ZA200700832B - Method for the production of acrylic acid by means of heterogeneously catalyzed partial gas phase oxidation of propylene - Google Patents
Method for the production of acrylic acid by means of heterogeneously catalyzed partial gas phase oxidation of propyleneInfo
- Publication number
- ZA200700832B ZA200700832B ZA200700832A ZA200700832A ZA200700832B ZA 200700832 B ZA200700832 B ZA 200700832B ZA 200700832 A ZA200700832 A ZA 200700832A ZA 200700832 A ZA200700832 A ZA 200700832A ZA 200700832 B ZA200700832 B ZA 200700832B
- Authority
- ZA
- South Africa
- Prior art keywords
- propylene
- acrylic acid
- gas phase
- heterogeneously catalyzed
- phase oxidation
- Prior art date
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title abstract 5
- 230000003647 oxidation Effects 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical class CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 5
- 239000001294 propane Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/17—Ink jet characterised by ink handling
- B41J2/175—Ink supply systems ; Circuit parts therefor
- B41J2/17503—Ink cartridges
- B41J2/17513—Inner structure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention relates to a method for producing acrylic acid by means of two-stage heterogeneously catalyzed partial gas phase oxidation of propylene. According to said method, previously dehydrogenated propane is used as a propylene source while the first partial oxidation stage is operated so as to limit propylene reaction. Furthermore, unreacted propane and propylene contained in the product gas mixture of the second partial oxidation stage are largely redirected into the propane dehydrogenation process taking place upstream.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58446904P | 2004-07-01 | 2004-07-01 | |
| DE200410032129 DE102004032129A1 (en) | 2004-07-01 | 2004-07-01 | Production of acrolein and acrylic acid, e.g. chemical intermediate and monomer, comprises dehydrogenation and partial oxidation of propane by adding cycle gas at point where propane in main feed is partly dehydrogenated |
| DE200510009891 DE102005009891A1 (en) | 2005-03-01 | 2005-03-01 | Preparation of acrolein or acrylic acid involves conducting starting reaction gas mixture having propylene and molecular oxygen reactants and inert molecular nitrogen and propane diluent gasses through fixed catalyst bed |
| DE200510010111 DE102005010111A1 (en) | 2005-03-02 | 2005-03-02 | Preparation of acrolein or acrylic acid involves conducting starting reaction gas mixture having propylene and molecular oxygen reactants and inert molecular nitrogen and propane diluent gasses through fixed catalyst bed |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200700832B true ZA200700832B (en) | 2008-11-26 |
Family
ID=39745880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200700832A ZA200700832B (en) | 2004-07-01 | 2007-01-30 | Method for the production of acrylic acid by means of heterogeneously catalyzed partial gas phase oxidation of propylene |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1765759B1 (en) |
| JP (2) | JP2008504309A (en) |
| KR (1) | KR101206583B1 (en) |
| CN (1) | CN1980882B (en) |
| AT (1) | ATE520640T1 (en) |
| MY (1) | MY137626A (en) |
| RU (1) | RU2415126C2 (en) |
| TW (1) | TWI370814B (en) |
| WO (1) | WO2006002703A1 (en) |
| ZA (1) | ZA200700832B (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1980878B (en) * | 2004-07-01 | 2010-09-29 | 巴斯福股份公司 | Method for the production of acrolein, acrylic acid, or a mixture thereof by means of heterogeneously catalyzed partial gas phase oxidation of propylene |
| EP1765759B1 (en) * | 2004-07-01 | 2011-08-17 | Basf Se | Method for the production of acrylic acid by means of heterogeneously catalyzed partial gas phase oxidation of propylene |
| DE102005061626A1 (en) * | 2005-12-21 | 2007-06-28 | Basf Ag | Continuous heterogeneous catalyzed partial dehydrogenation of hydrocarbon involves feeding hydrocarbon to reaction chamber enclosed by shell made of specific steel, passing hydrocarbon through catalyst bed and dehydrogenating feed |
| DE102005062010A1 (en) | 2005-12-22 | 2007-06-28 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propylene to acrylic acid comprises introducing a reaction gas mixture into a reaction zone, and transferring the product gas mixture into a condensed phase and a separation zone |
| DE102007055086A1 (en) | 2007-11-16 | 2009-05-20 | Basf Se | Manufacture of acrylic acid involves subjecting precursor to heterogeneously catalyzed gas phase partial oxidation with oxygen in catalyst, reducing gas mixture, and subjecting crude acrylic acid to thermal separation process |
| DE102007004960A1 (en) | 2007-01-26 | 2008-07-31 | Basf Se | Production of acrylic acid by partial gas phase oxidation, for use e.g. as monomer, includes extracting acrylic acid with organic solvent from acidic stream obtained in purification column |
| DE102010048405A1 (en) | 2010-10-15 | 2011-05-19 | Basf Se | Long term operation of heterogeneously catalyzed partial gas phase oxidation of propene to acrolein, comprises conducting reaction gas input mixture containing propene, molecular oxygen and inert gas, through solid catalyst bed |
| DE102011076931A1 (en) | 2011-06-03 | 2012-12-06 | Basf Se | Aqueous solution containing acrylic acid and its conjugate base |
| WO2013048646A1 (en) * | 2011-09-29 | 2013-04-04 | Rohm And Haas Company | Process for the (amm)oxidation of lower molecular weight alkanes and alkenes |
| KR102224278B1 (en) | 2017-04-12 | 2021-03-08 | 주식회사 엘지화학 | Catalyst system for oxidative dehydrogenation reaction, reactor for oxidative dehydrogenation comprising the same system and oxidative dehydrogenation method |
| KR102262896B1 (en) | 2017-11-30 | 2021-06-09 | 주식회사 엘지화학 | Catalyst system for oxidative dehydrogenation reaction, reactor for producing butadiene comprising the same system and method for preparing 1,3-butadiene |
| KR102072475B1 (en) | 2018-08-22 | 2020-02-03 | 한국화학연구원 | Catalyst for manufacturing acrylic acid and a method for manufacturing acrylic acid using it |
| CN112939810B (en) * | 2021-03-29 | 2023-05-16 | 上海师范大学 | Method for synthesizing acrylonitrile by ammoxidation of acrolein |
| US20240343667A1 (en) | 2021-07-28 | 2024-10-17 | Basf Se | Process for preparing acrylic acid |
| WO2025172146A1 (en) | 2024-02-15 | 2025-08-21 | Basf Se | Method for producing acrylic acid |
| WO2025219137A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing acrylic acid production waste streams by gasification and fermentation |
| WO2025219135A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing high calorific acrylic acid production waste streams |
| WO2025219136A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing acrylic acid production waste streams |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3287066B2 (en) * | 1993-06-28 | 2002-05-27 | 住友化学工業株式会社 | Method for producing acrylic acid |
| EP0731077B1 (en) * | 1995-03-10 | 1999-10-13 | Basf Aktiengesellschaft | Process for the preparation of acrolein, acrylic acid or their mixtures from propane |
| EP0731082B1 (en) * | 1995-03-10 | 1999-06-02 | Basf Aktiengesellschaft | Process for continuous heterogenous catalyzed partial oxidation of propylene in gaseous phase to acrolein, acrylic acid or their mixture |
| CA2261268A1 (en) * | 1996-04-01 | 1997-10-09 | Jonathan Lester Brockwell | Processes for the oxidation of alkanes |
| JP3545562B2 (en) * | 1997-02-10 | 2004-07-21 | 鐘淵化学工業株式会社 | Foam comprising modified polypropylene resin composition and method for producing the same |
| EP1045688A1 (en) * | 1998-01-16 | 2000-10-25 | Biomira Usa Inc. | Lipomatrix preparation |
| DE19837518A1 (en) * | 1998-08-19 | 2000-02-24 | Basf Ag | Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using modified air with less nitrogen and more oxygen than normal air as the oxygen source |
| MY121878A (en) * | 1999-03-10 | 2006-02-28 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrylic acid |
| MY119958A (en) * | 1999-03-10 | 2005-08-30 | Basf Ag | Catalytic gas-phase oxidation of propene to acrylic acid |
| CZ303896B6 (en) * | 2000-04-11 | 2013-06-12 | Basf Aktiengesellschaft | A method for purifying the melt of crude acrylic acid |
| DE10131297A1 (en) * | 2001-06-29 | 2003-01-09 | Basf Ag | Production of partial (ammo)oxidation products of an olefinic hydrocarbon, useful for acrolein/acrylic acid from propane, comprises intermittent supplementation of olefin from another source. |
| JP2003251184A (en) * | 2001-11-19 | 2003-09-09 | Mitsubishi Chemicals Corp | Method for producing composite oxide catalyst |
| US7326802B2 (en) * | 2002-09-27 | 2008-02-05 | Basf Aktiengesellschaft | Preparation of at least one partial oxidation and/or ammoxidation product of propylene |
| DE10313209A1 (en) * | 2003-03-25 | 2004-03-04 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid, useful for the production of adhesive, comprises use of a gas phase mixture having a molar ratio of oxygen to propene of 1.5-2.5 |
| JP3999160B2 (en) | 2003-05-14 | 2007-10-31 | 株式会社日本触媒 | Method for producing easily polymerizable substance |
| EP1765759B1 (en) * | 2004-07-01 | 2011-08-17 | Basf Se | Method for the production of acrylic acid by means of heterogeneously catalyzed partial gas phase oxidation of propylene |
-
2005
- 2005-04-21 EP EP05743080A patent/EP1765759B1/en not_active Revoked
- 2005-04-21 RU RU2007103614/04A patent/RU2415126C2/en not_active IP Right Cessation
- 2005-04-21 AT AT05743080T patent/ATE520640T1/en active
- 2005-04-21 CN CN2005800224730A patent/CN1980882B/en not_active Expired - Fee Related
- 2005-04-21 KR KR1020077002532A patent/KR101206583B1/en not_active Expired - Fee Related
- 2005-04-21 WO PCT/EP2005/004282 patent/WO2006002703A1/en not_active Ceased
- 2005-04-21 JP JP2007518467A patent/JP2008504309A/en active Pending
- 2005-05-06 TW TW094114839A patent/TWI370814B/en not_active IP Right Cessation
- 2005-05-09 MY MYPI20052058A patent/MY137626A/en unknown
-
2007
- 2007-01-30 ZA ZA200700832A patent/ZA200700832B/en unknown
-
2011
- 2011-02-08 JP JP2011024996A patent/JP2011088940A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011088940A (en) | 2011-05-06 |
| EP1765759B1 (en) | 2011-08-17 |
| KR101206583B1 (en) | 2012-11-29 |
| JP2008504309A (en) | 2008-02-14 |
| WO2006002703A1 (en) | 2006-01-12 |
| CN1980882B (en) | 2010-12-08 |
| RU2007103614A (en) | 2008-08-10 |
| RU2415126C2 (en) | 2011-03-27 |
| EP1765759A1 (en) | 2007-03-28 |
| TW200613262A (en) | 2006-05-01 |
| KR20070043995A (en) | 2007-04-26 |
| CN1980882A (en) | 2007-06-13 |
| MY137626A (en) | 2009-02-27 |
| TWI370814B (en) | 2012-08-21 |
| ATE520640T1 (en) | 2011-09-15 |
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