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MXPA04003658A - Procedimiento y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico. - Google Patents

Procedimiento y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico.

Info

Publication number
MXPA04003658A
MXPA04003658A MXPA04003658A MXPA04003658A MXPA04003658A MX PA04003658 A MXPA04003658 A MX PA04003658A MX PA04003658 A MXPA04003658 A MX PA04003658A MX PA04003658 A MXPA04003658 A MX PA04003658A MX PA04003658 A MXPA04003658 A MX PA04003658A
Authority
MX
Mexico
Prior art keywords
catalyst
carboxylic acid
acid salts
supporting structure
primary alcohols
Prior art date
Application number
MXPA04003658A
Other languages
English (en)
Inventor
James M Allman
Original Assignee
Monsanto Technology Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology Llc filed Critical Monsanto Technology Llc
Publication of MXPA04003658A publication Critical patent/MXPA04003658A/es
Publication of MX244781B publication Critical patent/MX244781B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B01J25/02—Raney nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Esta invencion esta dirigida a un procedimiento para elaborar una sal de un acido carboxilico; el procedimiento comprende poner en contacto un catalizador con una mezcla alcalina que comprende un alcohol primario; en una modalidad, el catalizador comprende una estructura de soporte de metal (preferiblemente una estructura de soporte de metal esponjoso que comprende al menos aproximadamente 10% en peso de niquel) que posee una fase activa que contiene cobre en la superficie de la misma y hierro como modificador del catalizador; la estructura de soporte es resistente a la deformacion bajo las condiciones de la reaccion de deshidrogenacion; esta invencion tambien esta dirigida a catalizadores que contienen niquel novedosos que poseen una fase activa que contiene cobre y hierro como modificador del catalizador que se puede utilizar, por ejemplo, en el procedimiento anterior; esta invencion se refiere ademas a procedimientos para elaborar dichos catalizadores.
MXPA04003658 2001-10-18 2002-10-16 Procedimiento y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico. MX244781B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33022601P 2001-10-18 2001-10-18
PCT/US2002/032953 WO2003033140A2 (en) 2001-10-18 2002-10-16 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts

Publications (2)

Publication Number Publication Date
MXPA04003658A true MXPA04003658A (es) 2004-07-22
MX244781B MX244781B (es) 2007-04-03

Family

ID=23288828

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA04003658 MX244781B (es) 2001-10-18 2002-10-16 Procedimiento y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico.

Country Status (10)

Country Link
US (1) US7126024B2 (es)
EP (1) EP1436080A2 (es)
CN (1) CN1729052A (es)
AR (1) AR037115A1 (es)
AU (1) AU2002362929B2 (es)
BR (1) BR0213428A (es)
CA (1) CA2463776A1 (es)
IN (1) IN2004CH00786A (es)
MX (1) MX244781B (es)
WO (1) WO2003033140A2 (es)

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Also Published As

Publication number Publication date
AR037115A1 (es) 2004-10-20
WO2003033140A2 (en) 2003-04-24
US20050043566A1 (en) 2005-02-24
CA2463776A1 (en) 2003-04-24
BR0213428A (pt) 2005-12-20
AU2002362929B2 (en) 2007-08-09
EP1436080A2 (en) 2004-07-14
US7126024B2 (en) 2006-10-24
IN2004CH00786A (es) 2006-01-13
CN1729052A (zh) 2006-02-01
MX244781B (es) 2007-04-03
AU2002362929A1 (en) 2003-04-28
WO2003033140A3 (en) 2003-07-17

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