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WO2025238337A1 - A system and process for treating wine - Google Patents

A system and process for treating wine

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Publication number
WO2025238337A1
WO2025238337A1 PCT/GB2025/050984 GB2025050984W WO2025238337A1 WO 2025238337 A1 WO2025238337 A1 WO 2025238337A1 GB 2025050984 W GB2025050984 W GB 2025050984W WO 2025238337 A1 WO2025238337 A1 WO 2025238337A1
Authority
WO
WIPO (PCT)
Prior art keywords
wine
gas
aeration
oxygen
treatment zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/GB2025/050984
Other languages
French (fr)
Inventor
Michael William PRITCHARD
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vinalchemy Ltd
Original Assignee
Vinalchemy Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB2406752.2A external-priority patent/GB2633889B/en
Priority claimed from GBGB2504234.2A external-priority patent/GB202504234D0/en
Application filed by Vinalchemy Ltd filed Critical Vinalchemy Ltd
Publication of WO2025238337A1 publication Critical patent/WO2025238337A1/en
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12HPASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
    • C12H1/00Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
    • C12H1/12Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages without precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312Diffusers
    • B01F23/23123Diffusers consisting of rigid porous or perforated material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/236Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids specially adapted for aerating or carbonating beverages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2376Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
    • B01F23/23761Aerating, i.e. introducing oxygen containing gas in liquids
    • B01F23/237611Air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2376Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
    • B01F23/23761Aerating, i.e. introducing oxygen containing gas in liquids
    • B01F23/237612Oxygen
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G1/00Preparation of wine or sparkling wine
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G1/00Preparation of wine or sparkling wine
    • C12G1/06Preparation of sparkling wine; Impregnation of wine with carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12HPASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
    • C12H1/00Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
    • C12H1/12Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages without precipitation
    • C12H1/14Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages without precipitation with non-precipitating compounds, e.g. sulfiting; Sequestration, e.g. with chelate-producing compounds

Definitions

  • Aerating wine during production is a deliberate process aimed at enhancing its flavour profile and overall quality. Aeration involves exposing the wine to oxygen, which can help soften harsh tannins, release volatile compounds responsible for aroma, and promote chemical reactions that improve the wine's complexity.
  • Winemakers may choose to aerate wine during production in one of several ways, including splash racking, pumping over, barrel aging and micro-oxygenation.
  • the splash racking approach involves transferring wine from one container to another in a way that exposes it to air, often causing it to splash and mix with oxygen.
  • Micro-oxygenation is a controlled process where small, precise amounts of oxygen are introduced into the wine through a permeable membrane. It allows winemakers to carefully regulate the level of oxygen exposure and its impact on the wine.
  • a method for producing wine comprises dosing a flowing body of a wine product with a stream of bubbles of a gas mixture to promote aeration of the wine product during one or more stages of wine production, wherein the gas mixture comprises an inert sparging gas and no more than 10% by volume of oxygen (02).
  • the inert carrier sparging gas comprises nitrogen (N2) and/or argon (Ar).
  • the gas mixture comprises substantially between 0.3% and 10% by volume of oxygen, preferably no more than 5%, more preferably in the range of 0.5% to 3%, even more preferably around 1.5%.
  • the gas mixture comprises vitiated air.
  • vitiated air means air in which the oxygen content has been reduced.
  • the vitiated air comprises substantially between 0.3% and 10% by volume of oxygen, preferably no more than 5%, more preferably in the range of 0.5% to 3%, even more preferably around 1.5%.
  • the gas mixture is air which has been pressurised using an inert sparging gas such as N2 or Ar to reduce the oxygen content, or obtained by mixing oxygen with an inert gas, which may either be pre-mixed within a single vessel, obtained through gas entrainment of air using an inert carrier gas, or mixed in situ when feeding from multiple sources of gas.
  • an inert sparging gas such as N2 or Ar
  • an inert gas which may either be pre-mixed within a single vessel, obtained through gas entrainment of air using an inert carrier gas, or mixed in situ when feeding from multiple sources of gas.
  • the method further comprises the step of introducing a flow of the wine product through an aeration device where the flow of wine product is dosed with the gas mixture.
  • the method comprises dosing a flowing body of a wine product within a gas reactor system (GR.S) having at least one aeration treatment zone, with a counterflowing stream of bubbles of the aeration gas which rise against the wine flow under their own upthrust.
  • GR.S gas reactor system
  • the flow of wine product is obtained from a wine vessel, more preferably a wine tank or a wine barrel.
  • the method further comprises the step of directing a flow of aerated wine product to a vessel for storage, the vessel being selected from a bottle, a wine barrel and a wine tank.
  • a system for aerating a wine product in the production of wine comprises: a housing for receiving a flow of the wine product, the housing having an aeration treatment zone, a wine input port coupled to a proximal end of the aeration treatment zone, and a wine output port coupled to a distal end of the aeration treatment zone; a source of aeration gas; and, a gas introducer positioned within the aeration treatment zone and coupled to the source of aeration gas for introducing a stream of gas bubbles in the wine product as it flows through the aeration treatment zone to the wine output port, thereby to aerate the wine product.
  • the aeration gas comprises an inert sparging gas mixed with between 0.3% by volume of oxygen and 10% by volume of oxygen.
  • the aeration gas is vitiated air.
  • the system comprises a gas diffuser, sometimes known as a bubble diffuser, which produces fine gas bubbles to provide a high surface area for the fast and efficient mass transfer of oxygen to the wine.
  • a gas diffuser sometimes known as a bubble diffuser, which produces fine gas bubbles to provide a high surface area for the fast and efficient mass transfer of oxygen to the wine.
  • the gas diffuser is formed from a porous material. Examples of suitable porous materials include a stone air diffuser and a porous sinter diffuser, preferably formed from sintered metal. In some embodiments, a plurality of gas diffusers can be used.
  • the housing comprises a gas port for venting excess aeration gas.
  • the method comprises the step of adjusting one or more of the following controllable settings to control an aeration dosage selected from:
  • the dosing of the wine is effective to modify one or more of the following measurable characteristics of the wine product:
  • the method comprises the step of using feedback control of one or more of the controllable settings to achieve a desired level of one or more of the measurable characteristics of the wine.
  • Feedback control may be at least partially automated.
  • the method may include a test phase for determining a set of controllable characteristics to achieve a set of desired wine characteristics for a sample of the wine product. Once these have been determined, system settings can be set accordingly before applying the treatment to the production batch.
  • FIG 1 shows a typical set of stages in the traditional commercial production of wine
  • Figure 2 shows an example of a wine treatment system in accordance with the present invention incorporating a Gas Reactor System (GRS);
  • GRS Gas Reactor System
  • FIGS 3 to 5 each show a simplified schematic of an alternative gas injection apparatus for use in the wine treatment system of Figure 2;
  • FIGS 6 to 8 show further examples of GRS arrangements for use in a wine treatment system. Detailed description
  • Figure 1 shows several of the typical production stages of wine making.
  • a wine treatment system and process in accordance with the present invention can be used by a winemaker at one or more of these production stages.
  • FIG. 3 Once pressing (stage 3) has completed the wine treatment system may be employed.
  • juice settling (stage 4) it is used here to improve colour stability, phenolic structure.
  • Dissolved 02 may also be altered at this stage. It can also be used here to alter the S02 composition within the wine including reducing total S02. It may also be used to prevent the need for S02 addition at this stage.
  • the wine treatment system may be employed, either before S02 addition, or of just after. It may be used here to improve colour stability, phenolic structure, aromatic integration, pigmentation of tannins, and either increasing the wines reductive strength still further or reduce it, dependent upon the uptake and interaction of the 02. Dissolved 02 may also be adjusted at this stage. It may also be used to alter the titratable acidity. It can be used here to alter the S02 composition within the wine including reducing bound and total S02.
  • the wine treatment system may also be employed during storage (stage 7). It is used here to provide additional phenolic structuring, aroma integration and to alter the wines reductive strength. Dissolved 02 may also be altered at this stage. It can also be used here to alter the S02 composition within the wine including reducing bound and total S02. It may be used to alter the titratable acidity.
  • the wine treatment may also be used during blending (stage 8). It could be used on one or more of the components of the wine blend, or the final blend.
  • the wine treatment system can also be employed immediately prior to bottling (stage 11).
  • the wine treatment system described herein may also be used at similar stages in the production of sparkling wine (not shown), particularly before or after what is known as the dosage stage to further adjust the sensory profile of the wine to the needs of the winemaker. It may also be useful in the production of fortified wines such as Port, Sherry, Madeira and Marsala.
  • Figure 2 shows an example of a wine treatment system and process in accordance with aspects of the present invention.
  • untreated wine is held in a storage vessel 1 prior to treatment.
  • the storage vessel 1 may be a wine tank or a wine barrel.
  • Pump 2 is a peristaltic pump which allows the flow rate of the wine to be accurately set.
  • Wine flows horizontally through an inlet pipe 3 and then into a vertically aligned pipe section 4 of the GRS 50. An aeration gas is introduced to the vertical pipe section
  • a gas diffuser 5 for creating a counter flowing stream of fine gas bubbles (also known as a bubble diffuser) which rise upwardly as a result of their inherent buoyancy.
  • a gas diffuser 5 for creating a counter flowing stream of fine gas bubbles (also known as a bubble diffuser) which rise upwardly as a result of their inherent buoyancy.
  • more than one gas diffuser may be employed, each either carrying the same aeration gas or a different gas which collectively forms the aeration gas.
  • Aeration gas is obtained from a storage vessel 12, whose flow is regulated by a regulator valve 13 and passes through a flow meter 14. It is coupled to the gas diffuser
  • the aeration gas comprises vitiated air.
  • the term 'vitiated air' means air in which the oxygen content has been reduced.
  • the gas mixture is air which has been pressurised using nitrogen i . e. , nitrogen is introduced into a volume of air at atmospheric pressure. It is possible to achieve substantially the same mixture of gases using other set ups, some of which are described below with reference to Figures 3 to 5.
  • the aeration gas comprises between 0.3% and 10% by volume of oxygen, preferably no more than 5%, more preferably in the range of 0.5% to 3%, even more preferably around 1.5%.
  • the downward flow of the wine may, depending on the flow rate established, at least partially entrain the counterflowing stream of aeration gas bubbles 6 within the flowing body of wine against the buoyancy force (upthrust) of the bubbles.
  • the entrained aeration gas bubbles 6 travel in the direction of the flow of the wine until they reverse direction and rise upwardly to the top of the vertical pipe section 4.
  • the aeration gas bubbles 6 expand as they rise upwardly against the flow of the wine to the top of the vertical pipe section 4.
  • Fine aeration gas bubbles 6 are created by the diffuser 5, typically measuring in the order of around ⁇ 0.5mm in diameter initially, which provide a large surface area for oxygen to dissolve into the wine. As the 02 dissolves into the wine it then reacts with the compounds and other chemistry in the wine.
  • Dissolved 02 that has not reacted with the wine, unreacted 02, is removed from solution by the nitrogen (or argon) content in the gas, through an action known as sparging.
  • valve 24 is shown as a pressure release valve but could equally be a release valve or a gas permeable membrane, for instance a hydrophobic membrane.
  • the treated wine continues to travel horizontally and exits this section via an outlet pipe 10 to a pump 11, where it then exits the GRS 50.
  • the treated wine may then be sent for bottling or returned to a storage vessel until it is ready for further treatment or to be bottled.
  • Some of the stored wine may be kept for a period of time to mature further or, it may be used in dosage, blending and other stages of wine making.
  • the aeration gas counterflow arrangement established within a designated aeration treatment zone shown in Figure 2 ensures a consistent aeration dosage, with unreacted oxygen within that zone being sparged away from the direction of travel of the wine flow by the inert gas, e.g., nitrogen, thereby avoiding unwanted additional oxygen reactions.
  • the wine is then ready for bottling immediately after leaving the system having been correctly dosed with aeration gas.
  • the height of the column of wine within the vertical pipe section 4 can be adjusted through selection of the height or diameter of the vertical pipe section.
  • the vertical pipe section 4 could be telescopically adjustable or tiltable.
  • the diameter of the pipe section 4 may vary across its length.
  • the pipe section may be non-contiguous i.e., split over a number of vertically stepped sections.
  • each gas diffuser 5 within the vertical pipe section 4 may be raised or lowered.
  • reaction zone The column of the vertical pipe section 4 from the top surface of the wine 16 to the base section 17, where the vast majority of the aeration gas bubbles turn back and travel up the vertical pipe section 4 towards the surface, is known as the reaction zone (RZ) or gas treatment zone.
  • a material 18 such as stainless-steel wire wool or other suitable material(s) is placed into the RZ to help prevent foaming of the wine.
  • the material 18 could also incorporate a quantity of iron or copper to further aid chemical reactions within the wine.
  • oak chips 19 or other additional ingredients can be placed in the RZ.
  • the aeration gas bubbles 6 and wine pass through the oak chips 19, reacting with and drawing out properties from within the chips, such as tannins.
  • Remnants of the aeration gas 6 rises to the top of the vertical pipe section 4 and can accumulate at or around point 20. It can then exit the vertical pipe section 4 via a valve 21.
  • Valve 21 is shown as a pressure release valve but could equally be a release valve or a gas permeable membrane, for instance a hydrophobic membrane.
  • the top of the vertical pipe section 4 could simply be open to the surrounding atmosphere to vent remnants of the aeration gas.
  • a mixture of aeration gas and wine may also exit the vertical pipe section 4 via an outlet pipe 22 governed by a valve 28, where it can be sent back to the original storage vessel 1 (or, if required, to a different storage vessel).
  • This foam will naturally dissipate across the surface of the wine in the storage vessel and thereby act as an inert protective blanket against unwanted atmospheric oxidation.
  • any volatiles that have been released from the wine during processing within the GRS 50 may be captured within the foam and subsequently dissolved back into the wine and returned to the storage vessel, thereby reducing volatile aroma loss.
  • the overspill of wine can simply be drained or stored for further use.
  • the pressure within the GRS 50 may be regulated or it could be kept broadly at atmospheric pressure. A higher than atmospheric pressure within the system may help to increase the solubility of the aeration gas into the wine.
  • the temperature of the wine can also be controlled to affect the take-up rate of the 02 and other characteristics of the wine product, or to reduce volatile evaporation.
  • a wine sampling port 23 is provided so that a wine maker can take samples of the wine. Such sampling is then used to inform any adjustments needed to the system.
  • Other sampling ports may be used to sample wine at various points in the system.
  • An oxygen meter 29 can be used to read the dissolved oxygen levels within the wine product prior to treatment.
  • a further oxygen meter 30 can be used to read the dissolved oxygen levels within the treated wine product. Comparisons can then be made and then used to inform any adjustments needed to the system.
  • the system can be controlled through appropriate adjustments as follows:
  • the diameter of the vertical pipe section 4 can be selected along with its shape
  • the height of the vertical pipe section 4 can be selected as well as its diameter
  • System parameters which can be adjusted to control an aeration dosage include (but are not limited to) :
  • Wine can be sampled before treatment and tested using industry standard tests such as the Modified Somers Method to determine the ratio of monomeric and polymerised phenolics.
  • the wine can be sampled again after treatment to determine the increase in polymerisation and adjustments made accordingly dependent upon the result the wine maker requires.
  • tests that can be performed include such tests as total, free and bound SO2, PH, dissolved oxygen, acetaldehyde and colour. Taste, smell, feel and appearance tests may also be performed. The results of these and other tests or measurements may be used to adjust the system.
  • HPLC High-performance liquid chromatograph
  • Table 2 shows the results of these experimental settings when used to treat a sample body of red wine.
  • the red wine's titratable acidity went from 5.013g/l in the untreated wine to 4.875g/l in the treated wine. There was no change in the PH which remained at 3.688.
  • Condensed Tannins (Epicatechin) went from 30.754 mg/l in the untreated wine to 32.054 mg/l in the treated wine.
  • Anthocyanins went from 107.556 mg/l in the untreated wine to 75.157 mg/l in the treated wine.
  • Colour Density went from 6.765 au in the untreated wine to 7.168 au in the treated wine. The treatment positively correlated with higher condensed tannins and higher colour density against the untreated wine.
  • Table 3 shows results of the same experimental settings when used to treat a body of white wine.
  • pure 02 gas stored in gas cylinder 12 is introduced via a first gas diffuser 5, whilst a flow of inert sparging gas from a gas cylinder 32, such as N2, is introduced via a separate gas diffuser stone 5A to create a combined volume of micro-bubbles 6 of aeration gas.
  • a flow of inert sparging gas from a gas cylinder 32, such as N2 is introduced via a separate gas diffuser stone 5A to create a combined volume of micro-bubbles 6 of aeration gas.
  • the respective flow rates of the two gases can be controlled to effect various levels of solubility, reaction and 02 removal or addition.
  • the distance between and relative positioning of the diffusers 5 can be adjusted.
  • Figure 4 shows a simplified schematic an alternative gas injection arrangement for use in the GRS 50 of Figure 2 for providing the aeration gas.
  • gas cylinder 12 contains 100% N2 and a separate gas cylinder 33 contains 100% 02.
  • the 02 could be regulated into the flow of the N2 to achieve similar or the same result as premixing both gases or using a source of vitiated air. This would allow the percentage of 02 to be altered more easily.
  • Figure 5 shows yet another alternative gas injection arrangement for use in the GRS 50 of Figure 2 for providing the aeration gas, where a gas cylinder 12 contains N2 and atmospheric air is entrained into the flow by means of a venturi 26.
  • a pump (not shown) can be provided to introduce atmospheric air into the flow of N2 as to achieve the desired mix of vitiated air for the purpose of aeration.
  • FIGS 6 to 8 show further examples of GRS arrangements for use in a wine treatment system in accordance with the present invention each of which incorporates multiple reaction zones (RZ) i.e., have multiple vertically disposed pipe sections. These designs allow for significantly higher throughput and processing of the wine product.
  • RZ reaction zones
  • untreated wine is held in a storage vessel (not shown) prior to treatment.
  • the storage vessel may be a wine tank or a wine barrel.
  • the same reference numerals used in Figure 2 are used in these figures.
  • a pump 2 which may be a peristaltic pump, which allows the flow rate of the wine to be accurately set.
  • Wine flows horizontally through an inlet pipe 3 and then into a plurality (in this case 3) vertically aligned pipe sections 4 of the GRS 50 arranged in a linearly distributed configuration, each of which provides a reaction zone (RZ) for dosing of a flow of wine product.
  • RZ reaction zone
  • flow regulators 100 can be used to balance the flow of wine.
  • An aeration gas is introduced from a gas storage vessel 12 into the vertical pipe sections 4 below the level of their respective inlet pipes 3 via gas diffusers 5. More than one gas diffuser may be employed per vertical pipe section 4, each either carrying the same aeration gas or a different gas which collectively forms the aeration gas.
  • the flow of aeration gas from the gas storage vessel 12 is regulated by a regulator valve 13 and passes through a flow meter 14. It is coupled to the gas diffusers 5 along a gas transport pipe 15.
  • the gas supply to each gas diffuser 5 can be further regulated by a gas regulator 101.
  • the respective inlet gas diffusers 5 could be fed by separate gas storage vessels and regulated with regulator valves (not shown).
  • the treated wine continues to travel horizontally and exits this section via an outlet pipe 10 to a pump 11, where it then exits the GRS 50.
  • the treated wine may then be sent for bottling or returned to a storage vessel until it is ready to be bottled.
  • Some of the stored wine may be kept for a period of time to mature further or, it may be used in dosage, blending and other stages of wine making.
  • wine flows horizontally through an inlet pipe 3 and then into a plurality (in this case 2) of vertically aligned pipe sections 4 of a GRS 50 arranged in a linearly distributed configuration either side of a single gas trap section 9.
  • Each vertical pipe section provides a reaction zone (RZ) for dosing a flow of wine product as it flows to the outlet pipe 10.
  • RZ reaction zone
  • flow regulators 100 can be used to balance the flow of wine.
  • An aeration gas is introduced to the vertical pipe sections 4 below the level of their respective inlet pipes 3 via gas diffusers.
  • more than one gas diffuser 5 may be employed per vertical pipe section 4, each either carrying the same aeration gas or a different gas which collectively forms the aeration gas.
  • Aeration gas is obtained from a gas storage vessel 12, whose flow is regulated by a regulator valve 13 and passes through a flow meter 14. It is coupled to the gas diffusers 5 along a gas transport pipe 15. The gas to each gas diffuser 5 can be further regulated by a gas regulator 101.
  • the respective inlet gas diffusers 5 could be fed by separate gas storage vessels and regulated with regulator valves (not shown).
  • the treated wine then continues to travel vertically downwards and then horizontally along a pipe section and exits via an outlet pipe 10 to a pump 11, where it then exits the GRS 50.
  • FIG 8 is a plan view of another example of a GRS 50 having a clustered arrangement of vertical pipe sections 4 (in this case 8) which are radially distributed around a single gas trap zone 9.
  • a tank not shown
  • the vertical pipe sections 4 each of which provides a reaction zone (RZ) for dosing a flow of wine product with an aeration gas from a gas storage vessel 12 as it travels to the outlet pipe 10.
  • RZ reaction zone
  • the system may include an array of two or more such GRS 50 having this clustered arrangement.
  • Embodiments of the present invention make it possible to use the complete extraction of juice from the grape, in contrast to known wine making processes which discard this as waste product. This is possible because the process described above accelerates the natural aging of the wine over a very short period of time, allowing even high- extraction levels to be processed, thereby significantly reducing costs.
  • producing wine in this short time frame also leads to significant energy savings and attendant costs within the winery from reduced energy consumption associated with the heating, cooling and lighting required over a shortened period of as little as 3 to 4 months.

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Abstract

A method for producing wine comprises dosing a flowing body of a wine product with a stream of bubbles of a gas mixture to promote aeration of the wine product during one or more stages of wine production, wherein the gas mixture comprises an inert sparging gas having between 03% and 10% by volume of oxygen (O2). A preferred system for aerating a wine product during the production of wine comprises a housing for receiving a flow of the wine product, the housing having an aeration treatment zone, a wine input port coupled to a proximal end of the aeration treatment zone, and a wine output port coupled to a distal end of the aeration treatment zone; a source of aeration gas; and, a gas introducer apparatus positioned within the aeration treatment zone and coupled to the source of aeration gas for introducing a stream of gas bubbles in the wine product as it flows through the aeration treatment zone to the wine output port, thereby to aerate the wine product.

Description

A SYSTEM AND PROCESS FOR TREATING WINE
Background
Aerating wine during production is a deliberate process aimed at enhancing its flavour profile and overall quality. Aeration involves exposing the wine to oxygen, which can help soften harsh tannins, release volatile compounds responsible for aroma, and promote chemical reactions that improve the wine's complexity.
Winemakers may choose to aerate wine during production in one of several ways, including splash racking, pumping over, barrel aging and micro-oxygenation.
The splash racking approach involves transferring wine from one container to another in a way that exposes it to air, often causing it to splash and mix with oxygen.
In pumping over, during fermentation, winemakers pump the fermenting juice or wine from the bottom of the tank and spray it over the top. This action not only helps with mixing but also introduces oxygen to the wine.
Wine stored in barrels naturally undergoes slow oxygenation through the tiny pores of the wood. This process contributes to the wine's development and maturation.
Micro-oxygenation is a controlled process where small, precise amounts of oxygen are introduced into the wine through a permeable membrane. It allows winemakers to carefully regulate the level of oxygen exposure and its impact on the wine.
Overall, aerating wine during production can help improve its sensory characteristics and overall drinking experience. However, it is a delicate balance, as excessive aeration can lead to oxidation and undesirable flavours. Winemakers must carefully monitor the process to achieve the desired results.
Summary of the invention
According to a first aspect of the present invention, a method for producing wine comprises dosing a flowing body of a wine product with a stream of bubbles of a gas mixture to promote aeration of the wine product during one or more stages of wine production, wherein the gas mixture comprises an inert sparging gas and no more than 10% by volume of oxygen (02).
Preferably, the inert carrier sparging gas comprises nitrogen (N2) and/or argon (Ar). In preferred embodiments, the gas mixture comprises substantially between 0.3% and 10% by volume of oxygen, preferably no more than 5%, more preferably in the range of 0.5% to 3%, even more preferably around 1.5%.
In preferred embodiments, the gas mixture comprises vitiated air. In this application, the term 'vitiated air' means air in which the oxygen content has been reduced. The vitiated air comprises substantially between 0.3% and 10% by volume of oxygen, preferably no more than 5%, more preferably in the range of 0.5% to 3%, even more preferably around 1.5%.
In some embodiments, the gas mixture is air which has been pressurised using an inert sparging gas such as N2 or Ar to reduce the oxygen content, or obtained by mixing oxygen with an inert gas, which may either be pre-mixed within a single vessel, obtained through gas entrainment of air using an inert carrier gas, or mixed in situ when feeding from multiple sources of gas.
Preferably, the method further comprises the step of introducing a flow of the wine product through an aeration device where the flow of wine product is dosed with the gas mixture.
In preferred embodiments, the method comprises dosing a flowing body of a wine product within a gas reactor system (GR.S) having at least one aeration treatment zone, with a counterflowing stream of bubbles of the aeration gas which rise against the wine flow under their own upthrust.
Preferably, the flow of wine product is obtained from a wine vessel, more preferably a wine tank or a wine barrel.
Preferably, the method further comprises the step of directing a flow of aerated wine product to a vessel for storage, the vessel being selected from a bottle, a wine barrel and a wine tank.
In preferred embodiments, the wine product is taken at a stage of production selected from one or more of juice settling, fermentation, maturation, barrel or other storage stage, blending, dosage and bottling. According to a second aspect of the present invention, a system for aerating a wine product in the production of wine, comprises: a housing for receiving a flow of the wine product, the housing having an aeration treatment zone, a wine input port coupled to a proximal end of the aeration treatment zone, and a wine output port coupled to a distal end of the aeration treatment zone; a source of aeration gas; and, a gas introducer positioned within the aeration treatment zone and coupled to the source of aeration gas for introducing a stream of gas bubbles in the wine product as it flows through the aeration treatment zone to the wine output port, thereby to aerate the wine product.
Preferably, the aeration gas comprises an inert sparging gas mixed with between 0.3% by volume of oxygen and 10% by volume of oxygen.
In some embodiments, the aeration gas is vitiated air.
Preferably, the system comprises a gas diffuser, sometimes known as a bubble diffuser, which produces fine gas bubbles to provide a high surface area for the fast and efficient mass transfer of oxygen to the wine. Preferably, the gas diffuser is formed from a porous material. Examples of suitable porous materials include a stone air diffuser and a porous sinter diffuser, preferably formed from sintered metal. In some embodiments, a plurality of gas diffusers can be used.
Preferably, the housing comprises a gas port for venting excess aeration gas.
Preferably, the method comprises the step of adjusting one or more of the following controllable settings to control an aeration dosage selected from:
• wine temperature;
• gas temperature;
• wine flow rate;
• aeration gas flow rate;
• aeration gas composition; and,
• exposure (dwell) time.
Preferably, the dosing of the wine is effective to modify one or more of the following measurable characteristics of the wine product:
• titratable acidity; • PH;
• dissolved oxygen;
• aroma;
• taste;
• level of condensed tannins;
• level of monomeric tannins;
• level of anthocyanins;
• colour density;
• free SO2;
• bound SO2;
• total SO2;
• total phenolics;
• total hydroxycinnamic acids;
• total flavonoids;
• Somers Chemical Age 1;
• Somers Chemical Age 2; and,
• pigmentation.
In preferred embodiments, the method comprises the step of using feedback control of one or more of the controllable settings to achieve a desired level of one or more of the measurable characteristics of the wine. Feedback control may be at least partially automated.
The method may include a test phase for determining a set of controllable characteristics to achieve a set of desired wine characteristics for a sample of the wine product. Once these have been determined, system settings can be set accordingly before applying the treatment to the production batch.
Brief description of the drawings
Examples of the present invention will now be described in detail with reference to the accompanying drawings, in which:
Figure 1 shows a typical set of stages in the traditional commercial production of wine; Figure 2 shows an example of a wine treatment system in accordance with the present invention incorporating a Gas Reactor System (GRS);
Figures 3 to 5 each show a simplified schematic of an alternative gas injection apparatus for use in the wine treatment system of Figure 2; and,
Figures 6 to 8 show further examples of GRS arrangements for use in a wine treatment system. Detailed description
Figure 1 shows several of the typical production stages of wine making. As disclosed herein, a wine treatment system and process in accordance with the present invention can be used by a winemaker at one or more of these production stages.
Figure 1 - Once pressing (stage 3) has completed the wine treatment system may be employed. In juice settling (stage 4) it is used here to improve colour stability, phenolic structure. Dissolved 02 may also be altered at this stage. It can also be used here to alter the S02 composition within the wine including reducing total S02. It may also be used to prevent the need for S02 addition at this stage.
During maturation (stage 6) the wine treatment system may be employed, either before S02 addition, or of just after. It may be used here to improve colour stability, phenolic structure, aromatic integration, pigmentation of tannins, and either increasing the wines reductive strength still further or reduce it, dependent upon the uptake and interaction of the 02. Dissolved 02 may also be adjusted at this stage. It may also be used to alter the titratable acidity. It can be used here to alter the S02 composition within the wine including reducing bound and total S02.
The wine treatment system may also be employed during storage (stage 7). It is used here to provide additional phenolic structuring, aroma integration and to alter the wines reductive strength. Dissolved 02 may also be altered at this stage. It can also be used here to alter the S02 composition within the wine including reducing bound and total S02. It may be used to alter the titratable acidity.
The wine treatment may also be used during blending (stage 8). It could be used on one or more of the components of the wine blend, or the final blend.
The wine treatment system can also be employed immediately prior to bottling (stage 11).
The wine treatment system described herein may also be used at similar stages in the production of sparkling wine (not shown), particularly before or after what is known as the dosage stage to further adjust the sensory profile of the wine to the needs of the winemaker. It may also be useful in the production of fortified wines such as Port, Sherry, Madeira and Marsala. Figure 2 shows an example of a wine treatment system and process in accordance with aspects of the present invention.
In Figure 2, untreated wine is held in a storage vessel 1 prior to treatment. Depending on the relevant stage of wine production, the storage vessel 1 may be a wine tank or a wine barrel.
Wine enters a Gas Reactor System (GRS) 50 via a pump 2. In preferred embodiments, pump 2 is a peristaltic pump which allows the flow rate of the wine to be accurately set. Wine flows horizontally through an inlet pipe 3 and then into a vertically aligned pipe section 4 of the GRS 50. An aeration gas is introduced to the vertical pipe section
4 below the level of the inlet pipe 3 via a gas diffuser 5 for creating a counter flowing stream of fine gas bubbles (also known as a bubble diffuser) which rise upwardly as a result of their inherent buoyancy. As described below, more than one gas diffuser may be employed, each either carrying the same aeration gas or a different gas which collectively forms the aeration gas.
Aeration gas is obtained from a storage vessel 12, whose flow is regulated by a regulator valve 13 and passes through a flow meter 14. It is coupled to the gas diffuser
5 along a gas transport pipe 15.
In preferred embodiments, the aeration gas comprises vitiated air. In this application, the term 'vitiated air' means air in which the oxygen content has been reduced. In some embodiments, the gas mixture is air which has been pressurised using nitrogen i . e. , nitrogen is introduced into a volume of air at atmospheric pressure. It is possible to achieve substantially the same mixture of gases using other set ups, some of which are described below with reference to Figures 3 to 5.
The aeration gas comprises between 0.3% and 10% by volume of oxygen, preferably no more than 5%, more preferably in the range of 0.5% to 3%, even more preferably around 1.5%.
The downward flow of the wine may, depending on the flow rate established, at least partially entrain the counterflowing stream of aeration gas bubbles 6 within the flowing body of wine against the buoyancy force (upthrust) of the bubbles. The entrained aeration gas bubbles 6 travel in the direction of the flow of the wine until they reverse direction and rise upwardly to the top of the vertical pipe section 4. The aeration gas bubbles 6 expand as they rise upwardly against the flow of the wine to the top of the vertical pipe section 4.
Fine aeration gas bubbles 6 are created by the diffuser 5, typically measuring in the order of around ~0.5mm in diameter initially, which provide a large surface area for oxygen to dissolve into the wine. As the 02 dissolves into the wine it then reacts with the compounds and other chemistry in the wine.
Dissolved 02 that has not reacted with the wine, unreacted 02, is removed from solution by the nitrogen (or argon) content in the gas, through an action known as sparging.
The wine continues to flow down the vertical pipe section 4 where it then travels horizontally into a horizontal pipe section 7. Any residual gas bubbles 8 that remain entrained in the wine rise up vertically and are collected in a gas trap section 9. This residual gas may be vented via a valve 24. Valve 24 is shown as a pressure release valve but could equally be a release valve or a gas permeable membrane, for instance a hydrophobic membrane.
The treated wine continues to travel horizontally and exits this section via an outlet pipe 10 to a pump 11, where it then exits the GRS 50. The treated wine may then be sent for bottling or returned to a storage vessel until it is ready for further treatment or to be bottled. Some of the stored wine may be kept for a period of time to mature further or, it may be used in dosage, blending and other stages of wine making.
The aeration gas counterflow arrangement established within a designated aeration treatment zone shown in Figure 2 ensures a consistent aeration dosage, with unreacted oxygen within that zone being sparged away from the direction of travel of the wine flow by the inert gas, e.g., nitrogen, thereby avoiding unwanted additional oxygen reactions. In the example of a pre-bottling treatment, the wine is then ready for bottling immediately after leaving the system having been correctly dosed with aeration gas.
It will be understood that the height of the column of wine within the vertical pipe section 4 can be adjusted through selection of the height or diameter of the vertical pipe section. The vertical pipe section 4 could be telescopically adjustable or tiltable. The diameter of the pipe section 4 may vary across its length. In some embodiments, the pipe section may be non-contiguous i.e., split over a number of vertically stepped sections.
Likewise, the position of each gas diffuser 5 within the vertical pipe section 4 may be raised or lowered.
The column of the vertical pipe section 4 from the top surface of the wine 16 to the base section 17, where the vast majority of the aeration gas bubbles turn back and travel up the vertical pipe section 4 towards the surface, is known as the reaction zone (RZ) or gas treatment zone.
In preferred embodiments, a material 18 such as stainless-steel wire wool or other suitable material(s) is placed into the RZ to help prevent foaming of the wine. The material 18 could also incorporate a quantity of iron or copper to further aid chemical reactions within the wine.
In some embodiments, oak chips 19 or other additional ingredients can be placed in the RZ. The aeration gas bubbles 6 and wine pass through the oak chips 19, reacting with and drawing out properties from within the chips, such as tannins.
Remnants of the aeration gas 6 (including remnants of the aeration gas that have come out of solution) rises to the top of the vertical pipe section 4 and can accumulate at or around point 20. It can then exit the vertical pipe section 4 via a valve 21. Valve 21 is shown as a pressure release valve but could equally be a release valve or a gas permeable membrane, for instance a hydrophobic membrane. Alternatively, the top of the vertical pipe section 4 could simply be open to the surrounding atmosphere to vent remnants of the aeration gas.
A mixture of aeration gas and wine, typically in the form of a foam, may also exit the vertical pipe section 4 via an outlet pipe 22 governed by a valve 28, where it can be sent back to the original storage vessel 1 (or, if required, to a different storage vessel). This foam will naturally dissipate across the surface of the wine in the storage vessel and thereby act as an inert protective blanket against unwanted atmospheric oxidation. Additionally, any volatiles that have been released from the wine during processing within the GRS 50 may be captured within the foam and subsequently dissolved back into the wine and returned to the storage vessel, thereby reducing volatile aroma loss. Alternatively, the overspill of wine can simply be drained or stored for further use. The pressure within the GRS 50 may be regulated or it could be kept broadly at atmospheric pressure. A higher than atmospheric pressure within the system may help to increase the solubility of the aeration gas into the wine. The temperature of the wine can also be controlled to affect the take-up rate of the 02 and other characteristics of the wine product, or to reduce volatile evaporation.
A wine sampling port 23 is provided so that a wine maker can take samples of the wine. Such sampling is then used to inform any adjustments needed to the system. Other sampling ports (not shown) may be used to sample wine at various points in the system.
An oxygen meter 29 can be used to read the dissolved oxygen levels within the wine product prior to treatment. A further oxygen meter 30 can be used to read the dissolved oxygen levels within the treated wine product. Comparisons can then be made and then used to inform any adjustments needed to the system.
The system can be controlled through appropriate adjustments as follows:
• the temperature of the wine;
• the temperature of the gas;
• the percentage of 02 within the mix;
• the volume of flow of gas can be adjusted by valve 13;
• the volume of flow of the wine can be adjusted via the pump 2 and/or pump 11;
• the pumps 2 and 11 may be used separately or together;
• the respective flow rates of the pumps 2 and 11 can be varied;
• the RZ can be altered by adjustment of the flow of wine via pumps 2 and 11;
• the height of the column of wine in the vertical pipe section 4 can be adjusted to alter the total volume of wine in contact with the gas bubbles;
• the diameter of the vertical pipe section 4 can be selected along with its shape;
• the height of the vertical pipe section 4 can be selected as well as its diameter;
• the flow rate of any overspill foam can be adjusted; and,
• the pressure within the GRS 50.
An example of the settings for an experimental system for the GRS 50 of Figure 2, is given below in Table 1. Various system parameters can be altered manually, semi automatically or even automatically using feedback control, and a feedback control system 31 may be provided for this purpose. They may be adjusted based upon the measurements taken from one or more locations within the system.
System parameters which can be adjusted to control an aeration dosage include (but are not limited to) :
• wine temperature;
• gas temperature;
• wine flow rate;
• aeration gas flow rate;
• GRS 50 pressure
• aeration gas composition; and,
• exposure (dwell) time.
Dosing of the wine may be effective to modify one or more of the following measurable characteristics of the wine product:
• titratable acidity;
• PH;
• dissolved oxygen;
• aroma;
• taste;
• level of condensed tannins;
• level of monomeric tannins;
• level of anthocyanins;
• colour density;
• free SO2;
• bound SO2;
• total SO2;
• total phenolics;
• total hydroxycinnamic acids;
• total flavonoids;
• Somers Chemical Age 1;
• Somers Chemical Age 2; and,
• Pigmentation.
Wine can be sampled before treatment and tested using industry standard tests such as the Modified Somers Method to determine the ratio of monomeric and polymerised phenolics. The wine can be sampled again after treatment to determine the increase in polymerisation and adjustments made accordingly dependent upon the result the wine maker requires.
Other tests that can be performed include such tests as total, free and bound SO2, PH, dissolved oxygen, acetaldehyde and colour. Taste, smell, feel and appearance tests may also be performed. The results of these and other tests or measurements may be used to adjust the system.
The following are examples of measurements of the wine that can be taken in situ\
• dissolved oxygen;
• temperature;
• PH;
• titratable acidity; and,
• colour.
Other measurements can be taken ex vivo including :
• phenolic compound composition;
• SO2 Levels;
• condensed tannins; and,
• monomeric tannins.
An example of a device that can be used to measure tannins is a High-performance liquid chromatograph (HPLC).
Table 1
Table 2 below shows the results of these experimental settings when used to treat a sample body of red wine. Table 2
The red wine's titratable acidity went from 5.013g/l in the untreated wine to 4.875g/l in the treated wine. There was no change in the PH which remained at 3.688. Condensed Tannins (Epicatechin) went from 30.754 mg/l in the untreated wine to 32.054 mg/l in the treated wine. Anthocyanins went from 107.556 mg/l in the untreated wine to 75.157 mg/l in the treated wine. Colour Density went from 6.765 au in the untreated wine to 7.168 au in the treated wine. The treatment positively correlated with higher condensed tannins and higher colour density against the untreated wine.
Table 3 below shows results of the same experimental settings when used to treat a body of white wine.
Table 3
The white wine's titratable acidity went from 7.35g/l in the untreated wine to 7.05g/l in the treated wine. Free SO2 went from 27.2 to 24. Bound SO2 went from 68.8 to 67.2. Total SO2 went from 96 to 91.2. Total Phenolics went from 1.892 to 2.216. Total Hydroxycinnamic acids went from 2.74 to 2.998. Total Flavonoids went from 0.065533 to 0.21733. Brown Pigments went from 0.114 to 0.06. Figure 3 shows a simplified schematic of an alternative gas injection apparatus suitable for use in the GRS 50 in Figure 2 for providing the aeration gas. In this example, pure 02 gas stored in gas cylinder 12 is introduced via a first gas diffuser 5, whilst a flow of inert sparging gas from a gas cylinder 32, such as N2, is introduced via a separate gas diffuser stone 5A to create a combined volume of micro-bubbles 6 of aeration gas. The respective flow rates of the two gases can be controlled to effect various levels of solubility, reaction and 02 removal or addition. The distance between and relative positioning of the diffusers 5 can be adjusted.
Figure 4 shows a simplified schematic an alternative gas injection arrangement for use in the GRS 50 of Figure 2 for providing the aeration gas. In this example, gas cylinder 12 contains 100% N2 and a separate gas cylinder 33 contains 100% 02. The 02 could be regulated into the flow of the N2 to achieve similar or the same result as premixing both gases or using a source of vitiated air. This would allow the percentage of 02 to be altered more easily.
Figure 5 shows yet another alternative gas injection arrangement for use in the GRS 50 of Figure 2 for providing the aeration gas, where a gas cylinder 12 contains N2 and atmospheric air is entrained into the flow by means of a venturi 26. Alternatively, a pump (not shown) can be provided to introduce atmospheric air into the flow of N2 as to achieve the desired mix of vitiated air for the purpose of aeration.
Figures 6 to 8 show further examples of GRS arrangements for use in a wine treatment system in accordance with the present invention each of which incorporates multiple reaction zones (RZ) i.e., have multiple vertically disposed pipe sections. These designs allow for significantly higher throughput and processing of the wine product.
Similar to the example in Figure 2, in the system illustrated in Figure 6, untreated wine is held in a storage vessel (not shown) prior to treatment. Depending on the relevant stage of wine production, the storage vessel may be a wine tank or a wine barrel. For convenience, the same reference numerals used in Figure 2 are used in these figures.
Wine enters the GRS 50 via a pump 2, which may be a peristaltic pump, which allows the flow rate of the wine to be accurately set. Wine flows horizontally through an inlet pipe 3 and then into a plurality (in this case 3) vertically aligned pipe sections 4 of the GRS 50 arranged in a linearly distributed configuration, each of which provides a reaction zone (RZ) for dosing of a flow of wine product. At each inlet, flow regulators 100 can be used to balance the flow of wine. An aeration gas is introduced from a gas storage vessel 12 into the vertical pipe sections 4 below the level of their respective inlet pipes 3 via gas diffusers 5. More than one gas diffuser may be employed per vertical pipe section 4, each either carrying the same aeration gas or a different gas which collectively forms the aeration gas.
The flow of aeration gas from the gas storage vessel 12 is regulated by a regulator valve 13 and passes through a flow meter 14. It is coupled to the gas diffusers 5 along a gas transport pipe 15. The gas supply to each gas diffuser 5 can be further regulated by a gas regulator 101.
Alternatively, the respective inlet gas diffusers 5 could be fed by separate gas storage vessels and regulated with regulator valves (not shown).
The wine continues to flow down the vertical pipe sections 4 where it then travels horizontally into a horizontal pipe section 7. Any residual aeration gas bubbles (not shown) that remain entrained in the wine rise up vertically and are collected in respective gas trap sections 9. Residual aeration gas or foam may be vented via a valve (not shown).
The treated wine continues to travel horizontally and exits this section via an outlet pipe 10 to a pump 11, where it then exits the GRS 50. The treated wine may then be sent for bottling or returned to a storage vessel until it is ready to be bottled. Some of the stored wine may be kept for a period of time to mature further or, it may be used in dosage, blending and other stages of wine making.
In the example shown in Figure 7, wine flows horizontally through an inlet pipe 3 and then into a plurality (in this case 2) of vertically aligned pipe sections 4 of a GRS 50 arranged in a linearly distributed configuration either side of a single gas trap section 9. Each vertical pipe section provides a reaction zone (RZ) for dosing a flow of wine product as it flows to the outlet pipe 10. At each inlet, flow regulators 100 can be used to balance the flow of wine. An aeration gas is introduced to the vertical pipe sections 4 below the level of their respective inlet pipes 3 via gas diffusers. Again, more than one gas diffuser 5 may be employed per vertical pipe section 4, each either carrying the same aeration gas or a different gas which collectively forms the aeration gas.
Aeration gas is obtained from a gas storage vessel 12, whose flow is regulated by a regulator valve 13 and passes through a flow meter 14. It is coupled to the gas diffusers 5 along a gas transport pipe 15. The gas to each gas diffuser 5 can be further regulated by a gas regulator 101.
Alternatively, the respective inlet gas diffusers 5 could be fed by separate gas storage vessels and regulated with regulator valves (not shown).
The wine continues to flow down the vertical pipe sections 4 where it then travels horizontally into a horizontal pipe section 7. Residual aeration gas bubbles (not shown) that remain entrained in the wine rise up vertically and are collected in gas trap section 9 shared by the vertical pipe sections 4. This residual aeration gas or foam may be vented via a valve (not shown).
The treated wine then continues to travel vertically downwards and then horizontally along a pipe section and exits via an outlet pipe 10 to a pump 11, where it then exits the GRS 50.
Figure 8 is a plan view of another example of a GRS 50 having a clustered arrangement of vertical pipe sections 4 (in this case 8) which are radially distributed around a single gas trap zone 9. In the same manner as for the example shown in Figure 7, wine flows from a tank (not shown) through the GRS 50 to the outlet pipe 10 via the vertical pipe sections 4, each of which provides a reaction zone (RZ) for dosing a flow of wine product with an aeration gas from a gas storage vessel 12 as it travels to the outlet pipe 10.
In some embodiments, the system may include an array of two or more such GRS 50 having this clustered arrangement.
Some of the potential commercial advantages of the wine making process and systems described above will now be discussed.
Embodiments of the present invention make it possible to use the complete extraction of juice from the grape, in contrast to known wine making processes which discard this as waste product. This is possible because the process described above accelerates the natural aging of the wine over a very short period of time, allowing even high- extraction levels to be processed, thereby significantly reducing costs.
Additionally, producing wine in this short time frame also leads to significant energy savings and attendant costs within the winery from reduced energy consumption associated with the heating, cooling and lighting required over a shortened period of as little as 3 to 4 months.
Traditionally, when wine is produced it is left for an average of 12 months to age and mature before sale, again contributing to cost. Wine makers often do not have the storage capacity within their own winery so pay for 3rd party off-site storage. Reducing the time taken to produce wine using the process described above significantly reduces these contributory costs
Winemakers are often operating in a constrained cash flow environment with significant quantities of cash tied up in stock that is not ready for sale. They often employ asset- backed finance as a way of freeing up cash from their stock. This is costly and further reduces their profit margins. The process described above means that finished wine can reach the consumer market far more quickly than would traditionally be possible, thereby alleviating this problem.
Traditionally aged wines require little to no additives, as time naturally refines their structure and balance. However, many winemakers cannot afford extended aging and instead rely on costly additives, such as binding agents and astringency-masking compounds like gum Arabic, to accelerate the process. Recent changes to certain product labeling laws now require winemakers to disclose these additives, aligning with growing consumer demand for cleaner, more transparent products.
The process described above enhances wine quality naturally, significantly reducing - and in many cases eliminating - the need for these additives, allowing winemakers to produce cleaner, more authentic wines.

Claims

1. A method for producing wine comprising dosing a flowing body of a wine product with a stream of bubbles of a gas mixture to promote aeration of the wine product during production, wherein the gas mixture comprises an inert sparging gas and between 0.3% and 10% by volume of oxygen, preferably between 0.5% and 3% by volume of oxygen, and more preferably around 1.5% by volume of oxygen.
2. A method according to claim 1, wherein the inert sparging gas comprises nitrogen.
3. A method according to claim 1 or 2, wherein the gas mixture comprises vitiated air.
4. A method according to claim 1 or 2, wherein the gas mixture is air which has been pressurised using an inert sparging gas, or obtained by mixing oxygen with an inert gas, which may either be pre-mixed within a single vessel, obtained through gas entrainment of air using an inert carrier gas, or mixed in situ when feeding from multiple sources of gas.
5. A method according to any preceding claim, comprising the step of introducing a flow of the wine product through one or more aeration treatment zones within a gas reactor system with a counterflowing stream of bubbles of a gas mixture.
6. A method according to claim 5, wherein the flow of wine product is obtained from a wine vessel, preferably a wine tank or a wine barrel.
7. A method according to any preceding claim, comprising the step of directing a flow of aerated wine product to a vessel for storage, the vessel being selected from a wine bottle, a wine barrel and a wine tank.
8. A method according to any preceding claim, wherein the wine product is taken at a stage of production selected from one or more of fermentation, maturation, barrel dosage or other storage stage, blending and bottling.
9. A method according to any preceding claim, comprising the step of adjusting one or more of the following controllable settings to control an aeration dosage: i. wine temperature; ii. gas temperature; iii. wine flow rate; iv. aeration gas flow rate; v. aeration gas composition; and, vi. exposure (dwell) time.
10. A method according to any preceding claim, wherein the dosing of the wine is effective to modify one or more of the following measurable characteristics of the wine product: i. titratable acidity; ii. PH; iii. level of condensed tannins; iv. level of monomeric tannins; v. level of anthocyanin; vi. colour density; vii. aroma; viii. taste; ix. free SO2; x. bound SO2; xi. total SO2; xii. total phenolics; xiii. total hydroxycinnamic acids; xiv. total flavonoids; xv. Somers Chemical Age 1; xvi. Somers Chemical Age 2; and, xvii. pigmentation.
11. A method according to claim 10 when dependent on claim 9, comprising the step of using feedback control of one or more of the controllable settings to achieve a desired level of one or more of the measurable characteristics of the wine.
12. A method according to claim 11, wherein the feedback control is at least partially automated.
13. A method according to claim 11 or 12, comprising running an initial test phase on a sample of the wine product for determining a set of controllable characteristics to achieve a set of desired wine characteristics for the wine product, to be applied during a subsequent production phase.
14. A system for aerating a wine product during the production of wine, comprising: a housing for receiving a flow of the wine product, the housing having a gas reactor system comprising at least one aeration treatment zone, a wine input port coupled to a proximal end of the aeration treatment zone, and a wine output port coupled to a distal end of the aeration treatment zone; and, a gas introducer apparatus positioned within the aeration treatment zone and adapted to be coupled to a source of aeration gas for introducing a counterflowing stream of aeration gas bubbles in the wine product as it flows through the aeration treatment zone to the wine output port, thereby to aerate the wine product.
15. A system according to claim 14, further comprising a source of aeration gas, wherein the aeration gas comprises an inert carrier gas mixed with between 0.3% and 10% by volume of oxygen, preferably between 0.5% and 3% by volume of oxygen, and more preferably around 1.5% by volume of oxygen.
16. A system according to claim 14 or 15, wherein the aeration gas is vitiated air, preferably air which has been pressurised using an inert sparging gas.
17. A system according to any of claims 14 to 16, wherein the housing comprises one or more gas traps for venting excess aeration gas.
18. A system according to any of claims 14 to 17, further comprising at least one pump for creating a flow of wine.
19. A system according to any of claims 14 to 18, further comprising a feedback control system for feedback control of one or more controllable settings to achieve a desired level of one or more measurable characteristics of the wine product.
20. A system according to claim 19, wherein the controllable settings include one or more of: i. wine temperature; ii. gas temperature; iii. wine flow rate; iv. aeration gas flow rate; v. aeration gas composition; and, vi. exposure (dwell) time.
21. A system according to any of claims 14 to 20, comprising one or more vertically aligned pipes providing one or more gas treatment zones for dosing a flow of wine with an aeration gas, the vertical pipes being coupled to the wine input port and the wine output port, each vertical pipe provided with a respective gas introducer apparatus and coupled to a gas trap.
22. A system according to claim 21, wherein the gas treatment zones share a common gas trap.
23. A system according to claim 21 or 22, in which the vertical pipes are arranged in clustered configuration, preferably radially distributed around a gas trap.
24. A method for producing wine comprising dosing a flowing body of a wine product within an aeration treatment zone with a counterflowing stream of bubbles of a gas mixture to promote aeration of the wine product during production, wherein the gas mixture comprises an inert sparging gas and between 0.5% and 5% by volume of oxygen, preferably no more than 3% by volume of oxygen, and more preferably around 1.5% by volume of oxygen.
25. A method according to claim 24, in which the bubbles are introduced into the aeration treatment zone via a bubble diffuser so as to rise upwardly under their own upthrust relative to a downward flow of the wine product through the aeration treatment zone.
26. A method for producing wine comprising dosing a body of a wine product during production as it flows vertically within an aeration treatment zone with a stream of bubbles of a gas mixture to promote aeration of the wine product as the gas bubbles rise upwardly within the aeration treatment zone opposite to the direction of flow of the wine product, wherein the gas mixture comprises an inert sparging gas and between 0.5% and 3% by volume of oxygen.
PCT/GB2025/050984 2024-05-13 2025-05-07 A system and process for treating wine Pending WO2025238337A1 (en)

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GB2406752.2A GB2633889B (en) 2024-05-13 2024-05-13 A system and process for treating wine
GBGB2504234.2A GB202504234D0 (en) 2025-03-23 2025-03-23 A system and process for treating wine
GB2504234.2 2025-03-23

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Citations (7)

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Publication number Priority date Publication date Assignee Title
WO2008148729A2 (en) * 2007-06-07 2008-12-11 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude An improved sparging assembly and sparging method
ITVR20090061A1 (en) * 2009-05-05 2010-11-06 Luca Zavarise PROCEDURE AND PLANT FOR THE TREATMENT OF TWO FLUIDS
US20110070331A1 (en) * 2007-09-06 2011-03-24 Ultra Maturation, Llc Accelerating Aging of Ethanol-Based Beverages
US20110268856A1 (en) * 2008-10-29 2011-11-03 Michael Paetzold Method for maturing wine and device for implementing same
US20150203801A1 (en) * 2012-07-25 2015-07-23 Mecanica Logroñesa 71, S.L. Fermentation method and apparatus
WO2016073744A1 (en) * 2014-11-05 2016-05-12 Max Mackenzie Gas-infused fluids and methods of making and using same
CN112368364A (en) * 2018-06-18 2021-02-12 科莱恩产品 (德国) 公司 Method for dealcoholizing a beverage

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008148729A2 (en) * 2007-06-07 2008-12-11 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude An improved sparging assembly and sparging method
US20110070331A1 (en) * 2007-09-06 2011-03-24 Ultra Maturation, Llc Accelerating Aging of Ethanol-Based Beverages
US20110268856A1 (en) * 2008-10-29 2011-11-03 Michael Paetzold Method for maturing wine and device for implementing same
ITVR20090061A1 (en) * 2009-05-05 2010-11-06 Luca Zavarise PROCEDURE AND PLANT FOR THE TREATMENT OF TWO FLUIDS
US20150203801A1 (en) * 2012-07-25 2015-07-23 Mecanica Logroñesa 71, S.L. Fermentation method and apparatus
WO2016073744A1 (en) * 2014-11-05 2016-05-12 Max Mackenzie Gas-infused fluids and methods of making and using same
CN112368364A (en) * 2018-06-18 2021-02-12 科莱恩产品 (德国) 公司 Method for dealcoholizing a beverage

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