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CO5540339A2 - PROCESS FOR THE PREPARATION OF CICLOHEXANOL DERIVATIVES - Google Patents

PROCESS FOR THE PREPARATION OF CICLOHEXANOL DERIVATIVES

Info

Publication number
CO5540339A2
CO5540339A2 CO03111625A CO03111625A CO5540339A2 CO 5540339 A2 CO5540339 A2 CO 5540339A2 CO 03111625 A CO03111625 A CO 03111625A CO 03111625 A CO03111625 A CO 03111625A CO 5540339 A2 CO5540339 A2 CO 5540339A2
Authority
CO
Colombia
Prior art keywords
alkyl
hydrogen
cycloalkyl
formula
preparation
Prior art date
Application number
CO03111625A
Other languages
Spanish (es)
Inventor
Keun-Sik Kim
Kwang-Il Kim
Sung-Woo Lee
Jin-Soo Park
Ki-Byung Chai
Original Assignee
Wyeth Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wyeth Corp filed Critical Wyeth Corp
Publication of CO5540339A2 publication Critical patent/CO5540339A2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/30Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1.- Un proceso para la preparación de derivados de ciclohexanol de la fórmula I ( I )en donde R6 y R7 son sustituyentes orto o para, independientemente seleccionados del grupo compuesto por hidrógeno, hidroxilo, alquilo C1-C6, alcoxi C1-C6, aralcoxi C7-C9, alcanoiloxi C2-C7, alquilmercapto C1-C6, halo o trifluorometilo; R8 es hidrógeno o alquilo C1-C6; p es uno de los enteros 0, 1, 2, 3 o 4; y R9 es hidrógeno o alquilo C1-C6; comprendiendo la reacción de un compuesto de la fórmula II con un compuesto de la fórmula III,en presencia de un catalizador de una base no organometálica representada por la fórmula IV o V, en presencia o ausencia de un solvente de reacción.en donde A es -(CH2)n - en donde n es un entero del 2 al 4; B es -(CH2)m - donde m es un entero del 2 al 5; X es CH2, O, NH o NRAND#39, donde RAND#39 es un alquilo C1-C4 o acilo o un polímero de soporte alquilo; cada uno de R1 a R4 son independientemente hidrógeno, un alquilo, un cicloalquilo o un polímero de soporte alquilo o cicloalquilo, y todos de R1 a R4 no son hidrógeno, y R5 es un alquilo, un cicloalquilo o un polímero de soporte alquilo o cicloalquilo, y en donde R9 es un alquilo, el grupo alquilo es introducido por alquilación.1.- A process for the preparation of cyclohexanol derivatives of the formula I (I) in which R6 and R7 are ortho or para substituents, independently selected from the group consisting of hydrogen, hydroxyl, C1-C6 alkyl, C1-C6 alkoxy, C7-C9 aralkoxy, C2-C7 alkanoyloxy, C1-C6 alkylmercapto, halo or trifluoromethyl; R8 is hydrogen or C1-C6 alkyl; p is one of the integers 0, 1, 2, 3 or 4; and R9 is hydrogen or C1-C6 alkyl; comprising the reaction of a compound of the formula II with a compound of the formula III, in the presence of a catalyst of a non-organometallic base represented by the formula IV or V, in the presence or absence of a reaction solvent. wherein A is - (CH2) n - where n is an integer from 2 to 4; B is - (CH2) m - where m is an integer from 2 to 5; X is CH2, O, NH or NRAND # 39, where RAND # 39 is a C1-C4 alkyl or acyl or an alkyl support polymer; each of R1 to R4 are independently hydrogen, an alkyl, a cycloalkyl or an alkyl or cycloalkyl support polymer, and all of R1 to R4 are not hydrogen, and R5 is an alkyl, a cycloalkyl or an alkyl or cycloalkyl support polymer , and wherein R9 is an alkyl, the alkyl group is introduced by alkylation.

CO03111625A 2001-06-22 2003-12-22 PROCESS FOR THE PREPARATION OF CICLOHEXANOL DERIVATIVES CO5540339A2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020010035889A KR20030000217A (en) 2001-06-22 2001-06-22 Process for the preparation of cyclohexanol derivatives

Publications (1)

Publication Number Publication Date
CO5540339A2 true CO5540339A2 (en) 2005-07-29

Family

ID=36604137

Family Applications (1)

Application Number Title Priority Date Filing Date
CO03111625A CO5540339A2 (en) 2001-06-22 2003-12-22 PROCESS FOR THE PREPARATION OF CICLOHEXANOL DERIVATIVES

Country Status (21)

Country Link
EP (1) EP1397344A1 (en)
JP (1) JP2004531577A (en)
KR (2) KR20030000217A (en)
CN (1) CN1267410C (en)
AR (1) AR034609A1 (en)
BR (1) BR0210542A (en)
CA (1) CA2450914A1 (en)
CO (1) CO5540339A2 (en)
EA (1) EA007486B1 (en)
EC (1) ECSP034920A (en)
HU (1) HUP0400867A3 (en)
IL (1) IL159448A0 (en)
MX (1) MXPA03011401A (en)
NO (1) NO20035586L (en)
NZ (1) NZ530594A (en)
PL (1) PL366613A1 (en)
SG (1) SG156520A1 (en)
TW (1) TWI250973B (en)
UA (1) UA78511C2 (en)
WO (1) WO2003000652A1 (en)
ZA (1) ZA200400451B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100651353B1 (en) * 2002-02-01 2006-11-28 에스케이 주식회사 Process for continuously preparing venlafaxine intermediates in high yield
WO2005049560A2 (en) * 2003-09-29 2005-06-02 Sun Pharmaceutical Industries Limited Process for the preparation of anti-depressant compound
TW200523258A (en) * 2003-10-02 2005-07-16 Wyeth Corp Process for the preparation of 1-[cyano(phenyl)methyl]-cyclohexanol compounds
MX2007016049A (en) * 2005-06-29 2008-03-10 Wyeth Corp Process for the preparation of 1-[cyano (4-hydroxyphenyl)methyl]c yclohexanol compounds.
MX2007016179A (en) 2006-04-17 2008-03-11 Teva Pharma Polymorphic forms of tegaserod maleate.
US20090062572A1 (en) * 2006-07-26 2009-03-05 Valerie Niddam-Hildesheim Processes for the synthesis of O-desmethylvenlafaxine
JP4763788B2 (en) * 2006-07-26 2011-08-31 テバ ファーマシューティカル インダストリーズ リミティド Method for synthesizing O-desmethylvenlafaxine
WO2011121452A2 (en) 2010-03-29 2011-10-06 Pliva Hrvatska D.O.O. Crystal forms of o-desmethylvenlafaxine fumarate
US10428291B2 (en) 2014-03-28 2019-10-01 Cummins Filtration Ip, Inc. Ashless oil additives and their use as TBN boosters
JP2021510385A (en) 2018-01-10 2021-04-22 ハンツマン・インターナショナル・エルエルシー Polyurethane-containing formulation with isoanate functional value

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4535186A (en) * 1983-04-19 1985-08-13 American Home Products Corporation 2-Phenyl-2-(1-hydroxycycloalkyl or 1-hydroxycycloalk-2-enyl)ethylamine derivatives
GB8902209D0 (en) * 1989-02-01 1989-03-22 Wyeth John And Brother Limited Preparation of cyclohexanol derivatives and novel thioamide intermediates
TWI228118B (en) * 2000-08-30 2005-02-21 Ciba Sc Holding Ag Process for the preparation of substituted phenylacetonitriles

Also Published As

Publication number Publication date
BR0210542A (en) 2004-06-22
HUP0400867A2 (en) 2004-08-30
KR20040011548A (en) 2004-02-05
KR100874835B1 (en) 2008-12-19
HUP0400867A3 (en) 2005-04-28
TWI250973B (en) 2006-03-11
JP2004531577A (en) 2004-10-14
ECSP034920A (en) 2004-02-26
MXPA03011401A (en) 2004-04-05
ZA200400451B (en) 2005-06-29
WO2003000652A8 (en) 2004-05-21
CN1531524A (en) 2004-09-22
UA78511C2 (en) 2007-04-10
IL159448A0 (en) 2004-06-01
CA2450914A1 (en) 2003-01-03
NZ530594A (en) 2006-06-30
KR20030000217A (en) 2003-01-06
WO2003000652A1 (en) 2003-01-03
SG156520A1 (en) 2009-11-26
PL366613A1 (en) 2005-02-07
CN1267410C (en) 2006-08-02
EA007486B1 (en) 2006-10-27
EA200400069A1 (en) 2004-06-24
AR034609A1 (en) 2004-03-03
EP1397344A1 (en) 2004-03-17
NO20035586D0 (en) 2003-12-15
NO20035586L (en) 2003-12-15

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