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CN116195369A - Short wavelength radiation source with multi-segment collector module - Google Patents

Short wavelength radiation source with multi-segment collector module Download PDF

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CN116195369A
CN116195369A CN202180054712.XA CN202180054712A CN116195369A CN 116195369 A CN116195369 A CN 116195369A CN 202180054712 A CN202180054712 A CN 202180054712A CN 116195369 A CN116195369 A CN 116195369A
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plasma
debris
housing
radiation
short wavelength
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CN116195369B (en
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亚历山大·尤里耶维奇·维诺霍多夫
弗拉基米尔·维塔列维奇·伊万诺夫
丹尼斯·亚历山大罗维奇·格鲁什科夫
萨米尔·埃尔维
康斯坦丁·尼古拉耶维奇·科谢列夫
米哈伊尔·谢尔盖耶维奇·克里沃科里托夫
弗拉基米尔·米哈伊洛维奇·克里夫松
亚历山大·安德烈耶维奇·拉什
维亚切斯拉夫·瓦列里耶维奇·梅德韦杰夫
尤里·维克托罗维奇·西德尔尼科夫
奥列格·鲍里索维奇·赫里斯托福罗夫
奥列格·费利克索维奇·亚库舍夫
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Isteq Private Ltd
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Isteq Private Ltd
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05GX-RAY TECHNIQUE
    • H05G2/00Apparatus or processes specially adapted for producing X-rays, not involving X-ray tubes, e.g. involving generation of a plasma
    • H05G2/001Production of X-ray radiation generated from plasma
    • H05G2/009Auxiliary arrangements not involved in the plasma generation
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05GX-RAY TECHNIQUE
    • H05G2/00Apparatus or processes specially adapted for producing X-rays, not involving X-ray tubes, e.g. involving generation of a plasma
    • H05G2/001Production of X-ray radiation generated from plasma
    • H05G2/009Auxiliary arrangements not involved in the plasma generation
    • H05G2/0094Reduction, prevention or protection from contamination; Cleaning

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  • Optics & Photonics (AREA)
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Abstract

A radiation source comprises a collector module comprising an optical collector in a vacuum chamber with an emitting plasma, and further comprising means for debris mitigation, the means comprising at least two housings arranged to output concentric beams of short wavelength radiation without debris, the beams reaching the optical collector, preferably consisting of several identical mirrors. Each housing has a permanent magnet outside it that creates a magnetic field inside it to slow down the charged portions of the debris particles and provide a concentric beam of short wavelength radiation free of debris. Other debris mitigation techniques are also used. Preferably, the plasma is a laser generated plasma of a liquid metal target provided by a rotating target assembly to a laser beam focal region. The technical result of the present invention is a high power, high brightness, debris free short wavelength radiation source having a large collection solid angle, preferably greater than 0.25 sr.

Description

具有多段式集光器模块的短波长辐射源Short-wavelength radiation source with multi-segment collector modules

技术领域technical field

本发明涉及高亮度辐射源,其设计用于产生波长约为0.4至200nm的软X射线、极紫外(EUV)和真空紫外(VUV)辐射,本发明也涉及辐射收集方法,其在大收集角度下提供高效的碎片减缓,以确保大功率光源及其集成设备的长期运行。The present invention relates to high-brightness radiation sources designed to produce soft X-rays, extreme ultraviolet (EUV) and vacuum ultraviolet (VUV) radiation with wavelengths of about 0.4 to 200 nm, and also to methods of radiation collection which operate at large collection angles Provide efficient debris mitigation to ensure the long-term operation of high-power light sources and their integrated equipment.

背景技术Background technique

高强度软X射线、极紫外(EUV)和真空紫外(VUV)范围的辐射源用于许多领域:用于显微镜、生物医学和医学诊断、材料测试、纳米结构分析、原子物理学和光刻。Radiation sources in the high-intensity soft X-ray, extreme ultraviolet (EUV) and vacuum ultraviolet (VUV) ranges are used in many fields: in microscopy, biomedicine and medical diagnostics, materials testing, nanostructural analysis, atomic physics and lithography.

通过将大功率激光的辐射聚焦在目标上和放电中,可以获得在软X射线范围(0.4–10nm)、EUV(10–20nm)和VUV(20–120nm)范围内有效发射的等离子体。By focusing the radiation of a high-power laser on the target and in the discharge, plasmas emitting efficiently in the soft X-ray range (0.4–10nm), EUV (10–20nm) and VUV (20–120nm) can be obtained.

根据国际专利申请PCT/EP2013/061941,于2013年8月22日公开,编号为WO 2014/00071的一种激光产生等离子体(LPP)EUV光源,带有集光器模块,包括:集光器,用于收集由产生辐射的等离子体产生的辐射,并引导产生的辐射;还包括用于抑制等离子体辐射束中的红外激光辐射的装置。According to the international patent application PCT/EP2013/061941, published on August 22, 2013, No. WO 2014/00071 A laser-produced plasma (LPP) EUV light source, with a collector module, comprising: a collector , for collecting radiation generated by the radiation-generating plasma, and for directing the generated radiation; and means for suppressing infrared laser radiation in the plasma radiation beam.

LPP EUV光源具有高亮度的特点。然而,存在保护光学集光器不受碎片影响的问题,以确保LPP EUV光源的长寿命。LPP EUV light source has the characteristics of high brightness. However, there is the issue of protecting the optical collector from debris to ensure the long lifetime of the LPP EUV light source.

在辐射源操作期间,作为等离子体副产物产生的碎片可以是高能离子、中性原子或蒸汽以及等离子体燃料材料团簇的形式。碎片颗粒会使集光器光学件退化,集光器光学件可能由位于辐射源附近的一个或多个集光器反射镜组成。除了沉积在集光器反射镜上的微滴和颗粒会降低其反射系数之外,高速颗粒还会损坏集光器反射镜,可能还会损坏位于集光器反射镜后面的光学系统的其它部分。这就迫切需要开发无碎片的高亮度短波长辐射源。During operation of the radiation source, debris generated as a by-product of the plasma can be in the form of energetic ions, neutral atoms or vapors, and clusters of plasma fuel material. Debris particles can degrade the collector optics, which may consist of one or more collector mirrors located near the radiation source. In addition to the droplets and particles deposited on the collector mirror reducing its reflectance, high velocity particles can damage the collector mirror and possibly other parts of the optical system behind the collector mirror . There is an urgent need to develop fragment-free sources of high-brightness short-wavelength radiation.

根据2013年8月22日以WO/2013/122505号公开的国际专利申请PCT/RU2012/000701,已知一种激光触发放电等离子体EUV光源。聚焦的激光束被导向其中一个电极,从而激光触发的放电具有不对称的、主要弯曲的香蕉状形状。这种放电的固有磁场具有梯度,所述梯度决定了放电等离子体向弱磁场区域的主要运动。等离子体流的方向与光学集光器的方向显著不同。为了获得高辐射功率,以高脉冲重复率产生放电。本发明提供了对带电粒子的简单且高效的减缓。According to the international patent application PCT/RU2012/000701 published on 22 August 2013 as WO/2013/122505, a laser-triggered discharge plasma EUV light source is known. A focused laser beam is directed at one of the electrodes so that the laser-triggered discharge has an asymmetric, predominantly curved, banana-like shape. The intrinsic magnetic field of this discharge has a gradient which determines the main movement of the discharge plasma towards the region of weak magnetic field. The direction of the plasma flow is significantly different from that of the optical collector. In order to obtain high radiant power, the discharge is generated at a high pulse repetition rate. The present invention provides simple and efficient mitigation of charged particles.

然而,抑制中性粒子和团簇需要使用更复杂的碎片减缓技术。However, suppressing neutrals and clusters requires the use of more sophisticated debris mitigation techniques.

软X射线、EUV和VUV范围内的光生成使用激光产生等离子体最有效。近年来,投影极紫外光刻技术的发展在很大程度上促进了LPP辐射源的发展,所述光刻技术用于大批量生产具有7nm节点及以下的集成电路(IC)。Light generation in the soft X-ray, EUV and VUV ranges is most efficient using laser-generated plasmas. The development of LPP radiation sources has been largely facilitated in recent years by the development of projection EUV lithography for mass production of integrated circuits (ICs) with the 7nm node and below.

在2016年2月23日公开的美国专利9268031中公开了一种基于在特殊注入气体中沿短波长辐射束路径产生的辅助等离子体的碎片减缓技术。由于暴露于辅助等离子体而获得电荷的碎片随后被脉冲电场偏转。所述方法对于保护光学集光器免受碎片的离子/蒸汽部分的影响是有效的,例如,在使用氙作为等离子体燃料的源中。In US Patent No. 9,268,031 published on February 23, 2016, a debris mitigation technique based on an assisted plasma generated in a special injected gas along the path of a short-wavelength radiation beam is disclosed. Fragments that have acquired charge as a result of exposure to the auxiliary plasma are then deflected by the pulsed electric field. The method is effective for protecting optical concentrators from the ion/vapor fraction of debris, for example, in sources using xenon as the plasma fuel.

然而,在使用金属作为等离子体形成材料的源中,对光学集光器元件的主要威胁是碎片颗粒的微滴部分,而这种方法对此无能为力。However, in sources using metals as the plasma-forming material, the main threat to the optical collector elements is the droplet fraction of debris particles, which this approach does nothing about.

根据2013年8月27日公开的美国专利8519366,已知一种使用Sn液滴目标的LPPEUV辐射源中的碎片减缓方法。所述方法涉及对碎片颗粒的带电部分进行磁减缓。除此之外,碎片技术还包括用于提供缓冲气体保护流的箔阱和端口,这提供了对液体金属目标材料的中性原子和团簇的充分有效的捕获。From US patent 8519366 published on 27 August 2013, a method of debris mitigation in LPPE UV radiation sources using Sn droplet targets is known. The method involves magnetically slowing charged portions of debris particles. In addition to this, the fragmentation technique also includes foil traps and ports for providing a shielded flow of buffer gas, which provides sufficiently efficient trapping of neutral atoms and clusters of the liquid metal target material.

然而,需要额外的、相当复杂的方法来减缓碎片颗粒的微滴部分。However, additional, rather complex methods are required to slow down the droplet fraction of debris particles.

2007年11月27日公开的美国专利7302043中已知的碎片减缓方法部分没有这一缺陷。所述方法使用快速旋转光闸,所述光闸(shutter)能够在一个旋转周期期间通过至少一个开口传输短波长辐射,并且在光闸的另一旋转周期期间防止碎屑通过。。The debris mitigation methods known from US Patent 7,302,043, published November 27, 2007, do not partly have this drawback. The method uses a rapidly rotating shutter capable of transmitting short wavelength radiation through at least one opening during one rotation cycle and preventing the passage of debris during another rotation cycle of the shutter. .

然而,在紧凑型辐射源中使用这种方法来减少碎片在技术上太难实现。However, using this approach to reduce debris in a compact radiation source is technically too difficult to achieve.

这一缺陷在很大程度上缺乏从2020年4月28日公开的美国专利10638588、2020年3月10日公开的美国专利10588210和2020年5月5日公开的美国专利申请20200163197中已知的短波长辐射源,其以全文引用的方式并入本说明书。这些专利文献中公开的源包含真空室,所述真空室具有旋转目标组件。碎片减缓装置的复杂性包括目标以大于80m/s的高线速度旋转。为了抑制碎片的离子/蒸汽部分,提供了箔阱、磁场和保护缓冲气体的定向流动。在辐射源的实施例中,可更换的碳纳米管膜(CNT膜)安装在短波长辐射束的路径中。此外,围绕发射等离子体区域的碎片防护罩固定安装,以使激光束进入脉冲发射等离子体区域,并从中射出短波长辐射束。还建议使用激光预脉冲来抑制碎片的离子部分。另一种建议的碎片减缓机制是使用高重复频率的激光脉冲,例如,约为1MHz,以确保通过后续脉冲的辐射和等离子体使由先前的激光脉冲产生的尺寸高达0.1μm的微滴蒸发。This deficiency largely lacks the knowledge already known from US Patent 10638588 published on April 28, 2020, US Patent 10588210 published on March 10, 2020, and US Patent Application 20200163197 published on May 5, 2020. A source of short wavelength radiation, which is incorporated by reference in its entirety into this specification. The sources disclosed in these patent documents comprise a vacuum chamber with a rotating target assembly. The complexity of debris mitigation devices includes the target rotating at high linear velocities greater than 80m/s. To suppress the ionic/vapor fraction of debris, foil traps, magnetic fields, and directed flow of protective buffer gas are provided. In an embodiment of the radiation source, a replaceable carbon nanotube membrane (CNT membrane) is installed in the path of the short wavelength radiation beam. In addition, a debris shield surrounding the emitting plasma region is fixedly mounted so that the laser beam enters the pulsed emitting plasma region and emits a short wavelength radiation beam therefrom. It is also suggested to use laser pre-pulsing to suppress the ionic portion of the fragments. Another suggested debris mitigation mechanism is the use of high repetition rate laser pulses, for example, around 1 MHz, to ensure that droplets up to 0.1 μm in size produced by previous laser pulses are evaporated by radiation and plasma of subsequent pulses.

这些方法具有足够高的碎片减缓效率,然而,其旨在收集短波长等离子体辐射的相对较小的空间角度,因此,短波长辐射束的平均功率对于许多应用来说是不够的。These methods have sufficiently high debris mitigation efficiencies, however, they are aimed at collecting relatively small spatial angles of short-wavelength plasma radiation and, therefore, the average power of the short-wavelength radiation beam is insufficient for many applications.

发明内容Contents of the invention

因此,需要消除至少一些上述缺陷。特别地,需要改进的光源,其紧凑、功率大、收集角大,并且在短波长辐射的输出光束的路径中提供基本上完全的碎片减缓。Therefore, there is a need to eliminate at least some of the above-mentioned disadvantages. In particular, there is a need for improved light sources that are compact, high powered, have large collection angles, and provide essentially complete debris mitigation in the path of the output beam of short wavelength radiation.

本发明旨在解决与软X射线、EUV和VUV辐射的纯高亮度源的平均功率成倍增加相关的技术问题,同时确保其商业可用性和经济运行。The present invention aims to solve the technical problems associated with the multiplication of the average power of purely high-brightness sources of soft X-ray, EUV and VUV radiation, while ensuring their commercial availability and economical operation.

本发明的技术结果是在以大的、优选大于0.25sr的立体角传播的短波长辐射束中创建了大功率高亮度短波长辐射源,具有高效的碎片减缓。The technical result of the present invention is the creation of a high power high brightness short wavelength radiation source with efficient debris mitigation in a short wavelength radiation beam propagating at a large solid angle, preferably greater than 0.25 sr.

可以通过等离子体短波长辐射源实现所述目的,所述辐射源具有集光器模块,所述集光器模块包括位于真空室中的光学集光器,其中等离子体发射短波长辐射,还包括用于在所述短波长辐射到所述光学集光器的路径上减少碎片的装置。The object can be achieved by a plasma short-wavelength radiation source having a concentrator module comprising an optical concentrator located in a vacuum chamber, wherein the plasma emits short-wavelength radiation, further comprising means for reducing debris on the path of said short wavelength radiation to said optical collector.

所述源的特征在于,碎片减缓装置包括至少两个外壳,其布置为输出到达光学集光器的短波长辐射的无碎片同心束,每个外壳外部都有永磁体,在外壳内部产生磁场,并且由永磁体形成的磁场从同心束中去除碎片颗粒的带电部分,以提供无碎片的同心束。The source is characterized in that the debris mitigation means comprises at least two housings arranged to output a debris-free concentric beam of short-wavelength radiation reaching the optical concentrator, each housing having a permanent magnet on the outside, generating a magnetic field inside the housing, And the magnetic field formed by the permanent magnet removes the charged part of the debris particles from the concentric beam to provide a debris-free concentric beam.

优选地,每个外壳的外表面包含两个基本上平行于来自等离子体的短波长辐射传播方向并平行于垂直方向或另一选定方向延伸的第一面。Preferably, the outer surface of each enclosure comprises two first faces extending substantially parallel to the direction of propagation of short wavelength radiation from the plasma and parallel to the vertical or another selected direction.

优选地,每个外壳包括两个第二面,其基本上平行于来自等离子体的短波长辐射传播方向延伸,并且基本上垂直于外壳的两个第一面。Preferably, each enclosure comprises two second faces extending substantially parallel to the direction of propagation of short wavelength radiation from the plasma and substantially perpendicular to the two first faces of the enclosure.

根据本发明的实施例,每个外壳的第一面的面积大于外壳表面的其余部分的面积,并且永磁体基本上与每个外壳的第一面接触。According to an embodiment of the invention, the area of the first face of each housing is larger than the rest of the surface of the housing, and the permanent magnet is substantially in contact with the first face of each housing.

根据本发明的实施例,每个外壳的第一面的面积小于外壳表面的其余部分的面积,并且永磁体位于外壳表面的第一面之外。According to an embodiment of the invention, the area of the first face of each housing is smaller than the area of the rest of the housing surface, and the permanent magnets are located outside the first face of the housing surface.

根据本发明的实施例,每个外壳的两个第一面之间的角度小于30度。According to an embodiment of the invention, the angle between the two first faces of each housing is smaller than 30 degrees.

本发明的实施例中,两个相邻外壳的相邻面之间的角度为3至10度。In an embodiment of the present invention, the angle between adjacent surfaces of two adjacent shells is 3 to 10 degrees.

在本发明的实施例中,位于彼此最远离的外壳的最远离的部分上的永磁体通过磁芯连接。In an embodiment of the invention, the permanent magnets located on the furthest parts of the housings furthest from each other are connected by magnetic cores.

在本发明的实施例中,光学集光器包含安装在短波长辐射的每个无碎片同心束路径中的多个反射镜。In an embodiment of the invention, the optical collector comprises a plurality of mirrors mounted in the path of each fragment-free concentric beam of short wavelength radiation.

优选地,所有反射镜的反射表面形成球体,其中一个焦点为等离子体,另一个焦点是光学集光器的所有反射镜焦点。Preferably, the reflective surfaces of all mirrors form a sphere, one of the focal points being the plasma and the other focal point being the focal point of all mirrors of the optical concentrator.

优选地,碎片减缓装置包括基于碳纳米管(CNT)的膜,所述膜安装在每个外壳和短波长辐射束路径中的集光器之间。Preferably, the debris mitigation means comprises a carbon nanotube (CNT) based membrane mounted between each housing and a light collector in the path of the short wavelength radiation beam.

在本发明的实施方案中,碎片减缓装置包括保护气流,在每个外壳内部引导进入等离子体,同时每个CNT膜用作短波长辐射的无碎片同心束的退出的外壳窗口,以及防止保护气体通过其退出的气体挡板。In an embodiment of the invention, the debris mitigation device includes a shielding gas flow that directs the incoming plasma inside each enclosure, while each CNT film serves as an enclosure window for the exit of a fragment-free concentric beam of short-wavelength radiation, and prevents the shielding gas from The gas baffle through which it exits.

在本发明的实施例中,永磁体沿着外壳的整个长度定位。In an embodiment of the invention, permanent magnets are positioned along the entire length of the housing.

优选地,碎片减缓装置包括放置在每个外壳中的箔板,并相对于等离子体沿径向定向,基本上垂直于磁场线。Preferably, the debris mitigation means comprises a foil plate placed in each enclosure and oriented radially with respect to the plasma, substantially perpendicular to the magnetic field lines.

在本发明的实施例中,等离子体可选自:激光产生等离子体、z箍缩等离子体、等离子体焦点、放电产生等离子体和激光引发的放电产生的等离子。In an embodiment of the invention, the plasma may be selected from the group consisting of: laser-generated plasma, z-pinch plasma, plasma focus, discharge-generated plasma, and laser-induced discharge-generated plasma.

优选地,等离子体是由旋转目标组件提供给激光束聚焦区域的液体金属目标的激光产生等离子体。Preferably, the plasma is laser-generated plasma provided by the rotating target assembly to the liquid metal target in the laser beam focus region.

优选地,目标是熔融金属层,通过离心力在环形槽的旋转轴表面上形成,在旋转目标组件中实现。Preferably, the target is a layer of molten metal, formed by centrifugal force on the surface of the axis of rotation of the annular groove, achieved in a rotating target assembly.

在另一方面,本发明涉及收集辐射的方法,包括:通过光学集光器收集等离子体形成位置处等离子体发射的辐射,并将至少一部分辐射引导至焦点,其中由等离子体辐射发射的所述等离子体辐射被引导通过至少两个外壳,所述外壳配备有用于碎片减缓的装置。In another aspect, the invention relates to a method of collecting radiation comprising: collecting, by an optical concentrator, radiation emitted by a plasma at a location where the plasma is formed, and directing at least a portion of the radiation to a focal point, wherein the radiation emitted by the plasma The plasma radiation is directed through at least two enclosures equipped with means for debris mitigation.

优选地,在每个外壳外部都有永磁体,在外壳内部产生磁场,由永磁体形成的磁场减缓碎片颗粒的带电部分,并且在每个外壳中还使用其它碎片减缓技术,包括保护气流、箔捕集器、CNT膜,以提供无碎片的同心束。Preferably, there are permanent magnets on the outside of each enclosure, a magnetic field is generated inside the enclosure, the magnetic field formed by the permanent magnets slows down the charged portion of debris particles, and other debris mitigation techniques are also used in each enclosure, including shielded airflow, foil Trap, CNT membrane to provide debris-free concentric beams.

优选地,光学集光器包含安装在每个无碎片同心束路径中的多个反射镜,所有反射镜的反射表面位于椭球或修改椭球的表面上,其中一个焦点是等离子体,另一个焦点则是光学集光器的所有反射镜焦点。Preferably, the optical collector comprises a plurality of mirrors mounted in each debris-free concentric beam path, all mirrors having reflective surfaces on the surface of an ellipsoid or modified ellipsoid, one of the focal points being the plasma and the other The focal point is the focal point of all the mirrors of the optical collector.

本发明的上述和其它目的、优点和特征将在以下对其实施例的非限制性描述中更加明显,所述描述作为参考附图的示例提供。The above and other objects, advantages and features of the present invention will be more apparent from the following non-limiting description of embodiments thereof, provided as examples with reference to the accompanying drawings.

附图说明Description of drawings

附图说明了本发明的本质,其中:The essence of the invention is illustrated by the accompanying drawings, in which:

图1、图2为根据本发明的带有多段式集光器模块的短波长辐射源示意图。Fig. 1 and Fig. 2 are schematic diagrams of a short-wavelength radiation source with a multi-segment optical collector module according to the present invention.

图3、图4–为带有旋转目标组件的激光产生等离子体辐射源示意图。Figure 3, Figure 4 – Schematic diagram of a laser-generated plasma radiation source with a rotating target assembly.

这些图不涵盖,而且也不限制实施本技术解决方案的选项的整个范围,而仅代表其实施的特定情况的说明性材料。These figures do not cover, nor limit, the entire range of options for implementing the technical solution, but merely represent illustrative material for a particular case of its implementation.

具体实施方式Detailed ways

根据图1中以不同比例示出的本发明实施例的示例,等离子体辐射源包括真空室1,所述真空室1具有发射短波长辐射的脉冲高温等离子体2的区域。作为副产物,碎片颗粒(包括蒸汽、离子和等离子体形成材料的团簇)在等离子体区域中产生。等离子体辐射源还包括集光器模块,所述集光器模块包括光学集光器3和放置在从等离子体2引导到光学集光器3的短波长辐射束5的路径上的用于碎片减缓的装置4。光学集光器将短波长辐射重定向到中间焦点,然后重定向到使用短波长辐射操作的光学系统。According to the example of an embodiment of the invention shown in different scales in FIG. 1 , the plasma radiation source comprises a vacuum chamber 1 having a region of pulsed high-temperature plasma 2 emitting short-wavelength radiation. As a by-product, debris particles (including vapors, ions, and clusters of plasma-forming materials) are generated in the plasma region. The plasma radiation source also comprises a concentrator module comprising an optical concentrator 3 and a device for debris placed on the path of the short wavelength radiation beam 5 directed from the plasma 2 to the optical concentrator 3 Mitigation device4. Optical concentrators redirect short-wavelength radiation to an intermediate focal point and then to an optical system that operates with short-wavelength radiation.

根据本发明,用于碎片减缓的装置4包括至少两个外壳(casing)6,其布置成输出到达光学集光器3的短波长辐射的无碎片同心束7,优选由多个反射镜8组成。典型的等离子体尺寸约为0.1mm(测量为自由电子密度的FWHM或发光等离子体区域的亮度分布的FWHM),因此,等离子体辐射源可以被视为准点,并且从其发出的辐射束是同心的。According to the invention, the device 4 for debris mitigation comprises at least two casings 6 arranged to output a debris-free concentric beam 7 of short-wavelength radiation reaching an optical collector 3, preferably consisting of a plurality of mirrors 8 . A typical plasma size is about 0.1mm (measured as the FWHM of the free electron density or the FWHM of the brightness distribution of the luminous plasma region), therefore, the plasma radiation source can be considered as a punctual point, and the radiation beam emanating from it is concentric of.

每个外壳6的外部都有永磁体9,永磁体9在外壳6内部产生磁场,由永磁体9形成的磁场从同心束7中去除碎片颗粒的带电部分,以提供无碎片的同心束。On the outside of each housing 6 there is a permanent magnet 9 which generates a magnetic field inside the housing 6, the magnetic field formed by the permanent magnet 9 removes charged parts of debris particles from the concentric beam 7 to provide a debris free concentric beam.

每个外壳6的外表面包含两个第一面10,其基本上平行于来自等离子体2的短波长辐射传播方向,并平行于垂直方向或另一个选定方向延伸。The outer surface of each enclosure 6 comprises two first faces 10 substantially parallel to the direction of propagation of the short wavelength radiation from the plasma 2 and extending parallel to the vertical or another selected direction.

每个外壳6的外部都有永磁体9,其在外壳6内部产生磁场,其磁感应矢量基本上垂直于外壳的光轴。On the outside of each housing 6 there is a permanent magnet 9 which generates a magnetic field inside the housing 6 whose magnetic induction vector is substantially perpendicular to the optical axis of the housing.

优选地,永磁体9沿着外壳6的整个长度定位。Preferably, the permanent magnets 9 are positioned along the entire length of the housing 6 .

与已知的解决方案相比,根据本发明的碎片减缓装置4是一种多段式系统,其允许显著增加短波长等离子体辐射收集的立体角,同时保持高效的碎片减缓。收集立体角的增加使得可以显著(几倍)增加短波长辐射的收集功率,从而提高在几乎所有应用领域中使用此类辐射源的效率。Compared to known solutions, the debris mitigation device 4 according to the invention is a multi-segment system that allows a significant increase in the solid angle of collection of short-wavelength plasma radiation while maintaining efficient debris mitigation. The increase in the collection solid angle makes it possible to significantly (several times) increase the collection power of short-wavelength radiation, thereby increasing the efficiency of using such radiation sources in almost all fields of application.

在单段式系统中,外壳横向尺寸的简单增加会导致带电粒子磁保护的有效性急剧下降。这是由于这样的事实,即沿着磁场力线的外壳的尺寸越大,外外壳积中的磁感应值越低,这导致带电粒子从发射短波长3的等离子体区域传播穿过外壳到达集电镜8的横向速度降低。因此,在所述段运动过程中,粒子不能偏转足够的距离以避免撞击反射镜。实验表明,为了有效地操作磁保护,在距离发射短波长的等离子体区域约40mm的外壳中心处的磁感应值必须不小于0.5T,磁体位于其上的角度不应超过30度。In a single-section system, a simple increase in the lateral dimension of the enclosure can lead to a drastic decrease in the effectiveness of the magnetic protection against charged particles. This is due to the fact that the larger the size of the enclosure along the field lines of the magnetic field, the lower the magnetic induction value in the enclosure volume, which causes charged particles to propagate through the enclosure from the plasma region emitting short wavelengths to the collector mirror The lateral speed of 8 is reduced. Therefore, during said segment of motion, the particles cannot be deflected far enough to avoid hitting the mirror. Experiments have shown that in order to effectively operate the magnetic protection, the magnetic induction value at the center of the enclosure about 40mm from the plasma region emitting short wavelength must not be less than 0.5T, and the angle at which the magnet is located should not exceed 30 degrees.

因此,使用多段式碎片减缓系统(其中外壳表面之间的平面角不超过30度),可以在每个外壳中产生足够大小的恒定磁场,以便对带电粒子进行高效磁减缓。Therefore, using a multi-stage debris mitigation system (where the plane angle between the enclosure surfaces does not exceed 30 degrees), a constant magnetic field of sufficient magnitude can be generated in each enclosure for efficient magnetic mitigation of charged particles.

根据本发明的优选实施例,位于彼此最远的外壳6的第一面10上的永磁体9通过磁芯11连接。磁芯11优选由软磁钢制成,通过将磁场集中在磁芯中,可以减少由于散射而造成的磁场损失,从而增加每个外壳的体积,从而提高磁碎片减缓的效率。According to a preferred embodiment of the invention, the permanent magnets 9 located on the first face 10 of the housing 6 furthest from each other are connected by a magnetic core 11 . The magnetic core 11 is preferably made of soft magnetic steel. By concentrating the magnetic field in the magnetic core, the loss of the magnetic field due to scattering can be reduced, thereby increasing the volume of each shell, thereby improving the efficiency of magnetic debris mitigation.

在本发明的一个实施例中,每个外壳6包括两个第二面12,其基本上平行于来自等离子体2的短波长辐射传播方向延伸,并且基本上垂直于外壳的两个第一面10。In one embodiment of the invention, each enclosure 6 comprises two second faces 12 extending substantially parallel to the direction of propagation of the short-wavelength radiation from the plasma 2 and substantially perpendicular to the two first faces of the enclosure 10.

第一和第二面10、12相对于等离子体2在径向上的定向为多段式碎片减缓系统提供了高的几何透明度。在本发明的实施例中,两个相邻外壳6的相邻面之间的角度在3至10度的范围内。The radial orientation of the first and second faces 10, 12 relative to the plasma 2 provides high geometric transparency for the multi-stage debris mitigation system. In an embodiment of the invention, the angle between adjacent faces of two adjacent housings 6 is in the range of 3 to 10 degrees.

在本发明的优选实施例中,每个外壳6的第一面10的面积大于外壳6表面的其余部分的面积,并且永磁体9基本上与每个外壳6中的第一面接触。In a preferred embodiment of the invention, the area of the first face 10 of each housing 6 is larger than the rest of the surface of the housing 6 , and the permanent magnet 9 is substantially in contact with the first face in each housing 6 .

在另一个实施例(未示出)中,每个外壳6的第一面10的面积可以小于外壳的其余表面的面积,并且永磁体9可以位于外壳6的表面上,在其第一面10之外,例如,在每个外壳6大的第二面12上。In another embodiment (not shown), the area of the first face 10 of each shell 6 can be smaller than the area of the remaining surface of the shell, and the permanent magnet 9 can be located on the surface of the shell 6, on the first face 10 thereof. Also, for example, on the second large face 12 of each housing 6 .

碎片减缓装置4优选包括碳纳米管膜13,其安装在同心束7路径中的每个外壳6和光学集光器3的反射镜8之间。CNT膜的厚度优选在20至100nm的范围内,这确保了其在小于20nm的波长范围内的高强度和高透明度。因此,CNT膜13由于其在短于20nm的波长范围内的高透明度而提供了同心束7的出射。同时,CNT膜13防止碎片颗粒通过,从而提供无碎片的短波长辐射同心束7。The debris mitigation device 4 preferably comprises a carbon nanotube film 13 mounted between each housing 6 in the path of the concentric beam 7 and the mirror 8 of the optical collector 3 . The thickness of the CNT film is preferably in the range of 20 to 100 nm, which ensures its high strength and high transparency in the wavelength range of less than 20 nm. Thus, the CNT film 13 provides for the exit of the concentric beam 7 due to its high transparency in the wavelength range shorter than 20 nm. At the same time, the CNT membrane 13 prevents the passage of debris particles, thereby providing a debris-free concentric beam 7 of short-wavelength radiation.

除此之外,碎片减缓装置还包括保护气流,这些气流在每个外壳6内被引导到等离子体中,而每个CNT膜13同时充当外壳窗口,用于短波长辐射的无碎片同心束7的出口,以及防止保护气体通过其出口的气体挡板。In addition to this, the debris mitigation device includes protective gas flows that are guided into the plasma within each enclosure 6, while each CNT film 13 simultaneously acts as an enclosure window for a fragment-free concentric beam of short-wavelength radiation 7 outlet, and a gas baffle that prevents the shielding gas from passing through its outlet.

在保护气体压力约为20Pa的情况下,在外壳中提供平均真空,可增加气体分子和从等离子体区域散射的碎片颗粒之间的碰撞次数,从而使其偏离直线运动。同时,使用CNT膜作为气体密封允许仅在外壳内使用增加的压力,而不是沿着同心束7到消费光学器件的整个传播路径。这减少了由于气体中的吸收而导致的短波长辐射的损失。With a shielding gas pressure of about 20 Pa, providing an average vacuum in the enclosure increases the number of collisions between gas molecules and debris particles scattered from the plasma region, causing them to deviate from linear motion. At the same time, the use of the CNT membrane as a gas seal allows the use of increased pressure only within the enclosure, rather than along the entire propagation path of the concentric beam 7 to the consumer optics. This reduces the loss of short wavelength radiation due to absorption in the gas.

为了获得大于20nm波长范围内的辐射,不使用CNT膜13,因为其在指示范围内的透明度随着辐射波长的增加而急剧降低。In order to obtain radiation in the wavelength range greater than 20 nm, the CNT film 13 is not used, since its transparency in the indicated range decreases sharply with increasing radiation wavelength.

在图2所示的优选实施例中,光学集光器3包含多个反射镜8,而所有反射镜的反射表面属于旋转椭球体或换言之,球体15,其中一个焦点是脉冲发射等离子体2的区域,另一个焦点则是光学集光器3的反射镜8的焦点16。这种反射镜的生产非常昂贵,因为集光器反射镜衬底的粗糙度仅为0.2–0.3nm,并且这种反射镜的成本,特别是具有非球面轮廓的反射镜,根据面积增加2-3倍的规律,随着其尺寸的增加而增加。因此,使用几个相同的反射镜8显著降低了光学集光器的成本。In the preferred embodiment shown in FIG. 2 , the optical collector 3 comprises a plurality of mirrors 8 , while the reflective surfaces of all mirrors belong to spheroids or in other words, spheres 15 , one of the focal points of which is the pulsed emission plasma 2 The other focal point is the focal point 16 of the mirror 8 of the optical concentrator 3 . Such mirrors are very expensive to produce because the collector mirror substrate has a roughness of only 0.2–0.3 nm, and the cost of such mirrors, especially with aspheric profiles, increases by 2- 3-fold regularity, increasing as its size increases. Thus, the use of several identical mirrors 8 significantly reduces the cost of the optical collector.

脉冲发射等离子体可选自:激光产生等离子体、z箍缩等离子体、等离子体焦点、放电产生等离子体、激光触发放电等离子体。The pulsed emission plasma may be selected from the group consisting of: laser generated plasma, z-pinch plasma, plasma focus, discharge generated plasma, laser triggered discharge plasma.

在一个优选实施例中,脉冲高温等离子体是由旋转目标组件输送到激光束聚焦区域的液体金属目标材料的激光等离子体,如2020年5月21日公开的专利申请20200163197所述,所述专利申请以全文引用的方式并入本文中。In a preferred embodiment, the pulsed high-temperature plasma is a laser plasma of a liquid metal target material delivered by a rotating target assembly to the focal region of the laser beam, as described in patent application 20200163197 published on May 21, 2020, which The application is hereby incorporated by reference in its entirety.

根据图3中示意性示出的本发明的优选实施例,目标17是通过离心力在旋转目标组件20的环形槽19的面向旋转轴18的表面上形成的熔融金属层。图4示意性地示出了本发明优选实施例的等距视图。According to a preferred embodiment of the invention shown schematically in FIG. 3 , the target 17 is a layer of molten metal formed by centrifugal force on the surface of the annular groove 19 of the rotating target assembly 20 facing the axis of rotation 18 . Figure 4 schematically shows an isometric view of a preferred embodiment of the invention.

使用图3和图4所示的液体金属目标的激光产生等离子体的优选实施例中的高亮度短波长辐射源的操作如下进行。真空室1由无油泵送系统泵送至10-5…10-8毫巴以下的压力,去除能够与液体金属目标材料相互作用的气态成分,如氮、氧、碳等。Operation of the high-brightness short-wavelength radiation source in the preferred embodiment of the laser-generated plasma using the liquid metal target shown in Figures 3 and 4 proceeds as follows. The vacuum chamber 1 is pumped by an oil-free pumping system to a pressure below 10 -5 ... 10 -8 mbar to remove gaseous components that can interact with the liquid metal target material, such as nitrogen, oxygen, carbon, etc.

目标17,其材料属于无毒低熔点金属组,包括Sn、Li、In、Ga、Pb、Bi、Zn及其合金,通过旋转目标组件与聚焦激光束21一起输送到相互作用区。目标暴露于聚焦的脉冲激光束21,所述激光束具有1kHz至1MHz范围内的高脉冲重复率。根据目标材料和目标上的激光功率密度,在软X射线和/或EUV和/或VUV光谱范围内产生激光等离子体的短波长辐射。The target 17, whose material belongs to the group of non-toxic low-melting point metals, including Sn, Li, In, Ga, Pb, Bi, Zn and their alloys, is delivered to the interaction zone together with the focused laser beam 21 by rotating the target assembly. The target is exposed to a focused pulsed laser beam 21 with a high pulse repetition rate in the range of 1 kHz to 1 MHz. Depending on the target material and the laser power density on the target, short-wavelength radiation of the laser plasma is generated in the soft X-ray and/or EUV and/or VUV spectral range.

等离子体2发射的短波长辐射束5穿过外壳6,优选穿过CNT膜13,被转换成无碎片的同心束,射向光学集光器3的反射镜8。因此,永磁体9(图4)产生一个恒定磁场,最好垂直于同心束的轴线。在洛伦兹力的作用下,碎片颗粒(主要是离子)的带电部分偏离了沿着同心束7的轴线的直线运动,与外壳6的内壁或特别放置在外壳中的板22碰撞,如图3所示,碎片颗粒被其捕获。安装在外壳6中的板22径向地指向等离子体2,并且优选地垂直于由磁体9产生的磁场线。板22允许更有效地捕获高速带电粒子,因为粒子的速度越高,其在磁场影响下偏转的横向距离越小。与其一起,所述保护气流防止碎片颗粒的离子/蒸汽部分的移动,将其沉积在外壳6和板22的壁上,保护CNT膜13免受碎片的影响。由于CNT膜在短于20nm的波长范围内的高透明度,CNT膜提供短波长光束到集光器3的反射镜8的出射。同时,CNT膜13防止碎片通过,从而为每个反射镜8提供可靠的保护。此外,通过组织通过气体入口14供应的保护气体的定向流动,确保了外壳6中的有效碎片减缓。保护气流保护CNT膜13免受碎片的离子/蒸汽部分的影响,从而延长其使用寿命。The short-wavelength radiation beam 5 emitted by the plasma 2 passes through the housing 6 , preferably through the CNT film 13 , is converted into a fragment-free concentric beam, and is directed towards the mirror 8 of the optical collector 3 . Thus, the permanent magnet 9 (Fig. 4) generates a constant magnetic field, preferably perpendicular to the axis of the concentric beam. Under the action of the Lorentz force, the charged parts of the debris particles (mainly ions) deviate from the linear motion along the axis of the concentric beam 7 and collide with the inner wall of the housing 6 or a plate 22 specially placed in the housing, as shown in Fig. 3, debris particles are captured by it. A plate 22 mounted in the housing 6 is directed radially towards the plasma 2 and preferably perpendicular to the magnetic field lines generated by the magnet 9 . The plate 22 allows a more efficient trapping of high-speed charged particles, since the higher the speed of the particles, the smaller is the lateral distance that they are deflected under the influence of the magnetic field. Together with this, the protective gas flow prevents the movement of the ionic/vapour fraction of the debris particles, depositing it on the walls of the housing 6 and plate 22, protecting the CNT film 13 from debris. Due to the high transparency of the CNT film in the wavelength range shorter than 20 nm, the CNT film provides the exit of the short wavelength light beam to the mirror 8 of the collector 3 . At the same time, the CNT film 13 prevents debris from passing through, thereby providing reliable protection for each mirror 8 . Furthermore, effective debris mitigation in the housing 6 is ensured by organizing the directional flow of the shielding gas supplied through the gas inlet 14 . The shielding gas flow protects the CNT membrane 13 from the ionic/vapor portion of the debris, thereby prolonging its lifetime.

沿着激光束21的路径,也使用了类似的碎片减缓方法。Along the path of the laser beam 21, similar debris mitigation methods are used.

上述装置实现了本发明的特定实施例,其一个方面涉及收集辐射的方法。所述方法包括由光学集光器3在等离子体形成位置收集等离子体2发射的短波长辐射,并将至少一部分辐射引导至图2的焦点16。由等离子体2发射的辐射束5被引导通过至少两个外壳6,外壳6与用于碎片减缓的装置4集成,并被布置成形成出自外壳6的短波长辐射的无碎片同心束7,到达所述光学集光器3。The apparatus described above enables a particular embodiment of the invention, one aspect of which relates to a method of collecting radiation. The method comprises collecting short wavelength radiation emitted by the plasma 2 at the plasma formation location by an optical collector 3 and directing at least a portion of the radiation to the focal point 16 of FIG. 2 . The radiation beam 5 emitted by the plasma 2 is directed through at least two enclosures 6 integrated with the means for debris mitigation 4 and arranged to form a debris-free concentric beam 7 of short-wavelength radiation exiting the enclosures 6, reaching The optical collector 3.

在每个外壳外部,在外壳6内部产生磁场的永磁体9用于减缓碎片颗粒的带电部分,其它碎片减缓技术,包括保护气流、箔阱、CNT膜也用于每个外壳中,以提供无碎片的同心束7。Outside each enclosure, permanent magnets 9 that generate a magnetic field inside the enclosure 6 are used to slow down the charged portion of the debris particles, other debris mitigation technologies including shielded airflow, foil traps, CNT membranes are also used in each enclosure to provide Concentric bundles of fragments7.

光学集光器3优选地包含安装在每个无碎片同心束7的路径中的多个反射镜8,并且所有反射镜的反射表面位于椭球15或修改的椭球的表面上,其中一个焦点是等离子体2,另一个焦点16是光学集光器3的所有反射镜8的焦点。与完美的椭球形状相比,改进的椭球形状可用于提供远场中收集的辐射的改进的强度均匀性。The optical collector 3 preferably comprises a plurality of mirrors 8 mounted in the path of each debris-free concentric beam 7, and the reflective surfaces of all mirrors lie on the surface of an ellipsoid 15 or a modified ellipsoid, one of the focal points is the plasma 2 and the other focal point 16 is the focal point of all mirrors 8 of the optical concentrator 3 . An improved ellipsoidal shape may be used to provide improved intensity uniformity of radiation collected in the far field compared to a perfect ellipsoidal shape.

因此,本发明可以创造出无碎片、强大、高亮度的软X射线、EUV和VUV辐射源,使用寿命长且易于使用。Thus, the present invention enables the creation of fragment-free, powerful, high-brightness sources of soft X-ray, EUV and VUV radiation that are long-lasting and easy to use.

工业适用性Industrial applicability

所提出的装置适用于多种应用,包括显微镜、材料科学、材料X射线诊断、生物医学和医学诊断、纳米和微观结构检查,包括EUV光刻的光化掩模缺陷检查。The proposed device is suitable for a variety of applications, including microscopy, materials science, materials X-ray diagnostics, biomedical and medical diagnostics, nano- and microstructural inspection, including photomask defect inspection for EUV lithography.

Claims (20)

1. A plasma short wavelength radiation source having a collector module, comprising: an optical collector (3) located in a vacuum chamber (1) having a plasma (2) emitting short wavelength radiation, and further comprising means (4) for reducing debris on the short wavelength radiation path to the optical collector (3), wherein
The device (4) for debris mitigation comprises at least two housings (6) arranged to output a debris-free concentric beam (7) of the short wavelength radiation reaching the optical collector (3),
and outside each housing (6) there is a permanent magnet (9) which generates a magnetic field inside the housing (6) and the magnetic field formed by the permanent magnets (9) removes the charged portions of the debris particles from the concentric bundle (7) to provide a debris-free concentric bundle.
2. The source of claim 1, wherein the outer surface of each housing comprises two first faces (10) extending substantially parallel to the direction of propagation of short wavelength radiation from the plasma (2), and optionally the two first faces are parallel to the vertical direction.
3. The source of claim 2, wherein each housing (6) comprises two second faces (12) extending substantially parallel to a direction of propagation of short wavelength radiation from the plasma (2) and substantially perpendicular to the two first faces (10) of the housing.
4. A source according to claim 2, wherein the area of the first face (10) of each housing (6) is larger than the area of the remaining surface of the housing (6), and the permanent magnet (9) is substantially in contact with the first face (10) of each housing (6).
5. A source according to claim 2, wherein the first face (10) of each housing (6) has an area smaller than the area of the remaining surface of the housing (6), and the permanent magnet (9) is located on the surface of the housing (6) outside its first face (10).
6. The source of claim 2, wherein the angle between the two first faces (10) of each housing (6) is less than 30 degrees.
7. A source according to claim 2, wherein the angle between adjacent faces of the two adjacent housings (6) is 3 to 10 degrees.
8. A source according to claim 1, wherein the permanent magnets (9) located on the mutually most distant parts of the mutually most distant housing (6) are connected by means of a magnetic core (11).
9. The source of claim 1, wherein the optical collector (3) comprises a plurality of mirrors (8) mounted in the path of each of the debris-free concentric beams (7).
10. A source according to claim 9, wherein the reflecting surfaces of all mirrors (8) form spheres (15), one of the foci being the plasma (2) and the other focus (16) being the focus of all mirrors of the optical collector.
11. The source according to claim 1, wherein the means (4) for debris mitigation comprise a membrane (13) based on Carbon Nanotubes (CNTs) mounted between each housing (6) and the optical collector (3).
12. The source according to claim 11, wherein the means (4) for debris mitigation comprises a flow of shielding gas which is guided into the plasma inside each enclosure (6), while each CNT film (13) simultaneously acts as an enclosure window for exit of the debris-free concentric beam (7) of short wavelength radiation and as a gas barrier for preventing exit of the shielding gas therethrough.
13. A source according to claim 1, wherein the permanent magnet (9) is positioned along the entire length of the housing.
14. A source according to claim 1, wherein the means (4) for debris mitigation comprise a foil plate (22) placed in each of the housings (6) and oriented in a radial direction with respect to the plasma (2), substantially perpendicular to the magnetic field lines.
15. The source of claim 1, wherein the plasma may be selected from: laser-produced plasma, z-pinch plasma, plasma focus, discharge-produced plasma, and laser-triggered discharge plasma.
16. The source of claim 1, wherein the plasma is a laser generated plasma of a liquid metal target (17) provided by a rotating target assembly (20) to a focal region of a laser beam (21).
17. The source according to claim 16, wherein the target (17) is a layer of molten metal formed by centrifugal force on a surface of an annular groove (19) facing the rotation axis (18), which is embodied in the rotating target assembly (20).
18. A method of collecting radiation, comprising: collecting radiation emitted by the plasma by an optical collector at a plasma formation location and directing at least a portion of the radiation emitted by the plasma radiation to a focal point, wherein
Radiation emitted by the plasma radiation is directed through at least two housings provided with means for debris mitigation and arranged to form a debris-free concentric beam of short wavelength radiation exiting the housings to the optical collector.
19. The method of claim 18, wherein a permanent magnet generating a magnetic field inside the enclosure is used to slow down the charged portion of the debris particles outside each enclosure, and optionally includes a shielding gas flow, foil trap, CNT film debris mitigation element.
20. The method of claim 18, wherein the optical collector comprises a plurality of mirrors mounted in the path of each of the debris-free concentric beams, and the reflective surfaces of all mirrors are located on the surface of an ellipsoid or modified ellipsoid, with one focus being the plasma.
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