MX2013005510A - Un proceso para la produccion de acido metacrilico y sus derivados y los polimeros producidos a partir de los mismos. - Google Patents
Un proceso para la produccion de acido metacrilico y sus derivados y los polimeros producidos a partir de los mismos.Info
- Publication number
- MX2013005510A MX2013005510A MX2013005510A MX2013005510A MX2013005510A MX 2013005510 A MX2013005510 A MX 2013005510A MX 2013005510 A MX2013005510 A MX 2013005510A MX 2013005510 A MX2013005510 A MX 2013005510A MX 2013005510 A MX2013005510 A MX 2013005510A
- Authority
- MX
- Mexico
- Prior art keywords
- methacrylic acid
- acid
- production
- derivatives
- decarboxylation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title abstract 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 238000006114 decarboxylation reaction Methods 0.000 abstract 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- ODBLHEXUDAPZAU-ZAFYKAAXSA-N D-threo-isocitric acid Chemical compound OC(=O)[C@H](O)[C@@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-ZAFYKAAXSA-N 0.000 abstract 1
- ODBLHEXUDAPZAU-FONMRSAGSA-N Isocitric acid Natural products OC(=O)[C@@H](O)[C@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-FONMRSAGSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 abstract 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 abstract 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 abstract 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C51/38—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by decarboxylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un proceso para la producción de ácido metacrílico. El proceso comprende la descarboxilación catalizada básica de al menos uno o una mezcla de ácidos dicarboxílicos seleccionados a partir de ácido itacónico, citracónico o mesacónico. La descarboxilación se lleva a cabo en el rango mayor que 240 y hasta 275°C para proveer una alta selectividad. El producto de ácido metacrílico se puede esterificar para producir un éster. También se describe un método para preparar polímeros o copolímeros de ácido metacrílico o ésteres de ácido metacrílico utilizando el proceso. Opcionalmente, el proceso puede estar precedido por una descarboxilación y, en caso de ser necesario, un paso de deshidratación en una fuente de preácido tal como ácido cítrico o ácido isocítrico.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1019915.6A GB201019915D0 (en) | 2010-11-24 | 2010-11-24 | A process for the production of methacrylic acid and its derivatives and polmers produced therefrom |
| GBGB1105467.3A GB201105467D0 (en) | 2011-03-31 | 2011-03-31 | A process for the production of methacrylic acid and its derivatives and polymers produced therefrom |
| PCT/GB2011/052271 WO2012069813A1 (en) | 2010-11-24 | 2011-11-18 | A process for the production of methacrylic acid and its derivatives and polymers produced therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2013005510A true MX2013005510A (es) | 2013-12-16 |
Family
ID=45099138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013005510A MX2013005510A (es) | 2010-11-24 | 2011-11-18 | Un proceso para la produccion de acido metacrilico y sus derivados y los polimeros producidos a partir de los mismos. |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US9174913B2 (es) |
| EP (1) | EP2643283B1 (es) |
| JP (1) | JP5857064B2 (es) |
| KR (1) | KR20130129977A (es) |
| CN (1) | CN103228606B (es) |
| AR (1) | AR083970A1 (es) |
| AU (1) | AU2011333557A1 (es) |
| BR (1) | BR112013012861B1 (es) |
| CA (1) | CA2817641C (es) |
| EA (1) | EA201390751A1 (es) |
| ES (1) | ES2552981T3 (es) |
| MX (1) | MX2013005510A (es) |
| MY (1) | MY179932A (es) |
| NZ (1) | NZ611514A (es) |
| SG (1) | SG190294A1 (es) |
| TW (1) | TW201229025A (es) |
| UA (1) | UA110121C2 (es) |
| UY (1) | UY33749A (es) |
| WO (1) | WO2012069813A1 (es) |
| ZA (1) | ZA201303625B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013019323B1 (pt) | 2011-02-09 | 2019-12-24 | Lucite International Uk Limited | método de extrair ácido (met)acrílico a partir de um meio de reação aquoso, processo para a produção de ácido (met)acrílico, e, método de preparar polímeros ou copolímeros de ácido (met)acrílico ou ésteres de ácido (met)acrílico |
| GB201207388D0 (en) * | 2012-04-27 | 2012-06-13 | Lucite Int Uk Ltd | A process for the production of methacrylic acid and its derivatives and polymers produced therefrom |
| TW201508064A (zh) * | 2013-08-02 | 2015-03-01 | Lucite Int Uk Ltd | 製造甲基丙烯酸及其衍生物之方法 |
| AU2014311940B2 (en) * | 2013-08-26 | 2018-01-04 | Stichting Wageningen Research | Process for the production of methacrylic acid |
| AU2014221198B2 (en) * | 2013-09-16 | 2015-05-07 | Armstrong World Industries, Inc. | Methods for preparing methacrylic acid from biobased starting materials |
| CN108026548A (zh) | 2015-05-19 | 2018-05-11 | 卢塞特英国国际有限公司 | 生物制备甲基丙烯酸及其衍生物的方法 |
| CN106060964A (zh) * | 2016-07-01 | 2016-10-26 | 惠州市德赛西威汽车电子有限公司 | 一种车载蓝牙电话系统中快速自动连接手机的方法及装置 |
| GB201707034D0 (en) | 2017-05-03 | 2017-06-14 | Gradley Michell Lorraine | Modified microorganisms and methods for production of useful products |
| SI3553045T1 (sl) | 2018-04-09 | 2025-03-31 | Kemijski inštitut | Postopek za proizvodnjo monomera metakrilne kisline iz karboksilnih kislin, ki izvirajo iz biomase |
| GB2621337A (en) | 2022-08-08 | 2024-02-14 | Mitsubishi Chemical Uk Ltd | Process for the biological production of methacrylic acid and derivatives thereof |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE550710A (es) * | ||||
| US2504049A (en) | 1946-03-04 | 1950-04-11 | Du Pont | Preparation of polymethacrylic acid and of polymeric products containing polymethacrylic acid |
| DE2323328C2 (de) | 1973-05-09 | 1982-04-01 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Abtrennung von Acrylsäure aus einer angesäuerten wäßrigen Butanol-Acrylsäure-Veresterungsablauge |
| JPS57168906A (en) | 1981-04-13 | 1982-10-18 | Kao Corp | Maleic acid/(meth)acrylic acid copolymer |
| DE4443557A1 (de) * | 1994-12-07 | 1996-06-13 | Roehm Gmbh | Hochwärmeformbeständige, spannungsrißbeständige Polymethacrylat-Formmassen |
| GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| DE10203565C1 (de) * | 2002-01-29 | 2003-07-10 | Roehm Gmbh | Verfahren zur Herstellung eines schlagzähen Polymethylmethacrylat- Formkörpers und Verwendung des so hergestellten Kunststoffformkörpers |
| EP2085376B1 (en) | 2008-01-30 | 2012-09-05 | Evonik Röhm GmbH | Process for preparation of high purity methacrylic acid |
| FR2938536B1 (fr) | 2008-11-18 | 2012-07-13 | Arkema France | Procede de fabrication d'un methacrylate de methyle derive de la biomasse |
| GB0922255D0 (en) | 2009-12-21 | 2010-02-03 | Lucite Int Uk Ltd | Method of producing acrylic and methacrylic acid |
-
2011
- 2011-11-18 CA CA2817641A patent/CA2817641C/en active Active
- 2011-11-18 SG SG2013037411A patent/SG190294A1/en unknown
- 2011-11-18 WO PCT/GB2011/052271 patent/WO2012069813A1/en not_active Ceased
- 2011-11-18 NZ NZ61151411A patent/NZ611514A/en not_active IP Right Cessation
- 2011-11-18 US US13/989,363 patent/US9174913B2/en active Active
- 2011-11-18 MY MYPI2013700847A patent/MY179932A/en unknown
- 2011-11-18 BR BR112013012861-5A patent/BR112013012861B1/pt not_active IP Right Cessation
- 2011-11-18 EP EP11791623.9A patent/EP2643283B1/en not_active Not-in-force
- 2011-11-18 UA UAA201307885A patent/UA110121C2/uk unknown
- 2011-11-18 AU AU2011333557A patent/AU2011333557A1/en not_active Abandoned
- 2011-11-18 KR KR1020137015228A patent/KR20130129977A/ko not_active Withdrawn
- 2011-11-18 MX MX2013005510A patent/MX2013005510A/es active IP Right Grant
- 2011-11-18 EA EA201390751A patent/EA201390751A1/ru unknown
- 2011-11-18 JP JP2013540434A patent/JP5857064B2/ja not_active Expired - Fee Related
- 2011-11-18 CN CN201180056814.1A patent/CN103228606B/zh not_active Expired - Fee Related
- 2011-11-18 ES ES11791623.9T patent/ES2552981T3/es active Active
- 2011-11-23 UY UY0001033749A patent/UY33749A/es not_active Application Discontinuation
- 2011-11-23 TW TW100142975A patent/TW201229025A/zh unknown
- 2011-11-23 AR ARP110104366A patent/AR083970A1/es unknown
-
2013
- 2013-05-17 ZA ZA2013/03625A patent/ZA201303625B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014505668A (ja) | 2014-03-06 |
| CA2817641A1 (en) | 2012-05-31 |
| CA2817641C (en) | 2018-08-21 |
| KR20130129977A (ko) | 2013-11-29 |
| EP2643283A1 (en) | 2013-10-02 |
| TW201229025A (en) | 2012-07-16 |
| EA201390751A1 (ru) | 2013-11-29 |
| US9174913B2 (en) | 2015-11-03 |
| US20130303713A1 (en) | 2013-11-14 |
| BR112013012861B1 (pt) | 2019-10-08 |
| EP2643283B1 (en) | 2015-08-12 |
| JP5857064B2 (ja) | 2016-02-10 |
| SG190294A1 (en) | 2013-06-28 |
| WO2012069813A1 (en) | 2012-05-31 |
| CN103228606A (zh) | 2013-07-31 |
| NZ611514A (en) | 2015-04-24 |
| UY33749A (es) | 2012-06-29 |
| ES2552981T3 (es) | 2015-12-03 |
| CN103228606B (zh) | 2016-11-09 |
| MY179932A (en) | 2020-11-19 |
| ZA201303625B (en) | 2014-06-25 |
| BR112013012861A2 (pt) | 2016-08-23 |
| AU2011333557A1 (en) | 2013-06-27 |
| UA110121C2 (uk) | 2015-11-25 |
| AR083970A1 (es) | 2013-04-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |