EP0367966A1 - Brûleur pour la gazéification des combustibles solides à grains fins ou pulvérulents - Google Patents
Brûleur pour la gazéification des combustibles solides à grains fins ou pulvérulents Download PDFInfo
- Publication number
- EP0367966A1 EP0367966A1 EP89117730A EP89117730A EP0367966A1 EP 0367966 A1 EP0367966 A1 EP 0367966A1 EP 89117730 A EP89117730 A EP 89117730A EP 89117730 A EP89117730 A EP 89117730A EP 0367966 A1 EP0367966 A1 EP 0367966A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- channel
- gasification
- fuel
- injection lance
- feed channel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002309 gasification Methods 0.000 title claims abstract description 77
- 239000004449 solid propellant Substances 0.000 title claims abstract description 8
- 239000000446 fuel Substances 0.000 claims abstract description 46
- 238000002347 injection Methods 0.000 claims abstract description 27
- 239000007924 injection Substances 0.000 claims abstract description 27
- 239000007800 oxidant agent Substances 0.000 claims abstract description 26
- 239000000428 dust Substances 0.000 claims abstract description 25
- 239000000376 reactant Substances 0.000 claims abstract description 17
- 239000007789 gas Substances 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 12
- 239000012159 carrier gas Substances 0.000 claims abstract description 11
- 230000001590 oxidative effect Effects 0.000 claims description 11
- 239000003500 flue dust Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000009434 installation Methods 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 239000002893 slag Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000094396 Bolitoglossa carri Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/50—Fuel charging devices
- C10J3/506—Fuel charging devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
Definitions
- the invention relates to a gasification burner for a system for the gasification of fine-grained to dust-like solid fuels, which has a gasification reactor, with a central first feed channel for primary oxidizing agents, a surrounding ring fuel channel for the fuels which are introduced with a carrier gas, the fuel -Ringkanal surrounding second annular feed channel for secondary oxidant, and with cooling channels and optionally at least one moderator gas ring channel, wherein a majority of the gasification burners burn with their fuel / reactant jet into the gasification reactor and the fuel / reactant jets in the gasification reactor a primary reaction zone of high temperature form and an essentially carbon monoxide and hydrogen-containing raw gas is withdrawn from the gasification reactor.
- the basic structure of the gasification burner is symmetrical.
- the gasification is carried out as pressure gasification.
- the solid fuels are in particular coal, coke, petroleum coke and the like. Oxygen and / or air and, if appropriate, water vapor are used in particular as oxidizing agents.
- the carrier gas is an inert gas, such as nitrogen or carbon dioxide, or dedusted raw gas.
- reactant denotes both the oxidizing agent and reaction products which have already formed, and if appropriate also moderator gas and carrier gas.
- the raw gas leaving the reactor is known to carry fly dust, which, for. B. carries in an amount of up to 15 wt .-% fuel. The dust is removed from the raw gas with suitable dedusting devices. Its disposal is complex.
- fly dust In order to dispose of the fly dust, it is known to return the fly dust to the gasification process. Its fuel component is to be burned, and the fly dust is to be melted down. As part of known measures (EP 0 072 457 B1, EP 0 109 109 B1), the fly dust is mixed with the fresh fuel and fed to the gasification burners together with the fuel. This is complex and requires special processing of the fly ash, namely extensive and complicated technical facilities with large safety precautions. The pore space or gap space of the flying dust is filled with the raw gas containing carbon monoxide and hydrogen, which has to be diluted or removed only below the danger limit by repeated application and pumping with inert gas.
- the loading of the raw gas separated from the fly dust is also cumbersome and complex, since it often contains sulfur and, for reasons of environmental protection, cannot be flared or otherwise burned and released into the atmosphere. Incidentally, it disturbs that the fly dust added to the fresh fuel reduces the calorific value of the fuel, which influences the thermodynamics and the reaction kinetics of the gasification process. It is also known to return the fly dust to the gasification reactor (DE 2 909 008 C2), specifically via feed nozzles separate from the gasification burners. This affects the gasification reaction and has hardly found its way into practice. In practice, it is rather common (DE-AS 2 325 204) to blow up the flying dust in a reactor onto the slag, the residual carbon generally also going into the slag.
- Gasification burners are known in various embodiments. In particular, practice knows those of the structure described at the beginning. It is common to integrate such gasification burners and pilot burners.
- the invention has for its object to provide a gasification burner of the structure described above and the intended purpose described above, with the fly dust, in particular the accumulated in the plant for gasifying the solid fuels, can be returned without disturbing the gasification process in this.
- the invention teaches that a tubular injection lance is arranged in the first feed channel, which is surrounded by oxidizing agent, and that a fly dust / carrier gas stream can be injected into the core of the fuel / reactant jet through the injection lance.
- a fly dust / carrier gas stream can be injected into the core of the fuel / reactant jet through the injection lance.
- the injection lance is preferably inserted axially into the first feed channel. This leads to a symmetrical, circular fuel-reagent jet.
- the invention makes use of the fact that a fuel / reactant jet emerging from a gasification burner, in particular a rotationally symmetrical fuel / reactant jet, is very stable in terms of gas dynamics and can carry a flow of fly ash into the primary reaction zone.
- the gasification reaction begins in the fuel / reactant flow and is not disturbed by the flying dust, as in the primary reaction zone, which also contributes to the fact that its residual carbon is also gasified.
- the volume flow of airborne dust must not be chosen too large.
- the primary reaction zone the dust is hardly discharged more than usual and without the recirculation described. It does not accumulate.
- a special fly dust disposal is no longer necessary when working with gasification burners according to the invention, the fly dust is rather melted into slag.
- the arrangement will be such that the injection lance opens into the area of the mouth of the first feed channel, the fuel channel and the second feed channel in the burner front.
- a preferred embodiment of the invention which allows adjustment to different operating conditions, is characterized in that the injection lance and thus its mouth are adjustable in the axial direction.
- the primary oxidant can flow around the injection lance.
- this embodiment also ensures that the fly dust arrives in the primary reaction zone and does not interfere with the gasification process.
- the situation is more stable if the injection lance is surrounded by an oxidant channel and this is surrounded by the first supply channel.
- the design be such that the oxidant channel has a mouth that runs parallel to the axis of the gasification burner, the first feed channel has an outward mouth, and the second feed channel has an inward mouth.
- the second feed channel with a plurality of orifices distributed equidistantly over the circumference.
- the mouth can also be designed as an annular gap. As in the context of the known measures, it is advisable to arrange a cooling channel between the first supply channel and the fuel ring channel.
- a preferred embodiment is characterized in that the injection lance is set up for supplying a flow of flue dust that is smaller by a factor of 0.01 to 0.15 than the fuel flow. In this area, it is generally possible to recycle all of the fly dust, with its proportion of fuel, which occurs in a plant for the gasification of fine-grained to dust-like solid fuels.
- the gasification burner shown in the figures is for a system, not shown, for gasification from fine-grained to dust-like against solid fuels.
- the plant has a gasification reactor.
- a majority of the gasification burners burn with their fuel / reactant jet into the gasification reactor and are generally distributed equidistantly around the circumference of the gasification reactor.
- the fuel / reactant jets form a high temperature primary reaction zone in the gasification reactor. It is understood that a raw gas is withdrawn from the gasification reactor.
- the basic structure of the gasification burner includes a first feed channel 1 for the primary oxidizing agent, a surrounding fuel ring channel 2 for the fuels that are introduced with a carrier gas, a second annular feed channel 3 for secondary oxidizing agent and cooling channels 4 surrounding the fuel ring channel 2, and optionally at least one moderator gas ring channel 5.
- the injection lance 6 In the first feed channel 1 there is a tubular injection lance 6 which is surrounded by oxidizing agent.
- a flight dust / carrier gas stream can be injected into the core of the fuel / reactant jet through the injection lance 6.
- the carrier gas is, for example, raw gas.
- the injection lance 6 opens in the area of the mouths of the first feed channel 1, the fuel ring channel 2 and the second feed channel 3 and thus, as it were, in the front of the gasification burner.
- a funnel-shaped training follows.
- the injection lance 6 runs in the axis of the gasification burner. It can be axially adjustable in the direction of the double arrow, which allows adaptation to different operating conditions.
- the injection lance 6 is surrounded by an oxidant channel 7 and this is surrounded by the first supply channel 1.
- the oxidizing agent channel 7 has an opening 8 which is directed parallel to the axis of the gasification burner and accordingly the oxidizing agent emerges from an oxidizing channel, enveloping the flue dust flow.
- the first feed channel 1 in contrast, has an outwardly directed mouth 9.
- the mouth 10 of the second feed channel 3, on the other hand, is directed inward, as is also common in the gasification burners described at the outset. It is within the scope of the invention to provide the second feed channel 3 with a plurality of orifices 11 distributed equidistantly over the circumference, as was indicated in FIG. 2.
- An annular cooling channel 4 is located between the first supply channel 1 and the fuel ring channel 2.
- a flame monitor 12 was indicated, with which the gasification burner can be monitored in a known manner.
- An outer cooling jacket 13 with further cooling channels 4 follows. It is within the scope of the invention to arrange an insulated ignition electrode 14 in the injection lance 6, as was indicated by dash-dotted lines at the mouth of the injection lance 6.
- the injection lance 6, the oxidant channel 7, the first feed channel 1 and the cooling channel 4 are located in or on a unitary component which is illustrated by close hatching and is adjustable in the axial direction.
- the gasification burner according to the invention consists, as it were, of two independent assemblies, which are also interchangeable. By exchanging an adaptation to different operating conditions is possible.
- the oxidizing agent oxygen required for the gasification of the fine-grained to dust-like fuel is divided into two streams, the primary and the secondary gasification oxygen, whose mass ratios between primary and secondary can be 1: 1.15 to 1.3.
- the arrangement is such that the oxygen flow from the first feed channel strikes the fuel flow at an inflow angle of 0 to 20 ° to the central axis of the gasification burner.
- the exit velocity of 60 to 120 m / s of the primary oxygen also serves to accelerate the fuel from a low initial velocity to the velocity which corresponds to or approximates the axial velocity of the secondary oxygen. This emerges at an angle of 20 to 50 ° to the central axis of the gasification burner at a speed of 40 to 100 m / s.
- the flame monitor 12 is of particular importance. It makes it possible to determine whether caked-on particles of particulate matter have formed.
- the gasification burner according to the invention can also be used as a pilot burner, in particular in coal gasification plants.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Gasification And Melting Of Waste (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3837586A DE3837586A1 (de) | 1988-11-05 | 1988-11-05 | Vergasungsbrenner fuer eine anlage fuer die vergasung von festen brennstoffen |
| DE3837586 | 1988-11-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0367966A1 true EP0367966A1 (fr) | 1990-05-16 |
| EP0367966B1 EP0367966B1 (fr) | 1992-12-09 |
Family
ID=6366554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89117730A Expired - Lifetime EP0367966B1 (fr) | 1988-11-05 | 1989-09-26 | Brûleur pour la gazéification des combustibles solides à grains fins ou pulvérulents |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0367966B1 (fr) |
| CN (1) | CN1020502C (fr) |
| DD (1) | DD286031A5 (fr) |
| DE (2) | DE3837586A1 (fr) |
| DK (1) | DK169526B1 (fr) |
| ES (1) | ES2036776T3 (fr) |
| PL (1) | PL163597B1 (fr) |
| ZA (1) | ZA897382B (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0437698A1 (fr) * | 1989-12-19 | 1991-07-24 | Krupp Koppers GmbH | Procédé pour faire fonctionner une installation de gazéification de combustibles solides |
| WO2012041808A1 (fr) * | 2010-10-01 | 2012-04-05 | Shell Internationale Research Maatschappij B.V. | Brûleur pour la gazéification d'un combustible solide |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1323261C (zh) * | 2005-06-24 | 2007-06-27 | 北京航天动力研究所 | 一种可燃粉体旋流燃烧器 |
| DE102006060867B4 (de) * | 2006-12-22 | 2020-07-02 | Khd Humboldt Wedag Gmbh | Drehofenbrenner |
| US20130160856A1 (en) * | 2011-12-22 | 2013-06-27 | General Electric Company | Multi-port injector system and method |
| DE102013106656A1 (de) * | 2013-06-25 | 2015-01-08 | Brinkmann Industrielle Feuerungssysteme Gmbh | Brennerlanze und Verfahren zum Betreiben einer Brennerlanze für industrielle Thermoprozesse |
| CN105090944B (zh) * | 2015-07-08 | 2017-11-10 | 安徽科达洁能股份有限公司 | 燃烧器、气流床气化炉及气流床气化炉的燃烧方法 |
| DE102017204581A1 (de) * | 2017-03-20 | 2018-09-20 | Technische Universität Bergakademie Freiberg | Brennerkopf zur Anordnung im Kopf eines Vergasers zur Primäroxidation gasförmiger Vergasungsstoffe in Vergasern nach dem Prinzip der autothermen Reformierung (ATR) oder der nichtkatalytischen Partialoxidation (POX) |
| DE202017107794U1 (de) | 2017-12-20 | 2018-01-22 | Choren Industrietechnik GmbH | Brennerspitze und Pilotbrenner |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2253385A1 (de) * | 1972-10-31 | 1974-05-09 | Texaco Development Corp | Verfahren und brenner zur synthesegasherstellung |
| US4113445A (en) * | 1977-01-31 | 1978-09-12 | Texaco Development Corporation | Process for the partial oxidation of liquid hydrocarbonaceous fuels |
| EP0098043A2 (fr) * | 1982-06-29 | 1984-01-11 | Texaco Development Corporation | Brûleur et procédé d'oxydation partielle |
| US4443230A (en) * | 1983-05-31 | 1984-04-17 | Texaco Inc. | Partial oxidation process for slurries of solid fuel |
| DE3440088A1 (de) * | 1984-11-02 | 1986-05-07 | Veba Oel Entwicklungs-Gesellschaft mbH, 4650 Gelsenkirchen | Brenner |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4480559A (en) * | 1983-01-07 | 1984-11-06 | Combustion Engineering, Inc. | Coal and char burner |
| DD251476A3 (de) * | 1985-11-12 | 1987-11-18 | Freiberg Brennstoffinst | Kohlenstaubbrenner |
-
1988
- 1988-11-05 DE DE3837586A patent/DE3837586A1/de active Granted
-
1989
- 1989-09-26 ES ES198989117730T patent/ES2036776T3/es not_active Expired - Lifetime
- 1989-09-26 EP EP89117730A patent/EP0367966B1/fr not_active Expired - Lifetime
- 1989-09-26 DE DE8989117730T patent/DE58902964D1/de not_active Expired - Fee Related
- 1989-09-28 ZA ZA897382A patent/ZA897382B/xx unknown
- 1989-10-26 PL PL89282031A patent/PL163597B1/pl unknown
- 1989-10-30 CN CN89108235A patent/CN1020502C/zh not_active Expired - Fee Related
- 1989-11-02 DD DD89334171A patent/DD286031A5/de not_active IP Right Cessation
- 1989-11-03 DK DK548589A patent/DK169526B1/da not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2253385A1 (de) * | 1972-10-31 | 1974-05-09 | Texaco Development Corp | Verfahren und brenner zur synthesegasherstellung |
| US4113445A (en) * | 1977-01-31 | 1978-09-12 | Texaco Development Corporation | Process for the partial oxidation of liquid hydrocarbonaceous fuels |
| EP0098043A2 (fr) * | 1982-06-29 | 1984-01-11 | Texaco Development Corporation | Brûleur et procédé d'oxydation partielle |
| US4443230A (en) * | 1983-05-31 | 1984-04-17 | Texaco Inc. | Partial oxidation process for slurries of solid fuel |
| DE3440088A1 (de) * | 1984-11-02 | 1986-05-07 | Veba Oel Entwicklungs-Gesellschaft mbH, 4650 Gelsenkirchen | Brenner |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0437698A1 (fr) * | 1989-12-19 | 1991-07-24 | Krupp Koppers GmbH | Procédé pour faire fonctionner une installation de gazéification de combustibles solides |
| WO2012041808A1 (fr) * | 2010-10-01 | 2012-04-05 | Shell Internationale Research Maatschappij B.V. | Brûleur pour la gazéification d'un combustible solide |
| US8545726B2 (en) | 2010-10-01 | 2013-10-01 | Shell Oil Company | Burner for the gasification of a solid fuel |
| AU2011310704B2 (en) * | 2010-10-01 | 2015-05-21 | Air Products And Chemicals, Inc. | A burner for the gasification of a solid fuel |
| US10066832B2 (en) | 2010-10-01 | 2018-09-04 | Air Products And Chemicals, Inc. | Burner for the gasification of a solid fuel |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2036776T3 (es) | 1993-06-01 |
| DE58902964D1 (de) | 1993-01-21 |
| CN1042596A (zh) | 1990-05-30 |
| DD286031A5 (de) | 1991-01-10 |
| DK169526B1 (da) | 1994-11-21 |
| PL163597B1 (pl) | 1994-04-29 |
| EP0367966B1 (fr) | 1992-12-09 |
| DE3837586A1 (de) | 1990-05-10 |
| ZA897382B (en) | 1990-07-25 |
| DK548589D0 (da) | 1989-11-03 |
| CN1020502C (zh) | 1993-05-05 |
| DK548589A (da) | 1990-05-06 |
| DE3837586C2 (fr) | 1992-02-20 |
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Legal Events
| Date | Code | Title | Description |
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| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| 17Q | First examination report despatched |
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| GRAA | (expected) grant |
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| GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
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