CN1006689B - Recovery of usable mineral from ore by foaming agent composite and foaming flotation - Google Patents
Recovery of usable mineral from ore by foaming agent composite and foaming flotationInfo
- Publication number
- CN1006689B CN1006689B CN85106476A CN85106476A CN1006689B CN 1006689 B CN1006689 B CN 1006689B CN 85106476 A CN85106476 A CN 85106476A CN 85106476 A CN85106476 A CN 85106476A CN 1006689 B CN1006689 B CN 1006689B
- Authority
- CN
- China
- Prior art keywords
- ore
- foaming agent
- propylene oxide
- flotation
- valuable mineral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004088 foaming agent Substances 0.000 title claims abstract description 59
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 53
- 239000011707 mineral Substances 0.000 title claims abstract description 53
- 238000005188 flotation Methods 0.000 title claims abstract description 31
- 238000011084 recovery Methods 0.000 title description 32
- 238000005187 foaming Methods 0.000 title description 4
- 239000002131 composite material Substances 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 34
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 32
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 7
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000009291 froth flotation Methods 0.000 claims description 16
- 239000006260 foam Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 5
- 150000001924 cycloalkanes Chemical class 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 claims description 2
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 claims description 2
- 150000002016 disaccharides Chemical class 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002245 particle Substances 0.000 abstract description 4
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 239000010419 fine particle Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000010949 copper Substances 0.000 description 40
- 229910052802 copper Inorganic materials 0.000 description 22
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- -1 Alkane polyol Chemical class 0.000 description 10
- 229920001451 polypropylene glycol Polymers 0.000 description 9
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 8
- 238000007667 floating Methods 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 229920013701 VORANOL™ Polymers 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 150000001896 cresols Chemical class 0.000 description 3
- 125000001033 ether group Chemical group 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical class CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 2
- 229910052770 Uranium Chemical group 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 229910052951 chalcopyrite Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical class CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 2
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- FVGBHSIHHXTYTH-UHFFFAOYSA-N pentane-1,1,1-triol Chemical class CCCCC(O)(O)O FVGBHSIHHXTYTH-UHFFFAOYSA-N 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 239000011297 pine tar Substances 0.000 description 2
- 229940068124 pine tar Drugs 0.000 description 2
- JCBJVAJGLKENNC-UHFFFAOYSA-M potassium ethyl xanthate Chemical compound [K+].CCOC([S-])=S JCBJVAJGLKENNC-UHFFFAOYSA-M 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 2
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical group [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- KOPMZTKUZCNGFY-UHFFFAOYSA-N 1,1,1-triethoxybutane Chemical compound CCCC(OCC)(OCC)OCC KOPMZTKUZCNGFY-UHFFFAOYSA-N 0.000 description 1
- VSKYWEYQEJNVOT-UHFFFAOYSA-N 1-amino-1-oxobutane-2-sulfonic acid Chemical compound CCC(C(N)=O)S(O)(=O)=O VSKYWEYQEJNVOT-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 229910015369 AuTe Inorganic materials 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229920013710 Dow VORANOL™ CP 450 Polyol Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical class CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-VKHMYHEASA-N S-propylene oxide Chemical compound C[C@H]1CO1 GOOHAUXETOMSMM-VKHMYHEASA-N 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- XEIPQVVAVOUIOP-UHFFFAOYSA-N [Au]=S Chemical compound [Au]=S XEIPQVVAVOUIOP-UHFFFAOYSA-N 0.000 description 1
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 description 1
- LAISNASYKAIAIK-UHFFFAOYSA-N [S].[As] Chemical compound [S].[As] LAISNASYKAIAIK-UHFFFAOYSA-N 0.000 description 1
- BFEBVEVTVKJYGD-UHFFFAOYSA-N [S].[U] Chemical compound [S].[U] BFEBVEVTVKJYGD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005667 alkyl propylene group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- GSWGDDYIUCWADU-UHFFFAOYSA-N aluminum magnesium oxygen(2-) Chemical compound [O--].[Mg++].[Al+3] GSWGDDYIUCWADU-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052948 bornite Inorganic materials 0.000 description 1
- 229910052972 bournonite Inorganic materials 0.000 description 1
- 229910052933 brochantite Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical compound OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 description 1
- HIZCIEIDIFGZSS-UHFFFAOYSA-N carbonotrithioic acid Chemical compound SC(S)=S HIZCIEIDIFGZSS-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- BUGICWZUDIWQRQ-UHFFFAOYSA-N copper iron sulfane Chemical compound S.[Fe].[Cu] BUGICWZUDIWQRQ-UHFFFAOYSA-N 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- ZMHWUUMELDFBCZ-UHFFFAOYSA-M copper(1+);hydroxide Chemical compound [OH-].[Cu+] ZMHWUUMELDFBCZ-UHFFFAOYSA-M 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052971 enargite Inorganic materials 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 229930195729 fatty acid Chemical class 0.000 description 1
- 239000000194 fatty acid Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- CLTXFEAAEJABQN-UHFFFAOYSA-N heptane-1,1,1-triol Chemical class CCCCCCC(O)(O)O CLTXFEAAEJABQN-UHFFFAOYSA-N 0.000 description 1
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical class CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- KEHCHOCBAJSEKS-UHFFFAOYSA-N iron(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Fe+2] KEHCHOCBAJSEKS-UHFFFAOYSA-N 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000005217 methyl ethers Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- XRENWZZZPGOSQE-UHFFFAOYSA-N octane-1,1,1-triol Chemical class CCCCCCCC(O)(O)O XRENWZZZPGOSQE-UHFFFAOYSA-N 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- MAYUCBCSAVDUKG-UHFFFAOYSA-N orthoacetic acid Chemical class CC(O)(O)O MAYUCBCSAVDUKG-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- ZXRDVSMSMOZCPT-UHFFFAOYSA-N phosphorodithious acid Chemical compound OP(S)S ZXRDVSMSMOZCPT-UHFFFAOYSA-N 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012913 prioritisation Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- LOUPRKONTZGTKE-LHHVKLHASA-N quinidine Chemical compound C([C@H]([C@H](C1)C=C)C2)C[N@@]1[C@H]2[C@@H](O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-LHHVKLHASA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229910052959 stibnite Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
- RPBNQQGUJBCUGO-UHFFFAOYSA-N sulfanylidenechromium Chemical compound [S].[Cr] RPBNQQGUJBCUGO-UHFFFAOYSA-N 0.000 description 1
- VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical compound [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 description 1
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 description 1
- JOKPITBUODAHEN-UHFFFAOYSA-N sulfanylideneplatinum Chemical compound [Pt]=S JOKPITBUODAHEN-UHFFFAOYSA-N 0.000 description 1
- PGWMQVQLSMAHHO-UHFFFAOYSA-N sulfanylidenesilver Chemical compound [Ag]=S PGWMQVQLSMAHHO-UHFFFAOYSA-N 0.000 description 1
- 229910052970 tennantite Inorganic materials 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052969 tetrahedrite Inorganic materials 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- WQYSXVGEZYESBR-UHFFFAOYSA-N thiophosphoryl chloride Chemical compound ClP(Cl)(Cl)=S WQYSXVGEZYESBR-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910000442 triuranium octoxide Inorganic materials 0.000 description 1
- 229910000439 uranium oxide Inorganic materials 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Physical Water Treatments (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The present invention relates to a foaming agent composition and a method for recycling useful minerals from ores in a water-bearing ore slurry form by flotation. The foaming agent composition comprises a reaction product of C1-C20 polyhydroxy alkane or C3-C20 polyhydroxy naphthene and propylene oxide or a mixture of the propylene oxide and oxirane. The method has conditions that the mixture contains at least 50 mole percent of the propylene oxide, and the molecular weight of the reaction product is from 150 to 1400. The foaming agent composition and the method of the present invention are particularly suitable for the flotation of 75% of fine useful minerals or more fine particle useful minerals of which the ore particle size is equal to or smaller than 75 micrometers.
Description
The invention relates to and from ore, reclaim foaming agent composition and the froth flotation method that valuable mineral is used.The inventive method is the general ore of enrichment effectively not only, and particle concentration is equal to or less than 75 microns ore effectively.In the art, usually the fine granularity ore is called sludge.
Foaming agent composition of the present invention and method can be from the ores that contains metal or nonmetal valuable mineral, selective recovery particulate valuable mineral in foam, and the not unwanted ore part of carrier band, i.e. gangue.
When reclaiming the particulate valuable mineral from ore, about 75% ore grain size is 75 microns or littler.The ore of preferentially selecting for use, granularity be equal to or less than 75 microns account for 80%; The ore that override is selected for use, granularity be equal to or less than 75 microns account for 90%.
By making ore classification, promptly the method that therefrom smitham is sorted out in grain and the big grain ore can be made the smitham that uses among the present invention.Utilize the sieve of suitable specification, perhaps use hydrocyclone or utilize other method known in the art, can accomplish this point.Perhaps mineral powder can be broken into the particulate product that wherein contain required percentage.Pulverizing refers to the process that ore grain size is reduced.Can adopt in the art one of several known method to pulverize, for example ground ore in rod mill.Also can in a double-circuit system (a twocircuit system), carry out flotation, big grain and middle grain valuable mineral reclaim in first step froth flotation process in this system, can adopt foaming agent composition of the present invention and method for floating then, reclaim the mine tailing that contains the particulate valuable mineral by the second step froth flotation process.
" ore " this term here refer to go out from underground mining, to form form of mixtures with gangue and to contain the ore of valuable mineral.Gangue refers to those materials that are not worth and need separate with valuable mineral here.Can use foaming agent composition of the present invention and method for floating to reclaim metal oxide, metal sulfide and other metal values.
Froth flotation is the method that adopts usually during the enrichment valuable mineral from ore.In floatation process, ore is pulverized, wet grinding is to obtaining ore pulp then.In moisture ore pulp, add usually and the foaming agent of trapping agent and usefulness, so that in flotation step subsequently, promote valuable mineral partly to separate with unwanted ore part or gangue.Blast air then in this ore pulp, so that produce one deck foam in its surface, and used trapping agent sticks to the method on the formed bubble during this blowing air step by making valuable mineral, promotes that foaming agent separates valuable mineral from ore.The adhesion process of valuable mineral is optionally carried out, so that make the ore part that does not contain valuable mineral, promptly gangue does not stick on the said bubble.The foam of mineral is rich in collection, further handles to obtain required valuable mineral then., be not called " flotation tailing " usually, do not remake from wherein extracting the further processing of valuable mineral usually by that part of ore of foam carrier band.Foaming agent composition of the present invention and method for floating generally can be used to contain the ore of metal or nonmetal valuable mineral.
When froth flotation, usually wish from ore, to reclaim valuable mineral as much as possible, recovery is undertaken by the selectivity mode, in other words in this foam not carrier band unwanted ore part, i.e. gangue are arranged.Bubble or foam performance though chemical compound lot all has, in industrial froth flotation manipulation, use the most widely foaming agent be such as C
5～C
8Alcohols, pine tar class, cresols class, etc. the C of monohydroxy compound, polypropylene glycol
1～C
4The monohydroxy compound of alkyl ether and the dihydroxy thing that resembles polypropylene glycol and so on.The foaming agent of extensive employing in froth flotation manipulation is to contain the nonpolar hydrophobic grouping and the compound of single polarity hydrophilic radical such as hydroxyl for example.The typical representative compounds of this class foaming agent is mixed amyl alcohol class, methyl isobutyl carbinol, hexanol class and enanthol class, cresols class, terpineol or the like.The effective foaming agent of other of commercial use is the C of polypropylene glycol
1～C
4Alkyl ether, particularly molecular weight are that 140～2100 polypropylene glycol methyl ether, especially molecular weight are the polypropylene glycol methyl ethers in 200～500 scopes.In addition, some oxyalkyl chain alkanes, for example triethoxybutane also uses as foaming agent in the flotation of some ore.
When handling certain ore, compare with other foaming agent, though it is about 1% to use preferred foaming agent that the rate of recovery of valuable mineral is improved, the little raising of this quantity but is very important economically, because industrial day output is often up to 50,000 tons of ores.Owing to can run into very high material stream passed speed usually in the industrial floatation process, the quite little improvement on the valuable mineral rate of recovery all can cause some tons of valuable minerals of many recovery every day.Therefore obviously, help to improve any foaming agent of the valuable mineral rate of recovery,, all be very to need, and may be very favorable in industrial floating operation even rate of recovery improvement value is little.
As everyone knows, in the froth flotation practice, helping under the good selective conditions of valuable mineral to gangue, it is quite difficult reclaiming particulate valuable mineral (sludge).This problem is not to make valuable ingredients usually, it is the problem that valuable mineral reaches high-recovery, would rather say so on the contrary and adopt the rate of recovery more much lower, so that make product have the problem of acceptable quality and grade (selectivity) than the required rate of recovery of valuable mineral.In fact people find usually, along with the increase of the particulate valuable mineral rate of recovery, reclaim product quality (selectivity) and sharply reduce.Therefore, increase the product quantity reclaimed with because of between the falling of product grade value of the product that reduction causes, exist a prioritization scheme economically.
Therefore, the invention provides a kind of improved foaming agent composition and method for floating that reclaims the particulate valuable mineral, has the high rate of recovery with froth flotation method.Foaming agent of the present invention can the selective recovery granularity be equal to or less than 75 microns particulate valuable mineral.
Specifically, the invention relates to and from moisture ore pulp, reclaim valuable mineral floatation frother composition, in said ore pulp, equal or be higher than 75% raw ore to have the granularity that is equal to or less than 75 microns, said foaming agent contains by 1) have the polyhydroxy alkane of 1～20 carbon atom or have the polyhydroxy cycloalkane of 3～20 carbon atoms, with 2) propylene oxide, the perhaps product between the mixture of propylene oxide and oxirane (is propylene oxide but need to have at least in this mixture 50% material), and the molecular weight of this product is from 150 to 1400.
Another aspect of the present invention is to reclaim the method for valuable mineral from ore, in said ore, be equal to, or greater than 75% ore grain size and be equal to or less than 75 microns, in the presence of collection agent and floatation frother, this ore that is under the moisture ore pulp form is carried out the flotation processing, it is characterized in that said foaming agent contains by 1) have the polyhydroxy alkane of 1～20 carbon atom or have the polyhydroxy cycloalkane of 3～20 carbon atoms, with 2) propylene oxide, the perhaps product between the mixture of propylene oxide and oxirane (is propylene oxide but need to have at least in this mixture 50% material), wherein said product molecular weight is from 150 to 1400.
Foaming agent composition of the present invention and method for floating under the high selectivity condition that has precedence over gangue for valuable mineral, have high-recovery beyond expectation.For this recovery, key factor is a foaming agent.This foaming agent not only can be used for flotation bulky grain or particle valuable mineral; and be specially adapted to flotation fine grained valuable mineral; be that granularity is equal to or less than 75 microns valuable mineral, help the selectivity of particulate valuable mineral gangue thereby caused improving.
In preferred specific embodiments, product of the present invention is equivalent to molecular formula:
R is C in the formula
1～C
20Alkyl group or C
3～C
20Cycloalkyl; R
1Be hydrogen or methyl; M is 3～10 integer; N is 1～8 number; Condition be each ether unit only containing a methyl, and another condition is in these ether units, at least 50% ether unit must have a methyl.
Can use such polyhydroxy C in the present invention
1～C
20Alkane or polyhydroxy C
3～C
20Cycloalkane, their can and propylene oxide, perhaps react with the mixture of oxirane and propylene oxide.Preferentially select polyhydroxy C for use
3～C
12Alkane and polyhydroxy C
3～C
12Cycloalkane.More preferably select polyhydroxy C for use
3～C
6Alkane and polyhydroxy C
5～C
8Cycloalkane; What override was selected for use is trihydroxy propane.
Operable in the present invention polyhydroxy paraffinic and polyhydroxy naphthenic comprise that being equivalent to molecular formula is R
OH) m hydrocarbon, wherein R and m definition those materials as above.The polyhydroxy paraffinic that is suitable for comprises trihydroxy ethane class, trihydroxy propane class, trihydroxybutane class, trihydroxy pentane class, trihydroxy hexane class, trihydroxy heptane class, trihydroxy octane class, diglycerol, D-sorbite, pentaerythrite, monose, disaccharide, sucrose or its mixture.The polyhydroxy paraffinic of more preferably selecting for use comprises: trihydroxy propane class, trihydroxybutane class, trihydroxy pentane class and trihydroxy hexane class.The polyhydroxy alkane that override is selected for use is 1,2,3-trihydroxy propane." many " refer to 3 or higher.Alkane polyol comprises the C that contains 3～10 oh groups
1～C
20Paraffinic preferentially selects for use and contains 3～8 oh groups, more preferably selects for use to contain 3～6 hydroxyls, and override selects the C that contains 3 hydroxyls for use
1～C
20Paraffinic.
Make polyhydroxy C
1～C
20Paraffinic or polyhydroxy C
3～C
20Naphthenic and propylene oxide reaction, perhaps with the mixture of oxirane and propylene oxide, (wherein this mixture contains the propylene oxide of 50 gram molecule % at least) reaction.Alkylene oxides is equivalent to molecular formula usually:
R in the formula
1Define as above, condition is to have only a R
1It can be methyl.Preferentially make polyhydroxy C
1～C
20Alkane or polyhydroxy C
3～C
20Cycloalkanes and propylene oxide reaction.In the molecular formula of mentioning in the above, R preferentially selects C for use
3～C
12Alkyl group or C
3～C
12Cycloalkyl, more preferably select C for use
3～C
6Alkyl group or C
5～C
8Cycloalkyl, override is selected C for use
3Alkyl group.M preferentially selects 3～8 integer for use, more preferably selects the integer between 3～6 for use, and override selects 3 for use.The preferred value of n is 1～4, and override selects 1～3 for use.
In the presence of base catalyst, for example in the presence of alkali metal hydroxide, amine or boron trifluoride, by making polyhydroxy C
1～C
20Alkane or polyhydroxy C
3～C
20The propylene oxide of cycloalkanes and suitable mole or with the contacted method of mixture of the oxirane and the propylene oxide of suitable mole, prepare foaming agent of the present invention.Usually, operable catalytic amount accounts for 0.5～1% of each reactant gross weight.For this reaction, typical temperature is not higher than 150 ℃, and pressure is not higher than 689kPa.In this specific embodiments, use the mixture of propylene oxide and oxirane, can simultaneously or add propylene oxide and oxirane successively.
Make polyhydroxy C
1～C
20Alkane or polyhydroxy C
3～C
20Cycloalkanes and q.s propylene oxide, perhaps the mixture with q.s oxirane and propylene oxide reacts, so that the product of preparation desired molecule amount, particularly molecular weight is 150～1400 product, more preferably selecting molecular weight for use is 200～800, and override is selected 250～500 product for use.
The sulfide ore that compound of the present invention is suitable for comprises the ore of Containing Sulfur copper, the ore of Containing Sulfur zinc, the ore of Containing Sulfur molybdenum, the ore of Containing Sulfur cobalt, the ore of Containing Sulfur nickel, the ore of Containing Sulfur lead, the ore of Containing Sulfur arsenic, the ore of Containing Sulfur silver, the ore of Containing Sulfur chromium, the ore of Containing Sulfur gold, the ore of Containing Sulfur platinum and the ore of Containing Sulfur uranium.Can use the inventive method, for example comprise the ore of cupric by froth flotation from the sulfide ore of sulphide-rich wherein: for example chessylite (CuS), vitreous copper (Cu
2S), chalcopyrite (CuFeS
2), vallerite (Cu
2Fe
4S
7Perhaps Cu
3Fe
4S
7), bornite (Cu
5FeS
4), chalmersite (Cu
2SFe
4S
5), enargite (Cu
3(As
1Sb) S
4), tetrahedrite (Cu
3SbS
2), tennantite (Cu
12As
4S
13), brochantite (Cu
4(OH)
6SO
4), hydroxyl copper mine (Cu
3SO
4(OH)
4), famatinite (Cu
3(SbAs) S
4) and bournonite (PbCuSbS
3), leaded ore: galena (PbS) for example contains the ore of antimony: stibnite (Sb for example
2S
3), contain the ore of zinc: zincblende (ZnS) for example, the ore of argentiferous: stephanite (Ag for example
5SbS
4) and argentite (Ag
2S), the ore that contains chromium: daubreelite (FeSCrS for example
3) and platiniferous, contain the ore of palladium: cooperite (pt(AsS) for example
2).
The oxide ore that the inventive method is suitable for comprise ore, the titanium-containing oxide of the ore of the ore of copper oxide, the ore that contains aluminum oxide, oxides-containing iron, the ore that contains iron titanium oxide, the ore that contains magnesium aluminum oxide, iron content chromated oxide ore, contain Mn oxide ore, contain the ore of tin-oxide and contain the ore of uranium oxide.Can for example comprise: the ore of cupric with the inventive method by the froth flotation oxide ore of enriched in metals oxide therefrom: cuprite (Cu for example
2O), black copper ore (CuO), malachite (Cu
2(OH)
2CO
3), chessylite (Cu
3(OH)
2(CO
3)
2), atacamite (Cu
2Cl(OH)
3), chrysocolla (CuSiO
3), contain the ore of aluminium: corundum for example contains the ore of zinc: for example zincite (ZnO) and smithsonite (ZnCO
3), the ore of iron content: for example bloodstone and magnetic iron ore, the ore that contains chromium is chromite (FeOCr for example
2O
3), the ore of iron content and titanium: ilmenite for example, the ore that contains magnesium and aluminium: spinelle for example, the ore that contains siderochrome, chromite for example, the ore of titaniferous: rutile for example, the ore that contains manganese: pyrolusite for example, the ore of stanniferous: the ore of cassiterite and uranium-bearing for example: the ore of for example ulrichile, and rich uranium: pitch blende (U for example
2O
5(U
3O
8)) and pittinite (UO
3NH
2O).Other precious metal ore that this method is suitable for comprises: gold containing ore: goldschmiditie (AuAgTe for example
2) and calaverite (AuTe), the ore of platiniferous and palladium: sperrylite (PtAs for example
2), and the ore of argentiferous: hessite (AgTe for example
2).
In the preferred specific embodiments of the present invention, the mineral of oxycompound or sulfide are reclaimed.In the specific embodiments that the present invention more preferably selects, copper sulfide, nickel sulfide, vulcanized lead, zinc sulphide or molybdenum sulfide are reclaimed.In the specific embodiments that override of the present invention is selected for use, copper sulfide is reclaimed.
Employed foaming dosage when froth flotation depends on type, grade and the granularity of ore and the foaming agent of concrete use.In general, this consumption of separable required valuable mineral is suitable from ore, it is found that operable foaming dosage less than the 0.05kg/ metric ton, preferred foaming agent consumption is the 0.0025-0.05kg/ metric ton, and the amount that override is selected for use is the 0.005-0.05kg/ metric ton.Froth flotation method of the present invention needs to use trapping agent usually.Any trapping agent well known in the art is as long as be suitable for reclaiming all being suitable for of required valuable mineral.And in the method for the invention, expection can with the form of other foaming agent composition mixture known in the art under use foaming agent of the present invention.
Operable in the present invention trapping agent for example has single thiocarbonic acid Arrcostab, the dithiocarbonic acids Arrcostab, the trithiocarbonic acid Arrcostab, dialkyl dithiocarbamate, the thionic alkyl carbamate, dialkyl thiourea, the phosphordithiic acid mono alkyl ester, dialkyl dithiophosphate and diaryl ester, the single thiophosphate dialkyl, thiophosphoryl chloride, phosphonodithioic acid dialkyl and diaryl ester, alkyl hydrosulfide, xanthogen formate ester (xanthogen formates), xanthate, mercaptobenzothiazoler, acid of ester fat and soap, alkyl sulfonic acid and salt thereof, alkyl and alkarylsulphonic acid and salt thereof, alkyl phosphoric acid and salt thereof, alkyl and aryl phosphoric acids and salt thereof, the sulfo-succinate, sulfo-butyramide acid esters, primary amine, secondary amine, tertiary amine, quaternary ammonium salt, Fixanol, chinidine and alkyl propylene diamine.And also can use the mixture of these known trapping agents in the present invention.
The foaming agent of above-mentioned introduction also can mix use with other known foaming agent.These known foaming agents for example have C
5～C
8Alcohols, pine tar class, cresols class, the C of polypropylene glycol
1～C
4The dihydroxy thing of alkyl ether, polypropylene glycol, glycols, fatty acid, soap class, alkylaryl sulfonate or the like.And can use the mixture of these foaming agents.In the present invention, all foaming agents that are suitable for froth flotation enrichment ore can use.
Foaming agent of the present invention is compared with for example using methyl isobutyl carbinol (MIBC), and under same recovery level condition, selectivity can improve 5% or more, can improve 10% under optimum condition, can improve 20% under optimum condition.
In order to illustrate that the present invention has provided the following example, but these embodiment do not limit the scope of the scope of the invention or claim.Except as otherwise noted, otherwise all umbers and percentage number average are by weight calculation.
In the following example, the performance that speed constant by providing flotation and the yield in the infinite time illustrate above-mentioned foaming agent composition.These numerals all are to use formula:
r＝R
∝〔1- (l-e
-Kt)/(K
t) 〕
Calculated, r is the valuable mineral amount that is reclaimed in time t in the formula, and K is the speed constant of recovery rate, R
∝It is the valuable mineral amount that in the infinite time, is reclaimed that calculates.Measuring the amount that in different time, is reclaimed, this this equation of series of values substitution is obtained R and K value.In R.Klimpel work " selection of chemistry of Flotation reagent " book (the 45th chapter, 907～934 pages, " design of mineral processing scheme ", and second edition, 1980, AIME(Denver)), above-mentioned formula is illustrated.
Embodiment 1
In this embodiment, checked the situation of three kinds of foaming agent floating cupric sulfides.In rod mill, add 500 grams and lift paddy (Pinto Valley) copper mine, be i.e. chalcopyrite copper-sulphide ores and 257 gram deionized waters.80.2% ore grain size is equal to or less than about 75 microns in this copper mine.The pH value required according to flotation subsequently also adds a certain amount of lime in rod mill.Make this rod mill rotate for 360 weeks then with 60 rev/mins rotating speed.Change the ore pulp that ground over to air-blowing flotation device (Agitair
Flotationmachine) in the 1500ml flotation cell.Stir this flotation cell with 1150 rev/mins speed, add lime then when needed again pH is adjusted to 10.0.
In this flotation cell, add trapping agent-amylic potassium xanthate (0.035kg/ metric ton), be controlled at then and add foaming agent (0.036kg/ metric ton) within 1 minute.Through after the control time another minute, the air speed that feeds this flotation cell is adjusted to 4.5 liters/minute, start automatic de-bubble paddle.At the 8th minute, take out foam sample.In baking oven, make this foam sample dried overnight, simultaneously flotation tailing.The sample of weighing drying is divided into several parts of assay samples, is crushed to required fine granularity, is dissolved in then in the acid so that analyzed.With these samples of direct current plasma analysis of spectral method.Analysis result comes together among the table I.
Digital proof in the table I, foaming agent of the present invention demonstrates the good rate of recovery having for copper under the condition of high selectivity to copper.The selectivity of foaming agent of the present invention with the foaming agent of commercial sale of common test compare better.When the fine mineral flotation, if use different foaming agents, the difference on the precious metals rate of recovery is then quite little.The maximum differential on effect between difference spumes shows (being selectivity) on the gangue amount that reclaims in the foam.
In the table II of table I and back, MIBC refers to methyl isobutyl carbinol.DF-200 is meant DOWFROTH here
200 (trade marks of Dow Chemical Company (The Dow Chemical Company)), it is the methyl ether that mean molecule quantity is approximately 200 propane diols.DF-250 is meant DOWFROTH here
The trade mark of 250(Dow Chemical Company), it is that mean molecule quantity is the methyl ether of about 250 polypropylene glycol.DF-1012 refers to DOWFROTH
The trade mark of 1012(Dow Chemical Company), it is the methyl ether that mean molecule quantity is approximately 400 polypropylene glycol.Voranol
2025 are meant that here mean molecule quantity is 250 the product by glycerine and propylene oxide.Voranol
CP 450 is meant that here mean molecule quantity is 700 the product by glycerine and propylene oxide.Voranol
R2070 are meant that here mean molecule quantity is 700 the product by glycerine and propylene oxide.D-sorbite
/ propylene oxide adduct is meant that here mean molecule quantity is that 762(or equivalent are 127) by D-sorbite
Product with propylene oxide.Sucrose-propylene oxide adduct is meant that here mean molecule quantity is that 984(or equivalent are 123) the product by sucrose and propylene oxide.
The table I
The arteries and veins selectivity that the gangue that copper reclaims reclaims
1Selectivity
2
Foaming agent
Rate (%) copper (gram) rate (%) stone (gram) is (gram) (%)
DF-200
30.891 6.68 0.081 39.9 11.0 0.168
MIBC
30.880 6.60 0.088 43.3 10.0 0.152
DF-250
30.884 6.63 0.093 45.8 9.5 0.145
DF-1012
30.877 6.58 0.110 54.2 8.0 0.121
Voranol
0.847 6.35 0.048 23.6 17.6 0.269
2025
CP450 0.913 6.85 0.069 34.0 13.2 0.202
Voranol
0.908 6.81 0.071 35.0 12.8 0.195
2070
50/50
DF-1012 0.901 6.76 0.085 41.9 10.6 0.162
+CP450
1Selectivity=(percentage that copper reclaims)/(percentage that gangue reclaims)
2Selectivity=(the gram number of copper)/(the gram number of gangue)
3Not embodiments of the invention.
Embodiment 2
Adopt the operating procedure of embodiment 1, use froth flotation machine flotation EL Teniente copper mine, wherein 91.1% ore grain size is equal to or less than 75 microns.The pH value of moisture ore pulp is 8.5 in flotation cell.Trapping agent is isopropyl methyl thionic carbamate (Z-200
, the trade (brand) name of Dow Chemical Company), consumption is the 0.062kg/ ton.The working concentration of foaming agent is the 0.025kg/ ton.Experimental result comes together among the table II.
Foaming agent of the present invention is used in the digital proof of table II, compares with the commodity foaming agent that is used for comparison, has the higher rate of recovery for copper.And foaming agent of the present invention compares with the commodity foaming agent of employing, at copper with respect to unexpected good aspect the selectivity of gangue.
The table II
Gangue reclaims
The copper recovery gangue selectivity that the foaming agent copper recovery reclaims
1Selectivity
2
(%) (gram) (%) (gram) (%) (gram)
MIBC
30.914 10.05 0.091 44.5 10.0 0.226
DF-200
30.908 9.99 0.088 43.0 10.3 0.233
DF-1012
30.867 9.54 0.115 56.2 7.5 0.170
CP-450 0.931 10.24 0.081 39.6 11.5 0.258
Sorbose
Alcohol
-
Propylene oxide 0.935 10.28 0.078 38.1 12.0 0.270
Adduct
50/50
DF-1012 0.904 9.94 0.098 47.9 9.2 0.208
+CP450
Sucrose-
Propylene oxide 0.928 10.21 0.084 41.1 11.0 0.248
Adduct
1Selectivity is the recovery per cent of copper and the ratio of gangue recovery per cent.
2Selectivity is the gram number of copper and the ratio of gangue gram number.
3Not embodiments of the invention.
Embodiment 3
In the present embodiment, tested the situation of three kinds of foaming agent floating cupric sulfides.In advance 500 gram copper mine stone-chalcopyrite copper sulfide ores are placed the rod mill that is added with 257 gram deionized waters.According to the required pH of later flotation, in this rod mill, also add a certain amount of lime.Make then this rod mill 60 rev/mins down rotation 360 change account for 50.1% raw material so that make granularity less than 75 microns ore charge.The ore pulp that ground is changed in the 1500ml flotation cell of air-blowing flotation device.Be to stir this flotation cell under 1150 rev/mins the condition at rotating speed, and add other lime where necessary pH is adjusted to required pH(10.0).
In this flotation cell, add trapping agent-amylic potassium xanthate (0.004kg/ metric ton), be controlled at then and add foaming agent (0.058kg/ metric ton) within 1 minute.After other 1 minute control time, the air conditioning in the feeding flotation cell under 4.5 liters/minute speed, is started automatic de-bubble blade then.Got foam 8 minutes.In baking oven, make this foam sample dried overnight, simultaneously flotation tailing.The sample of weighing drying is divided into several parts of analytic samples, is crushed to required fineness, is dissolved in the acid then and is analyzed.Adopt these samples of direct current plasma analysis of spectral method.In computer program, use foam sample weight, mine tailing example weight and the analysis result that reclaims, calculate the rate of recovery of metal and gangue, and parameters R and K value.Experimental result comes together among the table III.
The table III proves that when using CP-450 foaming agent of the present invention, granularity is very high less than about 200 microns copper particle rate of recovery.Granularity greater than 200 microns coarse grain in and granularity be lower than in 200 microns the particulate, the gangue rate of recovery is all very low.Therefore, the recovery selectivity for coarse grain and particulate copper mine is all very high.Selectivity percentage for the particulate copper mine has improved 19% at least.
The table III
Copper gangue selectivity
1Selectivity
1
Foaming agent R R R R+200-200
8 minutes 8 minutes 8 minutes 8 minutes R R
(+200) (200) (+200) (200) Cu/R gangue Cu/R gangue
DF-200
20.835 0.936 0.071 0.095 11.8 9.9
MIBC
20.830 0.923 0.074 0.110 11.2 8.4
DF-1012
20.935 0.889 0.084 0.148 11.1 6.0
CP-450 0.802 0.930 0.062 0.079 12.9 11.8
CP-450/
DF-1012 0.917 0.907 0.077 0.098 11.9 9.3
（50/50）
1Selectivity=(rate of recovery of Cu (%))/(rate of recovery of gangue (%))
2Not embodiments of the invention
Claims (3)
1, from ore, reclaim the method for particulate valuable mineral, comprising:
(1) make the step of ore classification, so as to make 75% or more ore grain size reach 75 microns or littler,
(2) ore is carried out froth flotation processing for the first time so that granularity is reclaimed in foam greater than 75 microns valuable mineral, wherein said 75 microns or following valuable mineral are stayed in the moisture ore pulp,
(3) in the presence of collection agent and floatation frother, moisture ore pulp is carried out flotation handle, wherein said foaming agent comprises: by
Polyhydroxy alkane or the polyhydroxy cycloalkanes of ((3) .1) formula R (OH) m, wherein R is 1-20 carbochain alkane or 3-20 carbon naphthene, m is the integer of 3-10, monose, disaccharide or its mixture and
((3) .2) propylene oxide, the perhaps product between the mixture of forming by propylene oxide and oxirane,
Condition is to contain 50% propylene oxide in said mixture at least, and the molecular weight of wherein said product is 150 to 1400.
Wherein said foaming agent adds moisture ore pulp according to the ratio that is lower than 0.05kg/ metric ton ore.
2, in accordance with the method for claim 1, wherein said foaming agent is 1,2, the product between 3-trihydroxy propane and the propylene oxide, and said product molecular weight is 200 to 800.
3, in accordance with the method for claim 1, wherein said ore is metallic sulfide ores, metal oxide ore, gold containing ore, contains platinum ore, contains the palladium ore or contain silver ore.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN85106476A CN1006689B (en) | 1984-09-13 | 1985-08-28 | Recovery of usable mineral from ore by foaming agent composite and foaming flotation |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64989084A | 1984-09-13 | 1984-09-13 | |
| CN85106476A CN1006689B (en) | 1984-09-13 | 1985-08-28 | Recovery of usable mineral from ore by foaming agent composite and foaming flotation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN85106476A CN85106476A (en) | 1987-03-25 |
| CN1006689B true CN1006689B (en) | 1990-02-07 |
Family
ID=24606650
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN85107378A Pending CN85107378A (en) | 1984-09-13 | 1985-08-27 | Frother composition and froth flotation process for recovering useful coal from raw coal |
| CN85106476A Expired CN1006689B (en) | 1984-09-13 | 1985-08-28 | Recovery of usable mineral from ore by foaming agent composite and foaming flotation |
| CN85109643A Expired - Fee Related CN1020551C (en) | 1984-09-13 | 1985-10-12 | Process for froth flotation of useful components of minerals |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN85107378A Pending CN85107378A (en) | 1984-09-13 | 1985-08-27 | Frother composition and froth flotation process for recovering useful coal from raw coal |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN85109643A Expired - Fee Related CN1020551C (en) | 1984-09-13 | 1985-10-12 | Process for froth flotation of useful components of minerals |
Country Status (23)
| Country | Link |
|---|---|
| EP (1) | EP0174866B1 (en) |
| JP (2) | JPS6186960A (en) |
| KR (1) | KR900002702B1 (en) |
| CN (3) | CN85107378A (en) |
| AR (1) | AR242135A1 (en) |
| AU (1) | AU562083B2 (en) |
| BR (1) | BR8504419A (en) |
| CA (1) | CA1265877A (en) |
| DE (1) | DE3587166D1 (en) |
| ES (1) | ES8700699A1 (en) |
| FI (1) | FI79951C (en) |
| MX (1) | MX169955B (en) |
| MY (1) | MY101975A (en) |
| NO (1) | NO166846C (en) |
| PH (1) | PH21358A (en) |
| PL (1) | PL146943B1 (en) |
| RO (1) | RO95694B (en) |
| SU (1) | SU1419507A3 (en) |
| TR (1) | TR25780A (en) |
| YU (1) | YU45741B (en) |
| ZA (1) | ZA856955B (en) |
| ZM (1) | ZM6585A1 (en) |
| ZW (1) | ZW15285A1 (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH24537A (en) * | 1985-11-29 | 1990-08-03 | Dow Chemical Co | Collector composition for the froth flotation of mineral values |
| DE3716012A1 (en) * | 1987-05-11 | 1988-11-24 | Gerhard Dr Rer Nat Heinrich | Process for concentrating lead compounds |
| US5087757A (en) * | 1987-12-16 | 1992-02-11 | The Dow Chemical Company | Preparation of alkylthioethylamine salts |
| US5061459A (en) * | 1989-10-27 | 1991-10-29 | The British Petroleum Company P.L.C. | Prevention of copper dissolution during cyanidation of gold ores |
| ZA918140B (en) * | 1991-10-11 | 1992-07-29 | American Cyanamid Co | Recovery of platinum group metals and gold by synergistic reaction between allylalkylthionocarbamates and dithiophosphates |
| US5700369A (en) * | 1997-01-14 | 1997-12-23 | Guangzhou Institute Of Geochemistry Chinese Academy Of Sciences | Process for adsorboaggregational flotation of Carlin type natural gold ore dressing |
| US6833460B2 (en) | 1999-06-18 | 2004-12-21 | E. I. Du Pont De Nemours And Company | Preparation and use of gamma-butyrolactones as cross-linking agents |
| WO2007059559A1 (en) * | 2005-11-22 | 2007-05-31 | Barry Graham Lumsden | Improving mineral recovery from ore |
| AU2006317498B2 (en) * | 2005-11-22 | 2010-10-14 | Barry Graham Lumsden | Improving mineral recovery from ore |
| RU2315748C1 (en) * | 2006-10-06 | 2008-01-27 | Федеральное Государственное Образовательное Учреждение Высшего Профессионального Образования "Южный Федеральный Университет" | N,N'-BIS-(9-ANTHRYLMETHYL)CYCLOHEXANE-1,2-DIAMINE AS FLUORESCENT CHEMOSENSOR FOR CATIONS Zn2+ |
| US10522883B2 (en) | 2010-05-10 | 2019-12-31 | Rsr Technologies, Inc. | Recycling electrochemical cells and batteries |
| SI3066089T1 (en) | 2013-11-08 | 2020-03-31 | Promentis Pharmaceuticals, Inc. | Substituted n-acetyl-l-cysteine derivatives and related compounds |
| CN104028387B (en) * | 2014-06-17 | 2017-01-25 | 扬州大学 | Synthesis of novel coal flotation agent |
| CN104874488B (en) * | 2015-06-05 | 2017-05-24 | 昆明冶金研究院 | Collecting agent and preparation method and application thereof |
| CN106669959B (en) * | 2016-06-20 | 2019-02-22 | 中国矿业大学 | A kind of flotation agent for fine medium coal and its application |
| CN107138289B (en) * | 2017-06-26 | 2019-07-12 | 乌拉特前旗西沙德盖钼业有限责任公司 | A kind of cationic selects flotation frother |
| CN109174463B (en) * | 2018-08-21 | 2020-02-28 | 中国矿业大学 | Collector for flotation of oxidized coal slime and preparation method and flotation method |
| JP7344504B2 (en) * | 2018-09-14 | 2023-09-14 | 国立大学法人九州大学 | Ore beneficiation method |
| CN109365138B (en) * | 2018-11-30 | 2021-03-05 | 河南城建学院 | A new type of composite flotation agent for flotation of copper-nickel sulfide ore |
| CN109530094B (en) * | 2019-01-17 | 2021-05-28 | 湖南中医药大学 | Amidohydroxycarboxylic acid/hydroxamic acid compounds and their application in mineral flotation |
| CN110015727B (en) * | 2019-05-09 | 2021-07-09 | 安徽工业大学 | A kind of method for electrolytic air flotation to remove microplastics in water body |
| CN116209525A (en) * | 2020-08-11 | 2023-06-02 | 巴斯夫欧洲公司 | Method for flotation of silicate-containing iron ore |
| CN112058502B (en) * | 2020-09-07 | 2021-08-27 | 中南大学 | Efficient flotation collector for zinc sulfide and application thereof |
| US12036286B2 (en) | 2021-03-18 | 2024-07-16 | Seagen Inc. | Selective drug release from internalized conjugates of biologically active compounds |
| CN113245064A (en) * | 2021-04-30 | 2021-08-13 | 瓮福（集团）有限责任公司 | Method for removing sesquioxide in complex refractory collophanite |
| US20230302464A1 (en) * | 2022-03-25 | 2023-09-28 | Clariant International, Ltd. | Novel Cationic Collectors for Improving a Process for Froth Flotation of Silicates |
| CN117085852A (en) * | 2023-09-20 | 2023-11-21 | 广西高峰矿业有限责任公司 | Application of a lead sulfide collector in the flotation of complex multi-metal mixed minerals |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB547292A (en) * | 1940-03-30 | 1942-08-21 | American Cyanamid Co | Concentration process for separating acidic minerals from ore materials |
| US2364272A (en) * | 1941-09-04 | 1944-12-05 | American Cyanamid Co | Mineral concentration |
| GB554814A (en) * | 1941-09-06 | 1943-07-20 | American Cyanamid Co | Concentration of acidic minerals |
| US2365084A (en) * | 1942-03-31 | 1944-12-12 | American Cyanamid Co | Beneficiation of acidic minerals |
| GB578695A (en) * | 1943-04-20 | 1946-07-09 | American Cyanamid Co | Improvements in or relating to methods of concentrating ores |
| FR1136073A (en) * | 1955-11-09 | 1957-05-09 | Penarroya Miniere Metall | Improvements to the flotation process for oxidized zinc ores |
| US3772345A (en) * | 1970-09-08 | 1973-11-13 | Dow Chemical Co | Process for preparing n-alkylthioalkyl-o-alkylthiocarbamates and n-alkyl-thioalkyl-o-alkylcarbamates |
| BE795146A (en) * | 1972-02-08 | 1973-08-08 | Dow Chemical Co | IMPROVEMENTS RELATED TO THE FLOTATION OF SULPHIDE ORES |
| CA1006277A (en) * | 1973-10-11 | 1977-03-01 | Harvey L. Noblitt | Scheelite flotation |
| DE2547987C2 (en) * | 1975-10-27 | 1983-05-26 | Henkel KGaA, 4000 Düsseldorf | Flotation collector for Sylvin |
| JPS5599356A (en) * | 1979-01-25 | 1980-07-29 | Dow Chemical Co | Additive for alkanol amineetolu oil fatty acid coal flotation method |
| US4422928A (en) * | 1981-03-09 | 1983-12-27 | Exxon Research & Engineering Co. | Silica flotation collectors derived from isononyl alcohol |
| DE3128755A1 (en) * | 1981-07-21 | 1983-02-10 | Hoechst Ag, 6000 Frankfurt | 3-ALKOXIPROPYLENIMINO BIS (METHYLENE PHOSPHONIC ACIDS) AND THE SALTS THEREOF, METHOD FOR THE PRODUCTION AND USE THEREOF |
| JPS58104651A (en) * | 1981-12-15 | 1983-06-22 | ザ・ダウ・ケミカル・カンパニ− | Condensate of fatty acid and hydroxyalkylated polyalkylene polyamine as auxiliary agent coal froth flotation method |
-
1985
- 1985-08-27 CN CN85107378A patent/CN85107378A/en active Pending
- 1985-08-28 CN CN85106476A patent/CN1006689B/en not_active Expired
- 1985-09-04 CA CA000489953A patent/CA1265877A/en not_active Expired - Lifetime
- 1985-09-11 ZA ZA856955A patent/ZA856955B/en unknown
- 1985-09-12 AU AU47397/85A patent/AU562083B2/en not_active Ceased
- 1985-09-12 PH PH32772A patent/PH21358A/en unknown
- 1985-09-12 FI FI853490A patent/FI79951C/en not_active IP Right Cessation
- 1985-09-12 BR BR8504419A patent/BR8504419A/en not_active IP Right Cessation
- 1985-09-12 AR AR85301597A patent/AR242135A1/en active
- 1985-09-12 SU SU853957505A patent/SU1419507A3/en active
- 1985-09-12 ES ES546919A patent/ES8700699A1/en not_active Expired
- 1985-09-12 NO NO853580A patent/NO166846C/en unknown
- 1985-09-13 EP EP85306521A patent/EP0174866B1/en not_active Expired - Lifetime
- 1985-09-13 KR KR1019850006709A patent/KR900002702B1/en not_active Expired
- 1985-09-13 PL PL1985255363A patent/PL146943B1/en unknown
- 1985-09-13 JP JP60201886A patent/JPS6186960A/en active Granted
- 1985-09-13 ZW ZW152/85A patent/ZW15285A1/en unknown
- 1985-09-13 RO RO120103A patent/RO95694B/en unknown
- 1985-09-13 ZM ZM65/85A patent/ZM6585A1/en unknown
- 1985-09-13 YU YU144085A patent/YU45741B/en unknown
- 1985-09-13 DE DE8585306521T patent/DE3587166D1/en not_active Expired - Lifetime
- 1985-09-13 TR TR85/38005A patent/TR25780A/en unknown
- 1985-09-13 MX MX206628A patent/MX169955B/en unknown
- 1985-10-12 CN CN85109643A patent/CN1020551C/en not_active Expired - Fee Related
-
1986
- 1986-09-03 JP JP61207634A patent/JPS63107761A/en active Pending
-
1987
- 1987-08-10 MY MYPI87001262A patent/MY101975A/en unknown
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1006689B (en) | Recovery of usable mineral from ore by foaming agent composite and foaming flotation | |
| CN1036507C (en) | Activator-frother composition of good selectivity which can be used as additional reagent for the flotation | |
| CN1011765B (en) | Froth Flotation Method for Sulfide Minerals | |
| FI78242C (en) | Procedure for flotation of minerals from ore | |
| JP5856649B2 (en) | Dithiocarbamate compounds used in scavenger compositions for beneficiation of ore bodies | |
| CN1056445A (en) | The method that suppresses silica or siliceous gangue flotation in the mineral floating process | |
| JP5502006B2 (en) | Copper concentrate processing method | |
| CN86101646A (en) | The new collector composition that is used for froth flotation method | |
| US12458984B2 (en) | Application of selenium-containing organic compounds in copper sulfide flotation collectors | |
| CA1265265A (en) | Frother composition and a froth flotation process for the recovery of mineral | |
| US4246096A (en) | Flotation process | |
| JP2012201922A (en) | Method for treating copper concentrate | |
| JP2013155426A (en) | Method for treating copper concentrate | |
| JP2557125B2 (en) | Recovery of valuable minerals by foam flotation | |
| CN1294032A (en) | Precious metal and non-ferrous metal sulfide ore compound flotation agent | |
| JP2012201920A (en) | Method for treating copper concentrate | |
| JP5888780B2 (en) | Copper concentrate processing method | |
| USRE32778E (en) | Frothers demonstrating enhanced recovery of coarse particles in froth floatation | |
| GB2029274A (en) | Recovery of metal concentrates from mineral ores | |
| CA3170236A1 (en) | New frothers for minerals recovery | |
| CN1078927A (en) | Dense moisture phosphordithiic acid slaine and application process thereof | |
| CA1093225A (en) | Ore flotation with an aliphatic aldoxime | |
| GB2046747A (en) | 2-mercaptopyridine derivatives and their use in the recovery of metal concentrates | |
| CN1911528A (en) | Ore flotation activator and its preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |