CN1377255A

CN1377255A - Personal care articles

Info

Publication number: CN1377255A
Application number: CN00813792A
Authority: CN
Inventors: N·J·菲利普斯; D·R·戴; M·P·罗伦茨
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd
Priority date: 1999-08-02
Filing date: 2000-08-01
Publication date: 2002-10-30
Also published as: WO2001008655A1; MXPA02001303A; EP1202707A1; BR0012924A; KR20020046278A; AU776419B2; JP2003505494A; CA2380089A1; KR100447278B1; AU6508700A; CZ2002272A3

Abstract

本发明涉及一种基本干燥的一次性个人清洁用品,其包括:a)水不溶性衬底,其包括:1)总刮擦覆盖率值约小于17%的柔软的第一层;和2)邻接该第一层放置的剥落第二层,其中该第二层的总刮擦覆盖率值是约17%至约70%;和b)邻接该第一层和第二层放置的清洁组分,其中,该组分包括水不溶性衬底重量的约10%至1000%的起泡表面活性剂。本发明还涉及一种适用于调理的基本干燥的一次性个人护理用品。我们发现这些用品对于个人清洁领域,即对皮肤和毛发的清洁是特别有用的。The present invention relates to a substantially dry, disposable personal cleansing product comprising: a) a water insoluble substrate comprising: 1) a soft first layer having a total scratch coverage value of less than about 17%; and 2) an adjoining an exfoliating second layer disposed on the first layer, wherein the total scratch coverage value of the second layer is from about 17% to about 70%; and b) a cleaning component disposed adjacent to the first layer and the second layer, Wherein, the component comprises from about 10% to 1000% by weight of the water-insoluble substrate of the lathering surfactant. The present invention also relates to a substantially dry disposable personal care product suitable for conditioning. We have found these articles to be particularly useful in the area of personal cleansing, ie cleansing of the skin and hair.

Description

Personal-care supplies

Technical field

The present invention relates to be used to clean and/or treat the disposable personal care articles for use at the position of skin, hair and this processing of any other needs.These articles for use comprise water-insoluble substrate and cleaning component treat useful component (therapeutic benefit component) or this cleaning component and the treatment useful component all have, wherein, the water-insoluble substrate comprise total scraping coverage value be less than about 17% softish ground floor and total scraping coverage value be about 17% to about 70% peel off (exfoliating) second layer in abutting connection with what this ground floor was placed; Cleaning component comprises about 10% to about 1000% lathering surfactant of water-insoluble substrate weight, treats about 10% to about 1000% the treatment beneficial agent that useful component comprises water-insoluble substrate weight.In addition, component or this back two kinds of components that these articles for use comprise water-insoluble substrate and cleaning component or have a therapeutic effect all have, wherein, the water-insoluble substrate comprise average surface depth value (AverageProfilometer Depth Value) be less than about 8 softish ground floor and average case depth value be about 8 to about 80 peel off the second layer in abutting connection with what this ground floor was placed; Cleaning component comprises about 10% to about 1000% lathering surfactant of water-insoluble substrate weight, treats about 10% to about 1000% the treatment beneficial agent that useful component comprises water-insoluble substrate weight.It is that water is clipped them after with its moistening and (for example: on position conditioning) will be cleaned and/or treat that consumer uses the method for these articles for use.

The invention still further relates to method with article cleaning of the present invention and/or conditioning skin and hair.

Background of invention

The personal care product, especially cleaning and conditioning products are sold on market with various forms such as soap, facial cream, skin care liquid and gel traditionally.The many standards that can be accepted by consumer are satisfied in the general attempt of these products.These standards comprise cleaning effectiveness, skin sense, to skin, hair and oculomucous gentle degree, and foam number.Ideal personal cleanser is cleaning skin or hair leniently, produces little stimulation or does not stimulate, and should not make when frequent use a large amount of deposition or over-drying is arranged on skin or the hair.

Also highly need such cleaning and conditioning component are discharged from disposable products.Disposable products are easily, are used to hold bottle, bar rod, jar, pipe and other form foreign material of heaviness that cleaning product and other can produce the product of treatment or aesthetic effect (or cosmetic result) because disposable products need not carry people or store.Disposable products still are the much cleaner succedaneum that sponge, cleaning cloth or other are prepared the cleaning appliance that re-uses for a long time because these utensils can cultures of bacteria breeding, generation make us uncomfortable abnormal smells from the patient and with reuse other relevant undesirable feature.

Articles for use of the present invention can clean effectively and/or treat skin and hair in mode convenient, cheap, health astoundingly.The present invention does not have and need carry, store or use independent utensil (for example: cleaning cloth or sponge), cleaning agent and/or have the convenience of the product of therapeutic effect.These articles for use are easy to use, because they are disposable personal care articles for use or a plurality of disposable nursing materialss that are used to clean with administering therapeutic or aesthstic agent.In addition, these articles for use are suitable for use in other personal care appliance that is designed to the longer-term use or with it and are used in combination.In this case, articles for use of the present invention place and do not prepare in disposable independent personal care appliance such as bath towel or the cleaning cloth or attached thereto.In addition, disposable product removeability of the present invention ground is attached to the handle or the lever that are used for moving these articles for use on the surface of will clean and/or treat (as: conditioning).

Although in some preferred embodiments, articles for use of the present invention are applicable to personal care field, but they can also be used for its surface or position and need clean or make various other industries of used additives such as wax, conditioner, ultraviolet agrochemical such as car care, the nursing of sea-freight vehicle, home care, animal care etc.

In the preferred embodiment of the invention, these articles for use are applicable to personal care field, also are applicable to skin, hair, and the similar keratin surface of cleaning requirement cleaning.It is that water is clipped them on the position that will clean after with its moistening that consumer uses the method for these articles for use.These articles for use are made of together water-insoluble substrate and cleaning component or component or this two kinds of components with therapeutic effect, wherein, the water-insoluble substrate has total scraping coverage value to be less than about 17% softish ground floor and total scraping coverage value is about 17% to about 70% the second layer that peels off; Contain lathering surfactant in the cleaning component, treat about 10% to about 1000% the therapeutic agent that useful component (component with therapeutic effect) comprises water-insoluble substrate weight.Do not wish fetter, can think that the substrate that has two structure sheafs at least can improve foaming characteristic, thereby can improve cleaning and spalling resistance, and can make the release of the treatment beneficial agent that may be included in these articles for use or aesthstic beneficial agent and deposit optimization by theoretical.In addition, can think that multiplet of the present invention considered that the various of user of all kinds skins need widely.

Summary of the invention

The present invention relates to a kind of disposable personal care articles for use that are applicable to the substantially dry of cleaning, these articles for use comprise:

A) a kind of water-insoluble substrate, it comprises:

1) always swipes coverage value (Total Scratch Coverage Value) approximately less than 17% softish ground floor; With

2) peel off (epidermis) second layer in abutting connection with what this ground floor was placed, wherein total scraping coverage value of this second layer is about 17% to about 70%; With

B) a kind of cleaning component of placing in abutting connection with this ground floor and the second layer, wherein, this cleaning component comprises about 10% to about 1000% lathering surfactant of water-insoluble substrate weight.

In another embodiment, the present invention relates to a kind of disposable personal care articles for use that are applicable to the substantially dry of cleaning, these articles for use comprise:

A) a kind of water-insoluble substrate, it comprises:

1) the average surface depth value is approximately less than 8 softish ground floor; With

2) peel off (epidermis) second layer in abutting connection with what this ground floor was placed, wherein, the average surface depth value of this second layer is about 8 to about 80; With

B) a kind of cleaning component of placing in abutting connection with this ground floor and the second layer, wherein, this component comprises about 10% to about 1000% lathering surfactant of water-insoluble substrate weight.

In another embodiment, the articles for use of the invention described above also comprise the useful component of treatment except cleaning component, or replace cleaning component with this component.

The invention still further relates to the method for a kind of cleaning and/or treatment skin and hair, it comprises the steps: a) with these articles for use of water-wet and b) articles for use after the moistening are contacted with skin or hair.

Unless otherwise indicated, all percents and the ratio used among the application all are benchmark with weight, and unless otherwise indicated, all measurements are all carried out under 25 ℃.The present invention can comprise the key component described in the application and composition and optional components and composition, or by these components with become to be grouped into, or substantially by these components with become to be grouped into.

In description of the present invention, various embodiments and/or feature are separately disclosed.All these embodiments and feature made up be possible and can obtain the preferred embodiment of the invention that this it will be apparent to those skilled in the art that.

All disclosures that comprise patent, patent application, public publication that are mentioned among the application are introduced reference of the present invention.

The accompanying drawing summary

Fig. 1 is used to illustrate the arrangement mode of the equipment of measuring total scraping coverage value.

Detailed Description Of The Invention

" disposable " of using among the application adopted its common meaning, and the meaning is just to throw away after limited number of time uses or discarded articles for use, and total access times preferably are less than 25 times, more preferably from about are less than 10 times, most preferably from about are less than 2 times.

The meaning of " substantially dry " that uses among the application is that the moisturizing degree of articles for use of the present invention is approximately less than 0.95gms, preferably approximately less than 0.75gms, more preferably from about less than 0.5gms, even more preferably from about less than 0.25gms, further more preferably from about less than 0.15gms, most preferably from about less than 0.1gms. The mensuration of moisturizing degree (Moisture Retention) is discussed later.

Personal-care supplies of the present invention comprise following solvent. The water-insoluble substrate

Articles for use of the present invention comprise water-soluble substrate, and this substrate at least also comprises two-layer. Preferably, the structure of these two substrate layers is different, and ground floor is gentleer to consumer's skin than peeling off the second layer in use. But, this two-layer preferably to skin be salubrious property with non-scouring. The meaning of " non-scouring (non-scouring) " that uses among the application is that this two-layer attrition value is approximately greater than 15, preferably approximately greater than 30, more preferably from about greater than 50, even more preferably from about greater than 70, most preferably from about greater than 80, attrition value is measured by following attrition value assay method. But under any circumstance, every layer all is defined as existing inner surface outer surface is arranged again. In both cases, every layer inner surface all is towards the inboard or the inner most surface of articles for use of the present invention, and every layer outer surface all is toward the outer side or the outermost surface of articles for use of the present invention. Generally speaking, the orientation of articles for use of the present invention can be defined as: no matter a side of the more close articles for use for grasping of which layer (namely, grasp side), and a side of the articles for use that the more close position with cleaning and/or treat of another layer contacts, as: skin/position contact side. But the both sides of articles for use all are fit to and skin contact.

Do not wish to be fettered by theoretical, this water-insoluble substrate can improve the effect of cleaning and/or treatment. Every layer of this substrate or the structure of every side are different, and therefore, in any once use, the grasping side of these articles for use is different from the structure of skin/position contact side. This substrate can be as effectively bubbling and peeling off utensil. By with the physical contact of skin or hair, this substrate can help to a great extent cleaning and remove dirt, cosmetics, dead skin and other chip. But in some preferred embodiments, this substrate is non-scouring or non-abrasiveness to skin. Ground floor and the second layer

Water-insoluble substrate of the present invention comprises that also total scraping coverage value is about 17% to about 70% the second layer that peels off less than about 17% ground floor and the coverage value of always swiping. This water not feature of property substrate is that also it has the average surface depth value is about 8 to about 80 the second layer that peels off approximately less than the ground floor of 8 softness and average case depth value. In both cases, all preferably bulk and fluid transmissibility of ground floor. The meaning of " bulk (lofty) " that uses among the application is that the density of this layer is about 0.00005g/cm³To about 0.1g/cm³, preferred about 0.001 g/cm³To about 0.09g/cm³，5gms/in ²Under thickness be about 0.04 inch to about 2 inches. This two-layer all being used for retrains cleaning component or be retained in the articles for use. In addition, ground floor all is fit to contact with hair with skin with the second layer. Have in the two-layer situation at articles for use, every one deck or each side of articles for use all can be used as different purposes because it has different physical properties. As following assay method was defined, ground floor was soft, and the second layer has and more takes off the epidermis performance. Therefore, the more sensitive user of skin understands preferred ground floor, and skin is more coarse and the not irritated user of friction is understood the preferred second layer (or side). The scraping amount of every square of scraping area on the scraping area that water-insoluble substrate layer of the present invention produces represents that with total scraping coverage value this value is measured with following method. Equally, the average surface depth value is the tolerance to the mean depth of the scratch on the scratch-off surface of water-insoluble substrate layer generation. This depth value is measured with the assay method that describes in detail below.

The method comprises with plant equipment and then to be determined at the scratch that produces on the test surfaces with different analytical methods along the test surfaces substrate that rubs. The assay method of total scraping coverage value and average case depth value

Total scraping coverage value of the ground floor of water-insoluble substrate is approximately less than 17%, preferably approximately less than 15%, more preferably from about less than 12%, most preferably from about less than 9%. The average surface depth value of ground floor is approximately less than 8, preferably approximately less than 7.75, more preferably from about less than 7.5, most preferably from about less than 7.

Total scraping coverage value of the second layer of water-insoluble substrate of the present invention is about 17% to about 70%, and preferred about 17% to about 27%, and more preferably from about 17% to about 25%, and most preferably from about 17 % are to about 23%. The average surface depth value about 8 of the second layer is to about 80, and preferred about 8 to about 50, and more preferably from about 8 to about 40, and further preferred about 8 to about 25, and most preferably from about 8 to about 15.

Because different structures is arranged is the key character of these articles for use to articles for use of the present invention, so the difference of total scraping coverage value of ground floor and the second layer is preferably about 8 to about 37, and more preferably from about 8 to about 27, and further preferred about 8 to about 25, most preferably from about 8 to about 21. Equally, the difference of the average surface depth value of ground floor and the second layer is about 2 to about 20, and more preferably from about 2 to about 15, and further preferred about 2 to about 12, most preferably from about 2 to about 8.

In order to measure total scraping coverage value and average case depth value, need following equipment.

1.Martindale toothbrush abrasion tester: 103 types, more than the series number 103-1386/2. The Martindale 07-01-88 that James H.Heal and Co.Ltd.Textile Testing and QC Equipment produce. Base area: 43 * 44mm. Heavy: 1kg.

2. perspex band 11 * 8cm (as: ICI acrylic acid) (be used for measure total scraping coverage value).

3. coating polystyrene band 11 * 8cm. Polystyrene in white high compression has transparent general purpose polystyrene layer, as: EMA type articles for use SS-20201L (being used for measuring the average surface depth value).

4. substrate to be measured.

5. the white reflection blocks (Kodak).

6. neutral density disk(-sc) (Kodak).

7. Proscan 1000 talysurves that have Proscan 1000 softwares.

Perspex/polystyrene band that preparation is used to swipe: remove plastic protective coating from the side that will swipe, clean with ethanol (without the yarn fabric).This band is placed on the non-abrasiveness surface, it is dried in air.Sideline along the Martindale abrasion tester is bonded at perspex/polystyrene band on the pedestal of testing machine with adhesive tape.Perspex/polystyrene band is arranged on the pedestal of testing machine, makes under its track that is in scraping equipment between two parties, the length of band is exactly the direction that equipment moves.The cutting 2.5 " * 2.5 " the square substrate sample.Square substrate is adhered on the scraping footing of Martindale abrasion tester with two-sided tape, with direct of travel be ranked substrate axially.Fit on this equipment with the screw that the provides sets of footings of to swipe.At the pouring weight of a 1kg of top assembly of scraping footing, guarantee that this scraping footing can only be mobile along a direction (forward or backward).Secure screen of cover on whole M artindale abrasion tester.Make of the speed running of this machine with 50 cycle per minute clocks.(frequency=0.833Hz).In case machine shuts down, take off the footing of assembly, upgrade perspex/polystyrene band from the pedestal of machine.This perspex/polystyrene band is labelled, represent that this is the used substrate of sampling, is stored in the plastic bag.

In order to measure total scraping coverage value, use following device analysis polymethyl methacrylate (perspex) band.

1. light-source box, " Landsco " low angle light source case (Britain supplier: Printing; Packaging Machinery Agency)

2. upright KP-M1 black-white CCD photographing unit

3. frame bin probe (Britain supplier: Synoptics Ltd).

4. image processing software (as: business software commonly used is available from Britain supplier Synoptics Ltd).

Fig. 1 has illustrated the arrangement mode in order to the equipment of analyzing band.Parallel rays is incided with the straight angle on the surface of this sample, and sample becomes 60 degree angles with horizontal line.The CCD photographing unit is the observation sample surface on the direction of 30 degree.These angles make from the light of the sample surfaces of having no time reflect to form " the dark picture " through photographing unit, and scratch can make the formation " bright image " that is reflected of some light on the direction of photographing unit.Therefore, the scratch surface of seeing is the face of arranging with the direction that becomes a special angle with the light of photographing unit.Therefore, the angle between change light, sample and the photographing unit can cause the difference of the definite outward appearance of sample.For this difference is minimized, use fixing blocky light-source box as reliably, image source (opposite) repeatably with flexible fiber optic conduit, specimen holder is made with rigid material.

For the measured value of having reported, observation condition is provided with as follows:

15 microns every of image resolution ratios

The ken 7.68 * 7.68mm

With image digitazation to 256 gray level that the frame bin generates photographing unit, setting image is 512 * 512 pixels.Measure total scraping area that the CCD photographing unit is surveyed, calculate total scraping coverage value, be expressed as the percent of viewing area.It calculates by following journey with scrub images.At first, relate to the observation blank sample, calibrate.With this basic reference as the material of not swiping.This blank is with reference to producing the 20-25lux light intensity, and this measures with camera gun (apart from the about 85mm of this sample).Observe white reflection card, its reflectance is known as about 90%.With this as white reference.This white is with reference to producing the 80-85lux light intensity, and this measures with camera gun (apart from the about 85mm of this sample).Before photographing unit, may need an additional neutral density disk(-sc) (0.2OD), to guarantee that this white colourity is in the brightness range of this photographing unit.

Then carrying out shadow correction/gray scale draws.All images are carried out this basic shadow correction algorithm with any to a great extent the difference of compensation light on sample.This is to adopt greater than the high pass filter of 128 * 128 pixels to realize.Repaint tonal range, make it reach its logarithm level, to produce the response linear more with brightness.This be by the gray value with all pixels carry out P ' (x, y)=(P (x, y)) conversion realizes that the P ' here refers to new images to 1n.

Next step carries out classification to gradation of image.Use the black/white parameter to the classification again of each image then, be classified into the tonal range of 0-255 again, making the black mean parameter is 0, and white mean parameter is 255.

For survey the scratch that substrate produces on band, (effective on 240 * 240 microns area) applies the definition that high pass filter can improve scratch on image with 16 * 16 nuclears.Be threshold value of each image setting then.This thresholding is defined as (brightness of image average) * 90%+ (brightness of image SD).The total brightness of image makes this thresholding produce skew, and to compensate a kind of like this phenomenon: scratch is many more, and image is bright more.Get rid of the interior characteristic point of a certain area less than 4 points.Get rid of circular feature point (in order to eliminate effect of dust).The circularity of particle is defined as (4 ^*π ^*Area)/(girth 2), its value is 0-1 (circle that 1=is complete).Get rid of circularities greater than 0.6 particle.Then that all are remaining characteristic point is defined as visible scratch.Calculate total scratch area then, be expressed as the percent of viewing area.This value is total scraping coverage value.

In order to measure the average surface depth value, p-poly-phenyl ethylene band is analyzed.This analysis comprises and adhering on the talysurf scraping the polystyrene band that nuzzles up (scraping is towards last) that it is centered close on (1,1) lattice, guarantees dull and stereotyped level.It is following value that sweep parameter is set, and begins scanning then.

Starting position 002.0mm * 003.0mm

0.010mm * 0.010mm goes forward one by one

Distance (pitch) 1000 * 1000 μ m

X-y resolution 10 μ m

With Proscan computed in software and record roughness value Ra, Rz and Rmax, wherein Ra: the arithmetic average deviation of profile estimated value.That is: the arithmetic mean of instantaneous value of vertical coordinate Z (x) absolute value in sample length.Ra=1/1 ∫ | Z (x) | dx (length 0 → 1 integration) Rz: for every kind of profile, estimated length is divided into five five equilibriums, calculates the maximum profile peak height value of every part and the summation of the dark value of maximum profile paddy.Rz is the meansigma methods of these five values.Rmax: the summation of the dark value of maximum profile peak height value in estimated length and maximum profile paddy.NB: carry out the scanning of 1cm * 1cm with 1000 profiles, NB is the Ra of each profile, the meansigma methods of Rz and Rmax value.Rz represents the average surface depth value of test substrate.

The assay method of attrition value

Attrition value is represented " the non-scouring " of the ground floor and the second layer of articles for use of the present invention.The aspect of articles for use of the present invention can leniently be stripped off epidermis but is not coarse to skin.Therefore, the assay method of attrition value comprises with plant equipment and to be determined at the scratch that produces on the test surfaces with different analytical methods then along the test surfaces substrate that rubs.

This assay method needs following equipment.

1, Martindale toothbrush abrasion tester: 103 types, more than the series number 103-1386/2.The Martindale 07-01-88 that James H.Heal and Co.Ltd.Textile Testing and QC Equipment produce.Base area: 43 * 44mm.Heavy: 1kg.

2, coating polystyrene band 11 * 8cm.Transparent general purpose polystyrene layer is arranged on the polystyrene of white high compression, as: EMA type articles for use SS-20201L.

3, substrate to be tested.

4, gloss meter is as Sheen Tri-Microgloss 20-60-85.

Next analyze band.This band is placed on the cartridge paper of black background, a substrate is analyzed 5 samples at least to obtain repeatably meansigma methods.Vertical placement gloss meter (so that light beam and cut meet at right angles) also makes the center scrape on the side of nuzzling up in the polystyrene band.Select 20 ° of angular surveying samples to obtain attrition value.When attrition value reduced, the scratch of substrate or scrubbing character improved.

The material that is suitable as the ground floor and the second layer is selected from cellulosic nonwoven fabric, non-bulk non-woven fabrics, sponge (that is: natural with synthetic), shaping membrane, cotton-wool and composition thereof.This is two-layer to preferably include the material of the laminate that is selected from cellulosic nonwoven fabric, non-bulk non-woven fabrics, shaping membrane, cotton-wool, foam plastics, sponge, net structure foam plastics, vacuum and forms, Si Kelinbu (scrim), polymeric network (polymeric fabrics) and composition thereof.More preferably be that nonwoven layers comprises the material that is selected from cellulosic nonwoven fabric, non-bulk non-woven fabrics, shaping membrane, cotton-wool and composition thereof.The meaning of used " non-woven fabrics " is that this layer do not comprise the fiber that is spun into fabric among the application, and this layer does not need to comprise fiber such as shaping membrane, sponge, foam, Si Kelinbu etc.When this layer comprises fiber, this fiber can be random (that is: can arrange arbitrarily) be again can combing (that is: can along a principal direction combing).In addition, this two-layer composite that can form by extra play such as random and laminate carded fibers.

In one embodiment, polymeric network is arranged in ground floor as bonding, laminating such as Hydroentangled by utilizing heating or chemical method.This arrangement has improved the globality of ground floor and whole articles for use, thereby has increased the hydrophilic of these articles for use.Can be used for polymeric network of the present invention (also being called " Si Kelinbu " among the application) and be described in detail in United States Patent (USP) 4,636, in 419, introduce this patent herein as a reference.This crin cloth material can directly form on extrusion die, or passes through fibrillation or embossing by extruded film, stretches then or divide to obtain.This this crin cloth can be derived from polyolefin such as polyethylene or polypropylene or its copolymer, polybutylene terephthalate (PBT), polyethylene terephthalate, nylon 6, nylon 66 etc.This crin cloth material can be bought from various commercial source.Be applicable to that preferred Si Kelin cloth material of the present invention is polypropylene Si Kelinbu, can available from Conwd Plastics (Minneapolis, MN).Another kind of preferred Si Kelin cloth material is polyethylene Si Kelinbu, especially low density polyethylene (LDPE), also can be available from Conwed.

In another aspect of this invention, the applicant also finds: this Si Kelin cloth material is added ground floor, and heating makes this thin slice have macroscopical three-dimensional feature then.We find that this macroscopical three-dimensional has greatly improved the cleaning action of these articles for use, even are also to be like this under the situation of homogeneous when the basic weight of this thin slice.Specifically, when this Si Kelinbu/fibrous composite heats postcooling, can obtain this macroscopical three-dimensional.This process makes Si Kelinbu shrink (on the x-y direction), and the result is that itself and fiber bond together, and makes this thin slice have bigger three-dimensional.The term of Shi Yonging " X-Y direction " refers to the vertical plane of thickness with layer, laminate or articles for use or its assembly herein.X and Y direction correspond respectively to the length and the width of thin slice or wafer assemblies usually.The term of Shi Yonging " Z direction " refers to length and the vertical direction of width with cleaned slice of the present invention or its assembly herein.The Z direction is usually corresponding to the thickness of thin slice.

The three-dimensional degree of adding is by contraction (as: heating) extent control of the mixture of Si Kelinbu/cleaning component.Fiber in this structure is a non-woven fabrics, and when particularly this structure was Hydroentangled formation, the inclusions of this Si Kelinbu was useful especially.It is 09/082 in the serial number of the common pending trial of 1998.5.20 application that the suitable Si Kelinbu that comprises non-woven fabrics is described in further detail people such as Fereshtehkho, 396 and 09/082, in 349 the U.S. Patent application, introducing these patent applications herein is for reference fully.

The ground floor and the second layer can comprise various natural and synthetic fibers or material.The meaning of " natural " of Shi Yonging is that this is material derived in the side-product of plant, animal, insecticide or plant, animal and insecticide herein.Traditional basic parent material normally comprises any common synthetic or natural weaving length fiber or the fleece of its mixture.

The indefiniteness example of natural material used in this invention comprises but is not defined as filamentary fibers, keratin fiber and cellulose fibre.The indefiniteness example of keratin fiber comprises the fiber that is selected from wool fiber, Pilus Cameli fiber etc.The indefiniteness example of cellulose fibre comprises those fibers that are selected from wood pulps fiber, cotton fiber, hemp, tossa, flax fiber and composition thereof.The present invention preferably uses cellulose fibre.

The indefiniteness example of available synthetic material in the present invention comprises those materials that are selected from acetate fiber, acrylic fiber, cellulose ester fiber, modacrylic fiber, Fypro, polyester fiber, polyolefine fiber, vinal, artificial silk, polyethylene (plastics), polyurethane foam (plastics) and composition thereof.The example of appropriate synthetic materials comprises acrylic resin such as Acrilan, Ke Lisi synthetic fibre, acrylonitrile group fiber, Orlon; Cellulose ester fiber such as cellulose acetate, A Nier and A Xier; Polyamide such as nylon (as: nylon 6, nylon 66, NYLON610 etc.); Polyester such as fortrel, Ke Daier, pet fiber, poly fiber, dacron; Polyolefin such as polypropylene, polyethylene; Poly-ethyl acetate fiber; Polyurethane foam (plastics) and composition thereof.By the general description of these and other suitable fiber of above-mentioned material preparation at Riedel, ＂ NonwovenBonding Methods and Materials, ＂ Nonwoven World (1987); TheEncyclopedia Americana, 11 volumes, 147-153 page or leaf and 26 volumes, 566-581 page or leaf (1984); 1990.1.2 be issued to people's such as Thaman United States Patent (USP) 4,891,227; With United States Patent (USP) 4,891,228, introducing above-mentioned document herein is for reference fully.

Preferred polyolefine fiber is to be selected from polyethylene, polypropylene, polybutene, polypenthylene and composition thereof and copolymer.Preferred polyolefine fiber is to be selected from polyethylene, polypropylene and composition thereof and copolymer.The preferred polyester fiber is to be selected from polyethylene terephthalate, polybutylene terephthalate, poly terephthalic acid cyclohexyl two methylene esters and composition thereof and copolymer.Preferred polyester fiber is to be selected from polyethylene terephthalate, polybutylene terephthalate and composition thereof and copolymer.The synthetic fibers of the most preferred ground floor and the second layer comprise the solid polyester short fiber that those comprise polyethylene terephthalate homopolymer.Appropriate synthetic materials can comprise the single composition of solid (that is: chemical homogenizing) fiber, constitute fiber more (that is: a more than class material make fiber), multicomponent fibre (that is: comprise the synthetic fibers of two or more different silk fibers, these fibers are intertwined to a certain extent and form bigger fiber), and composition thereof.Preferred fiber comprises bicomponent fibre, constitutes fiber and composition thereof more.This bicomponent fibre can be core-skin formula (core-sheath) structure or structure side by side.In both cases, the ground floor and the second layer can comprise and include the above mixture of enumerating the fiber of material, or self comprise the above fiber of enumerating mixtures of material.

For core-skin formula fiber, core preferably includes and is selected from its T _gAt least than the T of leather material _gThe material of polyester, polyolefin and mixture thereof that height is about 10 ℃.On the contrary, the skin of bicomponent fibre preferably includes and is selected from its T _gAt least than the T of core material _gLow about 10 ℃ polyolefin, its T _gAt least than the T of core material _gThe low about 10 ℃ polyester polyolefin and the material of mixture thereof.

No matter be that the fiber of the ground floor and the second layer can have helical form or spiral or wave structure, and is especially true for bicomponent fibre under the situation of structure, core-skin formula structure or solid one-component structure side by side.

The preferred synthetic material that is used for the ground floor and/or the second layer can comprise nylon fiber.Preferred synthetic material comprises the nylon fiber that constitutes the Si Kelin layer of cloth, makes the Si Kelin layer of cloth have bonding additional nylon fiber thereon, makes accessory fibers form circular arc on this Si Kelin layer of cloth.

The non-woven fabrics that natural material is made is made up of at net or thin slice that fine wire mesh forms on the net the fibrous suspension of liquid state usually.Referring to people such as C.A.Hampel, The Encyclopedia ofChemistry, the third edition, 1973,793-795 page or leaf (1973); The EncyclopediaAmericana, 21 volumes, 376-383 page or leaf (1984); G.A.Smook, Handbook of Pulpand Paper Technologies.Technical Association for the Pulp andPaper Industry (1986); The full content that is incorporated herein these documents as a reference.

The non-woven fabrics of natural material used in this invention can be available from various wide range of commercial source.Be applicable to that the indefiniteness example that is purchased ply of paper of the present invention comprises Airtex ^, this is a kind of cellulose layer with embossing air-laid of about 71gsy basic weight, available from James River, and Green Bay, WI; And Walkisoft ^, this is a kind of embossing air-laid cellulose layer of the 75gsy of having basic weight, available from Walkisoft U.S.A., and Mount Holly, NC.

Other suitable nonwoven cloth material comprises but is not defined as the United States Patent (USP) 4 that the material that is disclosed in the following patent: 1984.5.8 is issued to Osborn, 447,294,1986.7.29 be issued to the United States Patent (USP) 4 of Bjorkquist, 603,176,1991.1.1 be issued to the United States Patent (USP) 4 of Bjorkquist, 981,557,1992.2.4 be issued to the United States Patent (USP) 5 of Bjorkquist, 085,736,1992.8.8 be issued to the United States Patent (USP) 5 of Bjorkquist, 138,002,1993.11.16 be issued to people's such as Phan United States Patent (USP) 5,262,007,1993.11.23 be issued to people's such as Phan United States Patent (USP) 5,264,082,1987.1.20 be issued to the United States Patent (USP) 4 of Trokhan, 637,859,1985.7.16 be issued to the United States Patent (USP) 4,529 of Trokhan, 480,1987.8.18 be issued to the United States Patent (USP) 4 of McNeil, 687,153,1993.6.29 be issued to people's such as Phan United States Patent (USP) 5,223,096, be issued to people's such as Rasch United States Patent (USP) 5 with 1997.10.21,679,222, be incorporated herein these patent full contents as a reference.

The method of making non-woven fabrics is well known in the art.These non-woven fabrics generally can become net method, melt jet method by air lay method, current, established law, spun-bond process or carded method are made altogether.In these manufacture methods, at first from long fibre or filament, cut out fiber or the filament that needs length, it is fed in water or the air-flow, then this fiber or filament are deposited on the screen cloth, the current or the air communication that are loaded with fiber are crossed this screen cloth.No matter how are its manufacture method or composition, then this layer is carried out at least a bonding operation, make ultimate fibre be combined together to form self-holding net.In the present invention, the preparation nonwoven layers that can in all sorts of ways, these methods comprise but are not defined as the combination that air-flow sprays entwine (airentanglement) method, hydroentanglement processes (hydroentanglement), hot sticky connection and these methods.

Being applicable to can be available from various wide range of commercial source at the bottom of the non-woven lining that synthetic material of the present invention makes.Be applicable to that the suitable ground floor of the present invention and the indefiniteness example of second layer material comprise HEF 40-047, this is a kind of porous Hydroentangled material, contain about 50% artificial silk and 50% polyester, basic weight with about 61 grams every square metre (gsm), available from Veratec, Inc., Walpole, MA; HEF 140-102, this is a kind of porous Hydroentangled material, contains about 50% artificial silk and 50% polyester, has the basic weight of about 67gsm, available from Veratec, Inc., Walpole, MA; Novonet ^149-616, this is the latticed material of a kind of hot adhesion, contains about 100% polypropylene, has the basic weight of about 60gsm, available from Veratec, Inc., Walpole, MA; Novonet ^149-801, this is the latticed material of a kind of hot adhesion, contains about 69% artificial silk, about 25% polypropylene and about 6% cotton, has the basic weight of about 90gsm, available from Veratec, Inc., Walpole, MA; Novonet ^149-191, this is the latticed material of a kind of hot adhesion, contains about 69% artificial silk, about 25% polypropylene and about 6% cotton, has the basic weight of about 120gsm, available from Veratec, Inc., Walpole, MA; HEF Nubtex ^149-801, this is a kind of caking, the Hydroentangled material of porous, contains about 100% polyester, has the basic weight of about 84gsm, available from Veratec, Inc., Walpole, MA; Keybak ^951V, this is a kind of dry porous material, contains about 75% artificial silk and about 25% acrylic fibers, has the basic weight of about 51gsm, available from Chicopee, New Brunswick, NJ; Keybak ^1368, this is a kind of porous material, contains about 75% artificial silk and about 25% polyester, has the basic weight of about 47gsm, available from Chicopee, and New Brunswick, NJ; Duralace ^1236, this is the Hydroentangled material of a kind of porous, contains about 100% artificial silk, has the basic weight of about 48gsm to about 138gsm, available from Chicopee, and New Brunswick, NJ; Duralace ^5904, this is the Hydroentangled material of a kind of porous, contains about 100% polyester, has the basic weight of about 48gsm to about 138gsm, available from Chicopee, and New Brunswick, NJ; Chicopee ^5763, this is material (8 * 6 holes of per inch that a kind of carded waterpower punching forms, every centimetre of 3 * 2 holes), contain about 70% artificial silk, about 30% polyester and choose any one kind of them up to the emulsion binder (acrylate or EVA yl) of about 5% weight ratio, have the basic weight of about 60gsm to about 90gsm, available from Chicopee, New Brunswick, NJ; Chicopee ^9900 series are (as Chicopee ^9931,62gsm, 50/50 rayon/polyester; And Chicopee ^9950,50gsm, 50/50 rayon/polyester), this is the Hydroentangled material that forms of a kind of carded, contains a kind of fiber composition, and this fiber composition contains 50% artificial silk/50% polyester to 0% artificial silk/100% polyester or 100% artificial silk/0% polyester, this material has the basic weight of about 36gsm to about 84gsm, available from Chicopee, New Brunswick, NJ; Sontara ^8868, this is a kind of Hydroentangled material, contains about 50% cellulose and about 50% polyester, has the basic weight of about 72gsm, available from Dupont Chemical Corp.Preferred nonwoven interlining bottom material has the basic weight of about 24gsm to about 96gsm, more preferably has the basic weight of about 36gsm to about 84gsm, and most preferably from about 42gsm is to the basic weight of about 78gsm.

The ground floor and the second layer also can be the polymeric network sponges, and this is described among the disclosed european patent application 702550Al of 1996.3.27, is incorporated herein this patent full content as a reference.This polymeric network sponge comprises the multilayer layer plate, and this laminate is made by the addition polymer and the polycarboxylic polyamide of nylon or very softish polymer such as olefinic monomer.

The ground floor and the second layer also can comprise formed film and composite, promptly comprise the multilayer material of formed film.This formed film preferably includes the plastics soft to skin.Suitable soft plastics forming film comprises but is not defined as polyolefin such as low density polyethylene (LDPE) (LDPE).Comprise that in nonwoven layers under the situation of plastics forming film, this nonwoven layers is preferably porous,, make that this layer is fluid penetrable as macropore or micropore.In one embodiment, this nonwoven layers comprises only the plastics forming of micropore film.The textured surface of these micropores is that positive side (protruding side) is preferably placed on the inner surface of the second layer and preferably towards this substrate inboard, that is: towards cleaning component/the have component of therapeutic effect.Comprise that at some textured surface has in the embodiment in hole at petal-shaped edge, do not wish to be fettered by theoretical, can think when the textured surface in this hole towards the cleaning component that contains surfactant/when having the composition of therapeutic effect, the petal-shaped edge that hands makes this textured surface to this articles for use applied pressure is folding inwardly and produce many valves at the inner surface of this layer, the cleaning component that includes of these articles for use of throttling/have the component of therapeutic effect so effectively, thus the service life of these articles for use prolonged.

In another embodiment, the ground floor and/or the second layer comprise the eurypyloue again plastics forming film of existing micropore.In such embodiments, this two-layer being fit to very much, contact with the position that will clean and/or treat, because this microporous membrane has the same sensation of cloth.In such embodiments, the textured surface of this layer (being the ground floor and/or the second layer) micropore is towards the opposite of the textured surface of macropore.In this case, can think that the three-dimensional thickness that these macropores form by textured surface maximizes the total wettability/foaming characteristic of these articles for use, in the use of these articles for use, these textured surfaces are in constant compression and decompress down, thereby produce abundant foam.

Under any circumstance, comprise that the ground floor of formed film and/or the second layer preferably have at least about 100 hole/cm ²Substrate is more preferably at least about 500 hole/cm ²Substrate, even more preferably at least about 1000 hole/cm ²Substrate, most preferably this substrate is at least about 1500 holes/cm ²Substrate.The preferred embodiment of the present invention comprises that having discharge is about 5cm ³/ cm ²-s is to about 70cm ³/ cm ²-s, more preferably from about 10cm ³/ cm ²-s is to about 50cm ³/ cm ²-s, most preferably from about 15cm ³/ cm ²-s is to about 40cm ³/ cm ²The ground floor of-s and/or the second layer.

The suitable formed film of the ground floor used in this invention and/or the second layer and the composite that comprises formed film comprise but are not defined as the United States Patent (USP) 4 that the material that is disclosed in the following patent: 1982.8.3 is issued to people such as Radel, 342,314, the patent application of not aesthetic state jointly 08/326 of common transfer, 571 and 1995.6.12 application, 1996.1.11 disclosed PCT application US95/07435, be issued to people's such as Curro United States Patent (USP) 4 with 1986.12.16,629,643, introduce these patent full contents herein as a reference.In addition, the ground floor and/or the second layer can be the formed film composites that comprises at least a formed film and at least a nonwoven layers, and wherein, nonwoven layers is that vacuum forms.Suitable formed film composite comprises but is not defined as vacuum lamination combined shaping membrane material that this material is composited by carded polypropylene non-woven fabric and formed film with 30gsm basic weight.

In addition, the ground floor and the second layer preferably bond together mutually to keep the globality of these articles for use.This bonding can be by point bonding (as: focus bonding), continuous bonding (as: lamination etc.) or discontinuous mode, or in the outer side edges of this layer along (or on every side) and/or in the dispersed locations bonding or mix bonding and form.This bonding also can form geometry and pattern such as rhombus, circle, square etc. on the outer surface of these layers and gained articles for use.

Articles for use of the present invention also can be designed to ground floor and any extra play is modified to a composite bed with two sides different structure.Therefore, actually, this water-insoluble substrate can think comprise have the dual structure side or the surface a composite bed.

Under any circumstance, preferably, the bond area between the ground floor and the second layer is not more than the about 50% of these layers total surface area, preferably is not more than approximately 15%, more preferably no more than about 10%, most preferably from about is not more than 8%.

Discussed herein every layer comprises that at least two surfaces are inner surface and outer surface, and each surface has identical or different structure and abrasion resistance.Preferably, articles for use of the present invention comprise substrate and therefore soft to skin layer.But the substrate of different structure results from and uses different combinations of materials or use different production methods or the combination of the two.For example, can make the water-insoluble substrate of dual structure, so that a kind of personal-care supplies to be provided, these articles for use have the following advantages: have as exfoliative more wear-resistant surface with as the leniently cleaning and the softer absorbing surface of auxiliary treatment.In addition, each of this substrate layer energy is manufactured to go out different colors, thereby helps the user to distinguish these surfaces.

In addition, every layer of these articles for use and these articles for use itself can be made into different shape and profile, comprise plain cushion, hassock, thin slice, spherical apparatus and erose apparatus.The definite size of each layer depends on purposes and the characteristic that this articles for use need, its surface area size can be about one square inch to about hundreds of square inch.The shape of special layer easily and articles for use comprises but is not defined as square, circle, rectangle, hourglass shape, glove shape or ellipse that its surface area is about 5in ²To about 200in ², preferably about 6in ²To about 120in ², 15in more preferably from about ²To about 100in ², thickness is extremely about 50mm of about 0.5mm, and preferably about 1mm is to about 25mm, and most preferably from about 2mm is to about 20mm.Cleaning component

Articles for use of the present invention comprise cleaning component, and this cleaning component also comprises one or more surfactants.This cleaning component and this water-insoluble substrate are in abutting connection with placement.In certain embodiments, this cleaning component immerses this water-insoluble substrate.In another embodiment, this cleaning component deposits on one or two surface of this substrate.Articles for use of the present invention comprise this water-insoluble substrate weight about 10% to about 1000%, preferred about 50% to 600%, 100% to about 250% surfactant more preferably from about.In water-insoluble substrate weight, articles for use of the present invention also preferably include the surfactant at least about 1 gram.Therefore, this cleaning component does not need drying just can add in this substrate.

The surfactant of cleaning component is preferably lathering surfactant." lathering surfactant " of Shi Yonging refers to a kind of surfactant that can produce foam or soap foam when with water mixing and mechanical agitation herein.This surfactant of preferred use, because the foam that increases is represented cleaning effectiveness, this is important for consumers.In certain embodiments, surfactant or surfactant mixtures are gentle.The meaning of " gentleness " of Shi Yonging is that these surfactants and articles for use of the present invention can be compared with the promptly synthetic soap of the synthetic soap slab based on alkyl glyceryl ether sulfonate (AGS) of gentleness the gentle degree of skin herein.Gentle degree or opposite irritating method that measurement comprises the articles for use of surfactant are based on the impaired test of protective layer of skin.In this test, surfactant is gentle more, and protective layer of skin is impaired more little.With radiolabeled (the using tritiated) water that contains in the radiation chamber ( ³H-H ₂O) relative quantity that enters the physiological buffer district by skin surface from testing liquid is measured the extent of damage of protective layer of skin.This test is described in T.J.Franz in the J.Invest.Dermatol., 1975,64,190-195 page or leaf; Be issued to 1987.6.16 in people's such as Small the United States Patent (USP) 4,673,525, be incorporated herein these two document full contents as a reference.Also can use other is the method for known meter surface-active agent gentleness degree for those of ordinary skills.

Can test various surfactants among the present invention, comprise being selected from anion lathering surfactant, nonionic lathering surfactant, cation lathering surfactant, both sexes lathering surfactant and its mixture.

The anion lathering surfactant

The indefiniteness example that is applicable to the anion lathering surfactant in the compositions of the present invention is disclosed in the following document: McCutcheon ' s, " detergent and emulsifying agent " (Detergentsand Emulsifiers), North American edition (1986) is published by AlluredPublishing Corporation; McCutcheon ' s, " functional material " (Functional Materials) North American Edition (1992); Be issued to people's such as Laughlin United States Patent (USP) 3,929,678 with 1975.12.30, introduce these document full content references herein.

Various anion surfactants may all be applicable to the present invention.The indefiniteness example of anion lathering surfactant comprises those surfactants that are selected from following substances: alkyl and alkyl ether sulfate; sulphated monoglycerides; sulfonation alkene; alkylaryl sulfonate; uncle or secondary alkyl sulfonate; alkyl sulfosuccinate; acyl taurate; acyl isethinate; alkyl glyceryl ether sulfonate; sulfonated formate; alpha-sulfonated fatty acid; alkylphosphonate; acyl glutamate; acyl sarcosinates; alkyl sulfoacetate; acylated peptide; the alkyl ether carboxy acid salt; lactoyl salt in the acyl group; anion fluoro surfactants and its mixture.The mixture of anion surfactant can use in the present invention effectively.

The anion surfactant that is used in this cleaning component comprises alkyl and alkyl ether sulfate.These materials molecular formula separately is R ₁O-SO ₃M and R ₁(CH ₂H ₄O) _x-O-SO ₃M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl of non-side chain, x is 1-10, and M is water-soluble cationic such as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.Alkyl sulfate is generally with sulfur trioxide or other known vulcanization process sulfuration monohydric alcohol (having about 8 to about 24 carbon atoms) preparation.Alkyl ether sulfate generally is oxirane and monohydric alcohol (having about 8 to about 24 carbon atoms) condensation, and sulfuration prepares then.These alcohol can also can synthesize derived from fat as Oleum Cocois or Adeps Bovis seu Bubali.The object lesson that is used in the alkyl sulfate in the cleaning component is lauryl or the myristyl sulfate of sodium, ammonium, potassium, magnesium or TEA.The example of operable alkyl ether sulfate comprises lauryl ether-3-sulfate of ammonium, sodium, magnesium or TEA.

Another kind of suitable anion surfactant is a sulphated monoglycerides, and molecular formula is R ₁CO-O-CH ₂-C (OH) H-CH ₂-OSO ₃M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl of non-side chain, M is water-soluble cationic such as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.These surfactants generally are by making glycerol and fatty acid (having about 8 to about 24 carbon atoms) reaction generate monoglyceride, with sulfur trioxide its sulphation being prepared then.Example of Sulfated monoglyceride is a cocos nucifera oil monoglyceride sodium sulfate.

Other suitable anion surfactant comprises alkene sulfonate, and molecular formula is R ₁SO ₃M, wherein R ₁Be to have about 12 monoolefines to about 24 carbon atoms, M is water-soluble cationic such as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine cation.The preparation method of these chemical compounds is: with not compound SO 3 sulfonated alpha-olefin, and the mixture of neutralizing acid reaction then, neutral condition is to make all sultoness that generate in the reaction be hydrolyzed into corresponding hydroxy silane sulfonate.An example of sulfonation alkene is a C14/C16 alpha-olefin sodium sulfonate.

Other suitable anion surfactant is a linear alkylbenzene sulfonate (LAS), and molecular formula is R ₁-C ₆H ₄SO ₃M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl of non-side chain, M is water-soluble cationic such as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.The preparation method of these surfactants is: use SO 3 sulfonated LABS.This examples of anionic surfactants is a dodecylbenzene sodium sulfonate.

Other anion surfactant that is suitable for use in the cleaning component comprises uncle or secondary alkyl sulfonate, and molecular formula is R ₁SO ₃M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl of non-side chain, M is water-soluble cationic such as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine.These surfactants generate with sulfur trioxide or other known method of sulfonating sulfonated alkane normally under chlorine existence and ultraviolet radiation.The uncle position that this sulfonating reaction both can occur in alkyl chain also can occur in secondary position.The C13-C17 alkylsulfonate that an example that is applicable to alkylsulfonate of the present invention is alkali metal or ammonium.

Other suitable anion surfactant is an alkyl sulfosuccinate, comprise N-octadecyl sulfonation succinamide acid disodium, lauryl sulfosuccinate diammonium, N-(1,2-two carboxyethyls)-N-octadecyl sulfosuccinate four sodium, diamyl succinate sodium sulfonate, succinic acid dihexyl sodium sulfonate and aerosol OT.

Can also use the taurate based on taurine, taurine also is known as 2-aminoethyl sulfonic acid.The example of taurate comprises the N-alkyltaurate, and as the N-alkyltaurate with hydroxyethyl sulfonate and dodecyl amine prepared in reaction, this reaction is specified in United States Patent (USP) 2,658, in 072, introduces this patent herein as a reference.Other example based on taurine comprises the acyl taurine salt that n-N-methyltaurine and fatty acid (about 8 to about 24 carbon atoms) reaction generate.

The another kind of anion surfactant that is suitable for use in this cleaning component is an acyl isethinate.The molecular formula of this acyl isethinate is generally R ₁CO-O-CH ₂CH ₂SO ₃M, wherein R ₁For having an appointment 10 to saturated or unsaturated, the side chain of about 30 carbon atoms or the alkyl of non-side chain, M is a cation.These surfactants generally are by fatty acid (about 8 to 30 carbon atoms) and alkali-metal isethionic acid reactant salt are generated.The indefiniteness example of these acyl isethinates comprises cocoyl ethylenehydrinsulfonic acid ammonium, cocoyl ethylenehydrinsulfonic acid sodium, lauroyl hydroxyethyl sulfonate and its mixture.

Other suitable anion surfactant is an alkyl glyceryl ether sulfonate, and molecular formula is R ₁-OCH ₂-C (OH) H-CH ₂-SO ₃M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl of non-side chain, M is water-soluble cationic such as ammonium, sodium, potassium, magnesium, triethanolamine, diethanolamine and monoethanolamine cation.These surfactants are with aliphatic alcohol (about 8 to about 24 carbon atoms) and chloropropylene oxide and sodium sulfite reacts or other known method generates.An example is a coconut palm glycerin ether sodium sulfonate.

Other suitable anion surfactant comprises that molecular formula is R ₁-CH (SO ₄The alpha-sulfonated fatty acid of)-COOH and molecular formula are R ₁-CH (SO ₄)-CO-O-CH ₃Sulfonated formate, R wherein ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl of non-side chain.These surfactants are generally by generating with sulfur trioxide or other known method of sulfonating alpha-sulfonated fatty acid or alkyl methyl ester (about 8 to about 24 carbon atoms).Its example comprises α-sulfonation coco-nut oil fatty acid and dodecyl methyl ester.

Other anion surfactant comprises phosphate such as monoalkyl, dialkyl group and trialkyl phosphate, with phosphorus pentoxide with have about 8 and generate to the monobasic side chain of about 24 carbon atoms or the reaction of non-branched-chain alcohos.Also available other the known phosphorylation method of these surfactants generates.An example of this class surfactant is list or dilauryl sodium phosphate.

Other anion surfactant comprises acyl glutamate, and corresponding molecular formula is R ₁CO-N (COOH) CH ₂CH ₂-CO ₂M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl or alkenyl of non-side chain, M is a water-soluble cationic.Its indefiniteness example comprises sodium lauroyl glutamate and cocoyl sodium glutamate.

Other anion surfactant comprises the alkanoyl sarcosinate, and corresponding molecular formula is R ₁CON (CH ₃) CH ₂CH ₂-CO ₂M, wherein R ₁For having an appointment 10 to saturated or unsaturated, the side chain of about 20 carbon atoms or the alkyl or alkenyl of non-side chain, M is a water-soluble cationic.Its indefiniteness example comprises sodium lauroyl sarcosine, cocoyl sodium sarcosinate and Hamposyl L ammonium.

Other anion surfactant comprises the alkyl ether carboxy acid salt, and corresponding molecular formula is R ₁(OCH ₂CH ₂) _x-OCH ₂-CO ₂M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl or alkenyl of non-side chain, x is 1 to 10, and M is a water-soluble cationic.Its indefiniteness example is the lauryl ether carboxylic acid sodium.

Other anion surfactant comprises lactoyl salt (acyl lactylates) in the acyl group, and corresponding molecular formula is R ₁CO-[O-CH (CH ₃) CO] _x-CO ₂M, wherein R ₁For having an appointment 8 to saturated or unsaturated, the side chain of about 24 carbon atoms or the alkyl or alkenyl of non-side chain, x is 3, and M is a water-soluble cationic.Its indefiniteness example is a lactoyl sodium in the cocoyl acyl group.

Other anion surfactant comprises carboxylate, and its indefiniteness example comprises lauroyl carboxylic acid sodium, cocoyl carboxylic acid sodium and lauroyl carboxylic acid ammonium.Also can use the anion fluoro surfactants.

Other anion surfactant comprises the natural soap that plant and/or Animal fat or oily saponification are obtained.Its example comprises sodium laurate, Sodium myristate, sodium palmitate, sodium stearate, tallow fatty acid sodium, coconut oil sodium.

Any counter ion M can be used in this anion surfactant.Counter ion is preferably selected from those cationes of sodium, potassium, ammonium, monoethanolamine, diethanolamine and triethanolamine.This counter ion is more preferably ammonium.

The nonionic lathering surfactant

The indefiniteness example that can be used on the nonionic lathering surfactant in the compositions of the present invention is disclosed in McCutcheon ' s, " detergent and emulsifying agent ", North American edition (1986) is published by allured Publishing Corporation; And McCutcheon ' s, " functional material " is among the North American Edition (1992); Introduce these two pieces of documents herein as a reference.

The nonionic lathering surfactant of using among the application comprises those surfactants that are selected from alkyl androstanediol, alkyl polyglucoside, polyhydroxy fatty acid amide, alkoxyl fatty acid ester, sucrose ester, amine oxide and its mixture.

Alkyl androstanediol of Shi Yonging and alkyl polyglucoside herein, but generalized definition is long-chain alcohol such as the pure and mild sugar of C8-30, or starch, or the polymer of sugar or starch is the condensation product of glucoside or poly glucoside.The molecular formula of these chemical compounds is (S) _n-O-R, wherein S is sugar moieties such as glucose, fructose, mannose, galactose, and n is about 1 to about 1000 integer, and R is the C8-30 alkyl.Can comprise decanol, spermol, stearyl alcohol, lauryl alcohol, myristyl alcohol, oleyl alcohol etc. derived from the long-chain alcohol of this alkyl.The preferred example of these surfactants comprises that S is that glucose moiety, R are that C8-20 alkyl, n are those surfactants of about 1 to about 9 integer.The example of commercially available these surfactants comprises decyl poly glucoside (available from the APG 325CS of Henkel) and lauryl poly glucoside (available from APG 600CS and 625 CS of Henkel).Also can use sucrose ester surfactant such as sucrose cocos nucifera oil ester and sucrose lauryl.

Other useful ionic surfactant pack is drawn together polyhydroxy fatty acid amide surfactant, its more specifically example comprise glucamide, its corresponding structure formula is:

Wherein, R ¹Be H, C ₁-C ₄Alkyl, 2-hydroxyethyl, 2-hydroxypropyl, preferred C ₁-C ₄Alkyl, more preferably methyl or ethyl, most preferable; R ²Be C ₅-C ₃₁Alkyl or alkenyl, preferred C ₇-C ₁₉Alkyl or alkenyl, more preferably C ₉-C ₁₇Alkyl or alkenyl, more preferably C ₁₁-C ₁₅Alkyl or alkenyl; Z is the polyhydroxy alkyl part, and this alkyl is to have at least 3 hydroxyls directly to connect thereon straight-chain hydrocarbons, or its oxidation alkyl derivative (the preferred ethoxyquin or third oxidation).Z is preferably sugar moieties, is selected from glucose, fructose, maltose, lactose, galactose, mannose, xylose and composition thereof.Corresponding to a kind of particularly preferred surfactant of said structure is cocos nucifera oil alkyl N-methyl glucosamine amide (i.e. R wherein ²The CO-part is derived from fatty acid distribution of coconut oil).The method for preparing this polyhydroxy fatty acid amide component is disclosed in as in the following document: Thomas Hedley; Co., Ltd application, the disclosed british patent specification 809,060 of 1959.2.18; 1960.12.20 be issued to the United States Patent (USP) 2,965,576 of E.R.Wilson; 1995.3.8 be issued to the United States Patent (USP) 2,703,798 of A.M.Schwartz; 1934.12.25 be issued to the United States Patent (USP) 1,985,424 of Piggott, be incorporated herein above-mentioned document as a reference.

The example of other non-ionic surface active agent comprises amine oxide.The general formula of this amine oxide is R ₁R ₂R ₃N → O, wherein R ₁Contain alkyl, thiazolinyl or have an appointment 8 to about 18 carbon atoms, about 0 to about 10 ethylene oxide moieties, the about 0 monohydroxy alkyl to about 1 glyceryl part; R ₂And R ₃Comprise about 1 to about 3 carbon atoms and about 0 to about 1 hydroxyl, as methyl, ethyl, propyl group, ethoxy or hydroxypropyl.Arrow in this molecular formula is that the tradition of semi-polar bond is represented mode.The example that is suitable for use in the amine oxide among the present invention comprises dimethyl-dodecyl amine oxide, oil base two (2-ethoxy) amine oxide, dimethyl octyl group amine oxide, dimethyl decyl amine oxide, dimethyl myristyl amine oxide, 3,6,9-trioxa heptadecyl diethylamide oxide, two (2-ethoxy)-myristyl amine oxides, 2-dodecane oxygen ethyl dimethyl amine oxide, 3-dodecyloxy-2-hydroxypropyl two (3-hydroxypropyl) amine oxide, dimethyl cetyl amine oxide.

The indefiniteness example that is applicable to preferred surfactant of the present invention comprises and is selected from C8-C14 glucamide, C8-C14 alkyl polyglucoside, sucrose cocos nucifera oil ester, sucrose lauryl, dodecyl amine oxide, coco amine oxide and composition thereof.

The cation lathering surfactant

The cation lathering surfactant also can be used among the present invention.Suitable cation lathering surfactant comprises but is not defined as fatty amine, two fatty quaternary amines, three fatty quaternary amines, imidazoline quaternary amine and its mixture.Suitable fatty amine comprises monoalkyl quaternary amine such as cetrimonium bromide.Suitable quaternary amine is a dialkyl amide ethyl-hydroxyethyl sulphuric acid dimethylammonium.But preferred fat amine.When this cation lathering surfactant is the basic lathering surfactant of this cleaning component, preferably use suds booster.In addition, we find: non-ionic surface active agent mixes when using effective especially with this cation lathering surfactant.

The both sexes lathering surfactant

The term of Shi Yonging " both sexes lathering surfactant " also comprises zwitterionic surfactant herein, and its subclass as amphoteric surfactant is known for those of ordinary skills.

Various both sexes lathering surfactant all can be used in the compositions of the present invention.Useful especially those surfactants extensively are described as secondary aliphatic amine or tertiary amines derived thing, wherein, nitrogen preferably is in cation state, the fat base is the straight or branched group, wherein, a group in these groups contains ionizing water soluble group such as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.

The indefiniteness example that is used in the amphoteric surfactant in the compositions of the present invention is disclosed in McCutcheon ' s, and " detergent and emulsifying agent ", North American edition (1986) is published by allured Publishing Corporation; And McCutcheon ' s, " functional material " among the North American Edition (1992), is incorporated herein these two pieces of documents as a reference.

The indefiniteness example of both sexes or zwitterionic surfactant is those surfactants that are selected from betanin, sulfobetaines, hydroxy sulfo lycine, alkyl imines acetate, imino group dioxane carboxylate, amino alkane carboxylate and its mixture.

The example of betanin comprises the betanin than chain alkyl, as the coco dimethyl carboxymethyl betaine, the lauryl dimethyl carboxymethyl betaine, lauryl dimethyl α-carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, cetyl dimethyl betaine (can be purchased with Lonzaine 16SP) from Lonza Corp., two (2-ethoxy) carboxymethyl betaines of lauryl, oleyl dimethyl γ-carboxylic CAB, two (2-hydroxypropyl) α of lauryl-carboxyethyl betanin, the coco dimethyl azochlorosulfonate propyl lycine, lauryl dimethyl sulfoethyl betanin, lauryl is two-(2-ethoxy) azochlorosulfonate propyl lycine, amido betaine and amide sulfo betaine (RCONH (CH wherein ₂) ₃-be connected on the nitrogen-atoms of this betanin), oleyl betanin (can be purchased with amphoteric Velvetex OLB-50) from Henkel, and cocamido propyl betaine (can be purchased with Velvetex BK-35 and BA-35) from Henkel.

The example of sulfobetaines and hydroxy sulfo lycine comprises such as the betanin of cocamidopropyl propyl amide hydroxy sulfo lycine (can be purchased with Mirataine CBS from Rhone-Poulenc).

The amphoteric surfactant that the present invention preferably uses has following structural formula:

R wherein ¹Be 9 unsubstituted, saturated or undersaturated, the straight or branched alkyl of having an appointment, R to about 22 carbon atoms ¹Preferably have about 11 to about 18 carbon atoms, more preferably from about 12 to about 18 carbon atoms, and further preferred about 14 to about 18 carbon atoms; M is about 1 to about 3 integer, and preferred about 2 to about 3, is more preferably about 3; N is 0 or 1, preferred 1; R ²And R ³Be independently selected from 1 not replacement or the mono-substituted alkyl of hydroxyl of having an appointment, R to about 3 carbon atoms ²And R ³CH preferably ₃X is selected from CO ₂, SO ₃And SO ₄R ⁴Be selected from 1 not the replacing or the alkyl of mono-substituted saturated or unsaturated, the straight or branched of hydroxyl of having an appointment to about 5 carbon atoms.When X is CO ₂The time, R ⁴Preferably have an appointment 1 or 3 carbon atom, more preferably 1 carbon atom.When X is SO ₃Or SO ₄The time, R ⁴Preferably have an appointment 2 to 4 carbon atoms, more preferably 3 carbon atoms.

The example of amphoteric surfactant of the present invention comprises following chemical compound:

Cetyl dimethyl betaine (this chemical compound is also used CTFA called after cetyl betaine):

Cocamido propyl betaine

Wherein R has an appointment 9 to about 13 carbon atoms

The cocamidopropyl propyl amide hydroxy sulfo lycine

Wherein R has an appointment 9 to about 13 carbon atoms.

The example of the zwitterionic surfactant that other is useful is an alkyl imines acetate, imino group dioxane carboxylate and amino alkane carboxylate, and its molecular formula is RN[CH ₂] _mCO ₂M] ₂And RNH (CH ₂) _mCO ₂M, wherein m is 1 to 4, and R is the C8-C22 alkyl or alkenyl, and M is H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium.Also comprise imidazoline salt and ammonium derivative.The object lesson of suitable amphoteric surfactant comprises 3-dodecyl-alanine sodium, 3-dodecyl amino propane sulfonic acid sodium, N-is than the chain alkyl aspartic acid such as those are according to United States Patent (USP) 2,438, the material of 091 preparation is incorporated herein this patent as a reference; With with trade name " Miranol " product sold, it is described in United States Patent (USP) 2,528,378, is incorporated herein this patent as a reference.The example of the amphiprotic substance that other is useful comprises two acid phosphates, as cocamidopropyl propyl amide PG-phosphoric acid chlorination diammonium (can be purchased with Monaquat PTC from Mona Corp.).The both sexes acetate also is useful as glycerol-lauryl both sexes oxalic acid disodium, glycerol-lauryl both sexes sodium acetate and its mixture.

Preferred lathering surfactant is selected from the anion lathering surfactant, the nonionic lathering surfactant, cation lathering surfactant and both sexes lathering surfactant, wherein, the anion lathering surfactant is selected from the lauroyl sarcosine ammonium, the tridecyl ether sodium sulfate, sodium N-lauroyl sarcosinate, Zetesol AP, sodium laureth sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, cocoyl isethionic acid ammonium, the cocoyl hydroxyethyl sulfonate, the lauroyl hydroxyethyl sulfonate, cetyl sodium sulfate, single lauryl sodium phosphate, cocos nucifera oil glycerin ether sodium sulfonate, C9-C22 soap sodium and its mixture; The nonionic lathering surfactant is selected from lauryl amine oxide, coco amine oxide, decyl polydextrose, lauryl polydextrose, sucrose cocos nucifera oil acid esters, C12-14 glucose amide, sucrose lauryl and its mixture; The cation lathering surfactant is selected from fatty amine, two fatty quaternary amines, three fatty quaternary amines, imidazoline quaternary amine and its mixture; The both sexes lathering surfactant is selected from glycerol-lauryl both sexes oxalic acid disodium, glycerol-lauryl both sexes sodium acetate, cetyl dimethyl betaine, cocamidopropyl betaine, cocamidopropyl propyl amide hydroxy sulfo lycine and its mixture.Component (treating useful component) with therapeutic effect

In certain embodiments of the invention, these articles for use consist essentially of the component with therapeutic effect.This component is placed in abutting connection with the water-insoluble substrate, comprising water-insoluble substrate weight about 10% to about 1000%, more preferably from about 10% to about treatment beneficial agent of 500%, most preferably from about 10% to about 250%, the treatment beneficial agent is preferably selected from hydrophobic conditioner, hydrophilic conditioner, structure conditioner and its mixture.

Hydrophobic conditioner

Articles for use of the present invention can comprise one or more hydrophobic conditioners, and this hydrophobic conditioner produces conditioning effect to skin or hair in the use of articles for use.Articles for use of the present invention preferably include this water-insoluble substrate weight about 0.5% to about 1000%, more preferably from about 1% to about 200%, most preferably from about 10% to about 100% hydrophobic conditioner.

Hydrophobic conditioner can be selected from one or more weighted arithmetic mean solubility parameter values and be less than or equal to 10.5 hydrophobic conditioner.Can think mathematical definition based on this solubility parameter, if a kind of hydrophobic conditioner comprises that two or more chemical compounds and wherein a kind of solubility parameter were greater than 10.5 o'clock, obtain required weighted arithmetic mean solubility parameter, that is: it is possible being less than or equal to 10.5.

Solubility parameter is known for this area regular convention formula chemist, is commonly used to represent the compatibility and the dissolubility of various materials in the Recipe.

The solubility parameter δ of chemical compound is defined as the square root of this chemical compound cohesion energy density.In general, the solubility parameter of chemical compound is to calculate with the molal volume of each component of the tabular value of the additional group (additivegroup) that produces heat of vaporization and this chemical compound, and formula is:

δ = {[\frac{\underset{i}{Σ} E_{i}}{\underset{i}{Σ} m_{i}}]}^{1 / 2}

∑ wherein _iE _i=heat of vaporization that additional group produces and and

∑ _iM _i=the heat of vaporization of additional group generation molal volume and various atoms and atomic group that additional group produces and the standard scale train value of molal volume are collected in Barton, A.F.M. " solubility parameter handbook (Handbook of SolubilityParameters), CRC Press, the 6th chapter, table 3, in the 64-66 page or leaf (1985), introduce document content herein as a reference.Above solubility parameter formula is described in Fedors, R.F., estimate the method (＂ A Method for EstimatingBoth the Solubility Parameters and Molar Volumes of Liquids ＂) of solubility parameter and liquid molal volume, " Polym Eng Sci " (Polymer Engineering and Science), 14 volumes, 2 phases, in the 147-154 page or leaf (February 1974), introduce document content herein as a reference.

Solubility parameter is obeyed law of mixtures, and the solubility parameter value of mixture is weighted arithmetic mean (the being weighted average) value of the solubility parameter of every kind of composition of this mixture.Referring to chemistry and physics handbook (Handbook of Chemistry and Physics), the 57th edition, CRCPress, p.C-726 (1976-1977) introduces the document herein as a reference.

The prescription chemist is generally with (cal/cm ³) ^1/2Be unit report and use solubility parameter.The list value of the heat of vaporization that additional group produces " is being the unit report with kJ/mol in the solubility parameter handbook.But the list value of these heats of vaporization uses following known relational expression to be easy to be converted to cal/mol:

1J/mol=0.239006cal/mol and 1000J=1kJ is referring to Gordon, people such as A.J., The Chemist ' s Companion, John Wiley ﹠amp; Sons, the 456-463 page or leaf, (1972) introduce the document herein as a reference.

The solubility parameter value of various chemical substances is also tabulated.The list value of solubility parameter is referring to above-mentioned " solubility parameter handbook.Also can be referring to (the Solubility Effects In Product of the dissolubility effect in ＂ product, packing, infiltration and the preservation, Package, Penetration, And Preservation) ＂, C.D.Vaughan, Cosmetics andToiletries, 103 volumes, in October, 1988, the 47-69 page or leaf, introducing these documents herein is for reference fully.

The indefiniteness example of hydrophobic conditioner comprises and is selected from mineral oil, vaseline, lecithin, hydrolecithin, lanoline, lanolin derivative, the C7-C40 branched-chain hydrocarbons, the C1-C30 alcohol ester of C1-C30 carboxylic acid, the C1-C30 alcohol ester of C2-C30 dicarboxylic acids, the monoglyceride of C1-C30 carboxylic acid, two glyceride of C1-C30 carboxylic acid, the triglyceride of C1-C30 carboxylic acid, the ethylene glycol ester of C1-C30 carboxylic acid, the ethylene glycol diester of C1-C30 carboxylic acid, the propylene glycol monoester of C1-C30 carboxylic acid, the propylene glycol diesters of C1-C30 carboxylic acid, the polyester of C1-C30 dicarboxylic acid monoester and sugar, polydimethylsiloxane, poly-diaromatic siloxane, poly-alkaryl siloxanes, Cyclomethicone with 3 to 9 silicon atoms, vegetable oil, hydrogenated vegetable oil, polypropylene glycol C4-C20 alkyl ether, two C8-C30 alkyl ethers and its mixture.

The mineral oil that also is known as vaseline liquid is the mixture of the liquid hydrocarbon that obtained by oil.Referring to The Merck Index, the 10th edition (Tenth Edition), Entry 7048,1033 pages (1983) and " international cosmetic ingredient dictionary " (International CosmeticIngredient Dictionary), the 5th edition, 1 volume, 415-417 page or leaf (1993) is introduced these documents herein as a reference.

The vaseline that also is known as vaseline is the gluey system of non-straight chain solid hydrocarbons and high boiling point liquid hydrocarbon, accommodates the most liquid hydrocarbon in the micelle inside of this glue system.Referring to The MerckIndex, the 10th edition, 7047,1033 pages of Entry (1983); Schindler, Drug.Cosmet.Ind., 78-80,82 (1961); " international cosmetic ingredient dictionary ", the 5th edition, 1 volume, 537 pages (1993), introducing these documents herein is for reference fully.

Lecithin also can be used as hydrophobic conditioner.It is the natural mixture that is attached to the diglyceride of some fatty acid on the cholinester of phosphoric acid.

The 7 straight or branched hydrocarbon to about 40 carbon atoms of having an appointment can be used for the present invention.The indefiniteness example of these hydrocarbon materials comprises dodecane, Fancol ID, isotriacontane, cholesterol, Parleam, docosane (being the C22 hydrocarbon), hexadecane, 2-Methylpentadecane (Permethyl ^101A, by Presperse, the hydrocarbon that South Plainfield, NJ are purchased).The C7-C40 iso-paraffins also is useful, and it is the C7-C40 branched-chain hydrocarbons.Poly decene is a kind of side chain liquid hydrocarbon, also is useful in the present invention, can (Edison is NJ) with trade name Puresyn 100 from Mobile Chemical ^With Puresyn 3000 ^Be purchased.

The C1-C30 alcohol ester of C1-C30 carboxylic acid and C2-C30 dicarboxylic acids usefully also, it comprises straight chain and branched material and aromatic derivant.Also useful este is the monoglyceride as the C1-C30 carboxylic acid, two glyceride of C1-C30 carboxylic acid, the triglyceride of C1-C30 carboxylic acid, the ethylene glycol ester of C1-C30 carboxylic acid, the ethylene glycol ester of C1-C30 carboxylic acid, the ethylene glycol diester of C1-C30 carboxylic acid, the propylene glycol monoester of C1-C30 carboxylic acid and the propylene glycol diesters of C1-C30 carboxylic acid.In straight chain, side chain and aryl carboxylic acid are also included within.The also usefully propoxylation of these materials and ethoxylated derivative.Its indefiniteness example comprises the diisopropyl sebacate, diisopropyl adipate, isopropyl myristate, isopropyl palmitate, myristyl propionate, ethylene glycol bisthioglycolate stearic acid diester, 2-ethylhexyl cetylate, Dermol 105, two-2-ethylhexyl maleate, cetin, myristyl myristate, stearyl stearate, the stearic acid cetyl, behenic acid 20 diester, di-2-ethylhexyl maleate, di-n-octyl sebacate, diisopropyl adipate, the cetyl caprylate, the dilinoleic acid diisopropyl ester, the caprylic/capric triglyceride, PEG-6 caprylic/capric triglyceride, PEG-8 caprylic/capric triglyceride and its mixture.

Also usefully the C1-C30 monoesters of various sugar and polyester and related substances.These esters are derived from sugar or polyhydroxy part and a kind of or a plurality of carboxylic moiety.These esters at room temperature can be that liquid also can be solid, and this depends on the sour and sugared of these esters of formation.The example of liquid ester comprises: glucose four oleates, soya fatty acid (unsaturated) glucose tetra-ester, mixing soya beans fatty acid oil mannose four esters, galactose oleic acid four esters, Arabinose linoleic acid four esters, xylose four linoleates, galactose penta oleate, sorbose four oleates, unsaturated soya fatty acid sorbose six esters, xylitol penta oleate, sucrose four oleates, sucrose penta oleate, sucrose six oleates, sucrose seven oleates, sucrose eight oleates and its mixture.The example of solid ester comprises: sorbose six esters, and wherein the mol ratio of cetylate and arachidonate (arachidate) is 1: 2 in the carboxylate moiety; The Raffinose octaester, wherein the mol ratio of linoleate and mountain acid esters is 1: 3 in the carboxylate moiety; Maltose six esters, the mol ratio of Semen Helianthi fatty acid oil and tetracosanoic acid is 3: 4 in the wherein esterification carboxylic moiety; The mol ratio of oleic acid and mountain acid is 2: 6 in the sucrose octaester, wherein esterification carboxylic moiety; With the sucrose octaester, the mol ratio of lauric acid, linoleic acid and mountain acid is 1: 3: 4 in the wherein esterification carboxylic moiety.Preferred solid matter is a sucrose polyfatty acid esters, and wherein esterification degree is 7-8, wherein in the fatty acid part be C18 single-and/or the mol ratio of two-unsaturated acids and mountain acid be 1: 7 to 3: 5.Particularly preferred solid polyester is the sucrose octaester, wherein have an appointment in the molecule 7 mountain fatty acid parts and about 1 oleic acid part.Other material comprises Oleum Gossypii semen or sucrose soya fatty acid ester.This ester material further describes in following patent: 1977.1.25 is issued to the United States Patent (USP) 2,831,854 and 4,005,196 of Jandacek; 1977.1.25 be issued to the United States Patent (USP) 4,005,195 of Jandacek; 1994.4.26 be issued to people's such as Letton United States Patent (USP) 5,306,516; 1994.4.26 be issued to people's such as Letton United States Patent (USP) 5,306,515; 1994.4.26 be issued to people's such as Letton United States Patent (USP) 5,306,514; 1989.1.10 be issued to people's such as Jandacek United States Patent (USP) 4,797,300; 1976.6.15 be issued to people's such as Rizzi United States Patent (USP) 3,963,699; 1985.3.21 be issued to the United States Patent (USP) 4,518,772 of Volpenhein; 1985.3.21 be issued to the United States Patent (USP) 4,517,360 of Volpenhein; Introduce these patents herein as a reference.

Non-volatile polysiloxanes also is useful as polydialkysiloxane, poly-diaromatic siloxane and poly-alkaryl siloxanes.These polysiloxanes are disclosed in the United States Patent (USP) 5,069,897 that 1991.12.3 is issued to Orr, introduce this patent herein as a reference.Should the poly-corresponding chemical general formula of alkylsiloxane be R ₃SiO[R ₂SiO] _XSiR ₃, wherein R is that alkyl group (R is preferably methyl or ethyl, more preferably methyl), x are the integer up to about 500, selects the x value to obtain the molecular weight that needs.Commercially available poly-alkylsiloxane comprises that polydimethylsiloxane is known dimethicone, and its indefiniteness example comprises the Vicasil that is sold by General Electric Company ^Series material and the DowCorning that sells by Dow Corning Corporation ^200 series materials.The object lesson that is applicable to polydimethylsiloxane of the present invention comprises Dow Corning ^225 fluids, its viscosity are 10 centistokes, and boiling point is higher than 200 ℃; With Dow Corning ^200 fluid series, its viscosity are respectively 50,350 and 12500 centistokes, and boiling point is higher than 200 ℃.Also useful material such as trimethyl-methane siloxy esters of silicon acis, it is a polymer, corresponding chemical general formula is [(CH ₂) ₃SiO _1/2] _x[SiO ₂] _y, wherein x is about 1 to about 500 integer, y is about integer of 1 to 500.With Dow Corning ^The trimethyl-methane siloxy esters of silicon acis that 593 fluid merchants sell, it is the mixture that contains polydimethylsiloxane.Be applicable to the dimethiconol that also has of the present invention, it is hydroxy-end capped polydimethylsiloxane.These materials can be used chemical general formula R ₃SiO[R ₂SiO] _XSiR ₂OH and HOR ₂SiO[R ₂SiO] _XSiR ₂OH represents that wherein, R is alkyl (R is preferably methyl or ethyl, more preferably methyl), and x is the integer up to about 500, selects the x value to obtain the molecular weight that needs.The dimethiconol sold of merchant is generally sold (as Dow Coning with the mixture of itself and polydimethylsiloxane or cyclohexyl methyl siloxanes ^1401,1402 and 1403 fluids).Be applicable to the poly-alkaryl siloxanes that also has of the present invention, viscosity is about 15 PSIs to about 65 centistokes in the time of preferred 25 ℃.These materials are commercially available, as: the polyphenylene trimethicone fluid (Dow Corning Corporation sale) of SF1075 aminomethyl phenyl fluid (General Electric Company sale) and 556 cosmetics-stages.The alkylation polysiloxanes also is applicable to the present invention as poly-methyl decyl siloxanes and Methyl Octyl siloxanes, and these materials can be available from General Electric Company.Be applicable to also have alkyl-modified siloxanes such as alkyl methyl siloxanes and alkyl-dimethyl radical siloxane of the present invention, wherein this alkyl chain contains 10 to 50 carbon atoms.These siloxanes can trade mark ABIL WAX 9810 (C ₂₄-C ₂₈The alkyl methyl siloxanes) (Goldschmidt sale) and SF1632 (16-octadecyl methyl siloxanes) (General Electric Company sale) buy.

Vegetable oil and hydrogenated vegetable oil are also in the present invention available.The example of vegetable oil and hydrogenated vegetable oil comprises safflower oil, Oleum Ricini, Oleum Cocois, cotton seed oil, herring oil, palm-kernel oil, Petiolus Trachycarpi oil, Oleum Arachidis hypogaeae semen, soybean oil, rapeseed oil, Semen Lini oil, Testa oryzae oil, Oleum Pini, Oleum sesami, to seed oil of sunflower, the hydrogenation safflower oil, castor oil hydrogenated, hydrogenated coconut oil, the hydrogenation cotton seed oil, hydrogenation herring oil, hydrogenated palm kernel oil, hydrogenated palm oil, hydrogenated groundnut, oil with hydrogenated soybean, hydrogenated rapeseed oil, the hydrogenation Semen Lini oil, the hydrogenation Testa oryzae oil, the hydrogenation Oleum sesami, hydrogenation is to seed oil of sunflower and its mixture.

Also can use alkyl ether, the C1-C20 carboxylate of polypropylene glycol, two-C8-C30 alkyl ether of C4-C20 polypropylene glycol.The indefiniteness example of these materials comprises PPG-14 butyl ester, PPG-15 stearyl ether, dioctyl ether, dodecyl Octyl Ether and its mixture.

Hydrophobic chelating agen also can be used as hydrophobic conditioner in the present invention.Suitable reagent is described in the United States Patent (USP) 4,387,244 and the common unsettled U.S. Patent application 09/258,747 and 09/259,485 of 1999.2.26 with people's such as Schwartz name application that 1983.6.7 is issued to people such as Scanlon.

Hydrophilic conditioner

Articles for use of the present invention can randomly comprise one or more hydrophilic conditioners.The indefiniteness example of hydrophilic conditioner comprise those be selected from polyhydroxy-alcohol, polypropylene glycol, Polyethylene Glycol, urea, 2-pyrrolidone-5-carboxylic acid, ethoxylation and/or propoxylation C3-C6 two pure and mild triols, Alpha-hydroxy C2-C6 carboxylic acid, ethoxylation and/propoxylation sugar, acrylic copolymer, sugar up to about 12 carbon atoms arranged, have up to about the sugar alcohol of 12 carbon atoms and those materials of its mixture.The object lesson of useful hydrophilic conditioner comprises as urea; Guanidine; Glycolic and glycolic hydrochlorate (as ammonium and alkyl quaternary ammonium salts); Lactic acid and lactate (as ammonium and alkyl quaternary ammonium salts); Sucrose, fructose, glucose, erythrose (eruthrose), erithritol, Sorbitol, mannitol, glycerol, hexanetriol, propylene glycol, butanediol, hexanediol etc.; Polyethylene Glycol such as PEG-2, PEG-3, PEG-30, PEG-50, polypropylene glycol such as PPG-9, PPG-12, PPG-15, PPG-17, PPG-20, PPG-26, PPG-30, PPG-34; The alkoxylate glucose; Hyaluronic acid; Cation skin condition polymer (as quaternary ammonium polymer, for example polyquaternary ammonium salt polymer) and its mixture.Glycerol is particularly preferred hydrophilic conditioner in articles for use of the present invention.Also can use following substances: as various forms of Aloes (as the Aloe gel body), chitosan and chitosan derivatives such as chitosan lactate, lactamide monoethanolamine; Acetamide monoethanolamine and its mixture.Also can use propoxylated glycerol, as be described in the propoxylation glycerol in the United States Patent (USP) 4,976,953 that 1990.12.11 is issued to people such as Orr, introduce this patent herein as a reference.

Component with therapeutic effect can be made into various forms.In one embodiment of the invention, the component with therapeutic effect is an emulsion form.For example, oil-in-water, Water-In-Oil, W/O/W and polysiloxanes bag O/w emulsion are applicable to the present invention.In the application's emulsion, " water " not only refers to water but also refers to water miscible or miscible reagent such as glycerol.

The component that preferably has therapeutic effect comprises emulsion, and emulsion also comprises water and oil phase.This point is understandable to those skilled in the art, and a kind of component can be divided into water or oil phase substantially, and this depends on the water-soluble/dispersibility of the treatment beneficial agent in the component.In one embodiment, oil phase comprises one or more hydrophobic conditioners.In another embodiment, water comprises one or more hydrophilic conditioners.

The component with therapeutic effect of emulsion form of the present invention generally contains water and oil phase or fat mutually.Suitable oil or fat can be natural or synthetic (promptly synthetical) derived from animal, plant or oil.The hydrophobic in the above conditioner part of these oil has been done discussion.Suitable water component comprises hydrophilic conditioner discussed above.The preferred emulsions form comprises water-in-oil emulsion, polysiloxanes bag aqueous emulsion and other reversed-phase emulsion.In addition, preferred emulsion also contains just like the hydrophilic conditioner of glycerol to form oil bag glycerol emulsion.

The component with therapeutic effect of emulsion form preferably also contain the component with therapeutic effect weight about 1% to about 10%, preferred about 2% to about 5% emulsifying agent.Emulsifying agent can be nonionic, anion or cationic.Suitable emulsifying agent is disclosed in the United States Patent (USP) 3,755,560 that 1973.8.28 for example is issued to people such as Dickert; 1983.12.20 be issued to people's such as Dixon United States Patent (USP) 4,421,769; And McCutcheon ' s Detergents andEmulsifiers, North American Edition is in the 317-324 page or leaf (1986).Foam was minimized when the component with therapeutic effect of emulsion form also can contain defoamer and makes it be applied to skin.Defoamer comprises high-molecular weight polysiloxanes and other material well known in the art as this purposes.

Component with therapeutic effect can also be a microemulsion." microemulsion " of Shi Yonging refers to the mixture of two kinds of stable immiscible solvents of thermokinetics (a kind of is nonpolar, and another kind is polar) herein, and this mixture is stable by amphiphillic surfactant.Preferred microemulsion comprises water-in-oil microemulsion.

The structure conditioner

Component with therapeutic effect can comprise the structure conditioner.Suitable structure conditioner comprises but is not defined as loose structure agent such as ceramide, plasmalogen etc.

In another embodiment, the component with therapeutic effect that contains therapeutic agent is included in the compositions that forms coacervate.The compositions that forms coacervate preferably includes the carrier of acceptable this polymer of cationic polymer, anion surfactant and skin and surfactant.This cationic surfactant can be selected from nature bone frame QAS polymer, synthetic skeleton QAS polymer, natural skeleton amphiphilic polymers, synthetic skeleton amphiphilic polymers and its mixture.

More preferably be, cationic polymer is selected from natural skeleton QAS polymer, and natural skeleton QAS polymer is selected from polyquaternary ammonium salt-4, polyquaternary ammonium salt-10, polyquaternary ammonium salt-24, PG-hydroxyethyl-cellulose alkyl diammonium chloride, guar gum hydroxypropyl three ammonium chlorides, hydroxypropyl guar gum hydroxypropyl three ammonium chlorides and its mixture; Synthetic skeleton QAS polymer is selected from polyquaternary ammonium salt-2, polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, polyquaternary ammonium salt-11, polyquaternary ammonium salt-16, polyquaternary ammonium salt-17, polyquaternary ammonium salt-18, polyquaternary ammonium salt-28, polyquaternium-32, polyquaternary ammonium salt-37, polyquaternary ammonium salt-43, polyquaternary ammonium salt-44, polyquaternary ammonium salt-46, poly-formoxyl aminopropyl three ammonium chlorides, acrylamide propyl three ammonium chloride/acrylamide copolymers and its mixture; Natural skeleton amphiphilic polymers is selected from chitosan, quaternized protein, aminosal and its mixture; Synthetic skeleton amphiphilic polymers is selected from polyquaternary ammonium salt-22, polyquaternary ammonium salt-39, polyquaternary ammonium salt-47, adipic acid/dimethylamino hydroxypropyl divinyl triamine copolymer, polyvinylpyrrolidone/dimethyl aminoethyl methacrylic acid salt copolymer, caprolactam/polyvinylpyrrolidone/dimethyl aminoethyl methacrylic acid salt copolymer, caprolactam/polyvinylpyrrolidone/dimethylaminopropyl Methacrylamide terpolymer, polyvinylpyrrolidone/dimethylaminopropyl methacrylamide copolymer, polyamine and its mixture; Cationic polymer even be more preferably synthetic skeleton amphiphilic polymers.Cationic polymer even further polyamine more preferably.

When this cationic polymer was polyamine, the cationic polyamine polymer was preferably selected from polymine, polyvinylamine, polypropylene imines, polylysine and its mixture.Even more preferably be that this cationic polyamine polymer is a polymine.

At cationic polymer is in some embodiment of polyamine, and this polyamine can be hydrophobicity or hydrophilically modified polyamine.In this case, this cationic polyamine polymer is selected from henzylate polyamine, ethoxyquin polyamine, the third oxidation polyamine, alkyl polyamine, amidatioon polyamine, esterification polyamine and its mixture.The compositions of this formation coacervate comprise this formation coacervate compositions weight about 0.01% to about 20%, more preferably from about 0.05% to about 10%, most preferably from about this cationic polymer of 0.1% to about 5%.

Suitable anion surfactant comprises above-mentioned those materials relevant with " cleaning component ".Preferably, for this compositions that forms coacervate, anion surfactant is selected from sarcosinate, glutamate, Glu, alkyl sodium sulfate, alkylsurfuric acid ammonium, sodium alkylether sulphate, alkyl ether ammonium sulfate, the positive ammonium sulfate of lauryl ether, the positive sodium sulfate of lauryl ether, isethionate, glycerol ether sulfonate, sulfosuccinate and its mixture.More preferably be that this anion surfactant is selected from sodium N-lauroyl sarcosinate, lauroyl glutamate list sodium, alkyl sodium sulfate, alkylsurfuric acid ammonium, sodium alkylether sulphate, alkyl ether ammonium sulfate and its mixture.

The compositions of suitable formation coacervate further describes the U.S. Patent application of examining common 09/397,747 with people's such as Schwartz name application; U.S. Patent application 09/397,746 with people's such as Heinrich name application; U.S. Patent application 09/397,712 with people's such as Schwartz name application; In the U.S. Patent application 09/397,723 of name such as Heinrich application and the U.S. Patent application 09/397,722 with people's such as Venkitaraman name application, these patents are all applied at 1999.9.16.

The compositions of this formation coacervate also can comprise the carrier of acceptable this polymer of anionic polymer, cationic surfactant and skin and surfactant.Optional copolymer and other the natural or synthetic polymer (as polystyrene, polybutene, polyurethane etc.), natural natural gum and its mixture of deriving from acrylic acid polymer, polyacrylamide polymers, acrylic acid and acrylamide of this anionic polymer.Suitable natural gum comprises alginate esters (as propylene glycol alginate), pectin, chitosan (as the chitosan lactate) and modification natural gum (as starch matsutake alcohol succinate) and composition thereof.More preferably be that this anionic polymer is selected from acrylic acid polymer, polyacrylamide polymers, pectin, chitosan and its mixture.The preferred articles for use of the present invention comprise this formation coacervate composition weight about 0.01% to about 20%, more preferably from about 0.05% to about 10%, most preferably from about this anionic polymer of 0.1% to about 5%.Suitable anion surfactant comprises but is not defined as those materials discussed herein.

The component with therapeutic effect of these articles for use is fit to provide the effect of treatment or aesthstic skin or hair, and this reaches by conditioner and all ingredients are deposited on skin or the hair surface.All ingredients comprises but is not defined as acne active matter, crease-resistant active matter, antibacterial activity thing, antifungal actives, antiphlogistic activity thing, local anesthesia active matter, artificial suntan (tanningagent) and promoter, antiviral agent, enzyme, sunscreen actives thing, antioxidant, scurf cracking-off agent and its mixture.

It is to be further understood that: this component with therapeutic effect can be contained in the cleaning component of the present invention, and vice versa, makes its formation have the one-component that can't separate composition.The embodiment of a plurality of articles for use

Articles for use of the present invention can independent packaging or and other articles for use that can produce the effect that main articles for use institute can not produce pack together, as aesthetics, treatment, function or other effect, thus formation personal-care supplies bag.Additional articles for use in this personal belongings bag preferably include the water-insoluble substrate, this water-insoluble substrate comprises at least one deck and comprises the cleaning component of lathering surfactant or have the component of therapeutic effect, and this cleaning component or the component with therapeutic effect deposit on the substrate layer of these additional articles for use or immerse wherein.

Additional articles for use among the present invention except the treatment or aesthetic effect also can have functional effect or replace this treatment or aesthetic effect.For example, these additional articles for use can be used as drying appliance, with the auxiliary water of removing on skin behind shower or the dipping bath or the hair.

Surface saturation factor assay method

Comprise that the component with therapeutic effect in the articles for use of the present invention of the component with therapeutic effect is substantially on substrate surface.The meaning of " substantially on substrate surface " is surperficial saturation factor greater than about 1.25, be preferably greater than about 1.5, more preferably greater than about 2.0, even more preferably greater than about 2.25, most preferably greater than about 2.5.The surface saturation factor refers to the measured value ratio of the reagent on this substrate surface.Obtain these measured values by attenuated total reflectance (ATR) FT-IR spectrum.The those of ordinary skill that this spectrographic use is the analytical chemistry field is known.

Use conditioner and be not suitable for the object of the invention operation and/or product rheological method in many traditional methods employings of substrate.For example, this substrate net is immersed the fluid bath of conditioner is pushed this substrate net then with metering roll method, so-called " soaking crowded " method is used conditioner in entire substrate, therefore in use can not provide effectively to make compositions disengaging cloth transfer to another surperficial chance.And the conditioner that load is enough on the many articles for use employing substrates among the present invention requires the load factor of about 100-200% of this drying substrate weight usually to play effective effect on whole health.The personal care appliance of known these high capacities of employing can be by avoiding on the entire substrate that these loads is evenly distributed on comprise substrate interior because the aesthetic problem that high capacity produced substantially.The applicant surprisingly finds: the conditioner of high capacity in use can remain on this articles for use surface, therefore can advantageously provide and make reagent directly transfer to the chance on the surface of being treated from substrate, compositions of the present invention can produce the aesthetic effect of improvement simultaneously.

Obtain these measured values with following program:

Instrument configuration: with being positioned at Cambridge, the Bio Rad Labs of MA, the BioRad FTS-7 spectrometer collection infrared spectrum that DigitalLaboratory Division makes.Usually, these measured values are 4cm by resolution generally ^-1100 scanning elements form.The collection optical system is made of the ZnSe atr crystal of plane 60 degree, and this crystal is by being positioned at Fairfield, the Graseby Specac of CT, Inc. manufacturing.Data are collected down at 25 ℃, and with Grams 386 software analysis, this software is by being positioned at Salem, the GalacticIndustries Corp. distribution of NH..Before the measurement, this crystal is with suitable solvent clean.Sample is placed under the pouring weight that is placed on constant weight to 4 kilogram on the atr crystal.

Experimental procedure:

(1) spectrum of reference (background) structure cell of back air drying is cleaned in measurement.

(2) at first, select not have the substrate of beneficial agent, the substrate of selection comprises the outer surface of these articles for use.Substrate is placed in the atr crystal top, and outer surface is against on the crystal.At first this substrate is flat on the measuring table.Apply the pouring weight of 4kg then in this substrate top.Then, (it is 4cm that resolution is generally arranged to measure spectrum ^-1100 scanning elements).This substrate can be used as internal standard, because can demarcate the one absorbance of this substrate like this.Demarcate the main peak and the wave number of this substrate.

(3) to having applied the substrate of beneficial agent, repeat above-mentioned steps.Demarcate the peak height of main reagent, this peak height is the highest observation peak, and this peak or do not correspond to before observed substrate peak, or corresponding to observed substrate peak demonstrates existence owing to this conditioner and makes the maximum percent that absorbance increases.Write down the wave number and the absorbance at several reagent peak.

(4) from the spectrum of step 3 mensuration, select at the substrate peak of the wave number generation of step 2 mensuration, and this peak does not correspond to the main reagent peak that step 3 is selected.Wave number that record is selected from step 3 absorption spectrum and trap.

(5) ratio of the peak height of the substrate of the peak height of each reagent of calculation procedure 3 mensuration and step 4 mensuration.This greatest measure is represented the surperficial saturation factor of these articles for use.Contain some examples wherein in the following table:

Substrate ^*	Substrate peak and peak height	Conditioner	The conditioner peak height	Ratio
Substrate ^*	Substrate peak and peak height	Conditioner	The conditioner peak height	Ratio	Cotton-wool (polyester mixture of PET/PE binary composition fiber hot adhesion) with 70%	0.0865 (the C=O peak is at 1710cm ^-1)	(the C-O peak is at 1030cm for glycerol ^-1)	0.181	?2.09
Cotton-wool (polyester mixture of PET/PE binary composition fiber hot adhesion) with 70%	0.0865 (the C=O peak is at 1710cm ^-1)	(the C-H peak is at 2923cm for hydrocarbon ^-1)	0.160	?1.85		0.0865 (the C=O peak is at 1710cm ^-1)	(the C-O peak is at 1030cm for glycerol ^-1)	0.181	?2.09
	0.0865 (the C=O peak is at 1710cm ^-1)	(the C-H peak is at 2923cm for hydrocarbon ^-1)	0.160	?1.85	70% artificial silk/30 % polyester, Hydroentangled formation	0.0333 (the C=O peak is at 1710cm ^-1)	(the C-O peak is at 1030cm for glycerol ^-1)	0.0684	?2.05

^*The substrate of these kinds is easy to be purchased, for example can be from PGI Nonwovens, and Benson, NC are purchased degree of preserving moisture assay method

As mentioned above, articles for use of the present invention are thought substantially dry.The meaning of " substantially dry " of Shi Yonging is that the degree of preserving moisture of articles for use of the present invention is less than about 0.95gms herein, preferably, be more preferably less than about 0.5gms, even be more preferably less than about 0.25gms less than about 0.75gms, further preferably less than about 0.15gms, most preferably less than about 0.1gms.Dry sensation when degree of preserving moisture refers to that user contacts articles for use of the present invention, this sensation with " wetting " wiping is opposite.

In order to measure the degree of preserving moisture of the disposable product based on substrate of articles for use of the present invention and other, need following equipment and material.

Bandaid (Bonnty) blank sheet of paper towel	Procter ﹠ Gamble SKU 37,000 63037 basic weights=42.14gsm
Bandaid (Bonnty) blank sheet of paper towel	Procter ﹠ Gamble SKU 37,000 63037 basic weights=42.14gsm	Balance	Degree of accuracy is 0.0g
The Rec Mulberry	0.5 " thickness is even as big as covering sample fully, its heavy 1000g	Balance	Degree of accuracy is 0.0g
The Rec Mulberry		Pouring weight	Pouring weight of 2000g or amount to a plurality of pouring weights of heavy 2000g

Then, divide another name two pieces of paper towel and write down every napkin weight.A piece of paper towel is placed on the plane (as testing stand).Put the sample articles for use on this napkin.Another napkin is placed on these sample articles for use.Then, successively dish being restrained Mulberry and 2000g pouring weight places and is sandwiched on the intermediary sample articles for use.Wait for 1 minute.After 1 minute, remove pouring weight and Rec Mulberry.The napkin of weighing top and bottom also writes down weight.

For the napkin of top and bottom, all use final weight (after 1 minute) to deduct starting weight and calculate degree of preserving moisture.The weight difference of top and bottom napkin added and.If tested a plurality of articles for use, then the gross weight difference is averaged to obtain degree of preserving moisture.The embodiment of a plurality of chambers

Articles for use of the present invention also can comprise one or more chambers.These chambers or be to form closed area and produce at interval owing to these substrate layers link (as bonding) mutually at the diverse location place.These chambers are used for separating as the various components with articles for use, separate as the cleaning component and the conditioner that will contain surfactant.Various components with separation articles for use of treatment or aesthetics or cleaning effect can discharge from chamber in every way, these delivery modes comprise but be not defined as chamber dissolving, emulsifying, mechanical transfer, pierce through, substrate layer strip off that spalling, explosion, extrusion maybe will constitute this chamber part.Optional components

Articles for use of the present invention can comprise various other components, for example are used in the component in those products of known type traditionally, as long as they are acceptables to the change of effect of the present invention.These optional components should be applicable to people's skin and hair, that is: when these components join in the articles for use of the present invention, they are suitable for the contact skin with the people, and not having uncomfortable toxicity, incompatibility, unstability, allergy etc., these reactions should be in rational medical science or pharmacists's determination range.The CTFA Cosmetic Ingredient Handbook has described the cosmetics that are generally used for the skin nursing industry and the pharmacy composition of various indefinitenesses in the 2nd edition (1992), these compositions are applicable to articles for use of the present invention.The example of these compositions comprises enzyme, grinding agent, peel off the bits agent, absorbent, aesthstic composition such as spice, pigment, color agent/coloring agent, quintessence oil, the skin sensitizer, astringents etc. are as (Oleum Caryophylli, menthol, Camphora, Oleum Eucalypti, acetaminol, menthyl lactate, the Radix Hamamelidis Mollis distillation), go the acne agent (as resorcinol, sulfur, salicylic acid, erythromycin, zinc etc.), anti-caking agent, defoamer, additional antibacterial (as iodo propyl group butyl carbamate), antioxidant, binding agent, bio-additive, buffer agent, filler, chelating agen, chemical addition agent, coloring agent, aesthstic astringent, aesthstic antibacterial, denaturant, the medicine astringent, external-use analgesic, as the auxiliary film property of compositions and film former or the material such as the polymer (as the copolymer of eicosylene and vinylpyrrolidone) of affinity of increasing, wetting agent, opacifier, P ^HRegulator, propellant, Reducing agent, the multivalence compounding ingredient, Porcelana Skin Bleaching Agent Porcelana (or skin lightening agent) is (as hydroquinone, kojic acid, vitamin C, the phosphoric acid Magnesium ascorbate, the ascorbic acid glucamine), skin skin moistening and/or consolidant are (as panthenol and derivant (as the ethyl panthenol), Aloe, pantothenic acid and its derivant, allantoin, bisabolol and glycyrrhizic acid dipotassium), skin treatment agent comprises prevention, delay, reagent that the inhibition wrinkle of skin forms and/or wrinkle removing agent are (as 'alpha '-hydroxy acids, for example lactic acid and glycol acid and beta-hydroxy acid, for example salicylic acid), thickening agent, hydrocolloid, specific zeolite and vitamin and its derivant are (as vitamin E, the vitamin E acetate ester, beta-carotene, retinoic acid, vitamin A, biostearin, the Palimitate-A ester, nicotinic acid, nicotiamide etc.).Articles for use of the present invention can comprise carrier component well known in the art.These carriers can comprise one or more compatible liquid or solid filler or vehicles that are suitable for skin or hair.

Articles for use of the present invention can randomly comprise one or more such optional components.Preferred articles for use randomly comprise the component with therapeutic effect that contains therapeutic agent of safety and effective dose, and this therapeutic agent is selected from element-vitamine compound, skin treatment agent, removes the acne active matter, crease-resistant active matter, anti-skin atrophy actives, antiphlogistic activity thing, local anesthesia thing, artificial suntan and promoter, antibacterial activity thing, antifungal actives, sunscreen actives thing, antioxidant, exfoliant and its mixture.The meaning of " safety and the effective dose " of Shi Yonging is that the amount of chemical compound or component is enough to produce positive role or effect herein, but low to being enough to avoid producing serious adverse (as unsuitable toxicity or allergy) the i.e. rational terrible ratio of generation in rational medical judgment scope.

Be applicable to that optional components of the present invention can be according to the binding mode classification of their treatments or aesthetic effect or setting.Yet, should be understood that: be applicable to optional components of the present invention in some cases, can produce not only a kind of treatment or aesthetic effect or effect by more than one binding mode.Therefore, it is for convenience that the present invention classifies, rather than wants component is limited to certain application-specific or a plurality of application of enumerating.When using these optional components, the salt of pharmaceutically acceptable these components also is applicable to the present invention.

Element-vitamine compound

Articles for use of the present invention can comprise element-vitamine compound, its precursor and derivant.These element-vitamine compounds both can be natural also can be synthetic.The suitable vitamins chemical compound comprises but is not defined as vitamin A (as: beta-carotene, retinoic acid, vitamin A, biostearin, Palimitate-A ester, vitamin A propionate ester etc.), vitamin B (as: nicotinic acid, nicotiamide, vitamin B ₂, pantothenic acid etc.), vitamin C (as: ascorbic acid etc.), vitamin D (as: ergosterol, vitamin D ₂, vitamin D ₃Deng), vitamin E (as: vitamin E acetate ester etc.) and vitamin K (as: vitamin K ₁, vitamin K ₃, in conjunction with bacterium naphthoquinone etc.) chemical compound.

Specifically, articles for use of the present invention can comprise the vitamin B of safety and effective dose ₃Chemical compound.Vitamin B ₃For regulating skin is useful especially, this point is described in the common unsettled U.S. Patent application 08/834 of application on April 11st, 1997, among 010 (corresponding to disclosed International Application No. WO 97/39733 A1 on October 30th, 1997), introducing this application herein is for reference fully.Treatment component of the present invention preferably includes about 0.01% to about 50%, and more preferably from about 0.1% to about 10%, even more preferably from about 0.5% to about 10%, further more preferably from about 1% to about 5%, and 2% to 5% vitamin B most preferably from about ₃Chemical compound.

" the vitamin B of Shi Yonging herein ₃Chemical compound " chemical compound that refers to have following structural formula:

Wherein R is-CONH ₂(being nicotiamide) ,-COOH (being nicotinic acid) or-CH ₂OH (being nicotinyl alcohol), its derivant and any aforesaid salt.

Said vitamin B ₃The example of the derivant of chemical compound comprises nicotinate, and this ester comprises nicotinyl alcohol esters, nicotinic acid N-oxide and the nicotinoyl amine n-oxide that does not cause vasodilative nicotinate and the amino acid whose ester of cigarette base, carboxylic acid.

Suitable vitamins B ₃The example of chemical compound is being known in the art, can be from many sources such as the Sigma Chemical Company (St.Louis, MO), ICN Biomedicals, Inc. (Irvin, CA) and Aldrich Chemical Company (Milwaukee WI) is purchased.

These element-vitamine compounds can be included in the material of substantially pure, or are included in the extract that obtains by suitable physics and/or Chemical Decomposition method with natural origin (as plant).Skin treatment agent

Articles for use of the present invention can comprise one or more skin treatment agents.The suitable skin therapeutic agent comprises those therapeutic agents that can effectively prevent, delay, suppress wrinkle of skin formation and/or wrinkle removing.The example of suitable skin therapeutic agent comprises but is not defined as for example lactic acid and glycol acid and beta-hydroxy acid salicylic acid for example of 'alpha '-hydroxy acids.Go the acne agent

Be applicable to that the example that goes the acne agent in the articles for use of the present invention comprises keratolytic such as salicylic acid (oxybenzoic acid), salicylic derivant such as 5-MEXORYL SAM and resorcinol; Biostearin such as retinoic acid and derivant thereof (as: trans and cis); The D of sulfur-bearing and L aminoacid and derivant and salt, especially their N-acetyl derivative, its preferred example are N-acetyl group-L-cysteine; Thioctic acid; Antibiotic and antibacterial such as acyl peroxide, Piroctone Olamine, tetracycline, 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether, 3,4,4 '-neko, Azelaic Acid and its derivant, phenyl phenol, phenoxypropanol, phenoxy group isopropyl alcohol, ethyl acetate, clindamycin and meclocycline; Sebostats such as flavonoid; With bile salts such as scymnol sulfuric ester and its derivant, deoxycholate and cholate.Crease-resistant and anti-skin atrophy actives

Be applicable to that example crease-resistant and anti-skin atrophy actives of the present invention comprises retinoic acid and its derivant (as: trans and cis); Vitamin A; Davitin A; Nicotiamide; Salicylic acid and derivant thereof; The D of sulfur-bearing and L aminoacid and derivant and salt, N-acetyl derivative especially, its preferred example is N-acetyl group-L-cysteine; Mercaptan such as ethyl mercaptan; Hydroxy acid, phytic acid, thioctic acid; Lysophosphatidic acid and exfoliant (as phenol etc.).Non-steroidal anti-inflammatory active matter (NSAIDS)

The example that is applicable to the NSAIDS in the articles for use of the present invention comprises following substances: propanoic derivatives, acetogenin, sulfonyl amino acid (fenamic acid) derivant, diphenyl carboxylic acid derivates, oxicams.All these NSAIDS are described in detail in the United States Patent (USP) 4,985,459 that was issued to people such as Sunshine on January 15th, 1991, and introducing this patent herein is for reference fully.The example of useful NSAIDS comprises acetylsalicylic acid, ibuprofen, naproxen, benoxaprofen, flurbiprofen, fenoprofen, fenbufen, ketoprofen, indoprofen, pirprofen, carprofen, oxaprozin, pranoprofen, miroprofen, tioxaprofen, suprofen, alminoprofen, tiaprofenic acid, fluprofen and bucloxic acid.The useful steroid antibiotic medicine that also has comprises hydrocortisone etc.Local anesthetic

The example that is applicable to the local anesthetic in the articles for use of the present invention comprises benzocaine, lignocaine, fourth croak caine, chloroprocaine hydrochloride, dibucaine, clothing ferrum caine, all caines of phonetic piperazine, pantocaine, dyclonine, hexylcaine hydrochloride, procaine, cocaine, ketamine, pramoxine, phenol and its pharmaceutically acceptable salt.Artificial suntan and promoter

Be applicable to that the artificial suntan in the articles for use of the present invention and the example of promoter comprise dihydroxy acetone, tyrosine, tyrosine ester for example tyrosine ethyl ester and phosphate DOPA.Antibiotic and antifungal actives

The example that is applicable to the antibiotic and antifungal actives in the articles for use of the present invention comprises the beta-lactam medicine, quinolone medicine, cirramycin, norfloxacin, tetracycline, erythromycin, amikacin, 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether, 3,4,4 '-trichloro-symmetrical diphenyl urea (3,4,4 '-trichlorobanilide), phenyl phenol, phenoxypropanol, the phenoxy group isopropyl alcohol, doxycycline, cirramycin, chlohexidine, duomycin, oxytetracycline, clindamycin, ethambutol, own stilbamidine isethionate, metronidazole, penta amidine, gentamycin, kanamycin, lincomycin, methacycline, hexamethylenamine, minocycline, neomycin, netilmicin, paromomycin, streptomycin, tobramycin, miconazole (miconazole), the tetracycline hydrochloride, erythromycin, erythromycin zinc, erythromycin propionate lauryl sulfate, the erythromycin octadecanoate ester, amikacin sulfate, the doxycycline hydrochloride, the capreomycin sulfuric ester, the chlorhexidine gluconate ester, the chlohexidine hydrochloride, Chlortetracycline HCl salt, tetramycin hydrochloride, the clindamycin hydrochloride, the ethambutol hydrochloride, the metronidazole hydrochloride, penta amidine hydrochloride, the gentamycin sulfuric ester, the kanamycin sulfuric ester, the lincomycin hydrochloride, methacycline hydrochloride, hexamethylenamine hippuric acid ester, the hexamethylenamine mandelate, minocycline hydrochloride, the Tuttomycin ester, the netilmicin sulfuric ester, the paromomycin sulfuric ester, the streptomycin sulfuric ester, the tobramycin sulfuric ester, the miconazole hydrochlorate, amandin hydrochlorate (amanfadinehydrochloride), amandin sulfate (amanfadine sulfate), Octopirox, para-chlorometaxylenol, nystatin, tineatonsurans is moved back, 2-mercaptopyridine zinc oxide and clotrimazole.Anti-virus agent

Articles for use of the present invention can also comprise one or more Anti-virus agents.Suitable Anti-virus agent comprise but be not defined as slaine (as, silver nitrate, copper sulfate, iron chloride etc.) and organic acid (as, maleic acid, salicylic acid, succinic acid, benzoic acid etc.).In the special compositions that contains other suitable Anti-virus agent, include the not aesthetic jointly state patent application sequence 09/421084 people such as () Beerse of those Anti-virus agents that are described in the following patent application: 1999.10.19 application; 09/421131 (people such as Biedermann); 09/420646 (people such as Morgan); With 09/421179 (people such as Page).Enzyme

Articles for use of the present invention can randomly comprise one or more enzymes.Such enzyme is the acceptable enzyme of skin preferably.Suitable enzyme comprises but is not defined as keratinase, protease, amylase, subtilisin etc.The sunscreen actives thing

Can be used for the sunscreen actives thing that also has of the present invention.The United States Patent (USP) 5087445 that various sunscreen: 1992.2.11 is issued to people such as Haffey has been described in the following document; 1991.12.17 be issued to people's such as Turner United States Patent (USP) 5073372; 1991.12.17 be issued to people's such as Turner United States Patent (USP) 5073371; And people such as Segarin is at Chapter VIII, and 189 pages Cosmetics Science and Technology introduces these documents herein as a reference.The indefiniteness example that can be used on the sunscreen in the compositions of the present invention is selected from 2-ethylhexyl-p-methoxycinnamic acid ester; 2-ethylhexyl N; N-dimethyl-Para-Aminobenzoic ester, Para-Aminobenzoic, 2-Phenylbenzimidazole-5-sulfonic acid; octocrylene; the hydroxyl methoxy benzophenone, salicylic acid ester in the high Meng, ethylhexyl salicylate; 4; 4 '-methoxyl group-tert-butyl group dibenzoyl methane, 4-isopropyl diphenyl formoxyl methane, 3-benzylidene Camphora; 3-(4-methylbenzene methylene) Camphora; titanium dioxide, zinc oxide, silicon dioxide; ferrum oxide, and composition thereof.Other useful sunscreen is disclosed in 1990.6.26 and is issued to Sabatelli United States Patent (USP) 4937370; Be issued to 1991.3.12 in people's such as Sabatelli the United States Patent (USP) 4999186, introduce these two pieces of patents herein as a reference.The more preferred example of these sunscreen comprises that those are selected from 2; the 4-N of 4-dihydroxy benzenes ketone; N-(2-ethylhexyl) methylamino benzoate; the 4-N that has 4-hydroxy benzophenone acyl group methane; N-(2-ethylhexyl) methylamino benzoate; the 4-N of 2-hydroxyl-4-(2-hydroxyl-oxethyl) benzophenone; N-(2-ethylhexyl)-methylamino benzoate; the 4-N of 4-(2-hydroxyl-oxethyl) dibenzoyl methane; N-(2-ethylhexyl)-methylamino benzoate, and composition thereof material.The definite consumption of sunscreen changes according to selected sunscreen and the sun protection factor (SPF) that will reach.SPF is that typical sunscreens prevents that the photoprotection of erythema from measuring.Referring to the FederalRegister of 1978.8.25,43 volumes, 166 phases, the 38206-38269 page or leaf is introduced the document herein as a reference.Hydrocolloid

Can randomly comprise hydrocolloid in the articles for use of the present invention.

Hydrocolloid is being known in the art, and helps to prolong the service life of the surfactant that contains in the cleaning component of the present invention, makes these articles for use can use a shower or dipping bath at least.Suitable hydrocolloid comprises but is not defined as xanthan gum, carboxymethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, methyl and ethyl cellulose, natural gum, gudras guar gum, locust beam gum, native starch, deionization starch (as, starch succinic acid octene ester) etc.The heat release zeolite

Can randomly comprise zeolite and other chemical compound that exothermic reaction can take place when mixing with water in the articles for use of the present invention.Form the polymer gel agent of hydrogel

Articles for use of the present invention can randomly comprise aqueous gel, that is: " hydrogel " that is formed by polymer gel agent that forms hydrogel and water.When having aqueous gel, preferably include about 0.1% to about 100% of water-insoluble substrate weight in these articles for use, more preferably from about 3% to about 50%, the most preferably from about polymer gel agent of 5% to about 35% formation hydrogel, this dried basis weight amount that is based on the polymer gel agent that forms hydrogel is calculated.

In general, the polymer gel agent of formation hydrogel of the present invention is the partial cross-linked at least polymer by the monomer preparation that contains polymerisable unsaturated acids, this monomer be water miscible or hydrolysis after water miscible.It includes the mono-vinyl unsaturated compound of at least one hydrophilic radical, and this unsaturated compound comprises that (but not being defined as) contain the alkylene unsaturated acids and the anhydride of at least one C=C olefinic double bonds.As for these monomers, the water miscible meaning is that this monomer is soluble in 25 ℃ deionized water, and dissolubility is 0.2% at least, preferably is 1.0% at least.

During polymerization, above-mentioned monomeric unit generally accounts for about 25mol% to 99.99mol% of the polymer gel agent material (butt polymer weight) of acidiferous monomer, and preferably about 50mol% to 99.99mol% is most preferably at least about 75mol%.

The polymer gel agent of the formation hydrogel that the present invention uses is partial cross-linked gellant to sufficiently high degree, crosslinked degree preferably is high enough to the glass transition temperature (Tg) that makes the polymer that obtains and is not less than about 140 ℃, therefore, the used term " the polymer gel agent of formation hydrogel " of the application should be the polymer that can reach this parameter.The Tg that forms the polymer gel agent of hydrogel preferably is not less than about 180 ℃, more preferably is, this polymer did not have Tg before decomposing under about 370 ℃ or the higher temperature.Carry out differential scanning calorimetry (DSC) with the sample of 5mg or less amount with the firing rate of 20.0 ℃/min and can measure Tg.Tg is calculated as the starting point of the hot-fluid variation that transforms corresponding to glassy state and the midrange between the terminal point on DSC thermal capacity heating curves.Using DSC to measure Tg is being known in the art, be described in the ＂ Use of DSC To Obtain Accurate Thermodynamicand Kinetic Data ＂ of B.Casseland M.P.DiVito, U.S.'s laboratory (American Laboratory), in January, 1994, " heat is analyzed " (the Thermal Analysis) of 14-19 page or leaf and B.Wunderlich, Academic Press, Inc. is in 1990.

The polymer gel agent of formation hydrogel is characterised in that its high-absorbable and keeps the ability of moisture under its absorption or " gel " state.The every gram of polymer gel agent that the present invention preferably forms hydrogel can absorb the water (deionized water) at least about 40g, preferably at least about 60g/g, more preferably at least about 80g/g.Can these be called the value of " absorptive capacity " according to above-mentioned absorptive capacity " tea bag " determination of test procedure.

The polymer gel agent of formation hydrogel of the present invention generally is partial cross-linked at least.Suitable crosslinking agent is being known in the art, and comprises the chemical compound that at least two polymerizable double bonds are arranged as (1); (2) have at least one polymerizable double bond and at least one can with the chemical compound of the functional group of acidiferous monomer substance reaction; (3) have at least two can with the chemical compound of the functional group of acidiferous monomer substance reaction; (4) can form the polyvalent metal compounds of ion-type cross-bond.

Have the cross-linking agent of at least two polymerizable double bonds to comprise (i) two or polyvinyl compound such as divinylbenzene and divinyl toluene; (ii) have two or polyester of polyhydric unsaturated list or polycarboxylic acids such as two or triacrylate of polyhydric alcohol, polyhydric alcohol such as ethylene glycol, trimethylolpropane, glycerol, or polyoxyethylene glycol; (iii) two acrylic acid amides such as N,N methylene bis acrylamide; (iv) can be by the carbamyl ester that polyurethane and hydroxyl monomer reaction are obtained; (v) two of polyhydric alcohol or polyallyl ether; (vi) two of polycarboxylic acids or polyene propyl diester such as dially phthalate, diallyl adipate etc.; (vii) have the unsaturated list of monoene propyl diester of polyhydric alcohol or the acrylate of polycarboxylate such as Polyethylene Glycol mono allyl ether; (viii) two or triallylamine.

There are at least one polymerizable double bond and at least one to comprise N hydroxymethyl acrylamide, glycidyl acrylate etc. with the cross-linking agent of the functional group of acidiferous monomer substance reaction.There are at least two can comprise Biformyl with the suitable crosslinking agent of the functional group of acidiferous monomer substance reaction; Polyhydric alcohol such as ethylene glycol and glycerol; Polyamine such as alkylene diamine (as: ethylenediamine); Poly-alkylene polyamine; Polyepoxides; Two or poly epihydric alcohol base ether etc.The suitable polyvalent metal cross-linking agent that can form the ion-type cross-bond comprises the oxide of alkaline-earth metal (as: calcium, magnesium) and zinc, and hydroxide and salt of weak acid (as: carbonate, acetate etc.) comprise as calcium oxide and two zinc acetates.

The cross-linking agent of many above-mentioned types is described in detail in the following patent: 1978.2.28 is issued to people's such as Masuda United States Patent (USP) 4076663 and the United States Patent (USP) 4861539 that 1989.8.29 is issued to people such as Allen.Introduce these two pieces of patents herein as a reference.Preferred cross-linking agents comprises two or polyester of unsaturated list or polycarboxylic acids, the monoene propyl diester of polyhydric alcohol, bisacrylamide and two or triallylamine.The object lesson of particularly preferred cross-linking agent comprises N, N '-methylene-bisacrylamide and trimethylolpropane triacrylate.

Cross-linking agent generally accounts for about 0.001-5mol% of the polymer of the formation hydrogel that obtains, and is more typically, and cross-linking agent accounts for about 0.01-3mol% of the polymer gel agent of the formation hydrogel that the present invention uses.

The polymer gel agent of formation hydrogel herein can be used with the neutral form of its part.In order to reach purpose of the present invention, as 25mol% at least, the preferred monomer that is used to form polymer of 50mol% at least is during by the neutral acidiferous monomer of alkali, and this polymer can think that part is neutral.Suitable be used for the hydroxide (as: KOH that neutral alkaline kation comprises alkali metal and alkaline-earth metal, ammonium, replacement ammonium, NaOH), with amine such as amino alcohol (as: 2-amino-2-methyl-1, ammediol, diethanolamine and 2-amino-2-methyl-1-propanol).In total monomer, the percent of the acidiferous monomer that is neutralized is called " degree of neutralization " in this application.Degree of neutralization preferably is no more than 98%.

The polymer gel agent that is applicable to formation hydrogel of the present invention is being known in the art, and is described in the following patent: 1978.2.28 is issued to people's such as Masuda United States Patent (USP) 4,076,663; 1977.12.13 be issued to the United States Patent (USP) 4,062,817 of Westerman; 1981.8.25 be issued to people's such as Tsubakimoto United States Patent (USP) 4,286,082; 1991.10.29 be issued to people's such as Goldman United States Patent (USP) 5,061,259; Be issued to people's such as Brandt United States Patent (USP) 4,654,039 with 1987.3.31.Introduce these patents herein as a reference.

The polymer gel agent that is applicable to formation hydrogel of the present invention also is described in the following patent: 1988.3.15 is issued to the United States Patent (USP) 4,731,067 of Le-Khac; 1988.5.10 be issued to the United States Patent (USP) 4,743,244 of Le-Khac; 1989.3.21 be issued to the United States Patent (USP) 4,813,945 of Le-Khac; 1989.11.14 be issued to the United States Patent (USP) 4,880,868 of Le-Khac; 1990.1.9 be issued to the United States Patent (USP) 4,892,533 of Le-Khac; 1991.6.25 be issued to the United States Patent (USP) 5,026,784 of Le-Khac; 1992.1.7 be issued to the United States Patent (USP) 5,079,306 of Le-Khac; 1992.9.29 be issued to the United States Patent (USP) 5,151,465 of Le-Khac; 1989.8.29 be issued to Allen, the United States Patent (USP) 4,861,539 of Farrer and Flesher; Be issued to Allen with 1990.10.9, the United States Patent (USP) 4,962,172 of Farrer and Flesher.Introduce these patents herein as a reference.

The polymer gel agent of the formation hydrogel of suitable particle form can be from HoechstCelanese Corporation, Portsmouth, VA, the U.S. (Sanwet ^TMThe superabsorbent polymer), Nippon Shokubai, Japan (Aqualic ^TM, as L-75, L-76) with Dow ChemicalCompany, Midland, MI, the U.S. (Dry Tech ^TM) be purchased.

The polymer gel agent of the formation hydrogel of fibers form can be from CamelotTechnologies Inc., Leominster, MA, the U.S. (Fibersorb ^TM, as, SA 7200H, SA 7200M, SA 7000L, SA 7000 and SA 7300) be purchased.

Articles for use of the present invention can also contain other hydrophilic gelling agent.These gellant comprise the aforesaid polymer that contains carboxylic acid, difference is that it has crosslinked than low degree, their Tg is lower than 140 ℃, also comprises various other water solublity or colloidal state water-soluble polymers, as cellulose ether (as: hydroxyethyl-cellulose, methylcellulose, HYDROXY PROPYL METHYLCELLULOSE), polyvinylpyrrolidone, polyvinyl alcohol, guar gum, hydroxypropyl guar gum and xanthan gum.In these additional hydrophilic gelling agent, preferably contain acid polymer, particularly contain the polymer of carboxylic acid.Particularly preferably be and comprise with the polyalkenyl polyether of polyhydric alcohol crosslinked acrylic acid water-soluble polymer and the acrylate of choosing wantonly or those polymer of multi-functional vinylidene monomer.

Available preferred copolymer in the present invention is the thiazolinyl unsaturated carboxylic acid monomer that is selected from acrylic acid, methacrylic acid and ethylacrylic acid of the polymer that contains the monomer mixture of following material: 95-99wt%; About 1wt% is the acrylate with following structural formula of about 3.5wt% extremely, Wherein, R is the alkyl that contains 10-30 carbon atom, R ₁Be hydrogen, methyl or ethyl; With the crosslinked polyalkenyl polyether of the polymerizable polyol alcohol of 0.1-0.6wt%, each molecular polylol contains more than one alkene ether, and wherein, the parent polyhydric alcohol contains at least 3 carbon atoms and at least 3 hydroxyls.

Preferably, these polymer contain have an appointment the 96wt% extremely acrylic acid and the acrylate of about 2.5wt% to about 3.5wt% of about 97.9wt%, and wherein, alkyl contains 12-22 carbon atom, R ₁Be methyl, most preferred acrylate is the methacrylic acid stearyl.Preferably, the monomeric amount of crosslinked polyalkenyl polyether is about 0.2-0.4wt%.Preferred crosslinked polyalkenyl polyether monomer is pi-allyl tetramethylolmethane, trimethylolpropane allyl ether or allyl sucrose.These polymer are described in detail in the United States Patent (USP) 4,509,949 that 1985.4.5 is issued to people such as Huang, introduce this patent herein as a reference.

Other in the present invention available preferred copolymer is the polymer that contains at least two kinds of monomer components, and a kind of monomer component is a monomer thiazolinyl unsaturated carboxylic acid, and another kind is a polyalkenyl, the polyethers of polyhydric alcohol.If desired, in this monomer mixture, can also have other monomeric substance, even also account for significant proportion.

The first kind of monomer component that is used to prepare these carboxylic acid polyalcohols is the thiazolinyl unsaturated carboxylic acid that contains at least one active C=C olefinic double bonds and at least one carboxyl.Preferred carboxylic acid monomer is the acrylic acid with following general formula: Wherein, R ²Be selected from hydrogen, halogen, cyanogen (C=N) group, monovalent alkyl, unit price alkaryl and unit price alcyl.In these groups, most preferably acrylic acid, methacrylic acid and ethylacrylic acid.Other useful carboxylic acid monomer is maleic anhydride or its acid.The consumption of acid is that about 95.5wt% is to about 98.9wt%.

The second kind of monomer component that is used for preparing these carboxylic acid polyalcohols is the polyalkenyl polyether that each molecule has an above alkene ether, and for example the two keys of thiazolinyl are connected the thiazolinyl on the methylene of end, CH ₂=C＜.

Can be present in additional monomer material in these polymer comprises and contains at least two end CH ₂The multi-functional vinylidene monomer of＜group comprises as butadiene, isoprene, divinylbenzene, divinyl naphthalene, allyl acrylate etc.These polymer are described in detail in the United States Patent (USP) 2,798,053 that 1957.7.2 is issued to Brown, introduce this patent herein as a reference.

The example of available polymers of carboxylic acid in the present invention comprises Carbomer 934, Carbomer 941, Carbomer 950, Carbomer 951, Carbomer 954, Carbomer980, and Carbomer 981, Carbomer 1342, acrylate/C10-30 alkyl acrylate cross-linked polymer (can be from B.F.Goodrich respectively with Carbopol 934, Carbopol941, Carbopol 950, Carbopol 951, Carbopol 954, and Carbopol 980, and Carbopol 981, Carbopol 1342 and Pemulen series are purchased).

What other in the present invention available polymers of carboxylic acid comprised Hoechst CelaneseCorporation sale is the sodium salt of the acrylic acid copolymer of trade mark with Hostaceren PN73.What also comprise Lipo Chemicals Inc. sale is the aquogel polymer of trade mark with the HYPAN hydrogel.These hydrogels are made up of the crystalline wafer of the nitrate on the C-C skeleton that has various other side groups such as carboxyl, amide groups, amidino groups.Its example comprises HYPAN SA100H, this be a kind of can be available from the polymer powder of Lipo Chemical..

The neutralization reagent of acid groups of these polymer of being used to neutralize comprises aforesaid those materials.Cationic surfactant

Cationic surfactant belongs to non-foaming surfactant, still, as long as it does not have a negative impact to the desired properties of articles for use of the present invention, just can be used in the articles for use of the present invention.

The indefiniteness example of available cationic surfactant in the present invention is disclosed in McCutcheon ' s, and " detergent and emulsifying agent ", North American edition (1986) is published by allured Publishing Corporation; And McCutcheon ' s, " functional material " among the North American Edition (1992), introduces these two pieces of documents herein as a reference.

The indefiniteness example of available cationic surfactant in the present invention comprises the kation alkyl ammonium salt with following formula:

R ₁R ₂R ₃R ₄N ⁺X ^-Wherein, R ₁Be selected from and have an appointment 12 to the alkyl or the aromatic radical of about 18 carbon atoms or 12 aryl or the alkaryls of having an appointment to about 18 carbon atoms; R ₂, R ₃And R ₄All be independently selected from hydrogen, have an appointment 1 to the alkyl or the aromatic radical of about 18 carbon atoms or 12 aryl or the alkaryls of having an appointment to about 18 carbon atoms; X be selected from chloride ion, bromide ion, iodide ion, acetate, phosphate radical, nitrate anion, sulfate radical, methylsulfate, ethyl sulphate, tosylate, lactate, citrate, ethanol acid group, and composition thereof anion.In addition, alkyl can also contain ehter bond or hydroxyl or amino substituent group (as, alkyl can contain Polyethylene Glycol and polypropylene glycol part).

More preferably be R ₁Be 12 the alkyl of having an appointment to about 18 carbon atoms; R ₂Be selected from hydrogen, 1 the alkyl of having an appointment to about 18 carbon atoms; R ₃And R ₄All be independently selected from hydrogen, 1 the alkyl of having an appointment to about 3 carbon atoms; X is as the described anion of epimere.

Most preferably be R ₁Be 12 the alkyl of having an appointment to about 18 carbon atoms; R ₂, R ₃And R ₄All be selected from hydrogen or have an appointment 1 alkyl to about 3 carbon atoms; X is aforesaid anion.

Other substituting useful cationic surfactant comprises amino-amide, wherein, in the said structure formula, R ₁Selectively be R ₅CO-(CH ₂) _n-, wherein, R ₅Be 12 alkyl to about 22 carbon atoms of having an appointment, n is about 2 to about 6, is more preferably about 2 to about 4, most preferably is about 2 to about 3 integer.The indefiniteness example of these cationic emulsifiers comprise stearamide propyl PG-phosphoric acid chlorination diammonium, stearamide propyl ethyl diethyl sulphuric acid dimethylammonium, stearamide propyl dimethyl (myristyl acetate) ammonium chloride, stearamide propyl dimethyl cetyl ammonium tosylate, stearamide propyl alkyl dimethyl ammonium chloride, stearamide propyl dimethyl DL-Lactic acid ammonium salt., and composition thereof.

The indefiniteness example of quaternary cationics comprises those surfactants that are selected from following substances: cetyl ammonium chloride, cetyl bromination ammonium, lauryl chlorination ammonium, lauryl bromination ammonium, stearyl chlorination ammonium, the stearyl ammonium bromide, the cetyl alkyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lauryl dimethyl ammonium chloride, the lauryl dimethyl ammonium bromide, the stearyl alkyl dimethyl ammonium chloride, stearyl dimethyl ammonium bromide, the cetyl trimethyl ammonium chloride, the cetyl trimethylammonium bromide, lauryl trimethyl ammonium chloride, the lauryl trimethylammonium bromide, the stearyl trimethyl ammonium chloride, the stearyl trimethylammonium bromide, lauryl dimethyl ammonium chloride, stearyl dimethyl cetyl ditallow dimethyl ammonium chloride, two cetyl ammonium chloride, two cetyl bromination ammoniums, dilauryl ammonium chloride, the dilauryl ammonium bromide, distearyl ammonium chloride, the distearyl ammonium bromide, two cetyl ammonio methacrylates, two cetyl methyl ammonium bromide, the dilauryl ammonio methacrylate, dilauryl methyl ammonium bromide, the distearyl ammonio methacrylate, distearyl methyl ammonium bromide, and composition thereof.Other quaternary ammonium salt comprises the quaternary ammonium salt of those C12-C22 alkyl carbon chains wherein derived from tallow acid or coco-nut oil fatty acid.Term " Adeps Bovis seu Bubali " refers to the alkyl derived from tallow acid (normally hydrogenated tallow), and tallow acid has the mixture of the alkyl chain of C16-C18 scope usually.Term " Oleum Cocois " refers to the alkyl derived from coco-nut oil fatty acid, and coco-nut oil fatty acid has the mixture of the alkyl chain of C12-C14 scope usually.Example derived from the quaternary ammonium salt of these Adeps Bovis seu Bubali and Cortex cocois radicis oil sources comprises two Adeps Bovis seu Bubali alkyl dimethyl ammonium chlorides, two Adeps Bovis seu Bubali dimethyl methyl ammonium sulfate, two (h-tallow) alkyl dimethyl ammonium chloride, two (h-tallow) dimethyl acetic acid ammonium, two Adeps Bovis seu Bubali dipropyl ammonium phosphate, two Adeps Bovis seu Bubali dimethyl ammonium nitrates, two (Oleum Cocois alkyl) alkyl dimethyl ammonium chloride, two (Oleum Cocois alkyl) dimethyl ammonium bromide, tallow ammonium chloride, Oleum Cocois ammonium chloride, stearamide propyl PG-phosphoric acid chlorination diammonium, stearamide propyl ethyl diethyl sulphuric acid dimethylammonium, stearamide propyl dimethyl (myristyl acetate) ammonium chloride, stearamide propyl dimethyl cetyl ammonium tosylate, the stearamide propyl alkyl dimethyl ammonium chloride, stearamide propyl dimethyl DL-Lactic acid ammonium salt., and composition thereof.

Can be used for preferred cationic surfactant of the present invention and comprise those surfactants that are selected from following substances: dilauryl alkyl dimethyl ammonium chloride, VARISOFT TA100, myristyl alkyl dimethyl ammonium chloride, two palmityl alkyl dimethyl ammonium chlorides, VARISOFT TA100, and composition thereof.Chelating agen

Articles for use of the present invention can also comprise the chelate and the chelating agen of safety and effective dose.The term that uses among the application " chelate " or " chelating agen " refer to and can remove the activator of the metal ion in the system by forming complex, make metal ion be not easy to participate in or catalyzed chemical reaction.The inclusions of this chelating agen is specially adapted to protect and makes skin excessively play bits or make the ultraviolet radiation that skin texture changes and can damage other environment agent of skin.

The chelating agen that can in compositions of the present invention, add safety and effective dose, its measure compositions preferably about 0.1% to about 10%, more preferably from about 1% to about 5%.Be applicable to that illustration chelating agen of the present invention is disclosed in the following patent: 1996.1.30 is issued to people's such as Bissett United States Patent (USP) 5,487,884; 1995.10.31 people's such as disclosed Bush publication number is 91/16035 international monopoly; With people's such as the disclosed Bush of 1995.10.31 publication number be 91/16034 international monopoly.The preferred sequestrant that is applicable to compositions of the present invention is furil-dioxime and derivant thereof.Flavonoid

Articles for use of the present invention can randomly comprise flavonoids.Flavonoid is disclosed in United States Patent (USP) 5,686 widely, in 082 and 5,686,367, introduces these two pieces of patents herein as a reference.Be applicable to flavonoid of the present invention be selected from unsubstituted flavanone, mono-substituted flavanone, and composition thereof flavanone; Be selected from unsubstituted chalcone derivative, mono-substituted chalcone derivative, disubstituted chalcone derivative, trisubstituted chalcone derivative, and composition thereof; Be selected from unsubstituted flavone, mono-substituted flavone, disubstituted flavone, and composition thereof flavone; One or more isoflavone; Be selected from unsubstituted coumarin, mono-substituted coumarin, disubstituted coumarin, and composition thereof coumarin; Be selected from unsubstituted chromone, mono-substituted chromone, disubstituted chromone, and composition thereof color ketone; One or more dicoumarins; One or more 4-Chromanones; One or more chromanols; Its isomer (as: cis/trans isomer); And composition thereof.Joined the flavonoid that sugar etc. or these substituent mixture replace by hydroxyl, C1-C8 alkyl, C1-C4 alkoxyl, O-independently with one or more hydrogen atoms of term " replacement " representation class flavone among the application.

The example of suitable flavonoid comprises but is not defined as unsubstituted flavanone, the monohydroxy flavanone (as: 2 '-the hydroxyl flavanone, 6-hydroxyl flavanone, 7-hydroxyl flavanone etc.), monoalkoxy flavanone (as: 5-methoxyl group flavanone, 6-methoxyl group flavanone, 7-methoxyl group flavanone, 4 '-the methoxyl group flavanone etc.), unsubstituted chalcone derivative (particularly unsubstituted trans chalcone derivative), the monohydroxy chalcone derivative (as: 2 '-hydroxy chalcone, 4 '-hydroxy chalcone etc.), the dihydroxy chalcone derivative (as: 2 ', 4-dihydroxy chalcone derivative, 2 ', 4 '-the dihydroxy chalcone derivative, 2,2 '-the dihydroxy chalcone derivative, 2 ', 3-dihydroxy chalcone derivative, 2 ', 5 '-the dihydroxy chalcone derivative etc.), with the trihydroxy chalcone derivative (as: 2 ', 3 ', 4 '-the trihydroxy chalcone derivative, 4,2 ', 4 '-the trihydroxy chalcone derivative, 2,2 ', 4 '-the trihydroxy chalcone derivative etc.), unsubstituted flavone, 7,2 '-dihydroxyflavone, 3 ', 4 '-the dihydroxy naphthlene flavone, 4 '-flavonol, 5,6-benzo cornel ketone (benzoflavone), with 7,8-benzo cornel ketone, unsubstituted isoflavone, daidzein (7,4 '-dihydroxy isoflavone), 5,7-dihydroxy-4 '-the methoxyl group isoflavone, soybean isoflavone (mixture that from Semen sojae atricolor, extracts), unsubstituted coumarin, 4 hydroxy coumarin, umbelliferone, the 6-hydroxy-4-methylcoumarin, unsubstituted chromone, 3-formyl chromone, 3-formyl-6-isopropyl chromone, unsubstituted dicoumarin, unsubstituted 4-Chromanone, unsubstituted chromanol, and composition thereof.

Be applicable to preferred class flavone of the present invention be unsubstituted flavanone, methoxyl group flavanone, unsubstituted chalcone derivative, 2 ', 4-dihydroxy chalcone derivative, and composition thereof.Most preferably unsubstituted flavanone, unsubstituted chalcone derivative (particularly its transisomer), and composition thereof.

They can be the extracts of synthetic material or natural source (as: plant).The material that is derived from natural material can further derive (as: with the preparation of the extract of natural source join sugar, ester or ether derivant).Be applicable to that flavonoids of the present invention can be purchased from a plurality of businessmans, as: Indofine Chemical Company, Inc. (Somerville, New Jersey), Steraloids, Inc. (Wilton, New Hampshi re) and Aldrich ChemicalCompany, and Inc. (Milwaukee, Wisconsin).

Can also use the mixture of above-mentioned flavonoids.

The concentration of flavonoids described herein in compositions of the present invention preferably about 0.01% is to about 20%, and more preferably from about 0.1% to about 10%, and most preferably from about 0.5% to about 5%.Sterol

Articles for use of the present invention can also comprise one or more sterol compounds of safety and effective dose.The example of useful sterol compound comprise sitosterol, stigmasterol, campesterol, brassicasterol, lanosterol, 7-dehydrocholesterol, and composition thereof.These sterols itself can be synthetic or from natural source, as: the mixture (as: phytosterol) that extracts from plant source.Degrease agent (anti-cellulite agent)

Articles for use of the present invention can also comprise the degrease agent of safety and effective dose.Suitable degrease agent can comprise but not be defined as Xanthine compounds (as: caffeine, theophylline, theobromine and aminophylline).Skin lightening agent

Articles for use of the present invention can comprise skin lightening agent.When using skin lightening agent, said composition preferably include composition weight about 0.1% to about 10%, more preferably from about 0.2% to about 5%, also preferred about 0.5% to about 2% skin lightening agent.Suitable skin lightening agent comprises those those skin lightening agents well known in the art, and it comprises kojic acid, arbutin, vitamin C and derivant thereof, as: other salt of phosphoric acid ascorbic acid magnesium salt or phosphoric acid SODIUM ASCORBATE or phosphoric acid ascorbic acid.Be applicable to that skin lightening agent of the present invention also comprises those skin lightening agents that are described in the following patent application: corresponding to the PCT application US 95/07432 of 1995.6.12 application with the name of Hillebrand in the serial number of 1995.6.7 application be 08/479,935 examine patent application jointly; With corresponding to 1995.3.1 application, the disclosed PCT application of 1995.9.8 U S95/02809 with KallaL.Kvalnes, Mitchell A.DeLong, Barton J.Bradbury, the serial number that the name of Curtis B.Motley and John D.Carter is applied in 1995.2.24 is 08/390,152 careful jointly patent application.Binding agent

Articles for use of the present invention can randomly comprise binding agent.Binding agent or bonding material are used for each layer of the present invention is sealed mutually to keep the globality of articles for use.Binding agent can be a various forms, and these forms comprise but are not defined as spray, net, single layer, viscose fibre etc.Suitable binding agent can comprise latex, polyamide, polyester, polyolefin, and composition thereof.Extra play

In another embodiment, articles for use of the present invention can comprise one or more extra plays, and those of ordinary skills know: extra play and the ground floor and the second layer be separate with different, still, extra play a bit links to each other with these two layers at place at certain.Extra play is applicable to the most close hands of raising or other total holding property in the articles for use side of the equipment of wanting to carry out on the clean Surface mechanism.Extra play also is applicable to the soft sense that improves the articles for use side that contacts with the position that will clean and/or treat.Under any circumstance, these extra plays all can also be called the continuous alignment layer except these two basic layers of articles for use of the present invention, as: the 3rd layer, the 4th layer etc.

Suitable extra play can be that macroscopic view goes up expansion.Surperficial consistent net, ribbon and the film of representing with three-dimensionally shaped structure " expanded " in the application's use on the macroscopic view, make two surfaces of net, ribbon and film have three-dimensionally shaped pattern corresponding to the textured surface of the macro cross-section of molding structure, wherein when the vertical dimension of observer's eyes and network plane is 12 inches approximately, the textured surface that comprises this pattern can use normal naked eye (that is, vision is 20/20 normal naked eye) to differentiate.

The molding structure that the application uses " burr " (embossed) represent material has the main pattern that is made of projection.On the contrary, the molding structure of (debossed) represent material with " dimpled grain " has the pattern that mainly is made of the capillary network that caves in.The film that preferred macroscopic view goes up expansion comprises formed film, and this film structurally is a kind of bulk film.These films are described in the United States Patent (USP) 5,554,145 that 1996.9.10 is issued to people such as Roe, introduce this patent herein as a reference.

Be applicable to that thickness is that the material of one millimeter extra play comprises but is not defined as those and is disclosed in Web materials in the United States Patent (USP) 5,518,801 that 1996.5.21 is issued to people such as Chappell at least, introduces this patent herein as a reference.Production method

Utilize traditional method cleaning component and/or component with therapeutic effect to be added on the thin slice of the suitable ground floor or the second layer and can produce personal-care supplies of the present invention, traditional method comprises but is not defined as sprinkling, dip-coating, spraying, slit coating and roll and shifts (as: pressure roll or finish roll).Thin slice with rest layers places on the thin slice of ground floor then, preferably in cleaning component and/or have on the component of therapeutic effect, but not always not like this.With traditional encapsulating method with these thin slice involutions together, traditional encapsulating method comprises but is not defined as heat-sealing, press seal, gummed, ultrasonic sealing etc.Hot sealing device can change in design, under the situation that can not seal effectively, in this example and other example, can between aspect, use the heat sealable fibroreticulate interposed layer of low melting point, for example be known as Wonder Under (produce by Pellon, can be from H.Levinson ﹠amp; Co., Chicago, IL is purchased) the Fypro net, can not change the effect and the purposes of articles for use like this.Thin slice after will sealing then is divided into and is suitable for the unit that consumer uses.Optional production stage can comprise with the calendering method articles for use are smooth, and drying is wrinkling, shrinks stretching, extension or other mechanically deform.Cleaning and will have treatment or the reagent of aesthetic effect is transported to method on skin or the hair

The invention still further relates to method with personal-care supplies cleaning skin of the present invention or hair.These methods comprise the steps: that a) water will be applicable to the disposable personal care articles for use moistening of the substantially dry of cleaning, these articles for use comprise the water-insoluble substrate, this substrate comprise total scraping coverage value be less than about 17% softish ground floor and total scraping coverage value be about 17% to about 70% peel off the second layer in abutting connection with what this ground floor was placed; And cleaning component, it is placed in abutting connection with this ground floor and the second layer, and wherein, this component comprises about 10% to about 1000% lathering surfactant of water-insoluble substrate weight; With b) articles for use after the moistening are contacted with skin or hair.In addition, the present invention relates to the method for cleaning skin and hair, this method comprises the steps: a) will to be applicable to the disposable personal care articles for use moistening of the substantially dry of cleaning, these articles for use comprise the water-insoluble substrate, this substrate comprise the average surface depth value be less than about 8 softish ground floor and average case depth value be about 8 to about 80 peel off the second layer in abutting connection with what this ground floor was placed; Place in abutting connection with this ground floor and the second layer with cleaning component, wherein, this component comprises about 10% to about 1000% lathering surfactant of water-insoluble substrate weight; With b) articles for use after the moistening are contacted with skin or hair.

Other method comprises the similar step of using the articles for use with disclosed all the other physical properties among the application.

In another embodiment, the component that the present invention is used for having therapeutic effect is transported to the position (as: skin that needs are handled, hairs etc.) on, wherein, this method comprises following additional step: the disposable personal care articles for use moistening of the substantially dry described in A) water falls the preceding paragraph; With 2) component with therapeutic effect places in abutting connection with this water-insoluble substrate, and wherein, this component comprises about 10% to about 1000% treatment beneficial agent of water-insoluble substrate weight; With B) articles for use after the moistening are contacted with skin or hair.

Articles for use of the present invention are that water is active, therefore, will use water-wet before use.Represent that with the active ＂ of ＂ water articles for use of the present invention give consumer with dried forms among the application, should be with using after the water-wet.We find: when articles for use of the present invention comprised lathering surfactant, they can produce foaming or the ＂＂ that is activated when stirring after water contacts again.Therefore, make its moistening under the current by being immersed in articles for use in the water or it being in.When comprising lathering surfactant in the cleaning component in the articles for use of the present invention, articles for use with before skin or hair contact or in the process of contact by mechanical agitation and/or make the articles for use distortion can make articles for use produce foam.The foam that produces can be used for cleaning skin or hair.In the process of cleaning and the cleaning of water subsequently, all reagent with treatment or aesthetic effect all are deposited on skin or the hair.Substrate and skin or hair contact and the effect of the inclusions of one or more deposition aids will improve the deposition that these have the reagent of treatment or aesthetic effect.

Embodiment

The following examples further describe and illustrate the embodiment in the protection domain of the present invention.In the following embodiments, all the components is all represented with its live vol.To provide these embodiment just in order illustrating, and can not to think limitation of the invention, because can make many variations to the present invention in the case of without departing from the spirit and scope of protection of the present invention.

The title of composition is its chemical name or CTFA name.I. cleaning component

Embodiment 1

Preparation in the following manner is used for the representative cleaning component of articles for use of the present invention.

The soap slab that comprises following component of cutting 53.0gms.

Component	Wt％
Component	Wt％	Cocoyl ethylenehydrinsulfonic acid sodium	27.77
Paraffin	16.72	Cocoyl ethylenehydrinsulfonic acid sodium	27.77
Paraffin	16.72	Alkyl glycerol sodium sulfonate (AGS)	14.90
Soap	11.41	Alkyl glycerol sodium sulfonate (AGS)	14.90
Soap	11.41	Glycerol	8.57
Water	5.50	Glycerol	8.57
Water	5.50	Stearic acid	5.74
Ethylenehydrinsulfonic acid sodium	3.04	Stearic acid	5.74
Ethylenehydrinsulfonic acid sodium	3.04	NaCl	1.41
EDTA	0.10	NaCl	1.41
EDTA	0.10	Hydroxyl ethylidene diphosphonic acid	0.10
Polyox	0.03	Hydroxyl ethylidene diphosphonic acid	0.10
Polyox	0.03	Spice	0.70
Other (comprising pigment)	4.01	Spice	0.70
Other (comprising pigment)	4.01	Amount to	100

With the glycerol (99.7%) of this soap slab stripping and slicing and 37.0gms, the water of 9.5gms and the spice of 0.5gms mix.When continue stirring with this mixture heated to 200.On the standard three-roll grinder, be stored in the suitable sealed container with the mixture cold grinding and with cleaning component.

Embodiment 2

The soap slab that comprises following component of cutting 40.0gms.

Component	Wt％
Component	Wt％	Soda soap	52.40
Alkyl glycerol sodium sulfonate (AGS)	16.50	Soda soap	52.40
Alkyl glycerol sodium sulfonate (AGS)	16.50	Magnesium soap	13.40
Glycerol	0.19	Magnesium soap	13.40
Glycerol	0.19	Water	5.50
Stearic acid	1.60	Water	5.50
Stearic acid	1.60	Ethylenehydrinsulfonic acid sodium	3.00
NaCl	3.89	Ethylenehydrinsulfonic acid sodium	3.00
NaCl	3.89	EDTA	0.10
Hydroxyl ethylidene diphosphonic acid	0.10	EDTA	0.10
Hydroxyl ethylidene diphosphonic acid	0.10	Spice	0.70
Other (comprising pigment)	2.62	Spice	0.70
Other (comprising pigment)	2.62	Amount to	100

With the glycerol (99.7%) of this soap slab stripping and slicing and 45.0gms, the water of 4.5gms and the spice of 0.5gms mix.When continue stirring with this mixture heated to 200.On the standard three-roll grinder, be stored in the suitable sealed container with the mixture cold grinding and with cleaning component.

Embodiment 3

Preparation in the following manner is used for the representative Powdered cleaning component of articles for use of the present invention.

The soap slab that comprises following component of cutting 40.0gms.

Component	Wt％
Component	Wt％	Soap (magnesium soap and soda soap)	80.16
Water	11.50	Soap (magnesium soap and soda soap)	80.16
Water	11.50	Stearic acid	5.70
NaCl	1.10	Stearic acid	5.70
NaCl	1.10	EDTA	0.25
Spice	1.15	EDTA	0.25
Spice	1.15	Other (comprising pigment)	0.14

Amount to

100

This soap slab fragment is stored in the suitable sealed container.

Embodiment 4

The soap slab that comprises following component of cutting 40.0gms.

Component	Wt％
Component	Wt％	Soap (magnesium soap and soda soap)	80.16
Water	11.50	Soap (magnesium soap and soda soap)	80.16
Water	11.50	Stearic acid	5.70
NaCl	1.10	Stearic acid	5.70
NaCl	1.10	EDTA	0.25
Spice	1.15	EDTA	0.25
Spice	1.15	Other (comprising pigment)	0.14
Amount to	100	Other (comprising pigment)	0.14

This soap slab fragment is mixed with 90: 10 weight ratio with sodium bicarbonate, on the standard three-roll grinder, mixture is ground twice.Collect fragment and it is stored in the suitable sealed container.

Embodiment 5

Preparation in the following manner is used for the representative cleaning component of articles for use of the present invention.The cleaning component of embodiment 2 is mixed with the soap slab fragment of the protease of 0.1wt%.Then, the mixture that obtains being mixed the back with cleaning component, the sodium carboxymethyl cellulose of the dry hydrocolloid of 2wt% grinds.The enzyme cleaning component is stored in the suitable sealed container.

Embodiment 6

Preparation comprises the representative cleaning liquid component of following component.

Component	Wt％
Component	Wt％	Cocos nucifera oil alkyl glycerol sodium sulfonate (AGS)	7.2
Ammonium lauryl sulfate (ALS)	10.4	Cocos nucifera oil alkyl glycerol sodium sulfonate (AGS)	7.2
Ammonium lauryl sulfate (ALS)	10.4	Alkyl lauryl ether sulfate (AE3S)	10.4
Poly(ethylene oxide) (PolyOx WSR N-3000, Union Carbide)	0.5	Alkyl lauryl ether sulfate (AE3S)	10.4

HANSHENGJIAO	1.4
HANSHENGJIAO	1.4	Water	70.1

Embodiment 7

Preparation in the following manner is used for the representative cleaning component of articles for use of the present invention.The soap slab stripping and slicing of the embodiment 2 of 3lbs heated up to soap slab with two and 3/4ths glasss isopropyl alcohol (99%) melt.After the soap slab fusing, add remaining alcohol.Adding 10 ounces of sugar is dissolved in the least possible water.About 4 dyestuff is blended in 8 ounces the glycerol.Add glycerol (99.7%).Heating becomes the rope form band equably up to low-viscosity (mobile) liquid and falls from mixing tool when continue stirring, and when this material is fallen on the cold surface, the part material will harden.To harden in this mixture impouring suitable containers.The advantage of this mixture can melt when being heating again, and therefore, it is easy to processing with the preparation articles for use.

Embodiment 8

Preparation comprises the representative nonirritant cleaning liquid component of following component.

Component	Wt％
Component	Wt％	Cocamidopropyl betaine	17.1
The tridecyl ether sodium sulfate	8.3	Cocamidopropyl betaine	17.1
The tridecyl ether sodium sulfate	8.3	POE 100 sorbitan monooleates	7.5
Other (comprising spice, antiseptic, dyestuff)	2.0	POE 100 sorbitan monooleates	7.5
Other (comprising spice, antiseptic, dyestuff)	2.0	Water	65.1

Said composition is characterised in that it is to skin and eyes nonirritant.

Embodiment 9

Component	Wt％
Component	Wt％	Polymeric quaternary ammonium salts 10	0.50
Glycerol lauric acid both sexes sodium acetate	5.4	Polymeric quaternary ammonium salts 10	0.50
Glycerol lauric acid both sexes sodium acetate	5.4	The 3-sodium laureth sulfate	11.6
Two sodium edtas	0.20	The 3-sodium laureth sulfate	11.6
Two sodium edtas	0.20	Two hydration sodium citrates	0.50
Anhydrous citric acid	1.0	Two hydration sodium citrates	0.50

PEG-6 caprylic/capric glyceride	2.0
PEG-6 caprylic/capric glyceride	2.0	Coconut oleoyl amine MEA	2.0
Glycerol	3.5	Coconut oleoyl amine MEA	2.0
Glycerol	3.5	MgSO ₄-7H ₂O (Epsom salts)	1.5
The Malaysia soybean oil	2.5	MgSO ₄-7H ₂O (Epsom salts)	1.5
The Malaysia soybean oil	2.5	The deodorization soybean oil	5.0
Other (comprising spice, caustic alkali, coloring agent)	1.5	The deodorization soybean oil	5.0
Other (comprising spice, caustic alkali, coloring agent)	1.5	Water	62.8

This mixture is gentle, is applicable to allergic skin.

Embodiment 10

Component	Wt％
Component	Wt％	Polymeric quaternary ammonium salts 10	0.1
Sodium sulfate	1.5	Polymeric quaternary ammonium salts 10	0.1
Sodium sulfate	1.5	Lauryl alcohol	0.3
Sodium laureth sulfate	5.8	Lauryl alcohol	0.3
Sodium laureth sulfate	5.8	Anhydrous citric acid	0.2
Cocamidopropyl betaine	15.5	Anhydrous citric acid	0.2
Cocamidopropyl betaine	15.5	Sodium N-lauroyl sarcosinate	1.5
Other impurity (comprising spice, blue colorant)	1.0	Sodium N-lauroyl sarcosinate	1.5
Other impurity (comprising spice, blue colorant)	1.0	Water	74.1

Embodiment 11

Preparation comprises the representative cleaning component of following component.

Component	Wt％
Component	Wt％	The decyl polyglucose	12.0
Cocamidopropyl betaine	12.0	The decyl polyglucose	12.0
Cocamidopropyl betaine	12.0	Sodium N-lauroyl sarcosinate	12.0
Butanediol	3.6	Sodium N-lauroyl sarcosinate	12.0
Butanediol	3.6	PEG?14M	1.8

Polymeric quaternary ammonium salts 10	0.9
Polymeric quaternary ammonium salts 10	0.9	D-panthenol	0.7
Phenoxyethanol	0.5	D-panthenol	0.7
Phenoxyethanol	0.5	Benzyl alcohol	0.5
Methyl parahydroxybenzoate	0.45	Benzyl alcohol	0.5
Methyl parahydroxybenzoate	0.45	Propyl p-hydroxybenzoate	0.25
Two sodium edtas	0.2	Propyl p-hydroxybenzoate	0.25
Two sodium edtas	0.2	Water	55.1

Embodiment 12

Component	Wt％
Component	Wt％	EGDS	3.1
Cocamidopropyl betaine	4.0	EGDS	3.1
Cocamidopropyl betaine	4.0	TEA soap (molecular weight is about 330)	9.5
Mono alkyl phosphate	15.0	TEA soap (molecular weight is about 330)	9.5
Mono alkyl phosphate	15.0	The cocos nucifera oil amine oxide	7.5
1, the 2-propylene glycol	1.0	The cocos nucifera oil amine oxide	7.5
1, the 2-propylene glycol	1.0	Ethanol	3.0
Other (spice, coloring agent, antiseptic)	8.9	Ethanol	3.0
Other (spice, coloring agent, antiseptic)	8.9	Water	48.0

When continue stirring with this mixture heated to 50 ℃, up to this mixture lose its former weight 38% and have a pasty consistency.The advantage of this cleaning component is to be easy to process and do not need dry again with substrate layer.

Embodiment 13

Component	Wt％
Component	Wt％	SEFA ^*Cottonate	57.5
Citric acid	0.30	SEFA ^*Cottonate	57.5
Citric acid	0.30	Cocamidopropyl betaine	3.5

Sodium N-lauroyl sarcosinate	10.7
Sodium N-lauroyl sarcosinate	10.7	Ethylene vinyl acetate polymer (Elvax 40W)	8.0
Siloxane polymer microballon (Tospearly 145A)	20.0	Ethylene vinyl acetate polymer (Elvax 40W)	8.0

SEFA ^*It is the initial of the sucrose ester of fatty acid

Under 90 ℃ and high shear stirring condition, ethylene vinyl acetate polymer is melted among the SEFAcottonate.Mix after adding surfactant and citric acid.Add siloxane polymer microballon, mixing, cool off then.Said composition can melt again and be easy to immerse in the fabric or apply thereon.

Embodiment 14

Component	Wt％
Component	Wt％	10-lauryl ether carboxylic acid sodium (Empicol CB5S ^*)	50.0
C12-14,12EO alcohol ethoxylate (Empilan KB12*)	50.0	10-lauryl ether carboxylic acid sodium (Empicol CB5S ^*)	50.0

^*Can be from Albright ﹠amp; Wilson is purchased

With alcohol ethoxylate fusing, infiltrate in the carboxylate, stir, cooling curing is easy to use up to it.Said composition can melt again and be easy to immerse in the fabric or apply thereon.

Embodiment 15

Component	Wt％
Component	Wt％	Lauroyl glutamate list sodium	22.0
Cocamidopropyl betaine	2.0	Lauroyl glutamate list sodium	22.0
Cocamidopropyl betaine	2.0	Sodium chloride	1.0
Glycerol	2.5	Sodium chloride	1.0
Glycerol	2.5	Water	72.5

Under the stirring of gentleness that these component heating are even up to it.

Embodiment 16

Component	Wt％
Component	Wt％	Triethanolamine	2.9
Polymeric quaternary ammonium salts 39	0.1	Triethanolamine	2.9
Polymeric quaternary ammonium salts 39	0.1	The mono phosphoric acid ester lauryl	4.0
C12-C14N-methyl glucoside amide ¹	5.0	The mono phosphoric acid ester lauryl	4.0
C12-C14N-methyl glucoside amide ¹	5.0	Cocamidopropyl propyl hydroxy sulfobetaines ²	2.0
Sodium decyl sulfate	0.5	Cocamidopropyl propyl hydroxy sulfobetaines ²	2.0
Sodium decyl sulfate	0.5	Monohydrate potassium	0.3
Spice, antiseptic and other	4.0	Monohydrate potassium	0.3
Spice, antiseptic and other	4.0	Water	81.2

¹Can be purchased from Hoechst Celanese

²Can be purchased from Rhone Poulenc

Under 60 ℃ these compositions slowly being added in the following sequence all is dissolved in the water up to each composition: TEA, mono phosphoric acid ester lauryl, glucose amide.Add sulfobetaines, polymeric quaternary ammonium salts 39 and sulfate after being cooled to 45 ℃, stir as before.Add spice, antiseptic postcooling to room temperature.

Embodiment 17

Prepare representational cleaning component by mixing following component.

Component	Wt％
Component	Wt％	The lauroyl polyglucose ¹	20.0
Cetyl trimethyl ammonium bromide	4.0	The lauroyl polyglucose ¹	20.0
Cetyl trimethyl ammonium bromide	4.0	Spice, antiseptic and other	4.0
Water	72.0	Spice, antiseptic and other	4.0

¹Can be purchased II. with Plantaren 1200 from Henkel and treat useful component

Embodiment 18-22

Prepare representational skin condition component by mixing following component.

Component	Embodiment 18	Embodiment 19	Embodiment 20	Embodiment 21	Embodiment 22
Component	Embodiment 18	Embodiment 19	Embodiment 20	Embodiment 21	Embodiment 22	?SEFA ^*Cottonate	?48.0	?75.0	?33.5	?40.0	?80.0

SEFA ^*Behenic acid	12.0	?25.0	?8.4	?10.0	10.0
SEFA ^*Behenic acid	12.0	?25.0	?8.4	?10.0	10.0	Vaseline	10.0	?-	?7.0	?-	-
Three (behenic acid) glyceride	5.0	?-	?3.5	?-	-	Vaseline	10.0	?-	?7.0	?-	-
Three (behenic acid) glyceride	5.0	?-	?3.5	?-	-	Stearyl alcohol	-	?-	?-	5.0	-
Paraffin	-	?-	?-	15.0	-	Stearyl alcohol	-	?-	?-	5.0	-
Paraffin	-	?-	?-	15.0	-	Cholesteryl ester	25.0	?-	?17.5	-	-
Ceresine	-	?-	?-	-	10.0	Cholesteryl ester	25.0	?-	?17.5	-	-
Ceresine	-	?-	?-	-	10.0	Glycerol	-	?-	28.0	-	-
Mono stearic acid triacyl glycerol	-	?-	1.9	-	-	Glycerol	-	?-	28.0	-	-
Mono stearic acid triacyl glycerol	-	?-	1.9	-	-	Two Palmic acids, ten glyceride	-	?-	0.2	-	-
Nonyl phenol polyglycine ether ¹	-	?-	-	30.0	-	Two Palmic acids, ten glyceride	-	?-	0.2	-	-

^*SEFA is the initial of the sucrose ester of fatty acid

¹Hamplex?TNP，Hampshire?Chemical?Co.

Embodiment 23-27

Component	Embodiment 23	Embodiment 24	Embodiment 25	Embodiment 26	Embodiment 27
Component	Embodiment 23	Embodiment 24	Embodiment 25	Embodiment 26	Embodiment 27	Vaseline (white)	35.87	?35.87	-	-	?34.0
Mineral oil	11.0	?13.0	-	-	?10.0	Vaseline (white)	35.87	?35.87	-	-	?34.0
Mineral oil	11.0	?13.0	-	-	?10.0	Jojoba oil	-	?-	-	4.5
Oleum Ricini	10.0	?9.0	-	-		Jojoba oil	-	?-	-	4.5
Oleum Ricini	10.0	?9.0	-	-		Cupu oil	-	?-	-	-	?5.0
Two iso stearyl trimethyl propane siloxysilicate materials	20.0	?20.0	-	-		Cupu oil	-	?-	-	-	?5.0
Two iso stearyl trimethyl propane siloxysilicate materials	20.0	?20.0	-	-		Polydimethylsiloxane, the fluid of 500cSt	-	?-	0.7	1.5

Decamethylcyclopentasiloxane	-	?-	-	16.5
Decamethylcyclopentasiloxane	-	?-	-	16.5		Octamethylcy-clotetrasiloxane	-	?-	-	10.0
Polydimethylsiloxane, natural gum	-	?-	5.9	7.5		Octamethylcy-clotetrasiloxane	-	?-	-	10.0
Polydimethylsiloxane, natural gum	-	?-	5.9	7.5		Stearyl methylsiloxane wax	-	?-	-	3.0
Polybutene	-	?-	-	4.5		Stearyl methylsiloxane wax	-	?-	-	3.0
Polybutene	-	?-	-	4.5		Candelilla wax	4.6	?4.6	-	-	?6.0
Paraffin	-	?-	-	15.0	?2.0	Candelilla wax	4.6	?4.6	-	-	?6.0
Paraffin	-	?-	-	15.0	?2.0	Microwax	-	?-	-	6.0	?4.0
Cera Flava	3.0	?3.0	-	-	?4.0	Microwax	-	?-	-	6.0	?4.0
Cera Flava	3.0	?3.0	-	-	?4.0	Ceresine	6.0	?6.0	-	-
Brazil wax	3.0	?3.0	-	-		Ceresine	6.0	?6.0	-	-
Brazil wax	3.0	?3.0	-	-		Castor oil hydrogenated	0.50	?0.50	4.0	-
Silicon dioxide	-	?-	-	4.5		Castor oil hydrogenated	0.50	?0.50	4.0	-
Silicon dioxide	-	?-	-	4.5		Sodium magnesium silicate	-	?-	-	1.5
Tocopherol	0.03	?0.03	-	-		Sodium magnesium silicate	-	?-	-	1.5
Tocopherol	0.03	?0.03	-	-		The cyclohexyl methyl siloxanes	-	?-	59.0	-
Stearyl alcohol	-	?-	25.5	-	?9.0	The cyclohexyl methyl siloxanes	-	?-	59.0	-
Stearyl alcohol	-	?-	25.5	-	?9.0	Hexadecanol					?9.0
Glyceryl stearate	-	?-	2.6	-		Hexadecanol					?9.0
Glyceryl stearate	-	?-	2.6	-		The acetyl group monoglyceride					?15.0
Two iso stearyl maleates ¹	-	?-	-	6.0		The acetyl group monoglyceride					?15.0
Two iso stearyl maleates ¹	-	?-	-	6.0		Glycerol distearate	-	?-	-	9.5
Glycerol	-	?-	-	6.0		Glycerol distearate	-	?-	-	9.5
Glycerol	-	?-	-	6.0		Water	-	?-	-	3.0
Nonyl phenol polyglycine ether ²	-	?-	5.0	-		Water	-	?-	-	3.0
Nonyl phenol polyglycine ether ²	-	?-	5.0	-		Micronized titanium dioxide		?5.0	-	-
Octyl methoxycinnamate	5.0	?-	-	-		Micronized titanium dioxide		?5.0	-	-
Octyl methoxycinnamate	5.0	?-	-	-		Spice and other	1.0	?1.0	1.0	1.0	?2.0

¹Can be purchased about half acetyl groupization from Eastman Chemical Co. with Myvacet 7-07

²Can be purchased with Hamplex TNP from Hampshire Chemical Co.

Embodiment 28

Component	Embodiment 28
Component	Embodiment 28	Poly decene ¹	53.3
Stearyl alcohol	7.7	Poly decene ¹	53.3
Stearyl alcohol	7.7	The 12-hydroxy stearic acid	13.5
Nonyl phenol polyglycine ether	25.0	The 12-hydroxy stearic acid	13.5
Nonyl phenol polyglycine ether	25.0	Octyl methoxycinnamate	1.5

¹Puresyn?3000，Mobil?Chemical?Co.

Embodiment 29-31

Component	Embodiment 29	Embodiment 30	Embodiment 31
Component	Embodiment 29	Embodiment 30	Embodiment 31	Glycerol	95.0	?95.0	?94.0
Ten glyceryl dipalmitates ¹	5.0	?1.0	?5.0	Glycerol	95.0	?95.0	?94.0
Ten glyceryl dipalmitates ¹	5.0	?1.0	?5.0	Ten glyceryls two (docosane acid esters)		?4.0
Three (two dodecyne acid esters) (Tribehenin)			?1.0	Ten glyceryls two (docosane acid esters)		?4.0

¹Can be purchased with Polyaldo 10-2-P from Lonza

Embodiment 32-36

The representative conditioning component that is used for articles for use of the present invention with following method preparation.

Component	Embodiment 32	Embodiment 33	Embodiment 34	Embodiment 35	Embodiment 36
Component	Embodiment 32	Embodiment 33	Embodiment 34	Embodiment 35	Embodiment 36	Hydrophobic phase:
SEFA ^*cottonate	?4.65	?4.65	?15.5	?15.5		Hydrophobic phase:
SEFA ^*cottonate	?4.65	?4.65	?15.5	?15.5		SEFA ^*Behenic acid	?0.35	?0.35	?8.0	?8.0
Tribehenin			?6.0	?6.0		SEFA ^*Behenic acid	?0.35	?0.35	?8.0	?8.0
Tribehenin			?6.0	?6.0		Vaseline			?4.0	?4.0	?4.4

Cupu oil					15.5
Cupu oil					15.5	C10-C30 cholesterol/lanosterol ester			?13.0	?13.0
C30-C45 alkyl methyl siloxanes ¹						C10-C30 cholesterol/lanosterol ester			?13.0	?13.0
C30-C45 alkyl methyl siloxanes ¹						Polyglyceryl-4 isostearate (with) the hexadecyldimethyl benzyl ammonium siloxanes (with) lauric acid hexyl ester ²	5.0	5.0
PEG30 dimerization hydroxy stearic acid ester ³			?3.0				5.0	5.0
PEG30 dimerization hydroxy stearic acid ester ³			?3.0			Four glycerol monostearates				?2.1
Two Palmic acids, ten glyceride				?0.90		Four glycerol monostearates				?2.1
Two Palmic acids, ten glyceride				?0.90		Ceresin					5.5
Cera Flava					7.0	Ceresin					5.5
Cera Flava					7.0	Lecithin, purification					10.0
The 1-single-stearic					10.0	Lecithin, purification					10.0
The 1-single-stearic					10.0	Aqueous favoring:
Glycerol	70.0	66.5	?42.30	?42.30	40.0	Aqueous favoring:
Glycerol	70.0	66.5	?42.30	?42.30	40.0	Water		3.5			5.0
The PVM/MA decadiene crosslinked polymer ⁴			?0.25	?0.25		Water		3.5			5.0
The PVM/MA decadiene crosslinked polymer ⁴			?0.25	?0.25		Sodium hydroxide (10% solution)			?0.25	?0.25
Gelatin					2.6	Sodium hydroxide (10% solution)			?0.25	?0.25
Gelatin					2.6	Active skin care ingredient:
Panthenol	20.0	10.0	?2.50			Active skin care ingredient:
Panthenol	20.0	10.0	?2.50			Nicotine		5.0	?2.50	?3.0
Urea		5.0	?2.50	?2.50		Nicotine		5.0	?2.50	?3.0
Urea		5.0	?2.50	?2.50		Allantoin			?0.20	?0.20
The chlorination of acetamido propyl group				?2.0		Allantoin			?0.20	?0.20

Trimethylammonium

^*SEFA is the initial of the sucrose ester of fatty acid ¹Can be purchased with AMS-C30 from Dow Corning ²Can be purchased with Abil WE-09 from Goldschmidt ³Can be purchased with Arlacel P135 from ICI ⁴Can be purchased all emulsification methods with Stabileze 06 from ISP:

With hydrophobic heat phase to 70 ℃, add hydrophobic active skin care ingredient, stir up to evenly.With aqueous favoring composition and the premixing of hydrophilic active skin care ingredient, make its dissolving or diffusion with regard to leniently heating if desired.Then it is slowly added hydrophobic phase, continue to stir.Processing (high-shear mixer homogenizes; Ultrasonic homogenizer; Or high pressure homogenisers is as the Micro Fluid bed device available from MicrofluidicsCorp.).It is applied on the substrate surface immediately or in ice or frozen water rapidly under the cool to room temperature.It is stored in the controlled environment, if desired, it is in keeps its chemical stability under the nitrogen environment.

Embodiment 37-41

As described in embodiment 32-36, prepare representational conditioning component with following compositions.

Component	Embodiment 37	Embodiment 38	Embodiment 39	Embodiment 40	Embodiment 41
Component	Embodiment 37	Embodiment 38	Embodiment 39	Embodiment 40	Embodiment 41	Hydrophobic phase:
SEFA ^*cottonate			15.0	16.0		Hydrophobic phase:
SEFA ^*cottonate			15.0	16.0		SEFA ^*Behenic acid			7.5	4.0
Tribehenin			6.0			SEFA ^*Behenic acid			7.5	4.0
Tribehenin			6.0			Vaseline			4.0	4.0	4.4
Cupu oil					15.5	Vaseline			4.0	4.0	4.4
Cupu oil					15.5	Poly decene ¹	50.0	46.5
C10-C30 cholesterol/lanosterol ester			13.0	10.5		Poly decene ¹	50.0	46.5
C10-C30 cholesterol/lanosterol ester			13.0	10.5		PEG30 dimerization hydroxy stearic acid ester			3.0	3.0
Ceresin					5.5	PEG30 dimerization hydroxy stearic acid ester			3.0	3.0

Cera Flava					7.0
Cera Flava					7.0	Aluminum in the mineral oil/magnesium hydroxyl stearate ²				7.5
C30-38 alkene/isopropyl maleate copolymer ³				2.5		Aluminum in the mineral oil/magnesium hydroxyl stearate ²				7.5
C30-38 alkene/isopropyl maleate copolymer ³				2.5		Tissuemat E ⁴				1.0
Lecithin, purification					10.0	Tissuemat E ⁴				1.0
Lecithin, purification					10.0	Spice and other			1.0
The 1-single-stearic					10.0	Spice and other			1.0
The 1-single-stearic					10.0	Aqueous favoring:
Glycerol	30.0	25.0	34.80	20.0	38.0	Aqueous favoring:
Glycerol	30.0	25.0	34.80	20.0	38.0	Water	8.0	8.0			5.0
PEG?2000				17.0		Water	8.0	8.0			5.0
PEG?2000				17.0		The PVM/MA decadiene crosslinked polymer			0.25
Sodium hydroxide (10% solution)			0.25			The PVM/MA decadiene crosslinked polymer			0.25
Sodium hydroxide (10% solution)			0.25			Gelatin	9.50	9.50			2.6
Active skin care ingredient:						Gelatin	9.50	9.50			2.6
Active skin care ingredient:						Nicotine			2.50
Methanol in 50% the beta-schardinger dextrin-		2.50				Nicotine			2.50
Methanol in 50% the beta-schardinger dextrin-		2.50				Vitamin C (natural)		2.50
Tocopherol (natural)		1.00		2.50		Vitamin C (natural)		2.50
Tocopherol (natural)		1.00		2.50		Sorbitol			2.50
Lactic acid	2.5					Sorbitol			2.50
Lactic acid	2.5					Urea			2.50
Allantoin			0.20			Urea			2.50
Allantoin			0.20			Pure as jade pure					1.50
Chlohexidine					0.50	Pure as jade pure					1.50
Chlohexidine					0.50	Benzoyl peroxide			5.0

The salicylic acid of 15% in the PPG14 butyl ether				12.0
The salicylic acid of 15% in the PPG14 butyl ether				12.0		Salicylic acid			2.5

¹Can be purchased with Puresyn 3000 from Mobil ²Can be purchased with Gilugel Min from Giulini Chemie ³Can be purchased with Performa 1608 from New Phase Technologies ⁴Can be purchased with Performalene 400 from New Phase Technologies

Embodiment 42-46

Component	Embodiment 42	Embodiment 43	Embodiment 44	Embodiment 45	Embodiment 46
Component	Embodiment 42	Embodiment 43	Embodiment 44	Embodiment 45	Embodiment 46	Hydrophobic phase:
SEFA ^*cottonate	20.5	15.5			16.0	Hydrophobic phase:
SEFA ^*cottonate	20.5	15.5			16.0	Mineral oil			7.50
SEFA ^*Behenic acid	8.0	8.0			8.0	Mineral oil			7.50
SEFA ^*Behenic acid	8.0	8.0			8.0	Tribehenin	9.5	6.0		6.0
Vaseline (white or ultrawhite color)	4.0	4.0	22.6	3.0	4.0	Tribehenin	9.5	6.0		6.0
Vaseline (white or ultrawhite color)	4.0	4.0	22.6	3.0	4.0	Candelilla wax			4.50
Paraffin			3.00	14.0		Candelilla wax			4.50
Paraffin			3.00	14.0		Microwax			1.50
Cera Flava			3.00			Microwax			1.50
Cera Flava			3.00			C10-C30 cholesterol/lanosterol ester	18.0	13.0		13.0
The lauryl methyl siloxanes is polyhydric alcohol altogether ¹				5.0		C10-C30 cholesterol/lanosterol ester	18.0	13.0		13.0
				5.0		The acetyl group monoglyceride ²			11.3
Stearyl alcohol			6.8			The acetyl group monoglyceride ²			11.3
Stearyl alcohol			6.8			Hexadecanol			6.8
Stearic acid						Hexadecanol			6.8

PEG30 dimerization hydroxy stearic acid ester	4.5	3.0
PEG30 dimerization hydroxy stearic acid ester	4.5	3.0			Two Palmic acids, ten glyceride ³					0.90
Four glycerol monostearates				2.10	Two Palmic acids, ten glyceride ³					0.90
Four glycerol monostearates				2.10	Spice and other	1.0		3.0	2.0
Aqueous favoring:					Spice and other	1.0		3.0	2.0
Aqueous favoring:					Glycerol	22.8	27.5	25.0	38.0	41.0
Two Palmic acids, ten glyceride ³	2.5			0.90	Glycerol	22.8	27.5	25.0	38.0	41.0
Two Palmic acids, ten glyceride ³	2.5			0.90	The calcium silicates microsphere ⁴		15.0
Active skin care ingredient:					The calcium silicates microsphere ⁴		15.0
Active skin care ingredient:					Melon ear hydroxypropyl chlorination trimethylammonium	1.00
The chitosan glycolate		2.50			Melon ear hydroxypropyl chlorination trimethylammonium	1.00
The chitosan glycolate		2.50			Nicotine	1.50	2.50	2.50
0.2% acrylate copolymer 940, pH6.0			38.0		Nicotine	1.50	2.50	2.50
0.2% acrylate copolymer 940, pH6.0			38.0		Vitamin A					2.50
Phytantriol ⁵	1.00				Vitamin A					2.50
Phytantriol ⁵	1.00				Urea	2.50	3.0	2.50
Vitamin C				2.50	Urea	2.50	3.0	2.50
Vitamin C				2.50	Borage oil					2.50
Ascorbic palmitate				1.50	Borage oil					2.50
Ascorbic palmitate				1.50	Acetamido propyl group chlorination trimethylammonium ⁶	2.50

¹Can be purchased with Dow Q2-5200 from Dow Corning ²Half acetyl groupization can be purchased with Myvacet 7-07 from Eastman Chemical Co. ³Can be purchased with Polyaldo 10-2-P from Lonza ⁴Can be purchased with Celite C from Celite Co. ⁵Can be purchased with Hydagen CMF from Henkel ⁶Can be purchased embodiment 43 with Incromectant AQ from Croda: glycerol is added the microsphere, the fat of sneaking into fusing then mutually in, store after the cooling or be applied on the substrate.

Embodiment 47-52

Component	Embodiment 47	Embodiment 48	Embodiment 49	Embodiment 50	Embodiment 51	Embodiment 52
Component	Embodiment 47	Embodiment 48	Embodiment 49	Embodiment 50	Embodiment 51	Embodiment 52	Hydrophobic phase:
SEFA ^*cottonate	16.0	16.0	16.0	16.0	16.0	16.0	Hydrophobic phase:
SEFA ^*cottonate	16.0	16.0	16.0	16.0	16.0	16.0	Mineral oil
SEFA ^*Behenic acid		8.0	8.0	8.0	8.0	8.0	Mineral oil
SEFA ^*Behenic acid		8.0	8.0	8.0	8.0	8.0	Tribehenin	6.0	6.0	6.0	6.0	6.0	6.0
Vaseline (white or ultrawhite color)	4.0	4.0	4.0	4.0	4.0	4.0	Tribehenin	6.0	6.0	6.0	6.0	6.0	6.0
Vaseline (white or ultrawhite color)	4.0	4.0	4.0	4.0	4.0	4.0	C10-C30 cholesterol/lanosterol ester	13.0	13.0	13.0	13.0	13.0	13.0
Stearyl dimethicone	2.0						C10-C30 cholesterol/lanosterol ester	13.0	13.0	13.0	13.0	13.0	13.0
Stearyl dimethicone	2.0						The polydimethylsiloxane hydroxy stearic acid ester	4.0
Dimethicone copolyol docosane acid esters	2.0						The polydimethylsiloxane hydroxy stearic acid ester	4.0
Dimethicone copolyol docosane acid esters	2.0						PEG 30 dimerization hydroxy stearic acid esters			3.0		3.0
Sodium lauroyl glutamate				2.00			PEG 30 dimerization hydroxy stearic acid esters			3.0		3.0
Sodium lauroyl glutamate				2.00			The stearyl sodium lactate				2.00
Calcium stearate						5.0	The stearyl sodium lactate				2.00
Calcium stearate						5.0	Two Palmic acids, ten glyceride	0.90	0.90		0.90		0.90

Four glycerol monostearates	2.10	2.10		2.10		2.10
Four glycerol monostearates	2.10	2.10		2.10		2.10	Spice and other	1.00	1.00	1.00	1.00	1.00	1.00
Aqueous favoring:							Spice and other	1.00	1.00	1.00	1.00	1.00	1.00
Aqueous favoring:							Glycerol	44.5	42.5	35.5	35.5	25.0	43.0
75% polymine in water ¹?pH?6.5			4.50	4.50			Glycerol	44.5	42.5	35.5	35.5	25.0	43.0
75% polymine in water ¹?pH?6.5			4.50	4.50			Water						2.0
Two Palmic acids, ten glyceride			2.50	2.50			Water						2.0
Two Palmic acids, ten glyceride			2.50	2.50			Pyrogenic silica					20.0
Propylene glycol alginate ²						2.0	Pyrogenic silica					20.0
Propylene glycol alginate ²						2.0	Active skin care ingredient:
Nicotine		2.00			2.00		Active skin care ingredient:
Nicotine		2.00			2.00		Chitosan		1.50
Green tea extract	4.50						Chitosan		1.50
Green tea extract	4.50						Aloe vera gel		3.0
Vitamin C			2.50				Aloe vera gel		3.0
Vitamin C			2.50				Ascorbic palmitate			2.00	2.50
Acetamido propyl group chlorination trimethylammonium			2.00		2.00		Ascorbic palmitate			2.00	2.50

¹Can be purchased with Epomin SP-018 from Nippon Shokubai Co. ²Can be purchased with Kelcoloid HVF from Kelco

Embodiment 53-55

Component	Embodiment 53	Embodiment 54	Embodiment 55
Component	Embodiment 53	Embodiment 54	Embodiment 55	Hydrophobic phase
Lecithin, purification ¹	15.4	?10.3	?10.8	Hydrophobic phase
Lecithin, purification ¹	15.4	?10.3	?10.8	Decane	28.6	?19.2	?15.0

Mineral oil			5.0
Mineral oil			5.0	Tricontanyl?PVP ²			26.0
Stearyl alcohol		13.0		Tricontanyl?PVP ²			26.0
Stearyl alcohol		13.0		The 12-hydroxy stearic acid		19.4
Aqueous favoring				The 12-hydroxy stearic acid		19.4
Aqueous favoring				Glycerol	28.0	18.8	19.6
Propylene glycol	28.0	18.8	19.6	Glycerol	28.0	18.8	19.6
Propylene glycol	28.0	18.8	19.6	Active skin care ingredient
Pure as jade pure		0.20		Active skin care ingredient
Pure as jade pure		0.20		Salicylic acid		0.40
Nicotine			4.0	Salicylic acid		0.40

¹Can be purchased with Epikuron 200 from Lucas Meyer ²Can be purchased with Ganex WP-660 from ISP

All the components is stirred together, up to forming microemulsion.At first skin care ingredient is added mate most its solubility parameter mutually in.When adding wax, heat at leisure, just in time reach the softening point of wax, stirring makes its dispersion, is applied on the substrate or behind the cool to room temperature then to store.

Embodiment 56-58

Component	Embodiment 56	Embodiment 57	Embodiment 58
Component	Embodiment 56	Embodiment 57	Embodiment 58	Hydrophobic phase:
2-Methylpentadecane	????42.29	????43.0	????28.3	Hydrophobic phase:
2-Methylpentadecane	????42.29	????43.0	????28.3	Dioctyl sulfonic acid sodium succinate ²	????10.62	????7.0	????7.1
Aqueous favoring:				Dioctyl sulfonic acid sodium succinate ²	????10.62	????7.0	????7.1
Aqueous favoring:				Glycerol	????35.17	????19.0	????23.6
Water	????11.72	????19.0	????7.8	Glycerol	????35.17	????19.0	????23.6
Water	????11.72	????19.0	????7.8	Brazil wax			????29.0
Gelatin		????6.0		Brazil wax			????29.0
Gelatin		????6.0		Active skin care ingredient:
Pure as jade pure	????0.20			Active skin care ingredient:
Pure as jade pure	????0.20			Titanium dioxide, cosmetics			????4.2

Titanium dioxide, micronization		????4.2
Titanium dioxide, micronization		????4.2		Salicylic acid		????1.8

¹Can be purchased with Epikuron 200 from Lucas Meyer ²Can be purchased with Aerosol OT from Pfaltz and Bauer

At first skin care ingredient is added mate most its solubility parameter mutually in.Then all the components is stirred together, up to forming microemulsion.It is coated on the substrate surface.

Embodiment 59-64

The A part	Embodiment 59	Embodiment 60	Embodiment 61	Embodiment 62	Embodiment 63	Embodiment 64
The A part	Embodiment 59	Embodiment 60	Embodiment 61	Embodiment 62	Embodiment 63	Embodiment 64	Lauroyl ether sodium sulfate (SLES, the active matter as 27% adds)	15.0	6.51	6.20			5.9
Cocamidopropyl betaine ¹	13.5	5.85	5.57	5.82	5.19	5.3		15.0	6.51	6.20			5.9
Cocamidopropyl betaine ¹	13.5	5.85	5.57	5.82	5.19	5.3	Sodium N-lauroyl sarcosinate ²	1.35	0.60	0.57	6.01	5.36	0.54
The decyl polyglucose ³				5.80	5.18		Sodium N-lauroyl sarcosinate ²	1.35	0.60	0.57	6.01	5.36	0.54
The decyl polyglucose ³				5.80	5.18		Lauryl alcohol	1.31	0.56	0.54			0.54
Polymine ⁴	7.87	3.38	3.22	2.64	2.36	3.2	Lauryl alcohol	1.31	0.56	0.54			0.54
Polymine ⁴	7.87	3.38	3.22	2.64	2.36	3.2	Citric acid (aqueous solution with 50% adds)	0.32	0.11	0.11			0.09
EDTA four sodium	0.28						Citric acid (aqueous solution with 50% adds)	0.32	0.11	0.11			0.09
EDTA four sodium	0.28						Sulphuric acid	5.4	2.37	2.25			2.2
Antiseptic, spice	0.62	0.45	0.43	2.86	2.55	0.3	Sulphuric acid	5.4	2.37	2.25			2.2
Antiseptic, spice	0.62	0.45	0.43	2.86	2.55	0.3	Sodium sulfate	7.9	3.47	3.21			3.0
Glycerol	26.45	56.7	46.4	44.1	39.36	44.8	Sodium sulfate	7.9	3.47	3.21			3.0
Glycerol	26.45	56.7	46.4	44.1	39.36	44.8	Sorbitol			5.0
SEFA ^*cottonate					12.8		Sorbitol			5.0

SEFA ^*Behenic acid

8.0

B moiety-polymer gellant

Gelatin (Gelatin)		4.2
Gelatin (Gelatin)		4.2		Polyacrylamide and isoparaffin ⁵		??7.5
Polyurethane latex in 50% isopropyl alcohol ⁶			??34.1	Polyacrylamide and isoparaffin ⁵		??7.5
Polyurethane latex in 50% isopropyl alcohol ⁶			??34.1	Acrylate copolymer ⁷		??7.5
The polystyrolsulfon acid ester copolymer ⁸	??1.1			Acrylate copolymer ⁷		??7.5
The polystyrolsulfon acid ester copolymer ⁸	??1.1			The chitosan lactate	??5.4

C part-physics gellant

12-hydroxyl-stearic acid	10.0			?10.66
12-hydroxyl-stearic acid	10.0			?10.66			Stearyl alcohol	10.0	?20.0	?20.0	?7.11	?15.0

^*SEFA is the initial of the sucrose ester of fatty acid ¹Can be purchased with Tegobetaine F from Goldschmidt ²Can be purchased 31% activity with Hamposyl L-30 (721 type) from Hampshire Chemical ³Can be purchased with Plantaren 2000NP from Henkel ⁴Can be purchased with Epomin SP-018 from Nippon Shokubai Co., molecular weight is about 1800 ⁵Can be purchased with Carbopol Ultrez from B.F.Goodrich ⁶Can be purchased with Sancure 2710 from B.F.Goodrich, to comprise the pre-composition preparation of about 20% polymer, 30% water, 50%IPA ⁷Can be purchased with Sepigel 305 from Seppic Corp. ⁸Can be purchased with AQ38S from Eastman Chemical

Surfactant and aliphatic alcohol are mixed, when stirring, be heated 65 ℃ with the low speed impeller-agitator.Stop heating, when continuing stirring, make it be cooled to 65 ℃.The adding cationic polymer also stirs.The residual components that when stirring, slowly adds the A part.To its processing that homogenizes, so that SEFA is dispersed into emulsion.Use the concentrated sulphuric acid titration, reach about 6.5 up to its pH.A part compositions is dispersed in the dish back is no more than in temperature that drying prepares drying composite up to wherein not containing moisture substantially with this in 65 ℃ the suitable baking box (vacuum or convection current).The composition of exsiccant A part is mixed with the polymer gel agent of B part, and heating makes its dissolving or dispersion.The compositions that obtains is mixed with the physics gellant.Heating makes the gellant fusing and is dissolved in the compositions.Apply it on the substrate surface or behind the cool to room temperature and store.

Embodiment 65-70

As described in embodiment 59-64, prepare the representative conditioning component that is used for articles for use of the present invention with following compositions.

The A part	Embodiment 65	Embodiment 66	Embodiment 67	Embodiment 68	Embodiment 69	Embodiment 70
The A part	Embodiment 65	Embodiment 66	Embodiment 67	Embodiment 68	Embodiment 69	Embodiment 70	Sodium N-lauroyl sarcosinate ¹	8.87			?11.4	?10.8	?10.8
Polymine ²	7.39	?7.50	?7.50	?9.5	?9.0	?9.0	Sodium N-lauroyl sarcosinate ¹	8.87			?11.4	?10.8	?10.8
Polymine ²	7.39	?7.50	?7.50	?9.5	?9.0	?9.0	Water	4.43	?3.00	?3.00	?5.7	?5.4	?5.4
Sulphuric acid	6.36	(QS) in right amount	In right amount	?8.1	?7.7	?7.7	Water	4.43	?3.00	?3.00	?5.7	?5.4	?5.4
Sulphuric acid	6.36	(QS) in right amount	In right amount	?8.1	?7.7	?7.7	Spice, other
Glycerol	34.45	?52.5	?45.0	?41.3	?39.25	?34.25	Spice, other
Glycerol	34.45	?52.5	?45.0	?41.3	?39.25	?34.25	Propylene glycol	2.50
Urea		?2.50	?2.50	?2.0	?1.9	?1.9	Propylene glycol	2.50
Urea		?2.50	?2.50	?2.0	?1.9	?1.9	Panthenol				?2.0	?1.9	?1.9
Nicotine		?2.50	?2.50	?2.0	?1.9	?1.9	Panthenol				?2.0	?1.9	?1.9
Nicotine		?2.50	?2.50	?2.0	?1.9	?1.9	Salicylic acid
Poly methyl silsesquioxane ³					?4.20	?4.20	Salicylic acid
Poly methyl silsesquioxane ³					?4.20	?4.20	Muscovitum, the Margarita shape					?3.85	?3.85
Stearyl methylsiloxane wax						?5.0	Muscovitum, the Margarita shape					?3.85	?3.85
Stearyl methylsiloxane wax						?5.0	SEFA cottonate			?5.0

Vaseline

5.0

B moiety-polymer gellant

Gelatin						0.1
Gelatin						0.1	Polyacrylamide and isoparaffin ⁴	??16.0	?12.0	?12.0

C part-physics gellant

12-hydroxyl-stearic acid	12.0	?12.0	?10.5
12-hydroxyl-stearic acid	12.0	?12.0	?10.5	Brazil wax	?18.0	?14.1	?14.1
Stearyl alcohol	8.0	?8.0	?7.0	Brazil wax	?18.0	?14.1	?14.1

¹Can be purchased dry thing from Hampshire Chemical with Hamposyl L-95 ²Can be purchased with Epomin SP-018 from Nippon Shokubai Co., molecular weight is about 1800 ³Can be from Kobo, Inc. is purchased with Tospearl 145A ⁴Can be purchased with Sepigel 305 from Seppic Corp.

Embodiment 71-74

Preparation comprises the representative skin condition component of following component.

Component	Embodiment 71	Embodiment 72	Embodiment 73	Embodiment 74
Component	Embodiment 71	Embodiment 72	Embodiment 73	Embodiment 74	SEFA ^*cottonate		?62.0	?52.0
Vaseline			?4.5		SEFA ^*cottonate		?62.0	?52.0
Vaseline			?4.5		Stearyl alcohol	4.0
Stearic acid	3.0				Stearyl alcohol	4.0
Stearic acid	3.0				Wool grease		?20.0	?13.0
Ethylene vinyl acetate polymer ¹		?10.0	?10.0		Wool grease		?20.0	?13.0
Ethylene vinyl acetate polymer ¹		?10.0	?10.0		Poly decene ²			?2.0	?2.0
Sodium N-lauroyl sarcosinate ³	25.0	?3.00	?3.0		Poly decene ²			?2.0	?2.0
Sodium N-lauroyl sarcosinate ³	25.0	?3.00	?3.0		Lauryl betaine ⁴		?1.50	?2.0
Glycerol lauric acid both sexes acetas ⁶				?5.25	Lauryl betaine ⁴		?1.50	?2.0
Glycerol lauric acid both sexes acetas ⁶				?5.25	The 3-sodium laureth sulfate ⁶				?10.5
Coconut oleoyl amine MEA ⁷				?2.80	The 3-sodium laureth sulfate ⁶				?10.5
Coconut oleoyl amine MEA ⁷				?2.80	Sulphuric acid	In right amount

Melon ear hydroxypropyl chlorination trimethylammonium	0.50	0.50
Melon ear hydroxypropyl chlorination trimethylammonium	0.50	0.50		Cholesterol ⁸	9.0	1.0
Nonyl phenol polyglycine ether ⁹		5.0		Cholesterol ⁸	9.0	1.0
Nonyl phenol polyglycine ether ⁹		5.0		Micronized titanium dioxide			4.0
Octyl methoxycinnamate		4.0		Micronized titanium dioxide			4.0
Octyl methoxycinnamate		4.0		Nicotine		2.5
Glycerol	10.0		3.00	Nicotine		2.5
Glycerol	10.0		3.00	Water	48.5			55.95
PEG-6 caprylic/capric glyceride			3.40	Water	48.5			55.95
PEG-6 caprylic/capric glyceride			3.40	The Malaysia soybean oil				1.50
Soybean oil (deodorization)			8.0	The Malaysia soybean oil				1.50
Soybean oil (deodorization)			8.0	Palm kernel fatty acid				2.60
Polymeric quaternary ammonium salts 10			0.40	Palm kernel fatty acid				2.60
Polymeric quaternary ammonium salts 10			0.40	Spice, antiseptic, other				4.60

^*SEFA is the initial of the sucrose ester of fatty acid ¹Can be purchased with Elvax 40W from DuPont ²Can be purchased with Puresyn 3000 from Mobil ³As being purchased with Hamposyl L95 (solid) or L30 (30% active component water) from Hampshire Chemical ⁴Can be from Albright ﹠amp; Wilson is purchased (80% betanin, 20% salt) with Empigen BS98 ⁵Can be from Albright ﹠amp; Wilson is purchased with Empigen CDL60 ⁶Can be from Albright ﹠amp; Wilson is purchased with Empicol ESC3 ⁷Can be from Albright ﹠amp; Wilson is purchased with Empilan CME/G ⁸Can be purchased with Super Hartolan from Croda ⁹Hamplex TNP, Hampshire Chemical Co.

With lipidic component fusing, add entry (if can use) and wetting agent, add surfactant, heat continuously and stir up to it even.Add skin care activity thing and precipitant behind the cool to room temperature.With sulphuric acid pH regulator is arrived about 7.0.With nebulization, roll-in method, infusion process or other method it is applied on the substrate, before packing, makes its drying (if containing moisture).III. personal-care supplies embodiment 75

Prepare representational skin cleaning article with following method

The cleaning component of 4 gram embodiment 11 are applied in the Permeability that includes low-melting heat-sealing Fypro and a side of fusible net.The Permeability net be Pellon produce can be from H.Levinson ﹠amp; Co., Chicago, the Wonder that IL is purchased.Cleaning component is applied on the oval area of about 13cm * 18cm.Cleaning component is air-dry.2 oz/yd onesize with this net will be cut into ²The polyester cotton of (oz/sq yd) is placed on that this is fusible online.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The polyester cotton thickness of measuring under 5gsi. is about 0.23 inch (in.).Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.Nonwoven layers is placed fusible off the net second side that forms these articles for use.Nonwoven layers is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.The shape of these articles for use is ellipses of about 122mm * 160mm.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of Sentinel Model 808 heat sealing machines of MA in grid pattern with the multiple spot mull technique together with these layers involution.The diameter of measuring each bonding point is about 4mm, is evenly distributed with about 51 involution points independently.This articles for use finishing back is standby.

Embodiment 76

Prepare representational skin cleaning article with following method

The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second net is the bulk low-density cotton of air-laid, and second net is added on first substrate continuously, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 160mm of fillet, 51 seal points are arranged in each articles for use altogether approximately.

Embodiment 77

Prepare representational skin clean and conditioning article with following method

Use the skin conditioning composition of 3 gram embodiment 34, use half consumption in each side of the final articles for use of embodiment 75.The occupation mode of said composition is that the compositions with hot liquid (60-70 ℃) evenly is coated in by slit on the surface of articles for use, and each side of articles for use applies the compositions of half amount.

Embodiment 78

Use the skin conditioning composition of 3 gram embodiment 18, use half consumption in each side of the final articles for use of embodiment 75.The occupation mode of said composition is that the compositions with hot liquid (60-70 ℃) evenly is coated in by slit on the surface of articles for use, and each side of articles for use applies the compositions of half amount.

Embodiment 79

Use the skin conditioning composition of 3 gram embodiment 65, use half consumption in each side of the final articles for use of embodiment 75.The occupation mode of said composition is that the compositions with hot liquid (60-70 ℃) evenly is coated in by slit on the surface of articles for use, and each side of articles for use applies the compositions of half amount.

Embodiment 80

Use the skin conditioning composition of 3 gram embodiment 34, use half consumption in each side of the final articles for use of embodiment 76.The occupation mode of said composition is that the compositions with hot liquid (60-70 ℃) evenly is coated in by slit on the surface of articles for use, and each side of articles for use applies the compositions of half amount.Embodiment 81

Use the skin conditioning composition of 3 gram embodiment 18, use half consumption in each side of the final articles for use of embodiment 76.The occupation mode of said composition is that the compositions with hot liquid (60-70 ℃) evenly is coated in by slit on the surface of articles for use, and each side of articles for use applies the compositions of half amount.

Embodiment 82

Use the skin conditioning composition of 3 gram embodiment 65, use half consumption in each side of the final articles for use of embodiment 76.The occupation mode of said composition is that the compositions with hot liquid (60-70 ℃) evenly is coated in by slit on the surface of articles for use, and each side of articles for use applies the compositions of half amount.

Embodiment 83

Prepare representational skin cleaning article with following method

The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second net is the bulk low-density cotton of air-laid, and second net is added on first substrate continuously, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 480mm of fillet.

Embodiment 84

Prepare representational skin cleaning article with following method

The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second net is the bulk low-density cotton of air-laid, and second net is added on first substrate continuously, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.It is online three the substrate net identical with second substrate net to be added to second substrate continuously, and it is contacted with second substrate.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 90mm of fillet.

Embodiment 85

Prepare representational skin cleaning article with following method

The cleaning component of 4 gram embodiment 12 are applied in the Permeability that includes low-melting heat-sealing Fypro and a side of fusible net.The Permeability net be Pellon produce can be from H.Levinson ﹠amp; Co., Chicago, the Wonder that IL is purchased.Cleaning component is applied on the oval area of about 13cm * 18cm.Cleaning component is air-dry.2 oz/yd onesize with this net will be cut into ²Polyester cotton be placed on that this is fusible online.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..The saturating rate of the gas of this polyester cotton is about 1270cfm/ft ², its foam permeability critical pressure is about 2.7cmH ₂O.Can think that this polyester cotton is a hot adhesion, not use binding agent, nonwoven layers is placed fusible off the net second side that forms these articles for use.Nonwoven layers is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.The shape of these articles for use is ellipses of about 122mm * 160mm.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of Sentinel Model 808 heat sealing machines of MA in grid pattern with the multiple spot mull technique together with these layers involution.The diameter of measuring each bonding point is about 4mm, is evenly distributed with about 51 involution points independently.This articles for use finishing back is standby.

Embodiment 86-88

Cleaning component with embodiment 1,2 and 5 prepares representational skin cleaning article by following method.

8 gram cleaning component are coated on the Permeability that includes low-melting heat-sealable fiber and a side of fusible net.In four quadrants, form about 10 inches * 12 inches rectangle, make not have surfactant between each limit and quadrant and seal each layer.The Permeability net is generally can supply the fibrous low density polyethylene (LDPE) (LDPE or LLDPE) that retail trader is purchased from sewed product.4 oz/yd onesize with this net will be cut into ²Polyester cotton be placed on that this is fusible online.The basic weight of polyester cotton is 4 oz/yd ², be that about 30 microns polyester fiber constitutes by average diameter, by can be from Stearns Textiles, the Mountain Mist Extra HeavyBatting #205 binding agent bonding that Cincinnati, OH are purchased.Fibrous nonwoven layer is that the basic weight of 55% cellulose and 45% is the Hydroentangled mixture of the polyester (can be from The Texwipe Company, Saddle River, NJ is purchased with Technicloth II) of about 65gsm, and this nonwoven layers is placed fusible off the net.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of SentinelModel 808 heat sealing machines of MA is being enough to polyester cotton melted and is flowing under the temperature and pressure that forms fully sealing in the ground floor with rectangle pane glass shape with these layers involution together, and it is sufficient depressing sealing 6-10 second at about 370 temperature and 30psi machine usually.Continuous involution around at the edge, the pane cross portion that on each X and Y direction a width to be arranged all be about 2mm.After the articles for use cooling,, store standby then with its finishing and fillet.

Embodiment 89-90

Cleaning component powder with embodiment 3 and 4 prepares representational skin clean and conditioning article by following method.

The exsiccant cleaning component powder of 4 grams is applied in the Permeability that includes low-melting heat-sealable fiber and a side of fusible net.The Permeability net be Pellon produce can be from H.Levinson ﹠amp; Co., Chicago, the Wonder that IL is purchased.Powder evenly is sprayed on the oval area of about 17cm * 19cm.2 oz/yd onesize with this net will be cut into ²Polyester cotton be placed on that this is fusible online.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..The saturating rate of the gas of this polyester cotton is about 1270cfm/ft ², its foam permeability critical pressure is about 2.7cm H ₂O.Can think that this polyester cotton is a hot adhesion, does not use binding agent.Second nonwoven layers of preparation is waterpower punching, comprises that diameter is about 10 microns polyester fiber, and wherein to include fibre diameter be about 150 microns, the polypropylene plain weave beaujolais that interweaves of inlaying a lace every about 0.8cm.The second layer of cutting is bigger than the size that articles for use need, being placed on temperature and being in about 150 ℃ convection oven about 10 minutes, is about 0.12in. up to the X of this layer and the dimensional contraction on the Y direction to 70% and its macroscopic thickness of measuring under 5gsi. of its original size.This layer is about 64gsm in perisystolic macroscopical average basis weight, and the average diameter in hole is about 0.5mm.The second layer is placed fusible off the net, and with these layers involution together with the multiple spot mull technique, also with utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, near involution 2mm its periphery is wide for the heat seal die of Sentinel Model 808 heat sealing machines of MA.The diameter of each bonding point is about 3mm, is evenly distributed with about 51 involution points independently.After the finishing of this articles for use, apply the skin conditioning composition of 2.5 gram embodiment 25 in its bulked cotton one side, method is that to make said composition remain about 60 ℃ raw material storage tank by a slit drum apparatus that is processed with the 1.5mm slit and temperature reinforced.Said composition is cooling rapidly on the articles for use surface, is stored in the packing of metallisation film of sealing it standby.

Embodiment 91-96

Cleaning liquid component with embodiment 6,8,9,15,16 and 17 prepares representational skin clean and conditioning article by following method.

The cleaning liquid component is applied in a side of first substrate, and method is to brush with brush, up to there being 2 gram solid cleaning components to apply thereon with the pane pattern, can not brush on its sideline and seal point.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.This substrate in 45 ℃ convection oven air-dry about 6 hours or air-dry to touching up exsiccant degree.Second substrate is the bulk low-density cotton of air-laid, is placed on first substrate, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of Sentinel Model 808 heat sealing machines of MA is being enough to this cotton melted and is flowing under the temperature and pressure that forms fully sealing in the ground floor with rectangle pane glass shape with these layers involution together, and it is sufficient depressing sealing 6-10 second at about 370 temperature and 30psi machine usually.Continuous involution around at the edge, the pane cross portion that on each X and Y direction a width to be arranged all be about 2mm.With the finishing of cooled articles for use, apply the skin conditioning composition of 3 gram embodiment 26 then in its bulked cotton one side, method is that to make said composition remain about 60 ℃ raw material storage tank by a slit drum apparatus that is processed with the 1.5mm slit and temperature reinforced.Said composition is cooling rapidly on the articles for use surface, is stored in the packing of metallisation film of sealing it standby.

Embodiment 97-102

Prepare representational skin clean and conditioning article with the cleaning liquid component of embodiment 7 and the skin conditioning composition of embodiment 19-24 by following method.

With 4 cleaning liquid components squeeze continuously first move online, this net is the bulk low-density cotton of air-laid, the basic weight of this polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.Be stored in about 65 ℃ storage tank after the cleaning liquid component is heated to its fusing point, it is pumped into the extruder head of 4 cylinder plumes of continuous metering, by extruder head it is squeezed on the net, uniform distribution on the net, the charging rate that finally reaches is the 5 gram compositionss of having an appointment on each final articles for use.Second net is micropore and macropore formed film, and this is a kind of formed film that is disclosed in the United States Patent (USP) 4629643, second net is added in continuously first is online, and macropore protrudes side facing to polyester cotton and cleaning component.In heating, make skin conditioning composition have the speed of 3 gram compositionss to be coated in equably on the cotton surface of exposure on the final articles for use with each by slit.Make its cooling curing on the articles for use surface then.After these are netted continuous involution, cut facing to the formed film side, cut into the rectangle of the 120mm * 160mm of band fillet with thermometal cylinder and pressure roller.Articles for use packing back is standby.

Embodiment 103-105

Prepare representational skin clean and conditioning article with the cleaning liquid component of embodiment 6 and the skin conditioning composition of embodiment 56,57 and 58 by following method.

The cleaning liquid component is applied in a side of first substrate, and method is to brush with brush, up to there being 2 gram solid cleaning components to apply thereon with the pane pattern, can not brush on its sideline and seal point.This substrate is that basic weight is 2 oz/yd ²Polyester cotton, be that the fibre blend of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.This cotton thickness of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.With the cleaning component drying.Second substrate be have good bulk and basic weight for the high wet strength of about 53gsm with the agglutinating cellulose napkin of binding agent, be placed on the side of polyester cotton of exposure cleaning component.Useful napkin can be from The Procter ﹠amp; Gamble Company is purchased, and these commodity are with BountyRinse ﹠amp; Reuse ^Sell, it also can keep the height on its Z direction when moistening, and its thickness under 5gsi. is about 0.047in., and it is bulk/and soft ratio is about 1.28.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of Sentinel Model 808 heat sealing machines of MA is being enough to form under the temperature and pressure of suitable sealing with rectangle pane glass shape with these layers involution together, continuous involution around at the edge, the pane cross portion that on each X and Y direction a width to be arranged all be about 2mm.With articles for use finishings, apply 1.5 gram skin conditioning compositions in its bulked cotton one side then, method is that to make said composition remain about 60 ℃ raw material storage tank by a slit drum apparatus that is processed with the 1.5mm slit and temperature reinforced.Said composition is cooling rapidly on the articles for use surface, is stored in the packing of metallisation film of sealing it standby.

Embodiment 106

Prepare representational skin clean and conditioning article with following method.

The method that the cleaning component of embodiment 12 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second net is the bulk low-density cotton of air-laid, and second net is added on first substrate continuously, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.It is online three the substrate net identical with second substrate net to be added to second substrate continuously, and it is contacted with second substrate.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.The skin condition liquid of embodiment 53 is sprayed to the speed of the 0.5 gram said composition of having an appointment on the about 25gsm of every side or each the final articles for use this is online.This net is cut into the orthogonal single articles for use of about 120mm * 90mm of fillet, and the packing back is standby.

Embodiment 107-108

Skin conditioning composition with embodiment 54 and 55 prepares representational skin clean and conditioning article by following method.

(can be with active cleaning component of the low water of embodiment 2 and aluminosilicate from PQCorporation, Valley Forge, PA is purchased with Advera 401 N, because it is exposed in the water back exothermic reaction takes place, so can produce heat) to carry out triple-roller mill with 1: 1 ratio broken.10 gram cleaning component are applied in a side of polyester cotton layer, and the basic weight of this polyester cotton is 2 oz/yd ², be that the fibre blend of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.Surfactant is applied on the fiber, and about 10 inches * 12 inches rectangle of common formation makes and does not have surfactant between each limit and quadrant in four quadrants.Second nonwoven layers of preparation is the waterpower punching, comprise that diameter is about 10 microns polyester fiber, and wherein include the diameter that crosses the nonwoven layers width be about 100 microns and with diameter that width intersects be the plain weave beaujolais that interweaves about 250 microns fiber, inlay a lace every about 1cm.This plain weave beaujolais can be from Conwed plastics, Minneapolis, and MN is purchased.The basic weight of second nonwoven layers is about 70gsm, because net tension force that produces in the production process of this nonwoven layers and tension force subsequently are loose, so this nonwoven layers is slightly wrinkling.With the multiple spot mull technique together with these layers involution, also with utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, near involution 2mm its periphery is wide for the heat seal die of Sentinel Model 808 heat sealing machines of MA.The diameter of each bonding point is about 3mm, is evenly distributed with about 51 involution points independently.After the finishing of this articles for use, apply 4 gram skin conditioning compositions in its bulked cotton one side, method is that to make said composition remain about 60 ℃ raw material storage tank by a slit drum apparatus that is processed with the 1.5mm slit and temperature reinforced.Said composition is cooling rapidly on the articles for use surface, is stored in the packing of metallisation film of sealing it standby.

Embodiment 109-116

Skin conditioning composition with embodiment 59,60,61,62,63,68,69 and 70 prepares representational skin clean and conditioning article by following method.

Be evenly dispersed on the bulked cotton with the cleaning component of hands with 4 gram embodiment 11, the basic weight of this polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.This cotton thickness of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.Fibrous nonwoven layer is that the basic weight of 55% cellulose and 45% is that the polyester of about 65gsm (can be from The Texwipe Company, Saddle River, NJ is purchased with Technicloth II) Hydroentangled mixture, this nonwoven layers is placed on the side that is coated with cleaning component of polyester cotton.With the link type seal plate with these layers involution together, this junction panel uses the not plate of heating, wherein has along the storage tank of the equally distributed reversed stream tube shape of hexagonal mesh pattern, and the base diameter of cannula-like storage tank is about 1.2cm, and its centre-to-centre spacing is about 2cm.The confined area between the recess is not recessed into several millimeters inwards on the hot plate, forms connectivity slot.Hot plate has the ectoloph of the groove precision-fit on the confined area with hot plate not.Hot plate contacts with cellulose/polyester substrate, with the pressing plate hot sealing device as available from Sencorp, Hyannis, SentinelModel 808 heat sealing machines of MA seal.The non-final articles for use that obtain have outstanding sleeve-shaped on the polyester cotton side, in the cellulose/polyester substrate side of articles for use outstanding short recess or " button " are arranged, and make both sides all be easy to hold.These articles for use are cut into the rectangle of about 120mm * 160mm.The groove district of each articles for use sucks the skin conditioning composition of 3 gram heat, makes its cooling curing then, and this articles for use packing back is standby.

Embodiment 117

Restrain the side of the cleaning liquid components brushing of embodiment 10 with 8 at Permeability that includes low-melting heat-sealable fiber and fusible net.In four quadrants, form about 10 inches * 12 inches rectangle, make and do not have surfactant between each limit and quadrant.The Permeability net is generally can supply fibrous low density polyethylene (LDPE) (LDPE or the LLDPE) material that retail trader is purchased from sewed product.With composition dries.4 oz/yd onesize with this net will be cut into ²Polyester cotton be placed on that this is fusible online.The basic weight of polyester cotton is 4 oz/yd ², be that about 30 microns polyester fiber constitutes by average diameter, by can be from Stearns Textiles, the Mountain Mist Extra Heavy Batting #205 binding agent bonding that Cincinnati, OH are purchased.Fibrous nonwoven layer is that the basic weight of 55% cellulose and 45% is the Hydroentangled mixture of the polyester (can be from TheTexwipe Company, Saddle River, NJ is purchased with Technicloth II) of about 65gsm, and this nonwoven layers is placed fusible off the net.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of Sentinel Model 808 heat sealing machines of MA is being enough to polyester cotton melted and is flowing under the temperature and pressure that forms fully sealing in the ground floor with rectangle pane glass shape with these layers involution together, and it is sufficient depressing sealing 6-10 second at about 370 temperature and 30psi machine usually.Continuous involution around at the edge, the pane cross portion that on each X and Y direction a width to be arranged all be about 2mm.The care composition of 5 gram embodiment 64 is brushed on these articles for use, and each side is brushed the consumption of half, with the articles for use after drying, then with its finishing and fillet, stores standby then.

Embodiment 118-119

Skin conditioning composition with embodiment 66 and 67 prepares representational skin clean and conditioning article by following method.

The cleaning liquid component of embodiment 15 is applied on first substrate, and method is that the substrate with 120mm * 160mm partly is immersed in the body lotion of said composition, increases by 8 grams approximately up to its weight.This substrate is that basic weight is 2 oz/yd ²Polyester cotton, be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.With the substrate drying.Second substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm, and second substrate placed on first substrate.With the ultrasonic sealing machine with these substrate involutions together, sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.4 gram skin conditioning compositions are applied to the both sides of articles for use equably, and method is that to make said composition remain about 60 ℃ raw material storage tank by a slit drum apparatus that is processed with the 1.5mm slit and temperature reinforced.Said composition is cooling rapidly on the articles for use surface, is stored in the packing of metallisation film of sealing it standby.Embodiment 120-124

Skin conditioning composition with embodiment 27-31 prepares representational skin clean and conditioning article by following method.

The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate net is the bulk low-density polyester cotton of air-laid, and second substrate net is added on first substrate continuously, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.It is online three the substrate net identical with second substrate net to be added to second substrate continuously, and it is contacted with second substrate.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.The skin conditioning composition that will pump from hot tank by slit die is by the both sides of slit coating at the substrate net, coating speed is that 3 gram skin conditioning compositions (every side has the coating amount of 140 grams approximately) are arranged on each final articles for use, makes it pass through a cooling fan then so that compositions cooling fast on the outer surface of articles for use.This net is cut into the orthogonal single articles for use of about 120mm * 90mm of fillet.

Embodiment 125-145

Skin conditioning composition with embodiment 32-52 prepares representational skin clean and conditioning article by following method.

The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate net is the bulk low-density cotton of air-laid, and second substrate net is added on first substrate continuously, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.It is online three the substrate net identical with second substrate net to be added to second substrate continuously, and it is contacted with second substrate.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.The skin conditioning composition that will pump from hot tank by slit die is by the both sides of slit coating at the substrate net, coating speed is that 3 gram skin conditioning compositions (every side has the coating amount of 140 grams approximately) are arranged on each final articles for use, makes it pass through a cooling fan then so that compositions cooling fast on the outer surface of articles for use.With the stability of slit coating storage tank continuous stirring with the maintenance emulsion.This net is cut into the orthogonal single articles for use of about 120mm * 90mm of fillet.

Embodiment 146-147

Skin clean and care composition with embodiment 71 and 74 prepare representational skin clean and conditioning article by following method.

First and second substrate all are cut into about 12 inches * 9 inches rectangle.First substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate is that basic weight is 2 oz/yd ²Polyester cotton, be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of Sentinel Model 808 heat sealing machines of MA is being enough to polyester cotton melted and is flowing under the temperature and pressure that forms fully sealing in the ground floor with rectangle pane glass shape with these layers involution together, and it is sufficient depressing sealing 6-10 second at about 370 temperature and 30psi machine usually.Continuous involution around at the edge, the pane cross portion that on each X and Y direction a width to be arranged all be about 2mm.After the articles for use cooling, its finishing into about 11 inches * 8.5 inches, is brushed 10 gram skin cleans and care composition on the outer surface of both sides, each side is brushed the consumption of half approximately.After the composition dries it is stored for future use.

Embodiment 148-149

Skin clean and care composition with embodiment 72 and 73 prepare representational skin clean and conditioning article by following method.

First and second substrate all are cut into about 12 inches * 9 inches rectangle.First substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate is that basic weight is 2 oz/yd ²Polyester cotton, be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.With utilizing the pressing plate hot sealing device as available from Sencorp, Hyannis, the heat seal die of Sentinel Model 808 heat sealing machines of MA is being enough to polyester cotton melted and is flowing under the temperature and pressure that forms fully sealing in the ground floor with rectangle pane glass shape with these layers involution together, and it is sufficient depressing sealing 6-10 second at about 370 temperature and 30psi machine usually.Continuous involution around at the edge, the pane cross portion that on each X and Y direction a width to be arranged all be about 2mm.After the articles for use cooling, it is repaired into about 11 inches * 8.5 inches, with 8 gram cleanings and care composition by slit coating on these articles for use, on each side surface of articles for use, evenly apply 4 gram compositionss with the X-Y table, X-Y table is a programmable control survey system, the monitoring X-Y coordinate control system that comprises hot tank, pump, switch valve, the slit head that is maintained at about 70 ℃ and be used for applicator head.Compositions is cooling fast on the articles for use surface.Then it is stored for future use.

Embodiment 150-152

Preparation comprises the cleaning liquid component of following component:

Component	Embodiment 150	Embodiment 151	Embodiment 152
Component	Embodiment 150	Embodiment 151	Embodiment 152	The 3-sodium laureth sulfate			3.60
C13/C14 methyl branch sodium sulfate	5.00	5.60	4.50	The 3-sodium laureth sulfate			3.60
C13/C14 methyl branch sodium sulfate	5.00	5.60	4.50	The alkane sodium sulfonate		6.40
The alpha-olefin sodium sulfonate			5.20	The alkane sodium sulfonate		6.40
The alpha-olefin sodium sulfonate			5.20	Sodium lauryl sulfate	5.50

Glycerol lauric acid both sexes sodium acetate	4.50	?5.30	?3.65
Glycerol lauric acid both sexes sodium acetate	4.50	?5.30	?3.65	Coconut oleoyl amine MEA	3.55	?3.20	?2.80
Succinic acid	2.80	?5.70	?6.00	Coconut oleoyl amine MEA	3.55	?3.20	?2.80
Succinic acid	2.80	?5.70	?6.00	Sodium succinate	0.10	?0.14	?0.30
Citric acid	3.00	?4.30	?5.00	Sodium succinate	0.10	?0.14	?0.30
Citric acid	3.00	?4.30	?5.00	Sodium citrate	1.60	?1.10	?1.40
Malonic acid	4.00	?2.20		Sodium citrate	1.60	?1.10	?1.40
Malonic acid	4.00	?2.20		Glycerol	10.00	?15.00	?8.50
Palm kernel 12-18 fatty acid	2.00		?3.00	Glycerol	10.00	?15.00	?8.50
Palm kernel 12-18 fatty acid	2.00		?3.00	Spice	1.00	?1.20	?1.00
MgSO ₄-7H ₂O	0.89	?0.90	?0.80	Spice	1.00	?1.20	?1.00
MgSO ₄-7H ₂O	0.89	?0.90	?0.80	Water	54.21	?47.61	?52.25
Salicylic acid	1.85			Water	54.21	?47.61	?52.25
Salicylic acid	1.85			Pure as jade pure		?0.25
Trichloro-symmetrical diphenyl urea		?1.10		Pure as jade pure		?0.25
Trichloro-symmetrical diphenyl urea		?1.10		The 2-mercaptopyridine zinc oxide			?2.00

Cleaning component is brushed on a side of substrate, up to there being 10 gram compositionss to be added on 11 inches * 8.5 inches the part.This substrate is that basic weight is 2 oz/yd ²Polyester cotton, be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.With first substrate drying.With the ultrasonic sealing machine second substrate layer is pressed on the untreated side of first substrate, sealer is sealed to and comprises that inter-network is the dot pattern of the seal point of 4mm every the equally distributed diameter of 2cm.Second substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.The skin conditioning composition of embodiment 19 is coated in equably by slit on the whole surface of second substrate, coating speed be have on each articles for use 3 the gram compositionss, make its cooling after, package spare.These articles for use have persistent antiviral, antifungal and antibacterial activity to Gram-negative and positive microorganism, can bubble well, and gentle to skin.Embodiment 153

Be evenly dispersed on the bulked cotton with the cleaning component of hands with 4 gram embodiment 11, the basic weight of this polyester cotton is 4 oz/yd ², being cut to 130mm * 175mm, it comprises that average diameter is about 30 microns polyester fiber, by can be from Stearns Textiles, the Mountain Mist Extra Heavy Batting #205 binding agent bonding that Cincinnati, OH are purchased.Fibrous nonwoven layer is that the basic weight of 55% cellulose and 45% is that the polyester of about 65gsm (can be from TheTexwipe Company, Saddle River, NJ is purchased with Technicloth II) Hydroentangled mixture, this nonwoven layers is placed on the side that is coated with surfactant of polyester cotton.With the link type seal plate with these layers involution together, this junction panel uses the not plate of heating, wherein has along the storage tank of the equally distributed reversed stream tube shape of hexagonal mesh pattern, and the base diameter of cannula-like storage tank is about 1.2cm, and its centre-to-centre spacing is about 1.5cm.The confined area between the recess is not outwards given prominence to several millimeters on the hot plate, forms to be communicated with ridge.Hot plate has the water jacket of the ridge precision-fit on the confined area with hot plate not.Hot plate contacts with cellulose/polyester substrate, with the pressing plate hot sealing device as available from Sencorp, Hyannis, Sentinel Model 808 heat sealing machines of MA seal.The non-final articles for use that obtain all have features of terrain in both sides, help to bubble, and also are easy to hold, and are easy in use slide on skin surface.These articles for use are cut into the rectangle of about 120mm * 160mm.

Preparing following reversed-phase emulsion paste and these articles for use uses together:

Component	％
Component	％	PEG30 dimerization hydroxy stearic acid ester	3.0
SEFA?cottonate	20.0	PEG30 dimerization hydroxy stearic acid ester	3.0
SEFA?cottonate	20.0	Vaseline	4.0
Three (two dodecyne acid esters) (Tribenin)	5.0	Vaseline	4.0
Three (two dodecyne acid esters) (Tribenin)	5.0	C10-C30 cholesterol/lanosterol ester	13.0
The SEFA behenic acid	5.0	C10-C30 cholesterol/lanosterol ester	13.0
The SEFA behenic acid	5.0	Glycerol	50.0

When stirring, liposoluble constituent is heated to 70 ℃.Under vigorous stirring, slowly add glycerol.Said composition is homogenized.Bogging down area on the cellulose/polyester side of articles for use sucks the skin condition reversed-phase emulsion of 3 gram heat and sticks with paste, and compositions is cooled to semi-solid the paste fast.This articles for use packing back is standby.Embodiment 154-158

Skin conditioning composition with embodiment 19,29,34,55 and 60 prepares representational skin condition articles for use by following method.

The method that care composition is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four bands that width is 5mm of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of compositions is that 3 gram compositionss are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second net is the bulk low-density polyester cotton of air-laid, and second net is added on first substrate continuously, makes a side contacts that does not contain skin conditioning composition of itself and first substrate.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 160mm of fillet, 51 seal points are arranged on each articles for use altogether approximately.

Embodiment 159-163

Skin conditioning composition with embodiment 19,28,34,55 and 69 prepares representational skin condition articles for use by following method.

The method that care composition is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four bands that width is 5mm of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of compositions is that 1.1 gram compositionss are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second net is the bulk low-density cotton of air-laid, and second net is added on first substrate continuously, makes a side contacts that does not contain skin conditioning composition of itself and first substrate.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 90mm of fillet, 51 seal points are arranged on each articles for use altogether approximately.These articles for use can be applied on the less skin part easily, for example, and face, elbow, neck and/or foot.

Embodiment 164

Prepare representational skin cleaning article with following method.

The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 0.40 gram cleaning component is arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate net is the bulk low-density cotton of air-laid, and second substrate net is added on first substrate continuously, and it is contacted with surfactant layer.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.It is online three the substrate net identical with second substrate net to be added to second substrate continuously, and it is contacted with second substrate.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 90mm of fillet.

Embodiment 165-169

Skin conditioning composition with embodiment 19,28,34,55 and 69 prepares representational skin clean and conditioning article.

The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 0.52 gram cleaning component is arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate net is the bulk low-density cotton of air-laid, and second substrate net is added on first substrate continuously, and it is contacted with surfactant layer.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.It is online three the substrate net identical with second substrate net to be added to second substrate continuously, and it is contacted with second substrate.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.The skin conditioning composition that will pump from hot tank by slit die is by the both sides of slit coating at the substrate net, coating speed is that 1.25 gram skin conditioning compositions (every side has the coating amount of 55gsm approximately) are arranged on each final articles for use, makes it pass through a cooling fan then so that compositions cooling fast on the outer surface of articles for use.This net is cut into the orthogonal single articles for use of about 120mm * 90mm of fillet.

Embodiment 170

Prepare representational skin clean and conditioning article (apparatus) bag with following method.

The preparation skin cleaning article.The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate net is the bulk low-density cotton of air-laid, and second substrate net is added on first substrate continuously, and it is contacted with the layer that contains surfactant.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 480mm of fillet.

Preparation skin condition articles for use.The method that the care composition of embodiment 34 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four bands that width is 5mm of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of compositions is that 3 gram compositionss are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second net is the bulk low-density cotton of air-laid, and second net is added on first substrate continuously, makes a side contacts that does not contain skin conditioning composition of itself and first substrate.Polyester cotton comprises the bicomponent fibre of PET fiber, 35% 3 Denier with PET core and PE skin of 30% 15 Denier and the mixture of 35% the bicomponent fibre with 10 Denier that same core one skin (core-sheath) forms, and its basic weight is 100g/m ²(gsm), these nets are added in the ultrasonic sealing machine continuously, sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 160mm of fillet, 51 seal points are arranged on each articles for use altogether approximately.

Skin cleaning article and skin condition articles for use are packaged together in the packaging bag.

Embodiment 171

The preparation skin cleaning article.The method that the cleaning component of embodiment 11 is applied on the side of first substrate is: it is extruded by coating head continuously, become along the 20mm of being separated by respectively, the 40mm of net width measure and four lines of 20mm, make each side of net that the pair of parallel line all be arranged.The extruded velocity of cleaning component is that 4.4 gram cleaning component are arranged on each final articles for use.This substrate is the spunlaced mixture of the PET fiber of 70% artificial silk and 30%, and with styrene butadiene binding agent bonding, it is the hole of about 2mm that the waterpower punching forms diameter, and its basic weight is about 70gsm.Second substrate net is the bulk low-density cotton of air-laid, and second substrate net is added on first substrate continuously, and it is contacted with surfactant layer.The basic weight of polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..Can think that this polyester cotton is a hot adhesion, not use binding agent, its coverage rate of always swiping is about 22%.These nets are added in the ultrasonic sealing machine continuously, and sealer is sealed to and comprises that the equally distributed diameter of inter-network is the dot pattern of the seal point of 4mm.This net is cut into the orthogonal single articles for use of about 120mm * 480mm of fillet.

Preparation skin condition articles for use.The substrate for preparing Hydroentangled fibre blend, a side of this substrate has more soft more fine-titred fiber, and its second side has thicker fiber.The method for preparing this substrate is: with two basic weights all is that the net of the polyester that comprises 10 Denier (PET) fiber of about 20gsm carries out air-laid, and net is at another above net.Diameter is about 100 microns, is added to continuously on these two fleeces as the 3rd net every the polypropylene plain weave beaujolais net of about 0.8cm edge with lace.All be that the 4th net of the polyester fiber that comprises 3 Denier of about 20gsm and the 5th net air-laid are at this online face with basic weight.These nets are fixed in the net arrangement after Hydroentangled, and being dried on drying cylinder does not have moisture, and because plain weave beaujolais lax, can produce about 20% contraction.The water-soluble acrylic acid bonding copolymer that will hang down Tg (about 5 ℃) with the wet adding speed of about 7gsm by finish roll is added to the crude fibre side of net, and is dry then.The skin conditioning composition of embodiment 21 is coated in equably by slit on the both sides of net, and coating speed is to be about 25gsm on each side.With hot shears hair roller the substrate net is cut into the orthogonal single articles for use of about 120mm * 100mm of fillet, when these articles for use of cutting, plain weave beaujolais fiber slightly bounces back from its sideline.

Embodiment 172

Prepare first side.The ground floor of first side of preparation is a kind of polyester cotton, and the basic weight of this polyester cotton is 2 oz/yd ², be that the mixture of the fiber of about 23 microns and 40 microns constitutes by average diameter, at least some fibers are corrugated.The thickness of the polyester cotton of measuring under 5gsi. is about 0.23in..The saturating rate of the gas of this polyester cotton is about 1270cfm/ft ², its foam permeability critical pressure is about 2.7cm H ₂O.Can think that this polyester cotton is a hot adhesion, does not use binding agent.This polyester cotton is cut into 10 square inches.The second layer of first side of preparation is the thin slice of 10 square inches micropore 100 order formed films, and this is to form by waterpower punching under high pressure on the drum barrel that includes 100 order forming screens (for example, be disclosed in the United States Patent (USP) 4629643 forming screen).This thin slice is placed above the ground floor, make to protrude on the side direction of hole and place.With 25 the gram embodiment 1 skin cleansing compositions place first side in the heart.Smooth slightly said composition, making it become thickness is that about 0.5 inch and diameter are several inches shapes.To be placed on the said composition with onesize 10 square inches the impermeability polyethylene film of ground floor.The skin conditioning compositions of 25 gram embodiment 63 are formed and the same shape of Cleasing compositions, with the same X-Y position of surfactant on place this above film this care composition.When placing micropore and macropore shaping rete (also being disclosed in the United States Patent (USP) 4629643), the protrusion side that makes macropore is towards compositions, and the protrusion side that makes micropore is towards last placement.Also this layer is cut into 10 square inches.Last one deck of preparation is the Hydroentangled mixture with fiber of soft, fine denier fiber.The method for preparing this layer is: with two basic weights all is that the net of the polyester that comprises 3 Denier (PET) fiber of about 17gsm carries out air-laid, and net is at another above net.Bulk plain weave beaujolais net has in one direction, and diameter is about 100 microns fiber, and to be used in diameter on another direction be about 40 microns fiber edge lace, inlay a lace every about 1.0cm, this plain weave beaujolais net is added on these two fleeces continuously as the 3rd net.Such net can be from Conwed Plastics, Minneapolis, and MN is purchased.All be that the 4th net of the polyester fiber that comprises 3 Denier of about 17gsm and the 5th net air-laid are at this online face with basic weight.These nets are fixed in the net arrangement after Hydroentangled, and being dried on drying cylinder does not have moisture, and because net tension force that in Hydroentangled and dry run, produces and plain weave beaujolais lax subsequently, this net meeting is wrinkling.This layer cutting is placed on some other above layer into about 10 inches * 10 inches.With pressing plate type hot sealing device as available from Sencorp, Hyannis, Sentinel Model 808 heat sealing machines of MA are with these layers heat-sealing.Use a groove (not heating) base plate, its shape is used to hold compositions, uses groove (heating) top board that mates with base plate around the circular seal frame to seal.General air-proof condition is: 300 ℃ stopped about 3.5 seconds down, and the supply pressure of machine is about 30psig, and still, these conditions change with the water-tight equipment that uses.To package spare after the articles for use finishing.

Claims

1. A substantially dry disposable personal care product suitable for cleaning, characterized in that the product comprises:

a) a water insoluble substrate comprising:

1) a soft first layer having a total scratch coverage value of less than about 17%; and

2) a second layer of exfoliation placed adjacent to the first layer, wherein the second layer has a total scratch coverage value of from about 17% to about 70%; and

b) A cleansing component positioned adjacent to the first and second layers, wherein the cleansing component comprises from about 10% to about 1000% by weight of the water-insoluble substrate of a lathering surfactant.

2. The article of claim 1, wherein the first and/or second layer comprises fibers selected from natural fibres, synthetic fibres, and mixtures thereof.

3. The article of claim 1, wherein the first and second layers comprise those selected from nonwoven and woven fabrics.

4. The article of claim 3, wherein the nonwoven is selected from the group consisting of batting, formed films, cellulosic nonwovens and mixtures thereof.

5. The article of claim 1, wherein the cleansing component is disposed between said first and second layers.

6. The article of claim 1, wherein said first and second layers are point bonded to each other.

7. A method for cleaning skin and hair, the method comprising the steps of:

a) wetting the article of claim 1; and

b) Bringing the wetted article into contact with the skin or hair.

8. A substantially dry disposable personal care product, characterized in that the product comprises:

a) a water insoluble substrate comprising:

1) a soft first layer with an average surface depth value of less than about 8; and

2) an exfoliated second layer placed adjacent to the first layer, wherein the second layer has an average surface depth value of from about 8 to about 80; and

9. A substantially dry disposable personal care product suitable for conditioning, characterized in that the product comprises:

a) a water insoluble substrate comprising:

2) exfoliating the second layer, wherein the second layer has a total scratch coverage value of about 17% to about 70%; and

a) A therapeutic benefit component placed adjacent to said water insoluble substrate, wherein the component comprises from about 10% to about 1000% by weight of the water insoluble substrate of a therapeutic benefit agent.

10. A substantially dry disposable personal care product comprising:

a) a water insoluble substrate comprising:

b) A therapeutic benefit component positioned adjacent to said water insoluble substrate, wherein the composition comprises from about 10% to about 1000% by weight of the water insoluble substrate of a therapeutic benefit agent.

11. A personal care kit comprising the product of claim 1 and an additional product comprising a substrate and a therapeutic benefit component.