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DK3529227T3 - Fremgangsmåde til fremstilling af diener - Google Patents

Fremgangsmåde til fremstilling af diener Download PDF

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Publication number
DK3529227T3
DK3529227T3 DK17783534.5T DK17783534T DK3529227T3 DK 3529227 T3 DK3529227 T3 DK 3529227T3 DK 17783534 T DK17783534 T DK 17783534T DK 3529227 T3 DK3529227 T3 DK 3529227T3
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DK
Denmark
Prior art keywords
dienes
making
making dienes
Prior art date
Application number
DK17783534.5T
Other languages
English (en)
Inventor
Daniele Delledonne
Alberto Cesana
Marco Mattachini
Monica Vittoria Pastori
Original Assignee
Versalis Spa
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Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Application granted granted Critical
Publication of DK3529227T3 publication Critical patent/DK3529227T3/da

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/12—Alkadienes
    • C07C11/16—Alkadienes with four carbon atoms
    • C07C11/167—1, 3-Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
    • C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
    • C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
    • C07C33/03—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond in beta-position, e.g. allyl alcohol, methallyl alcohol
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
DK17783534.5T 2016-10-19 2017-10-18 Fremgangsmåde til fremstilling af diener DK3529227T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT102016000105178A IT201600105178A1 (it) 2016-10-19 2016-10-19 Procedimento per la produzione di dieni
PCT/EP2017/076554 WO2018073282A1 (en) 2016-10-19 2017-10-18 Process for producing dienes

Publications (1)

Publication Number Publication Date
DK3529227T3 true DK3529227T3 (da) 2022-05-02

Family

ID=58159387

Family Applications (1)

Application Number Title Priority Date Filing Date
DK17783534.5T DK3529227T3 (da) 2016-10-19 2017-10-18 Fremgangsmåde til fremstilling af diener

Country Status (20)

Country Link
US (1) US11498887B2 (da)
EP (1) EP3529227B1 (da)
JP (1) JP7033127B2 (da)
KR (1) KR102503689B1 (da)
CN (1) CN109982989B (da)
BR (1) BR112019007826B1 (da)
CA (1) CA3039337A1 (da)
CL (1) CL2019000930A1 (da)
DK (1) DK3529227T3 (da)
EA (1) EA037338B1 (da)
ES (1) ES2914251T3 (da)
HU (1) HUE058302T2 (da)
IL (1) IL265894B (da)
IT (1) IT201600105178A1 (da)
MX (1) MX2019003924A (da)
PL (1) PL3529227T3 (da)
SA (1) SA519401572B1 (da)
SG (1) SG11201903003QA (da)
TN (1) TN2019000104A1 (da)
WO (1) WO2018073282A1 (da)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
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US10919030B2 (en) * 2016-09-30 2021-02-16 Regents Of The University Of Minnesota Forming dienes from cyclic ethers and diols, including tetrahydrofuran and 2-methyl-1,4-butanediol
US12227467B2 (en) * 2018-09-21 2025-02-18 Versalis S.P.A. Process for bio-1,3-butanediol purification from a fermentation broth
US11472753B2 (en) 2019-07-05 2022-10-18 Sekisui Chemical Co., Ltd. Method for producing 1,3-butadiene
CN114364650A (zh) * 2019-07-05 2022-04-15 积水化学工业株式会社 1,3-丁二烯的制造方法
IT201900015069A1 (it) * 2019-08-27 2021-02-27 Versalis Spa Catalizzatore comprendente coke e procedimento per la produzione di dieni.
CN112958146B (zh) * 2019-12-12 2022-04-19 中国科学院大连化学物理研究所 一种mfi分子筛纳米片负载的锆基催化剂及其在制备丁二烯反应中的应用
IT201900025000A1 (it) * 2019-12-20 2021-06-20 Versalis Spa Procedimento per la produzione di dieni.
CN115364844A (zh) * 2021-05-21 2022-11-22 中国石油化工股份有限公司 一种再生脱氧催化剂及其制备方法和应用
US20240327730A1 (en) * 2023-03-28 2024-10-03 Alliance For Sustainable Energy, Llc Deydrogenative Coupling of Low-Value Light Alkanes to Sustainable Aviation Fuel

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US2426678A (en) 1943-04-27 1947-09-02 Us Ind Chemicals Inc Revivification of phosphate catalysts
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
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US3832449A (en) 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
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US5601798A (en) 1993-09-07 1997-02-11 Pq Corporation Process for preparing zeolite Y with increased mesopore volume
IT1290846B1 (it) 1996-12-12 1998-12-14 Enichem Spa Composizione catalitica e processo per l'alchilazione e/o la transalchilazione di composti aromatici
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BRPI1013426A2 (pt) 2009-04-30 2016-11-08 Genomatica Inc organismos para produção de 1,3-butanodiol
WO2012016787A1 (en) * 2010-08-03 2012-02-09 Total Petrochemicals Research Feluy Process to make olefins from isobutanol
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JP6081950B2 (ja) * 2014-03-25 2017-02-15 Ｊｘエネルギー株式会社 脱水触媒、及び共役ジエンの製造方法
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WO2015146789A1 (ja) * 2014-03-25 2015-10-01 Ｊｘ日鉱日石エネルギー株式会社 脱水触媒、及び共役ジエンの製造方法
HUE059279T2 (hu) * 2014-05-16 2022-11-28 Versalis Spa Eljárás alkének elõállítására és azok felhasználása 1,3-butadién elõállításához
EP2952498A1 (en) 2014-08-11 2015-12-09 LANXESS Deutschland GmbH Dehydration of 2,3-butanediole
KR102287828B1 (ko) * 2014-12-17 2021-08-10 에스케이이노베이션 주식회사 2,3-부탄디올의 탈수화 생성물로부터 1,3-부타디엔 및 메틸에틸케톤을 회수하는 방법
CN105712819B (zh) * 2014-12-17 2020-08-07 Sk新技术株式会社 由2,3-丁二醇脱水产物回收1,3-丁二烯和甲基乙基酮的方法
US10196326B2 (en) 2015-02-23 2019-02-05 Versalis S.P.A. Process for the production of dienes
US10179323B2 (en) * 2016-06-07 2019-01-15 Fina Technology, Inc. Metal oxide catalyst systems for conversion of ethanol to butadiene

Also Published As

Publication number Publication date
CL2019000930A1 (es) 2019-08-02
KR20190078594A (ko) 2019-07-04
PL3529227T3 (pl) 2022-06-20
MX2019003924A (es) 2019-08-12
HUE058302T2 (hu) 2022-07-28
EP3529227B1 (en) 2022-04-06
EP3529227A1 (en) 2019-08-28
ES2914251T3 (es) 2022-06-08
KR102503689B1 (ko) 2023-02-23
CA3039337A1 (en) 2018-04-26
SG11201903003QA (en) 2019-05-30
WO2018073282A1 (en) 2018-04-26
JP2019532065A (ja) 2019-11-07
IL265894A (en) 2019-06-30
BR112019007826A2 (pt) 2019-07-16
US11498887B2 (en) 2022-11-15
EA037338B1 (ru) 2021-03-15
JP7033127B2 (ja) 2022-03-09
US20190241481A1 (en) 2019-08-08
CN109982989A (zh) 2019-07-05
TN2019000104A1 (en) 2020-10-05
SA519401572B1 (ar) 2022-12-27
EA201990649A1 (ru) 2019-09-30
IL265894B (en) 2021-09-30
IT201600105178A1 (it) 2018-04-19
BR112019007826B1 (pt) 2022-05-24
CN109982989B (zh) 2023-05-12

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