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MX2019008901A - Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion. - Google Patents

Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion.

Info

Publication number
MX2019008901A
MX2019008901A MX2019008901A MX2019008901A MX2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A
Authority
MX
Mexico
Prior art keywords
free
stage
highly reactive
sulfide
lithium hydroxide
Prior art date
Application number
MX2019008901A
Other languages
English (en)
Inventor
Vitze Hannes
Nickel Vera
Lang Sebastian
Plath Armine
Müller Marc-Christian
Pietzner Sebastian
Original Assignee
Albemarle Germany Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Germany Gmbh filed Critical Albemarle Germany Gmbh
Publication of MX2019008901A publication Critical patent/MX2019008901A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/38—Dehydration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/26—Selection of materials as electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/20—Powder free flowing behaviour
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

La invención se refiere a un polvo de sulfuro de litio altamente reactivo, de alta pureza, de flujo libre y libre de tierra que tiene un tamaño de partícula promedio entre 250 y 1500 µm y áreas de superficie BET entre 1 y 100 m2/g. La invención, además, se refiere a un proceso para su preparación, donde, en una primera etapa, monohidrato de hidróxido de litio se calienta en una unidad de temperatura controlada a una reacción de temperatura entre 150°C y 450°C en ausencia de aire y se hace pasar un gas inerte sobre o a través de este, hasta que el agua residual de contenido de cristalización del hidróxido de litio formado es menor que 5 % en peso y, en una segunda etapa, el hidróxido de litio anhidro formado en la primera etapa se mezcla, se desborda o atraviesa mediante una fuente de azufre gaseoso del grupo que consiste en sulfuro de hidróxido, sulfuro elemental, disulfuro de carbono, mercaptanos o nitruros de azufre.
MX2019008901A 2017-02-03 2018-02-02 Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion. MX2019008901A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102017201772 2017-02-03
PCT/EP2018/052688 WO2018141919A1 (de) 2017-02-03 2018-02-02 Hochreaktives, staubfreies und freifliessendes lithiumsulfid und verfahren zu dessen herstellung

Publications (1)

Publication Number Publication Date
MX2019008901A true MX2019008901A (es) 2020-01-30

Family

ID=61189440

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019008901A MX2019008901A (es) 2017-02-03 2018-02-02 Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion.

Country Status (12)

Country Link
US (1) US11542162B2 (es)
EP (1) EP3577067B1 (es)
KR (1) KR102485791B1 (es)
CN (1) CN110475745B (es)
AR (1) AR110926A1 (es)
AU (1) AU2018214232B2 (es)
CA (1) CA3050338A1 (es)
IL (1) IL268424B (es)
MX (1) MX2019008901A (es)
TW (1) TWI748052B (es)
WO (1) WO2018141919A1 (es)
ZA (1) ZA201905012B (es)

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US12051824B2 (en) 2020-07-10 2024-07-30 Polyplus Battery Company Methods of making glass constructs
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US12454478B2 (en) 2022-09-09 2025-10-28 Polyplus Battery Company Ionically conductive glass preform
US12294050B2 (en) 2014-12-02 2025-05-06 Polyplus Battery Company Lithium ion conducting sulfide glass fabrication
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US20190173128A1 (en) 2014-12-02 2019-06-06 Polyplus Battery Company Making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies and battery cells
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US10868293B2 (en) 2017-07-07 2020-12-15 Polyplus Battery Company Treating sulfide glass surfaces and making solid state laminate electrode assemblies
US10629950B2 (en) 2017-07-07 2020-04-21 Polyplus Battery Company Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies
US11631889B2 (en) 2020-01-15 2023-04-18 Polyplus Battery Company Methods and materials for protection of sulfide glass solid electrolytes
US12482827B2 (en) 2021-04-13 2025-11-25 Polyplus Battery Company Binary phosphorus nitride protective solid electrolyte intermediary structures for electrode assemblies
US10707536B2 (en) 2016-05-10 2020-07-07 Polyplus Battery Company Solid-state laminate electrode assemblies and methods of making
CN112125283A (zh) * 2020-08-03 2020-12-25 浙江工业大学 一种利用固液混合加热制备硫化锂的方法
US12021187B2 (en) 2020-08-04 2024-06-25 Polyplus Battery Company Surface treatment of a sulfide glass solid electrolyte layer
US12021238B2 (en) 2020-08-04 2024-06-25 Polyplus Battery Company Glassy embedded solid-state electrode assemblies, solid-state batteries and methods of making electrode assemblies and solid-state batteries
US12034116B2 (en) 2020-08-04 2024-07-09 Polyplus Battery Company Glass solid electrolyte layer, methods of making glass solid electrolyte layer and electrodes and battery cells thereof
CN112002939B (zh) * 2020-08-31 2021-10-15 成都新柯力化工科技有限公司 一种锂电池固体电解质的清洁制备方法
EP3964480A1 (en) * 2020-09-02 2022-03-09 AMG Lithium GmbH Process for preparing lithium salts
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JP7484737B2 (ja) * 2021-01-19 2024-05-16 トヨタ自動車株式会社 硫化物固体電解質、前駆体、全固体電池および硫化物固体電解質の製造方法
CN112939034B (zh) * 2021-03-19 2023-08-15 江西云威新材料有限公司 一种工业级碳酸锂制备电池级无水氢氧化锂的方法
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JP2023014712A (ja) * 2021-07-19 2023-01-31 古河機械金属株式会社 硫化リチウムの製造方法および硫化リチウムの製造装置
WO2023032701A1 (ja) * 2021-09-02 2023-03-09 Ａｇｃ株式会社 硫化リチウムの製造方法
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KR102707192B1 (ko) * 2022-02-28 2024-09-20 주식회사 레이크테크놀로지 황화리튬 제조 장치
CN115535968A (zh) * 2022-10-12 2022-12-30 天津大学 一种硫化锂的制备方法及硫化锂
FR3143861B1 (fr) * 2022-12-20 2025-04-18 Eurecat Sa Procédé de production de sulfure de lithium dans un réacteur à lit circulant
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KR20250156793A (ko) * 2023-03-10 2025-11-03 스페셜티 오퍼레이션스 프랑스 황화물 고체 재료의 입자를 제조하는 방법
CN121127437A (zh) 2023-03-10 2025-12-12 法国特种经营公司 用于制备硫化锂粉末的方法
CN116354315B (zh) * 2023-03-30 2025-08-01 宁波容百新能源科技股份有限公司 一种硫化锂的制备方法及硫化锂
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Also Published As

Publication number Publication date
AU2018214232A1 (en) 2019-08-29
IL268424A (en) 2019-09-26
KR102485791B1 (ko) 2023-01-05
BR112019015828A2 (pt) 2020-03-31
US20200165129A1 (en) 2020-05-28
EP3577067B1 (de) 2025-11-19
KR20190114977A (ko) 2019-10-10
CA3050338A1 (en) 2018-08-09
AR110926A1 (es) 2019-05-15
IL268424B (en) 2021-03-25
TWI748052B (zh) 2021-12-01
WO2018141919A1 (de) 2018-08-09
ZA201905012B (en) 2021-05-26
AU2018214232B2 (en) 2020-06-25
TW201840468A (zh) 2018-11-16
CN110475745B (zh) 2023-03-31
EP3577067A1 (de) 2019-12-11
US11542162B2 (en) 2023-01-03
CN110475745A (zh) 2019-11-19

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