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MX9702678A - Dispersion de copolimero con alto contenido de solidos a partir de un latex y su uso en materiales selladores. - Google Patents

Dispersion de copolimero con alto contenido de solidos a partir de un latex y su uso en materiales selladores.

Info

Publication number
MX9702678A
MX9702678A MX9702678A MX9702678A MX9702678A MX 9702678 A MX9702678 A MX 9702678A MX 9702678 A MX9702678 A MX 9702678A MX 9702678 A MX9702678 A MX 9702678A MX 9702678 A MX9702678 A MX 9702678A
Authority
MX
Mexico
Prior art keywords
high solids
latex
water
particles
percent
Prior art date
Application number
MX9702678A
Other languages
English (en)
Other versions
MXPA97002678A (es
Inventor
James H Dunaway
Pamela K Hernandez
Gregory P Bidinger
Original Assignee
Goodrich Co B F
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodrich Co B F filed Critical Goodrich Co B F
Publication of MXPA97002678A publication Critical patent/MXPA97002678A/es
Publication of MX9702678A publication Critical patent/MX9702678A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C08L31/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18—Spheres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Sealing Material Composition (AREA)
  • Polymerisation Methods In General (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Paper (AREA)
  • Cosmetics (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Paints Or Removers (AREA)
  • Medicinal Preparation (AREA)

Abstract

Un método para polimerizar predominantemente uno o más monomeros de acrilato y/o acetato de vinilo en presencia de un látex resulta en dispersiones con alto contenido de solidos de partículas de polímero con viscosidades menores que las observadas tradicionalmente. Un % significativo de monomeros agregados puede estar presente en partículas grandes, que no tienen formas esféricas. Algunas de las partículas de látex originales son retenidas durante la polimerizacion y este aumento del contenido de solidos y disminucion de la viscosidad por el empaquetado en los intersticios entre las partículas grandes. El contenido de solidos de polímero total puede variarse fácilmente de 70 a 92 o más % por peso, los cuales son mayores que los logrados en cualquiera de las polimerizaciones acuosa reportadas previamente. Las viscosidades a contenidos de solidos muy elevados llegan a ser similares a una pasta, pero los materiales aun son estables durante el almacenamiento y además manejarse sin romper la dispersion en una porcion de polímero aglomerada y el agua liberada. Las dispersiones son utiles para formar materiales selladores, membranas, etc., ya sea con o sin otros aditivos. Un uso preferido es como un compuesto para calafateo a base de agua y acrilato, donde el alto contenido de solidos y la tixotropía de la dispersion permite la formacion de un calafateo a base de agua con poca contraccion.
MX9702678A 1994-10-11 1995-10-04 Dispersion de copolimero con alto contenido de solidos a partir de un latex y su uso en materiales selladores. MX9702678A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08321288 1994-10-11
US08/321,288 US5541253A (en) 1994-10-11 1994-10-11 High solids copolymer dispersion from a latex and its use in sealants
PCT/US1995/012762 WO1996011234A1 (en) 1994-10-11 1995-10-04 High solids copolymer dispersion from a latex and its use in sealants

Publications (2)

Publication Number Publication Date
MXPA97002678A MXPA97002678A (es) 1998-02-01
MX9702678A true MX9702678A (es) 1998-02-28

Family

ID=23249977

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9702678A MX9702678A (es) 1994-10-11 1995-10-04 Dispersion de copolimero con alto contenido de solidos a partir de un latex y su uso en materiales selladores.

Country Status (30)

Country Link
US (2) US5541253A (es)
EP (1) EP0785970B1 (es)
JP (1) JPH10507221A (es)
KR (1) KR970707234A (es)
CN (1) CN1085701C (es)
AT (1) ATE179444T1 (es)
AU (1) AU703054B2 (es)
BR (1) BR9509330A (es)
CA (1) CA2202378C (es)
CZ (1) CZ112497A3 (es)
DE (1) DE69509404T2 (es)
DK (1) DK0785970T3 (es)
EE (1) EE03572B1 (es)
ES (1) ES2133828T3 (es)
GR (1) GR3030075T3 (es)
HU (1) HU219677B (es)
IL (1) IL115535A (es)
LT (1) LT4278B (es)
LV (1) LV11903B (es)
MA (1) MA23688A1 (es)
MX (1) MX9702678A (es)
MY (1) MY112737A (es)
NO (1) NO311365B1 (es)
NZ (1) NZ295529A (es)
PL (1) PL181430B1 (es)
RO (1) RO116479B1 (es)
RU (1) RU2177013C2 (es)
SK (1) SK282482B6 (es)
TW (1) TW406092B (es)
WO (1) WO1996011234A1 (es)

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Also Published As

Publication number Publication date
CZ112497A3 (en) 1997-10-15
GR3030075T3 (en) 1999-07-30
TW406092B (en) 2000-09-21
EP0785970A1 (en) 1997-07-30
EP0785970B1 (en) 1999-04-28
RO116479B1 (ro) 2001-02-28
SK46597A3 (en) 1997-10-08
AU3889195A (en) 1996-05-02
IL115535A (en) 1999-10-28
PL319632A1 (en) 1997-08-18
CN1163631A (zh) 1997-10-29
DE69509404D1 (de) 1999-06-02
WO1996011234A1 (en) 1996-04-18
CA2202378A1 (en) 1996-04-18
EE03572B1 (et) 2001-12-17
EE9700108A (et) 1997-12-15
DK0785970T3 (da) 1999-10-25
KR970707234A (ko) 1997-12-01
US5744544A (en) 1998-04-28
SK282482B6 (sk) 2002-02-05
LV11903A (lv) 1997-12-20
DE69509404T2 (de) 1999-12-16
ATE179444T1 (de) 1999-05-15
JPH10507221A (ja) 1998-07-14
NO311365B1 (no) 2001-11-19
US5541253A (en) 1996-07-30
LV11903B (en) 1998-05-20
HUT77718A (hu) 1998-07-28
NZ295529A (en) 1999-04-29
ES2133828T3 (es) 1999-09-16
HU219677B (hu) 2001-06-28
LT4278B (lt) 1998-01-26
NO971666L (no) 1997-05-29
AU703054B2 (en) 1999-03-11
BR9509330A (pt) 1997-10-14
MA23688A1 (fr) 1996-07-01
RU2177013C2 (ru) 2001-12-20
NO971666D0 (no) 1997-04-11
MY112737A (en) 2001-08-30
CN1085701C (zh) 2002-05-29
CA2202378C (en) 2003-05-06
IL115535A0 (en) 1996-01-19
LT97084A (en) 1997-10-27
PL181430B1 (pl) 2001-07-31

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