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CA2017353A1 - Procede de production continue en vrac de (co)polymeres vinylaromatiques tres resistants - Google Patents

Procede de production continue en vrac de (co)polymeres vinylaromatiques tres resistants

Info

Publication number
CA2017353A1
CA2017353A1 CA2017353A CA2017353A CA2017353A1 CA 2017353 A1 CA2017353 A1 CA 2017353A1 CA 2017353 A CA2017353 A CA 2017353A CA 2017353 A CA2017353 A CA 2017353A CA 2017353 A1 CA2017353 A1 CA 2017353A1
Authority
CA
Canada
Prior art keywords
reactor
high impact
continuous bulk
bulk production
vinylaromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2017353A
Other languages
English (en)
Other versions
CA2017353C (fr
Inventor
Claudio Buonerba
Savino Matarrese
Franco Balestri
Italo Borghi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedipe SpA
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2017353A1 publication Critical patent/CA2017353A1/fr
Application granted granted Critical
Publication of CA2017353C publication Critical patent/CA2017353C/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1862—Stationary reactors having moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Silicon Polymers (AREA)
CA002017353A 1989-05-24 1990-05-23 Procede de production continue en vrac de (co)polymeres vinylaromatiques tres resistants Expired - Lifetime CA2017353C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT8920623A IT1230085B (it) 1989-05-24 1989-05-24 Processo per la produzione in massa e in continuo di (co) polimeri vinil aromatici antiurto.
IT20623A/89 1989-05-24

Publications (2)

Publication Number Publication Date
CA2017353A1 true CA2017353A1 (fr) 1990-11-24
CA2017353C CA2017353C (fr) 2000-11-07

Family

ID=11169703

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002017353A Expired - Lifetime CA2017353C (fr) 1989-05-24 1990-05-23 Procede de production continue en vrac de (co)polymeres vinylaromatiques tres resistants

Country Status (19)

Country Link
US (1) US5166260A (fr)
EP (1) EP0400479B1 (fr)
JP (1) JP2885884B2 (fr)
KR (1) KR0178368B1 (fr)
CN (1) CN1031271C (fr)
AT (1) ATE118020T1 (fr)
AU (1) AU627879B2 (fr)
BR (1) BR9002429A (fr)
CA (1) CA2017353C (fr)
CZ (1) CZ283471B6 (fr)
DE (1) DE69016499T2 (fr)
ES (1) ES2068281T3 (fr)
HU (1) HU207872B (fr)
IT (1) IT1230085B (fr)
PL (1) PL164659B1 (fr)
RU (1) RU2061706C1 (fr)
TN (1) TNSN90067A1 (fr)
TR (1) TR26403A (fr)
ZA (1) ZA903957B (fr)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW366351B (en) * 1994-12-26 1999-08-11 Mitsui Chemicals Inc Production process of acrylonitrile (co)polymers
KR100361886B1 (ko) * 1994-12-30 2003-01-29 주식회사 엘지씨아이 고유동,내충격성스티렌계수지조성물의연속적제조방법
IT1283041B1 (it) * 1996-05-21 1998-04-07 Enichem Spa Procedimento per la preparazione di resine abs
IT1284931B1 (it) * 1996-10-08 1998-05-28 Enichem Spa Processo in continuo per la reticolazione selettiva della fase dispersa di polimeri aes impiegante apparecchi di miscelazione posti
US6013735A (en) * 1998-02-13 2000-01-11 Ethyl Corporation Process for the preparation of acrylate and methacrylate polymers
DE69901954D1 (de) 1998-04-28 2002-08-01 Heriot Watt University Edinbur Verfahren und vorrichtung zur phasen-getrennten synthese
KR20000013236A (ko) * 1998-08-06 2000-03-06 유현식 이형성이 우수한 고강성 열가소성 수지의 제조방법
US6380304B1 (en) * 1999-09-30 2002-04-30 The Dow Chemical Company Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions
IT1314260B1 (it) 1999-12-03 2002-12-06 Enichem Spa Procedimento per la produzione di polimeri vinilaromaticieventualmente contenenti un nitrile etilenicamente insaturo.
US6448353B1 (en) 2000-02-08 2002-09-10 3M Innovative Properties Company Continuous process for the production of controlled architecture materials
US6569941B2 (en) * 2001-03-30 2003-05-27 Fina Technology, Inc. Process for manufacturing impact resistant monovinylaromatic polymers
US7514263B2 (en) 2001-04-02 2009-04-07 3M Innovative Properties Company Continuous process for the production of combinatorial libraries of materials
KR100463348B1 (ko) * 2001-12-18 2004-12-23 주식회사 엘지화학 잔류 응력 크랙 저항성이 우수한 고무 변성 스티렌계수지의 제조 방법
KR100464697B1 (ko) * 2001-12-26 2005-01-05 제일모직주식회사 이형성이 우수한 고유동 열가소성 수지의 제조방법
KR100464696B1 (ko) * 2001-12-26 2005-01-05 제일모직주식회사 고내열 열가소성 수지의 제조방법
KR100465880B1 (ko) * 2001-12-27 2005-01-13 제일모직주식회사 고유동 고강성 열가소성 수지의 제조방법
RU2217442C1 (ru) * 2002-05-06 2003-11-27 Открытое акционерное общество "Пластполимер" Способ получения ударопрочного полистирола
US7632916B2 (en) 2002-08-02 2009-12-15 3M Innovative Properties Company Process to modify polymeric materials and resulting compositions
US6716935B1 (en) 2002-12-19 2004-04-06 3M Innovative Properties Company Continuous process for the production of controlled architecture materials under high solids loading conditions
US6969490B2 (en) * 2003-06-26 2005-11-29 3M Innovative Properties Company Device for the continuous process for the production of controlled architecture materials
US7129297B2 (en) * 2003-09-29 2006-10-31 Fina Technology, Inc. Polystyrene blends and a method of making same
KR100568772B1 (ko) * 2003-10-07 2006-04-07 주식회사 엘지화학 고충격 및 고광택을 갖는 아크릴로니트릴-부타디엔-스티렌 수지 제조방법
ITMI20040752A1 (it) * 2004-04-16 2004-07-16 Polimeri Europa Spa Procedimento per la preparazione di co polimeri vinilaromatici aggraffati su elastometro in modo controllato
CN100489000C (zh) 2004-04-21 2009-05-20 陶氏环球技术公司 改进的本体聚合的橡胶-改性单亚乙烯基芳族共聚物组合物
KR100671135B1 (ko) 2004-09-08 2007-01-17 주식회사 엘지화학 고충격 고광택 고무변성 스티렌계 공중합 수지의 제조방법
ITMI20042401A1 (it) * 2004-12-16 2005-03-16 Polimeri Europa Spa Procedimento per la preparazione di co-polimeri vinilaromatici antiurto aggraffati su elastomero
EP2357036B1 (fr) * 2008-11-21 2017-09-27 LG Chem, Ltd. Procédé et appareil de fabrication de particule de polymère
US10538611B2 (en) 2014-04-18 2020-01-21 Nippon A&L Inc. Graft copolymer and thermoplastic resin composition
TW202330677A (zh) 2021-12-10 2023-08-01 義大利商佛沙里斯股份有限公司 橡膠強化的乙烯芳香族(共)聚合物及其製備方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3945976A (en) * 1968-09-30 1976-03-23 Standard Oil Company Process for producing impact resistant polymer
CA979569A (en) * 1970-12-09 1975-12-09 Toray Industries, Inc. Method for producing impact resistant thermoplastic resin by continuous bulk polymerization
ES459128A1 (es) * 1976-05-28 1978-04-01 Monsanto Co Un procedimiento industrial para preparar una polimezcla.
US4254236A (en) * 1979-03-07 1981-03-03 Monsanto Company Process for the continuous mass polymerization of polyblends having a bimodal rubber particle size
US4325915A (en) * 1980-03-27 1982-04-20 Toray Industries, Inc. Bulk polymerization reactor
DE3018643C2 (de) * 1980-05-16 1982-07-08 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von schlagfest modifizierten Styrolpolymerisaten
US4451612A (en) * 1980-09-22 1984-05-29 Mobil Oil Corporation Continuous process for the preparation of rubber modified polymers
US4325919A (en) * 1981-01-19 1982-04-20 Amax Inc. Autoclave soda digestion of scheelite concentrates with feedback control
US4640959A (en) * 1983-09-16 1987-02-03 The Dow Chemical Company ABS type resin having disperse particles of a rubber exhibiting a high solution viscosity and a method for its preparation
US4594391A (en) * 1984-05-21 1986-06-10 The Dow Chemical Company Impact-modified monovinylidene aromatic polymer injection molding resins
WO1988003538A1 (fr) * 1986-11-07 1988-05-19 Manuel Darryl F Procede de polymerisation a chaud pour la production d'un large spectre de resines
JPS63118315A (ja) * 1986-11-07 1988-05-23 Nippon Steel Chem Co Ltd スチレン系耐衝撃性樹脂の製造法
NL8700208A (nl) * 1987-01-28 1988-08-16 Dow Chemical Nederland Verbeterde met rubber versterkte monovinylideen-aromatische polymeerharsen en een werkwijze voor de bereiding daarvan.
IT1218559B (it) * 1987-04-07 1990-04-19 Montedipe Spa Processo per la produzione in soluzione e in continuo di resine termoplastiche stireniche

Also Published As

Publication number Publication date
KR0178368B1 (ko) 1999-05-15
CN1047508A (zh) 1990-12-05
EP0400479B1 (fr) 1995-02-01
HUT55810A (en) 1991-06-28
KR900018147A (ko) 1990-12-20
AU5583490A (en) 1990-11-29
ES2068281T3 (es) 1995-04-16
EP0400479A2 (fr) 1990-12-05
PL164659B1 (pl) 1994-09-30
DE69016499T2 (de) 1995-06-14
CZ251790A3 (en) 1997-11-12
HU207872B (en) 1993-06-28
RU2061706C1 (ru) 1996-06-10
PL285304A1 (en) 1991-02-11
HU903163D0 (en) 1990-10-28
AU627879B2 (en) 1992-09-03
JPH03210311A (ja) 1991-09-13
CZ283471B6 (cs) 1998-04-15
IT1230085B (it) 1991-10-05
DE69016499D1 (de) 1995-03-16
ATE118020T1 (de) 1995-02-15
CA2017353C (fr) 2000-11-07
BR9002429A (pt) 1991-08-06
CN1031271C (zh) 1996-03-13
IT8920623A0 (it) 1989-05-24
ZA903957B (en) 1991-03-27
JP2885884B2 (ja) 1999-04-26
EP0400479A3 (fr) 1991-10-09
TNSN90067A1 (fr) 1991-03-05
US5166260A (en) 1992-11-24
TR26403A (tr) 1995-03-15

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