CA2370380A1 - Melange polymere formant un hydrogel - Google Patents
Melange polymere formant un hydrogel Download PDFInfo
- Publication number
- CA2370380A1 CA2370380A1 CA002370380A CA2370380A CA2370380A1 CA 2370380 A1 CA2370380 A1 CA 2370380A1 CA 002370380 A CA002370380 A CA 002370380A CA 2370380 A CA2370380 A CA 2370380A CA 2370380 A1 CA2370380 A1 CA 2370380A1
- Authority
- CA
- Canada
- Prior art keywords
- hydrogel
- forming polymer
- polymer
- polymer mixture
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920002959 polymer blend Polymers 0.000 title claims abstract description 66
- 229920000642 polymer Polymers 0.000 claims abstract description 198
- 239000000203 mixture Substances 0.000 claims abstract description 78
- 239000002253 acid Substances 0.000 claims abstract description 46
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 21
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- 230000002745 absorbent Effects 0.000 claims abstract description 9
- 239000004971 Cross linker Substances 0.000 claims description 89
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 61
- 238000004132 cross linking Methods 0.000 claims description 50
- 239000000843 powder Substances 0.000 claims description 45
- 229920002873 Polyethylenimine Polymers 0.000 claims description 39
- 229920001577 copolymer Polymers 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 33
- 150000002148 esters Chemical class 0.000 claims description 31
- 238000001035 drying Methods 0.000 claims description 29
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 29
- 230000007062 hydrolysis Effects 0.000 claims description 28
- 238000006460 hydrolysis reaction Methods 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 27
- 150000001735 carboxylic acids Chemical class 0.000 claims description 24
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- 238000012360 testing method Methods 0.000 claims description 14
- 238000011033 desalting Methods 0.000 claims description 12
- 229920000578 graft copolymer Polymers 0.000 claims description 11
- 238000005259 measurement Methods 0.000 claims description 9
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- 125000001841 imino group Chemical group [H]N=* 0.000 abstract description 5
- 239000000499 gel Substances 0.000 description 96
- 239000000243 solution Substances 0.000 description 64
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 40
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 33
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- 229920005601 base polymer Polymers 0.000 description 22
- 239000011780 sodium chloride Substances 0.000 description 22
- 238000006116 polymerization reaction Methods 0.000 description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 19
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- 229920001223 polyethylene glycol Polymers 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 16
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 15
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 15
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- 125000000524 functional group Chemical group 0.000 description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 14
- 125000003277 amino group Chemical group 0.000 description 14
- 239000007787 solid Substances 0.000 description 14
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- 239000002202 Polyethylene glycol Substances 0.000 description 12
- 235000013772 propylene glycol Nutrition 0.000 description 12
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 11
- 150000007513 acids Chemical class 0.000 description 11
- 239000002585 base Substances 0.000 description 11
- 239000003999 initiator Substances 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
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- 239000000463 material Substances 0.000 description 10
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- 239000004926 polymethyl methacrylate Substances 0.000 description 10
- 238000005507 spraying Methods 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 230000002378 acidificating effect Effects 0.000 description 9
- 239000000654 additive Substances 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 235000011121 sodium hydroxide Nutrition 0.000 description 9
- 210000002700 urine Anatomy 0.000 description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 238000001291 vacuum drying Methods 0.000 description 8
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 7
- 238000005054 agglomeration Methods 0.000 description 7
- 230000002776 aggregation Effects 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 150000001991 dicarboxylic acids Chemical class 0.000 description 7
- 239000012153 distilled water Substances 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- 239000000017 hydrogel Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000006386 neutralization reaction Methods 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 238000010998 test method Methods 0.000 description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 6
- 238000006845 Michael addition reaction Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000004809 Teflon Substances 0.000 description 6
- 229920006362 Teflon® Polymers 0.000 description 6
- 235000010323 ascorbic acid Nutrition 0.000 description 6
- 239000011668 ascorbic acid Substances 0.000 description 6
- 229960005070 ascorbic acid Drugs 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000004202 carbamide Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 6
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 5
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- 229940052303 ethers for general anesthesia Drugs 0.000 description 5
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- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 5
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- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
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- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- VSJBBIJIXZVVLQ-UHFFFAOYSA-N tert-butyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(C)(C)C VSJBBIJIXZVVLQ-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 1
- CSKKAINPUYTTRW-UHFFFAOYSA-N tetradecoxycarbonyloxy tetradecyl carbonate Chemical compound CCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCC CSKKAINPUYTTRW-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical class C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 238000007056 transamidation reaction Methods 0.000 description 1
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 230000002618 waking effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/12—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
- C08L101/14—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La présente invention concerne un mélange polymère formant un hydrogel. Ce mélange comprend a) un polymère I formant un hydrogel, avec des restes acides, et b) un polymère II formant un hydrogel, avec des restes amino et/ou imino, le rapport des restes acides sur la somme des restes amino et/ou imino s'élevant de 1 : 9 à 9 : 1. Cette invention concerne également l'utilisation de ces mélanges dans des articles d'hygiène absorbants.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19917919.0 | 1999-04-20 | ||
| DE1999117919 DE19917919A1 (de) | 1999-04-20 | 1999-04-20 | Hydrogel-formende Polymermischung |
| DE19931720.8 | 1999-07-08 | ||
| DE1999131720 DE19931720A1 (de) | 1999-07-08 | 1999-07-08 | Hydrogel-formende Polymermischung |
| PCT/EP2000/003220 WO2000063295A1 (fr) | 1999-04-20 | 2000-04-11 | Melange polymere formant un hydrogel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2370380A1 true CA2370380A1 (fr) | 2000-10-26 |
Family
ID=26053000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002370380A Abandoned CA2370380A1 (fr) | 1999-04-20 | 2000-04-11 | Melange polymere formant un hydrogel |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1175460A1 (fr) |
| JP (1) | JP2002542364A (fr) |
| BR (1) | BR0009873A (fr) |
| CA (1) | CA2370380A1 (fr) |
| MX (1) | MXPA01010496A (fr) |
| PL (1) | PL351567A1 (fr) |
| WO (1) | WO2000063295A1 (fr) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6849665B2 (en) | 2000-12-29 | 2005-02-01 | Basf Aktiengesellschaft | Absorbent compositions |
| US7147752B2 (en) | 2002-12-31 | 2006-12-12 | Kimberly-Clark Worldwide, Inc. | Hydrophilic fibers containing substantive polysiloxanes and tissue products made therefrom |
| US7186318B2 (en) | 2003-12-19 | 2007-03-06 | Kimberly-Clark Worldwide, Inc. | Soft tissue hydrophilic tissue products containing polysiloxane and having unique absorbent properties |
| US7479578B2 (en) | 2003-12-19 | 2009-01-20 | Kimberly-Clark Worldwide, Inc. | Highly wettable—highly flexible fluff fibers and disposable absorbent products made of those |
| US7811948B2 (en) | 2003-12-19 | 2010-10-12 | Kimberly-Clark Worldwide, Inc. | Tissue sheets containing multiple polysiloxanes and having regions of varying hydrophobicity |
| US7816301B2 (en) | 2005-09-30 | 2010-10-19 | Nippon Shokubai Co., Ltd. | Aqueous-liquid-absorbing agent and its production process |
| US7838567B2 (en) | 2002-02-06 | 2010-11-23 | Basf Aktiengesellschaft | Foams made from water-absorbing, basic polymers, method for the production and utilization thereof |
| EP1729881A4 (fr) * | 2004-03-31 | 2012-07-04 | Nippon Catalytic Chem Ind | Un agent absorbant de liquides aqueux et procédé pour la fabrication de celui-ci |
| US8324446B2 (en) | 2004-06-30 | 2012-12-04 | Kimberly-Clark Worldwide, Inc. | Unitary absorbent core with binding agents |
| US9486981B2 (en) | 2011-09-13 | 2016-11-08 | Basf Se | Use of polyethyleneimines in the preparation of polyamides |
| US9777078B2 (en) | 2006-07-19 | 2017-10-03 | Basf Se | Method for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL362772A1 (en) * | 2000-12-29 | 2004-11-02 | Basf Aktiengesellschaft | Hydrogels coated with steric or electrostatic spacers |
| DE10239074A1 (de) * | 2002-08-26 | 2004-03-11 | Basf Ag | Wasserabsorbierendes Mittel und Verfahren zu seiner Herstellung |
| ATE419052T1 (de) * | 2003-03-27 | 2009-01-15 | Basf Se | Prozess zur reduzierung des gehalts wasserlöslicher salze in wässrigen vinylamin- polymerlösungen |
| US7872168B2 (en) | 2003-10-31 | 2011-01-18 | Kimberely-Clark Worldwide, Inc. | Stretchable absorbent article |
| US7662745B2 (en) | 2003-12-18 | 2010-02-16 | Kimberly-Clark Corporation | Stretchable absorbent composites having high permeability |
| JP4824911B2 (ja) * | 2004-01-30 | 2011-11-30 | 一般財団法人川村理化学研究所 | ヒドロゲル、架橋ヒドロゲル及びそれらの製造方法 |
| US7772456B2 (en) | 2004-06-30 | 2010-08-10 | Kimberly-Clark Worldwide, Inc. | Stretchable absorbent composite with low superaborbent shake-out |
| US7247215B2 (en) | 2004-06-30 | 2007-07-24 | Kimberly-Clark Worldwide, Inc. | Method of making absorbent articles having shaped absorbent cores on a substrate |
| GB0704335D0 (en) * | 2007-03-07 | 2007-04-11 | Fujifilm Imaging Colorants Ltd | Process for preparing an encapsulated particulate solid |
| JP5370712B2 (ja) * | 2008-02-21 | 2013-12-18 | 日東電工株式会社 | 酸性水溶性標的物質吸着ポリマー及びその製造方法 |
| BRPI0917678B1 (pt) | 2008-09-02 | 2019-09-10 | Basf Se | processo para a produção de papel, de cartão e de papelão |
| CN103442567B (zh) | 2011-03-23 | 2016-02-10 | 巴斯夫欧洲公司 | 含有包含咪唑鎓基团的聚合离子型化合物的组合物 |
| US9359518B2 (en) | 2011-11-23 | 2016-06-07 | Basf Se | Aqueous binder for granular and/or fibrous substrates |
| ES2640272T3 (es) | 2011-11-23 | 2017-11-02 | Basf Se | Aglutinante acuoso para sustratos granulados y/o fibrosos |
| DE102011119332A1 (de) * | 2011-11-25 | 2013-05-29 | Centrum Für Angewandte Nanotechnologie (Can) Gmbh | Verwendung von über radikalische Emulsionspolymerisation erhältlichen Polymeren als Verdicker für Reinigungsmittel |
| JP5940633B2 (ja) * | 2014-11-13 | 2016-06-29 | 株式会社パイロットコーポレーション | ゲル状組成物の製造方法 |
| WO2017194331A1 (fr) | 2016-05-12 | 2017-11-16 | Basf Se | Utilisation de sels de polyimidazolium en tant qu'inhibiteurs de transfert de colorants |
| JP7692697B2 (ja) * | 2020-12-29 | 2025-06-16 | ユニ・チャーム株式会社 | 複合吸収体及び衛生用品 |
| CN116144041B (zh) * | 2022-10-21 | 2025-04-04 | 中石化石油工程技术服务股份有限公司 | 一种基于点击化学构建的双网络水凝胶压裂液的制备方法 |
| CN120157914A (zh) * | 2025-03-13 | 2025-06-17 | 中国石油大学(北京) | 一种生物质凝胶及其制备方法和应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4137217A (en) * | 1972-07-01 | 1979-01-30 | Eishun Tsuchida | Polyion complex and method for preparing the same |
| EP0493011B1 (fr) * | 1990-12-21 | 2009-07-29 | Nippon Shokubai Co., Ltd. | Matière absorbant l'eau et procédé de production; absorbant et procédé de production |
| CN1064974C (zh) * | 1994-08-12 | 2001-04-25 | 花王株式会社 | 生产改进的高吸收聚合物的方法 |
| US6951895B1 (en) * | 1996-12-02 | 2005-10-04 | Kimberly-Clark Worldwide, Inc. | Absorbent composition |
| WO1999034843A1 (fr) * | 1998-01-07 | 1999-07-15 | The Procter & Gamble Company | Compositions polymeres absorbantes a haute capacite de sorption sous l'application d'une pression |
-
2000
- 2000-04-11 CA CA002370380A patent/CA2370380A1/fr not_active Abandoned
- 2000-04-11 JP JP2000612376A patent/JP2002542364A/ja not_active Withdrawn
- 2000-04-11 PL PL35156700A patent/PL351567A1/xx unknown
- 2000-04-11 BR BR0009873-6A patent/BR0009873A/pt not_active Application Discontinuation
- 2000-04-11 WO PCT/EP2000/003220 patent/WO2000063295A1/fr not_active Ceased
- 2000-04-11 EP EP00925196A patent/EP1175460A1/fr not_active Withdrawn
-
2001
- 2001-10-17 MX MXPA01010496 patent/MXPA01010496A/es not_active Application Discontinuation
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6849665B2 (en) | 2000-12-29 | 2005-02-01 | Basf Aktiengesellschaft | Absorbent compositions |
| US7838567B2 (en) | 2002-02-06 | 2010-11-23 | Basf Aktiengesellschaft | Foams made from water-absorbing, basic polymers, method for the production and utilization thereof |
| US7147752B2 (en) | 2002-12-31 | 2006-12-12 | Kimberly-Clark Worldwide, Inc. | Hydrophilic fibers containing substantive polysiloxanes and tissue products made therefrom |
| US7186318B2 (en) | 2003-12-19 | 2007-03-06 | Kimberly-Clark Worldwide, Inc. | Soft tissue hydrophilic tissue products containing polysiloxane and having unique absorbent properties |
| US7479578B2 (en) | 2003-12-19 | 2009-01-20 | Kimberly-Clark Worldwide, Inc. | Highly wettable—highly flexible fluff fibers and disposable absorbent products made of those |
| US7811948B2 (en) | 2003-12-19 | 2010-10-12 | Kimberly-Clark Worldwide, Inc. | Tissue sheets containing multiple polysiloxanes and having regions of varying hydrophobicity |
| EP1729881A4 (fr) * | 2004-03-31 | 2012-07-04 | Nippon Catalytic Chem Ind | Un agent absorbant de liquides aqueux et procédé pour la fabrication de celui-ci |
| US8324446B2 (en) | 2004-06-30 | 2012-12-04 | Kimberly-Clark Worldwide, Inc. | Unitary absorbent core with binding agents |
| US7816301B2 (en) | 2005-09-30 | 2010-10-19 | Nippon Shokubai Co., Ltd. | Aqueous-liquid-absorbing agent and its production process |
| CN101283003B (zh) * | 2005-09-30 | 2013-11-13 | 株式会社日本触媒 | 含水液体吸收剂和它的生产方法 |
| US9777078B2 (en) | 2006-07-19 | 2017-10-03 | Basf Se | Method for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution |
| US9486981B2 (en) | 2011-09-13 | 2016-11-08 | Basf Se | Use of polyethyleneimines in the preparation of polyamides |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002542364A (ja) | 2002-12-10 |
| EP1175460A1 (fr) | 2002-01-30 |
| MXPA01010496A (es) | 2002-03-01 |
| PL351567A1 (en) | 2003-05-05 |
| WO2000063295A1 (fr) | 2000-10-26 |
| BR0009873A (pt) | 2002-04-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |