MX2013012762A - Composicion acuosa de revestimiento para piel y metodo para revestir piel. - Google Patents
Composicion acuosa de revestimiento para piel y metodo para revestir piel.Info
- Publication number
- MX2013012762A MX2013012762A MX2013012762A MX2013012762A MX2013012762A MX 2013012762 A MX2013012762 A MX 2013012762A MX 2013012762 A MX2013012762 A MX 2013012762A MX 2013012762 A MX2013012762 A MX 2013012762A MX 2013012762 A MX2013012762 A MX 2013012762A
- Authority
- MX
- Mexico
- Prior art keywords
- leather
- aqueous
- coating
- dispersion
- aqueous polymer
- Prior art date
Links
- 239000010985 leather Substances 0.000 title abstract 5
- 239000011248 coating agent Substances 0.000 title abstract 2
- 239000008199 coating composition Substances 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000004815 dispersion polymer Substances 0.000 abstract 4
- 239000005056 polyisocyanate Substances 0.000 abstract 3
- 229920001228 polyisocyanate Polymers 0.000 abstract 3
- 239000006185 dispersion Substances 0.000 abstract 2
- 229920000058 polyacrylate Polymers 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 229920003009 polyurethane dispersion Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
- D06N3/147—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes characterised by the isocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
- C14C11/006—Surface finishing of leather using macromolecular compounds using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31547—Of polyisocyanurate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Textile Engineering (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Una composición acuosa de revestimiento para piel que tiene estabilidad en almacenamiento mejorada incluye de 1 a 40 por ciento por peso de un poliisocianato emulsionable que comprende el producto de reacción de un isocianurato y un emulsionante, en donde la funcionalidad promedio del isocianato del poliisocianato emulsionable es de 2 a 4.5; y de 60 a 99 por ciento por peso de una dispersión polimérica acuosa que tiene una Tg de -70 a 40°C y seleccionada de una dispersión polimérica (met)acrílica, una dispersión de poliuretano, una dispersión híbrida de polímero (met)acrílico/poliuretano y una combinación que comprende una o más de las dispersiones poliméricas acuosas anteriores; en donde todos los porcentajes por peso son sobre una base seca, y en base a la cantidad total en seco del poliisocianato emulsionable y la dispersión polimérica acuosa. La dispersión polimérica acuosa puede estar libre de grupos hidroxilo. También se describe un método para revestir piel con la composición y un artículo de piel revestido.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261722913P | 2012-11-06 | 2012-11-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013012762A true MX2013012762A (es) | 2014-05-22 |
| MX339786B MX339786B (es) | 2016-06-09 |
Family
ID=49274540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013012762A MX339786B (es) | 2012-11-06 | 2013-10-31 | Composicion acuosa de revestimiento para piel y metodo para revestir piel. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9200404B2 (es) |
| EP (1) | EP2727949B1 (es) |
| JP (1) | JP6247492B2 (es) |
| KR (1) | KR102083865B1 (es) |
| CN (1) | CN103805009B (es) |
| BR (1) | BR102013026837B1 (es) |
| MX (1) | MX339786B (es) |
| TW (1) | TWI498392B (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101619636B1 (ko) * | 2014-11-07 | 2016-05-10 | 현대자동차주식회사 | 내구성이 향상된 스티어링 휠 커버용 인조 피혁 및 그 제조방법 |
| TWI705114B (zh) * | 2015-08-31 | 2020-09-21 | 美商羅門哈斯公司 | 用於皮革面塗層的水性多段共聚物組合物 |
| JP6910354B2 (ja) * | 2015-12-09 | 2021-07-28 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 水分散性ポリイソシアネート |
| US11111394B2 (en) * | 2016-01-27 | 2021-09-07 | Nippon Paint Automotive Coatings Co., Ltd. | Primer coating composition and method for forming coating film |
| BR112018071854A2 (pt) | 2016-05-13 | 2019-02-19 | Dow Global Technologies Llc | composição de revestimento aquoso e método de preparação de uma composição de revestimento aquoso |
| CN105837736B (zh) * | 2016-06-19 | 2017-07-18 | 徐州鸿丰高分子材料有限公司 | 一种耐寒皮革涂饰剂的制备方法 |
| US11035013B2 (en) * | 2018-03-22 | 2021-06-15 | Lear Corporation | Use of hydroxy functional waterborne resins to create urethane crosslinking in leather finishes |
| KR102027323B1 (ko) * | 2018-09-18 | 2019-10-01 | 조맹상 | 수성 방오처리된 폴리우레탄 인조피혁의 제조방법 |
| KR102816232B1 (ko) * | 2018-11-15 | 2025-06-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 합성 피혁 물품 및 이의 제조 방법 |
| CN113079700B (zh) * | 2018-11-15 | 2023-10-03 | 陶氏环球技术有限责任公司 | 合成皮革制品及其制备方法 |
| NL2022904B1 (en) * | 2019-04-09 | 2020-10-20 | Stahl Int B V | Method for upgrading and embossing leather |
| CN111944111B (zh) * | 2019-04-30 | 2022-04-22 | 万华化学集团股份有限公司 | 一种水性自消光聚氨酯分散体和制备方法及其组合物 |
| WO2021101651A1 (en) | 2019-11-19 | 2021-05-27 | Dow Silicones Corporation | Aqueous leather coating composition |
| EP4081596B1 (en) | 2019-12-23 | 2025-01-15 | Dow Silicones Corporation | Aqueous emulsion including interpenetrating network of silicone gum and crosslinked organic polymer |
| EP4097160B1 (en) * | 2020-01-27 | 2024-03-06 | Italkem Srl | Macromolecular compounds and use thereof in compositions |
| IT202000017317A1 (it) * | 2020-07-16 | 2022-01-16 | Italkem Srl | Composti di tipo macromolecolare e suo uso in composizioni |
| IT202000001486A1 (it) * | 2020-01-27 | 2021-07-27 | Italkem Srl | Composti di tipo macromolecolare e suo uso in composizioni |
| CN111269390B (zh) * | 2020-03-19 | 2021-09-17 | 浙江华峰合成树脂有限公司 | 一种合成革面层用聚氨酯树脂及其制备方法 |
| WO2021247341A1 (en) * | 2020-06-04 | 2021-12-09 | Rohm And Haas Company | Aqueous dispersion of single phase crosslinked microspheres and film-forming polyurethane particles |
| CN111875773B (zh) * | 2020-07-15 | 2022-03-22 | 沾化神茂皮革助剂有限公司 | 水性自消光聚氨酯皮革涂饰剂配方及其制备方法 |
| CN111793188B (zh) * | 2020-08-10 | 2021-03-12 | 上海思盛聚合物材料有限公司 | 含羟基自消光水性聚氨酯及由其组成的自消光涂料 |
| CN111996812A (zh) * | 2020-08-18 | 2020-11-27 | 广州溢成印花有限公司 | 一种仿皮革纹路工艺及其应用 |
| JP2023532141A (ja) * | 2021-02-02 | 2023-07-26 | Dic株式会社 | 水分散性ポリイソシアネート組成物、該組成物の製造方法、水性硬化性組成物、水性塗料、及び物品 |
| CN113969097A (zh) * | 2021-10-27 | 2022-01-25 | 兴业皮革科技股份有限公司 | 一种基于无重金属鞣牛坯革的绿色涂饰方法 |
| KR102402167B1 (ko) | 2021-11-09 | 2022-05-30 | 주식회사 지디원 | 그래핀이 함유된 가죽용 코팅제 |
| CN114403540B (zh) * | 2021-12-22 | 2023-11-17 | 浙江三益鞋业有限公司 | 一种抗老化的女靴及其制备方法 |
| CN115368792B (zh) * | 2022-09-28 | 2023-03-28 | 广州海豚新材料有限公司 | 水性皮革边油及其制备方法和应用 |
| CN120981626A (zh) | 2023-10-27 | 2025-11-18 | 美国陶氏有机硅公司 | 硅酮-(甲基)丙烯酸酯共聚物乳液及其制备以及乳液赋予纺织品拒油性的用途 |
| WO2025106268A1 (en) * | 2023-11-16 | 2025-05-22 | Dow Global Technologies Llc | Aqueous coating composition containing an aminosiloxane ester copolymer, method for preparation of the aqueous coating composition, and use for treating leather |
| WO2025106269A1 (en) | 2023-11-16 | 2025-05-22 | Dow Global Technologies Llc | Aqueous coating composition containing an aminosiloxane ester copolymer and a polyurethane binder, and methods for preparation and use thereof |
| WO2025216964A1 (en) | 2024-04-11 | 2025-10-16 | Dow Silicones Corporation | Aqueous coating composition containing a hydroxyl – functional aminosiloxane ester copolymer, method for preparation thereof, and use for leather treatment |
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| JP2003246827A (ja) * | 2002-02-26 | 2003-09-05 | Dainippon Ink & Chem Inc | 水分散性ポリイソシアネート組成物、水性硬化性組成物、水性硬化性組成物を含む塗料および接着剤 |
| DE10238146A1 (de) * | 2002-08-15 | 2004-02-26 | Basf Ag | Wasseremulgierbare Isocyanate mit verbesserten Eigenschaften |
| DE10238148A1 (de) * | 2002-08-15 | 2004-02-26 | Basf Ag | Wasseremulgierbare Isocyanate mit verbesserten Eigenschaften |
| KR101111990B1 (ko) | 2002-10-31 | 2012-02-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리우레탄 분산액 및 이로부터 제조된 제품 |
| EP1599526B1 (en) | 2003-02-28 | 2012-06-13 | Dow Global Technologies LLC | Preparation of isocyanurate group containing polyisocyanate mixtures |
| JP3770275B2 (ja) * | 2004-08-19 | 2006-04-26 | 大日本インキ化学工業株式会社 | 水性プライマー組成物、それを用いた下地処理方法および積層構造体 |
| US20080103263A1 (en) * | 2004-09-03 | 2008-05-01 | Bedri Erdem | Emulsifiable Polyisocyanate |
| ATE532808T1 (de) | 2004-09-03 | 2011-11-15 | Dow Global Technologies Llc | Blockierte isocyanate und ihre verwendung in beschichtungszusammensetzungen |
| CN101341173B (zh) * | 2005-12-19 | 2010-12-15 | 朗盛德国有限责任公司 | 可固化的氟化共聚物及其涂料和方法 |
| JP2007314919A (ja) | 2006-05-29 | 2007-12-06 | Dainippon Ink & Chem Inc | 皮革用表面仕上げ剤およびそれを用いた皮革 |
| JP5404598B2 (ja) * | 2007-03-26 | 2014-02-05 | ビーエーエスエフ ソシエタス・ヨーロピア | 水乳化性ポリイソシアネート |
| US8461255B2 (en) * | 2007-12-06 | 2013-06-11 | Mitsui Chemicals, Inc. | Aqueous polyurethane resin, hydrophilic resin, and film |
| JP5225908B2 (ja) * | 2009-03-26 | 2013-07-03 | 三井化学株式会社 | 合成皮革用二液硬化型水系接着剤 |
| EP2236532A1 (de) * | 2009-03-31 | 2010-10-06 | Bayer MaterialScience AG | Nanopartikelmodifizierte hydrophile Polyisocyanate |
| JP5753181B2 (ja) * | 2010-10-06 | 2015-07-22 | ミドリホクヨー株式会社 | 防汚性付与皮革 |
| JP5479296B2 (ja) * | 2010-10-06 | 2014-04-23 | 三井化学株式会社 | 水性ポリウレタン樹脂、親水性樹脂およびフィルム |
-
2013
- 2013-10-01 JP JP2013206192A patent/JP6247492B2/ja not_active Expired - Fee Related
- 2013-10-02 EP EP13187179.0A patent/EP2727949B1/en not_active Not-in-force
- 2013-10-14 TW TW102136935A patent/TWI498392B/zh not_active IP Right Cessation
- 2013-10-17 BR BR102013026837A patent/BR102013026837B1/pt not_active IP Right Cessation
- 2013-10-28 US US14/064,296 patent/US9200404B2/en not_active Expired - Fee Related
- 2013-10-31 MX MX2013012762A patent/MX339786B/es active IP Right Grant
- 2013-11-05 KR KR1020130133709A patent/KR102083865B1/ko not_active Expired - Fee Related
- 2013-11-06 CN CN201310545695.7A patent/CN103805009B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| MX339786B (es) | 2016-06-09 |
| TWI498392B (zh) | 2015-09-01 |
| EP2727949A1 (en) | 2014-05-07 |
| JP2014098143A (ja) | 2014-05-29 |
| US9200404B2 (en) | 2015-12-01 |
| JP6247492B2 (ja) | 2017-12-13 |
| US20140162073A1 (en) | 2014-06-12 |
| TW201425494A (zh) | 2014-07-01 |
| KR20140058379A (ko) | 2014-05-14 |
| BR102013026837A2 (pt) | 2015-08-25 |
| EP2727949B1 (en) | 2016-11-23 |
| KR102083865B1 (ko) | 2020-03-03 |
| CN103805009B (zh) | 2018-03-30 |
| CN103805009A (zh) | 2014-05-21 |
| BR102013026837B1 (pt) | 2020-04-14 |
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