CA2137773A1 - Compositions granulaires agricoles dispersables dans l'eau - Google Patents

Compositions granulaires agricoles dispersables dans l'eau

Info

Publication number: CA2137773A1
Authority: CA; Canada
Prior art keywords: water; heat; activated binder; molecular weight; granules
Prior art date: 1992-06-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002137773A

Other languages

English (en)

Inventor

Roy Quinn Freeman Iii

Lionel Samuel Sandell

Thomas Joseph Zaucha

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-06-16

Filing date

1993-06-10

Publication date

1993-12-23

1993-06-10 Application filed by Individual filed Critical Individual

1993-12-23 Publication of CA2137773A1 publication Critical patent/CA2137773A1/fr

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 90
239000008187 granular material Substances 0.000 claims abstract description 63
229920001223 polyethylene glycol Polymers 0.000 claims abstract description 42
239000011230 binding agent Substances 0.000 claims abstract description 32
239000002202 Polyethylene glycol Substances 0.000 claims abstract description 18
235000010603 pastilles Nutrition 0.000 claims abstract description 18
150000001298 alcohols Chemical class 0.000 claims abstract description 11
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 11
239000000194 fatty acid Substances 0.000 claims abstract description 11
229930195729 fatty acid Natural products 0.000 claims abstract description 11
150000004665 fatty acids Chemical class 0.000 claims abstract description 11
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 10
229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 10
238000000034 method Methods 0.000 claims description 36
239000004480 active ingredient Substances 0.000 claims description 29
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
239000000654 additive Substances 0.000 claims description 21
239000004615 ingredient Substances 0.000 claims description 19
239000007884 disintegrant Substances 0.000 claims description 14
239000002270 dispersing agent Substances 0.000 claims description 12
239000000080 wetting agent Substances 0.000 claims description 10
239000003795 chemical substances by application Substances 0.000 claims description 9
229920001577 copolymer Polymers 0.000 claims description 9
239000000126 substance Substances 0.000 claims description 8
239000003381 stabilizer Substances 0.000 claims description 7
230000008961 swelling Effects 0.000 claims description 7
239000003701 inert diluent Substances 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 4
238000005520 cutting process Methods 0.000 claims description 2
150000002191 fatty alcohols Chemical class 0.000 claims 1
230000000361 pesticidal effect Effects 0.000 abstract description 11
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
-1 hydroY.ybenzonitrile Chemical compound 0.000 description 27
238000004062 sedimentation Methods 0.000 description 23
229920002594 Polyethylene Glycol 8000 Polymers 0.000 description 21
238000012360 testing method Methods 0.000 description 19
238000001125 extrusion Methods 0.000 description 17
239000002245 particle Substances 0.000 description 15
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
238000009472 formulation Methods 0.000 description 11
239000000575 pesticide Substances 0.000 description 10
239000011734 sodium Substances 0.000 description 10
229910052708 sodium Inorganic materials 0.000 description 10
238000005469 granulation Methods 0.000 description 9
230000003179 granulation Effects 0.000 description 9
239000000843 powder Substances 0.000 description 8
239000004562 water dispersible granule Substances 0.000 description 8
VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 7
238000000354 decomposition reaction Methods 0.000 description 7
238000002844 melting Methods 0.000 description 7
230000008018 melting Effects 0.000 description 7
238000002156 mixing Methods 0.000 description 7
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 7
229910052939 potassium sulfate Inorganic materials 0.000 description 7
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
239000005584 Metsulfuron-methyl Substances 0.000 description 6
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
238000001816 cooling Methods 0.000 description 6
RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 description 6
235000011151 potassium sulphates Nutrition 0.000 description 6
239000002002 slurry Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
230000032683 aging Effects 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
239000000463 material Substances 0.000 description 5
230000007704 transition Effects 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
239000011575 calcium Substances 0.000 description 4
229910052791 calcium Inorganic materials 0.000 description 4
229910000019 calcium carbonate Inorganic materials 0.000 description 4
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
235000013539 calcium stearate Nutrition 0.000 description 4
239000012141 concentrate Substances 0.000 description 4
239000003085 diluting agent Substances 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000001267 polyvinylpyrrolidone Substances 0.000 description 4
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
239000000344 soap Substances 0.000 description 4
235000017557 sodium bicarbonate Nutrition 0.000 description 4
238000005507 spraying Methods 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
239000000642 acaricide Substances 0.000 description 3
150000003863 ammonium salts Chemical class 0.000 description 3
239000008116 calcium stearate Substances 0.000 description 3
NSWAMPCUPHPTTC-UHFFFAOYSA-N chlorimuron-ethyl Chemical group CCOC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(Cl)=CC(OC)=N1 NSWAMPCUPHPTTC-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000000428 dust Substances 0.000 description 3
239000000155 melt Substances 0.000 description 3
238000003801 milling Methods 0.000 description 3
229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 3
238000007711 solidification Methods 0.000 description 3
230000008023 solidification Effects 0.000 description 3
238000003860 storage Methods 0.000 description 3
ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
239000000454 talc Substances 0.000 description 3
229910052623 talc Inorganic materials 0.000 description 3
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 3
FPCVFWSJHMLPDB-UHFFFAOYSA-N 2-[[4-[(2,4-diaminopteridin-6-yl)methyl-methylamino]benzoyl]amino]-4-fluoropentanedioic acid Chemical compound C=1N=C2N=C(N)N=C(N)C2=NC=1CN(C)C1=CC=C(C(=O)NC(CC(F)C(O)=O)C(O)=O)C=C1 FPCVFWSJHMLPDB-UHFFFAOYSA-N 0.000 description 2
XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 2
239000005472 Bensulfuron methyl Substances 0.000 description 2
229920002785 Croscarmellose sodium Polymers 0.000 description 2
239000005510 Diuron Substances 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
230000000895 acaricidal effect Effects 0.000 description 2
239000000443 aerosol Substances 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
230000000844 anti-bacterial effect Effects 0.000 description 2
239000007900 aqueous suspension Substances 0.000 description 2
239000003899 bactericide agent Substances 0.000 description 2
XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
238000005056 compaction Methods 0.000 description 2
239000001767 crosslinked sodium carboxy methyl cellulose Substances 0.000 description 2
235000010947 crosslinked sodium carboxy methyl cellulose Nutrition 0.000 description 2
MZZBPDKVEFVLFF-UHFFFAOYSA-N cyanazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C#N)=N1 MZZBPDKVEFVLFF-UHFFFAOYSA-N 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
238000010981 drying operation Methods 0.000 description 2
239000000417 fungicide Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000004009 herbicide Substances 0.000 description 2
239000002917 insecticide Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000010008 shearing Methods 0.000 description 2
239000001632 sodium acetate Substances 0.000 description 2
235000017281 sodium acetate Nutrition 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
229940048086 sodium pyrophosphate Drugs 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
239000008107 starch Substances 0.000 description 2
229940032147 starch Drugs 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
XERJKGMBORTKEO-VZUCSPMQSA-N (1e)-2-(ethylcarbamoylamino)-n-methoxy-2-oxoethanimidoyl cyanide Chemical compound CCNC(=O)NC(=O)C(\C#N)=N\OC XERJKGMBORTKEO-VZUCSPMQSA-N 0.000 description 1
NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 1
WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 1
LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
IMLJLCJZQLGHJS-JEKSYDDFSA-N (4s,4ar,5s,5ar,6s,12ar)-4-(dimethylamino)-1,5,6,10,11,12a-hexahydroxy-6-methyl-3,12-dioxo-4,4a,5,5a-tetrahydrotetracene-2-carboxamide;dihydrate Chemical compound O.O.C1=CC=C2[C@](O)(C)[C@H]3[C@H](O)[C@H]4[C@H](N(C)C)C(=O)C(C(N)=O)=C(O)[C@@]4(O)C(=O)C3=C(O)C2=C1O IMLJLCJZQLGHJS-JEKSYDDFSA-N 0.000 description 1
JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 description 1
YIKWKLYQRFRGPM-UHFFFAOYSA-N 1-dodecylguanidine acetate Chemical compound CC(O)=O.CCCCCCCCCCCCN=C(N)N YIKWKLYQRFRGPM-UHFFFAOYSA-N 0.000 description 1
HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
239000002794 2,4-DB Substances 0.000 description 1
YIVXMZJTEQBPQO-UHFFFAOYSA-N 2,4-DB Chemical compound OC(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-N 0.000 description 1
239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 1
MZHCENGPTKEIGP-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-UHFFFAOYSA-N 0.000 description 1
STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 description 1
KFEFNHNXZQYTEW-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-4-methylbenzoic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=CC(C)=CC=C1C(O)=O KFEFNHNXZQYTEW-UHFFFAOYSA-N 0.000 description 1
CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 description 1
LLWADFLAOKUBDR-UHFFFAOYSA-N 2-methyl-4-chlorophenoxybutyric acid Chemical compound CC1=CC(Cl)=CC=C1OCCCC(O)=O LLWADFLAOKUBDR-UHFFFAOYSA-N 0.000 description 1
UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 description 1
FSCWZHGZWWDELK-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione Chemical compound O=C1C(C)(C=C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FSCWZHGZWWDELK-UHFFFAOYSA-N 0.000 description 1
PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
CTSLUCNDVMMDHG-UHFFFAOYSA-N 5-bromo-3-(butan-2-yl)-6-methylpyrimidine-2,4(1H,3H)-dione Chemical compound CCC(C)N1C(=O)NC(C)=C(Br)C1=O CTSLUCNDVMMDHG-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
239000005489 Bromoxynil Substances 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
239000005745 Captan Substances 0.000 description 1
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HSSBORCLYSCBJR-UHFFFAOYSA-N Chloramben Chemical compound NC1=CC(Cl)=CC(C(O)=O)=C1Cl HSSBORCLYSCBJR-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
239000005747 Chlorothalonil Substances 0.000 description 1
239000005496 Chlorsulfuron Substances 0.000 description 1
239000005499 Clomazone Substances 0.000 description 1
239000005756 Cymoxanil Substances 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
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239000005644 Dazomet Substances 0.000 description 1
239000005892 Deltamethrin Substances 0.000 description 1
239000004375 Dextrin Substances 0.000 description 1
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LWLJUMBEZJHXHV-UHFFFAOYSA-N Dienochlor Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C1(Cl)C1(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LWLJUMBEZJHXHV-UHFFFAOYSA-N 0.000 description 1
QAHFOPIILNICLA-UHFFFAOYSA-N Diphenamid Chemical compound C=1C=CC=CC=1C(C(=O)N(C)C)C1=CC=CC=C1 QAHFOPIILNICLA-UHFFFAOYSA-N 0.000 description 1
NPWMZOGDXOFZIN-UHFFFAOYSA-N Dipropetryn Chemical compound CCSC1=NC(NC(C)C)=NC(NC(C)C)=N1 NPWMZOGDXOFZIN-UHFFFAOYSA-N 0.000 description 1
239000005766 Dodine Substances 0.000 description 1
239000001692 EU approved anti-caking agent Substances 0.000 description 1
239000005533 Fluometuron Substances 0.000 description 1
YWBVHLJPRPCRSD-UHFFFAOYSA-N Fluridone Chemical compound O=C1C(C=2C=C(C=CC=2)C(F)(F)F)=CN(C)C=C1C1=CC=CC=C1 YWBVHLJPRPCRSD-UHFFFAOYSA-N 0.000 description 1
239000005787 Flutriafol Substances 0.000 description 1
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239000005562 Glyphosate Substances 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 description 1
239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
239000005981 Imazaquin Substances 0.000 description 1
XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 description 1
239000005867 Iprodione Substances 0.000 description 1
JLLJHQLUZAKJFH-UHFFFAOYSA-N Isouron Chemical compound CN(C)C(=O)NC=1C=C(C(C)(C)C)ON=1 JLLJHQLUZAKJFH-UHFFFAOYSA-N 0.000 description 1
239000005570 Isoxaben Substances 0.000 description 1
UQVYUTAMNICZNI-UHFFFAOYSA-N Karbutilate Chemical compound CN(C)C(=O)NC1=CC=CC(NC(=O)OC(C)(C)C)=C1 UQVYUTAMNICZNI-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
239000005572 Lenacil Substances 0.000 description 1
229920001732 Lignosulfonate Polymers 0.000 description 1
239000005574 MCPA Substances 0.000 description 1
239000005575 MCPB Substances 0.000 description 1
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239000004416 thermosoftening plastic Substances 0.000 description 1
239000004308 thiabendazole Substances 0.000 description 1
WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
229960004546 thiabendazole Drugs 0.000 description 1
235000010296 thiabendazole Nutrition 0.000 description 1
LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 description 1
BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
229960002447 thiram Drugs 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229910000385 transition metal sulfate Inorganic materials 0.000 description 1
XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 description 1
YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 description 1
REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
UGCNRZFAUBJVPT-UHFFFAOYSA-N tricyclohexyltin;hydrate Chemical compound O.C1CCCCC1[Sn](C1CCCCC1)C1CCCCC1 UGCNRZFAUBJVPT-UHFFFAOYSA-N 0.000 description 1
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
239000011345 viscous material Substances 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
238000009736 wetting Methods 0.000 description 1
235000016804 zinc Nutrition 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable

Landscapes

Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Toxicology (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Agronomy & Crop Science (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CA002137773A 1992-06-16 1993-06-10 Compositions granulaires agricoles dispersables dans l'eau Abandoned CA2137773A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US89940592A	1992-06-16	1992-06-16
US07/899,405		1992-06-16

Publications (1)

Publication Number	Publication Date
CA2137773A1 true CA2137773A1 (fr)	1993-12-23

Family

ID=25410905

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002137773A Abandoned CA2137773A1 (fr)	1992-06-16	1993-06-10	Compositions granulaires agricoles dispersables dans l'eau

Country Status (11)

Country	Link
EP (1)	EP0645961A1 (fr)
JP (1)	JPH07507803A (fr)
CN (1)	CN1082814A (fr)
AU (1)	AU4528693A (fr)
BR (1)	BR9306686A (fr)
CA (1)	CA2137773A1 (fr)
HU (1)	HUT70290A (fr)
IL (1)	IL106021A0 (fr)
RU (1)	RU94046230A (fr)
TW (1)	TW230742B (fr)
WO (1)	WO1993025074A1 (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2704387B1 (fr)	1993-04-28	1995-06-09	Rhone Poulenc Agrochimie	Compositions concentrees de matieres actives en agriculture.
US5431857A (en) *	1994-01-19	1995-07-11	The Procter & Gamble Company	Process for producing a high density detergent composition having improved solubility by agglomeration of anionic surfactants and an agglomerating agent
DE69520429T2 (de) *	1995-07-27	2001-10-04	Micro Flo Co., Mulberry	Einkapselung mit Emulgatoren
GB9521707D0 (en) *	1995-10-24	1996-01-03	Zeneca Ltd	Improved granule composition
IL135664A0 (en) *	1997-10-29	2001-05-20	Basf Ag	Solid formulation of a plant protection agent
DE19809242A1 (de) *	1998-03-05	1999-09-09	Basf Ag	Verfahren zur Herstellung von festen, sphärischen Formkörpern, enthaltend pharmazeutische Wirkstoffe in einer Bindemittelmatrix
PE20001522A1 (es) *	1999-02-11	2000-12-29	American Cyanamid Co	Composiciones extruidas livianas que contienen un portador ceramico liviano extruible, metodos de uso de las mismas y procesos para su preparacion
US6340656B1 (en)	1999-02-11	2002-01-22	American Cyanamid Co.	Light, extruded compositions containing a light, extrudable, ceramic carrier, methods for their use, and processes for their preparation
DE10036002A1 (de) *	2000-07-25	2002-02-14	Aventis Cropscience Gmbh	Herbizide Mittel
DE10036003A1 (de) *	2000-07-25	2002-02-14	Aventis Cropscience Gmbh	Herbizide Mittel
US7157094B2 (en) *	2001-03-09	2007-01-02	Arysta Lifescience North America Group	Granulated active ingredients
JP4408630B2 (ja)	2001-04-11	2010-02-03	バレントバイオサイエンシスコーポレーション	濃縮された水溶性顆粒状植物成長調節剤配合物およびそれらの使用方法
DE102005051830A1 (de)	2005-10-28	2007-05-03	Basf Ag	Polyalkoxylat-haltige Feststoffformulierungen, Verfahren zu ihrer Herstellung und ihre Verwendung
DE102005051823A1 (de) *	2005-10-28	2007-05-03	Basf Ag	Polyalkoxylat-haltige feste Pflanzenschutzmittel, Verfahren zu ihrer Herstellung und ihre Verwendung
CN101167464B (zh) *	2007-12-07	2010-04-07	张少武	一种四螨嗪水分散粒剂及其制备方法
US20130243839A1 (en) *	2011-08-08	2013-09-19	Landec Corporation	Controlled, Sustained Release Particles for Treating Seeds and Plants and Methods for Making the Particles
EP2790501B1 (fr) *	2011-12-15	2017-03-15	Basf Se	Formules agricoles solides préparées à partir d'un mélange de pesticide et de polyalkoxylate, contenant en option un adjuvant liquide complexé avec du polycarboxylate
JP6527391B2 (ja) *	2015-06-02	2019-06-05	レジノカラー工業株式会社	表面処理有機酸組成物
WO2022096286A1 (fr) *	2020-11-05	2022-05-12	Clariant International Ltd	Procédé de fabrication de particules agglomérées de piroctone olamine

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4183740A (en) *	1978-01-05	1980-01-15	American Cyanamid Company	Solid compositions of a liquid surfactant and a pyrazolium herbicide
JP2770400B2 (ja) *	1989-04-18	1998-07-02	住友化学工業株式会社	農薬固型製剤
CA2083185A1 (fr) *	1990-03-12	1991-09-13	William Lawrence Geigle	Granules de pesticide dispersibles et solubles dans l'eau, liberees de leurs agents liants sous l'effet de la chaleur
RU2096955C1 (ru) *	1991-03-01	1997-11-27	Е.И.Дюпон Де Немур Энд Компани	Вододиспергируемая гранулированная пестицидная композиция, получаемая методом экструзии, и способ ее получения

1993
- 1993-05-18 TW TW082103884A patent/TW230742B/zh active
- 1993-06-10 EP EP93915220A patent/EP0645961A1/fr not_active Withdrawn
- 1993-06-10 BR BR9306686A patent/BR9306686A/pt not_active Application Discontinuation
- 1993-06-10 AU AU45286/93A patent/AU4528693A/en not_active Abandoned
- 1993-06-10 JP JP6501621A patent/JPH07507803A/ja active Pending
- 1993-06-10 HU HU9403616A patent/HUT70290A/hu unknown
- 1993-06-10 RU RU94046230/04A patent/RU94046230A/ru unknown
- 1993-06-10 CA CA002137773A patent/CA2137773A1/fr not_active Abandoned
- 1993-06-10 WO PCT/US1993/005371 patent/WO1993025074A1/fr not_active Ceased
- 1993-06-15 IL IL106021A patent/IL106021A0/xx unknown
- 1993-06-16 CN CN93108411.3A patent/CN1082814A/zh active Pending

Also Published As

Publication number	Publication date
RU94046230A (ru)	1996-10-27
WO1993025074A1 (fr)	1993-12-23
CN1082814A (zh)	1994-03-02
TW230742B (fr)	1994-09-21
EP0645961A1 (fr)	1995-04-05
AU4528693A (en)	1994-01-04
HUT70290A (en)	1995-09-28
IL106021A0 (en)	1993-10-20
HU9403616D0 (en)	1995-02-28
BR9306686A (pt)	1998-12-08
JPH07507803A (ja)	1995-08-31

Publication	Publication Date	Title
EP0720427B1 (fr)	1998-06-24	Compositions de granules destinees a l'agriculture, se dispersant dans l'eau et preparees par extrusion a chaud
CA2137773A1 (fr)	1993-12-23	Compositions granulaires agricoles dispersables dans l'eau
EP0575489B1 (fr)	1997-07-02	Compositions pour l'agriculture, granulaires et dispersibles dans l'eau, produites par extrusion thermique
EP0321527B1 (fr)	1992-08-12	Granules se dispersant dans l'eau
EP0519937B1 (fr)	1994-12-28	Granules pesticides dispersibles ou solubles dans l'eau, obtenus a partir de liants thermo-actives
EP0633722B1 (fr)	1997-06-04	Granules dispersibles dans l'eau, comprenant des pesticides liquides
JP5822055B2 (ja)	2015-11-24	農薬活性成分の放出が制御される固型農薬製剤
JP2003507395A (ja)	2003-02-25	水分散性農薬組成物
KR101291184B1 (ko)	2013-07-31	과립상 농약 조성물 및 그 제조 방법
RU2242274C2 (ru)	2004-12-20	Усовершенствованный способ экструзии
JP2010168298A (ja)	2010-08-05	農薬活性成分の放出が制御される固型農薬製剤
EP1161145B1 (fr)	2003-06-25	Procede de production de granules
WO2005120227A2 (fr)	2005-12-22	Composition chimique

Legal Events

Date	Code	Title	Description
1998-06-10	FZDE	Discontinued