disodium salt (CM 6035; Food Red 17; Curry Red; FD&C Red No. 40) and 3-hydroxy-4- (3-methyl-5-oxo-1-phenyl- 4,5-dihydro-1 H-pyrazol-4-ylazo) -naphthalene-1 - sulfonic acid sodium salt, chromium complex (Acid Red No. 195). The substantive dyes are used in the colorant in a total amount of about 0.01 to 10 percent by weight, preferably 0.1 to 5 percent by weight.
Neben den anionischen Farbstoffen kann das Färbemittel erforderlichenfalls weitere übliche und geeignete synthetische oder natürliche direktziehende Farbstoffe enthalten.In addition to the anionic dyes, the colorant can, if necessary, contain other customary and suitable synthetic or natural substantive dyes.
Übliche Zusätze in Lösungen, Cremes, Emulsionen, Aerosolschäumen oder Gelen sind zum Beispiel Lösungsmittel wie Wasser niedere aliphatische Alkohole, beispielsweise Ethanol, n-Propanol und Isopropanol, Glykolether oder Glykole wie Glycerin und 1 ,2-Propandiol, die alleine oder in Kombination miteinander eingesetzt werden. Weiterhin kann das Tönungsmittel für kosmetische Mittel bekannte Zusatzstoffe, beispielsweise Netzmittel oder Emulgatoren aus den Klassen der anionischen, kationischen, amphoteren oder nichtionogenen oberflächenaktiven Substanzen wie Fettalkoholsulfate, oxethylierte Fettalkoholsulfate, Alkylsulfonate, Alkylbenzolsulfonate, Alkyltrimethyl- ammoniumsalze, Alkylbetaine, oxethylierte Fettalkohle, oxethylierte Nonylphenole, Fettsäurealkanolamide, oxethylierte Fettalkohole, oxethylierte Nonylphenole, Fettsäurealkanolamide, oxethylierte Fettsäureester enthalten, wobei im allgemeinen die anionischen, nicht-ionischen und amphoteren Netzmittel und Emulgatoren bevorzugt werden. Ferner können Verdicker wie höhere Fettalkohole, Stärke oder Cellulosederivate, Parfüme, Haarvorbehandlungsmittel, Konditionierer, Haarquellmittel, Konservierungsstoffe, weiterhin Vaseline, Paraffinöl und Fettsäuren sowie außerdem Pflegestoffe wie kationische Harze, Lanolinderivate, Cholesterin, Pantothensäure und Betain enthalten sein. Die erwähnten Bestandteile werden in den für solche Zwecke üblichen Mengen
verwendet, zum Beispiel die Netzmittel und Emulgatoren in Konzentrationen von etwa 0,5 bis 30 Gewichtsprozent (bezogen auf das Färbemittel), die Verdicker in einer Menge von etwa 0,1 bis 25 Gewichtsprozent (bezogen auf das Färbemittel) und die Pflegestoffe in einer Konzentration von etwa 0,1 bis 5,0 Gewichtsprozent (bezogen auf das Färbemittel).Usual additives in solutions, creams, emulsions, aerosol foams or gels are, for example, solvents such as water, lower aliphatic alcohols, for example ethanol, n-propanol and isopropanol, glycol ethers or glycols such as glycerol and 1,2-propanediol, which are used alone or in combination with one another become. Furthermore, the tinting agent for cosmetic agents can be known additives, for example wetting agents or emulsifiers from the classes of anionic, cationic, amphoteric or nonionic surface-active substances, such as fatty alcohol sulfates, oxyethylated fatty alcohol sulfates, alkyl sulfonates, alkylbenzenesulfonates, alkyltrimethylammonium salts, alkylbetaoleols, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty alcohols, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty acids, oxethylated fatty alcohols, contain, ethoxylated fatty alcohols, ethoxylated nonylphenols, fatty acid alkanolamides, ethoxylated fatty acid esters, the anionic, nonionic and amphoteric wetting agents and emulsifiers being generally preferred. It can also contain thickeners such as higher fatty alcohols, starch or cellulose derivatives, perfumes, hair pretreatment agents, conditioners, hair swelling agents, preservatives, petroleum jelly, paraffin oil and fatty acids as well as care agents such as cationic resins, lanolin derivatives, cholesterol, pantothenic acid and betaine. The ingredients mentioned are in the usual amounts for such purposes used, for example the wetting agents and emulsifiers in concentrations of approximately 0.5 to 30 percent by weight (based on the colorant), the thickeners in an amount of approximately 0.1 to 25 percent by weight (based on the colorant) and the care substances in one concentration from about 0.1 to 5.0 percent by weight (based on the colorant).
In einer besonders bevorzugten Ausführungsform enthält das Färbemittel der 2. Komponente zusätzlich mindestens eine oberflächenaktive Verbindung aus der Gruppe der anionischen, amphoteren und nichtionogenen Netzmittel und Tenside, wobei die Konfektionierung als nicht-ionische, anionische oder amphotere Creme besonders bevorzugt ist. Durch den Zusatz der oberflächenaktiven Verbindungen wird einen besonders geringe Hautanfärbung erzielt.In a particularly preferred embodiment, the colorant of the second component additionally contains at least one surface-active compound from the group of anionic, amphoteric and nonionic wetting agents and surfactants, the formulation as non-ionic, anionic or amphoteric cream being particularly preferred. The addition of the surface-active compounds results in a particularly low skin coloration.
Der pH-Wert des gebrauchsfertigen Färbemittels beträgt etwa 1 bis 9, insbesondere 2,5 bis 8,5. Der gewünschte pH-Wert kann erforderlichenfalls durch Zugabe von organischen oder anorganischen Säuren oder alkalisierenden Mitteln eingestellt werden, beispielsweise mit Phosphorsäure, Salzsäure, Essigsäure, Salicylsäure, Malonsäure, Gluconsäurelacton oder α-Hydroxycarbonsäuren wie Glykolsäure, Milchsäure, Weinsäure, Zitronensäure oder Äpfelsäure, oder alkalisierenden Mitteln wie Alkanolaminen, Alkylaminen, Alkalihydroxiden, Ammoniumhydroxid, Alkalicarbonaten, Ammoniumcarbonaten oder Alkaliphosphaten.The pH of the ready-to-use colorant is about 1 to 9, in particular 2.5 to 8.5. If required, the desired pH can be adjusted by adding organic or inorganic acids or alkalizing agents, for example with phosphoric acid, hydrochloric acid, acetic acid, salicylic acid, malonic acid, gluconic acid lactone or α-hydroxycarboxylic acids such as glycolic acid, lactic acid, tartaric acid, citric acid or malic acid, or alkalizing agents Agents such as alkanolamines, alkylamines, alkali hydroxides, ammonium hydroxide, alkali carbonates, ammonium carbonates or alkali phosphates.
Die vorgenannten physiologisch verträglichen anorganischen und/oder organischen Salze ermöglichen eine deutliche Verbesserung des Aufziehverhaltens von anionischen Farbstoffen auf Keratinfasern wie zum
Beispiel Haare, Wolle oder Seide, wodurch intensivere und haltbarere Färbungen bei gleichzeitig geringer Hautanfärbung erzielt werden können.The aforementioned physiologically compatible inorganic and / or organic salts enable a significant improvement in the absorption behavior of anionic dyes on keratin fibers such as For example, hair, wool or silk, which enables more intensive and long-lasting dyeing to be achieved with a low skin coloration.
Obwohl die Salze zur Verbesserung des Aufziehverhaltens von anionischen direktziehenden Farbstoffen auf Keratinfasern besonders gut geeignet sind, können sie auch bei der Färbung von anderen natürlichen oder synthetischen Fasern, beispielsweise Baumwolle, Viskose, Nylon oder Celluloseacetat, mit anionischen direktziehenden Farbstoffen sehr vorteilhaft eingesetzt werden.Although the salts are particularly well suited for improving the absorption behavior of anionic direct dyes on keratin fibers, they can also be used very advantageously in the dyeing of other natural or synthetic fibers, for example cotton, viscose, nylon or cellulose acetate, with anionic direct dyes.
Die nachfolgenden Beispiele sollen den Gegenstand näher erläutern, ohne ihn auf diese Beispiele zu beschränken.The following examples are intended to explain the subject in more detail without restricting it to these examples.
B e i s p i e l eB e i s p i e l e
Beispiele 1.1 bis 1.5: TönungsmittelExamples 1.1 to 1.5: toning agents
X g direktziehende Farbstoff(e) gemäß Tabelle 1X g direct dye (s) according to Table 1
20,0 g Ethanol20.0 g ethanol
Y g Salze einer anorganischen und/oder organischen gemäß Tabelle 1 ad 100,00 g Wasser, vollentsalztY g salts of an inorganic and / or organic according to Table 1 ad 100.00 g water, fully desalinated
Das Salz wird dem Tönungsmittel direkt vor der Anwendung zugesetzt. 60 g des vorstehenden Tönungsmittels werden auf gebleichtes Haar aufgetragen und mit einem Pinsel gleichmäßig verteilt. Nach einer Einwirkungszeit von 30 Minuten bei 40 °C wird das Haar mit lauwarmem Wasser gespült und sodann getrocknet. Das Ergebnis dieser Färbehandlung ist in Tabelle 1 zusammengefaßt.
Tabelle 1 : FärberesultateThe salt is added to the tint just before use. 60 g of the above tint is applied to bleached hair and spread evenly with a brush. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with lukewarm water and then dried. The result of this dyeing treatment is summarized in Table 1. Table 1: Color results
Beispiel 2: TönungscremeExample 2: tinting cream
1 ,22 g Steareth-201.22 g Steareth-20
12,30 g Cetearylalcohol12.30 g cetearyl alcohol
10,00 g Ethanol10.00 g ethanol
0,005 g Acid Yellow No. 10.005 g Acid Yellow No. 1
0,13 g Acid Orange No. 70.13 g Acid Orange No. 7
0,05 g Acid Black No. 10.05 g Acid Black No. 1
0,026 g Acid Violet No. 430.026 g Acid Violet No. 43
0,058 g Acid Red No. 18 ad 100,00 g Wasser0.058 g Acid Red No. 18 ad 100.00 g water
Gebleichtes Haar wird zunächst mit einer Sprühlösung, die 1 Gewichtsprozent Calciumchlorid und 1 Gewichtsprozent Kaliumchlorid enthält vorbehandelt. Im Anschluss an diese Vorbehandlung werden 50 g der vorstehenden Tönungscreme auf das Haar aufgetragen. Nach einer
Einwirkungszeit von 30 Minuten bei 40 °C wird das Haar mit Wasser ausgespült und getrocknet. Es wird eine braune Färbung erhalten.Bleached hair is first pretreated with a spray solution that contains 1 percent by weight calcium chloride and 1 percent by weight potassium chloride. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After a Exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A brown color is obtained.
Beispiel 3: TönungscremeExample 3: tinting cream
3,00 g Natrium-Laurylethersulfat (28 %ige wässrige Lösung)3.00 g sodium lauryl ether sulfate (28% aqueous solution)
12,30 g Cetearylalcohol12.30 g cetearyl alcohol
20,00 g Ethanol20.00 g of ethanol
0,0625 g Acid Yellow No. 10.0625 g Acid Yellow No. 1
0,0625 g Acid Orange No. 70.0625 g Acid Orange No. 7
0,0625 g Acid Black No. 10.0625 g Acid Black No. 1
0,0625 g Acid Violet No. 430.0625 g Acid Violet No. 43
0,1500 g Acid Red No. 14 ad 100,00 g Wasser0.1500 g Acid Red No. 14 ad 100.00 g water
Gebleichtes Haar wird zunächst mit einer Sprühlösung, die 5 Gewichtsprozent Calciumpantothenat enthält, vorbehandelt. Im Anschluss an diese Vorbehandlung werden 50 g der vorstehenden Tönungscreme auf das Haar aufgetragen. Nach einer Einwirkungszeit von 30 Minuten bei 40 °C wird das Haar mit Wasser ausgespült und getrocknet. Es wird eine braune Färbung erhalten.Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A brown color is obtained.
Beispiel 4: TönungscremeExample 4: Tinting Cream
3,00 g Natrium-Laurylethersulfat (28 %ige wässrige Lösung)3.00 g sodium lauryl ether sulfate (28% aqueous solution)
12,30 g Cetearylalcohol12.30 g cetearyl alcohol
20,00 g Ethanol20.00 g of ethanol
0,3000 g Acid Orange No. 70.3000 g Acid Orange No. 7
0,2000 g Acid Red No. 330.2000 g Acid Red No. 33
0,2000 g FD & C Red No. 40
ad 100,00 g Wasser0.2000 g FD & C Red No. 40 ad 100.00 g water
Gebleichtes Haar wird zunächst mit einer Sprühlösung, die 5 Gewichtsprozent Calciumpantothenat enthält, vorbehandelt. Im Anschluss an diese Vorbehandlung werden 50 g der vorstehenden Tönungscreme auf das Haar aufgetragen. Nach einer Einwirkungszeit von 30 Minuten bei 40 °C wird das Haar mit Wasser ausgespült und getrocknet. Es wird eine orange-rote Färbung erhalten.Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. An orange-red color is obtained.
Beispiel 5: TönungscremeExample 5: tinting cream
3,00 g Natrium-Laurylethersulfat (28 %ige wässrige Lösung)3.00 g sodium lauryl ether sulfate (28% aqueous solution)
12,30 g Cetearylalcohol12.30 g cetearyl alcohol
20,00 g Ethanol20.00 g of ethanol
0,0430 g Acid Orange No. 70.0430 g Acid Orange No. 7
0,0350 g Acid Black No. 10.0350 g Acid Black No. 1
0,1140 g Acid Violet No. 430.1140 g Acid Violet No. 43
0,0580 g Acid Red No. 18 ad 100,00 g Wasser0.0580 g Acid Red No. 18 ad 100.00 g water
Gebleichtes Haar wird zunächst mit einer Sprühlösung, die 5 Gewichtsprozent Calciumpantothenat enthält, vorbehandelt. Im Anschluss an diese Vorbehandlung werden 50 g der vorstehenden Tönungscreme auf das Haar aufgetragen. Nach einer Einwirkungszeit von 30 Minuten bei 40 °C wird das Haar mit Wasser ausgespült und getrocknet. Es wird eine violette Färbung erhalten.Bleached hair is first pretreated with a spray solution containing 5% by weight calcium pantothenate. Following this pretreatment, 50 g of the above tinting cream are applied to the hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. A violet color is obtained.
Beispiel 6: VergleichsversucheExample 6: Comparative tests
Die Tönungsmittel gemäß der Beispiele 1 bis 5 werden jeweils mit und ohne Vorbehandlung in der in den Beispielen beschriebenen Weise zur
Färbung von Haaren verwendet und anschliessend die Intensität der erhaltenen Färbungen miteinander verglichen. Die Ergebnisse sind in der nachfolgenden Tabelle 2 zusammengefasst.The tinting agents according to Examples 1 to 5 are in each case with and without pretreatment in the manner described in the Examples Coloring hair used and then compared the intensity of the dyeings obtained. The results are summarized in Table 2 below.
Tabelle 2:Table 2:
Die Vergleichsversuche zeigen zweifelsfrei, dass durch die Vorbehandlung mit einem anorganischen oder organischen Salz deutlich farbintensivere Färbungen erhalten werden. The comparative experiments show beyond any doubt that the pretreatment with an inorganic or organic salt gives significantly more color-intensive stains.
Die in den vorliegenden Beispielen ermittelten L*a*b*-Farbmesswerte wurden mit einem Farbmessgerät der Firma Minolta, Typ Chromameter II, ermittelt. Hierbei steht der L-Wert für die Helligkeit (das heißt je geringer der L-Wert ist, umso größer ist die Farbintensität), während der a-Wert ein Maß für den Rotanteil ist (das heißt je größer der a-Wert ist, umso größer ist der Rotanteil). Der b-Wert ist ein Maß für den Blauanteil der Farbe, wobei der Blauanteil umso größer ist, je negativer der b-Wert ist.The L * a * b * color measurement values determined in the present examples were determined using a color measuring device from Minolta, type Chromameter II. Here, the L-value stands for the brightness (i.e. the lower the L-value, the greater the color intensity), while the a-value is a measure of the red component (i.e. the larger the a-value, the greater the red component is larger). The b-value is a measure of the blue component of the color, the more negative the b-value, the greater the blue component.
Alle in der vorliegenden Anmeldung genannten Prozentangaben stellen soweit nicht anders angegeben Gewichtsprozente dar.
Unless otherwise stated, all percentages mentioned in the present application represent percentages by weight.
Claims
1. Verwendung von physiologisch verträglichen Salzen anorganischer und/oder organischer Säuren zur Verbesserung des Aufziehverhaltens von anionischen direktziehenden Farbstoffen auf keratinische Fasern.1. Use of physiologically compatible salts of inorganic and / or organic acids to improve the absorption behavior of anionic direct dyes on keratin fibers.
2. Verwendung nach Anspruch 1 , dadurch gekennzeichnet, dass das Salz ausgewählt ist aus Chloriden, Bromiden, Sulfaten, Lactaten, Tartraten, Citraten, Malaten, Glycolaten, Glycerophoshaten, Phantothenaten, Phosphinaten, Glutamaten, Gluconaten, Phosphaten, Formiaten, Sorbaten, Aspartaten, Orotaten, Oxalaten und Acetaten des Natriums, Kaliums, Magnesiums, Caiciums, Ammoniums, Aluminiums oder Zinks.2. Use according to claim 1, characterized in that the salt is selected from chlorides, bromides, sulfates, lactates, tartrates, citrates, malates, glycolates, glycerophoshates, phantothenates, phosphinates, glutamates, gluconates, phosphates, formates, sorbates, aspartates, Orotates, oxalates and acetates of sodium, potassium, magnesium, calcium, ammonium, aluminum or zinc.
3. Verwendung nach Anspruch 2 oder 3, dadurch gekennzeichnet, dass das Salz ausgewählt ist aus Natriumchlorid, Kaliumchlorid, Magnesiumchlorid, Calciumchlorid und Calciumpanthotenat oder deren Mischungen.3. Use according to claim 2 or 3, characterized in that the salt is selected from sodium chloride, potassium chloride, magnesium chloride, calcium chloride and calcium panthotenate or mixtures thereof.
4. Verwendung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass das Salz in einer wässrigen Zubereitung oder in einem Färbemittel in einer Menge von 0,01 bis 10 Gewichtsprozent verwendet wird.4. Use according to one of claims 1 to 3, characterized in that the salt is used in an aqueous preparation or in a colorant in an amount of 0.01 to 10 percent by weight.
5. Verfahren zur Färbung keratinischer Fasern, bei dem die Faser zunächst mit einer mindestens ein physiologisch verträgliches Salz einer anorganischen und/oder organischen Säure enthaltenden wässrigen Zubereitung vorbehandelt wird, und anschliessend mit einem mindestens einen anionischen direktziehenden Farbstoff enthaltenden Färbemittel gefärbt wird. 5. A process for dyeing keratin fibers, in which the fiber is first pretreated with an aqueous preparation containing at least one physiologically tolerable salt of an inorganic and / or organic acid, and is then dyed with a dye containing at least one anionic direct dye.
6. Verfahren nach Anspruch 5, dadurch gekennzeichnet, dass man das Färbemittel je nach gewünschter Farbtiefe 5 bis 60 Minuten bei einer Temperatur von 20 bis 50 Grad Celsius auf das Haar einwirken lässt, sodann das Haar mit Wasser spült, gegebenenfalls mit einem Shampoo wäscht und trocknet.6. The method according to claim 5, characterized in that depending on the desired depth of color, the colorant is allowed to act on the hair for 5 to 60 minutes at a temperature of 20 to 50 degrees Celsius, then the hair is rinsed with water, optionally washed with a shampoo and dries.
7. Mehrkomponenten-Kit zur Färbung von keratinischen Fasern, dadurch gekennzeichnet, dass er eine mindestens ein physiologisch verträgliches Salz einer anorganischen oder organischen Säure enthaltende 1. Komponente und eine mindestens einen anionischen direktziehenden Farbstoff enthaltende 2. Komponente enthält.7. Multi-component kit for dyeing keratin fibers, characterized in that it contains a first component containing at least one physiologically compatible salt of an inorganic or organic acid and a second component containing at least one anionic direct dye.
8. Mehrkomponenten-Kit nach Anspruch 7, dadurch gekennzeichnet, dass die 1. Komponente mindestens ein Chlorid, Bromid, Sulfat, Lactat, Tartrat, Citrat, Malat, Glycolat, Glycerophoshat, Phantothenat, Phosphinat, Glutamat, Gluconat, Phosphat, Formiat, Sorbat, Aspartat, Orotat, Oxalat oder Acetat des Natriums, Kaliums, Magnesiums, Caiciums, Ammoniums, Aluminiums oder Zinks sowie gegebenenfalls Zusatzstoffe enthält.8. Multi-component kit according to claim 7, characterized in that the first component at least one chloride, bromide, sulfate, lactate, tartrate, citrate, malate, glycolate, glycerophoshate, phantothenate, phosphinate, glutamate, gluconate, phosphate, formate, sorbate , Aspartate, orotate, oxalate or acetate of sodium, potassium, magnesium, calcium, ammonium, aluminum or zinc and optionally additives.
9. Mehrkomponenten-Kit nach Anspruch 7 oder 8, dadurch gekennzeichnet, dass die 2. Komponente mindestens einen anionischen direktziehenden Farbstoff enthält.9. Multi-component kit according to claim 7 or 8, characterized in that the second component contains at least one anionic substantive dye.
10. Mehrkomponenten-Kit nach einem der Ansprüche 7 bis 9, dadurch gekennzeichnet, dass die 2. Komponente zusätzlich mindestens eine oberflächenaktive Verbindung aus der Gruppe der anionischen, amphoteren und nichtionogenen Netzmittel und Tenside enthält. 10. Multi-component kit according to one of claims 7 to 9, characterized in that the second component additionally contains at least one surface-active compound from the group of anionic, amphoteric and nonionic wetting agents and surfactants.
Applications Claiming Priority (3)
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|---|---|---|---|
| DE10032752 | 2000-07-05 | ||
| DE10032752A DE10032752A1 (en) | 2000-07-05 | 2000-07-05 | Use of salts to improve the absorption behavior of anionic direct dyes |
| PCT/EP2001/003605 WO2002002062A1 (en) | 2000-07-05 | 2001-03-29 | Use of salts for improving the absorption qualities of anionic direct dyes |
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| EP1210061A1 true EP1210061A1 (en) | 2002-06-05 |
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| EP1428497A1 (en) * | 2002-12-12 | 2004-06-16 | KPSS-Kao Professional Salon Services GmbH | Pre-treatment composition applied before colouring hair with acidic direct dyes |
| US6905523B2 (en) * | 2003-03-13 | 2005-06-14 | Aveda Corporation | Hair color application using cluster-modified water |
| US7060111B2 (en) | 2003-07-03 | 2006-06-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method for providing more vibrant, natural and long-lasting color to hair |
| US7074244B2 (en) | 2003-07-03 | 2006-07-11 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Hair dyeing method including an aligning step |
| EP1559403A1 (en) * | 2004-01-28 | 2005-08-03 | KPSS-Kao Professional Salon Services GmbH | Composition for dyeing human hair |
| EP1759684A1 (en) * | 2005-09-02 | 2007-03-07 | Wella Aktiengesellschaft | Process for bleaching keratin fibers |
| MX336048B (en) * | 2011-05-27 | 2016-01-07 | Procter & Gamble | Soluble solid hair coloring article. |
| FR2990852A1 (en) * | 2012-05-24 | 2013-11-29 | Oreal | ANIONIC DYE OR ANONIUM DYE AGAINST AMMONIUM OR PHOSPHONIUM ION, DYE COMPOSITION COMPRISING SAME, AND PROCESS FOR COLORING KERATINIC FIBERS FROM THESE DYES |
| US9820922B1 (en) | 2016-05-12 | 2017-11-21 | L'oreal | Methods and compositions for improving the quality and durability of color in artificially colored hair |
| US9833394B1 (en) | 2016-05-12 | 2017-12-05 | L'oreal | Methods and compositions for improving the quality and durability of color in artificially colored hair |
| US9839590B2 (en) | 2016-05-12 | 2017-12-12 | L'oreal | Methods and compositions for improving the quality and durability of color in artificially colored hair |
| WO2017197099A1 (en) * | 2016-05-12 | 2017-11-16 | L'oreal | Methods and compositions for improving the quality and durability of color in artificially colored hair |
| US10426716B2 (en) | 2017-08-30 | 2019-10-01 | L'oreal | Compositions and methods for improving color deposit and durability of color in artificially colored hair |
| US10363208B2 (en) * | 2017-08-30 | 2019-07-30 | L'oreal | Methods for improving the durability of color in artificially colored hair |
| GB201800877D0 (en) * | 2018-01-19 | 2018-03-07 | Perachem Ltd | Method and composition |
| US10328009B1 (en) * | 2018-03-29 | 2019-06-25 | L'oreal | Methods and compositions for improving the durability of color in artificially colored hair |
| FR3096896B1 (en) * | 2019-06-07 | 2025-10-31 | Di Visco | NEW HAIR COLOURING FORMULA |
| DE102019219650A1 (en) * | 2019-12-16 | 2021-06-17 | Henkel Ag & Co. Kgaa | Tint conditioner with improved coloring performance |
| EP4410266A1 (en) * | 2023-01-31 | 2024-08-07 | Kao Corporation | Method for dyeing of keratin fibers |
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| DE19705875C1 (en) * | 1997-02-15 | 1998-04-02 | Wella Ag | Oxidative hair colour, giving excellent result under mild conditions |
| JPH11217319A (en) * | 1998-01-27 | 1999-08-10 | Hoyu Co Ltd | Hair dye composition |
| DE19941450A1 (en) * | 1999-08-31 | 2001-03-01 | Schwarzkopf Gmbh Hans | hair coloring |
| US6540791B1 (en) * | 2000-03-27 | 2003-04-01 | The Procter & Gamble Company | Stable alkaline hair bleaching compositions and method for use thereof |
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| DE10032752A1 (en) | 2002-01-31 |
| US20020189031A1 (en) | 2002-12-19 |
| JP2004501943A (en) | 2004-01-22 |
| WO2002002062A1 (en) | 2002-01-10 |
| AU2001248361A1 (en) | 2002-01-14 |
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