AR036105A1 - Piridinas sustituidas herbicidas, agente herbicida, procedimiento para combatir las plantas perjudiciales o para la regulacion del crecimiento de las de cultivo, su utilizacion como tal y procedimiento para la preparacion de dichos compuestos - Google Patents
Piridinas sustituidas herbicidas, agente herbicida, procedimiento para combatir las plantas perjudiciales o para la regulacion del crecimiento de las de cultivo, su utilizacion como tal y procedimiento para la preparacion de dichos compuestosInfo
- Publication number
- AR036105A1 AR036105A1 ARP020102347A ARP020102347A AR036105A1 AR 036105 A1 AR036105 A1 AR 036105A1 AR P020102347 A ARP020102347 A AR P020102347A AR P020102347 A ARP020102347 A AR P020102347A AR 036105 A1 AR036105 A1 AR 036105A1
- Authority
- AR
- Argentina
- Prior art keywords
- formula
- substituted
- compound
- alkyl
- compounds
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 13
- 238000000034 method Methods 0.000 title abstract 6
- 239000004009 herbicide Substances 0.000 title abstract 4
- 230000012010 growth Effects 0.000 title abstract 2
- 230000002363 herbicidal effect Effects 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 title 1
- 230000026267 regulation of growth Effects 0.000 title 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 7
- 150000003839 salts Chemical class 0.000 abstract 4
- 241000196324 Embryophyta Species 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- -1 AXH compound Chemical class 0.000 abstract 2
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 239000005648 plant growth regulator Substances 0.000 abstract 2
- HCMJWOGOISXSDL-UHFFFAOYSA-N (2-isothiocyanato-1-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(CN=C=S)C1=CC=CC=C1 HCMJWOGOISXSDL-UHFFFAOYSA-N 0.000 abstract 1
- 125000006648 (C1-C8) haloalkyl group Chemical group 0.000 abstract 1
- LMZSMDKFORHLCQ-UHFFFAOYSA-N 3-(6-phenoxypyridin-2-yl)propanamide Chemical compound C1=CC=C(C=C1)OC2=CC=CC(=N2)CCC(=O)N LMZSMDKFORHLCQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 abstract 1
- 125000000041 C6-C10 aryl group Chemical group 0.000 abstract 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 230000010933 acylation Effects 0.000 abstract 1
- 238000005917 acylation reaction Methods 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 244000038559 crop plants Species 0.000 abstract 1
- 239000003630 growth substance Substances 0.000 abstract 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 210000000056 organ Anatomy 0.000 abstract 1
- 150000003222 pyridines Chemical class 0.000 abstract 1
- 238000009331 sowing Methods 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
- C07D213/643—2-Phenoxypyridines; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/69—Two or more oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Piridinas sustituidas que tienen la fórmula (1) y/o sus sales, en la cual: R1, iguales o diferentes entre sí, son H, halógeno, CN, nitro, SF5, alquilo C1-8, alquenilo C2-8, alquinilo C2-8, alcoxi C1-8, [alquil C1-8]-carbonilo o alquilsulfonilo C1-8, donde cada uno de los seis radicales mencionados en último término no está sustituido o está sustituido; S(O)p-R7, donde p = 0, 1 ó 2 y R7 es alquilo C1-8, haloalquilo C1-8 o NR8R9, donde R8 y R9, independientemente entre sí, representan H, alquilo C1-8, alquenilo C2-8, arilalquilo C7-10, alquilarilo C7-10 o arilo C6-10, donde cada uno de los cinco radicales mencionados en último término no está sustituido o está sustituido, o es un grupo de la fórmula (2) en la cual R10 es alquilo C1-8 no sustituido o sustituido, y W = O ó S; A es arilo opcionalmente sustituido o un radical heterocíclico opcionalmente sustituido; X es O ó S; R2, R3, R4, R5, iguales o diferentes entre sí, son, H, halógeno, CN, alcoxi C1-8 o alquilo C1-8, donde cada uno de ambos radicales mencionados en último término no está sustituido o está sustituido; m es 0 ó 1; R6 es H, alquilo C1-8, alcoxi C1-8, alquenilo C2-8 o alquinilo C2-8, donde cada uno de los cuatro radicales mencionados en último término no están sustituidos o están sustituidos, o es hidroxi o un radical acilo; y B es un radical acilo; o B y R6 forman conjuntamente una cadena de 5 o 6 miembros, con la excepción de la N-hidroxi-N[(6-fenoxi-2-piridil)metil]-acetamida y sus sales; agente herbicida o regulador del crecimiento de las plantas, procedimiento para combatir las plantas perjudiciales o para la regulación del crecimiento de las plantas de cultivo, su utilización como herbicidas y como reguladores del crecimiento de las plantas, y procedimiento para la preparación de dichos compuestos. Estos compuestos son adecuados por ejemplo como herbicidas y reguladores del crecimiento. Además presentan una efectividad herbicida destacada contra un amplio espectro de importantes plantas perjudiciales monocotiledóneas y dicotiledóneas. También son bien controladas las malezas perennes difíciles de combatir, que se propagan por rizomas, racimos de raíces, u otros órganos duraderos. Al respecto estos compuestos pueden ser aplicados en el procedimiento antes del sembrado, antes del brote desde la tierra o después de dicho brote. Un procedimiento para la preparación de un compuesto de fórmula (1) y/o de sus sales, de acuerdo con una o más de las reivindicaciones 1 a 6; caracterizado porque: a) un compuesto de la fórmula (3), en la cual los radicales R1 son como se definen en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6 y L es un grupo de partida o un grupo de la fórmula A-X-, donde A y X tal como se definen en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6, se alquila y a continuación se hace reaccionar con cianuro, obteniéndose un nitrilo de la fórmula general (4), en la cual R1 y L son como se define para la fórmula (1); b) el compuesto de la fórmula (4), en la cual L representa un grupo de partida, se hace reaccionar con un compuesto A-X-H y/o sus sales, en la cual A y X son como se define para la fórmula (1) de acuerdo con uno o más de las reivindicaciones 1 a 6, obteniéndose un compuesto de la fórmula (4), en la cual L representa un grupo de la fórmula A-X-; c) el compuesto obtenido de la fórmula general (4); obtenido en el paso a) o b), en el cual L representa un grupo A-X- y en la cual A, X y R1 son tal como se define en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6, se convierte por reducción en el compuesto amino de la fórmula general (5) en la cual R1, R2, R3, A y X son como se define en la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6; y a continuación: d1) el compuesto de la fórmula (5) se convierte por reacción con reactivos de acilación, obteniéndose un compuesto de la fórmula (1), en la cual R6 = H, m = 0 y A, X, R1, R2, R3 y B son como se definen para la fórmula (1) de acuerdo con una o más de las reivindicaciones 1 a 6; y opcionalmente los compuestos de la fórmula (1) en la cual R6 = H, se acilan a continuación; o d2) el compuesto de la fórmula (5) se alquila de manera reductiva con aldehidos, y a continuación se acila.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10130397A DE10130397A1 (de) | 2001-06-23 | 2001-06-23 | Herbizide substituierte Pyridine, Verfahren zu ihrer Herstellung und ihre Verwendung als Herbzide und Pflanzenwachstumsregulatoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR036105A1 true AR036105A1 (es) | 2004-08-11 |
Family
ID=7689249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP020102347A AR036105A1 (es) | 2001-06-23 | 2002-06-21 | Piridinas sustituidas herbicidas, agente herbicida, procedimiento para combatir las plantas perjudiciales o para la regulacion del crecimiento de las de cultivo, su utilizacion como tal y procedimiento para la preparacion de dichos compuestos |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6794336B2 (es) |
| EP (1) | EP1401827A2 (es) |
| JP (1) | JP2004536094A (es) |
| KR (1) | KR20040010775A (es) |
| CN (1) | CN1520407A (es) |
| AR (1) | AR036105A1 (es) |
| AU (1) | AU2002319249B2 (es) |
| BR (1) | BR0210638A (es) |
| CA (1) | CA2451354A1 (es) |
| CZ (1) | CZ20033547A3 (es) |
| DE (1) | DE10130397A1 (es) |
| IL (1) | IL159503A0 (es) |
| MX (1) | MXPA03011782A (es) |
| PL (1) | PL367131A1 (es) |
| RU (1) | RU2304141C2 (es) |
| SK (1) | SK15692003A3 (es) |
| TW (1) | TWI259057B (es) |
| UA (1) | UA76476C2 (es) |
| WO (1) | WO2003000679A2 (es) |
| ZA (1) | ZA200309245B (es) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1594848A1 (en) | 2003-02-19 | 2005-11-16 | Neurogen Corporation | Aryl acid pyrimidinyl methyl amides, pyridazinyl methyl amides and related compounds |
| WO2005007627A1 (ja) * | 2003-07-18 | 2005-01-27 | Nihon Nohyaku Co., Ltd. | フェニルピリジン誘導体、その中間体及びこれを有効成分とする除草剤 |
| JP4993407B2 (ja) | 2004-08-04 | 2012-08-08 | 大正製薬株式会社 | トリアゾール誘導体 |
| EP1988083B1 (en) | 2006-02-03 | 2014-04-02 | Taisho Pharmaceutical Co., Ltd. | Triazole derivative |
| RU2395499C2 (ru) * | 2006-02-06 | 2010-07-27 | Тайсо Фармасьютикал Ко., Лтд. | Ингибитор связывания сфингозин-1-фосфата |
| BRPI0710487A2 (pt) * | 2006-04-12 | 2012-06-05 | Merck & Co Inc | composto ou um sal farmaceuticamente aceitável do mesmo, composição farmacêutica, uso de um composto ou um sal farmaceuticamente aceitácel do mesmo e, método para tratar ou controlar a epilepsia e a dor e para o tratamento ou prevenção de um distúrbio do sono em um paciente. |
| SI2177512T1 (sl) | 2007-08-01 | 2012-06-29 | Taisho Pharmaceutical Co Ltd | Inhibitor vezave S1P1 |
| US8097712B2 (en) | 2007-11-07 | 2012-01-17 | Beelogics Inc. | Compositions for conferring tolerance to viral disease in social insects, and the use thereof |
| US8962584B2 (en) | 2009-10-14 | 2015-02-24 | Yissum Research Development Company Of The Hebrew University Of Jerusalem, Ltd. | Compositions for controlling Varroa mites in bees |
| DK3231872T3 (da) | 2010-03-08 | 2020-07-20 | Monsanto Technology Llc | Polynukleotidmolekyler til genregulering i planter |
| WO2013040049A1 (en) | 2011-09-13 | 2013-03-21 | Monsanto Technology Llc | Methods and compositions for weed control |
| US10760086B2 (en) | 2011-09-13 | 2020-09-01 | Monsanto Technology Llc | Methods and compositions for weed control |
| AU2012308753B2 (en) | 2011-09-13 | 2018-05-17 | Monsanto Technology Llc | Methods and compositions for weed control |
| US10806146B2 (en) | 2011-09-13 | 2020-10-20 | Monsanto Technology Llc | Methods and compositions for weed control |
| CN103958539B (zh) | 2011-09-13 | 2019-12-17 | 孟山都技术公司 | 用于杂草控制的方法和组合物 |
| US10829828B2 (en) | 2011-09-13 | 2020-11-10 | Monsanto Technology Llc | Methods and compositions for weed control |
| MX350771B (es) | 2011-09-13 | 2017-09-15 | Monsanto Technology Llc | Métodos y composiciones para el control de malezas. |
| CA2848695A1 (en) | 2011-09-13 | 2013-03-21 | Monsanto Technology Llc | Methods and composition for weed control comprising inhibiting ppg oxidase |
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| CA2876181C (en) * | 2012-06-30 | 2021-01-05 | Dow Agrosciences Llc | Pyridine n-oxides and processes for their preparation |
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| MX2015012334A (es) | 2013-03-13 | 2016-02-05 | Monsanto Technology Llc | Metodos y composiciones para el control de malezas. |
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| EP0723960B1 (en) * | 1995-01-26 | 2003-04-02 | Basf Aktiengesellschaft | Herbicidal 2,6-disubstituted pyridines and 2,4-disubstituted pyrimidines |
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| US5869426A (en) * | 1997-11-07 | 1999-02-09 | American Cyanamid Company | Herbicidal 6-thienyloxypyrid-2-carboxamides |
| ATE365734T1 (de) * | 1997-11-07 | 2007-07-15 | Basf Ag | Herbizide furanyl- und thienyloxyazine |
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| AU2000254293A1 (en) * | 1999-06-29 | 2001-01-31 | Kureha Kagaku Kogyo Kabushiki Kaisha | 2-(optionally substituted benzoylamino)-6-(optionally substituted phenoxy)pyridine derivatives, process for the preparation thereof and herbicides |
-
2001
- 2001-06-23 DE DE10130397A patent/DE10130397A1/de not_active Ceased
-
2002
- 2002-06-20 MX MXPA03011782A patent/MXPA03011782A/es active IP Right Grant
- 2002-06-20 RU RU2004101956/04A patent/RU2304141C2/ru not_active IP Right Cessation
- 2002-06-20 WO PCT/EP2002/006840 patent/WO2003000679A2/de not_active Ceased
- 2002-06-20 SK SK1569-2003A patent/SK15692003A3/sk not_active Application Discontinuation
- 2002-06-20 CA CA002451354A patent/CA2451354A1/en not_active Abandoned
- 2002-06-20 AU AU2002319249A patent/AU2002319249B2/en not_active Ceased
- 2002-06-20 JP JP2003507083A patent/JP2004536094A/ja not_active Abandoned
- 2002-06-20 CN CNA028126262A patent/CN1520407A/zh active Pending
- 2002-06-20 UA UA2004010503A patent/UA76476C2/uk unknown
- 2002-06-20 PL PL02367131A patent/PL367131A1/xx not_active Application Discontinuation
- 2002-06-20 EP EP02748802A patent/EP1401827A2/de not_active Withdrawn
- 2002-06-20 BR BR0210638-8A patent/BR0210638A/pt not_active IP Right Cessation
- 2002-06-20 KR KR10-2003-7016780A patent/KR20040010775A/ko not_active Ceased
- 2002-06-20 IL IL15950302A patent/IL159503A0/xx unknown
- 2002-06-20 CZ CZ20033547A patent/CZ20033547A3/cs unknown
- 2002-06-21 TW TW091113809A patent/TWI259057B/zh not_active IP Right Cessation
- 2002-06-21 AR ARP020102347A patent/AR036105A1/es not_active Application Discontinuation
- 2002-06-21 US US10/177,526 patent/US6794336B2/en not_active Expired - Fee Related
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2003
- 2003-11-27 ZA ZA200309245A patent/ZA200309245B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2304141C2 (ru) | 2007-08-10 |
| BR0210638A (pt) | 2004-07-20 |
| ZA200309245B (en) | 2004-06-09 |
| TWI259057B (en) | 2006-08-01 |
| KR20040010775A (ko) | 2004-01-31 |
| WO2003000679A3 (de) | 2003-04-24 |
| AU2002319249B2 (en) | 2008-01-31 |
| CN1520407A (zh) | 2004-08-11 |
| WO2003000679A2 (de) | 2003-01-03 |
| PL367131A1 (en) | 2005-02-21 |
| EP1401827A2 (de) | 2004-03-31 |
| CA2451354A1 (en) | 2003-01-03 |
| JP2004536094A (ja) | 2004-12-02 |
| US6794336B2 (en) | 2004-09-21 |
| IL159503A0 (en) | 2004-06-01 |
| UA76476C2 (en) | 2006-08-15 |
| DE10130397A1 (de) | 2003-01-09 |
| MXPA03011782A (es) | 2004-04-02 |
| US20030229125A1 (en) | 2003-12-11 |
| RU2004101956A (ru) | 2005-06-27 |
| CZ20033547A3 (cs) | 2004-05-12 |
| SK15692003A3 (sk) | 2004-07-07 |
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