CN116686609A - Agricultural nano mulch film and its manufacturing method - Google Patents
Agricultural nano mulch film and its manufacturing method Download PDFInfo
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Abstract
本发明涉及一种农用奈米地膜及其制造方法,该地膜内部均匀分散有奈米化之奈米肥料与奈米植纤或/及植物奈米碳纤或/及奈米竹碳,各元素粒径均值为在45微米以下;取材具降解作用之脂化生成材料,混合具奈米尺度之干式肥料干粒与植物干粒,经热作淋膜,以生成内部上、下层次,均匀分布有奈米肥料或/及奈米植纤之地膜,农用时由着地阴面往上依降解层面,岐分时程渐进释出所含植栽养分予土壤。本发明为提供农用过程中,可依照降解层次岐分时程,依序渐进释解或/及转化植栽需求养分,并可避免杂草光合生长。
The present invention relates to an agricultural nanometer mulch film and a manufacturing method thereof. The mulch film is uniformly dispersed with nanometerized fertilizer and nano plant fiber or/and plant nano carbon fiber or/and nano bamboo carbon. The average diameter is below 45 microns; the material is derived from lipid-forming materials with degradative effects, mixed with nano-scale dry fertilizer dry particles and plant dry particles, and coated with heat to form internal upper and lower layers, which are evenly distributed The mulch film with nano-fertilizer or/and nano-planted fiber, when used in agriculture, gradually releases the contained planting nutrients to the soil from the shady side of the ground to the top according to the degradable layer. The present invention provides that during the agricultural process, the nutrients required for planting can be sequentially and/or transformed according to the time course of the degradation levels, and the photosynthetic growth of weeds can be avoided.
Description
技术领域technical field
本发明涉及一种农用奈米地膜及其制造方法,The invention relates to an agricultural nano-mulch film and a manufacturing method thereof.
背景技术Background technique
农业植栽为了避免杂草丛生,以在田股表面避开植栽位置覆盖有地膜,地膜的作用除了避免杂草丛生之外,更具有土壤水分维持,以及避免昆虫滋长。In order to avoid overgrown weeds in agricultural planting, the surface of the field is covered with mulch film to avoid the planting position. The function of the mulch film is not only to prevent overgrown weeds, but also to maintain soil moisture and prevent the growth of insects.
传统使用的地膜为利用高分子塑化材料吹制后切割成膜,由于该材料为塑化聚合物,使用后会对土壤造成塑化污染,新进采用具降解作用的材料所制成的地膜,可大幅改善对土壤的塑化污染,更有加入植物碎化材,期许在地膜降解过程中释出,经转化为植栽需求养分,该碎化材粒径大明显为肉眼可见,相对地膜的厚度为薄状,因此该粒径与地膜的厚度比例后粒径为大,制成的地膜表面会形成有砂孔或植物纤维脱絮的状况,所形成的缺陷造成张力弱点,大幅影响地膜的抗拉力,另释放出植物纤维后,尚须经由细菌的侵蚀才能以分解转化出养分元素。The traditionally used mulch is blown by polymer plastic material and then cut into film. Since the material is a plasticized polymer, it will cause plastic pollution to the soil after use. The new mulch is made of degradable materials. , can greatly improve the plasticization pollution of the soil, and add plant crushed materials, which are expected to be released during the degradation process of the plastic film and transformed into nutrients needed for planting. The particle size of the crushed materials is obviously large and visible to the naked eye. The thickness of the film is thin, so the particle size is larger after the ratio of the particle size to the thickness of the mulch film. Sand holes or plant fiber deflocculation will be formed on the surface of the mulch film. The formed defects cause tension weakness and greatly affect the mulch film. The tensile strength is high, and after the plant fibers are released, they must be eroded by bacteria to decompose and transform nutrients.
有关习用地膜的制作,有采空气压力吹制,热熔的基材受到空气压力扩张为薄化,经裁剪成膜如塑料袋的制作方式,由于该植物碎粒相对地膜的厚度比较下为大粒径,且该尺寸在约十分之一比上膜厚的情况下,则因该植物纤维本体不具展流能力,与热熔基材的接触表面,会因变形率不同而发生剥离状况,使该膜面破孔,即使该比例不足以发生破孔,但在成膜表面,也会有因该纤维本体结构外露,在收卷或铺地的操作外力介入即脱絮,另若未达脱絮状况,所凸伸膜面的纤维也会造成膜面粗糙。Regarding the production of conventional mulch, air pressure blowing is adopted, and the hot-melt substrate is expanded by air pressure to become thinner, and then cut into a film like a plastic bag. Because the thickness of the plant debris is relatively large compared to the thickness of the mulch particle size, and the size is about one-tenth of the thickness of the upper film, because the plant fiber body does not have the ability to spread the flow, and the contact surface with the hot-melt substrate will be peeled off due to the difference in deformation rate. Make the film surface perforate, even if the ratio is not enough to cause perforation, but on the surface of the film, the structure of the main body of the fiber will be exposed, and it will be deflocculated when the external force intervenes in the operation of winding or laying the floor. In the case of deflocculation, the fibers protruding from the membrane surface will also cause the membrane surface to be rough.
另由于纤维粗大与膜厚比值小,所占据在膜面的容积空间大,相对在膜层表体或内部皆因此而形成膜层结构缺陷,明显造成基材分子间的链结。In addition, due to the small ratio of the fiber thickness to the film thickness, the volume space occupied on the film surface is large, and the structure defect of the film layer is formed on the surface or inside of the film layer, which obviously causes the link between the substrate molecules.
该地膜的制作,料有采热压延成膜,以及热淋膜方式成膜,其中以热淋膜方便制造薄状厚度,该方式为先前经淋膜作业或热膜状态中,藉由如图1所示,由具夹压的辗轮R实施热辗以重整分子键结和更薄化定尺,轧压过程中,热膜状态的地膜800内部所含植物碎粒21内部存在有空气,经辗轮R辗压后空气会外流,并经压力平衡作用及阻尼因素,常态上所挤出的气泡22会被移转到地膜800的表面,则在该气泡22所属地膜800的断面形成肉厚的缺陷而产生张力弱点,不利于抗拉,失去张力强度。The production of the mulch film is made of hot calendering and hot film forming. Among them, the hot film is used to make thin thickness. As shown in 1, hot rolling is carried out by the rolling wheel R with clamping to reform the molecular bond and make the size thinner. During the rolling process, there is air in the plant fragments 21 contained in the plastic film 800 in the hot film state. , the air will flow out after being rolled by the rolling wheel R, and through the pressure balance and damping factors, the normally extruded air bubbles 22 will be transferred to the surface of the plastic film 800, and then formed on the section of the plastic film 800 to which the air bubbles 22 belong The defect of meat thickness produces tension weakness, which is not conducive to tensile strength and loses tension strength.
如图2所示,由于该植物碎粒21无论是以吹制或淋膜辗压制作,所处位置常见会位居在地膜800的表面,因此由该植物碎粒21所占据的地膜800断面,也形成厚度的残缺,而发生抗拉的弱点。As shown in FIG. 2 , since the plant crumbs 21 are generally located on the surface of the mulch 800 no matter whether they are made by blowing or laminating and rolling, the section of the mulch 800 occupied by the plant crumbs 21 , Also form the incomplete thickness, and the weakness of tensile strength occurs.
请再参阅图3所示,在地膜800内部邻近的二植物碎粒21,由于粒径大占据大的容积空间,则二植物碎粒21邻靠区间,对位于地膜800水平断面位置,相同形成地膜800的聚合缺陷,而产生一抗拉弱点,以及该植物碎粒21若为大量,在吹制过程中,也因上述的弱点存在而吹破,另植物碎粒21颗粒为大,等待地膜800降解接触土壤后,尚需等候转化时间才能获得需求滋养元素,但该时程可能延后过植栽熟成采收期。Please refer to Fig. 3 again, the adjacent two plant particles 21 inside the plastic film 800 occupy a large volume space due to their large particle size, so the two plant particles 21 are adjacent to the interval and are located at the horizontal section of the plastic film 800. The aggregation defect of the mulch film 800 produces a tensile weakness, and if the plant crumbs 21 are in large quantities, they will be blown apart due to the existence of the above-mentioned weak points during the blowing process. After the 800 degrades and touches the soil, it still needs to wait for the transformation time to obtain the required nourishing elements, but this time course may be delayed beyond the harvesting period of planting maturity.
发明内容Contents of the invention
本发明的目的在于提供一种农用奈米地膜及其制造方法,其为提供农用过程中,可依照降解层次岐分时程,依序渐进释解或/及转化植栽需求养分,并可避免杂草光合生长。The purpose of the present invention is to provide an agricultural nano-mulch film and its manufacturing method, which can gradually explain or/and transform the nutrients required for planting in order to provide agricultural processes according to the time-separation of degradation levels, and can avoid Photosynthetic growth of weeds.
本发明是这样实现的,一种农用奈米地膜制造方法,其特征在于它包含有:一整备阶段,该整备阶段进一步包含有:(1)取材肥料干粒,经一干式奈米催化作业奈米化为奈米肥料之后进行一积囤;(2)取材植物干粒,经一干式奈米催化作业奈米化为奈米植纤之后进行所属一积囤;(3)取材降解材料,进行所属一积囤;一造粒阶段,将上述奈米肥料、奈米植纤、降解材料,分别经所属调配操作调配比例后集合执行一混合操作,再经一热熔挤制作业条状挤出执行切粒操作以生成母粒;一成膜阶段,取上述母粒经一热熔挤进操作,末端执行一淋膜作业,经一轧膜及冷却定型作业成型。The present invention is achieved in this way, a method for manufacturing agricultural nano-films, characterized in that it includes: a preparation stage, which further includes: (1) take dry fertilizer particles, through a dry nano-catalyzed operation After nano-fertilizers are converted into nano-fertilizers, a stockpile is carried out; (2) dry plant particles are taken as materials, and after a dry-type nano-catalysis operation, nano-planting is carried out after nano-planting; (3) materials are collected from degraded materials , carry out the first hoarding; the first granulation stage, the above-mentioned nano-fertilizers, nano-fibers, and degradable materials are assembled and performed in a mixing operation after the respective deployment operations and deployment ratios, and then a hot-melt extrusion operation is performed to make strips Extrusion performs pelletizing operation to produce master batches; in the first film forming stage, the above master batches are taken and subjected to a hot-melt extrusion operation, and a coating operation is performed at the end, and a film rolling and cooling and shaping operation are performed to form.
所述的该材料的容积比例为:降解材料取用50~75%;肥料干粒取用3~8%;植物干粒取用1~8%。The volume ratio of the material is as follows: 50-75% of the degradable material; 3-8% of the dry grain of the fertilizer; 1-8% of the dry grain of the plant.
所述的该混合操作同步混合有如下填充物:奈米氧化钙0.1~3%;滑石粉15~25%。In the mixing operation, the following fillers are mixed synchronously: 0.1-3% of nano-calcium oxide; 15-25% of talcum powder.
所述的该混合操作同步混合有如下追加改善剂:润滑剂0.5~1%;分散剂0.04~1.2%;扩链剂0.5~3%。In the mixing operation, the following additional improvers are mixed synchronously: 0.5-1% lubricant; 0.04-1.2% dispersant; 0.5-3% chain extender.
所述的肥料干粒与植物干粒经干式奈米催化作业催化后的粒径均值为在45微米以下。The average particle size of the dry fertilizer granules and dry plant granules catalyzed by the dry nano-catalysis operation is below 45 microns.
所述的该降解材料取材为聚对苯二甲酸丁酯(PBAT)。The said degradable material is made of polybutylene terephthalate (PBAT).
所述的该肥料干粒取材磷酸钾。The dry granules of the fertilizer are made of potassium phosphate.
所述的该植物干粒取材为具二氧化硅之植干。Said dry plant particles are obtained from plant stems with silicon dioxide.
所述的整备阶段复追加搭配有植物碳碎粒,经干式奈米催化作业完成积囤,施配比例为3~20%。In the preparation stage, plant carbon granules are additionally mixed, and the stockpiling is completed through dry nano-catalysis operation, and the proportion of dispensing is 3-20%.
所述的整备阶段或混合操作程序中,复追加搭配有奈米竹碳,施配比例为2~20%。In the preparation stage or the mixing operation procedure, the nano-bamboo carbon is additionally mixed, and the mixing ratio is 2-20%.
所述的该干式奈米催化作业为利用一压力缸体提供加工料进出,过程中利用所发生的干式高速流体,以发生高速动量,对加工物料执行奈米尺度之干式催化。The dry nano-catalysis operation is to use a pressure cylinder to provide processing materials in and out, and use the dry high-speed fluid generated during the process to generate high-speed momentum to perform nano-scale dry catalysis on the processing materials.
一种农用奈米地膜,其为由上述之中任何一项所述的制法所制成的地膜。An agricultural nanometer mulching film, which is a mulching film made by any one of the methods described above.
所述的该地膜之厚度为在0.05~1.2mm。The thickness of the said plastic film is 0.05-1.2mm.
所述的该地膜内部均匀分散有奈米化之奈米肥料与奈米植纤或/及植物奈米碳纤或/及奈米竹碳,各元素粒径均值为在45微米以下。The inside of the mulch film is uniformly dispersed with nano-sized nano-fertilizer and nano-planted fiber or/and plant nano-carbon fiber or/and nano-bamboo carbon, and the average particle size of each element is below 45 microns.
本发明农用奈米地膜及其制造方法,为提供农用过程中,可依照降解层次岐分时程,依序渐进释解或/及转化植栽需求养分,并可避免杂草光合生长之地膜及其制造方法,一整备阶段A将肥料干粒与植物干粒,经干式气动催化,使其粒径形成奈米化,配合所备置的降解材料,经一造粒阶段执行均匀混合,再经一热熔挤制作业以生成母粒,利用一成膜阶段将上述母粒以淋膜方式执行地膜成型,该地膜于农用时,具渐进释出养分。The agricultural nano-mulch film and its manufacturing method of the present invention are to provide a film and film that can gradually explain or/and transform the nutrients required for planting in accordance with the time course of degradation levels in the agricultural process, and can avoid the photosynthetic growth of weeds. Its manufacturing method, in the first preparation stage A, the dry fertilizer granules and the dry plant granules are subjected to dry pneumatic catalysis to make the particle size nanometer, and the degradable materials prepared are mixed uniformly through a granulation stage, and then After a hot-melt extrusion process to produce the masterbatch, the above-mentioned masterbatch is used to form a mulch film in a film-forming stage. When the mulch film is used in agriculture, it has a gradual release of nutrients.
本发明为上述肥料干粒的材料取用比例为3~8%,植物干粒取用比例为1~8%,降解材料取用比例为50~75%,并混合有填充物,该填充物有滑石粉、奈米氧化钙、以及大量奈米碳黑。According to the present invention, the ratio of the materials used for the above-mentioned dry fertilizer granules is 3-8%, the ratio used for the dried plant particles is 1-8%, and the ratio used for the degraded materials is 50-75%, and the fillers are mixed with the fillers. There are talcum powder, nano-calcium oxide, and a large amount of nano-carbon black.
本发明为在混合操作的过程中,可追加有改散剂,如润滑剂、分散剂或扩链剂。In the present invention, during the mixing operation, a dispersant such as a lubricant, a dispersant or a chain extender may be added.
本发明为上述各材料粒径的均质为在45微米以下。In the present invention, the homogeneity of the particle diameters of the above-mentioned materials is below 45 microns.
本发明为该整备阶段所备置的奈米植纤之中,填充有2%以上的奈米竹碳,该竹碳粒径为在45微米以下。In the present invention, more than 2% of the nano-bamboo carbon is filled in the nano-planted fiber prepared in the preparation stage, and the particle size of the bamboo carbon is below 45 microns.
本发明为其中该降解材料取材为聚对苯二甲酸丁酯(PBAT),以及肥料干粒取材为磷酸钾,植物干粒取材为二氧化硅之植干如稻谷。In the present invention, the degradable material is polybutylene terephthalate (PBAT), the fertilizer dry particles are potassium phosphate, and the plant dry particles are silicon dioxide dry plants such as rice.
本发明为在整备阶段,另备置有奈米化的碳黑,经造粒阶段、成膜阶段成形后,具有光阻效应,避免地膜遮覆区间杂草光合生长。In the present invention, in the preparation stage, nano-sized carbon black is additionally prepared, and after being formed in the granulation stage and the film-forming stage, it has a photoresist effect and prevents the photosynthetic growth of weeds in the film-covered area.
本发明为该干式奈米催化作业,是利用高能流体及高速叶片,在一压力缸内部产生高速搅动能量,以对加工物执行干式奈米化之工程。The present invention is the dry-type nano-catalysis operation, which uses high-energy fluid and high-speed blades to generate high-speed stirring energy inside a pressure cylinder to perform dry-type nanometerization of processed objects.
附图说明Description of drawings
图1为习用地膜的结构示意图。Figure 1 is a schematic diagram of the structure of a conventional plastic film.
图2为习用地膜的结构示意图之一。Figure 2 is one of the structural schematic diagrams of conventional mulch films.
图3为习用地膜的结构示意图之二。Fig. 3 is the second structural schematic diagram of conventional mulch film.
图4为本发明制作流程示意图。Fig. 4 is a schematic diagram of the production process of the present invention.
图5为本发明淋膜作业操作系统简示图。Fig. 5 is a schematic diagram of the coating operation system of the present invention.
图6为本发明制作流程示意图之一。Fig. 6 is one of the schematic diagrams of the production process of the present invention.
图7为本发明地膜农用过程作用示意图。Fig. 7 is a schematic diagram of the agricultural process of plastic film according to the present invention.
符号说明:Symbol Description:
肥料干粒10 干式奈米催化作业11 积囤12Fertilizer Dry Granules 10 Dry Nano Catalytic Operation 11 Hoarding 12
调配操作13 奈米肥料100 第一降解层面101Deployment Operation 13 Nano Fertilizer 100 First Degradation Level 101
第二降解层面102 第三降解层面103 第四降解层面104Second degradation level 102 Third degradation level 103 Fourth degradation level 104
植物干粒20 植物碎粒21 气泡22Dried plant grains 20 Plant crumbs 21 Air bubbles 22
奈米植纤200 降解材料30 降解本材300Nano-planted fiber 200 Degradable material 30 Degradable material 300
植物碳碎粒40 奈米碳纤400 混合操作50Vegetable Carbon Granules 40 Nano Carbon Fibers 400 Mixing Operations 50
热熔挤制作业60 冷却61 切粒操作62Hot melt extrusion operation60 Cooling61 Pelletizing operation62
母粒600 热熔挤进操作70 喂给机头71Masterbatch 600 Hot-melt extrusion operation 70 Feeding machine head 71
淋膜作业80 冷却定型作业81 淋膜押头82Laminating operation 80 Cooling and shaping operation 81 Laminating head 82
移载单元83 轧膜装置84 调整单元85Transfer unit 83 Film rolling device 84 Adjustment unit 85
冷却装置86 卷收装置87 地膜800Cooling device 86 Retracting device 87 Mulching film 800
植土90 整备阶段A 造粒阶段BPlanting soil 90 Preparation stage A Granulation stage B
成膜阶段C 辗轮R 奈米竹碳201Film-forming stage C Roller R Nano Bamboo Carbon 201
具体实施方式Detailed ways
本发明农用奈米地膜及其制造方法,为提供农用过程中,可依照降解层次岐分时程,依序渐进释解或/及转化所内含植栽需求养分,并可避免杂草光合生长之地膜及其制造方法,有关本发明之地膜制作方式如图4所示,主要分设有整备阶段A、造粒阶段B、成膜阶段C,其中该整备阶段A备置有肥料干粒10、植物干粒20与降解材料30,降解材料30取材PBAT进行积囤12,其中肥料干粒10为干状的材料,植物干粒20为植物干料经碎化之碎粒,分别经由干式奈米催化作业11,将之粒径催化为奈米尺度,并分别形成奈米肥料100与奈米植纤200,该干式奈米催化作业11为利用气体高速撞击方式所操作,完成后各别执行积囤12,上述各元素奈米化的程度为在45微米以下。The agricultural nano-mulch film and its manufacturing method provided by the present invention can gradually explain or/and transform the nutrients required for planting in the process of agricultural use according to the time course of degradation levels, and can avoid the photosynthetic growth of weeds The mulch film and its manufacturing method, the mulch film production method of the present invention is as shown in Figure 4, mainly divided into a preparation stage A, a granulation stage B, and a film-forming stage C, wherein the preparation stage A is equipped with dry fertilizer granules 10, Dry plant granules 20 and degradable material 30, degradable material 30 is made from PBAT for stockpiling 12, wherein the dry fertilizer granules 10 are dry materials, and the dry plant granules 20 are crushed granules of dry plant materials, which are respectively passed through the dry filter. Rice catalysis operation 11 catalyzes the particle size to nanoscale, and forms nano-fertilizer 100 and nano-fiber planting 200 respectively. The dry-type nano-catalysis operation 11 is operated by high-speed impact of gas. After completion, each Execution of stockpiling 12, the degree of nanonization of the above-mentioned elements is below 45 microns.
造粒阶段B为经由调配操作13,依比例分别分配上述阶段所完成的干式奈米肥料100,奈米植纤200,与降解材料30,从积囤12位置取得配置量之后集体进行混合操作50,其中该降解材料30取材容积比例为50~75%,奈米植纤200为取材1~8%,奈米肥料100取材为3~8%,经混合操作50充分混拌后,执行一热熔挤制作业60,热熔挤制作业60可利用双管式的螺旋挤压设备,将上述混合物挤出条状物,该条状物经冷却61操作定型后执行切粒操作62,以生成母粒600。The granulation stage B is to distribute the dry nano-fertilizer 100, nano-fiber planting 200, and degradable material 30 completed in the above-mentioned stages in proportion through the deployment operation 13, and collectively carry out the mixing operation after obtaining the allocation amount from the storage 12 position 50, wherein the volume ratio of the degradable material 30 is 50-75%, the nano-plant fiber 200 is 1-8%, and the nano-fertilizer 100 is 3-8%. After the mixing operation 50 is fully mixed, a Hot-melt extrusion operation 60, hot-melt extrusion operation 60 can utilize twin-pipe screw extrusion equipment to extrude the above-mentioned mixture into strips, and the strips are cooled 61 and then shaped into pellets to perform pelletizing operation 62 to Masterbatch 600 is produced.
一成膜阶段C,取材上述完成之母粒600,经一热熔挤进操作70操作后执行一淋膜作业80,淋膜作业80经一冷却定型作业81后,形成地膜800。In a film forming stage C, the above-mentioned completed masterbatch 600 is obtained, and after a hot-melt extrusion operation 70, a coating operation 80 is performed. After the coating operation 80 undergoes a cooling and shaping operation 81, a plastic film 800 is formed.
上述造粒阶段B的混合操作50程序中,复可追加同以干式催化作业所完成的粉态奈米竹碳201,取材比例为2~20%,与前述各元素集体进行混合操作50及完成共构之母粒600。In the mixing operation 50 program of the above-mentioned granulation stage B, the powdered nano-bamboo carbon 201 completed by the dry catalytic operation can be added again, and the ratio of the material taken is 2-20%, and the mixing operation 50 and Completed the co-structured masterbatch 600.
该奈米竹碳201混合在母粒600的前置作业如上开所述在混合操作过程补入外,也可相仿奈米肥料100等的方式,完备在整备阶段A的程序中,更由于奈米竹碳201不具化合活跃性,也可提前照比例干式混入已完成积囤12的奈米肥料100或奈米植纤200之中。The nano-bamboo carbon 201 is mixed in the pre-operation of the masterbatch 600 as described above and added in the mixing operation process, and it can also be completed in the procedure of the preparation stage A in the same way as the nano-fertilizer 100. Rice Bamboo Carbon 201 is not chemically active, and it can also be dry-mixed into the nano-fertilizer 100 or nano-plant fiber 200 that has been stockpiled 12 in advance according to the proportion.
取上述完备的母粒600执行成膜,在本发明中,由于混合生成物质为奈米化,除了成型过程中可得更佳展流能力外,也可提供制作更薄化的地膜800(在降解材料30本材成膜后张力许可的力度范围内),以及为了定型过程中,可让各素材之间分子键结更紧实,以增加张力强度,因此适合采用淋膜及轧辗方式制作地膜800,其中热熔挤进操作70与淋膜作业80共构为一成膜设备,相关设备执行成膜的工序请参阅如后。The above-mentioned complete masterbatch 600 is taken to form a film. In the present invention, since the mixed product is nano-sized, in addition to better spreading ability during the molding process, it can also provide a thinner film 800 (in the Degradable material 30 within the permissible tension range of the material after film formation), and in order to make the molecular bonds between the materials more tightly during the shaping process to increase the tensile strength, so it is suitable for production by lamination and rolling The mulch film 800, wherein the hot-melt extrusion operation 70 and the laminating operation 80 constitute a film-forming equipment, and the related equipment performs the film-forming process as follows.
如图5所示,该热熔挤进操作70取得上述母粒600经由热熔后,由一喂给机头71产生压力,执行淋膜作业80,淋膜作业80为利用一淋膜押头82形成裸带状的地膜800粗胚,该粗胚经一移载单元83移送到一轧膜装置84,该轧膜装置84为利用辗压方式,藉由调整单元85调整辗轮R的互对间隙,以将制程中的地膜800预先订出厚度,后由一冷却定型作业81完封,该冷却定型作业81可利用该一冷却装置86以平衡温度或吹拂热质方式形成温降的热处理操作,也因此使经过的地膜800分子结构链结更稳定,最后由一卷收装置87执行卷收,即形成本发明目的所完备的地膜800,其成形厚度为在0.05~1.2mm之间。As shown in Figure 5, after the hot-melt extrusion operation 70 obtains the above-mentioned masterbatch 600 through hot-melt, pressure is generated by a feeding head 71, and a coating operation 80 is performed. The coating operation 80 is to use a coating head 82 forms a bare strip-shaped mulch film 800 rough embryo, which is transferred to a film rolling device 84 through a transfer unit 83. The film rolling device 84 uses a rolling method to adjust the interaction between the rollers R by an adjustment unit 85. For the gap, the thickness of the film 800 in the process is pre-determined, and then it is sealed by a cooling and setting operation 81. The cooling and setting operation 81 can use the cooling device 86 to balance the temperature or blow the thermal mass to form a heat treatment operation of temperature drop. , so that the molecular structure of the passing mulching film 800 is more stable, and finally a retracting device 87 executes the rolling, that is, forming the complete mulching film 800 for the purpose of the present invention, and its forming thickness is between 0.05-1.2 mm.
请再参阅图6所示,在本发明制作方法的流程中,可追加混搭有植物碳黑,所应用的取材为植物碳碎粒40,同样经由干式流体催化的干式奈米催化作业11将之奈米化为奈米碳纤400取用比例为3~20%,其尺寸相同或接近奈米肥料100与奈米植纤200,完成后进入一积囤12,在造粒阶段B作业过程,经由所属调配操作13调配约3~8%后与奈米肥料100,奈米植纤200与降解材料30如图4中的比例集体进入混合操作50后,达成造粒阶段B,所得母粒600如图4中的成膜阶段C之操作,执行热熔挤进操作70和淋膜作业80,形成混合有植物碳碎粒40奈米化的地膜800,该植物碳碎粒40奈米化为奈米碳纤400,取材比例3~20%大量均匀分散在生成的地膜800内部产生抗折射功能,利用该奈米碳纤400可阻隔太阳光折射,使覆盖在底面的土壤中杂草幼苗,难以进行光合作用,而可抑制杂草生成,并藉由该色泽为黑色,而能作用为吸光剂的辅助吸收太阳热能,使在地膜下方会受温并保持暖温以利植物生长,尤其在冬季或天冷的地域使用。Please refer to Fig. 6 again, in the flow process of the preparation method of the present invention, plant carbon black can be added and mixed, and the applied material is plant carbon granules 40, and the dry nano-catalysis operation 11 through dry fluid catalysis is also performed. The ratio of taking it into nano carbon fiber 400 is 3 to 20%, and its size is the same as or close to nano fertilizer 100 and nano plant fiber 200. After completion, it enters a stockpile 12 and is in the granulation stage B operation process After blending about 3 to 8% with the nano-fertilizer 100, the nano-fiber planting 200 and the degradable material 30 as shown in Figure 4, after the subordinate deployment operation 13, they collectively enter the mixing operation 50 to reach the granulation stage B, and the obtained masterbatch 600 is as shown in the operation of the film-forming stage C in Figure 4, performing hot-melt extrusion operation 70 and film coating operation 80, forming a plastic film 800 mixed with 40 nanometers of plant carbon particles, and the plant carbon particles 40 nanometers It is carbon nanofiber 400, and the material ratio is 3-20%, and a large amount is evenly dispersed inside the generated mulch film 800 to produce anti-refraction function. The carbon nanofiber 400 can block the refraction of sunlight, making it difficult for weed seedlings to cover the soil on the bottom surface. Carry out photosynthesis, which can inhibit the growth of weeds, and because the color is black, it can act as a light absorbing agent to assist in absorbing solar heat, so that it will be warmed and kept warm under the mulch film to facilitate plant growth, especially in winter Or use in cold areas.
上述填充有大量比例的奈米碳纤400主要目的为提供阻隔太阳光以抑制所覆盖地面的杂草生成,前提在图4中所补给之奈米竹碳201所补入之比例为高的情况下,则藉奈米竹碳201本质类等为碳黑可具隔阻阳光折射能力,而可调降奈米碳纤400的用量比例。The main purpose of the aforementioned carbon nanofibers 400 filled with a large proportion is to block sunlight to suppress the growth of weeds on the covered ground. The premise is that the proportion of the nano-bamboo carbon 201 supplemented in Figure 4 is high. , the use of nano-bamboo carbon 201 as carbon black can block sunlight and refraction, and the proportion of nano-carbon fiber 400 can be adjusted.
请再参阅图7所示,本发明所完成的地膜800于农用时,该阴面覆盖接触到植土90的表面,地膜800所含的降解本材300受到植土90内部所含纳的细菌进入侵蚀,进行组织分化降解为水及二氧化碳。Please refer to FIG. 7 again. When the mulch film 800 completed by the present invention is used in agriculture, the shade covers the surface that touches the plant soil 90, and the degradable material 300 contained in the mulch film 800 is entered by the bacteria contained in the plant soil 90. Erosion, tissue differentiation and degradation into water and carbon dioxide.
该渐进的侵蚀定义为第一降解层面101、第二降解层面102、第三降解层面103、第四降解层面104。The progressive erosion is defined as the first degradation level 101 , the second degradation level 102 , the third degradation level 103 , and the fourth degradation level 104 .
地膜800本质由降解本材300含纳多数分散的奈米植纤200与奈米肥料100,奈米植纤200与奈米肥料100依据地膜800的厚度,随从降解层面所岐分的第一降解层面101、第二降解层面102、第三降解层面103、第四降解层面104……依序被解散,起先第一降解层面101所含纳的奈米肥料100,即依据降解的过程被解散而释放到土壤,此际第二降解层面102以上位于地膜800内部的奈米肥料100及奈米植纤200尚维持原位,当第一降解层面101依首段时程被降解消弥后即进入第二降解层面102,第二降解层面102内部所含的奈米肥料100及奈米植纤200相同被解释而释放到土壤,依序为第三降解层面103及第四降解层面104……,将各层次分别所含纳的奈米肥料100与奈米植纤200依据岐分时程,一一释放给植土90为植栽根部吸收,或经转化为养分供给植栽滋长需求,于是本发明的地膜800,在提供农用的过程中,会依据降解的层次及经过时程,依时程渐序层层发散奈米肥料100与奈米植纤200,提供地膜800农用植栽过程中,对于植土90无须额外施布本发明所具肥料,以及内部在每一层次中所含纳的奈米植纤200,也会依序的渗入植土90之中,经化合转化为植栽养分,具体可看出本发明的地膜800会依农用植栽的时程,依层次降解的时间关系而间续释放肥料及养素,在植栽培植生长到收成时程内的肥料施作必要,有相当正面的帮助,并且该奈米肥料100、奈米植纤200或/及奈米碳纤400为经奈米化为微细的粒径,侵入土让中,容易亲和在土壤的成分内部及快速转化,和易于被植栽根部吸收,以及受到水液或水气的带动,可轻易发散流布于土壤之中,且在地膜800的表面不会造成昔有的缺陷,影响地膜800的机械张力。The nature of the film 800 is degraded by the original material 300 containing a large number of dispersed nano fiber 200 and nano fertilizer 100, the nano fiber 200 and nano fertilizer 100 are based on the thickness of the film 800, following the first degradation of the degradation level The layer 101, the second degradation layer 102, the third degradation layer 103, the fourth degradation layer 104... were dissolved in sequence. At first, the nano-fertilizer 100 contained in the first degradation layer 101 was dissolved according to the degradation process. Released to the soil, the nano-fertilizer 100 and the nano-fiber 200 inside the plastic film 800 above the second degradation level 102 are still in place, and enter after the first degradation level 101 is degraded and eliminated according to the first period of time. The second degradation level 102, the nano-fertilizer 100 and the nano-plant fiber 200 contained in the second degradation level 102 are also explained and released to the soil, followed by the third degradation level 103 and the fourth degradation level 104..., The nano-fertilizer 100 and nano-plant fiber 200 contained in each level are released to the plant soil 90 one by one according to the time course of division, for absorption by the roots of the plant, or converted into nutrients to supply the growth needs of the plant. Invented mulch film 800, in the process of providing agricultural use, will gradually diverge nano-fertilizer 100 and nano-plant fiber 200 layer by layer according to the degradation level and time course, and provide mulch film 800 in the process of agricultural planting. For the plant soil 90, there is no need to additionally apply the fertilizer of the present invention, and the nano-plant fiber 200 contained in each layer inside will also infiltrate into the plant soil 90 in sequence, and be converted into plant nutrients by chemical combination Specifically, it can be seen that the mulch film 800 of the present invention will release fertilizers and nutrients intermittently according to the time course of agricultural planting and the time relationship of hierarchical degradation, and it is necessary to apply fertilizers within the time course of planting growth to harvest. There is quite positive help, and the nano-fertilizer 100, nano-fiber 200 or/and nano-carbon fiber 400 are nano-sized into fine particles, which penetrate into the soil and are easy to be compatible with the components of the soil and Rapid transformation, easy to be absorbed by plant roots, and driven by water or water vapor, it can easily spread in the soil, and will not cause previous defects on the surface of the mulch 800, affecting the mechanical tension of the mulch 800 .
有关可降解材料主要利用聚对苯二甲酸丁酯(PBAT)为之,PBAT是生物可降解热塑性化合物,经添加辅剂可以改善柔韧性和抗拉性,PBAT在有氧条件下尤其是空旷的田野,更具有充足阳光水气及微生物,有利于全面降解或和合生质堆肥,适用于农用地膜实施。Relevant degradable materials mainly use polybutylene terephthalate (PBAT). PBAT is a biodegradable thermoplastic compound. The flexibility and tensile properties of PBAT can be improved by adding auxiliary agents. PBAT is especially open under aerobic conditions. Fields, with sufficient sunlight, water vapor and microorganisms, are conducive to comprehensive degradation or composting with bio-mass, and are suitable for the implementation of agricultural mulch.
其中肥料干粒10可采具二氧化硅之植干,如稻谷、稻秆,本质二氧化硅微观下,呈现有奈米毛绒微结构,可对昆虫表体作针刺性的戳害或刺激,以得抑制性防虫效果。Among them, the dry fertilizer granules 10 can be taken from plants with silicon dioxide, such as rice and rice straw. Under the microscopic nature of silicon dioxide, there is a nano-fluffy microstructure, which can be used for acupuncture or poking damage to the surface of insects. Stimulate to obtain inhibitory insect repellent effect.
在图4或图6图标中,程序在混合操作50中,执行有填充物补入,该填充物为奈米氧化钙比例为0.1~3%,滑石粉15~25%,以及依成膜机械强度和淋膜作业环境和机具条件配合需求,可追加有改善剂,该改善剂为润滑剂0.5~1%,分散剂0.04~1.2%,扩链剂0.5~3%。In the icon of Fig. 4 or Fig. 6, the program is in the mixing operation 50, and the filler is added. According to the requirement of strength, coating operation environment and equipment conditions, improver can be added, the improver is 0.5-1% of lubricant, 0.04-1.2% of dispersant, 0.5-3% of chain extender.
在整备阶段A的程序中,包含完备之干式奈米竹碳,提供混合操作50成序混入,其比例为2~20%,粒径为在45微米以下。In the program of the preparation stage A, complete dry nano-bamboo carbon is included, and a mixing operation 50 is provided for orderly mixing, the proportion is 2-20%, and the particle size is below 45 microns.
本发明除了提供新进功能之地膜外,更在生产时,利用材料物质状态,而配合干式奈米化作业,可达快速材料备置及成膜过程可大幅降低热熔材料流动阻尼,其中有关干式奈米化作业为以干式处理为奈米尺度之处理设备系统,为利用高速流体物理作用,加上机械动量的操作,将粒径为可目视之粒状物质,以高动能分化处理为奈米尺度。系统设有一工作之回转轴心线,依该回转轴心线设有一原动轴,原动轴往一压力发生单元内部带动一引流轴筒,引流轴筒一端设有汲入口迎接待加工微粒物质,该加工物质经由引流轴筒传递进入增压叶轮的工作区间,引流轴筒径向带动一增压叶轮,整体运转于一刚性压力缸体,压力缸体工作径向圆表,向外导通有一释出口。In addition to providing a film with new functions, the present invention also utilizes the material state of the material during production, and cooperates with dry nanometerization operations to achieve rapid material preparation and film formation, and greatly reduce the flow resistance of hot-melt materials. The dry-type nano-processing is a nano-scale processing equipment system based on dry processing. In order to use the physical action of high-speed fluid and the operation of mechanical momentum, the particle size can be divided into granular substances that can be seen with high kinetic energy. Treated to the nanoscale. The system is equipped with a working axis of rotation, and a drive shaft is set according to the axis of rotation. The drive shaft drives a drainage shaft to the inside of a pressure generating unit. One end of the drainage shaft is provided with a suction port to receive the particulate matter to be processed. , the processed material is transferred into the working area of the booster impeller through the drainage shaft tube, and the drainage shaft tube radially drives a booster impeller, which runs in a rigid pressure cylinder as a whole. There is an exit.
系统具体为利用动力元带动压力发生单元,该压力发生单元内部依系统回转轴心线设有一圆舱形之压力缸体,压力缸体圆周一处对外导通有一释出口,内部设有一中心线与回转轴心线重迭之引流轴筒,引流轴筒径向结合有增压叶轮,整体共轴就位于压力缸体之中,引流轴筒一端设有一汲入口,汲入口外圆辐向经径向开设之压动槽口导通增压叶轮空间,被加工物由汲入口受压力缸体内部压力作用汲引进入压力缸体,藉由压力缸体内部所发生的气流高低压力差,和高速气流甚至为音速临界状态,及机械运转所发生的动量,复合多种物理性的操作,作用在被加工之物质微粒,以将可目视微粒尺寸的待加工物质(原料)有效分化为奈米尺度,该物质为干状质地,为有机或无机之碎粒物。Specifically, the system uses the power unit to drive the pressure generating unit. The pressure generating unit is equipped with a round cabin-shaped pressure cylinder according to the axis of rotation of the system. The circumference of the pressure cylinder is connected to the outside with a release port, and the inside is provided with a center line. The drainage shaft tube overlaps with the center line of the rotation axis. The drainage shaft tube is radially combined with a booster impeller. The whole coaxial is located in the pressure cylinder. One end of the drainage shaft tube is provided with a suction port, and the outer circle of the suction port radially The radially opened pressure slot leads to the space of the booster impeller, and the processed object is sucked into the pressure cylinder by the suction port under the internal pressure of the pressure cylinder. The air flow is even at the critical state of sound speed, and the momentum generated by mechanical operation, combined with various physical operations, acts on the processed material particles to effectively divide the processed material (raw material) into nanometers with a visual particle size Scale, the substance has a dry texture and is organic or inorganic crumbs.
本发明利用整备阶段为将肥料干粒与植物干粒经干式作业奈米化处理,附加有植物碳碎粒的混入,使总体所形成的地膜具有吸热阻光渐进释放肥料元素的特殊功能,地膜的张力可精准维持,铺设时可尽力拉掣平铺,实为一创新的地膜制作程序。In the preparation stage of the present invention, dry fertilizer particles and plant dry particles are subjected to dry-type nanonization treatment, and plant carbon particles are added, so that the overall formed plastic film has the special function of absorbing heat, blocking light, and gradually releasing fertilizer elements. , the tension of the mulch can be precisely maintained, and it can be spread as far as possible when laying, which is an innovative mulch production process.
Claims (14)
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| CN108912407A (en) * | 2018-06-14 | 2018-11-30 | 安徽精良同硕塑膜科技股份有限公司 | A kind of antibacterial biological degradable mulch |
| CN111165242A (en) * | 2020-01-20 | 2020-05-19 | 中国农业科学院农业环境与可持续发展研究所 | Fertilizer type biodegradable mulching film and preparation method thereof |
| CN210935282U (en) * | 2019-08-20 | 2020-07-07 | 萧智远 | Dry-type nano-material treatment device |
| KR102142972B1 (en) * | 2020-02-27 | 2020-08-10 | 주식회사 진바이오컴 | Biodegradable resin composition comprising mineral elements fertilizer and mineral elements fertilizer sustained and contolled releasing biodegradable mulching film |
| CN113429636A (en) * | 2021-07-02 | 2021-09-24 | 上海经海纬象生物材料有限公司 | Full-biodegradable straw reinforced starch material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108912407A (en) * | 2018-06-14 | 2018-11-30 | 安徽精良同硕塑膜科技股份有限公司 | A kind of antibacterial biological degradable mulch |
| CN210935282U (en) * | 2019-08-20 | 2020-07-07 | 萧智远 | Dry-type nano-material treatment device |
| CN111165242A (en) * | 2020-01-20 | 2020-05-19 | 中国农业科学院农业环境与可持续发展研究所 | Fertilizer type biodegradable mulching film and preparation method thereof |
| KR102142972B1 (en) * | 2020-02-27 | 2020-08-10 | 주식회사 진바이오컴 | Biodegradable resin composition comprising mineral elements fertilizer and mineral elements fertilizer sustained and contolled releasing biodegradable mulching film |
| CN113429636A (en) * | 2021-07-02 | 2021-09-24 | 上海经海纬象生物材料有限公司 | Full-biodegradable straw reinforced starch material and preparation method thereof |
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