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CN107163695A - A kind of fireproof coating for high security tray type cable bridge - Google Patents

A kind of fireproof coating for high security tray type cable bridge Download PDF

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Publication number
CN107163695A
CN107163695A CN201710578200.9A CN201710578200A CN107163695A CN 107163695 A CN107163695 A CN 107163695A CN 201710578200 A CN201710578200 A CN 201710578200A CN 107163695 A CN107163695 A CN 107163695A
Authority
CN
China
Prior art keywords
parts
fireproof coating
high security
type cable
cable bridge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710578200.9A
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Chinese (zh)
Inventor
郭宏富
张炳林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhenjiang Shenlong Electric Appliance Pipe Parts Co Ltd
Original Assignee
Zhenjiang Shenlong Electric Appliance Pipe Parts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhenjiang Shenlong Electric Appliance Pipe Parts Co Ltd filed Critical Zhenjiang Shenlong Electric Appliance Pipe Parts Co Ltd
Priority to CN201710578200.9A priority Critical patent/CN107163695A/en
Publication of CN107163695A publication Critical patent/CN107163695A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06Copolymers with styrene
    • C09D109/08Latex
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/02Halogenated hydrocarbons
    • C08K5/03Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a kind of fireproof coating for high security tray type cable bridge, in terms of weight fraction, including 100 120 parts of inorganic filler, 20 40 parts of binding agent, 50 80 parts of n-butanol, 10 20 parts of plasticizer, 10 20 parts of drier, 20 40 parts of fire retardant, 10 20 parts of preservative;Fireproof coating prepared by the present invention has excellent fire resistance, and heat-proof quality is strong, and excellent fire retarding performance, environmental pollution is small, and the cementability of fireproof coating of the present invention and crane span structure matrix is strong, good combination property;Cobalt iso-octoate is small with smell compared with traditional cobalt naphthenate, urges the features such as dry effect is good, isooctyl acid cerium can improve hardness and toughness, and can improve gloss and gloss retention;After testing, fireproof coating of the present invention meets GB14907 2002《Fire-resistant coating for steel structure general technical specifications》Standard, fire endurance reaches 3h 3.5h.

Description

A kind of fireproof coating for high security tray type cable bridge
Technical field
The present invention relates to cable testing bridge field, and in particular to a kind of fire prevention for high security tray type cable bridge is applied Material.
Background technology
Cable testing bridge system is the class staple product in manufacturing industry, is to be used for specification, protection in each infrastructure project The main equipment of cable and transmission line safety.General cable testing bridge is from high-quality is cold rolling or the steel plate such as hot rolling, heat zinc coating plate.By Non-ignitable in steel construction itself, the fire safety problem of steel construction was once once being ignored by people.Report and have according to domestic and international relevant information The experiment of shutting mechanism and statistics show that the mechanical strength of steel construction is reduced with the rise of temperature, at 500 DEG C or so, its Intensity drops to 40%~50%, the mechanical property of steel construction, such as yield point, compression strength, modulus of elasticity and load energy Power etc. is all rapid to be declined, and enabling capabilities are lost quickly, cause crane span structure to collapse.Therefore, steel construction is carried out protecting imperative.Steel Structure fire coating is brushed or is sprayed on steel structure surface, is played fire-proof and thermal-insulation, is prevented steel construction to be brought rapidly up in a fire And reducing intensity, it is to avoid steel construction loses enabling capabilities and causes crane span structure to collapse.
The content of the invention
In order to solve problems of the prior art, it is used for high security pellet type cable bridge the invention provides one kind The fireproof coating of frame, with preferable fire protecting performance.
Technical proposal that the invention solves the above-mentioned problems is:A kind of fire prevention for high security tray type cable bridge is applied Material, the preparation process of the fireproof coating is as follows:
(1) in terms of weight fraction, 100-120 parts of inorganic filler, 20-40 parts of binding agent, 50-80 parts of n-butanol, increasing are weighed Mould 10-20 parts of agent, 10-20 parts of drier, 20-40 parts of fire retardant, 10-20 parts of preservative;
(2) preservative, n-butanol, binding agent are added into stirrer for mixing uniformly, whipping temp is 50-70 DEG C, stirring Time is 1-2h, obtains mixed emulsion;
(3) order of liquid material after inorganic filler, plasticizer, drier, the first powder of fire retardant is added sequentially to stand In formula ball mill, after ball milling 0.5h, mixture is obtained;
(4) add mixture in mixer, then be slowly added into mixed emulsion, with 200r/min speed in mixer Degree stirring mixing 0.5h, whipping temp is 50-70 DEG C, stands 4h after insulation 1h, that is, obtains fireproof coating.
The inorganic filler is precipitated calcium carbonate, wollastonite, and precipitated calcium carbonate, the weight ratio of wollastonite are 2:1;It is described to urge Dry agent is cobalt iso-octoate, isooctyl acid cerium, and cobalt iso-octoate, the weight ratio of isooctyl acid cerium are 2:1;The preservative is triethanolamine salt Hydrochlorate, 1'3- double methylolurea, dibutyl hydroxy toluene, deionized waters, triethanolamine hydrochloride, 1'3- double methylolurea, two Butylated hydroxytoluene, the weight ratio of deionized water are 5:2:5:50.
The fire retardant is the one or more in TDE, brominated epoxy resin, melamine;The bonding Agent is the one or more in sodium metasilicate, potassium silicate, aluminum phosphate, furane resins, halogenated olefins resin, styrene-butadiene emulsion;It is described to increase Modeling agent is one or both of organophosphorus ester, oxygen chloropropane.
The present invention has beneficial effect:Fireproof coating prepared by the present invention has excellent fire resistance, heat-proof quality By force, excellent fire retarding performance, environmental pollution is small, and the cementability of fireproof coating of the present invention and crane span structure matrix is strong, combination property It is good;Cobalt iso-octoate is small with smell compared with traditional cobalt naphthenate, urges the features such as dry effect is good, and isooctyl acid cerium can improve hardness And toughness, and gloss and gloss retention can be improved;After testing, fireproof coating of the present invention meets GB14907-2002《Steel construction Fireproof coating general technical specifications》Standard, fire endurance reaches 3h-3.5h.
Embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment 1
A kind of fireproof coating for high security tray type cable bridge, the preparation process of the fireproof coating is as follows:
(1) in terms of weight fraction, weigh precipitated calcium carbonate 80,40 parts of wollastonite, 40 parts of styrene-butadiene emulsion, 80 parts of n-butanol, 20 parts of organophosphorus ester, cobalt iso-octoate 10,5 parts of isooctyl acid cerium, 40 parts of TDE, 20 parts of preservative;
(2) preservative, n-butanol, styrene-butadiene emulsion are added into stirrer for mixing uniformly, whipping temp is 70 DEG C, during stirring Between be 2h, obtain mixed emulsion;
(3) by precipitated calcium carbonate, wollastonite, organophosphorus ester, cobalt iso-octoate, isooctyl acid cerium, TDE according to The order of liquid material is added sequentially in vertical ball mill after first powder, after ball milling 0.5h, obtains mixture;
(4) add mixture in mixer, then be slowly added into mixed emulsion, with 200r/min speed in mixer Degree stirring mixing 0.5h, whipping temp is 70 DEG C, stands 4h after insulation 1h, that is, obtains fireproof coating.
The preservative is triethanolamine hydrochloride, 1'3- double methylolurea, dibutyl hydroxy toluene, deionized waters, three The double methylolureas of ethanolamine hydrochloric salt, 1'3-, dibutyl hydroxy toluene, the weight ratio of deionized water are 5:2:5:50.
Embodiment 2
A kind of fireproof coating for high security tray type cable bridge, the preparation process of the fireproof coating is as follows:
(1) in terms of weight fraction, weigh precipitated calcium carbonate 80,40 parts of wollastonite, 20 parts of styrene-butadiene emulsion, 80 parts of n-butanol, 20 parts of organophosphorus ester, 10 parts of cobalt iso-octoate, 5 parts of isooctyl acid cerium, 20 parts of melamine, 10 parts of preservative;
(2) preservative, n-butanol, styrene-butadiene emulsion are added into stirrer for mixing uniformly, whipping temp is 70 DEG C, during stirring Between be 1h, obtain mixed emulsion;
(3) by precipitated calcium carbonate, wollastonite, organophosphorus ester, cobalt iso-octoate, isooctyl acid cerium, melamine according to first powder The order of liquid material is added sequentially in vertical ball mill after material, after ball milling 0.5h, obtains mixture;
(4) add mixture in mixer, then be slowly added into mixed emulsion, with 200r/min speed in mixer Degree stirring mixing 0.5h, whipping temp is 70 DEG C, stands 4h after insulation 1h, that is, obtains fireproof coating.
The preservative is triethanolamine hydrochloride, 1'3- double methylolurea, dibutyl hydroxy toluene, deionized waters, three The double methylolureas of ethanolamine hydrochloric salt, 1'3-, dibutyl hydroxy toluene, the weight ratio of deionized water are 5:2:5:50.
Embodiment 3
A kind of fireproof coating for high security tray type cable bridge, the preparation process of the fireproof coating is as follows:
(1) in terms of weight fraction, weigh precipitated calcium carbonate 80,40 parts of wollastonite, 20 parts of styrene-butadiene emulsion, 50 parts of n-butanol, 10 parts of oxygen chloropropane, 8 parts of cobalt iso-octoate, 4 parts of isooctyl acid cerium, 20 parts of brominated epoxy resin, 20 parts of preservative;
(2) preservative, n-butanol, styrene-butadiene emulsion are added into stirrer for mixing uniformly, whipping temp is 50 DEG C, during stirring Between be 1h, obtain mixed emulsion;
(3) by precipitated calcium carbonate, wollastonite, oxygen chloropropane, cobalt iso-octoate, isooctyl acid cerium, brominated epoxy resin according to elder generation The order of liquid material is added sequentially in vertical ball mill after powder, after ball milling 0.5h, obtains mixture;
(4) add mixture in mixer, then be slowly added into mixed emulsion, with 200r/min speed in mixer Degree stirring mixing 0.5h, whipping temp is 50 DEG C, stands 4h after insulation 1h, that is, obtains fireproof coating.
The preservative is triethanolamine hydrochloride, 1'3- double methylolurea, dibutyl hydroxy toluene, deionized waters, three The double methylolureas of ethanolamine hydrochloric salt, 1'3-, dibutyl hydroxy toluene, the weight ratio of deionized water are 5:2:5:50.
After testing, the fireproof coating that prepared by embodiment 1-3 meets GB14907-2002《Fire-resistant coating for steel structure general technology Condition》Standard, fire endurance reaches 3h-3.5h.
Many other changes and remodeling can be made by not departing from the spirit and scope of the present invention.It should be appreciated that the present invention is not It is limited to specific embodiment, the scope of the present invention is defined by the following claims.

Claims (6)

1. a kind of fireproof coating for high security tray type cable bridge, it is characterised in that the preparation process of fireproof coating It is as follows:
(1) in terms of weight fraction, 100-120 parts of inorganic filler, 20-40 parts of binding agent, 50-80 parts of n-butanol, plasticizer are weighed 10-20 parts, 10-20 parts of drier, 20-40 parts of fire retardant, 10-20 parts of preservative;
(2) preservative, n-butanol, binding agent are added into stirrer for mixing uniformly, whipping temp is 50-70 DEG C, mixing time For 1-2h, mixed emulsion is obtained;
(3) order of liquid material after inorganic filler, plasticizer, drier, fire retardant county powder is added sequentially to vertical ball In grinding machine, after ball milling 0.5h, mixture is obtained;
(4) add mixture in mixer, then be slowly added into mixed emulsion, stirred in mixer with 200r/min speed Mixing 0.5min is mixed, whipping temp is 50-70 DEG C, stands 4h after insulation 1h, that is, obtains fireproof coating.
2. a kind of fireproof coating for high security tray type cable bridge as claimed in claim 1, it is characterised in that institute Inorganic filler is stated for precipitated calcium carbonate, wollastonite, precipitated calcium carbonate, the weight ratio of wollastonite are 2:1.
3. a kind of fireproof coating for high security tray type cable bridge as claimed in claim 1, it is characterised in that institute Drier is stated for cobalt iso-octoate, isooctyl acid cerium, cobalt iso-octoate, the weight ratio of isooctyl acid cerium are 2:1.
4. a kind of fireproof coating for high security tray type cable bridge as claimed in claim 1, it is characterised in that institute It is triethanolamine hydrochloride, 1'3- double methylolurea, dibutyl hydroxy toluene, deionized waters, triethanolamine hydrochloric acid to state preservative The double methylolureas of salt, 1'3-, dibutyl hydroxy toluene, the weight ratio of deionized water are 5:2:5:50.
5. a kind of fireproof coating for high security tray type cable bridge as claimed in claim 1, it is characterised in that institute It is the one or more in TDE, brominated epoxy resin, melamine to state fire retardant.
6. a kind of fireproof coating for high security tray type cable bridge as claimed in claim 1, it is characterised in that institute It is the one or more in sodium metasilicate, potassium silicate, aluminum phosphate, furane resins, halogenated olefins resin, styrene-butadiene emulsion to state binding agent; The plasticizer is one or both of organophosphorus ester, oxygen chloropropane.
CN201710578200.9A 2017-07-16 2017-07-16 A kind of fireproof coating for high security tray type cable bridge Pending CN107163695A (en)

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CN201710578200.9A CN107163695A (en) 2017-07-16 2017-07-16 A kind of fireproof coating for high security tray type cable bridge

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Application Number Priority Date Filing Date Title
CN201710578200.9A CN107163695A (en) 2017-07-16 2017-07-16 A kind of fireproof coating for high security tray type cable bridge

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111945974A (en) * 2020-08-19 2020-11-17 江苏凯丰幕墙材料有限公司 Manufacturing method of environment-friendly aluminum veneer
CN115678369A (en) * 2022-11-18 2023-02-03 河北悠扬时代环保科技有限公司 High-corrosion-resistance water-based acrylic polysiloxane protective paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126743A (en) * 1995-03-22 1996-07-17 武汉市高校新技术研究所 Special antirust anticorrosive paint HCPE
WO1999067315A1 (en) * 1998-06-25 1999-12-29 Abb Corporate Research Ltd. Resin system
CN1800283A (en) * 2005-01-05 2006-07-12 中国科学院过程工程研究所 Insulating mold coating and its uses
CN102260450A (en) * 2011-02-17 2011-11-30 湖南晟通科技集团有限公司 Anticorrosive paint
CN106634616A (en) * 2016-12-06 2017-05-10 广西科技大学 Preparation method of composite rare earth drier for oil paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126743A (en) * 1995-03-22 1996-07-17 武汉市高校新技术研究所 Special antirust anticorrosive paint HCPE
WO1999067315A1 (en) * 1998-06-25 1999-12-29 Abb Corporate Research Ltd. Resin system
CN1800283A (en) * 2005-01-05 2006-07-12 中国科学院过程工程研究所 Insulating mold coating and its uses
CN102260450A (en) * 2011-02-17 2011-11-30 湖南晟通科技集团有限公司 Anticorrosive paint
CN106634616A (en) * 2016-12-06 2017-05-10 广西科技大学 Preparation method of composite rare earth drier for oil paint

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111945974A (en) * 2020-08-19 2020-11-17 江苏凯丰幕墙材料有限公司 Manufacturing method of environment-friendly aluminum veneer
CN115678369A (en) * 2022-11-18 2023-02-03 河北悠扬时代环保科技有限公司 High-corrosion-resistance water-based acrylic polysiloxane protective paint and preparation method thereof

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Application publication date: 20170915