CN1961101B - Process for producing synthetic fibers suitable for artificial turf sports fields and such synthetic fibers - Google Patents
Process for producing synthetic fibers suitable for artificial turf sports fields and such synthetic fibers Download PDFInfo
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- D01D5/00—Formation of filaments, threads, or the like
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- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
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Abstract
Description
技术领域 technical field
本发明涉及一种适用于人造草坪运动场的合成纤维的制备方法,其包括以下步骤:The present invention relates to a kind of preparation method that is applicable to the synthetic fiber of artificial turf sports field, it comprises the following steps:
i)提供合成材料层;和i) providing a synthetic material layer; and
ii)由该合成材料层制得合成纤维。ii) Synthetic fibers are produced from the layer of synthetic material.
本发明还涉及这样的合成纤维和适用于运动场的人造草坪,该草坪由附着有本发明合成纤维的基底组成。The invention also relates to such synthetic fibers and to artificial turf suitable for use in sports fields, the turf consisting of a substrate to which the synthetic fibers according to the invention are attached.
背景技术 Background technique
目前,合成材料正用于各种目的。近年来,尤其是关于运动场人造草坪的各种合成材料的应用已明显增加。Synthetic materials are currently being used for various purposes. In recent years, the use of various synthetic materials has increased remarkably, especially with regard to artificial turf for sports fields.
在这一点上,人们的研究尤其集中在运动场人造草坪所用合成纤维的改进上,其中,将一定长度的纤维通过诸如簇生的方式附着于基底上。人们已经进行了人造草纤维以及由此得到的人造草坪运动场的改进,从而目前能够建成不仅在外观方面,而且特别是在运动中表现出的情况都与天然草坪运动场无太大区别的人造草坪运动场。In this regard, research has particularly focused on the improvement of synthetic fibers for use in artificial turf for sports fields in which lengths of fibers are attached to a substrate by means such as tufting. People have carried out the improvement of artificial turf fibers and the resulting artificial turf sports fields, so that it is now possible to build artificial turf sports fields not only in appearance, but especially in sports performance, which are not much different from natural turf sports fields. .
与天然草坪运动场不同,人造草坪运动场可以更长久和更集中的使用,而不必考虑天气情况。目前,新型人造草纤维的发展主要集中在得到一种纤维,其可以进一步减少受伤,例如滑动时引起的擦伤和灼伤、或扭伤关节的发生率。Unlike natural turf sports fields, artificial turf sports fields can be used longer and more intensively, regardless of weather conditions. At present, the development of new artificial grass fibers is mainly focused on obtaining a fiber that can further reduce the incidence of injuries, such as abrasions and burns caused by sliding, or sprained joints.
已明确改进用于人造草坪运动场的现有纤维可由合成材料层制得,例如通过剪切工序。该合成材料层可由不同合成材料的混合物组成,例如,其中一种合成材料赋予所述纤维以特定长度(抵抗断裂或撕裂),而混合物中的另一种合成材料为所述纤维提供特定的弹性或柔韧性或更好的滑动性能。Existing fibers, which have been specifically modified for use in artificial turf sports fields, can be produced from layers of synthetic material, for example by a shearing process. The synthetic material layer may consist of a mixture of different synthetic materials, for example, where one synthetic material imparts a specific length (resistance to breaking or tearing) to the fibers and another synthetic material in the mixture provides the fibers with a specific Elasticity or flexibility or better sliding properties.
这种现有合成纤维的一个缺点是:由于其均相结构,纤维的所有(次要)性质均匀地结合在纤维中。结果是,纤维具有的某些性质不如期望的显著,而其它性质却比期望的明显。因此,现有纤维的组成通常被标准化,而且它们的生产和材料成本通常不必要地高。A disadvantage of this existing synthetic fiber is that, due to its homogeneous structure, all (secondary) properties of the fiber are homogeneously incorporated in the fiber. As a result, fibers have certain properties that are less pronounced than desired, while others are more pronounced than desired. Consequently, the composition of existing fibers is often standardized, and their production and material costs are often unnecessarily high.
发明内容 Contents of the invention
因此,本发明的目的是提供一种更为通用的纤维,其一方面可用于特定用途,另一方面节省了生产和材料成本。根据本发明,所述合成材料层由至少两层不同的合成材料组成,采用共挤出法制备。It is therefore an object of the present invention to provide a more versatile fiber which, on the one hand, can be used for a specific application and, on the other hand, saves production and material costs. According to the invention, said layer of synthetic material consists of at least two layers of different synthetic materials, produced by coextrusion.
共挤出步骤实现了所用合成材料的各种性质的分离。通过赋予合成纤维以层状结构,能够使各层具有特定功能性质(function-specific property),该性质不需要、或仅需以明显降低的程度存在于纤维中的其它部位。这使得选择专门用于特定用途的纤维配方成为可能,除了更有效的材料消耗外,还产生一种合成纤维,其比均相组成的已知纤维具有明显改进的运动和纤维性。The coextrusion step enables the separation of the various properties of the synthetic materials used. By imparting a layered structure to synthetic fibers, it is possible to impart function-specific properties to the individual layers which need not, or only need to be present to a significantly reduced extent, elsewhere in the fiber. This enables the selection of fiber formulations tailored for specific applications, which, in addition to more efficient material consumption, result in a synthetic fiber with significantly improved movement and fibrous properties compared to known fibers of homogeneous composition.
根据本发明,通过在共挤出过程后拉伸纤维可以显著改进合成纤维的运动性。除了长度增加外,在拉伸过程后根据本发明正确选择材料以提供在横向上具有如此强度的纤维(例如其不易断裂)。当用于人造草坪运动场时,该纤维以及后续的人造草坪具有更长的寿命,并且人造草坪不需太多维护,因此可保持更长的运动时间。此外,也明显降低了运动者受伤的风险。According to the present invention, the movement of synthetic fibers can be significantly improved by drawing the fibers after the coextrusion process. In addition to the increase in length, a correct choice of material according to the invention after the stretching process provides fibers with such strength in the transverse direction that they are less likely to break, for example. When used on artificial turf sports fields, the fibers, and consequently the artificial turf, have a longer lifespan, and the artificial turf does not require as much maintenance so it stays active longer. In addition, the risk of injury for athletes is also significantly reduced.
根据本发明,纤维由至少一根或几根缠绕的单丝组成。该纤维可形成带状,更具体地,所述带状纤维可以被形成为原纤维化的带状纤维。According to the invention, the fibers consist of at least one or several twisted monofilaments. The fibers may be formed into ribbons, more specifically, the ribbon fibers may be formed into fibrillated ribbon fibers.
在根据本发明方法的第一实施方案中,合成材料层由第一合成材料的芯层组成,所述芯层的两面包覆有一个或多个外层,每个外层由不同的合成材料组成。In a first embodiment of the method according to the invention, the layer of synthetic material consists of a core layer of a first synthetic material covered on both sides by one or more outer layers each made of a different synthetic material composition.
由此可以获得不同合成材料的不同性质的功能分离,其中每个合成材料层具有特定功能性质,该性质在纤维中的其它部位是不必要的或不起作用的。A functional separation of the different properties of the different synthetic materials can thus be achieved, wherein each synthetic material layer has specific functional properties which are not necessary or have no effect elsewhere in the fiber.
依据欲制备的合成纤维所期望的特定功能性质,所述合成材料层可以具有不同的厚度。The layer of synthetic material may have different thicknesses depending on the specific functional properties desired for the synthetic fiber to be produced.
在第一实施方案中,第一合成材料由聚合物和塑性体的混合物组成,其中芯层中塑性体的比例尤其是30-80wt%,芯层中塑性体的比例更尤其是30-50wt%。从特定功能的观点看,这使得具有芯层的纤维显示出非常有利的不断裂性。In a first embodiment, the first synthetic material consists of a mixture of polymers and plastomers, wherein the proportion of plastomers in the core layer is especially 30-80% by weight, and the proportion of plastomers in the core layer is more particularly 30-50% by weight . From a specific functional point of view, this enables fibers with a core to exhibit a very favorable non-breakability.
在另一实施方案中,至少一种其它合成材料可包括亲水性添加剂。由此获得的人造草纤维具有能够吸湿(水)的特定功能特性。这使得人造草坪运动场能更长时间地保持湿润,从而对运动性能(滑动等)具有积极影响。当在运动场上运动时,吸收的水分如在天然草坪上一样被释放。In another embodiment, at least one other synthetic material may include a hydrophilic additive. The artificial grass fibers thus obtained have specific functional properties of being able to absorb moisture (water). This allows the artificial turf sports field to remain wet longer, which has a positive effect on sports performance (sliding, etc.). When playing on a sports field, the absorbed moisture is released as it is on natural grass.
可用作共挤出纤维的上层或外层的亲水性添加剂的例子是乙烯-乙烯醇共聚物。依据共聚物中乙烯醇的含量,该聚合物能够吸收更多的水分。An example of a hydrophilic additive that can be used as the top or outer layer of a coextruded fiber is ethylene vinyl alcohol copolymer. Depending on the amount of vinyl alcohol in the copolymer, the polymer is able to absorb more water.
另一亲水性添加剂的实施方案是聚甲基丙烯酸羟乙酯的使用。Another hydrophilic additive embodiment is the use of polyhydroxyethylmethacrylate.
在又一实施方案中,至少一种其它合成材料包括抗静电添加剂。结果是,在运动场上运动时产生的任何静电都能够被释放。通常,用于许多人造草坪运动场的纤维间的分散材料在运动中产生静电,并结果在运动场中向上迁移。因此,所述粒状分散材料能够扩散在整个空气中,这在运动中是令人不愉快的。In yet another embodiment, at least one other synthetic material includes an antistatic additive. The result is that any static electricity built up while playing on the playing field is able to be discharged. Typically, the inter-fiber dispersion material used in many artificial turf sports fields generates static electricity during play and consequently migrates up the field. Thus, the granular dispersion material can spread throughout the air, which is unpleasant in motion.
另外,抗静电添加剂确保不会通过运动者发生静电释放。Plus, antistatic additives ensure that no static discharges can occur through the athlete.
更特别地,抗静电添加剂(尤其是永久抗静电剂),可以是聚合物,如聚酰胺或聚醚嵌段酰胺。在另一实施方案中,所述添加剂是聚酯嵌段共聚物。More particularly, antistatic additives, especially permanent antistatic agents, may be polymers, such as polyamides or polyether block amides. In another embodiment, the additive is a polyester block copolymer.
附图说明 Description of drawings
下面将参照附图对本发明进行更加详细的解释,其中:The present invention will be explained in more detail below with reference to the accompanying drawings, wherein:
图1A-1D显示了根据本发明的合成纤维的不同实施方案;Figures 1A-1D show different embodiments of synthetic fibers according to the invention;
图2A和2B示例地显示了具有使用本发明方法制得的合成纤维的人造草坪运动场的一些实施方案。Figures 2A and 2B schematically show some embodiments of artificial turf sports fields having synthetic fibers made using the method of the present invention.
具体实施方式Detailed ways
纤维(10,20,30,40)由合成材料的薄片制得,所述薄片通过共挤出法获得,由至少两层不同的合成材料(11,12)组成,如图1A所示。与由均相合成材料混合物组成的现有的已知合成纤维相反,根据本发明的合成纤维(10,20,30,40)的层状结构能够使各层(该实施方案中的分层11和12)具有特定功能性质。结果是,在合成纤维的特定部位使用具有特定性能的合成材料避免或显著降低了该合成材料及其相关的特定功能性质在纤维中的其它部位存在的必要。The fibers (10, 20, 30, 40) are produced from sheets of synthetic material, obtained by coextrusion, consisting of at least two layers of different synthetic materials (11, 12), as shown in Figure 1A. Contrary to existing known synthetic fibers that consist of homogeneous synthetic material mixtures, the layered structure of the synthetic fibers (10, 20, 30, 40) according to the invention enables the individual layers (
例如,分层11可以使用合成材料,所述分层原则上赋予合成纤维以需要的机械强度(和硬度),尤其是不撕裂性,使得在所述人造草坪运动场上运动不会使用作人造草坪运动场的合成纤维撕裂。For example, a synthetic material can be used for the
在另一实施方案中,如图1B所示,合成纤维20由三层三种不同的以标号21、22、23表示的合成材料组成。中间层21由赋予纤维20以机械强度的廉价合成材料组成,而外层22和23可由不同的合成材料组成,各层都表现出不同的特定功能性质,该性质在合成纤维的外层表现最为突出,而不是在中间。In another embodiment, as shown in FIG. 1B , the
因此,外层21和22可具有弹性,例如与内层21相反,这为纤维提供了特定的硬度(抵抗断裂和撕裂),所述外层21或22的弹性对人造草坪运动场的运动性具有积极影响。Thus, the
在图1B所示的实施方案中,外层22和23可以由不同的合成材料组成,而图1C显示了外层32A和32B为由相同的合成材料组成的实施方案。In the embodiment shown in Figure IB,
图1D进一步显示了一种更为复杂的根据本发明的合成纤维的层状结构。通过不同合成材料的共挤出,制得了一种由中间芯层41组成并分别由不同类型的外层42A-42B或43A-43B包覆的层状合成纤维。Figure ID further shows a more complex layered structure of synthetic fibers according to the invention. By co-extrusion of different synthetic materials, a layered synthetic fiber is produced consisting of an
根据本发明的方法以及根据本发明制得的合成纤维的实质在于:与已知合成纤维相反,所述合成纤维不具有其中所有不同的合成材料及相关性质均匀结合在纤维中的均相结构。现有人造草坪运动场的均相结构或组成使得纤维的某些性质不如期望的显著,而其他性质却比期望的明显。The essence of the method according to the invention and of the synthetic fibers produced according to the invention is that, contrary to known synthetic fibers, they do not have a homogeneous structure in which all the different synthetic materials and related properties are homogeneously incorporated in the fibre. The homogeneous structure or composition of existing artificial turf sports fields renders some properties of the fibers less pronounced than desired, while others are more pronounced than desired.
使用本发明的方法可以获得基于特定配方的合成纤维,与标准化的纤维相反,该纤维在其某些部位表现出被认为是在其它部位不必要或不希望存在的特定功能性。Using the method of the invention it is possible to obtain synthetic fibers based on specific formulations which, in contrast to standardized fibers, exhibit in certain parts of them specific functionalities which are considered unnecessary or undesirable in other parts.
这使得能够更有效地使用各种(合成)材料,其不仅降低了成本,而且获得了一种更为通用的合成纤维,根据本发明,其比均相构造的已知纤维具有明显改进的运动和纤维性能。在该特定实施方案中,内层11、21、31和41由更为廉价的合成材料组成,其原则上赋予纤维以抵抗断裂或撕裂的特定强度。外层12、22、23、32A-32B、42A-42B和43A-43B由不必存在于纤维芯层的合成材料组成。This enables a more efficient use of various (synthetic) materials, which not only reduces costs, but also results in a more versatile synthetic fiber which, according to the invention, has a significantly improved movement than known fibers of homogeneous construction and fiber properties. In this particular embodiment, the
在本文中,一个特定实施方案是外层可由抗静电添加剂组成。抗静电添加剂抑制纤维通过由在人造草坪运动场上运动产生的静电而带电。反之,抗静电添加剂能够确保产生的静电由人造草坪运动场释放,并且,例如,不通过运动者释放(这将导致不愉快的经历)。In this context, a particular embodiment is that the outer layer may consist of antistatic additives. Antistatic additives inhibit fibers from being charged by static electricity generated by playing on artificial turf sports fields. Conversely, antistatic additives can ensure that static electricity generated is discharged by the artificial turf sports field and, for example, not by the player (which would lead to an unpleasant experience).
另外,在大多数人造草坪运动场中,由于产生静电的原因,所用粒状分散材料(通常由橡胶类材料组成)在人造草坪运动场中向上迁移,而且在运动场上运动的结果是使所述分散材料扩散在整个空气中。空气传播的粒状分散材料产生令运动者不安的影响。In addition, in most artificial turf sports fields, due to the generation of static electricity, the granular dispersion material used (usually composed of rubber-like materials) migrates upward in the artificial turf sports field, and the result of the movement on the sports field is to spread the dispersion material. in the whole air. Airborne granular and dispersed material can have unsettling effects on athletes.
抗静电剂尤其是永久抗静电剂可以是聚合物,例如聚酰胺或聚醚嵌段酰胺。在另一个实施方案中,该添加剂是聚酯嵌段共聚物。Antistatic agents, especially permanent antistatic agents, can be polymers, such as polyamides or polyether block amides. In another embodiment, the additive is a polyester block copolymer.
在另一个实施方案中,外层中的一层(或全部两个外层)(12、22-23、32a-32b、43a-43b)可包括亲水性添加剂。由此获得的人造草纤维具有能够从空气中吸湿(水),例如雨水的特定功能特性。这使得人造草坪运动场如天然草坪运动场一样更长时间地保湿,其对运动性能(尤其是当滑动等时)具有积极影响,同时在运动场上运动时,吸收的水分如在天然草坪上一样被释放。In another embodiment, one (or both) of the outer layers (12, 22-23, 32a-32b, 43a-43b) may include a hydrophilic additive. The artificial grass fibers thus obtained have specific functional properties of being able to absorb moisture (water) from the air, for example rainwater. This makes the artificial turf sports field moisturised for a longer period of time like a natural turf sports field, which has a positive effect on sports performance (especially when sliding, etc.), while at the same time when playing on the sports field, the absorbed moisture is released as on natural turf .
可以用作共挤出纤维的上层或外层(12、22-23、32a-32b、43a-43b)的亲水性添加剂的一个例子是乙烯-乙烯醇共聚物。依据共聚物中乙烯醇的含量,该共聚物可以吸收更多的水分。An example of a hydrophilic additive that can be used as the top or outer layer (12, 22-23, 32a-32b, 43a-43b) of the coextruded fiber is ethylene vinyl alcohol copolymer. Depending on the amount of vinyl alcohol in the copolymer, the copolymer can absorb more water.
在这种情况下,中间层(11、21、31、41)赋予纤维强度,而相对薄的上层(12、22-23、32a-32b、43a-43b)吸收水分。可以从空气(以雨水、雾等形式)中吸收水分或由有效的洒水装置提供水分。(通常,在人造草坪运动场上运动之前洒水。)In this case, the middle layer (11, 21, 31, 41) imparts strength to the fibres, while the relatively thin upper layer (12, 22-23, 32a-32b, 43a-43b) absorbs moisture. Moisture may be absorbed from the air (in the form of rain, fog, etc.) or provided by effective sprinklers. (Usually, sprinkle water before playing on artificial turf sports fields.)
在运动中,吸收的水分再次释放,这降低了例如滑动时受伤的风险。而且,吸收的水分使运动场的温度降低,由于人造草坪运动场能够被阳光加热,在不利条件下可高至70℃。During exercise, the absorbed moisture is released again, which reduces the risk of injury, for example when sliding. Moreover, the absorbed moisture lowers the temperature of the sports field, which can be as high as 70°C under adverse conditions, since the artificial turf sports field can be heated by sunlight.
用作外层(12、22-23、32a-32b、43a-43b)的亲水性添加剂的另一个实施方案是使用聚甲基丙烯酸羟乙酯。为了防止与中间层(11、21、31、41)的结合问题,需要五层共挤出结构,如图1D所示。在该情况下,层32a-42b是亲水层43a-43b与中间层41的结合层。Another embodiment for use as a hydrophilic additive for the outer layers (12, 22-23, 32a-32b, 43a-43b) is the use of polyhydroxyethylmethacrylate. To prevent bonding problems with the intermediate layers (11, 21, 31, 41), a five-layer coextruded structure is required, as shown in Figure 1D. In this case, the
为了说明的目的,所示人造草纤维的各层(如图1A-1D所示)具有不同的厚度。然而,所示厚度与所得人造草纤维的实际厚度不一致。For purposes of illustration, the various layers of artificial grass fibers (as shown in FIGS. 1A-1D ) are shown to have different thicknesses. However, the shown thickness does not correspond to the actual thickness of the obtained artificial grass fibers.
在图1D所示的实施方案中,结合层42a-42b比显示的薄很多,通常是总纤维厚度的1-5%,而其它层41-43a-43b相对较厚。如果将聚乙烯用作中间层11-21-31-41,则作为亲水性添加剂的乙烯-乙烯醇共聚物无须使用任何填充的结合层即可与中间层结合。In the embodiment shown in Figure ID, the bonding layers 42a-42b are much thinner than shown, typically 1-5% of the total fiber thickness, while the other layers 41-43a-43b are relatively thicker. If polyethylene is used as the intermediate layer 11-21-31-41, ethylene-vinyl alcohol copolymer as a hydrophilic additive can be bonded to the intermediate layer without using any filled bonding layer.
图2A和2B显示了几个人造草坪运动场的实施方案,其中使用了根据本发明的合成纤维。在这两个附图中,人造草坪运动场包括基底1,通过使用本发明方法获得的几种合成纤维2由例如簇生的方法附着在其上以标号3所示的位置。合成纤维2由合成材料层制得,所述合成材料由至少两种不同的合成材料通过共挤出的方法获得。合成纤维可单独、或作为例如缠在一起的纤维束2a-2c附着在基底上。更特别地,该通过共挤出制得的纤维可以是原纤维化的带状纤维。Figures 2A and 2B show several embodiments of artificial turf sports fields in which synthetic fibers according to the invention are used. In both figures, the artificial turf sports field comprises a substrate 1 to which several synthetic fibers 2 obtained by using the method according to the invention are attached at positions indicated by reference 3, for example by tufting. The synthetic fibers 2 are produced from layers of synthetic material obtained by coextrusion of at least two different synthetic materials. The synthetic fibers may be attached to the substrate individually, or as, for example, intertwined fiber bundles 2a-2c. More particularly, the fibers produced by coextrusion may be fibrillated ribbon-shaped fibers.
在另一个实施方案中,如图2B所示,根据本发明的合成纤维可以是单丝。在这种情况下,几根单丝可以缠绕成一束,之后,将每束附着于基底1上。在图2B中,基底具有开放结构并由支承纱线1a-1b的格栅组成,合成纤维2附着在该结构上。In another embodiment, as shown in Figure 2B, the synthetic fibers according to the present invention may be monofilaments. In this case, several monofilaments can be wound into a bundle, after which each bundle is attached to the substrate 1 . In Fig. 2B, the substrate has an open structure and consists of a grid of supporting yarns 1a-1b to which synthetic fibers 2 are attached.
Claims (26)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1026239 | 2004-05-19 | ||
| NL1026239A NL1026239C2 (en) | 2004-05-19 | 2004-05-19 | Method for manufacturing a plastic fiber for use in an artificial grass sports field as well as such a plastic fiber. |
| PCT/NL2005/000275 WO2005111281A1 (en) | 2004-05-19 | 2005-04-11 | Method for producing a synthetic fibre for use in an artificial grass sports field and such a synthetic fibre |
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| Publication Number | Publication Date |
|---|---|
| CN1961101A CN1961101A (en) | 2007-05-09 |
| CN1961101B true CN1961101B (en) | 2012-08-22 |
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| CN2005800179631A Expired - Lifetime CN1961101B (en) | 2004-05-19 | 2005-04-11 | Process for producing synthetic fibers suitable for artificial turf sports fields and such synthetic fibers |
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| US (1) | US20100040808A1 (en) |
| EP (1) | EP1747306B2 (en) |
| JP (1) | JP2007538183A (en) |
| KR (1) | KR20070035003A (en) |
| CN (1) | CN1961101B (en) |
| AU (1) | AU2005243347A1 (en) |
| EA (1) | EA008915B1 (en) |
| ES (1) | ES2608853T5 (en) |
| FI (1) | FI1747306T4 (en) |
| NL (1) | NL1026239C2 (en) |
| PT (1) | PT1747306T (en) |
| WO (1) | WO2005111281A1 (en) |
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| NL1026444C2 (en) * | 2004-06-17 | 2005-12-20 | Ten Cate Thiolon Bv | Artificial grass sports field provided with an infill material as well as such an infill material. |
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| NL1036418C2 (en) | 2009-01-14 | 2010-07-15 | Ten Cate Thiolon Bv | PLASTIC FIBER AND AN ARTIFICIAL GRASS FIELD WITH SUCH FIBER. |
| CN101476174B (en) * | 2009-01-20 | 2011-11-30 | 江苏共创人造草坪有限公司 | Enhanced artificial lawn fibre and preparation thereof |
| DE102009052848A1 (en) | 2009-11-11 | 2011-05-12 | Oerlikon Textile Gmbh & Co. Kg | Method for melt spinning monofilament optical fibers made from two different polymer melts, involves generating two different polymer melts by two separate extruders, and extruding polymer melts by spinning nozzle |
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| US10323361B1 (en) * | 2011-06-12 | 2019-06-18 | Dale Karmie | Synthetic turf system made with antistatic yarns and method of making |
| EP2726674B1 (en) * | 2011-07-01 | 2019-04-10 | Ten Cate Thiolon B.V. | Synthetic fibre and an artificial lawn comprising such a fibre |
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| EP3480361A1 (en) * | 2017-11-03 | 2019-05-08 | Polytex Sportbeläge Produktions-GmbH | Artificial turf fiber with a non-circular cladding |
| CN107988655B (en) * | 2017-12-29 | 2020-08-18 | 广州爱奇实业有限公司 | Grass silk fiber, preparation method thereof and simulated lawn prepared by adopting grass silk fiber |
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| Publication number | Publication date |
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| PT1747306T (en) | 2017-01-03 |
| EP1747306B1 (en) | 2016-09-28 |
| EP1747306B2 (en) | 2023-11-29 |
| KR20070035003A (en) | 2007-03-29 |
| NL1026239C2 (en) | 2005-11-22 |
| ES2608853T5 (en) | 2024-06-07 |
| JP2007538183A (en) | 2007-12-27 |
| AU2005243347A1 (en) | 2005-11-24 |
| WO2005111281A1 (en) | 2005-11-24 |
| US20100040808A1 (en) | 2010-02-18 |
| FI1747306T4 (en) | 2024-02-01 |
| EA008915B1 (en) | 2007-08-31 |
| ES2608853T3 (en) | 2017-04-17 |
| CN1961101A (en) | 2007-05-09 |
| EP1747306A1 (en) | 2007-01-31 |
| EA200602146A1 (en) | 2007-04-27 |
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