AR006753A1 - Procedimiento para la polimerizacion en suspension acuosa del cloruro de vinilo con intervencion de peroxidicarbonatos de dialquilo en solucion - Google Patents
Procedimiento para la polimerizacion en suspension acuosa del cloruro de vinilo con intervencion de peroxidicarbonatos de dialquilo en solucionInfo
- Publication number
- AR006753A1 AR006753A1 ARP970100200A ARP970100200A AR006753A1 AR 006753 A1 AR006753 A1 AR 006753A1 AR P970100200 A ARP970100200 A AR P970100200A AR P970100200 A ARP970100200 A AR P970100200A AR 006753 A1 AR006753 A1 AR 006753A1
- Authority
- AR
- Argentina
- Prior art keywords
- vinyl chloride
- solution
- aqueous suspension
- polymerization
- dialkyl
- Prior art date
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- 239000007900 aqueous suspension Substances 0.000 title abstract 4
- 238000010557 suspension polymerization reaction Methods 0.000 title abstract 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000005634 peroxydicarbonate group Chemical group 0.000 abstract 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 abstract 1
- 241000251468 Actinopterygii Species 0.000 abstract 1
- 235000011037 adipic acid Nutrition 0.000 abstract 1
- 239000001361 adipic acid Substances 0.000 abstract 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 229910017053 inorganic salt Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000003799 water insoluble solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/32—Peroxy compounds the —O—O— group being bound between two >C=O groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Procedimiento para la polimerización en suspensión acuosa del cloruro de vinilo con intervención de peroxidicarbonatos de dialquilo en solución. Serefiere a un procedimiento de polimerización en suspensión acuosa de cloruro de vinilo empleandoperoxidicarbonatos de dialquilo de cadenas alquílicas cortas,preferentemente de dietilo y de diisopropilo, en forma de una solución en un alcanodicarboxilato de dialquilo líquido e insoluble en agua. Losdisolventes preferidos son loshexanodica rboxilatos (adipatos) derivados del ácido adípico y alcanoles de C9 a C10. La concentración en perosixidicarbonatode dichas soluciones se eleva generalmente a 15-40% en peso. El procedimiento produce polímeros decloruro de vinilo de calidad mejorada queconducen a artículos conformados que presentan netamente menos ojos de pez. Se refiere igualmente a un procedimiento de polimerización donde se fabrica endos etapas una solución de peroxidicarbonatos dedialquilo de cadenas alquílicas cortas, particularmente adaptada a la polimerización en suspensiónacuosa del cloruro de vinilo. Según este procedimiento, se emplea una sal inorgánica en la etapa de fabricación del peroxidicarbonato (primeraetapa)y se separ a éste a continuación por extracción por medio de un disolvente insoluble en agua (segunda etapa).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE9600070A BE1009969A3 (fr) | 1996-01-25 | 1996-01-25 | Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR006753A1 true AR006753A1 (es) | 1999-09-29 |
Family
ID=3889493
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970100200A AR006753A1 (es) | 1996-01-25 | 1997-01-17 | Procedimiento para la polimerizacion en suspension acuosa del cloruro de vinilo con intervencion de peroxidicarbonatos de dialquilo en solucion |
| ARP980105695A AR017595A2 (es) | 1996-01-25 | 1998-11-11 | PROCEDIMIENTO PARA LA FABRICACIoN DE UNA SOLUCIoN DE PEROXIDICARBONATO DE DIALQUILO. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP980105695A AR017595A2 (es) | 1996-01-25 | 1998-11-11 | PROCEDIMIENTO PARA LA FABRICACIoN DE UNA SOLUCIoN DE PEROXIDICARBONATO DE DIALQUILO. |
Country Status (32)
| Country | Link |
|---|---|
| US (3) | US6258906B1 (es) |
| EP (1) | EP0876410B2 (es) |
| JP (3) | JP4889837B2 (es) |
| KR (2) | KR100476175B1 (es) |
| CN (2) | CN1267459C (es) |
| AR (2) | AR006753A1 (es) |
| AT (1) | ATE192460T1 (es) |
| AU (1) | AU723766B2 (es) |
| BE (1) | BE1009969A3 (es) |
| BG (1) | BG63396B1 (es) |
| BR (1) | BR9707080A (es) |
| CA (1) | CA2244154C (es) |
| CZ (1) | CZ292259B6 (es) |
| DE (1) | DE69701855T3 (es) |
| DZ (1) | DZ2170A1 (es) |
| EA (1) | EA000881B1 (es) |
| ES (1) | ES2148924T5 (es) |
| HR (1) | HRP970047B1 (es) |
| HU (1) | HU229149B1 (es) |
| IL (2) | IL125396A (es) |
| MY (1) | MY116847A (es) |
| NO (2) | NO318952B1 (es) |
| PL (1) | PL186797B1 (es) |
| PT (1) | PT876410E (es) |
| RO (1) | RO119887B1 (es) |
| SK (1) | SK284350B6 (es) |
| TR (1) | TR199801423T2 (es) |
| TW (1) | TW326048B (es) |
| UA (1) | UA63900C2 (es) |
| WO (1) | WO1997027229A1 (es) |
| YU (1) | YU49136B (es) |
| ZA (1) | ZA97449B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE1009969A3 (fr) * | 1996-01-25 | 1997-11-04 | Solvay | Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle. |
| BE1011295A3 (fr) * | 1997-07-22 | 1999-07-06 | Solvay | Solution organique de peroxydicarbonate de dialkyle, procede pour l'obtenir, preparation de polymeres halogenes a l'intervention de celle-ci et polymeres halogenes obtenus. |
| US6995221B2 (en) * | 1999-11-04 | 2006-02-07 | Oxy Vinyls, L.P. | Method for producing organic peroxides and their use in the radical polymerization of monomers |
| US6433208B1 (en) * | 1999-11-04 | 2002-08-13 | Oxy Vinyls Lp | Method for producing stable, dilute, aqueous, emulsified peroxydicarbonates by homogenization |
| US6846888B2 (en) * | 2001-02-01 | 2005-01-25 | Atofina Chemicals, Inc. | Stabilized organic peroxydicarbonate compositions |
| PL363747A1 (en) | 2001-03-23 | 2004-11-29 | Akzo Nobel N.V. | Storage stable aqueous organic peroxide emulsions |
| ATE399799T1 (de) * | 2004-05-05 | 2008-07-15 | Vestolit Gmbh & Co Kg | Verfahren zur herstellung von polymeren und copolymeren |
| EP1849804A1 (en) * | 2006-04-27 | 2007-10-31 | Arkema France | Process of free-radical polymerization or crosslinking in the presence of an organic peroxide by an ex situ process |
| EP1852418A1 (en) | 2006-04-27 | 2007-11-07 | Arkema France | Process for synthesizing selected organic peroxides |
| FR2968660B1 (fr) * | 2010-12-14 | 2014-03-07 | Solvay | Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle |
| FR2984331A1 (fr) * | 2011-12-15 | 2013-06-21 | Solvay | Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE118608C (es) | ||||
| US2370588A (en) * | 1942-10-22 | 1945-02-27 | Pittsburgh Plate Glass Co | Organic percarbonates |
| AT243234B (de) † | 1962-10-06 | 1965-10-25 | Hoechst Ag | Verfahren zur Herstellung von Lösungen von Peroxydikohlensäureestern |
| NL302390A (es) * | 1962-12-22 | |||
| DE1259325B (de) * | 1964-05-22 | 1968-01-25 | Hoechst Ag | Verfahren zur kontinuierlichen Herstellung von Loesungen von Peroxydikohlensaeureestern |
| GB1107956A (en) | 1966-02-28 | 1968-03-27 | Noury & Van Der Lande | Improvements in or relating to organic peroxydicarbonates |
| IL29131A (en) * | 1967-12-14 | 1971-01-28 | Kreisel M | Process for the polymerization of vinyl compounds |
| BE791488A (fr) * | 1971-11-18 | 1973-05-16 | Rhone Progil | Procede de preparation en continu de peroxydes |
| US3799916A (en) † | 1972-06-19 | 1974-03-26 | Air Prod & Chem | Vinyl chloride based polymers prepared by in-situ initiators in acid medium |
| JPS4997882A (es) * | 1973-01-08 | 1974-09-17 | ||
| FR2241566B1 (es) | 1973-04-03 | 1978-02-10 | Rhone Progil | |
| US3935243A (en) * | 1973-09-17 | 1976-01-27 | The Dow Chemical Company | Method for preparing polyperoxydicarbonate esters |
| FR2253760B1 (es) | 1973-12-05 | 1976-10-08 | Solvay | |
| US3950375A (en) * | 1973-12-10 | 1976-04-13 | Pennwalt Corporation | Continuous manufacture of peroxydicarbonates |
| DD118608A1 (es) † | 1975-04-14 | 1976-03-12 | ||
| NO761321L (es) * | 1975-07-30 | 1977-02-01 | Continental Oil Co | |
| JPS52142792A (en) * | 1976-05-25 | 1977-11-28 | Kureha Chem Ind Co Ltd | Suspension polymerization of vinyl chloride |
| JPS584933B2 (ja) * | 1978-05-31 | 1983-01-28 | 呉羽化学工業株式会社 | 可塑化塩化ビニリデン↓−塩化ビニル系共重合体の製造法 |
| JPS559067A (en) * | 1978-06-30 | 1980-01-22 | Ppg Industries Inc | Manufacture of peroxydicarbonates |
| SE7907690L (sv) | 1979-10-05 | 1981-03-18 | Ceskoslovenska Akademie Ved | Sett att framstella inre mjukad polyvinylklorid |
| JPS5887101A (ja) † | 1981-11-18 | 1983-05-24 | Kayaku Nuurii Kk | エチレン系不飽和単量体の重合用組成物 |
| JPS58103357A (ja) * | 1981-12-14 | 1983-06-20 | Nippon Oil & Fats Co Ltd | ジイソプロピルペルオキシジカ−ボネ−トの製造方法 |
| CA1207489A (en) * | 1982-03-16 | 1986-07-08 | Kazuhiko Kanki | Resin composition suitable for use in medical devices |
| US4584142A (en) * | 1983-11-03 | 1986-04-22 | Ppg Industries, Inc. | Alkyl percarbonates |
| US4590008A (en) * | 1984-06-07 | 1986-05-20 | Ppg Industries, Inc. | Novel organic peroxydicarbonates |
| JP3003247B2 (ja) * | 1991-02-28 | 2000-01-24 | 日本ゼオン株式会社 | 電子線架橋性プラスチゾル |
| JPH07188489A (ja) * | 1993-11-22 | 1995-07-25 | Sumitomo Chem Co Ltd | 粉末成形用塩化ビニル系樹脂組成物及びその製造方法 |
| US5548046A (en) * | 1994-02-16 | 1996-08-20 | Elf Atochem North America, Inc. | Stabilized dialkyl peroxydicarbonate compositions and their uses |
| JPH0812708A (ja) * | 1994-06-29 | 1996-01-16 | Sumitomo Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| BE1009969A3 (fr) * | 1996-01-25 | 1997-11-04 | Solvay | Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle. |
| BE1011294A3 (fr) * | 1997-07-22 | 1999-07-06 | Solvay | Solution organique de peroxydicarbonate de dialkyle, procede pour l'obtenir, preparation de polymeres halogenes a l'intervention de celle-ci et polymeres halogenes obtenus. |
-
1996
- 1996-01-25 BE BE9600070A patent/BE1009969A3/fr not_active IP Right Cessation
-
1997
- 1997-01-10 RO RO98-01217A patent/RO119887B1/ro unknown
- 1997-01-10 KR KR10-1998-0705740A patent/KR100476175B1/ko not_active Expired - Fee Related
- 1997-01-10 CZ CZ19982370A patent/CZ292259B6/cs not_active IP Right Cessation
- 1997-01-10 EP EP97901036A patent/EP0876410B2/fr not_active Expired - Lifetime
- 1997-01-10 KR KR10-2004-7010890A patent/KR20040091624A/ko not_active Withdrawn
- 1997-01-10 BR BR9707080A patent/BR9707080A/pt not_active IP Right Cessation
- 1997-01-10 US US09/117,098 patent/US6258906B1/en not_active Expired - Lifetime
- 1997-01-10 CN CNB021498466A patent/CN1267459C/zh not_active Expired - Fee Related
- 1997-01-10 CN CN97193272A patent/CN1132859C/zh not_active Expired - Fee Related
- 1997-01-10 ES ES97901036T patent/ES2148924T5/es not_active Expired - Lifetime
- 1997-01-10 IL IL12539697A patent/IL125396A/xx not_active IP Right Cessation
- 1997-01-10 WO PCT/EP1997/000164 patent/WO1997027229A1/fr not_active Ceased
- 1997-01-10 JP JP52648697A patent/JP4889837B2/ja not_active Expired - Fee Related
- 1997-01-10 AU AU14424/97A patent/AU723766B2/en not_active Ceased
- 1997-01-10 TR TR1998/01423T patent/TR199801423T2/xx unknown
- 1997-01-10 HU HU9900981A patent/HU229149B1/hu unknown
- 1997-01-10 SK SK988-98A patent/SK284350B6/sk not_active IP Right Cessation
- 1997-01-10 PT PT97901036T patent/PT876410E/pt unknown
- 1997-01-10 CA CA002244154A patent/CA2244154C/fr not_active Expired - Fee Related
- 1997-01-10 DE DE69701855T patent/DE69701855T3/de not_active Expired - Lifetime
- 1997-01-10 PL PL97328268A patent/PL186797B1/pl unknown
- 1997-01-10 EA EA199800653A patent/EA000881B1/ru not_active IP Right Cessation
- 1997-01-10 AT AT97901036T patent/ATE192460T1/de not_active IP Right Cessation
- 1997-01-10 IL IL13705597A patent/IL137055A/en not_active IP Right Cessation
- 1997-01-17 AR ARP970100200A patent/AR006753A1/es unknown
- 1997-01-20 ZA ZA97449A patent/ZA97449B/xx unknown
- 1997-01-22 DZ DZ970015A patent/DZ2170A1/fr active
- 1997-01-24 MY MYPI97000286A patent/MY116847A/en unknown
- 1997-01-24 YU YU2297A patent/YU49136B/sh unknown
- 1997-01-24 HR HR970047A patent/HRP970047B1/xx not_active IP Right Cessation
- 1997-02-27 TW TW086102412A patent/TW326048B/zh not_active IP Right Cessation
- 1997-10-01 UA UA98084552A patent/UA63900C2/uk unknown
-
1998
- 1998-07-24 BG BG102649A patent/BG63396B1/bg unknown
- 1998-07-24 NO NO19983430A patent/NO318952B1/no not_active IP Right Cessation
- 1998-11-11 AR ARP980105695A patent/AR017595A2/es active IP Right Grant
-
2001
- 2001-05-25 US US09/866,026 patent/US6617408B2/en not_active Expired - Fee Related
-
2003
- 2003-09-08 US US10/658,314 patent/US6878840B2/en not_active Expired - Fee Related
- 2003-11-12 NO NO20035017A patent/NO328156B1/no not_active IP Right Cessation
-
2007
- 2007-05-21 JP JP2007134357A patent/JP4291378B2/ja not_active Expired - Fee Related
-
2009
- 2009-08-07 JP JP2009184559A patent/JP2009287029A/ja active Pending
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