CN106381235A - Ultra-concentrated multifunctional laundry sheet and preparation method thereof - Google Patents
Ultra-concentrated multifunctional laundry sheet and preparation method thereof Download PDFInfo
- Publication number
- CN106381235A CN106381235A CN201610743605.9A CN201610743605A CN106381235A CN 106381235 A CN106381235 A CN 106381235A CN 201610743605 A CN201610743605 A CN 201610743605A CN 106381235 A CN106381235 A CN 106381235A
- Authority
- CN
- China
- Prior art keywords
- hyperconcetration
- garment piece
- mixture
- multifunctional washing
- laundry sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- 239000000853 adhesive Substances 0.000 claims abstract description 19
- 230000001070 adhesive effect Effects 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000314 lubricant Substances 0.000 claims abstract description 16
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 12
- 229930182490 saponin Natural products 0.000 claims abstract description 12
- 150000007949 saponins Chemical class 0.000 claims abstract description 12
- 238000005406 washing Methods 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 31
- 239000003921 oil Substances 0.000 claims description 17
- 235000019198 oils Nutrition 0.000 claims description 17
- 239000007884 disintegrant Substances 0.000 claims description 15
- 239000012298 atmosphere Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 7
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 5
- 244000060011 Cocos nucifera Species 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000005538 encapsulation Methods 0.000 claims description 5
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 5
- 238000007689 inspection Methods 0.000 claims description 5
- -1 neopelex Chemical compound 0.000 claims description 5
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 238000011056 performance test Methods 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 235000011803 sesame oil Nutrition 0.000 claims description 5
- 239000008159 sesame oil Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 3
- 229920001353 Dextrin Polymers 0.000 claims description 2
- 239000004375 Dextrin Substances 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 241000209140 Triticum Species 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 150000001720 carbohydrates Chemical class 0.000 claims description 2
- 235000019425 dextrin Nutrition 0.000 claims description 2
- 239000008172 hydrogenated vegetable oil Substances 0.000 claims description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract description 8
- 230000007613 environmental effect Effects 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000344 soap Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 241001122767 Theaceae Species 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000000341 volatile oil Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000006081 fluorescent whitening agent Substances 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- CCDRPBGPIXPGRW-JNKODXNQSA-N (4as,6ar,6as,6br,8ar,9r,10s,12ar,14bs)-9-(hydroxymethyl)-2,2,6a,6b,9,12a-hexamethyl-10-[(3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylic acid Chemical compound O([C@H]1CC[C@]2(C)[C@H]3CC=C4[C@@]([C@@]3(CC[C@H]2[C@@]1(CO)C)C)(C)CC[C@]1(CCC(C[C@H]14)(C)C)C(O)=O)C1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O CCDRPBGPIXPGRW-JNKODXNQSA-N 0.000 description 1
- NGKYAUZANWQMED-UHFFFAOYSA-N 5,6-epoxy-3-hydroxy-5,6-dihydro-10'-apo-beta-caroten-10'-al Natural products OC1C(O)C(O)C(C)OC1OC1C(OC2C(C3C(C4C(C5(CCC6(CCC(C)(C)CC6C5=CC4)C(=O)OC4C(C(O)C(O)C(COC5C(C(O)C(O)C(CO)O5)O)O4)O)C)(C)CC3)(C)CC2)(C)C)OCC(O)C1O NGKYAUZANWQMED-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- PALNVYHUKHRDOP-UHFFFAOYSA-N UNPD162310 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(OC7OC(CO)C(O)C(O)C7O)C6O)C(C)(C)C5CCC34C)C2C1)C(=O)O PALNVYHUKHRDOP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides an ultra-concentrated multifunctional laundry sheet, which comprises the following raw material components in weight percentage: 0.02-30% of tea saponin, 1-65% of surfactant, 0.01-50% of disintegrating agent, 0.01-30% of adhesive, 0.01-20% of lubricant, 0.01-10% of fragrant oil, 0.01-20% of solubilizer, and the balance water as a solvent. The surfactant is adopted as the main raw material of the laundry sheet, and the effect of the laundry sheet is obviously better than that of a soap, a detergent, a laundry detergent and other cleaning products. Meanwhile, the laundry sheet is water-saving and does not pollute the environment, which is consistent with the concepts of people in admiring natural protection, going green and realizing environmental protection. The preparation method of the laundry sheet has the advantages of easy production and low cost. Therefore, the industrial production of the laundry sheet is easily realized.
Description
Technical field
The present invention relates to daily cleaning chemical products technical field is and in particular to a kind of hyperconcetration Multifunctional washing garment piece and its preparation
Method.
Background technology
Laundry sheet is a kind of brand-new cleaning product, changes the form of conventional cleaning product, light be its maximum spy
Point, because it does not contain fluorescent whitening agent, the harmful components such as phosphorus, gradually fashionable European ＆ American Market, become cleaning product of new generation, be one
Plant neutral synthetic detergent.
But domestic at present many washing markets but have no small problem, modal washing powder on the market at present
In liquid detergent, generally contain the compositions such as fluorescent whitening agent, proteolytic enzyme, sodium tripolyphosphate, fluorescent whitening agent danger therein
Evil is maximum, to old man or child, must select cleaning product with caution.
Laundry sheet realize quantitation washing, overcome traditional washing powder, liquid detergent use in metering loaded down with trivial details, that is, save
Articles for washing, the environmental protection characteristic of its low bubble hyperconcetration has been saved again and has been used water, is expected to be promoted at home, with people's lives water
Flat raising, people's also more and more higher of the requirement to laundry sheet product quality, the demand of laundry sheet will be increasing, quality
Require also more and more higher, active matter is high, multi-functional, easy to use will be the development trend of laundry sheet.
Content of the invention
The technical problem to be solved is to provide a kind of easy to use, peace for above-mentioned the deficiencies in the prior art
Loopful guarantor, the hyperconcetration Multifunctional washing garment piece being easy to carry about with one and preparation method thereof.
The present invention is that the adopted technical scheme that solves the above problems is：
A kind of present invention hyperconcetration Multifunctional washing garment piece of offer, its component and raw material weight percentage are：
Tea Saponin 0.02%～30%,
Surfactant 1%～65%,
Disintegrant 0.01%～50%,
Adhesive 0.01%～30%,
Lubricant 0.01%～20%,
Fragrant atmosphere oil 0.01%～10%
Solubilizer 0.01%～20%
Excess water is solvent.
Further, described surfactant is laruyl alcohol sodium sulfovinate, neopelex, laureth sulphur
One or more of acid esters sodium and coconut oleoyl amine DEA.
Further, described disintegrant is dried starch.
Further, described adhesive is one of cellulose, wheat tooth dextrin, carbohydrate, polyethylene glycol and polyvinyl alcohol
Or it is several.
Further, described lubricant be magnesium stearate, silica, hydrogenated vegetable oil, isopropyl palmitate, glycerine,
One or more of Dormant oils.
Further, described solubilizer is one of PEG-400 and RH-40 hydrogenation sesame oil or two kinds.
The present invention provides a kind of preparation method of hyperconcetration Multifunctional washing garment piece, comprises the following steps：
(1) described surfactant and Tea Saponin are added in hot water according to percentage by weight and carry out being mixed and stirred for all
Even formation mixture A；
(2) weigh former disintegrant, adhesive and lubricant according to the percentage by weight of raw material and be added to stirring in mixture A
It is formed uniformly mixture B；
(3) weigh fragrant atmosphere oil according to the percentage by weight of raw material and solubilizer be added in the mixture B in step (2),
Carry out increase-volume decentralized processing and form mixture C；
(4) mixture C in step (3) is carried out with performance test, washes one's hair film drying forming, section, encapsulation, inspection and put in storage
Process, obtain required hyperconcetration Multifunctional washing garment piece.
Further, hot water temperature described in step (1) is 60～100 DEG C.
The beneficial effects of the present invention is：
The hyperconcetration Multifunctional washing garment piece that the present invention provides a kind of environmental protection easy to use, safe, is easy to carry about with one, this laundry sheet
Compounded with science such as washing assisant, Tea Saponin, fragrant atmosphere oil, adhesives with surfactant for primary raw material, the laundry sheet of preparation,
Its hyperconcetration, multi-functional both effectiveness be substantially better than the articless for washing such as soap, washing powder, liquid detergent, water-saving and free from environmental pollution,
Meet people and advocate nature, the theory of environmental protection, and also this preparation method has the characteristics that to be easy to produce, cost is it is easy to reality
Existing industrialized production.
Specific embodiment
With reference to specifically illustrating embodiments of the present invention, the mesh being only given to illustrate of these embodiments
, limitation of the invention can not be interpreted as, only for reference and explanation uses, and does not constitute to scope of patent protection of the present invention
Limit, because without departing from the spirit and scope of the present invention, the present invention can be carried out with many changes.
Embodiment 1
A kind of hyperconcetration Multifunctional washing garment piece, its component and raw material weight percentage are：
Tea Saponin 2%,
Surfactant 32%,
Disintegrant 15%,
Adhesive 15%,
Lubricant 6%,
Fragrant atmosphere oil 3%
Solubilizer 10%
Excess water is solvent.
In the present embodiment, described surfactant is laruyl alcohol sodium sulfovinate, neopelex, laureth
Sodium sulfovinate and coconut oleoyl amine DEA, respectively account for weight than for 10：6：2：1；
In the present embodiment, described disintegrant is dried starch.
In the present embodiment, described adhesive is cellulose and polyvinyl alcohol, respectively accounts for weight ratio for 1：9.
In the present embodiment, described lubricant respectively accounts for weight than for 1 for magnesium stearate, silica：5.
In the present embodiment, described solubilizer is that PEG-400 and RH-40 hydrogenate sesame oil, and each accounts for weight ratio for 1：3.
The present invention provides a kind of preparation method of hyperconcetration Multifunctional washing garment piece, comprises the following steps：
(1) described surfactant and difference saponin are added in hot water according to percentage by weight and carry out being mixed and stirred for all
Even formation mixture A；
(2) weigh former disintegrant, adhesive and lubricant according to the percentage by weight of raw material and be added to stirring in mixture A
It is formed uniformly mixture B；
(3) weigh fragrant atmosphere oil according to the percentage by weight of raw material and solubilizer be added in the mixture B in step (2),
Carry out increase-volume decentralized processing and form mixture C；
(4) mixture C in step (3) is carried out with performance test, washes one's hair film drying forming, section, encapsulation, inspection and put in storage
Process, obtain required hyperconcetration Multifunctional washing garment piece.
In the present embodiment, hot water temperature described in step (1) is 60 DEG C.
The hyperconcetration Multifunctional washing garment piece that the present invention provides a kind of environmental protection easy to use, safe, is easy to carry about with one, this laundry sheet
Compounded with science such as washing assisant, Tea Saponin, fragrant atmosphere oil, adhesives with surfactant for primary raw material, the laundry sheet of preparation,
Its hyperconcetration, multi-functional both effectiveness be substantially better than the articless for washing such as soap, washing powder, liquid detergent, water-saving and free from environmental pollution,
Meet people and advocate nature, the theory of environmental protection, and also this preparation method has the characteristics that to be easy to produce, cost is it is easy to reality
Existing industrialized production.
Embodiment 2
A kind of hyperconcetration Multifunctional washing garment piece, its component and raw material weight percentage are：
Tea Saponin 11%,
Surfactant 40%,
Disintegrant 10%,
Adhesive 10%,
Lubricant 8%,
Fragrant atmosphere oil 2%,
Solubilizer 4%,
Excess water is solvent.
In the present embodiment, described surfactant is laruyl alcohol sodium sulfovinate, neopelex, laureth
Sodium sulfovinate and coconut oleoyl amine DEA, respectively account for weight than for 10：5：3：1；
In the present embodiment, described disintegrant is dried starch.
In the present embodiment, described adhesive is polyvinyl alcohol.
In the present embodiment, described lubricant respectively accounts for weight than for 5 for glycerine, Dormant oils, silica：2：1.
In the present embodiment, described solubilizer hydrogenates sesame oil for RH-40.
The present invention provides a kind of preparation method of hyperconcetration Multifunctional washing garment piece, comprises the following steps：
(1) described surfactant and difference saponin are added in hot water according to percentage by weight and carry out being mixed and stirred for all
Even formation mixture A；
(2) weigh former disintegrant, adhesive and lubricant according to the percentage by weight of raw material and be added to stirring in mixture A
It is formed uniformly mixture B；
(3) weigh fragrant atmosphere oil according to the percentage by weight of raw material and solubilizer be added in the mixture B in step (2),
Carry out increase-volume decentralized processing and form mixture C；
(4) mixture C in step (3) is carried out with performance test, washes one's hair film drying forming, section, encapsulation, inspection and put in storage
Process, obtain required hyperconcetration Multifunctional washing garment piece.
In the present embodiment, hot water temperature described in step (1) is 90 DEG C.
Embodiment 3
A kind of hyperconcetration Multifunctional washing garment piece, its component and raw material weight percentage are：
Tea Saponin 15%,
Surfactant 35%,
Disintegrant 10%,
Adhesive 5%,
Lubricant 10%,
Fragrant atmosphere oil 2%
Solubilizer 5%
Excess water is solvent.
In the present embodiment, described surfactant is laruyl alcohol sodium sulfovinate, neopelex, laureth
Sodium sulfovinate and coconut oleoyl amine DEA, respectively account for weight than for 10：5：3：1；
In the present embodiment, described disintegrant is dried starch.
In the present embodiment, described adhesive is polyvinyl alcohol.
In the present embodiment, described lubricant respectively accounts for weight than for 3 for glycerine, Dormant oils, silica：1：1.
In the present embodiment, described solubilizer hydrogenates sesame oil for RH-40.
The present invention provides a kind of preparation method of hyperconcetration Multifunctional washing garment piece, comprises the following steps：
(1) described surfactant and difference saponin are added in hot water according to percentage by weight and carry out being mixed and stirred for all
Even formation mixture A；
(2) weigh former disintegrant, adhesive and lubricant according to the percentage by weight of raw material and be added to stirring in mixture A
It is formed uniformly mixture B；
(3) weigh fragrant atmosphere oil according to the percentage by weight of raw material and solubilizer be added in the mixture B in step (2),
Carry out increase-volume decentralized processing and form mixture C；
(4) mixture C in step (3) is carried out with performance test, washes one's hair film drying forming, section, encapsulation, inspection and put in storage
Process, obtain required hyperconcetration Multifunctional washing garment piece.
In the present embodiment, hot water temperature described in step (1) is 98 DEG C.
Table 1
As shown in table 1, laundry sheet provided by the present invention and washing powder and liquid detergent indices parameter comparison find, respectively
Item technical indicator has all reached advanced level, and on the premise of reaching identical laundry effect, the laundry sheet tool of this application
There are larger advantage, the especially best results in embodiment 1, invention provides a kind of environmental protection easy to use, safe, is easy to carry about with one
Hyperconcetration Multifunctional washing garment piece, this laundry sheet with surfactant be primary raw material and washing assisant, Tea Saponin, fragrant atmosphere oil,
The science such as adhesive compound, the laundry sheet of preparation, its hyperconcetration, multi-functional both effectiveness are substantially better than soap, washing powder, liquid detergent
Deng articles for washing, water-saving and free from environmental pollution, also comply with people and advocate nature, the theory of environmental protection, and this preparation method
Have the characteristics that to be easy to production, cost, it is easy to accomplish industrialized production.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not subject to above-described embodiment
Limit, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplify,
All should be equivalent substitute mode, be included within protection scope of the present invention.
Claims (8)
1. a kind of hyperconcetration Multifunctional washing garment piece is it is characterised in that its component and raw material weight percentage are：
Tea Saponin 0.02%～30%,
Surfactant 1%～65%,
Disintegrant 0.01%～50%,
Adhesive 0.01%～30%,
Lubricant 0.01%～20%,
Fragrant atmosphere oil 0.01%～10%
Solubilizer 0.01%～20%
Excess water is solvent.
2. a kind of hyperconcetration Multifunctional washing garment piece according to claim 1 it is characterised in that：Described surfactant is the moon
One or more of cinnamic alcohol sodium sulfovinate, neopelex, laureth sodium sulfovinate and coconut oleoyl amine DEA.
3. a kind of hyperconcetration Multifunctional washing garment piece according to claim 1 it is characterised in that：Described disintegrant is dry shallow lake
Powder.
4. a kind of hyperconcetration Multifunctional washing garment piece according to claim 1 it is characterised in that：Described adhesive is fiber
One or more of element, wheat tooth dextrin, carbohydrate, polyethylene glycol and polyvinyl alcohol.
5. a kind of hyperconcetration Multifunctional washing garment piece according to claim 1 it is characterised in that：Described lubricant is stearic acid
One or more of magnesium, silica, hydrogenated vegetable oil, isopropyl palmitate, glycerine, Dormant oils.
6. a kind of hyperconcetration Multifunctional washing garment piece according to claim 1 it is characterised in that：Described solubilizer is PEG-
400 and RH-40 hydrogenate one of sesame oil or two kinds.
7. a kind of preparation method of hyperconcetration Multifunctional washing garment piece is it is characterised in that comprise the following steps：
(1) described surfactant and Tea Saponin are added in hot water according to percentage by weight and carry out being mixed and stirred for uniform shape
Resulting mixture A；
(2) weigh former disintegrant, adhesive and lubricant according to the percentage by weight of raw material and be added in mixture A and stir
Form mixture B；
(3) weigh fragrant atmosphere oil according to the percentage by weight of raw material and solubilizer is added in the mixture B in step (2), carry out
Increase-volume decentralized processing forms mixture C；
(4) mixture C in step (3) is carried out with performance test, washes one's hair at film drying forming, section, encapsulation, inspection and warehouse-in
Reason, obtains required hyperconcetration Multifunctional washing garment piece.
8. a kind of hyperconcetration multifunctional laundry piece preparation method according to claim 7 it is characterised in that：In step (1)
Described hot water temperature is 60～100 DEG C.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610743605.9A CN106381235A (en) | 2016-08-27 | 2016-08-27 | Ultra-concentrated multifunctional laundry sheet and preparation method thereof |
| PCT/CN2016/111947 WO2018040411A1 (en) | 2016-08-27 | 2016-12-24 | Super-concentrated multi-functional laundry detergent sheet and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610743605.9A CN106381235A (en) | 2016-08-27 | 2016-08-27 | Ultra-concentrated multifunctional laundry sheet and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106381235A true CN106381235A (en) | 2017-02-08 |
Family
ID=57917526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610743605.9A Pending CN106381235A (en) | 2016-08-27 | 2016-08-27 | Ultra-concentrated multifunctional laundry sheet and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN106381235A (en) |
| WO (1) | WO2018040411A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106867710A (en) * | 2016-10-07 | 2017-06-20 | 广州市博贤化妆品有限公司 | A kind of clear water concentration laundry sheet and preparation method thereof |
| CN107022425A (en) * | 2017-05-03 | 2017-08-08 | 诺圆环保科技（苏州）有限公司 | A kind of antibacterial anti-corrosion removes formaldehyde type laundry sheet and preparation method thereof |
| CN107384614A (en) * | 2017-07-06 | 2017-11-24 | 汕头市楷达发有限公司 | A kind of highly enriched laundry sheet and preparation method thereof |
| CN107418778A (en) * | 2017-07-26 | 2017-12-01 | 诺圆环保科技（苏州）有限公司 | A kind of non-pigment without essence laundry sheet and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112980609A (en) * | 2021-02-22 | 2021-06-18 | 营口理工学院 | Extraction of natural nonionic surfactant tea saponin and development of antibacterial laundry detergent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1245527A (en) * | 1996-12-06 | 2000-02-23 | 普罗格特-甘布尔公司 | Coated detergent tablet |
| CN1421519A (en) * | 2001-11-23 | 2003-06-04 | 吕秀娟 | Laminar hygienic washing product, manufacturing method and use thereof |
| CN105219549A (en) * | 2015-11-12 | 2016-01-06 | 浙江工贸职业技术学院 | A kind of clothing removers and preparation method thereof |
| CN105238604A (en) * | 2015-11-09 | 2016-01-13 | 云南健牛生物科技有限公司 | High-stability salt-containing clothes washing effervescent tablet and preparation method thereof |
| CN105368598A (en) * | 2015-10-29 | 2016-03-02 | 广东星汇生物科技有限公司 | Tea saponin washing powder |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2306722A1 (en) * | 1999-04-23 | 2000-10-29 | Henkel Kommanditgesellschaft Auf Aktien | Detergent tablets containing binder compound |
| DE19953792A1 (en) * | 1999-11-09 | 2001-05-17 | Cognis Deutschland Gmbh | Detergent tablets |
| CN1428410A (en) * | 2001-12-25 | 2003-07-09 | 上海白猫有限公司 | Sheet detergent for washing clothes and its preparation method |
| CN108085146B (en) * | 2011-05-13 | 2020-10-16 | Lg生活健康株式会社 | tablets for washing |
| CN102643724B (en) * | 2012-04-13 | 2013-05-15 | 江南大学 | A kind of laundry detergent containing tea saponin and preparation method thereof |
-
2016
- 2016-08-27 CN CN201610743605.9A patent/CN106381235A/en active Pending
- 2016-12-24 WO PCT/CN2016/111947 patent/WO2018040411A1/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1245527A (en) * | 1996-12-06 | 2000-02-23 | 普罗格特-甘布尔公司 | Coated detergent tablet |
| CN1421519A (en) * | 2001-11-23 | 2003-06-04 | 吕秀娟 | Laminar hygienic washing product, manufacturing method and use thereof |
| CN105368598A (en) * | 2015-10-29 | 2016-03-02 | 广东星汇生物科技有限公司 | Tea saponin washing powder |
| CN105238604A (en) * | 2015-11-09 | 2016-01-13 | 云南健牛生物科技有限公司 | High-stability salt-containing clothes washing effervescent tablet and preparation method thereof |
| CN105219549A (en) * | 2015-11-12 | 2016-01-06 | 浙江工贸职业技术学院 | A kind of clothing removers and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106867710A (en) * | 2016-10-07 | 2017-06-20 | 广州市博贤化妆品有限公司 | A kind of clear water concentration laundry sheet and preparation method thereof |
| CN107022425A (en) * | 2017-05-03 | 2017-08-08 | 诺圆环保科技（苏州）有限公司 | A kind of antibacterial anti-corrosion removes formaldehyde type laundry sheet and preparation method thereof |
| CN107384614A (en) * | 2017-07-06 | 2017-11-24 | 汕头市楷达发有限公司 | A kind of highly enriched laundry sheet and preparation method thereof |
| CN107418778A (en) * | 2017-07-26 | 2017-12-01 | 诺圆环保科技（苏州）有限公司 | A kind of non-pigment without essence laundry sheet and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018040411A1 (en) | 2018-03-08 |
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