DE19540085A1 - Nitratarme, manganfreie Zinkphosphatierung - Google Patents

Nitratarme, manganfreie Zinkphosphatierung

Info

Publication number: DE19540085A1
Authority: DE; Germany
Prior art keywords: ions; phosphating; zinc; free; phosphating solution
Prior art date: 1995-10-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

DE1995140085

Other languages

German (de)

English (en)

Inventor

Jan-Willem Brouwer

Juergen Dr Geke

Karl-Heinz Gottwald

Peter Dr Kuhm

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-10-27

Filing date

1995-10-27

Publication date

1997-04-30

1995-10-27 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

1995-10-27 Priority to DE1995140085 priority Critical patent/DE19540085A1/de

1996-10-18 Priority to PCT/EP1996/004541 priority patent/WO1997016581A2/fr

1996-10-18 Priority to AU72960/96A priority patent/AU7296096A/en

1997-04-30 Publication of DE19540085A1 publication Critical patent/DE19540085A1/de

Status Withdrawn legal-status Critical Current

Links

229910052725 zinc Inorganic materials 0.000 title claims abstract description 31
239000011701 zinc Substances 0.000 title claims abstract description 31
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 30
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 title claims abstract description 12
229910002651 NO3 Inorganic materials 0.000 title claims description 11
238000000034 method Methods 0.000 claims abstract description 54
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 36
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 16
229910000831 Steel Inorganic materials 0.000 claims abstract description 11
239000010959 steel Substances 0.000 claims abstract description 11
229910045601 alloy Inorganic materials 0.000 claims abstract description 8
239000000956 alloy Substances 0.000 claims abstract description 8
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims abstract description 7
229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
239000007921 spray Substances 0.000 claims abstract description 7
229910001453 nickel ion Inorganic materials 0.000 claims abstract description 5
229910001429 cobalt ion Inorganic materials 0.000 claims abstract description 4
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims abstract description 4
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 3
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 21
-1 chlorate ions Chemical class 0.000 claims description 17
150000001768 cations Chemical class 0.000 claims description 15
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 11
229910052751 metal Inorganic materials 0.000 claims description 11
239000002184 metal Substances 0.000 claims description 11
XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 9
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
229910001431 copper ion Inorganic materials 0.000 claims description 9
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 8
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 8
238000007654 immersion Methods 0.000 claims description 8
230000003647 oxidation Effects 0.000 claims description 7
238000007254 oxidation reaction Methods 0.000 claims description 7
238000010422 painting Methods 0.000 claims description 6
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 4
239000011575 calcium Substances 0.000 claims description 4
ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 claims description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
235000000346 sugar Nutrition 0.000 claims description 4
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 3
235000015165 citric acid Nutrition 0.000 claims description 3
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 claims description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 claims description 2
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 2
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
239000000174 gluconic acid Substances 0.000 claims description 2
235000012208 gluconic acid Nutrition 0.000 claims description 2
239000004310 lactic acid Substances 0.000 claims description 2
235000014655 lactic acid Nutrition 0.000 claims description 2
239000001630 malic acid Substances 0.000 claims description 2
235000011090 malic acid Nutrition 0.000 claims description 2
235000002906 tartaric acid Nutrition 0.000 claims description 2
239000011975 tartaric acid Substances 0.000 claims description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
229910052721 tungsten Inorganic materials 0.000 claims description 2
239000010937 tungsten Substances 0.000 claims description 2
101100495769 Caenorhabditis elegans che-1 gene Proteins 0.000 claims 1
FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 claims 1
229910001335 Galvanized steel Inorganic materials 0.000 abstract description 8
239000008397 galvanized steel Substances 0.000 abstract description 8
239000004411 aluminium Substances 0.000 abstract 1
239000002253 acid Substances 0.000 description 14
229910052759 nickel Inorganic materials 0.000 description 14
229910019142 PO4 Inorganic materials 0.000 description 12
235000021317 phosphate Nutrition 0.000 description 12
230000007797 corrosion Effects 0.000 description 10
238000005260 corrosion Methods 0.000 description 10
239000010452 phosphate Substances 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
239000003973 paint Substances 0.000 description 9
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 8
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
229910052748 manganese Inorganic materials 0.000 description 6
239000011572 manganese Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
239000013078 crystal Substances 0.000 description 5
238000005554 pickling Methods 0.000 description 5
241001465754 Metazoa Species 0.000 description 4
239000010941 cobalt Substances 0.000 description 4
229910017052 cobalt Inorganic materials 0.000 description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
238000002161 passivation Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
238000009237 animal bath Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
229910001437 manganese ion Inorganic materials 0.000 description 3
239000000463 material Substances 0.000 description 3
239000011734 sodium Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
230000003213 activating effect Effects 0.000 description 2
230000004913 activation Effects 0.000 description 2
SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 2
SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000010276 construction Methods 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
238000004070 electrodeposition Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
239000007789 gas Substances 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 2
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
229910000399 iron(III) phosphate Inorganic materials 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
UJJUJHTVDYXQON-UHFFFAOYSA-N nitro benzenesulfonate Chemical compound [O-][N+](=O)OS(=O)(=O)C1=CC=CC=C1 UJJUJHTVDYXQON-UHFFFAOYSA-N 0.000 description 2
GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
229910052827 phosphophyllite Inorganic materials 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
239000011591 potassium Substances 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000000758 substrate Substances 0.000 description 2
JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 2
JESXATFQYMPTNL-UHFFFAOYSA-N 2-ethenylphenol Chemical class OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 description 1
ONMOULMPIIOVTQ-UHFFFAOYSA-M 3-Nitrobenzene sulphonate Chemical compound [O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 ONMOULMPIIOVTQ-UHFFFAOYSA-M 0.000 description 1
229910000680 Aluminized steel Inorganic materials 0.000 description 1
229910000967 As alloy Inorganic materials 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910000990 Ni alloy Inorganic materials 0.000 description 1
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
101150049168 Nisch gene Proteins 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
241001499740 Plantago alpina Species 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
150000008043 acidic salts Chemical class 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
150000007514 bases Chemical class 0.000 description 1
230000000711 cancerogenic effect Effects 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
231100000315 carcinogenic Toxicity 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000009918 complex formation Effects 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000005238 degreasing Methods 0.000 description 1
230000002999 depolarising effect Effects 0.000 description 1
239000008121 dextrose Substances 0.000 description 1
238000003618 dip coating Methods 0.000 description 1
230000009189 diving Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012458 free base Substances 0.000 description 1
229930182830 galactose Natural products 0.000 description 1
239000008103 glucose Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
239000008233 hard water Substances 0.000 description 1
239000002920 hazardous waste Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
RBLWMQWAHONKNC-UHFFFAOYSA-N hydroxyazanium Chemical class O[NH3+] RBLWMQWAHONKNC-UHFFFAOYSA-N 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
230000008595 infiltration Effects 0.000 description 1
238000001764 infiltration Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
210000004072 lung Anatomy 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 1
230000003340 mental effect Effects 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
229910001463 metal phosphate Inorganic materials 0.000 description 1
QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
150000002828 nitro derivatives Chemical class 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
MPNNOLHYOHFJKL-UHFFFAOYSA-N peroxyphosphoric acid Chemical compound OOP(O)(O)=O MPNNOLHYOHFJKL-UHFFFAOYSA-N 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000010802 sludge Substances 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
239000004575 stone Substances 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
230000001629 suppression Effects 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
238000004065 wastewater treatment Methods 0.000 description 1
150000003755 zirconium compounds Chemical class 0.000 description 1
OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/14—Orthophosphates containing zinc cations containing also chlorate anions
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/16—Orthophosphates containing zinc cations containing also peroxy-compounds
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/17—Orthophosphates containing zinc cations containing also organic acids
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations

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Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Chemical Treatment Of Metals (AREA)
Coating With Molten Metal (AREA)

DE1995140085 1995-10-27 1995-10-27 Nitratarme, manganfreie Zinkphosphatierung Withdrawn DE19540085A1 (de)

Priority Applications (3)

Application Number	Priority Date	Filing Date	Title
DE1995140085 DE19540085A1 (de)	1995-10-27	1995-10-27	Nitratarme, manganfreie Zinkphosphatierung
PCT/EP1996/004541 WO1997016581A2 (fr)	1995-10-27	1996-10-18	Phosphatation au zinc, a l'aide d'une solution sans manganese et a faible teneur en nitrate
AU72960/96A AU7296096A (en)	1995-10-27	1996-10-18	Low-nitrate, manganese-free zinc phosphatization

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE1995140085 DE19540085A1 (de)	1995-10-27	1995-10-27	Nitratarme, manganfreie Zinkphosphatierung

Publications (1)

Publication Number	Publication Date
DE19540085A1 true DE19540085A1 (de)	1997-04-30

Family

ID=7775975

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE1995140085 Withdrawn DE19540085A1 (de)	1995-10-27	1995-10-27	Nitratarme, manganfreie Zinkphosphatierung

Country Status (3)

Country	Link
AU (1)	AU7296096A (fr)
DE (1)	DE19540085A1 (fr)
WO (1)	WO1997016581A2 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0966554A4 (fr) *	1997-01-24	2000-04-05	Henkel Corp	Composition aqueuse de phosphatation et procede pour surfaces metalliques
US6179934B1 (en)	1997-01-24	2001-01-30	Henkel Corporation	Aqueous phosphating composition and process for metal surfaces
DE10006338A1 (de) *	2000-02-12	2001-08-23	Chemetall Gmbh	Verfahren zur Beschichtung von Metalloberflächen, wässeriges Konzentrat hierzu und Verwendung der beschichteten Metallteile
WO2009115485A1 (fr) *	2008-03-20	2009-09-24	Henkel Ag & Co. Kgaa	Peinture électrophorétique par immersion optimisée d'éléments assemblés et partiellement préphosphatés
CN107937892A (zh) *	2017-12-26	2018-04-20	廊坊京磁精密材料有限公司	高效环保钕铁硼磁体的磷化防锈方法

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LU30515A1 (fr) *
DE860307C (de) *	1942-10-17	1952-12-18	Parker Rust Proof Company	Verfahren zur Vorbereitung von Eisenblechen zur Anfertigung von Behaeltern
CH391420A (de) *	1959-09-23	1965-04-30	Metallgesellschaft Ag	Verfahren zur Aufbringung von Phosphatüberzügen mit chlorathaltigen Phosphatierungslösungen
FR1312108A (fr) *	1961-11-29	1962-12-14	Parker Ste Continentale	Procédé de régénération de solutions de phosphate de zinc chloratées et bromatées pour la phosphatation du fer et de l'acier
GB1272772A (en) *	1968-08-16	1972-05-03	Ici Ltd	Phosphating solutions
JPS52119435A (en) *	1976-04-01	1977-10-06	Nippon Packaging Kk	Phosphating process
JPS5811514B2 (ja) *	1979-05-02	1983-03-03	日本ペイント株式会社	金属表面の保護方法
ES8606528A1 (es) *	1985-02-22	1986-04-01	Henkel Iberica	Procedimiento para el fosfatado de superficies metalicas, especialmente ferreas
DE3630246A1 (de) *	1986-09-05	1988-03-10	Metallgesellschaft Ag	Verfahren zur erzeugung von phosphatueberzuegen sowie dessen anwendung
US4865653A (en) *	1987-10-30	1989-09-12	Henkel Corporation	Zinc phosphate coating process
DE4210513A1 (de) *	1992-03-31	1993-10-07	Henkel Kgaa	Nickel-freie Phosphatierverfahren
DE4214992A1 (de) *	1992-05-06	1993-11-11	Henkel Kgaa	Kupfer enthaltendes, nickelfreies Phosphatierverfahren
JPH08504890A (ja) *	1992-12-22	1996-05-28	ヘンケルコーポレーション	実質的にニッケルを含まないリン酸塩化被膜を形成するための組成物および方法
DE19500562A1 (de) *	1995-01-11	1996-07-18	Henkel Kgaa	Silberhaltige Zinkphosphatierlösung
DE19500927A1 (de) *	1995-01-16	1996-07-18	Henkel Kgaa	Lithiumhaltige Zinkphosphatierlösung
AU699822B2 (en) *	1995-03-07	1998-12-17	Henkel Corporation	Composition and process for forming an underpaint coating on metals

1995
- 1995-10-27 DE DE1995140085 patent/DE19540085A1/de not_active Withdrawn
1996
- 1996-10-18 AU AU72960/96A patent/AU7296096A/en not_active Abandoned
- 1996-10-18 WO PCT/EP1996/004541 patent/WO1997016581A2/fr not_active Ceased

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0966554A4 (fr) *	1997-01-24	2000-04-05	Henkel Corp	Composition aqueuse de phosphatation et procede pour surfaces metalliques
US6179934B1 (en)	1997-01-24	2001-01-30	Henkel Corporation	Aqueous phosphating composition and process for metal surfaces
DE10006338A1 (de) *	2000-02-12	2001-08-23	Chemetall Gmbh	Verfahren zur Beschichtung von Metalloberflächen, wässeriges Konzentrat hierzu und Verwendung der beschichteten Metallteile
DE10006338C2 (de) *	2000-02-12	2003-12-04	Chemetall Gmbh	Verfahren zur Beschichtung von Metalloberflächen, wässeriges Konzentrat hierzu und Verwendung der beschichteten Metallteile
WO2009115485A1 (fr) *	2008-03-20	2009-09-24	Henkel Ag & Co. Kgaa	Peinture électrophorétique par immersion optimisée d'éléments assemblés et partiellement préphosphatés
US8329013B2 (en)	2008-03-20	2012-12-11	Henkel Ag & Co. Kgaa	Optimized electrocoating of assembled and partly prephosphated components
CN107937892A (zh) *	2017-12-26	2018-04-20	廊坊京磁精密材料有限公司	高效环保钕铁硼磁体的磷化防锈方法

Also Published As

Publication number	Publication date
WO1997016581A2 (fr)	1997-05-09
AU7296096A (en)	1997-05-22
WO1997016581A3 (fr)	1997-06-19

Publication	Publication Date	Title
EP0717787B1 (fr)	1998-01-14	Procede de phosphatage sans nickel
EP0817872A1 (fr)	1998-01-14	PROCEDE DE PHOSPHATATION COMPORTANT UNE ETAPE DE RINçAGE FINAL A BASE DE METAL
DE19834796A1 (de)	2000-02-03	Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung
EP0931179B1 (fr)	2000-12-06	Procede pour la phosphatation d'un feuillard d'acier
DE19933189A1 (de)	2001-01-18	Verfahren zur korrosionsschützenden Behandlung oder Nachbehandlung von Metalloberflächen
DE19705701A1 (de)	1998-08-20	Verfahren zur Niedrig-Nickel-Phosphatierung mit metallhaltiger Nachspülung
DE10322446A1 (de)	2004-12-09	Vorbehandlung von Metalloberflächen vor einer Lackierung
EP0889977B1 (fr)	2000-08-23	Phosphatation du zinc avec faible quantite de cuivre et de manganese
DE19606018A1 (de)	1997-08-21	Zinkphosphatierung mit geringen Gehalten an Nickel- und/oder Cobalt
DE19540085A1 (de)	1997-04-30	Nitratarme, manganfreie Zinkphosphatierung
DE4330104A1 (de)	1995-03-09	Nickel- und Kupfer-freies Phosphatierverfahren
DE19956383A1 (de)	2001-05-31	Verfahren zur Phospatierung mit metallhaltiger Nachspülung
DE19538778A1 (de)	1997-04-24	Schichtgewichtssteuerung bei Hydroxylamin-beschleunigten Phosphatiersystemen
DE4341041A1 (de)	1995-06-08	Nickelfreies Phosphatierverfahren mit m-Nitrobenzolsulfonat
DE19958192A1 (de)	2001-06-07	Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung
EP1206589B1 (fr)	2003-04-16	Catalyseur pour la phosphatation de surfaces metalliques
DE19500927A1 (de)	1996-07-18	Lithiumhaltige Zinkphosphatierlösung
DE19733978A1 (de)	1999-02-11	Mit N-Oxiden beschleunigtes Phosphatierverfahren
DE19716075A1 (de)	1998-10-22	Mit Hydroxylamin und Chlorat beschleunigtes Phosphatierverfahren
DE19634732A1 (de)	1998-03-05	Rutheniumhaltige Zinkphosphatierung
EP1208246A1 (fr)	2002-05-29	Procede de phosphatation au zinc faisant intervenir des epoxydes
DE10310680A1 (de)	2004-09-23	Verfahren zur Phosphatierung mit einer Kombination von Beschleunigern
DE19921135A1 (de)	2000-11-09	Verfahren zur nickelarmen Zinkphoshatierung mit anschließender Wasserbehandlung
DE19750301A1 (de)	1999-05-20	Mit N-Oxiden und Clorat beschleunigtes Phosphatierverfahren

Legal Events

Date	Code	Title	Description
1999-12-09	8139	Disposal/non-payment of the annual fee