[go: up one dir, main page]

DK2738237T3 - Amfifilt makromolekyle og anvendelse deraf - Google Patents

Amfifilt makromolekyle og anvendelse deraf Download PDF

Info

Publication number
DK2738237T3
DK2738237T3 DK11869802.6T DK11869802T DK2738237T3 DK 2738237 T3 DK2738237 T3 DK 2738237T3 DK 11869802 T DK11869802 T DK 11869802T DK 2738237 T3 DK2738237 T3 DK 2738237T3
Authority
DK
Denmark
Prior art keywords
formula
amphiphilic macromolecule
amphiphilic
integer
structural unit
Prior art date
Application number
DK11869802.6T
Other languages
English (en)
Inventor
Jinben Wang
Xuefeng Shi
Xiaohui Xu
Hui Yang
Yilin Wang
Haike Yan
Original Assignee
Beijing Junlun Runzhong Science&Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Junlun Runzhong Science&Technology Co Ltd filed Critical Beijing Junlun Runzhong Science&Technology Co Ltd
Application granted granted Critical
Publication of DK2738237T3 publication Critical patent/DK2738237T3/da

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52Amides or imides
    • C08F220/54Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56Acrylamide; Methacrylamide
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02Well-drilling compositions
    • C09K8/03Specific additives for general use in well-drilling compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02Well-drilling compositions
    • C09K8/04Aqueous well-drilling compositions
    • C09K8/06Clay-free compositions
    • C09K8/12Clay-free compositions containing synthetic organic macromolecular compounds or their precursors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/62Compositions for forming crevices or fractures
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/62Compositions for forming crevices or fractures
    • C09K8/66Compositions based on water or polar solvents
    • C09K8/68Compositions based on water or polar solvents containing organic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D21H17/375Poly(meth)acrylamide
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/26Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/282Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Treatment Of Sludge (AREA)

Claims (13)

1. Amfifilt makromolekyle med, som gentagelsesenheder, en strukturenhed A til justering af molekylvægt, molekylvægtfordeling og ladningskarakteristika, en højt sterisk hindret strukturenhed B og en amfifil strukturenhed C, kendetegnet ved, at den højt sterisk hindrede strukturenhed B omfatter en struktur G og en struktur med formlen (4), hvor strukturen G er en cyklisk carbonhydridstruktur, der er dannet på basis af to naboliggende carbonatomer i hovedkæden eller er valgt fra en struktur med formlen (3):
hvor, i formel (3), R5 er H eller en methylgruppe, fortrinsvis H; R6 er et radikal, der er valgt fra gruppen bestående af strukturerne med formlen (5) og formlen (6):
i formel (5), a er et heltal fra 1 til 11, i formel (4), R7 er H; R8 er valgt fra gruppen bestående af H, -S03H og salte deraf, -(CH2)2CH2CI, -ΟΗ2Ν+(ΟΗ3)2(ΟΗ2)ξΟΗ3ΟΓ og -CH2N+(CH3)2 (CH2)2N+(CH3)2(CH2)aCH32Cr; ξ og σ hver især er heltal fra 1 til 15, og den amfifile strukturenhed C har en struktur med formlen (8):
i formel (8), R9 er H eller en methylgruppe; R-io er -O- eller -NH-; Ru er et radikal, der indeholder et ligekædet hydrocarbyl, et forgrenet hydrocarbyl, en polyoxyethylen (PEO), en polyoxypropylen (PPO), en EO-PO-blok, et mono-kvaternært ammoniumsalt, et fler-kvaternært ammoniumsalt eller en sulfon-syre og salte deraf.
2. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at strukturenhed A til justering af molekylvægt, molekylvægtfordeling og ladningskarakteristika omfatter en (meth)acrylamidmonomerenhed A-ι og/eller en (meth)acrylmonomerenhed A2.
3. Amfifilt makromolekyle ifølge krav 2, kendetegnet ved, at, baseret på 100 mol-% af alle gentagelsesenhederne af det amfifile makromolekyle, er molprocentdelen af (meth)acrylamidmonomerenhed A-i 70-99 mol-%; og molprocentdelen af (meth)acrylmonomerenhed A2 er 1-30 mol-%.
4. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at molprocentdelen af struktur G i alle gentagelsesenhederne af det amfifile makromolekyle er 0,02-2 mol-%; og molprocentdelen af strukturen med formel (4) i alle gentagelsesenhederne af det amfifile makromolekyle er 0,05-5 mol-%.
5. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at, baseret på 100 mol-% af alle gentagelsesenhederne af det amfifile makromolekyle, er molprocentdelen af strukturen med formel (8) i alle gentagelsesenhederne af det amfifile makromolekyle 0,05-10 mol-%.
6. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at strukturenhed A til justering af molekylvægt, molekylvægtfordeling og ladningskarakteristika har en struktur med formel (2);
hvor, i formel (2), R1 er H eller en methylgruppe; R2 og R3 uafhængigt er valgt fra gruppen bestående af H og en CrC3-alkylgruppe; R4 er valgt fra gruppen bestående af H og en methylgruppe; Gr er -OH eller -0-Na+; m og n betegner molprocentdelen af strukturenhederne i hele det amfifile makromolekyle, og m er fra 70 til 99 mol-%; n er fra 1 til 30 mol-%.
7. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at den cykliske carbonhydridstruktur, der er dannet på basis af to naboliggende carbonato-mer i hovedkæden, er valgt fra gruppen bestående af:
8. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at den højt sterisk hindrede strukturenhed B har en struktur med formel (7):
hvor, i formel (7), definitionen på G er som beskrevet i krav 1; definitionerne på R7 og R8 er beskrevet i formel (4); henholdsvis x og y betegner molprocentdelene af strukturenhederne i hele det amfifile makromolekyle, og x er fra 0,02 til 2 mol-%, y er fra 0,05 til 5 mol-%.
9. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at: strukturen, der består af R10 og Ru, kan være valgt blandt -0(CH2)gN+(CH3)2(CH2)hCH3X-, -ΝΗ(ΟΗ2)ίΝ+(ΟΗ3)2(ΟΗ2)£Η3Χ\ 0(CH2)kN+((CH2)pCH3)3X", -O(CH2)qN+(CH3)2(0H2)aCH(SO3H)CH2(EO)p(PO)Y(CH2)6CH3X, NH(CH2)qN+(CH3)2(CH2)aCH(S03H)CH2(E0)p(P0)Y(CH2)5CH3X, -0(CH2)qN+(CH3)2(CH2)aCH(C00H)CH2(E0)p(P0)Y(CH2)6CH3X', -NH(CH2)qN+(CH3)2(CH2)aCH(COOH)CH2(EO)p(PO)Y(CH2)6CH3X·, -0(CH2)2N+(CH3)2(CH2)ES03', -(ΟΟΗ(ΟΗ2Ν+(ΟΗ3)2(ΟΗ2)ξΟΗ3ΟΓ)ΟΗ2)ηΟ(ΟΗ2)θΟΗ3, -(OCH(CH2N+((CH2)ACH3)3Cr)CH2)i(CH2)KCH3, -OCH(CH2N+(CH3)2(CH2)rCH3X'))2, -OCH(CH2N+((CH2)sCH3)3X-))2; hvor henholdsvis g, i, k og q er heltal fra 1 til 6; henholdsvis h og j er heltal fra 3 til 21; p er et heltal fra 3 til 9; α er et heltal fra 1 til 12; henholdsvis β og γ er heltal fra 0 til 40; δ er et heltal fra 0 til 21; ε er et heltal fra 4 til 18; ζ er et heltal fra 1 til 21; henholdsvis η og τ er heltal fra 1 til 30; henholdsvis Θ og κ er heltal fra 3 til 21; λ er et heltal fra 0 til 9; r er et heltal fra 3 til 21; s er et heltal fra 3 til 9; og X' er Cl· eller Br\
10. Amfifilt makromolekyle ifølge krav 1, kendetegnet ved, at det amfifile makromolekyle har en struktur med formlen (9):
hvor, i formel (9), R4 er valgt fra gruppen bestående af H og en methyl-gruppe; m og n betegner molprocentdelene af strukturenhederne i hele det amfifile makromolekyle, og m er fra 70 til 99 mol-%; n er fra 1 til 30 mol-%; definitionerne på G, R7, R8, x og y er som beskrevet i formel (7); Rg er H eller en methylgruppe, R10 er -O- eller -NH-; Ru er et radikal, der indeholder et ligekædet hydrocarbyl, et forgrenet hydrocarbyl, en polyoxyethylen (PEO), en polyoxypropylen (PPO), en EO-PO-blok, et mono-kvaternært ammoniumsalt, et fler-kvaternært ammoniumsalt eller en sulfonsyre og salte deraf; z betegner molprocentdelene af strukturenheden i hele det amfifile makromo- lekyle, og z er fra 0,05 til 10 mol-%.
11. Amfifilt makromolekyle ifølge krav 1, som er en forbindelse af formlerne (l)-(X):
eller
12. Amfifilt makromolekyle ifølge et hvilket som helst af kravene 1 til 11, kendetegnet ved, at det har en molekylvægt på mellem 1000000-20000000.
13. Anvendelse af det amfifile makromolekyle ifølge et hvilket som helst af kravene 1 til 12 ved oliefeltboring, brønd-cementering, frakturering, opsamling og transport af råolie, spildevandsbehandling, slambehandling og papirfremstilling som forstærket olieproduktionsmiddel og oliefortrængningsmiddel, middel til reduktion af viskositeten af tung olie, fraktureringsfluid, lerstabilisator, spildevandsbehandlingsmiddel, fastholdelseshjælpemiddel og afvandingshjælpemiddel og forstærkningsmiddel til papirfremstilling.
DK11869802.6T 2011-07-26 2011-09-16 Amfifilt makromolekyle og anvendelse deraf DK2738237T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201110210362XA CN102432749B (zh) 2011-07-26 2011-07-26 两亲高分子及其用途
PCT/CN2011/001579 WO2013013357A1 (zh) 2011-07-26 2011-09-16 两亲高分子及其用途

Publications (1)

Publication Number Publication Date
DK2738237T3 true DK2738237T3 (da) 2017-03-06

Family

ID=45981131

Family Applications (1)

Application Number Title Priority Date Filing Date
DK11869802.6T DK2738237T3 (da) 2011-07-26 2011-09-16 Amfifilt makromolekyle og anvendelse deraf

Country Status (9)

Country Link
US (1) US9243095B2 (da)
EP (1) EP2738237B1 (da)
CN (1) CN102432749B (da)
CA (1) CA2842704C (da)
DK (1) DK2738237T3 (da)
EA (1) EA025834B1 (da)
ES (1) ES2615235T3 (da)
MY (1) MY166451A (da)
WO (1) WO2013013357A1 (da)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358862A (zh) * 2020-09-07 2021-02-12 中国石油天然气股份有限公司 一种适用于低流度致密油储层的驱油降粘压裂液

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102432749B (zh) 2011-07-26 2013-08-28 北京君伦润众科技有限公司 两亲高分子及其用途
CN104371061B (zh) 2013-08-14 2016-08-17 中国石油化工股份有限公司 一种阳离子聚合物及其在堵漏剂中的应用
BR112017007745B1 (pt) 2014-10-15 2022-01-18 Veolia Water Solutions & Technologies Support Tratamento de água produzida particularmente obtida a partir de um processo de recuperação de óleo quimicamente aprimorado com uso de polímeros de aumento de viscosidade
RU2700418C2 (ru) * 2017-07-11 2019-09-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Ярославский государственный технический университет" ФГБОУВО "ЯГТУ" Способ получения амфифильных статистических сополимеров
CN109992836B (zh) * 2019-03-05 2021-09-28 中国石油化工股份有限公司 适应不同油藏需求的粘弹性颗粒驱油剂高效选择方法
US11274240B2 (en) 2019-07-10 2022-03-15 Halliburton Energy Services, Inc. Cationic formation stabilizers compatible with anionic friction reducing polymers
CN110511329A (zh) * 2019-07-18 2019-11-29 中国石油天然气股份有限公司 一种含芳香基的聚合物型表面活性剂及其制备方法和应用
CN114426832A (zh) * 2020-10-15 2022-05-03 中国石油化工股份有限公司 一种边底水稠油油藏控水降粘剂的控水降粘方法
CN114456793B (zh) * 2020-10-21 2023-06-20 中国石油化工股份有限公司 一种针对低渗透稠油油藏的自降粘压裂液及其制备方法
CN114478906B (zh) 2020-10-26 2023-05-02 中国石油化工股份有限公司 一种聚丙烯酰胺基对称支化聚合物型表面活性剂及其制备方法和应用
CN114276488B (zh) * 2022-03-03 2022-06-03 河南博源新材料有限公司 一种长支链多头的阳离子型聚丙烯酰胺及其用途

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4653584A (en) * 1985-05-30 1987-03-31 The Standard Oil Company Maleimide-modified bioresistant polymers and enhanced oil recovery method employing same
US4959432A (en) 1986-05-19 1990-09-25 Union Carbide Chemicals And Plastics Company Inc. Acid viscosifier compositions
CN1314720C (zh) * 2004-12-13 2007-05-09 大连广汇化学有限公司 高分子量两性高分子的制备方法
FR2914647B1 (fr) * 2007-04-05 2011-10-21 Rhodia Recherches Et Tech Copolymere comprenant des unites betainiques et des unites hydrophobes et/ou amphiphiles,procede de preparation,et utilisations.
CN101284893B (zh) * 2008-06-06 2010-10-27 成都理工大学 梳型两亲水溶性共聚物及其制备方法和用途
CN101463116B (zh) * 2009-01-12 2011-07-20 成都理工大学 非线型缔合水溶性四元共聚物及其制备方法和用途
CN101492515B (zh) * 2009-01-23 2011-06-15 成都理工大学 丙烯酰胺改性接枝共聚物及其制备方法和用途
CN101857663B (zh) * 2009-04-09 2012-04-25 北京佛瑞克技术发展有限公司 用于酸压裂温控变粘的聚合物和聚合物交联体的制备方法
CN101570697B (zh) * 2009-06-01 2013-01-02 中国科学院化学研究所 一种原油破乳剂
CN101781386B (zh) * 2009-12-31 2012-06-13 中国科学院化学研究所 一种两亲高分子驱油剂的制备方法
CN101798503B (zh) * 2010-01-05 2012-07-11 西南石油大学 一种用于提高采收率的聚合物驱油剂及其应用
CN102432749B (zh) 2011-07-26 2013-08-28 北京君伦润众科技有限公司 两亲高分子及其用途

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358862A (zh) * 2020-09-07 2021-02-12 中国石油天然气股份有限公司 一种适用于低流度致密油储层的驱油降粘压裂液
CN112358862B (zh) * 2020-09-07 2022-08-09 中国石油天然气股份有限公司 一种适用于低流度致密油储层的驱油降粘压裂液

Also Published As

Publication number Publication date
CN102432749A (zh) 2012-05-02
CA2842704C (en) 2016-01-12
EP2738237A1 (en) 2014-06-04
EA201490337A1 (ru) 2014-05-30
ES2615235T3 (es) 2017-06-06
CN102432749B (zh) 2013-08-28
CA2842704A1 (en) 2013-01-31
EP2738237B1 (en) 2016-12-14
US9243095B2 (en) 2016-01-26
MY166451A (en) 2018-06-27
EP2738237A4 (en) 2015-08-05
US20150065672A1 (en) 2015-03-05
EA025834B1 (ru) 2017-02-28
WO2013013357A1 (zh) 2013-01-31

Similar Documents

Publication Publication Date Title
DK2738237T3 (da) Amfifilt makromolekyle og anvendelse deraf
DK2738191T3 (da) Amfifilt makromolekyle og anvendelse
DK2738189T3 (da) Amfifilt makromolekyle og anvendelse deraf
DK2738190T3 (da) Amfifilt makromolekyle og anvendelse
CN101492515A (zh) 丙烯酰胺改性接枝共聚物及其制备方法和用途
CN102952531A (zh) 一种海上油田驱油用表面活性剂及其制备方法
CN106590589A (zh) 驱油方法
CN112048039B (zh) 一种稠油降粘化合物、其制备方法、组合物及应用
CN103113522A (zh) Amps/mag聚合物制备及其在油气田开发中的应用方法