[go: up one dir, main page]

AR066682A1 - Un proceso para remover azufre a partir de sendas corrientes de gas de combustible, menos reactivas y mas reactivas que contienen azufre organico y olefinas livianas - Google Patents

Un proceso para remover azufre a partir de sendas corrientes de gas de combustible, menos reactivas y mas reactivas que contienen azufre organico y olefinas livianas

Info

Publication number
AR066682A1
AR066682A1 ARP080102174A ARP080102174A AR066682A1 AR 066682 A1 AR066682 A1 AR 066682A1 AR P080102174 A ARP080102174 A AR P080102174A AR P080102174 A ARP080102174 A AR P080102174A AR 066682 A1 AR066682 A1 AR 066682A1
Authority
AR
Argentina
Prior art keywords
fuel gas
reagent
sulfur
organic sulfur
containing organic
Prior art date
Application number
ARP080102174A
Other languages
English (en)
Inventor
Gary Lee Ripperger
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of AR066682A1 publication Critical patent/AR066682A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/02—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/06—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by gas-liquid contact
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

En la presente se describe un proceso para remover azufre orgánico de más de una corriente de gas de combustible reactivo. Un recipiente reactor contiene al menos un lecho de catalizador de hidrodesulfurizacion, el cual se utiliza parahidrodesulfurizar multiples corrientes de gas combustible reactivas con una corriente de gas combustible menos reactiva que se introduce en el recipiente reactor en un punto por encima del punto de introduccion de una corriente de gas combustiblemás reactiva. Se obtiene un gas de combustible hidrotratado a partir del recipiente reactor con concentracion de sulfuro de hidrogeno y menor contenido de azufre orgánico.
ARP080102174A 2007-05-25 2008-05-22 Un proceso para remover azufre a partir de sendas corrientes de gas de combustible, menos reactivas y mas reactivas que contienen azufre organico y olefinas livianas AR066682A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US94022107P 2007-05-25 2007-05-25

Publications (1)

Publication Number Publication Date
AR066682A1 true AR066682A1 (es) 2009-09-02

Family

ID=39689127

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP080102174A AR066682A1 (es) 2007-05-25 2008-05-22 Un proceso para remover azufre a partir de sendas corrientes de gas de combustible, menos reactivas y mas reactivas que contienen azufre organico y olefinas livianas

Country Status (4)

Country Link
US (1) US8257673B2 (es)
AR (1) AR066682A1 (es)
CA (1) CA2687588A1 (es)
WO (1) WO2008148081A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009032802A1 (de) 2009-07-10 2011-01-13 Uhde Gmbh Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe durch Regelung des Olefinanteils
US8808654B2 (en) * 2009-09-29 2014-08-19 Praxair Technology, Inc. Process for sulfur removal from refinery off gas

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2434868A (en) 1945-11-05 1948-01-20 Shell Dev Process for the removal of carbonyl sulfide from a hydrocarbon fluid
GB1044771A (es) 1963-04-02 1900-01-01
US3428429A (en) 1967-01-03 1969-02-18 Universal Oil Prod Co Method for purifying hydrogen
US3523009A (en) 1969-03-10 1970-08-04 Continental Oil Co Recovery of aluminum chloride from spent aluminum chloride alkylation catalyst sludge
US3730694A (en) 1971-08-11 1973-05-01 Atlantic Richfield Co Fuel gas upgrading
DE2250169A1 (de) 1972-10-13 1974-04-25 Metallgesellschaft Ag Verfahren zur entschwefelung technischer brenngase und synthesegase
GB1563251A (en) 1976-12-07 1980-03-26 Shell Int Research Process for working hydrogen suphidecontaining gases
US4153671A (en) 1977-01-13 1979-05-08 Nalco Chemical Company Catalytic gas purification process
US4545976A (en) 1983-11-10 1985-10-08 Exxon Research & Engineering Co. Hydrocarbon steam reforming using series steam superheaters
US4491516A (en) 1983-11-22 1985-01-01 Sun Refining And Marketing Company Hydrolysis of carbonyl sulfide over alumina
US4505881A (en) 1983-11-29 1985-03-19 Shell Oil Company Ammonium polysulfide removal of HCN from gaseous streams, with subsequent production of NH3, H2 S, and CO2
US4508693A (en) 1983-11-29 1985-04-02 Shell Oil Co. Solution removal of HCN from gaseous streams, with pH adjustment of reacted solution and hydrolysis of thiocyanate formed
JPH0333191A (ja) 1989-03-17 1991-02-13 Fuji Electric Co Ltd 脱硫反応器
JP2812486B2 (ja) 1989-05-15 1998-10-22 大阪瓦斯株式会社 炭化水素の水蒸気改質方法
US5482617A (en) 1993-03-08 1996-01-09 Mobil Oil Corporation Desulfurization of hydrocarbon streams
US5401391A (en) 1993-03-08 1995-03-28 Mobil Oil Corporation Desulfurization of hydrocarbon streams
US6231753B1 (en) 1996-02-02 2001-05-15 Exxon Research And Engineering Company Two stage deep naphtha desulfurization with reduced mercaptan formation
MY117311A (en) 1996-08-22 2004-06-30 Shell Int Research Process for reducing total sulphur content in gases containing hydrogen sulphide and other sulphur components
CN1063152C (zh) 1998-03-20 2001-03-14 湖北省化学研究所 一种变换兼有机硫转化的净化方法
US6113776A (en) 1998-06-08 2000-09-05 Uop Llc FCC process with high temperature cracking zone
US6083378A (en) * 1998-09-10 2000-07-04 Catalytic Distillation Technologies Process for the simultaneous treatment and fractionation of light naphtha hydrocarbon streams
WO2000069561A1 (en) 1999-05-14 2000-11-23 Hitachi Chemical Research Center, Inc. Liquid metal-heating apparatus for biological/chemical sample
US6444118B1 (en) * 2001-02-16 2002-09-03 Catalytic Distillation Technologies Process for sulfur reduction in naphtha streams
US7261809B2 (en) 2001-12-28 2007-08-28 Catalytic Distillation Technologies Process for ultra low sulfur gasoline
US7297251B2 (en) * 2002-05-21 2007-11-20 Exxonmobil Research And Engineering Company Multi-stage hydrodesulfurization of cracked naphtha streams with a stacked bed reactor
BR0202413A (pt) 2002-06-26 2004-05-11 Petroleo Brasileiro Sa Processo de hidrodessulfurização seletiva de correntes olefìnicas
GB0316433D0 (en) * 2003-07-14 2003-08-20 Boc Group Plc Process for recovering sulphur from a gas stream containing hydrogen sulphide
US8623308B2 (en) 2004-08-02 2014-01-07 Shell Oil Company Process for removing mercaptans from a gas stream comprising natural gas on an inert gas
US7037485B1 (en) 2004-11-18 2006-05-02 Praxair Technology, Inc. Steam methane reforming method
US20060118465A1 (en) 2004-12-02 2006-06-08 The University Of Western Ontario Catalytic sulfur removal from a hydrocarbon stream
US7507328B2 (en) * 2004-12-27 2009-03-24 Exxonmobile Research And Engineering Company Selective hydrodesulfurization and mercaptan decomposition process with interstage separation
DE102005013276A1 (de) 2005-02-11 2006-08-24 Linde Ag Verfahren und Vorrichtung zur Reinigung von Gasströmen
WO2006125759A1 (en) 2005-05-23 2006-11-30 Shell Internationale Research Maatschappij B.V. Fischer-tropsch plant

Also Published As

Publication number Publication date
US8257673B2 (en) 2012-09-04
US20090050534A1 (en) 2009-02-26
CA2687588A1 (en) 2008-12-04
WO2008148081A1 (en) 2008-12-04

Similar Documents

Publication Publication Date Title
ES2437998T3 (es) Proceso de hidrogenación
PE20121004A1 (es) Hidropirolisis de biomasa para producir combustibles liquidos de alta calidad
IN2012DN00457A (es)
BRPI0517762A (pt) método de reforma de metano a vapor
NZ621616A (en) Hydropyrolysis of biomass for producing high quality liquid fuels
AR014482A1 (es) Un proceso para la conversion de gas usando hidrogeno producido del gas de sintesis para remover azufre de los liquidos de hidrocarburo del pozo de gas
AR072674A1 (es) Un metodo para la produccion de hidrocarburos livianos a partir de gas con alto contenido de metano, una celda de combustible de oxido solido usada para la produccion de hidrocarburos livianos a partir de gas con alto contenido de metano y un catalizador para la produccion de hidrocarburos livianos
EA201100090A1 (ru) Реактор, структурированная насадка и способ усовершенствованного окисления сероводорода или полисульфидов в жидкой сере
WO2011123251A3 (en) Gasoline hydrodesulfurization and membrane unit to reduce mercaptan type sulfur
BR112015009800A2 (pt) processo melhorado de conversão de uma carga contendo a biomassa para a produção de hidrocarbonetos por via de síntese fischer-tropsch
BR112012010055A2 (pt) métodos para produzir produtos de hidrocarbonetos a partir de bio-óleos e/ou óleos de carvão
AR062654A1 (es) Metodo de gasificacion en lecho fluidizado diferenciado y aparato de gasificacion de combustible solido
EA201490089A1 (ru) Способ регулирования отношения водорода к монооксиду углерода в синтез-газе
AR070939A1 (es) Proceso para la conversion de biogas en combustible liquido
AR055292A1 (es) Produccion de hidrocarburos aromaticos a partir del metano
ATE528070T1 (de) Sauerstoffentfernung
MX2013006481A (es) Descomposicion de polisulfuros y remocion de acido sulfhidrico.
RU2008135998A (ru) Способ гидродесульфуризации потока углеводородов
RU2009133698A (ru) Способ и гидрообработка углеводородного топлива
BR112012021858A2 (pt) método para a produção de hidrogênio visando armazenamento e transporte
CN104437032A (zh) 一种合成原料气深度精脱硫工艺及其装置
AR078392A1 (es) Procedimiento para la conversion de corrientes de fluido de desecho de plantas de procesamiento quimico en productos beneficiosos para la agricultura
AR066680A1 (es) Un proceso para remover azufre de una corriente de gas combustible, que tambien contiene dioxido de carbono y olefinas livianas
ATE503720T1 (de) Reaktor und verfahren zur herstellung von schwefelwasserstoff
BR112012021913B8 (pt) método para produção de gás de síntese

Legal Events

Date Code Title Description
FB Suspension of granting procedure