DK0570404T3 - Agglomererede polymerpartikler af findelte, vandopløselige eller vandkvældbare polymerisater - Google Patents
Agglomererede polymerpartikler af findelte, vandopløselige eller vandkvældbare polymerisaterInfo
- Publication number
- DK0570404T3 DK0570404T3 DK92903573.1T DK92903573T DK0570404T3 DK 0570404 T3 DK0570404 T3 DK 0570404T3 DK 92903573 T DK92903573 T DK 92903573T DK 0570404 T3 DK0570404 T3 DK 0570404T3
- Authority
- DK
- Denmark
- Prior art keywords
- water
- soluble
- polymer particles
- agglomerated polymer
- swellable
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title abstract 8
- 239000002245 particle Substances 0.000 title abstract 4
- 239000002562 thickening agent Substances 0.000 abstract 2
- 238000007259 addition reaction Methods 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000008394 flocculating agent Substances 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5227—Processes for facilitating the dissolution of solid flocculants in water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/547—Tensides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/16—Powdering or granulating by coagulating dispersions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5242—Polymers of unsaturated N-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/04—Surfactants, used as part of a formulation or alone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Paper (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4103969A DE4103969A1 (de) | 1991-02-09 | 1991-02-09 | Verfahren zur herstellung von feinteiligen, wasserloeslichen oder wasserquellbaren polymerisaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK0570404T3 true DK0570404T3 (da) | 1997-06-02 |
Family
ID=6424727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK92903573.1T DK0570404T3 (da) | 1991-02-09 | 1992-02-03 | Agglomererede polymerpartikler af findelte, vandopløselige eller vandkvældbare polymerisater |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5346986A (fr) |
| EP (1) | EP0570404B1 (fr) |
| JP (1) | JP3115321B2 (fr) |
| AT (1) | ATE152465T1 (fr) |
| CA (1) | CA2085481A1 (fr) |
| DE (2) | DE4103969A1 (fr) |
| DK (1) | DK0570404T3 (fr) |
| ES (1) | ES2100334T3 (fr) |
| WO (1) | WO1992013912A1 (fr) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4202192A1 (de) * | 1992-01-28 | 1993-07-29 | Basf Ag | Waessrige polymerisatzubereitungen |
| DE69328378T2 (de) * | 1993-03-29 | 2000-12-07 | The Dow Chemical Co., Midland | Absorbentpolymer mit niedrigen Staubformungstendenzen |
| GB9402717D0 (en) * | 1994-02-11 | 1994-04-06 | Allied Colloids Ltd | Solid polymeric products and their use |
| DE4426236A1 (de) * | 1994-07-23 | 1996-01-25 | Heinz Neuschuetz | Hilfsmittel beim Herstellen von Anstrichmitteln und Putzen auf Kunststoffbasis |
| DE4435425A1 (de) | 1994-10-04 | 1996-04-11 | Basf Ag | Agglomerierte Polymerteilchen aus feinteiligen, wasserlöslichen oder wasserquellbaren Ammoniumcarboxylatgruppen enthaltenden Polymerisaten |
| DE19506287A1 (de) * | 1995-02-23 | 1996-08-29 | Basf Ag | Agglomerierte Polymerteilchen aus wasserquellbaren Polymerisaten, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5869542A (en) * | 1995-06-07 | 1999-02-09 | Cytec Technology Corp. | Spray drying of polymer-containing dispersions, water-in-oil emulsions and microemulsions and dry polymer products formed thereby |
| US5849862A (en) * | 1995-06-07 | 1998-12-15 | Cytec Technology Corp. | Processes of spray drying polymer-containing dispersions, water-in-oil emulsions and water-in-oil microemulsions |
| US6011089A (en) * | 1995-06-07 | 2000-01-04 | Cytec Technology Corp. | Spray drying of polymer-containing dispersions, water-in-oil emulsions and water-in-oil microemulsions, and dry polymer products formed thereby |
| GB9514283D0 (en) * | 1995-07-13 | 1995-09-13 | Allied Colloids Ltd | Solid polymeric products and their use |
| IT1279051B1 (it) * | 1995-10-27 | 1997-12-04 | 3V Sigma Spa | Composizioni addensanti in forma solida costituite da polimeri o copolimeri e poliglicoli |
| US5854340A (en) * | 1997-09-10 | 1998-12-29 | The Dow Chemical Company | Blended aromatic and diether condensation polymerization reflux solvent |
| DE10041394A1 (de) * | 2000-08-23 | 2002-03-07 | Stockhausen Chem Fab Gmbh | Verwendung von Wasser-in-Wasser-Polymerdispersionen zur Feuerverhütung und -bekämpfung |
| DE10118020A1 (de) * | 2001-04-10 | 2002-10-17 | Stockhausen Chem Fab Gmbh | Löschwasser-Additive |
| KR100428638B1 (ko) * | 2001-09-13 | 2004-04-30 | 주식회사 엘지화학 | 고분자 라텍스 수지 분체의 제조방법 |
| US6905243B2 (en) * | 2001-11-17 | 2005-06-14 | Dr. Friedrichs Gruppe Gmbh | Buoyancy liquid for galilean thermometer |
| DE10217201A1 (de) * | 2001-12-27 | 2003-07-17 | Bayer Ag | Staubarme Feststoffpräparationen |
| DE10213623A1 (de) * | 2002-03-27 | 2003-10-16 | Clariant Gmbh | Stabile Dispersionskonzentrate |
| JP2003289870A (ja) * | 2002-04-02 | 2003-10-14 | Inst Of Physical & Chemical Res | 新規ポリペプチド及びそれをコードする核酸 |
| EP1433526A3 (fr) | 2002-12-26 | 2007-03-14 | Nippon Shokubai Co., Ltd. | Composition à base de résine absorbant l'eau |
| SE0300726D0 (sv) * | 2003-03-14 | 2003-03-14 | Amersham Biosciences Ab | Method for preparing a separation medium |
| DE10334286B4 (de) | 2003-07-25 | 2006-01-05 | Stockhausen Gmbh | Pulverförmige,wasserabsorbierende Polymere mit mittels thermoplastischen Klebstoffen gebundenen Feinteilchen, Verfahren zu deren Herstellung sowie diese beinhaltende chemische Produkte und Verbunde |
| EP1696974B1 (fr) | 2003-12-19 | 2007-05-23 | Basf Aktiengesellschaft | Polymere gonflable formant un hydrogel, a faible fraction fine |
| DE102004015686A1 (de) | 2004-03-29 | 2005-10-27 | Basf Ag | Quellbare hydrogelbildende Polymere mit hoher Permeabilität |
| JP5395329B2 (ja) * | 2006-06-12 | 2014-01-22 | 株式会社 資生堂 | ゲル状組成物 |
| FR2902799B1 (fr) | 2006-06-27 | 2012-10-26 | Millipore Corp | Procede et unite de preparation d'un echantillon pour l'analyse microbiologique d'un liquide |
| US8163886B2 (en) * | 2006-12-21 | 2012-04-24 | Emd Millipore Corporation | Purification of proteins |
| US8362217B2 (en) | 2006-12-21 | 2013-01-29 | Emd Millipore Corporation | Purification of proteins |
| US8569464B2 (en) | 2006-12-21 | 2013-10-29 | Emd Millipore Corporation | Purification of proteins |
| DE102007032403A1 (de) * | 2007-07-10 | 2009-01-22 | Evonik Röhm Gmbh | Verwendung eines quellbaren Polymers zum Abdichten |
| WO2009151514A1 (fr) * | 2008-06-11 | 2009-12-17 | Millipore Corporation | Bioréacteur à cuve agitée |
| ES2749232T3 (es) | 2008-12-16 | 2020-03-19 | Emd Millipore Corp | Reactor de tanque agitado y procedimiento |
| US20100215820A1 (en) * | 2009-02-23 | 2010-08-26 | Aicardo Roa-Espinosa | Refining of edible oil |
| SG10201804385YA (en) | 2010-05-17 | 2018-06-28 | Emd Millipore Corp | Stimulus responsive polymers for the purification of biomolecules |
| PL2768779T3 (pl) * | 2011-10-19 | 2019-06-28 | Solenis Technologies Cayman, L.P. | Kompozycja zawierająca niejonowy środek powierzchniowo czynny i polimer jonowy |
| JP6359012B2 (ja) * | 2013-06-28 | 2018-07-18 | 住友精化株式会社 | 親水性増粘剤及び化粧料組成物 |
| JP6366549B2 (ja) * | 2015-08-06 | 2018-08-01 | 株式会社 Mtg | リムーバー用カバー |
| PL3807388T3 (pl) | 2018-06-15 | 2024-03-11 | Hercules Llc | Stałe niejonowe syntetyczne zagęszczacze asocjacyjne o gruboziarnistych cząstkach do formulacji farb oraz sposoby ich wytwarzania |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982749A (en) * | 1957-07-15 | 1961-05-02 | Dow Chemical Co | Inverse suspension polymerization of water soluble unsaturated monomers |
| US3284393A (en) * | 1959-11-04 | 1966-11-08 | Dow Chemical Co | Water-in-oil emulsion polymerization process for polymerizing watersoluble monomers |
| FR1398342A (fr) * | 1963-06-11 | 1965-05-07 | Asahi Chemical Ind | Perfectionnements apportés aux procédés pour la pulvérisation de polymères |
| DE2419764B2 (de) * | 1974-04-24 | 1979-12-06 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Dispersionen wasserlöslicher Polymerisate und deren Verwendung |
| US4059552A (en) * | 1974-06-21 | 1977-11-22 | The Dow Chemical Company | Cross-linked water-swellable polymer particles |
| US3975341A (en) * | 1974-08-05 | 1976-08-17 | Celanese Corporation | Water in oil emulsion process for preparing gel-free polyelectrolyte particles |
| US3849361A (en) * | 1974-10-24 | 1974-11-19 | Dow Chemical Co | Method of preparing water-dispersable polymer compositions |
| CH612984A5 (fr) * | 1974-12-02 | 1979-08-31 | Ciba Geigy Ag | |
| DE2557324C2 (de) * | 1975-12-19 | 1983-06-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von sedimentationsstabilen Wasser-in-Öl-Dispersionen von Acrylamidpolymerisaten |
| US4056503A (en) * | 1976-10-18 | 1977-11-01 | Celanese Corporation | Incorporation of multifunctional monomers (peta, tmpta, and hdoda) in vinyl-acrylic emulsion polymers |
| GB1591924A (en) * | 1976-10-25 | 1981-07-01 | Berger Jenson & Nicholson Ltd | Polymer aggregates |
| DE2926103A1 (de) * | 1979-06-28 | 1981-01-08 | Bayer Ag | Nichtwaessrige dispersionen wasserloeslicher polymerer |
| GB8401206D0 (en) * | 1984-01-17 | 1984-02-22 | Allied Colloids Ltd | Polymers and aqueous solutions |
| US4554018A (en) * | 1984-02-01 | 1985-11-19 | Allied Colloids Limited | Production of polymeric thickeners and their use in printing |
| US4535098A (en) * | 1984-03-12 | 1985-08-13 | The Dow Chemical Company | Material for absorbing aqueous fluids |
| DE3641700C3 (de) * | 1985-12-19 | 1994-07-07 | Basf Ag | Verfahren zur Herstellung von Wasser-in-Öl-Emulsionen vernetzter, wasserquellbarer Polymerisate und deren Verwendung |
| DE3926120A1 (de) * | 1989-08-08 | 1991-02-14 | Basf Ag | Verfahren zur herstellung von feinteiligen polymerisatpulvern |
-
1991
- 1991-02-09 DE DE4103969A patent/DE4103969A1/de not_active Withdrawn
-
1992
- 1992-02-03 ES ES92903573T patent/ES2100334T3/es not_active Expired - Lifetime
- 1992-02-03 WO PCT/EP1992/000226 patent/WO1992013912A1/fr not_active Ceased
- 1992-02-03 DK DK92903573.1T patent/DK0570404T3/da active
- 1992-02-03 EP EP92903573A patent/EP0570404B1/fr not_active Expired - Lifetime
- 1992-02-03 AT AT92903573T patent/ATE152465T1/de not_active IP Right Cessation
- 1992-02-03 DE DE59208430T patent/DE59208430D1/de not_active Expired - Fee Related
- 1992-02-03 JP JP04503512A patent/JP3115321B2/ja not_active Expired - Fee Related
- 1992-02-03 CA CA002085481A patent/CA2085481A1/fr not_active Abandoned
-
1993
- 1993-08-09 US US08/104,066 patent/US5346986A/en not_active Expired - Lifetime
-
1994
- 1994-04-04 US US08/222,587 patent/US5684107A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0570404B1 (fr) | 1997-05-02 |
| US5684107A (en) | 1997-11-04 |
| CA2085481A1 (fr) | 1992-08-10 |
| ES2100334T3 (es) | 1997-06-16 |
| JP3115321B2 (ja) | 2000-12-04 |
| JPH06505037A (ja) | 1994-06-09 |
| ATE152465T1 (de) | 1997-05-15 |
| WO1992013912A1 (fr) | 1992-08-20 |
| DE4103969A1 (de) | 1992-08-13 |
| US5346986A (en) | 1994-09-13 |
| EP0570404A1 (fr) | 1993-11-24 |
| DE59208430D1 (de) | 1997-06-05 |
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