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MXPA03010095A - Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico. - Google Patents

Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico.

Info

Publication number
MXPA03010095A
MXPA03010095A MXPA03010095A MXPA03010095A MXPA03010095A MX PA03010095 A MXPA03010095 A MX PA03010095A MX PA03010095 A MXPA03010095 A MX PA03010095A MX PA03010095 A MXPA03010095 A MX PA03010095A MX PA03010095 A MXPA03010095 A MX PA03010095A
Authority
MX
Mexico
Prior art keywords
random
terpolymers
block
olefin
styrene
Prior art date
Application number
MXPA03010095A
Other languages
English (en)
Inventor
David R. Wilson
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of MXPA03010095A publication Critical patent/MXPA03010095A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico, en una reaccion de un monomero de dieno conjugado con un copolimero o terpolimero aleatorios o de bloques, aromaticos, producidos usando metomeros con una alfa-olefina aromatica, o terpolimeros de un monomero de dieno conjugado con una alfa-olefina aromatica y una alfa-olefina alifatica, usando complejos metalicos que comprenden metales del grupo 3 al grupo 10 del Sistema Periodico de los Elementos, en combinacion con activadores y , opcionalmente, un material soportador. Mas en particular, los complejos metalicos usados para l a sintesis de los copolimeros o terpolimeros son metales lantanidos. De manera todavia mas particular, e l monomero o los monomeros de dieno y e l monomero o los monomeros de alfa- olefina aromatica, tales como, pero sin limitacion a ellos, butadieno y estireno o isopreno y estireno, son copolimerizados, lo que da copolimeros aleatorios o de bloques, o se terpolimeriza butadieno, estireno e isopreno, para dar terpolimeros aleatorios o de bloques, usando complejos metalicos que comprenden metales lantanidos en combinacion con activadores y, opcionalmente, con un material soportador. Se forma, de preferencia, copolimeros o terpolimeros aleatorios.
MXPA03010095A 2001-05-04 2002-04-30 Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico. MXPA03010095A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28885901P 2001-05-04 2001-05-04
PCT/US2002/013830 WO2002090394A1 (en) 2001-05-04 2002-04-30 Random or block co-or terpolymers produced by using of metal complex catalysts

Publications (1)

Publication Number Publication Date
MXPA03010095A true MXPA03010095A (es) 2004-03-16

Family

ID=23108976

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA03010095A MXPA03010095A (es) 2001-05-04 2002-04-30 Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico.

Country Status (9)

Country Link
US (1) US20040241251A1 (es)
EP (1) EP1401879A1 (es)
JP (1) JP2004532320A (es)
KR (1) KR20030097850A (es)
CN (1) CN1518561A (es)
BR (1) BR0209515A (es)
MX (1) MXPA03010095A (es)
WO (1) WO2002090394A1 (es)
ZA (1) ZA200307859B (es)

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JP2005506404A (ja) * 2001-10-12 2005-03-03 ダウ グローバル テクノロジーズ インコーポレイティド 金属錯体組成物、及び金属錯体組成物のポリジエン製造用触媒としての使用法
WO2004074333A2 (en) * 2003-02-18 2004-09-02 Dow Global Technologies Inc. Process for homo- or copolymerizationof conjugated olefines
CA2807874A1 (en) * 2003-02-21 2004-09-10 Styron Europe Gmbh Process for homo- or copolymerization of conjugated olefines
WO2005097845A1 (ja) * 2004-04-05 2005-10-20 Bridgestone Corporation 変性共役ジエン系重合体、重合開始剤及びそれらの製造方法、並びにゴム組成物
MX2007011349A (es) * 2005-03-17 2007-10-03 Dow Global Technologies Inc Modificacion del impacto de termoplasticos con interpolimeros de etileno/a-olefina.
JP5024755B2 (ja) * 2007-03-09 2012-09-12 独立行政法人理化学研究所 イソプレン系化合物の重合用の重合触媒組成物
JP5083870B2 (ja) * 2007-05-08 2012-11-28 株式会社ブリヂストン 共重合体の製造方法
EP2220128B2 (en) * 2007-11-09 2021-03-10 University of Maryland, College Park Process for preparation of polyolefins via living coordinative chain transfer polymerization
JP5248426B2 (ja) * 2009-07-01 2013-07-31 出光興産株式会社 重合触媒および芳香族ビニル化合物重合体の製造方法
US9803032B2 (en) * 2011-05-09 2017-10-31 Bridgeston Corporation Processes for the preparation of high-cis polydienes
CN104245749B (zh) * 2012-04-18 2017-03-01 株式会社普利司通 聚合催化剂组合物的制造方法、聚合催化剂组合物、聚合物组合物的制造方法和聚合物组合物
CN104693356A (zh) * 2015-01-29 2015-06-10 柳州市颖航汽配有限公司 一种汽车用耐热橡胶胶管
CN104817659B (zh) * 2015-05-04 2017-04-12 宁波工程学院 降冰片烯类、八氟环戊烯和苯乙烯三元共聚催化剂以及三元共聚方法
JP6713759B2 (ja) * 2015-12-03 2020-06-24 株式会社ブリヂストン 多元共重合体の製造方法及び多元共重合体
WO2021034041A1 (ko) * 2019-08-19 2021-02-25 주식회사 엘지화학 유기 보레이트계 촉매, 이를 이용한 이소부텐 올리고머의 제조방법 및 이로부터 제조된 이소부텐 올리고머
CN112279964A (zh) * 2020-10-29 2021-01-29 遂川海州树脂有限公司 一种利用复合催化剂制备改性间戊二烯石油树脂的方法
FR3123917B1 (fr) * 2021-06-10 2024-04-19 Michelin & Cie Système catalytique pour la polymérisation stéréospécifique de diènes et leur utilisation en procédé de synthèse de polymères diéniques

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Also Published As

Publication number Publication date
EP1401879A1 (en) 2004-03-31
US20040241251A1 (en) 2004-12-02
WO2002090394A1 (en) 2002-11-14
CN1518561A (zh) 2004-08-04
ZA200307859B (en) 2004-10-08
BR0209515A (pt) 2004-07-13
JP2004532320A (ja) 2004-10-21
KR20030097850A (ko) 2003-12-31

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