CN205944325U - Positive and negative pole piece processing system of lithium cell - Google Patents
Positive and negative pole piece processing system of lithium cell Download PDFInfo
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Abstract
Description
技术领域technical field
本实用新型属于废电池处理领域,具体涉及一种锂电池正负极片处理系统。The utility model belongs to the field of waste battery treatment, in particular to a treatment system for positive and negative plates of a lithium battery.
背景技术Background technique
废弃的锂电池中含有大量不可再生且经济价值高的金属资源,锂电池中的正极片材料为钴酸锂粉、负极片材料为石墨粉,无论正极片还是负极片中均含有大量的镍、铜、铝等金属材料。如果能有效地回收处理废弃或不合格的锂电池,不仅能减轻废旧电池对环境的压力,还可以避免造成钴、镍等金属资源的浪费。目前常见的处理办法有:深海填埋法、湿法冶金技术以及硫酸溶解法、碱煮-酸溶法等化工处理办法;深海填埋法严重污染环境,湿法冶金技术以及化工处理办法均需要添加多种化学物质,仍对环境造成污染,且分离过程复杂、工艺条件高,成本高,且对钴、铝分离效果不好。Abandoned lithium batteries contain a large amount of non-renewable metal resources with high economic value. The positive electrode material in lithium batteries is lithium cobalt oxide powder, and the negative electrode material is graphite powder. Both positive and negative electrodes contain a large amount of nickel, Metal materials such as copper and aluminum. If waste or unqualified lithium batteries can be effectively recycled, it will not only reduce the pressure on the environment from waste batteries, but also avoid the waste of metal resources such as cobalt and nickel. At present, the common treatment methods are: deep sea landfill, hydrometallurgical technology and chemical treatment methods such as sulfuric acid dissolution method, alkali boiling-acid dissolution method; deep sea landfill method seriously pollutes the environment, hydrometallurgical technology and chemical treatment methods all need Adding a variety of chemical substances still causes pollution to the environment, and the separation process is complicated, the process conditions are high, the cost is high, and the separation effect on cobalt and aluminum is not good.
实用新型内容Utility model content
本实用新型的目的是针对现有技术中废锂电池正负极片处理时存在的技术问题,提供一种锂电池正负极片处理系统,该系统完全采用机械敲打、破碎、分离等物理处理办法回收、分离锂电池中正负极材料,整套系统中不添加任何化学成分,不采用任何化学处理工艺,完全环保,一套系统可实现废锂电池正负极片材料的分离、回收的完整操作,无需其他设备配合,工序完整,简便。The purpose of this utility model is to provide a lithium battery positive and negative electrode processing system for the technical problems existing in the prior art in the treatment of waste lithium battery positive and negative electrodes. The method is to recycle and separate the positive and negative electrode materials in lithium batteries. The whole system does not add any chemical components, does not use any chemical treatment process, and is completely environmentally friendly. A set of systems can realize the complete operation of separation and recycling of the positive and negative electrode materials of waste lithium batteries. Without the cooperation of other equipment, the process is complete and simple.
为了解决上述技术问题,本实用新型采用的技术方案是:一种锂电池正负极片处理系统,该系统包括喂料平台、输送机、粉碎机、分析机、引风机、集料装置、脉冲净化器、以及分级筛及分选机;所述喂料平台输出端连接输送机,输送机输出端连接粉碎机,粉碎机输出端连接分析机,分析机输出端有两个:第一输出端经引风机连通集料装置,第二输出端连接分级筛,所述集料装置排气口连接脉冲净化器,集料装置出料口连接物料收集装置;所述分级筛输出端为三个:第一输出端经引风机连接集料装置,第二及第三输出端分别连接金属处理装置。In order to solve the above technical problems, the technical solution adopted by the utility model is: a lithium battery positive and negative plate processing system, the system includes a feeding platform, a conveyor, a pulverizer, an analysis machine, an induced draft fan, a collecting device, a pulse Purifier, grading screen and sorting machine; the output end of the feeding platform is connected to the conveyor, the output end of the conveyor is connected to the pulverizer, the output end of the pulverizer is connected to the analysis machine, and there are two output terminals of the analysis machine: the first output end Connect the collecting device through the induced draft fan, the second output end is connected to the classifying screen, the exhaust port of the collecting device is connected to the pulse purifier, and the outlet of the collecting device is connected to the material collecting device; the output ports of the classifying screen are three: The first output end is connected to the collecting device through the induced draft fan, and the second and third output ends are respectively connected to the metal processing device.
基于上述技术方案,所述集料装置由两个集料器组成:分为第一集料器及第二集料器,第一集料器出气口连接第二集料器进气口,第一及第二集料器出料口分别连接物料收集装置。Based on the above technical solution, the collecting device is composed of two collecting devices: the first collecting device and the second collecting device, the air outlet of the first collecting device is connected to the air inlet of the second collecting device, and the second collecting device is connected to the air inlet of the second collecting device. The outlets of the first and second collectors are respectively connected to the material collecting device.
基于上述技术方案,所述金属处理装置包括气流分选机及铝粉收集装置,分级筛第二输出端连接气流分选机,气流分选机分为金属输出端和非金属输出端,分级筛第三输出端及气流分选机金属输出端分别连接铝粉收集装置,气流分选机非金属输出端通过引风机连通第一集料器,所述物料收集装置为钴酸锂粉收集装置,第一及第二集料器出料口分别连接钴酸锂粉收集装置。Based on the above technical solution, the metal processing device includes an airflow separator and an aluminum powder collection device, the second output end of the classifying screen is connected to the airflow separator, the airflow separator is divided into a metal output end and a non-metal output end, and the classifying screen The third output end and the metal output end of the airflow separator are respectively connected to the aluminum powder collection device, and the non-metal output end of the airflow separator is connected to the first collector through the induced draft fan. The material collection device is a lithium cobaltate powder collection device, The discharge ports of the first and second collectors are respectively connected with lithium cobalt oxide powder collection devices.
基于上述技术方案,所述金属处理装置包括磁选机、比重分选机、铜粉收集装置及镍收集装置,分级筛第二输出端连接比重分选机,分级筛第三输出端连接磁选机,磁选机有两个物料输出口:第一物料输出口连接镍收集装置,第二物料输出口连接铜粉收集装置,所述比重分选机分为金属输出端和非金属输出端,比重分选机金属输出端连接到铜粉收集装置上、非金属输出端通过引风机连通第一集料器,所述物料收集装置为石墨粉收集装置,第一及第二集料器出料口分别连接石墨粉收集装置。Based on the above technical scheme, the metal processing device includes a magnetic separator, a specific gravity separator, a copper powder collection device and a nickel collection device, the second output end of the grading screen is connected to the specific gravity separator, and the third output end of the grading sieve is connected to the magnetic separator. The magnetic separator has two material output ports: the first material output port is connected to the nickel collection device, and the second material output port is connected to the copper powder collection device. The specific gravity separator is divided into a metal output port and a non-metallic output port. The metal output end of the specific gravity separator is connected to the copper powder collection device, and the non-metal output end is connected to the first collector through the induced draft fan. The material collection device is a graphite powder collection device, and the first and second collectors are discharged The ports are respectively connected to the graphite powder collection device.
有益效果:本实用新型为整套系统,各环节上、下衔接合理、节凑,系统完整,一套系统可实现废锂电池正极片及负极片回收、分离的完整操作,无需其他设备配合,正极片中的钴酸锂粉及负极片中的石墨粉能从废料中完全分离出来、分离纯度高,分离出的金属材料:铝粉、铜粉以及金属镍可回收再用,整套系统主要靠机械敲打、破碎等物料办法操作处理,中间不加入任何化学成分,操作过程完全环保,整套系统自动化程度高,生产效率快,省工省力。Beneficial effects: the utility model is a complete system, the upper and lower connections of each link are reasonable and compact, and the system is complete. A set of systems can realize the complete operation of recycling and separating the positive and negative electrodes of waste lithium batteries without the cooperation of other equipment. The lithium cobalt oxide powder in the sheet and the graphite powder in the negative electrode sheet can be completely separated from the waste with high separation purity. The separated metal materials: aluminum powder, copper powder and metal nickel can be recycled and reused. The whole system mainly relies on mechanical Beating, crushing and other materials are operated and processed without adding any chemical components in the middle. The operation process is completely environmentally friendly. The whole system has a high degree of automation, fast production efficiency, and labor-saving.
附图说明Description of drawings
图1是本实用新型废锂电池正极片处理系统结构示意图;Fig. 1 is a schematic structural diagram of the utility model waste lithium battery positive plate processing system;
图2是本实用新型废锂电池负极片处理系统结构示意图。Fig. 2 is a schematic diagram of the structure of the waste lithium battery negative plate treatment system of the utility model.
具体实施方式detailed description
下面结合具体实施方式对本实用新型做进一步说明,以便更好地理解本实用新型技术方案。The utility model will be further described below in combination with specific embodiments, so as to better understand the technical solution of the utility model.
实施例1:锂电池正负极片处理系统,本实施例系统主要用于正极片处理,该系统包括喂料平台、输送机、粉碎机、分析机、引风机、第一集料器及第二集料器、脉冲净化器以及分级筛及分选机;所述喂料平台输出端连接输送机,输送机输出端连接粉碎机,粉碎机输出端连接分析机,分析机输出端有两个:第一输出端经引风机连通第一集料器,第二输出端连接分级筛,第一集料器输出端连接第二集料器,第二集料器排气口连接脉冲净化器,集料装置出料口连接物料收集装置;所述分级筛输出端为三个:第一输出端经引风机连接集料装置,第二及第三输出端分别连接金属处理装置。所述金属处理装置包括气流分选机及铝粉收集装置,分级筛第二输出端连接气流分选机,分级筛第三输出端及气流分选机金属输出端分别连接铝粉收集装置,气流分选机非金属输出端通过引风机连通第一集料器,所述物料收集装置为钴酸锂粉收集装置,第一及第二集料器出料口分别连接钴酸锂粉收集装置。Embodiment 1: Lithium battery positive and negative plate processing system. The system in this embodiment is mainly used for positive plate processing. The system includes a feeding platform, a conveyor, a pulverizer, an analysis machine, an induced draft fan, the first collector and the second 2. Collector, pulse purifier, grading screen and sorting machine; the output end of the feeding platform is connected to the conveyor, the output end of the conveyor is connected to the pulverizer, the output end of the pulverizer is connected to the analysis machine, and the output end of the analysis machine has two : The first output end is connected to the first collector through the induced draft fan, the second output is connected to the grading screen, the output end of the first collector is connected to the second collector, and the exhaust port of the second collector is connected to the pulse purifier. The discharge port of the collecting device is connected to the material collecting device; there are three output ports of the grading sieve: the first output port is connected to the collecting device through the induced draft fan, and the second and third output ports are connected to the metal processing device respectively. The metal processing device includes an airflow separator and an aluminum powder collection device, the second output end of the grading sieve is connected to the airflow separator, the third output end of the grading sieve and the metal output end of the airflow separator are respectively connected to the aluminum powder collection device, and the air flow The non-metal output end of the sorter is connected to the first collector through the induced draft fan. The material collection device is a lithium cobalt oxide powder collection device, and the discharge ports of the first and second collectors are respectively connected to the lithium cobalt oxide powder collection device.
本系统中各组件作用如下:1.粉碎机:把破碎后的物料进行粉碎;2.分析机:把粉碎后的物料进行风选分离;3.引风机:把风选后石墨粉进行收集;4.集料器:把经过引风机的粉尘进行收集排放;5.脉冲净化器(空气净化器):把整套设备的粉尘进行净化;6.分级筛:把经分析机分选的物料进行筛选,把大的金属物料分选出来;7.磁选机:把金属中镍分离出来;8.气流分选机:把经过分选筛的细的物料再进行分级分选,把金属彻底分离出来。The functions of each component in this system are as follows: 1. Crusher: crush the crushed materials; 2. Analyzer: separate the crushed materials by winnowing; 3. Induced fan: collect the graphite powder after winnowing; 4. Collector: collect and discharge the dust passing through the induced draft fan; 5. Pulse purifier (air purifier): purify the dust of the whole set of equipment; 6. Classifying sieve: screen the materials sorted by the analysis machine , to sort out the large metal materials; 7. Magnetic separator: to separate the nickel in the metal; 8. Airflow separator: to classify and sort the fine materials that have passed through the sorting screen, and completely separate the metal .
本实施例中正极片处理工艺由以下工序组成:废锂电池正极片材料经输送机输送至粉碎机粉碎,粉碎至15-25目;经粉碎机粉碎后的物料输送至分析机,分析机将粉碎后的物料进行风选分离,分选出金属材料和钴酸锂粉;分选出的钴酸锂粉经引风机输送至集料装置收集,集料装置中的废气通过脉冲净化器净化后输出;The positive electrode sheet treatment process in this embodiment consists of the following procedures: the positive electrode sheet material of the waste lithium battery is transported to the pulverizer through the conveyor for pulverization, and pulverized to 15-25 mesh; the material pulverized by the pulverizer is transported to the analysis machine, and the analysis machine The pulverized materials are separated by air separation, and the metal materials and lithium cobalt oxide powder are separated; the sorted lithium cobalt oxide powder is transported to the collection device by the induced draft fan for collection, and the waste gas in the collection device is purified by the pulse purifier output;
经过分析机分析出的金属物料进入分级筛进行筛选,分级筛将金属材料进一步分离,分离出钴酸锂粉和金属部分,从分级筛输出的钴酸锂粉从第一输出端通过引风机汇入集料器,从分级筛筛选出的铝粉通过第三输出端直接收集,筛选出的其他物料通过第二输出端进入气流分选机,气流分选机把经过分级筛的细的物料再进行分级分选,分选出金属铝和钴酸锂粉,分离出的钴酸锂粉通过引风机汇入集料器收集,至此,正极片中的非金属部分钴酸锂粉及金属部分铝粉完成彻底分离。The metal material analyzed by the analyzer enters the grading sieve for screening, the grading sieve further separates the metal material, and separates the lithium cobaltate powder and the metal part, and the lithium cobaltate powder output from the grading sieve passes through the induced draft fan from the first output end. The aluminum powder screened out from the grading sieve is collected directly through the third output end, and other materials screened out enter the airflow separator through the second output end, and the airflow separator passes the fine materials through the grading sieve into the air separator. Carry out classification and sorting, sort out metal aluminum and lithium cobalt oxide powder, and the separated lithium cobalt oxide powder is collected by the induced draft fan into the collector. So far, the non-metallic part lithium cobalt oxide powder and the metal part aluminum The powder is completely separated.
实施例2:锂电池正负极片处理系统本实施例内容实施例1内容基本相同,相同部分内容不再重述,与实施例1不同的是:本实施例系统主要用于负极片处理,具体区别如下:金属处理装置包括磁选机、比重分选机、铜粉收集装置及镍收集装置,所述分级筛第二输出端连接比重分选机,分级筛第三输出端连接磁选机,磁选机有两个物料输出口:第一物料输出口连接镍收集装置,第二物料输出口连接铜粉收集装置,所述比重分选机金属输出端连接到铜粉收集装置上、非金属输出端通过引风机连通第一集料器,所述物料收集装置为石墨粉收集装置,第一及第二集料器出料口分别连接是石墨粉收集装置。Embodiment 2: Lithium battery positive and negative plate processing system The contents of this embodiment are basically the same as in Example 1, and the same parts will not be repeated. The difference from Example 1 is that the system in this embodiment is mainly used for negative plate processing. The specific differences are as follows: the metal processing device includes a magnetic separator, a specific gravity separator, a copper powder collection device and a nickel collection device, the second output end of the grading sieve is connected to the specific gravity separator, and the third output end of the grading sieve is connected to the magnetic separator , The magnetic separator has two material output ports: the first material output port is connected to the nickel collection device, the second material output port is connected to the copper powder collection device, and the metal output end of the specific gravity separator is connected to the copper powder collection device. The metal output end is connected to the first collector through an induced draft fan, the material collection device is a graphite powder collection device, and the outlets of the first and second collectors are respectively connected to a graphite powder collection device.
本实施例中负极片处理工艺由以下工序组成:废锂电池负极片材料经输送机输送至粉碎机粉碎,粉碎至15-25目;经粉碎机粉碎后的物料输送至分析机,分析机将粉碎后的物料进行风选分离,分选出金属材料和石墨粉;分选出的石墨粉经引风机输送至集料装置收集,集料装置中的废气通过脉冲净化器净化后输出;The negative electrode sheet treatment process in this embodiment is composed of the following procedures: the waste lithium battery negative electrode sheet material is transported to a pulverizer by a conveyor for pulverization, and pulverized to 15-25 mesh; the pulverized material is transported to an analyzer, and the analyzer will The pulverized materials are separated by winnowing, and the metal materials and graphite powder are sorted out; the sorted graphite powder is transported to the collection device by the induced draft fan for collection, and the waste gas in the collection device is purified by the pulse purifier and then output;
经过分析机分析出的金属物料进入分级筛进行筛选,分级筛将金属材料进一步分离,分离出石墨粉和金属部分,从分级筛输出的石墨粉从第一输出端通过引风机汇入集料器,从分级筛筛选出的铜粉通过第三输出端进入磁选机,磁选机把铜粉中的镍分离出来,从分级筛筛选出的其他物料通过第二输出端进入比重分选机,比重分选机把分级筛筛选出的其他物料进行比重分离,进一步分离出铜粉及石墨粉,分离出的石墨粉通过引风机汇入集料器收集。至此,负极片中的非金属部分石墨粉及金属部分铜粉及镍完成彻底分离。The metal material analyzed by the analyzer enters the grading sieve for screening, the grading sieve further separates the metal material, separates the graphite powder and the metal part, and the graphite powder output from the grading sieve enters the collector from the first output end through the induced draft fan , the copper powder screened from the grading sieve enters the magnetic separator through the third output end, and the magnetic separator separates the nickel in the copper powder, and other materials screened from the grading sieve enter the specific gravity separator through the second output end, The specific gravity separator performs specific gravity separation on other materials screened out by the grading sieve, and further separates copper powder and graphite powder, and the separated graphite powder is collected by the induced draft fan into the collector. So far, the graphite powder of the non-metal part and the copper powder and nickel of the metal part in the negative electrode sheet have been completely separated.
需要说明的是:本实用新型要保护的正负极片处理系统,其中正极片处理系统及负极片处理系统共用一套主系统,两者只是在金属处理部分稍有区别,本实用新型将各处理部分结合在一起组成一套完整的系统,一套系统即可实现废锂电池正极片材料及负极片材料的回收、分离操作,分离出来的石墨粉与钴酸锂混合粉单独收集,整套操作无需其他设备配合,不添加任何化学处理工艺,完全靠机械物理操作完成,完全环保,各组分分离纯度高,能源利用率高,整套系统自动化程度高,生产效率快,非常值得推广实施。It should be noted that: the positive and negative electrode sheet processing system to be protected by the utility model, wherein the positive electrode sheet processing system and the negative electrode sheet processing system share a set of main systems, the two are only slightly different in the metal processing part, the utility model will each The processing parts are combined to form a complete system. A set of systems can realize the recycling and separation of the positive and negative electrode materials of waste lithium batteries. The separated graphite powder and lithium cobaltate mixed powder are collected separately, and the whole set of operations No other equipment is needed, no chemical treatment process is added, and it is completely completed by mechanical and physical operations. It is completely environmentally friendly, has high separation purity of each component, high energy utilization rate, high degree of automation of the whole system, and fast production efficiency. It is very worthy of promotion and implementation.
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| CN201620932671.6U CN205944325U (en) | 2016-08-25 | 2016-08-25 | Positive and negative pole piece processing system of lithium cell |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106058359A (en) * | 2016-08-25 | 2016-10-26 | 巩义市城区润达机械厂 | Lithium batteries' positive and negative plate processing system and technology thereof |
| CN108666643A (en) * | 2018-04-17 | 2018-10-16 | 祝融峰 | Method for recycling anode material of lithium ion battery and device |
| JP2020174032A (en) * | 2019-04-10 | 2020-10-22 | 住友金属鉱山株式会社 | Method for collecting valuable resources from waste batteries and crushing equipment |
| CN116247325A (en) * | 2023-03-28 | 2023-06-09 | 重庆大学 | Product separation and collection equipment of retired lithium ion battery anode active material recovery cabin |
-
2016
- 2016-08-25 CN CN201620932671.6U patent/CN205944325U/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106058359A (en) * | 2016-08-25 | 2016-10-26 | 巩义市城区润达机械厂 | Lithium batteries' positive and negative plate processing system and technology thereof |
| CN106058359B (en) * | 2016-08-25 | 2018-07-06 | 巩义市城区润达机械厂 | Lithium battery positive-negative plate processing system and technique |
| CN108666643A (en) * | 2018-04-17 | 2018-10-16 | 祝融峰 | Method for recycling anode material of lithium ion battery and device |
| JP2020174032A (en) * | 2019-04-10 | 2020-10-22 | 住友金属鉱山株式会社 | Method for collecting valuable resources from waste batteries and crushing equipment |
| JP7423910B2 (en) | 2019-04-10 | 2024-01-30 | 住友金属鉱山株式会社 | Method for recovering valuables from waste batteries, crushing equipment |
| CN116247325A (en) * | 2023-03-28 | 2023-06-09 | 重庆大学 | Product separation and collection equipment of retired lithium ion battery anode active material recovery cabin |
| CN116247325B (en) * | 2023-03-28 | 2025-03-18 | 重庆大学 | A product separation and collection device for a retired lithium-ion battery positive electrode active material recovery cabin |
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