DK1684583T3 - Emulgerbare koncentrater, der indeholder adjuvanser - Google Patents
Emulgerbare koncentrater, der indeholder adjuvanser Download PDFInfo
- Publication number
- DK1684583T3 DK1684583T3 DK04811204.9T DK04811204T DK1684583T3 DK 1684583 T3 DK1684583 T3 DK 1684583T3 DK 04811204 T DK04811204 T DK 04811204T DK 1684583 T3 DK1684583 T3 DK 1684583T3
- Authority
- DK
- Denmark
- Prior art keywords
- emulsifiable concentrate
- water
- oil
- amount
- cloquintocet
- Prior art date
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- 239000012141 concentrate Substances 0.000 title description 4
- 239000000203 mixture Substances 0.000 claims description 76
- 239000004495 emulsifiable concentrate Substances 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000004009 herbicide Substances 0.000 claims description 27
- 239000002671 adjuvant Substances 0.000 claims description 22
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- 238000000034 method Methods 0.000 claims description 11
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- 239000000126 substance Substances 0.000 claims description 11
- COYBRKAVBMYYSF-UHFFFAOYSA-N heptan-2-yl [(5-chloroquinolin-8-yl)oxy]acetate Chemical group C1=CN=C2C(OCC(=O)OC(C)CCCCC)=CC=C(Cl)C2=C1 COYBRKAVBMYYSF-UHFFFAOYSA-N 0.000 claims description 10
- 239000002736 nonionic surfactant Substances 0.000 claims description 10
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- 230000001804 emulsifying effect Effects 0.000 claims description 8
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- ICJSJAJWTWPSBD-UHFFFAOYSA-N cloquintocet Chemical compound C1=CN=C2C(OCC(=O)O)=CC=C(Cl)C2=C1 ICJSJAJWTWPSBD-UHFFFAOYSA-N 0.000 claims description 7
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- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
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- JBDHZKLJNAIJNC-LLVKDONJSA-N clodinafop-propargyl Chemical group C1=CC(O[C@H](C)C(=O)OCC#C)=CC=C1OC1=NC=C(Cl)C=C1F JBDHZKLJNAIJNC-LLVKDONJSA-N 0.000 claims description 4
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- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
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- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Polymers CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 3
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- BCOZLGOHQFNXBI-UHFFFAOYSA-M benzyl-bis(2-chloroethyl)-ethylazanium;bromide Chemical compound [Br-].ClCC[N+](CC)(CCCl)CC1=CC=CC=C1 BCOZLGOHQFNXBI-UHFFFAOYSA-M 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 239000000828 canola oil Substances 0.000 description 1
- 235000019519 canola oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 150000005452 ethyl sulfates Chemical class 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010353 genetic engineering Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000003392 indanyl group Chemical group C1(CCC2=CC=CC=C12)* 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000005451 methyl sulfates Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 1
- 150000002888 oleic acid derivatives Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
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- 235000005985 organic acids Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 231100000208 phytotoxic Toxicity 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
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- 229920006294 polydialkylsiloxane Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
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- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
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- 239000008096 xylene Substances 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Claims (19)
1. Emulgerbart koncentrat, der omfatter: a) en herbicidt effektiv mængde, som er 1 til 30 vægt-% af mindst ét herbicid; b) eventuelt en mængde, som er effektiv til antagonisme af et herbicid, af mindst én safener; c) 5 til 80 vægt-% of mindst ét olieadjuvans, hvilket olieadjuvans omfatter en alkylester af en planteolie; d) en mængde af mindst ét ikke-vandblandbart opløsningsmiddel, der er tilstrækkelig til at holde den aktive bestanddel og safeneren i opløsning i nærvær af adjuvanset, hvor mængden af det mindst ene ikke-vandblandbare opløsningsmiddel er 5 til 70 vægt-%; og e) et emulgerende overfladeaktivt system i en mængde, der er tilstrækkelig til at danne en olie-i-vand-emulsion, når formuleringen tilsættes til vand, hvor mængden af det emulgerende overfladeaktive system er mellem 1 og 30 vægt-%; med det forbehold, at: a) omfatter en herbicidt effektiv mængde af mindst én forbindelse med formel I
(l) hvor Hal er halogen, Q er oxygen eller svovl, R er hydrogen, en alkalimetalion, eller en Cl-C6-alkylgruppe, som er ligekædet eller forgrenet, og som er usubstitueret eller substitueret med en C3-C6-alkynylgruppe; og b) omfatter en mængde, som er effektiv til antagonisme af et herbicid, af mindst én quinolinderivat-safener, der omfatter: cloquintocet; en alkalimetal-, jordalkalimetal-, sulfonium-eller ammoniumkation af cloquintocet; eller cloquintocet-mexyl; og hvor det emulgerbare koncentrat har et pH i intervallet fra 4,5 til 8,0, når det er fortyndet til en koncentration på 1% i destilleret vand; og hvor det emulgerbare koncentrat indeholder mindre end 2,5 % vand.
2. Emulgerbart koncentrat ifølge krav 1, der omfatter 25 til 70 vægt-% af det mindst ene olieadjuvans.
3. Emulgerbart koncentrat ifølge krav 1 eller 2, hvor mængden af det mindst ene ikke-vandblandbare opløsningsmiddel er 25 til 60 vægt-%.
4. Emulgerbart koncentrat ifølge krav 1, 2 eller 3, som har et pH i intervallet fra 5,0 til 7,0, når det er fortyndet til en koncentration på 1% i destilleret vand.
5. Emulgerbart koncentrat ifølge krav 1, 2, 3 eller 4, der indeholder mindre end 2,0 % vand.
6. Emulgerbart koncentrat ifølge krav 5, hvor forbindelsen med formel I er clodinafop-propargyl.
7. Emulgerbart koncentrat ifølge krav 1, 2, 3, 4 eller 5, hvor olieadjuvanset omfatter en methylester af en planteolie.
8. Emulgerbart koncentrat ifølge krav 7, hvor olieadjuvanset omfatter en methylester af rapsolie.
9. Emulgerbart koncentrat ifølge krav 1, 2, 3, 4 eller 5, hvor det emulgerende overfladeaktive system omfatter mindst ét ikke-ionisk overfladeaktivt stof.
10. Emulgerbart koncentrat ifølge krav 1, hvor safeneren omfatter cloquintocet-mexyl.
11. Emulgerbart koncentrat ifølge krav 1, 2, 3, 4 eller 5, der omfatter clodinafop-propargyl sammen med safeneren cloquintocet-mexyl.
12. Emulgerbart koncentrat ifølge krav 1, 2, 3, 4 eller 5, der yderligere omfatter mindst ét element udvalgt fra gruppen, der består af co-herbicider, fungicider, insekticider, acaricider og nematicider.
13. Emulgerbart koncentrat ifølge krav 1, 2, 3, 4 eller 5, der yderligere omfatter mindst ét element udvalgt fra gruppen, der består af kemiske stabilisatorer, viskositetskontrollerende midler, fortykningsmidler, bindemidler, klæbemidler, gødningsmidler og antiskummidler.
14. Pesticid sammensætning, der er opnået ved fortynding af et emulgerbart koncentrat ifølge krav 1, 2, 3, 4 eller 5 i en passende mængde vand til frembringelse af en olie-i-vand-emulsion.
15. Pesticid sammensætning ifølge krav 14, der yderligere omfatter mindst ét element udvalgt fra gruppen, der består af co-herbicider, fungicider, insekticider, acaricider og nematicider.
16. Fremgangsmåde til selektiv bekæmpelse af ukrudt i afgrøder af nytteplanter, hvilken fremgangsmåde omfatter behandling af nytteplanter, deres frø eller kimplater eller afgrødeområdet derfor med en pesticid sammensætning ifølge krav 14 .
17. Fremgangsmåde ifølge krav 16, hvor afgrøderne af nytteplanter er udvalgt fra gruppen, der består af majs, korn, ris og sojabønner.
18. Fremgangsmåde ifølge krav 17, hvor afgrøderne af nytteplanter er korn.
19. Fremgangsmåde ifølge krav 18, hvor afgrøden af nytteplanter er hvede eller byg.
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| US52056103P | 2003-11-17 | 2003-11-17 | |
| PCT/US2004/038414 WO2005048706A2 (en) | 2003-11-17 | 2004-11-16 | Emulsifiable concentrates containing adjuvants |
Publications (1)
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| DK1684583T3 true DK1684583T3 (da) | 2017-02-20 |
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| DK04811204.9T DK1684583T3 (da) | 2003-11-17 | 2004-11-16 | Emulgerbare koncentrater, der indeholder adjuvanser |
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| EP (1) | EP1684583B1 (da) |
| JP (4) | JP2007511537A (da) |
| CN (1) | CN100393204C (da) |
| AR (1) | AR046629A1 (da) |
| AU (1) | AU2004291163B2 (da) |
| BR (1) | BRPI0416669B1 (da) |
| CA (1) | CA2545403C (da) |
| DK (1) | DK1684583T3 (da) |
| ES (1) | ES2614303T3 (da) |
| MA (1) | MA28230A1 (da) |
| MX (1) | MXPA06005480A (da) |
| PL (1) | PL1684583T3 (da) |
| TN (1) | TNSN06140A1 (da) |
| UA (1) | UA85398C2 (da) |
| WO (1) | WO2005048706A2 (da) |
| ZA (1) | ZA200603944B (da) |
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| TW201113376A (en) * | 2009-09-01 | 2011-04-16 | Basf Agrochemical Products Bv | Herbicide-tolerant plants |
| UA107110C2 (uk) * | 2010-05-04 | 2014-11-25 | Застосування холодостійких метильованих рослинних олій як коформулянту для сільськогосподарських хімікатів | |
| MX341077B (es) | 2011-06-22 | 2016-08-04 | Dow Agrosciences Llc | Concentrados emulsionables de herbicida con adyuvante integrado. |
| TWI568351B (zh) * | 2011-06-22 | 2017-02-01 | 陶氏農業科學公司 | 具有自附（ｂｕｉｌｔ－ｉｎ）佐劑之除草劑顆粒 |
| UY34653A (es) * | 2012-03-05 | 2013-10-31 | Syngenta Participations Ag | ?composiciones herbicidas que proporcionan control amplio de malezas con fitotoxicidad resultante reducida para cultivares?. |
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| US10000693B2 (en) | 2013-03-14 | 2018-06-19 | Flotek Chemistry, Llc | Methods and compositions for use in oil and/or gas wells |
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| US10590332B2 (en) | 2013-03-14 | 2020-03-17 | Flotek Chemistry, Llc | Siloxane surfactant additives for oil and gas applications |
| US9464223B2 (en) | 2013-03-14 | 2016-10-11 | Flotek Chemistry, Llc | Methods and compositions for use in oil and/or gas wells |
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| CA2436834C (en) * | 2000-12-04 | 2010-01-26 | Syngenta Participations Ag | Microemulsifiable agrochemical concentrate |
| AR032844A1 (es) * | 2001-02-26 | 2003-11-26 | Syngenta Participations Ag | Composicion herbicida |
| JP2003128501A (ja) * | 2001-10-18 | 2003-05-08 | Nissan Chem Ind Ltd | 農薬乳剤組成物 |
| DE10209468A1 (de) * | 2002-03-05 | 2003-09-18 | Bayer Cropscience Gmbh | Herbizid-Kombinationen mit speziellen Sulfonylharnstoffen |
-
2004
- 2004-11-16 DK DK04811204.9T patent/DK1684583T3/da active
- 2004-11-16 AU AU2004291163A patent/AU2004291163B2/en not_active Expired
- 2004-11-16 AR ARP040104223A patent/AR046629A1/es active IP Right Grant
- 2004-11-16 PL PL04811204T patent/PL1684583T3/pl unknown
- 2004-11-16 UA UAA200606735A patent/UA85398C2/ru unknown
- 2004-11-16 BR BRPI0416669A patent/BRPI0416669B1/pt active IP Right Grant
- 2004-11-16 CA CA002545403A patent/CA2545403C/en not_active Expired - Lifetime
- 2004-11-16 WO PCT/US2004/038414 patent/WO2005048706A2/en not_active Ceased
- 2004-11-16 CN CNB2004800376739A patent/CN100393204C/zh not_active Expired - Lifetime
- 2004-11-16 ES ES04811204.9T patent/ES2614303T3/es not_active Expired - Lifetime
- 2004-11-16 EP EP04811204.9A patent/EP1684583B1/en not_active Expired - Lifetime
- 2004-11-16 JP JP2006540008A patent/JP2007511537A/ja not_active Withdrawn
- 2004-11-16 US US10/578,735 patent/US20080248955A1/en not_active Abandoned
- 2004-11-16 MX MXPA06005480A patent/MXPA06005480A/es active IP Right Grant
-
2006
- 2006-05-16 ZA ZA200603944A patent/ZA200603944B/en unknown
- 2006-05-16 TN TNP2006000140A patent/TNSN06140A1/en unknown
- 2006-06-15 MA MA29107A patent/MA28230A1/fr unknown
-
2011
- 2011-11-28 JP JP2011259435A patent/JP2012062318A/ja not_active Withdrawn
-
2014
- 2014-11-21 JP JP2014236766A patent/JP2015052013A/ja not_active Withdrawn
-
2016
- 2016-10-21 JP JP2016207095A patent/JP2017036321A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| MA28230A1 (fr) | 2006-10-02 |
| BRPI0416669A (pt) | 2007-02-13 |
| AU2004291163B2 (en) | 2011-01-27 |
| CA2545403A1 (en) | 2005-06-02 |
| EP1684583A4 (en) | 2012-04-25 |
| CN1893823A (zh) | 2007-01-10 |
| JP2015052013A (ja) | 2015-03-19 |
| TNSN06140A1 (en) | 2007-11-15 |
| UA85398C2 (ru) | 2009-01-26 |
| WO2005048706A2 (en) | 2005-06-02 |
| WO2005048706A3 (en) | 2005-11-10 |
| EP1684583B1 (en) | 2016-12-14 |
| AU2004291163A1 (en) | 2005-06-02 |
| CA2545403C (en) | 2009-10-20 |
| ZA200603944B (en) | 2007-09-26 |
| ES2614303T3 (es) | 2017-05-30 |
| EP1684583A2 (en) | 2006-08-02 |
| PL1684583T3 (pl) | 2017-09-29 |
| AR046629A1 (es) | 2005-12-14 |
| JP2007511537A (ja) | 2007-05-10 |
| JP2012062318A (ja) | 2012-03-29 |
| US20080248955A1 (en) | 2008-10-09 |
| BRPI0416669B1 (pt) | 2018-11-21 |
| JP2017036321A (ja) | 2017-02-16 |
| CN100393204C (zh) | 2008-06-11 |
| MXPA06005480A (es) | 2006-08-11 |
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