[go: up one dir, main page]

CA2692799A1 - Procede de fabrication de mousses de polyurethanne pour le traitement des blessures - Google Patents

Procede de fabrication de mousses de polyurethanne pour le traitement des blessures Download PDF

Info

Publication number
CA2692799A1
CA2692799A1 CA 2692799 CA2692799A CA2692799A1 CA 2692799 A1 CA2692799 A1 CA 2692799A1 CA 2692799 CA2692799 CA 2692799 CA 2692799 A CA2692799 A CA 2692799A CA 2692799 A1 CA2692799 A1 CA 2692799A1
Authority
CA
Canada
Prior art keywords
silane
foam
optionally
acid
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA 2692799
Other languages
English (en)
Inventor
Michael Mager
Michael Ludewig
Mathias Matner
Melita Dietze
Burkhard Fugmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2692799A1 publication Critical patent/CA2692799A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • A61L15/425Porous materials, e.g. foams or sponges
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/26Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0214Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4833Polyethers containing oxyethylene units
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71Monoisocyanates or monoisothiocyanates
    • C08G18/718Monoisocyanates or monoisothiocyanates containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122Hydrogen, oxygen, CO2, nitrogen or noble gases
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/142Compounds containing oxygen but no halogen atom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • C08J9/365Coating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • Hematology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Silicon Polymers (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
CA 2692799 2007-07-10 2008-06-27 Procede de fabrication de mousses de polyurethanne pour le traitement des blessures Abandoned CA2692799A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07013425A EP2014314A1 (fr) 2007-07-10 2007-07-10 Procédé destiné à la fabrication de mousses de polyuréthane pour le traitement d'une plaie
EP07013425.9 2007-07-10
PCT/EP2008/005259 WO2009007018A1 (fr) 2007-07-10 2008-06-27 Procédé de fabrication de mousses de polyuréthanne pour le traitement des blessures

Publications (1)

Publication Number Publication Date
CA2692799A1 true CA2692799A1 (fr) 2009-01-15

Family

ID=38521740

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2692799 Abandoned CA2692799A1 (fr) 2007-07-10 2008-06-27 Procede de fabrication de mousses de polyurethanne pour le traitement des blessures

Country Status (8)

Country Link
US (1) US9168324B2 (fr)
EP (2) EP2014314A1 (fr)
JP (1) JP5192040B2 (fr)
KR (1) KR20100035703A (fr)
CN (1) CN101687058B (fr)
CA (1) CA2692799A1 (fr)
TW (1) TW200918108A (fr)
WO (1) WO2009007018A1 (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007032342A1 (de) * 2007-07-11 2009-01-15 Bayer Materialscience Ag Verfahren zur Herstellung von Polyurethan-Schäumen auf Basis von speziellen alkoxysilanfunktionellen Polymeren
CA2694597C (fr) * 2009-02-25 2017-02-21 Robert Joseph Berry, Jr. Controleur et moniteur universels eloignes de machines
DE102009028640A1 (de) 2009-08-19 2011-02-24 Evonik Goldschmidt Gmbh Härtbare Masse enthaltend Urethangruppen aufweisende silylierte Polymere und deren Verwendung in Dicht- und Klebstoffen, Binde- und/oder Oberflächenmodifizierungsmitteln
DE102009028636A1 (de) * 2009-08-19 2011-02-24 Evonik Goldschmidt Gmbh Neuartige Urethangruppen enthaltende silylierte Präpolymere und Verfahren zu deren Herstellung
DE112010004968T5 (de) * 2009-12-22 2012-11-29 Fisher & Paykel Healthcare Corporation Limited Komponenten für medizinische Kreisläufe
US8772567B2 (en) 2010-08-19 2014-07-08 Paul Hartmann Ag Use of a polyurethane foam as a wound dressing in negative pressure therapy
ES2461916T3 (es) * 2010-08-19 2014-05-21 Paul Hartmann Ag Apósito con contenido en espuma y base de pomada para la terapia por presión negativa
JP2014520657A (ja) * 2011-07-20 2014-08-25 スリーエム イノベイティブ プロパティズ カンパニー イオン担持組成物を含んだ包帯
JP6141852B2 (ja) * 2011-09-29 2017-06-07 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBayer Intellectual Property GmbH 速硬化性アルコキシシランスプレーフォーム
CN103841998B (zh) * 2011-09-29 2016-04-27 拜耳知识产权有限责任公司 快速凝固的烷氧基硅烷喷涂泡沫
JP6043796B2 (ja) * 2011-09-29 2016-12-14 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBayer Intellectual Property GmbH プロペラントガス溶解性が改善された速硬化性スプレーフォームのためのα−アルコキシシラン末端化プレポリマー
CN104822774A (zh) * 2012-10-24 2015-08-05 墨尼克医疗用品有限公司 用于制备基于烷氧基硅烷的喷涂泡沫的多组分体系
EP2725044B1 (fr) * 2012-10-24 2017-06-21 Covestro Deutschland AG Prépolymère à terminaison alkoxysilane à base de polyols de polyéther carbonate pour mousse à atomiser
DE102013107464A1 (de) * 2013-07-15 2015-01-15 Wilhelm Fleischmann Wundauflage
JP2016214296A (ja) * 2015-05-14 2016-12-22 株式会社カネカ 粘着層を持つ軟質発泡体を用いた褥瘡予防パッド
DE102015007622A1 (de) * 2015-06-16 2016-12-22 Paul Hartmann Ag Vorrichtung zur Unterdrucktherapie von Wunden enthaltend siliconhaltigen Polyurethanschaumstoff
WO2017050840A1 (fr) * 2015-09-21 2017-03-30 Poly Terra Innovation Gmbh Matériau en mousse synthétique comprenant des polymères à terminaison silane
CN106038065B (zh) * 2016-05-26 2019-06-18 华南理工大学 一种基于聚硅氧烷超分子弹性体具有双层结构的皮肤创伤敷料及其制备方法
GB201610184D0 (en) 2016-06-10 2016-07-27 Eumar Tech Ltd Product
JP7053315B2 (ja) * 2018-03-09 2022-04-12 株式会社カネカ 断熱材、及び、断熱材の製造方法
EP3756850A1 (fr) * 2019-06-24 2020-12-30 Mölnlycke Health Care AB Fabrication à haut rendement de couches de mousse de polyuréthane
TWI733144B (zh) * 2019-07-22 2021-07-11 中鎮醫療產品科技股份有限公司 疤痕膠片用水膠及其製法
US12311650B2 (en) * 2019-07-22 2025-05-27 Tronjen Medical Technology Inc. Pressure relief cushion
JP7277346B2 (ja) * 2019-12-02 2023-05-18 株式会社イノアックコーポレーション シリコーン系樹脂発泡体の製造方法
PL3842075T3 (pl) * 2019-12-23 2023-10-16 Paul Hartmann Ag Opatrunek na ranę zawierający siloksan
TWI744865B (zh) * 2020-02-07 2021-11-01 中鎮醫療產品科技股份有限公司 預防壓瘡用的減壓墊
TWI733503B (zh) 2020-06-22 2021-07-11 中鎮醫療產品科技股份有限公司 聚氨酯泡綿敷料及傷口敷料產品
CN113480715A (zh) * 2021-07-27 2021-10-08 沈翔 一种聚氨酯膜敷料及其制备方法
WO2023247713A1 (fr) 2022-06-24 2023-12-28 Topsoe A/S Production d'ammoniac à partir de gaz de synthèse se caractérisant par une grande variété de charges d'alimentation d'installation
CN117599260A (zh) * 2024-01-23 2024-02-27 四川大学 一种具有抗炎功能的医用聚氨酯泡沫及其制备和应用

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1745526B2 (de) * 1967-03-16 1980-04-10 Union Carbide Corp., New York, N.Y. (V.St.A.) Verfahren zur Herstellung vulkanisierbarer, unter wasserfreien Bedingungen beständiger Polymerisate
BE789739A (fr) * 1971-10-05 1973-04-05 Lock Peter M Pansement chirurgical
US3978266A (en) * 1972-10-05 1976-08-31 Ionics Lyo Products Company Surgical dressings
US3979344A (en) * 1974-11-19 1976-09-07 Inmont Corporation Vulcanizable silicon terminated polyurethane polymer composition having improved cure speed
US4222925A (en) * 1978-08-02 1980-09-16 Inmont Corporation Vulcanizable silicon terminated polyurethane polymer compositions having improved cure speed
US4502479A (en) * 1979-09-04 1985-03-05 Minnesota Mining And Manufacturing Company Water-activated casting material
NZ199684A (en) 1981-02-13 1985-03-20 Smith & Nephew Ass Wound dressing;wound facing layer a conformable elastomeric integral net
ZA82933B (en) * 1981-02-13 1983-02-23 Smith & Nephew Ass Wound dressing, manufacture and use
US4619578A (en) * 1985-04-19 1986-10-28 Routledge James H Retractable wheel suspension apparatus
US4667661A (en) * 1985-10-04 1987-05-26 Minnesota Mining And Manufacturing Company Curable resin coated sheet having reduced tack
JPH0363061A (ja) * 1989-07-31 1991-03-19 Sanyo Chem Ind Ltd 医療用接着剤
US5409472A (en) * 1989-08-03 1995-04-25 Smith & Nephew Plc Adhesive polymeric foam dressings
GB8917788D0 (en) * 1989-08-03 1989-09-20 Smith & Nephew Adhesive dressing
US5423735A (en) * 1993-04-16 1995-06-13 Minnesota Mining And Manufacturing Company Orthopedic cast composed of an alkoxysilane terminated resin
US5603691A (en) * 1993-04-16 1997-02-18 Minnesota Mining And Manufacturing Company Method of using water soluble films in curable casting tapes
CA2180337A1 (fr) * 1994-01-21 1995-07-27 Matthew T. Scholz Materiau de platrage orthopedique poreux
CA2161712A1 (fr) * 1994-11-03 1996-05-04 Ketan N. Shah Compositions elastomeres modifiees au silane et articles obtenus a l'aide de ces compositions
GB9505495D0 (en) 1995-03-18 1995-05-03 Smith & Nephew Adhesives
US5925004A (en) * 1997-05-05 1999-07-20 Ebi Medical Systems, Inc. Method for controlled lubricant delivery when molding tacky materials
US5984884A (en) * 1997-05-05 1999-11-16 Ebi Medical Systems, Inc. Casting tape article and method for molding casts
US6369188B1 (en) * 1998-03-27 2002-04-09 Polymeright, Inc. Polyfunctional urethane- or urea-containing oligomers and polymers prepared therefrom
DE19831285A1 (de) 1998-07-13 2000-01-20 Rathor Ag Appenzell Prepolymerabmischung mit Silan-terminierten Prepolymeren
ES2287204T3 (es) * 2001-07-02 2007-12-16 Tosoh Corporation Metodo para producir una espuma de poliuretano rigida.
US6596786B2 (en) * 2001-08-17 2003-07-22 Alcatel Radiation-curable coating composition including oligomeric photoinitiator and/or oligomeric adhesion promoter
DE10204523A1 (de) * 2002-02-05 2003-08-07 Bayer Ag Alkoxysilan- und OH-Endgruppen aufweisende Polyurethanprepolymere mit erniedrigter Funktionalität, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung
US6979713B2 (en) * 2002-11-25 2005-12-27 3M Innovative Properties Company Curable compositions and abrasive articles therefrom
DE102005041953A1 (de) 2005-09-03 2007-03-08 Bayer Materialscience Ag Niedrigviskose alkoxysilangruppenaufweisende Prepolymere, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung

Also Published As

Publication number Publication date
US9168324B2 (en) 2015-10-27
EP2014314A1 (fr) 2009-01-14
CN101687058B (zh) 2016-06-22
WO2009007018A1 (fr) 2009-01-15
EP2175896A1 (fr) 2010-04-21
JP2010532691A (ja) 2010-10-14
KR20100035703A (ko) 2010-04-06
CN101687058A (zh) 2010-03-31
US20090018480A1 (en) 2009-01-15
TW200918108A (en) 2009-05-01
WO2009007018A8 (fr) 2010-01-07
EP2175896B1 (fr) 2015-08-19
JP5192040B2 (ja) 2013-05-08

Similar Documents

Publication Publication Date Title
US9168324B2 (en) Production of polyurethane foams for wound management
CN102089341B (zh) 亲水性脂肪族聚氨酯泡沫
JP5964843B2 (ja) 親水性脂肪族ポリウレタンフォーム
US8980966B2 (en) Hydrophilic aliphatic polyurethane foams
US20090054542A1 (en) Eo/po block copolymers useful as stabilizers for pur foams
US9920157B2 (en) Alkoxysilane-terminated prepolymer based on polyether carbonate polyols, for spray foams
JP5963710B2 (ja) ポリウレタン発泡シートの製造方法及びそれを用いた皮革様シート状物の製造方法
JP2010532691A5 (fr)
US8946315B2 (en) Hydrophilic aliphatic polyurethane foams
US20100330238A1 (en) Adhesive
JP2012502708A (ja) ポリウレタンフォーム層と熱可塑性ポリマー製被覆層とを有する創傷処置用品
US20130131206A1 (en) Method for producing flat, hydrophilic, aliphatic polyurethane foams
CN102971017B (zh) 制备具有低容积密度的亲水性脂族聚氨酯泡沫的方法
US9228049B2 (en) Method for producing hydrophilic, aliphatic polyurethane foams having low bulk density
JP2019530789A (ja) ポリウレタン及び組成物並びにそれらから形成される部材の硬化を遅延させる為の方法
JPH0253447B2 (fr)
HK1152956A (zh) 粘合剂

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20130625

FZDE Discontinued

Effective date: 20160525