WO2025213951A1 - Battery cell, battery, energy storage device, and electric device - Google Patents
Battery cell, battery, energy storage device, and electric deviceInfo
- Publication number
- WO2025213951A1 WO2025213951A1 PCT/CN2025/077068 CN2025077068W WO2025213951A1 WO 2025213951 A1 WO2025213951 A1 WO 2025213951A1 CN 2025077068 W CN2025077068 W CN 2025077068W WO 2025213951 A1 WO2025213951 A1 WO 2025213951A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wall
- battery cell
- electrode terminal
- hole
- insulating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/574—Devices or arrangements for the interruption of current
- H01M50/583—Devices or arrangements for the interruption of current in response to current, e.g. fuses
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
- H01M50/586—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries inside the batteries, e.g. incorrect connections of electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
- H01M50/59—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
- H01M50/593—Spacers; Insulating plates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present application relates to the field of battery technology, and in particular to a battery cell, a battery, an energy storage device, and an electrical device.
- the present application provides a battery cell, a battery, an energy storage device and an electrical device.
- the technical solution provided in the present application can effectively improve the reliability of the battery.
- the present application provides a battery cell.
- the battery cell includes a housing, an electrode assembly, a first electrode terminal, and a first insulating portion.
- the housing has a first wall.
- the electrode assembly is disposed within the housing.
- the first electrode terminal is disposed on the first wall and electrically connected to the electrode assembly, and is used for inputting and outputting electrical energy.
- the first insulating portion is disposed between the first wall and the first electrode terminal to insulate and isolate the first electrode terminal from the first wall.
- the first wall and the first electrode terminal can be effectively insulated and isolated, reducing the risk of internal short circuits in the battery cells due to a short circuit between the first wall and the first electrode terminal, thereby enhancing battery reliability.
- providing the first insulating portion between the first wall and the first electrode terminal can effectively reduce the risk of thermal runaway of the energy storage device due to the remaining battery cells in the battery running out of control, causing the outer casing to be charged with high voltage, resulting in the high voltage electricity flowing through the first wall and the electrode terminal, causing an internal short circuit in the battery cells.
- the battery cell further includes a first deformable member electrically connected to the first wall, and the first deformable member is configured to be deformable to contact the first electrode terminal to electrically connect the first electrode terminal to the first wall.
- the first deformable member when the internal pressure of the battery cell reaches a certain level, for example, a first threshold value, the first deformable member can be deformed to contact the first electrode terminal, thereby electrically connecting the first electrode terminal to the first wall, thereby realizing an internal short circuit in the battery cell, so that the electrical connection components inside the battery cell are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell, thereby playing a role in overcharge protection, and playing a role in reducing the risk of thermal runaway of the battery cell, thereby making the battery have higher reliability.
- a certain level for example, a first threshold value
- the first wall is formed with a first through hole and a second through hole
- the first electrode terminal passes through the first through hole
- the first deformable member closes the second through hole
- the first deformable member is configured to be deformable to partially pass through the second through hole to contact the first electrode terminal.
- the internal pressure of the battery cell when the internal pressure of the battery cell reaches a certain level, such as the first threshold value, the internal pressure of the battery cell can act on the first deformable member, so that the first deformable member deforms toward the outside of the first wall to effectively contact the first part of the first electrode terminal, thereby effectively realizing an internal short circuit of the battery cell, so that the electrical connection components inside the battery cell are melted due to the large current generated by the short circuit, so as to cut off the charge and discharge circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
- a certain level such as the first threshold value
- a projection of a first portion of the first electrode terminal located outside the first wall at least partially overlaps with a projection of the first deformable member.
- the first deformable member corresponding to the first part along the thickness direction of the first wall, it is possible to quickly contact the first part with a smaller deformation amount when the internal pressure of the battery cell reaches a certain level, such as the first threshold value, so that the first electrode terminal and the first wall are quickly electrically connected, thereby effectively realizing an internal short circuit of the battery cell, so that the electrical connection components inside the battery cell are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
- a certain level such as the first threshold value
- the first wall includes a main body portion and a first reinforcement portion connected to each other, and the first portion is provided on the first reinforcement portion.
- the overall strength of the first wall can be improved, and the risk of deformation of the first wall due to internal pressure of the battery cell or external impact, which causes the first deformable member to be unable to effectively contact the first part to conduct electricity between the first electrode terminal and the first wall, can be reduced.
- the first deformable member can effectively contact the first electrode terminal under abuse conditions such as overcharging of the battery cell, thereby effectively playing the role of overcharging protection, reducing the risk of thermal runaway of the battery cell, and making the battery have higher reliability.
- the length of the first wall is greater than or equal to 150 mm, and the width of the first wall is greater than or equal to 45 mm.
- the first reinforcement portion includes a first protrusion, which protrudes from a surface of the main body portion along the thickness direction of the first wall.
- the first reinforcement portion further includes a first recessed portion, which is arranged on another surface of the main body portion along the thickness direction of the first wall, and the first recessed portion is arranged opposite to the first protruding portion.
- the first recess is provided at a position corresponding to the first protrusion.
- the difficulty of forming the first protrusion can be reduced and material costs can be saved.
- the space of the first recess can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell.
- the space of the first recess can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
- the first protrusion is located on the outside of the first wall, and a first positioning groove is formed on the first protrusion.
- the first positioning groove accommodates the first part to limit the movement of the first part.
- the first electrode terminal can be effectively positioned and the displacement of the first electrode terminal can be limited.
- the risk of the first electrode terminal being separated from the internal electrical connection component of the battery cell and causing internal short circuit of the battery cell is reduced.
- the first electrode terminal can be effectively cooperated with the first deformable member to play the role of overcharge protection and improve the reliability of the battery.
- the first protrusion is located on the outside of the first wall, and along the thickness direction of the first wall, the dimension of the first protrusion protruding from the main body is greater than or equal to 0.1 mm and less than or equal to 5 mm.
- the protrusion of the first protrusion from the main body by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.1mm, the structural strength of the first wall can be effectively improved, allowing the first deformable member to effectively contact the first electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the first threshold, to provide overcharge protection, thereby improving the reliability of the battery.
- the protrusion of the first protrusion from the main body By setting the protrusion of the first protrusion from the main body to be less than or equal to 5mm, the space occupied by the first protrusion can be reduced, thereby reducing the impact on the battery's volumetric energy density.
- the protrusion of the first protrusion from the main body by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.1mm and less than or equal to 5mm, the reliability of the battery cell's overcharge protection and the battery's volumetric energy density can be balanced.
- the dimension of the first protrusion protruding from the main body is greater than or equal to 0.5 mm and less than or equal to 3 mm.
- the protrusion of the first protrusion from the main body by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.5mm, the structural strength of the first wall is further improved, allowing the first deformable member to efficiently contact the first electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the first threshold, thereby providing overcharge protection and thereby improving the reliability of the battery.
- the protrusion of the first protrusion from the main body By setting the protrusion of the first protrusion from the main body to be less than or equal to 3mm, the space occupied by the first protrusion can be effectively reduced, thereby reducing the impact on the battery's volumetric energy density.
- the protrusion of the first protrusion from the main body by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.5mm and less than or equal to 3mm, the reliability of the battery cell's overcharge protection and the battery's volumetric energy density can be balanced.
- the first insulating portion includes a first insulating member, at least a portion of which is arranged between a first portion of the first electrode terminal located on the outside of the first wall and the first wall, and the first insulating member is formed with a third through hole and a fourth through hole, and along the thickness direction of the first wall, the third through hole is arranged opposite to the first through hole, and the fourth through hole is arranged opposite to the second through hole.
- the first insulating member has a simple structure.
- the first electrode terminal is allowed to pass through the third through hole, so that the first electrode terminal is electrically connected to the electrode assembly and external charging and discharging is realized.
- the first deformable member is allowed to deform through the fourth through hole so as to contact the first part to realize overcharge protection.
- the first insulating member can effectively insulate and isolate the first part and the first wall, reducing the risk of internal short circuit of the battery cell due to short circuit between the first part and the first wall, thereby making the battery highly reliable.
- the first insulating member includes a first body and a first flange, the first body is located between the first part and the first wall, the first flange is arranged on the surface of the first body facing away from the first wall, and the first flange surrounds at least part of the outer peripheral surface of the first part.
- the first wall and the first part can be effectively insulated and isolated, so that there is a longer creepage distance between the first part and the first wall, and the first insulating member has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell due to short circuit between the first wall and the first electrode terminal, so that the battery has high reliability.
- the first insulating member further includes a second flange, which is disposed around the third through hole and is located between a hole wall of the first through hole and the first electrode terminal.
- the hole wall of the first through hole and the first electrode terminal can be effectively insulated and isolated, reducing the risk of the first electrode terminal contacting the hole wall of the first through hole and causing internal short circuit in the battery cell, thereby effectively improving the reliability of the battery.
- the battery cell further includes a second electrode terminal, a second insulating portion, and a second deformable member.
- the second electrode terminal is disposed on the first wall and electrically connected to the electrode assembly.
- the second electrode terminal is used for input and output of electrical energy, and the second electrode terminal and the first electrode terminal have opposite polarities.
- the second insulating portion is disposed between the first wall and the second electrode terminal to insulate and isolate the second electrode terminal from the first wall.
- the second deformable member is electrically connected to the first wall and is configured to be deformable to contact the second electrode terminal to electrically connect the second electrode terminal to the first wall.
- the first wall and the second electrode terminal can be effectively insulated and isolated, thereby reducing the risk of internal short circuit of the battery cell due to short circuit between the first wall and the second electrode terminal, and making the battery highly reliable;
- a second deformable member when the internal pressure of the battery cell reaches a certain level, such as a second threshold value, the second deformable member is deformed to contact the second electrode terminal, thereby electrically connecting the second electrode terminal to the second wall, and cooperating with the short circuit between the first deformable member and the first electrode terminal, the electrical connection component inside the battery cell is not short-circuited.
- the large current generated by the short circuit causes the fuse to cut off the charge and discharge circuit of the battery cell, thereby playing a role in overcharge protection and reducing the risk of thermal runaway of the battery cell, thereby making the battery have higher reliability; on the other hand, because the first electrode terminal and the second electrode terminal are both insulated and isolated from the first wall under non-abuse conditions, the outer shell of the battery cell can be uncharged, which is conducive to the battery cell forming an energy storage device, so that the risk of ignition and breakdown between two adjacent battery cells in the energy storage device is small. At the same time, by providing the second deformable member, the overcharge protection function can be effectively achieved, so that the energy storage device has high reliability.
- the second electrode terminal is a negative electrode terminal, so that the minimum pressure value for deformation of the second deformation member is greater than the minimum pressure value for deformation of the first deformation member.
- the second deforming member when the second electrode terminal is the negative electrode terminal, by making the minimum pressure value that causes the second deforming member to deform greater than the minimum pressure value that causes the first deforming member to deform, the second deforming member can be deformed when the pressure inside the battery cell is greater than that of the first deforming member.
- the battery cell can have an overcharge protection function.
- it can reduce the risk of gas production inside the battery cell causing the second deforming member to flip over, resulting in the shell being negatively charged and corroded by the electrolyte under non-overcharge abuse conditions, thereby ensuring the integrity of the shell to a certain extent, reducing the risk of electrolyte leakage, and thus improving the reliability of the battery.
- the first wall is formed with a fifth through hole and a sixth through hole
- the second electrode terminal passes through the fifth through hole
- the second deformable member closes the sixth through hole
- the second deformable member is configured to be deformable to partially pass through the sixth through hole to contact the second electrode terminal.
- the internal pressure of the battery cell when the internal pressure of the battery cell reaches a certain level, such as the second threshold value, the internal pressure of the battery cell can act on the second deformable member, so that the second deformable member deforms toward the outside of the first wall to effectively contact the third part of the second electrode terminal, and cooperates with the first deformable member to contact the first electrode terminal, so that the electrical connection component inside the battery cell is melted due to the large current generated by the short circuit, so as to cut off the charging and discharging circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
- a certain level such as the second threshold value
- a projection of a third portion of the second electrode terminal located outside the first wall at least partially overlaps with a projection of the second deformable member.
- the third part can be quickly contacted with a smaller deformation amount, thereby quickly electrically connecting the second electrode terminal and the first wall, and cooperating with the first deformable member to contact the first electrode terminal, the electrical connection component inside the battery cell is melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
- the first wall includes a main body portion and a second reinforcement portion connected to each other, and the third portion of the second electrode terminal located outside the first wall is disposed on the second reinforcement portion.
- the overall strength of the first wall can be improved, and the risk of deformation of the first wall due to internal pressure of the battery cell or external impact, which causes the second deformable member to be unable to effectively contact the third part to conduct electricity between the second electrode terminal and the first wall, can be reduced.
- the second deformable member can effectively contact the second electrode terminal under abuse conditions such as overcharging of the battery cell, thereby effectively playing a role in overcharging protection, reducing the risk of thermal runaway of the battery cell, and making the battery have higher reliability.
- the second reinforcing portion includes a second protrusion protruding from a surface of the body portion along the thickness direction of the first wall.
- the second reinforcement portion further includes a second recessed portion, which is arranged on another surface of the main body portion along the thickness direction of the first wall, and the second recessed portion is arranged opposite to the second protruding portion.
- a second recess is provided at a position corresponding to the second protrusion.
- the difficulty of forming the second protrusion can be reduced and material costs can be saved.
- the space of the second recess can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell.
- the space of the second recess can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
- the second protrusion is located on the outside of the first wall, and a second positioning groove is formed on the second protrusion.
- the second positioning groove accommodates the third part to limit the movement of the third part.
- the second electrode terminal can be effectively positioned and the displacement of the second electrode terminal can be limited.
- the risk of the second electrode terminal being separated from the internal electrical connection component of the battery cell and causing internal short circuit of the battery cell is reduced.
- the second electrode terminal can be effectively cooperated with the second deformable member to play the role of overcharge protection and improve the reliability of the battery.
- the second protrusion is located on the outside of the first wall, and along the thickness direction of the first wall, the dimension of the second protrusion protruding from the main body is greater than or equal to 0.1 mm and less than or equal to 5 mm.
- the protrusion of the second protrusion from the main body by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.1mm, the structural strength of the first wall can be effectively improved, allowing the second deformable member to effectively contact the second electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the second threshold, to provide overcharge protection, thereby improving the reliability of the battery.
- the protrusion of the second protrusion from the main body By setting the protrusion of the second protrusion from the main body to be less than or equal to 5mm, the space occupied by the second protrusion can be reduced, thereby reducing the impact on the battery's volumetric energy density.
- the protrusion of the second protrusion from the main body by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.1mm and less than or equal to 5mm, the reliability of the battery cell overcharge protection and the battery's volumetric energy density can be balanced.
- the dimension of the second protrusion protruding from the main body is greater than or equal to 0.5 mm and less than or equal to 3 mm.
- the protrusion of the second protrusion from the main body by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.5mm, the structural strength of the first wall is further improved, allowing the second deformable member to effectively contact the second electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the second threshold, to provide overcharge protection, thereby improving the reliability of the battery.
- the protrusion of the second protrusion from the main body By setting the protrusion of the second protrusion from the main body to be less than or equal to 3mm, the space occupied by the second protrusion can be effectively reduced, thereby reducing the impact on the battery's volumetric energy density.
- the protrusion of the second protrusion from the main body by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.5mm and less than or equal to 3mm, the reliability of the battery cell overcharge protection and the volumetric energy density of the battery can be balanced.
- the second insulating portion includes a second insulating member, at least a portion of which is arranged between the third portion and the first wall, and the second insulating member is formed with a seventh through hole and an eighth through hole.
- the seventh through hole is arranged opposite to the fifth through hole
- the eighth through hole is arranged opposite to the sixth through hole.
- the second insulating member has a simple structure.
- the second electrode terminal is allowed to pass through the seventh through hole, so that the second electrode terminal is electrically connected to the electrode assembly and external charging and discharging is realized.
- the second deformable member is allowed to deform through the eighth through hole so as to contact the third part to achieve overcharge protection.
- the second insulating member can effectively insulate and isolate the third part and the first wall, reducing the risk of internal short circuit of the battery cell due to short circuit between the third part and the first wall, thereby making the battery highly reliable.
- the second insulating member includes a second body and a third flange, the second body is located between the third part and the first wall, the third flange is arranged on the surface of the second body facing away from the first wall, and the third flange surrounds at least part of the outer peripheral surface of the third part.
- the first wall and the third part can be effectively insulated and isolated, so that there is a longer creepage distance between the third part and the first wall, and the second insulating member has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell due to short circuit between the first wall and the second electrode terminal, thereby increasing the reliability of the battery.
- the second insulating member further includes a fourth flange, which is arranged around the seventh through hole and is located between the hole wall of the fifth through hole and the second electrode terminal.
- the hole wall of the fifth through hole and the second electrode terminal can be effectively insulated and isolated, reducing the risk of the second electrode terminal contacting the hole wall of the fifth through hole and causing internal short circuit in the battery cell, thereby effectively improving the reliability of the battery.
- the resistance value of the second insulating portion is greater than or equal to 200 megohms.
- the resistance value of the second insulating portion to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the second electrode terminal and the first wall can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the second insulating portion and conducting the first wall and the second electrode terminal, causing an internal short circuit in the battery cell, thereby making the energy storage device more reliable.
- the resistance value of the first insulating portion is greater than or equal to 200 megohms.
- the resistance value of the first insulating portion to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the first electrode terminal and the first wall can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the first insulating portion, connecting the first wall and the first electrode terminal, and causing an internal short circuit in the battery cell, thereby making the energy storage device more reliable.
- the housing includes a shell and an end cover, wherein the shell has an opening.
- the first wall is the end cover, which is connected to the shell and closes the opening.
- the shell structure is simple, which facilitates the assembly of battery cells and helps improve battery manufacturing efficiency.
- a first insulating layer is provided on the inner wall of the shell.
- the electrolyte inside the shell can be effectively insulated and isolated from the inner wall of the shell, thereby reducing the risk of the shell being corroded by the electrolyte and the risk of electrolytic wire leakage, making the battery more reliable.
- the first insulating layer is an insulating coating provided on the inner wall of the shell.
- the electrolyte and the shell can be effectively separated, the electrolyte ion path between the motor assembly and the shell can be cut off, and the risk of shell corrosion can be reduced;
- the first insulating layer can be efficiently formed on the inner wall of the shell by spraying or other methods, so that the manufacturing efficiency of the battery is high;
- the insulating coating has high mechanical strength, which can effectively reduce the puncture of metal particles introduced by the manufacturing process, resulting in electrical connection between the electrode assembly and the shell, causing the risk of internal short circuit of the battery cell or the risk of corrosion of the shell, so that the battery has high reliability.
- the inner wall of the shell includes a blank area and an insulating area connected in sequence, the insulating area is provided with a first insulating layer, the blank area is connected to the first wall, and the first direction is parallel to the first wall and points to the direction of the electrode assembly.
- the effect of the first insulating layer on the connection between the shell and the first wall can be reduced.
- the first wall and the shell are welded to each other, and by providing a blank area, the welding quality between the first wall and the shell can be improved, thereby improving the quality of the battery.
- the projection of the electrode assembly on the inner wall of the shell does not overlap with the blank area, and the second direction is perpendicular to the first direction.
- the thickness of the first insulating layer is greater than or equal to 60 ⁇ m and less than or equal to 200 ⁇ m.
- the first insulating layer can have high mechanical strength and insulation performance, effectively isolating the shell from the electrolyte, reducing the risk of the shell being corroded by the electrolyte due to negative charge, and thus making the battery more reliable.
- the first insulating layer can effectively reduce the internal space occupied by the battery cell, making the battery cell have a higher volumetric energy density, and thus the battery has a higher volumetric energy density.
- both battery reliability and volumetric energy density can be taken into account.
- the thickness of the first insulating layer is greater than or equal to 80 ⁇ m and less than or equal to 130 ⁇ m.
- the first insulating layer can further have higher mechanical strength and insulation performance, effectively isolating the shell and the electrolyte, reducing the risk of the shell being corroded by the electrolyte due to negative charge, and making the battery more reliable.
- the first insulating layer can further reduce the internal space occupied by the battery cell, making the battery cell have a higher volume energy density, and thus the battery has a higher volume energy density.
- the thickness of the first insulating layer to be greater than or equal to 80 ⁇ m and less than or equal to 130 ⁇ m, it is possible to effectively balance the reliability and volume energy density of the battery.
- a second insulating layer is provided on the outer surface of the shell.
- the shell can be effectively insulated and protected, reducing the risk of corrosion by the electrolyte due to negative charge of the shell, so that the battery has higher reliability.
- some embodiments of the present application provide a battery, comprising the battery cell provided in the first aspect of claim 1.
- some embodiments of the present application provide an energy storage device comprising the battery cell provided in the first aspect.
- some embodiments of the present application provide an electrical device, comprising the battery cell provided in the first aspect, wherein the battery cell is used to provide electrical energy.
- FIG1 is a schematic diagram of a vehicle in some embodiments of the present application.
- FIG2 is a schematic diagram of an energy storage device in some embodiments of the present application.
- FIG3 is an exploded perspective view of a battery in some embodiments of the present application.
- FIG4 is an exploded perspective view of a battery cell in some embodiments of the present application.
- FIG5 is a perspective exploded view of a partial structure of a battery cell in some embodiments of the present application.
- FIG6 is a top view of a partial structure of a battery cell in some embodiments of the present application.
- FIG7 is a cross-sectional view taken along the line A-A in FIG6 ;
- FIG8 is a schematic diagram of a first wall and a first electrode terminal in some embodiments of the present application.
- FIG9 is a schematic diagram of a first deformable member in some embodiments of the present application.
- FIG10 is a perspective view of a first wall in some embodiments of the present application.
- FIG11 is a schematic diagram of a partial structure of a first wall in some embodiments of the present application.
- FIG12 is a schematic diagram of a first wall and a second electrode terminal in some embodiments of the present application.
- FIG13 is a schematic diagram of a second deformable member in some embodiments of the present application.
- FIG14 is a partial schematic diagram of the first wall in some embodiments of the present application.
- FIG15 is a schematic diagram of a housing and an electrode assembly in some embodiments of the present application.
- FIG16 is a schematic diagram of a housing and a first insulating layer in some embodiments of the present application.
- FIG17 is a schematic diagram of the shell and the first insulating layer in some other embodiments of the present application.
- Icons 10 - battery cell; 11 - housing; 110 - first wall; 111 - housing; 1100 - first through hole; 1101 - second through hole; 1102 - fifth through hole; 1103 - sixth through hole; 110a - body; 110b - first reinforcement; 110b0 - first convex portion; 110b1 - first concave portion; 110b2 - first positioning groove; 110c - second reinforcement; 110c0 - second convex portion; 110c1 - second concave portion; 110c2 - second positioning groove; 12 - electrode assembly; 120 - first electrode tab; 121 - second electrode tab; 123 - first adapter; 124 - second adapter; 13 - first electrode terminal; 130 - first portion; 131 - second portion; 14 - first insulating portion; 140 - first insulating member; 1400 - first body; 14001 - third through hole; 14002 - fourth through hole; 1401 - first flange; 1402 - second flange
- references herein to "embodiments” mean that a particular feature, structure, or characteristic described in connection with the embodiments may be included in at least one embodiment of the present application.
- the appearance of this phrase in various places in the specification does not necessarily refer to the same embodiment, nor does it constitute an independent or alternative embodiment that is mutually exclusive of other embodiments. It is understood, both explicitly and implicitly, by those skilled in the art that the embodiments described herein may be combined with other embodiments.
- the term "and/or” is simply a description of the association relationship between associated objects, indicating that three relationships can exist.
- a and/or B can represent the following three situations: A exists, A and B exist at the same time, and B exists.
- the character "/" in this document generally indicates that the associated objects are in an "or" relationship.
- multiple refers to more than two (including two).
- multiple groups refers to more than two groups (including two groups), and “multiple pieces” refers to more than two pieces (including two pieces).
- battery cells may include lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-lithium-ion batteries, sodium-ion batteries or magnesium-ion batteries, etc., which are not limited in the embodiments of the present application.
- Battery cells may be rectangular or in other shapes, etc., which are not limited in the embodiments of the present application.
- the battery mentioned in the embodiments of the present application refers to a single physical module that includes one or more battery cells to provide higher voltage and capacity.
- the battery generally includes a casing for encapsulating one or more battery cells. The casing can prevent liquids or other foreign matter from affecting the charging or discharging of the battery cells.
- a battery cell includes an electrode assembly and an electrolyte.
- the electrode assembly consists of a positive electrode sheet, a negative electrode sheet, and a separator.
- a battery cell primarily operates by the movement (e.g., deintercalation) of metal ions between the positive and negative electrode sheets.
- the positive electrode sheet includes a positive current collector and a positive active material layer.
- the positive active material layer is coated on the surface of the positive electrode collector.
- the positive electrode collector not coated with the positive active material layer protrudes from the positive electrode collector coated with the positive active material layer, and the positive electrode collector not coated with the positive active material layer serves as the positive electrode tab.
- the positive electrode current collector can be made of aluminum, and the positive electrode active material can be lithium cobalt oxide, lithium iron phosphate, ternary lithium, or lithium manganese oxide.
- the negative electrode sheet includes a negative current collector and a negative active material layer. The negative active material layer is coated on the surface of the negative electrode collector. The negative electrode collector not coated with the negative active material layer protrudes from the negative electrode collector coated with the negative active material layer, and the negative electrode collector not coated with the negative active material layer serves as the negative electrode tab.
- the negative electrode current collector can be made of copper, and the negative electrode active material can be carbon or silicon, among others.
- the separator can be made of materials such as PP (polypropylene) or PE (polyethylene).
- the electrode assembly can be a wound or laminated structure, although the embodiments of the present application are not limited thereto.
- the battery cell also includes a housing, an electrode assembly and an electrolyte disposed inside the housing.
- the housing has a first wall, and the first wall is provided with an electrode terminal connected to the electrode assembly, and the electrode terminal is used for input and output of electrical energy.
- the operating voltage of batteries is getting higher and higher.
- the high voltage can easily conduct the first wall and the electrode terminal, causing an internal short circuit in the battery cell and affecting the reliability of the battery.
- the battery cell includes a housing, an electrode assembly, a first electrode terminal and a first insulating portion.
- the housing has a first wall.
- the electrode assembly is disposed within the housing.
- the first electrode terminal is disposed on the first wall and electrically connected to the electrode assembly, and the first electrode terminal is used for input and output of electrical energy.
- the first insulating portion is disposed between the first wall and the first electrode terminal to insulate and isolate the first electrode terminal from the first wall.
- the first wall and the first electrode terminal can be effectively insulated and isolated, reducing the risk of internal short circuits in the battery cells due to a short circuit between the first wall and the first electrode terminal, thereby enhancing battery reliability.
- providing the first insulating portion between the first wall and the first electrode terminal can effectively reduce the risk of thermal runaway of the energy storage device due to the remaining battery cells in the battery running out of control, causing the outer casing to be charged with high voltage, resulting in the high voltage electricity flowing through the first wall and the electrode terminal, causing an internal short circuit in the battery cells.
- the energy storage device may include an energy storage container, an energy storage cabinet, etc.
- the energy storage cabinet may include a cabinet body and one or more batteries disposed on the cabinet body.
- the electrical device can be a vehicle, a mobile phone, a portable device, a laptop computer, a ship, a spacecraft, an electric toy, an electric tool, etc.
- the vehicle can be a new energy vehicle, which can be a pure electric vehicle, a hybrid vehicle, or an extended-range vehicle, etc.
- the spacecraft includes airplanes, rockets, space shuttles, and spacecraft, etc.
- the electric toys include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, and electric airplane toys, etc.
- the electric tools include metal cutting electric tools, grinding electric tools, assembly electric tools, and railway electric tools, such as electric drills, electric grinders, electric wrenches, electric screwdrivers, electric hammers, impact drills, concrete vibrators, and electric planers, etc.
- the electrical devices in the embodiments of the present application include but are not limited to those mentioned above.
- FIG1 is a schematic diagram of a vehicle in some embodiments of the present application.
- a controller 200, a motor 300, and a battery 100 may be provided inside the vehicle 1000.
- the controller 200 is used to control the battery 100 to power the motor 300.
- the battery 100 may be provided at the bottom, front, or rear of the vehicle 1000.
- the battery 100 may be used to power the vehicle 1000.
- the battery 100 may serve as an operating power source for the vehicle 1000 and for the circuit system of the vehicle 1000, for example, for the starting, navigation, and operating power requirements of the vehicle 1000.
- the battery 100 may serve not only as an operating power source for the vehicle 1000, but also as a driving power source for the vehicle 1000, replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000.
- FIG2 is a schematic diagram of an energy storage device in some embodiments of the present application.
- the energy storage device 2000 may include a cabinet 2001 and a plurality of batteries 100.
- the plurality of batteries 100 may be disposed in the cabinet 2001.
- the plurality of batteries 100 may be connected in series, in parallel, or in a mixed manner.
- FIG3 is a three-dimensional exploded view of the battery 100 in some embodiments of the present application.
- the battery 100 includes a battery cell 10 and a housing 20, wherein the battery cell 10 is housed within the housing 20.
- the housing 20 is used to provide a storage space for the battery cell 10, and the housing 20 can adopt a variety of structures.
- the housing 20 can include a first housing portion 21 and a second housing portion 22, wherein the first housing portion 21 and the second housing portion 22 overlap each other, and the first housing portion 21 and the second housing portion 22 jointly define a storage space for accommodating the battery cell 10.
- the second housing portion 22 can be a hollow structure with one end open, and the first housing portion 21 can be a plate-like structure, with the first housing portion 21 overlapping the open side of the second housing portion 22, so that the first housing portion 21 and the second housing portion 22 jointly define a storage space; the first housing portion 21 and the second housing portion 22 can also be hollow structures with one end open, with the open side of the first housing portion 21 overlapping the open side of the second housing portion 22.
- the box body 20 formed by the first box body portion 21 and the second box body portion 22 can be in various shapes, such as a cylinder, a cuboid, etc.
- each battery cell 10 may be fixed to the case 20 via a connector (such as a bolt), or each battery cell 10 may be fixed to the case 20 by bonding.
- Figure 4 is a three-dimensional exploded view of the battery cell 10 in some embodiments of the present application
- Figure 5 is a three-dimensional exploded view of the local structure of the battery cell 10 in some embodiments of the present application
- Figure 6 is a top view of the local structure of the battery cell 10 in some embodiments of the present application
- Figure 7 is a cross-sectional view taken along the A-A direction in Figure 6
- Figure 8 is a schematic diagram of the first wall and the first electrode terminal in some embodiments of the present application.
- the battery cell 10 includes a housing 11, an electrode assembly 12, a first electrode terminal 13, and a first insulating portion 14.
- the housing 11 has a first wall 110.
- the electrode assembly 12 is disposed within the housing 11.
- the first electrode terminal 13 is disposed on the first wall 110 and electrically connected to the electrode assembly 12.
- the first electrode terminal 13 is used for inputting and outputting electrical energy.
- the first insulating portion 14 is disposed between the first wall 110 and the first electrode terminal 13 to insulate and isolate the first electrode terminal 13 from the first wall 110.
- the housing 11 is a component for accommodating the electrode assembly 12.
- the housing 11 can also be used to accommodate an electrolyte, such as an electrolyte.
- the housing 11 includes a shell 111 and an end cap.
- a accommodating cavity is formed inside the shell 111, and the accommodating cavity is used to accommodate the electrode assembly 12.
- the shell 111 has an opening connected to the accommodating cavity.
- the end cap is covered at the opening of the shell 111 and forms a sealed connection to form a sealed space for accommodating the electrode assembly 12 and the electrolyte.
- the end cap can be connected to the shell 111 by welding, bonding, clamping or other connection methods.
- the housing 11 may also include a bottom plate, and openings are respectively formed at both ends of the shell 111, one of the openings is closed by the end cap, and the other opening is closed by the bottom plate.
- the material of the shell 11 can be metal or a combination of metal and non-metal.
- the shell 11 can be made of metal, such as aluminum, copper, iron, steel or aluminum alloy; for example, part of the shell 11 can be made of metal, and the rest can be made of non-metal, such as the end cover of the shell 11 can be made of metal, and the shell 111 or other parts of the shell 11 can be made of non-metallic materials.
- the electrode assembly 12 when assembling the battery cell 10, the electrode assembly 12 may be placed in the housing 111 first, and the housing 111 may be filled with electrolyte, and then the end cap may be attached to the opening of the housing 111 to complete the assembly of the battery cell 10.
- the electrode assembly 12 when assembling the battery cell 10, the electrode assembly 12 may be placed in the housing 111 first, and then the end cap may be attached to the opening of the housing 111, and then the housing 111 may be filled with electrolyte through the injection hole on the end cap, and then the injection hole may be closed to complete the assembly of the battery cell 10.
- the housing 11 can have various shapes, such as a cylindrical or prismatic structure.
- the shape of the housing 11 can be determined based on the specific shape of the electrode assembly 12. For example, if the electrode assembly 12 has a cylindrical structure, a cylindrical housing 11 can be selected. If the electrode assembly 12 has a flat structure, the housing 11 can be square.
- First wall 110 is part of the housing 11. It can support first electrode terminal 13, ensuring a stable ground state for electrical energy input and output.
- first wall 110 can be part of housing 111, such as a side wall or bottom wall of housing 111.
- first wall 110 can serve as an end cap.
- the first electrode terminal 13 is a component mounted on the first wall 110.
- the first electrode terminal 13 is used to electrically connect to the electrode assembly 12 so that current flows into or out of the first electrode tab 120 through the first electrode terminal 13.
- the polarity of the first electrode terminal 13 and the first electrode tab 120 is the same.
- the first electrode terminal 13 is made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal.
- the first electrode terminal 13 can be connected to the first electrode tab 120 through a first adapter 123.
- the first electrode tab 120 of the electrode assembly 12 is composed of a plurality of first sub-tabs stacked together. After welding one end of the first adapter 123 to the first electrode tab 120, the other end of the first adapter 123 can be welded to the first electrode terminal 13.
- the first insulating portion 14 has a high resistance, insulating the first electrode terminal 13 from the first wall 110.
- the first electrode terminal 13 has an exposed first portion 130.
- the first insulating portion 14 can be disposed between the outer side of the first wall 110 and the first portion 130 to insulate the first electrode terminal 13 from the first wall 110.
- the first insulating portion 14 can cover the outer periphery of the first portion 130 to increase the creepage distance between the first electrode terminal 13 and the first wall 110.
- a first through-hole 1100 is formed in the first wall 110.
- the first electrode terminal 13 can pass through the first through-hole 1100 to form a first portion 130 on the outside and a second portion 131 on the inside.
- the first portion 130 is used to connect to an external electrical connection member, and the second portion 131 is used to electrically connect to the electrode assembly 12.
- the first insulating portion 14 has a third through-hole 14001 formed in correspondence with the first through-hole 1100 for the first electrode terminal 13 to pass through.
- a major portion of the first insulating portion 14 is located between the first portion 130 and the first wall 110, while some portion of the first insulating portion 14 may be located between the first through-hole 1100 and the first electrode terminal 13.
- first insulating portion 14 is located between the first portion 130 and the first wall 110, while some portion of the first insulating portion 14 may be located between the first through-hole 1100 and the first electrode terminal 13, with the remaining portion of the first insulating portion 14 further located between the first wall 110 and the second portion 131.
- the first insulating portion 14 may be in a plate shape as a whole, and its two opposite surfaces are relatively flat so as to be stably positioned between the first electrode terminal 13 and the first wall 110 .
- the first insulating portion 14 can be made of a material with a relatively high resistance, such as an organic insulating material, an inorganic insulating material, or a mixed insulating material.
- the material of the first insulating portion 14 can include an insulating PPS (polyphenylene sulfide) material.
- the first insulating portion 14 can also be made of other materials with insulating properties, such as polypropylene and polyethylene.
- the resistance value of the first insulating portion 14 can be measured in megohms (M ⁇ ).
- M ⁇ megohms
- the resistance value of the first insulating portion 14 can be greater than or equal to 200 M ⁇ .
- the resistance value of the first insulating portion 14 can be other values, such as 1 M ⁇ , 10 M ⁇ , 20 M ⁇ , 30 M ⁇ , 40 M ⁇ , 50 M ⁇ , 60 M ⁇ , 70 M ⁇ , 80 M ⁇ , 90 M ⁇ , 100 M ⁇ , 110 M ⁇ , 120 M ⁇ , 130 M ⁇ ...210 M ⁇ , 220 M ⁇ , 230 M ⁇ , etc.
- the first wall 110 and the first electrode terminal 13 can be effectively insulated and isolated, reducing the risk of internal short circuits in the battery cells 10 due to a short circuit between the first wall 110 and the first electrode terminal 13, thereby enhancing battery reliability.
- providing the first insulating portion 14 between the first wall 110 and the first electrode terminal 13 can effectively reduce the risk of thermal runaway of the energy storage device due to the remaining battery cells 10 in the battery running out of control, causing the outer casing 11 to be charged with high voltage, resulting in the high voltage electricity flowing through the first wall 110 and the electrode terminal, causing an internal short circuit in the battery cells 10.
- Figure 9 is a schematic diagram of the first deformable member 15 in some embodiments of the present application.
- the battery cell 10 also includes the first deformable member 15, which is electrically connected to the first wall 110.
- the first deformable member 15 is configured to be deformable to contact the first electrode terminal 13 to electrically connect the first electrode terminal 13 to the first wall 110.
- the first deformable member 15 is mounted on the first wall 110 and is electrically connected to the first wall 110.
- the first deformable member 15 can be made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal.
- the first deformable member 15 can be welded to the inner side of the first wall 110.
- the first deformable member 15 is a structural member that deforms due to the internal pressure of the battery cell 10.
- the first deformable member 15 is used to protect the battery cell 10 from overcharge. For example, when the battery cell 10 is subjected to an abuse condition such as overcharge, the internal pressure increases. When the internal pressure reaches a first threshold, the first deformable member 15 deforms to contact the first electrode terminal 13, thereby electrically connecting the first wall 110 and the first electrode terminal 13, short-circuiting the positive and negative electrodes within the battery cell 10.
- the portion of the first deformable member 15 that is deformed by pressure to contact the first electrode terminal 13 may be the inner portion of the first electrode terminal 13 on the first wall 110, or the portion of the first electrode terminal 13 on the outer side of the first wall 110.
- the first deformable member 15 can be deformed and connected to the second portion 131 when the internal pressure of the battery cell 10 reaches the first threshold value.
- the first deformable member 15 can be deformed and connected to the first portion 130 when the internal pressure of the battery cell 10 reaches the first threshold value.
- the first deformable member 15 may be a flip sheet that flips under pressure.
- the first deformable member 15 has a disc-shaped outer profile and comprises, from the outside inward, a first skirt 150, a first flip foil 151, and a first electrical connection portion 152, which are sequentially connected.
- the first skirt 150 can be connected to the first wall 110.
- the first flip foil 151 is relatively thin and is designed to deform and flip under pressure. After the first flip foil 151 flips, it can push the first electrical connection portion 152 toward the first electrode terminal 13, thereby bringing the first electrical connection portion 152 into contact with the first electrode terminal 13.
- the first wall 110 has a second through hole 1101, and the first skirt 150 is welded to the first wall 110, so that the first deformable member 15 closes the second through hole 1101.
- the first flip foil 151 is collapsed away from the first wall 110.
- the pressure inside the battery cell 10 reaches a certain level, such as a first threshold, the first flip foil 151 flips toward the first wall 110 to push the first electrical connection portion 152, thereby allowing the first electrical connection portion 152 to pass through the second through hole 1101 and contact the first portion 130.
- the first electrode terminal 13 is electrically connected to the first tab 120 via a first adapter 123.
- the second tab 121 of the electrode assembly 12 can be electrically connected to the outer casing 11.
- the second tab 121 has opposite polarity to the first tab 120.
- the second tab 121 is connected to the outer casing 11 directly or via a second adapter 124, or the outer casing 11 is provided with a second electrode terminal 16, which is electrically connected to the outer casing 11, and the second tab 121 is connected to the second electrode terminal 16 directly or via a second adapter 124.
- the instantaneous high current generated can melt the electrical connection components within the battery cell 10, severing the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection.
- the melted electrical connection components may include the first adapter 123 and/or the second adapter 124.
- the first adapter 123 includes a first fuse portion, and the flow area of the first fuse portion can be smaller than the flow area of the remaining portion of the first adapter 123. This allows the first fuse portion to melt when a relatively large current flows through it, thereby disconnecting the current path between the first tab 120 and the first electrode terminal 13.
- the second adapter 124 includes a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the remaining portion of the second adapter 124. This allows the second fuse portion to melt when a relatively large current flows through it, thereby disconnecting the current path between the second tab 121 and the second electrode terminal 16 or the housing 11.
- the first electrode terminal 13 is electrically connected to the first electrode tab 120 via a first adapter 123
- the second electrode tab 121 of the electrode assembly 12 can be electrically connected to the second electrode terminal 16.
- the second electrode tab 121 has an opposite polarity to the first electrode tab 120, and the second electrode terminal 16 can be insulated and mounted to the housing 11, for example, to the first wall 110 of the housing 11.
- the second electrode tab 121 can be electrically connected to the second electrode terminal 16 via a second adapter 124.
- a second deformable member 18 is provided corresponding to the second electrode terminal 16.
- the second deformable member 18 is electrically connected to the housing 11 and is configured to deform to contact the second electrode terminal 16 to electrically connect the second electrode terminal 16 to the housing 11.
- the second deformable member 18 is configured to deform to contact the second electrode terminal 16 when the internal pressure of the battery cell 10 reaches a second threshold value to electrically connect the second electrode terminal 16 to the housing 11.
- the first deformable member 15 deforms, short-circuiting the first electrode terminal 13 and the outer shell 11.
- the second deformable member 18 deforms, short-circuiting the second electrode terminal 16 and the outer shell 11, thereby short-circuiting the positive and negative electrodes within the battery cell 10 and creating an internal short circuit.
- the large current generated instantaneously can melt the electrical connection components within the battery cell 10, cutting off the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection.
- the fused electrical connection components can include the first adapter 123 and/or the second adapter 124.
- the first adapter 123 has a first fuse portion, the flow area of which can be smaller than the flow area of the remaining portions of the first adapter 123, so that when a large current passes through, the first fuse portion can melt, thereby disconnecting the current path between the first tab 120 and the first electrode terminal 13.
- the second adapter 124 has a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the rest of the second adapter 124, so that when a larger current passes through, the second fuse portion can be melted, thereby disconnecting the current path between the second electrode tab 121 and the second electrode terminal 16.
- the first deformable member 15 when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold value, the first deformable member 15 is deformed to contact the first electrode terminal 13, so that the first electrode terminal 13 is electrically connected to the first wall 110, thereby realizing an internal short circuit of the battery cell 10, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell 10, thereby playing a role of overcharge protection, and playing a role of reducing the risk of thermal runaway of the battery cell 10, thereby making the battery have higher reliability.
- a certain level such as the first threshold value
- Figure 10 is a three-dimensional diagram of the first wall 110 in some embodiments of the present application
- Figure 11 is a schematic diagram of the local structure of the first wall 110 in some embodiments of the present application.
- the first wall 110 is formed with a first through hole 1100 and a second through hole 1101 through which the first electrode terminal 13 passes.
- the first deformable member 15 closes the second through hole 1101 and is configured to be deformable to partially pass through the second through hole 1101 and contact the first electrode terminal 13.
- the first electrode terminal 13 along the thickness direction z of the first wall, includes a first portion 130 located outside the first wall 110 and a second portion 131 at least partially located inside the first wall 110.
- the second portion 131 is used to electrically connect to the electrode assembly 12 of the battery cell 10.
- the first wall 110 may be an end cap of the housing 11 and may be plate-shaped.
- a first through-hole 1100 and a second through-hole 1101 are formed along the thickness direction z of the first wall 110.
- the first through-hole 1100 allows the first electrode terminal 13 to pass through, while the second through-hole 1101 allows the first deformable member 15 to pass through.
- the first electrode terminal 13 includes a first portion 130 and a second portion 131.
- the first portion 130 is located outside the first wall 110 and can be flat for electrical connection to external structures.
- a portion of the second portion 131 is located inside the first wall 110 for electrical connection to the electrode assembly 12, while another portion of the second portion 131 passes through a first through-hole 1100 to connect to the first portion 130.
- the connection between the second portion 131 and the first portion 130 includes, but is not limited to, welding, bonding, riveting, or screwing.
- the first portion 130 can be partially located outside the first wall 110, while another portion of the first portion 130 passes through the first through-hole 1100 to connect to the second portion 131.
- the first portion 130 can be partially located outside the first wall 110, while a portion of the second portion 131 is located inside the first wall 110. Another portion of the first portion 130 and another portion of the second portion 131 are located within the first through-hole 1100 and connected to each other.
- First deformable member 15 encloses second through-hole 1101 may mean that first deformable member 15 closes second through-hole 1101, thereby enclosing electrode assembly 12 and electrolyte.
- first skirt 150 of first deformable member 15 is disposed around the edge of second through-hole 1101 and welded to the inner side of first wall 110.
- the first deformation member 15 when the internal pressure of the battery cell 10 reaches a first threshold, the first deformation member 15 can be deformed toward the first portion 130 to pass through the second through hole 1101 and contact the first portion 130 .
- the second through hole 1101 can be a stepped hole, which can provide a connection portion for the first skirt 150 of the first deformable member 15, so that the first skirt 150 can be accommodated in the second through hole 1101, reducing the occupation of the internal space of the battery cell 10 by the first deformable member 15.
- the internal pressure of the battery cell 10 when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold value, the internal pressure of the battery cell 10 can act on the first deformable member 15, so that the first deformable member 15 is deformed toward the outside of the first wall 110 to effectively contact the first part 130 of the first electrode terminal 13, thereby effectively realizing an internal short circuit of the battery cell 10, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, so as to cut off the charge and discharge circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
- a certain level such as the first threshold value
- the projection of the first portion 130 of the first electrode terminal 13 located outside the first wall 110 at least partially overlaps with the projection of the first deformable member 15 .
- the first part 130 is larger in size, and along the thickness direction z of the first wall, a portion of the first part 130 can be set opposite the second part 131 to be connected to the second part 131, and a portion of the first part 130 can be opposite the first deformable member 15 to directly contact the first deformable member 15 when the first deformable member 15 is deformed.
- the projection of the first deformable member 15 may entirely fall on the first portion 130. In other embodiments, along the thickness direction z of the first wall, the projection of the first deformable member 15 may partially fall on the first portion 130, while another portion may be offset from the first portion 130.
- the first deformable member 15 along the thickness direction z of the first wall corresponding to the first part 130, when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold, it can quickly contact the first part 130 with a smaller deformation amount, thereby quickly electrically connecting the first electrode terminal 13 and the first wall 110, thereby effectively realizing an internal short circuit of the battery cell 10, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
- a certain level such as the first threshold
- the first wall 110 includes a main body portion 110 a and a first reinforcement portion 110 b connected to each other, and the first portion 130 is disposed on the first reinforcement portion 110 b .
- the first reinforcement portion 110b serves to strengthen the overall structural strength of the first wall 110 or to strengthen the local structural strength of the first wall 110, thereby increasing the impact resistance of the first wall 110 and reducing the risk of deformation of the first wall 110.
- the first reinforcement portion 110b may be a reinforcing rib, a concave-convex structure, or the like.
- the first wall 110 includes a main body portion 110a and a first reinforcement portion 110b stacked on the surface of the main body portion 110a.
- the material of the first reinforcement portion 110b is the same as that of the main body portion 110a.
- the thickness of the first wall 110 is larger at the location of the first reinforcement portion 110b, so that this location has greater structural strength.
- the first wall 110 includes a main body portion 110 a , which is punched to form a convex portion on one side and a concave portion on the other side of the main body portion 110 a , and the portions where the convex portion and the concave portion are located form the first reinforcement portion 110 b .
- the first wall 110 includes a main body portion 110a and a first reinforcement portion 110b, the main body portion 110a is arranged around the edge of the first reinforcement portion 110b, the material of the first reinforcement portion 110b and the material of the main body portion 110a can be the same or different, and the structural strength of the first reinforcement portion 110b is greater than that of the main body portion 110a.
- the first portion 130 is disposed on the first reinforcement portion 110 b ” can be understood as that the portion of the first wall 110 used to support the first portion 130 is the portion of the first wall 110 with greater structural strength.
- the overall strength of the first wall 110 can be improved, and the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the first deformable member 15 to be unable to effectively contact the first part 130 to conduct electricity between the first electrode terminal 13 and the first wall 110, can be reduced.
- the first deformable member 15 can effectively contact the first electrode terminal 13 under abuse conditions such as overcharging of the battery cell 10, thereby effectively playing the role of overcharge protection, reducing the risk of thermal runaway of the battery cell 10, and making the battery have higher reliability.
- the main body portion 110 a may be disposed around an edge of the first reinforcement portion 110 b .
- the first reinforcement portion 110b can be concave or convex relative to the main body portion 110a, such that the structural strength of the first reinforcement portion 110b is greater than that of the main body portion 110a.
- the thickness of the first reinforcement portion 110b can be greater than that of the main body portion 110a, such that the structural strength of the first reinforcement portion 110b is greater than that of the main body portion 110a.
- the length of the first wall is greater than or equal to 150 mm, and the width of the first wall is greater than or equal to 45 mm.
- the battery cell 10 may be a square battery cell, and the first wall 110 may be an end cap of the outer shell 11.
- the volume of the outer shell 11 may be designed to be larger, and for this purpose, the size of the end cap is larger.
- the dimension of the end cap in its length direction is marked as C, that is, the value of the length C of the first wall 110 may be greater than or equal to 150 mm, for example, the value of C is 150 mm, 160 mm, 170 mm, 180 mm, a larger value, or any value between two adjacent values.
- the dimension of the end cap in its width direction is marked as D, that is, the value of the width D of the first wall 110 may be greater than or equal to 45 mm, for example, the value of D is 45 mm, 55 mm, 65 mm, 75 mm, a larger value, or any value between two adjacent values.
- the length direction of the end cap may be the direction of the largest size of the end cap, the width direction of the end cap may be the direction of the smallest size, and the width direction of the end cap, the length direction of the end cap and the thickness direction of the end cap may be perpendicular to each other.
- the structural strength lost due to the increase in the size of the first wall 110 can be effectively compensated, the overall strength of the first wall 110 can be improved, and the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the first deformable member 15 to be unable to effectively contact the first portion 130 to conduct electricity between the first electrode terminal 13 and the first wall 110, can be reduced.
- the first deformable member 15 can effectively contact the first electrode terminal 13 under abuse conditions such as overcharging of the battery cell 10, thereby effectively playing the role of overcharge protection, reducing the risk of thermal runaway of the battery cell 10, and making the battery have higher reliability.
- the first reinforcement portion 110b includes a first protrusion 110b0 , which protrudes from a surface of the main body portion 110a along the thickness direction z of the first wall.
- the first reinforcement portion 110b includes a first protrusion 110b0 protruding from the surface of the first wall 110.
- the first protrusion 110b0 protrudes from the outer side of the first wall 110; or the first protrusion 110b0 protrudes from the inner side of the first wall 110.
- the first wall 110 may include a main body 110a, which defines a first reinforcement region.
- the first protrusion 110b0 may be disposed in the first reinforcement region, and the portion where the first reinforcement region is located may be considered the first reinforcement portion 110b.
- the first portion 130 may be disposed in the first reinforcement region, for example, the first portion 130 may be disposed on a surface of the first protrusion 110b0 facing away from the main body 110a, or in a portion of the main body 110a facing away from the first protrusion 110b0.
- the first protrusion 110b0 and the main body 110a may be separate structures, such as the first protrusion 110b0 being stacked on the main body 110a.
- connection between the first protrusion 110b0 and the main body 110a includes, but is not limited to, bonding, welding, riveting, or screwing.
- the first protrusion 110b0 and the main body 110a may be a unitary structure, formed integrally by stamping, casting, or other processes.
- the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the first deformable member 15 to be unable to effectively contact the first part 130 to conduct electricity between the first electrode terminal 13 and the first wall 110, can be effectively reduced, thereby making the battery have higher reliability.
- the first reinforcement portion 110b further includes a first recess 110b1 , which is disposed on another surface of the main body portion 110a along the thickness direction z of the first wall, and the first recess 110b1 is disposed opposite to the first protrusion 110b0 .
- the first concave portion 110b1 corresponds to the first convex portion 110b0.
- the first concave portion 110b1 is located on the inside of the first wall 110; conversely, when the first convex portion 110b0 is located on the inside of the first wall 110, the first concave portion 110b1 is located on the outside of the first wall 110.
- the first wall 110 may be formed by stamping to form the first convex portion 110b0 and the first concave portion 110b1. For example, along the thickness direction z of the first wall, a punch presses the first wall 110 from the inside to the outside of the first wall 110 to form the first convex portion 110b0 on the outside of the first wall 110 and the first concave portion 110b1 on the inside of the first wall 110.
- the first recess 110b1 is located on the inner side of the first wall 110, and at least part of the first deformable member 15 and the second portion 131 are located in the first recess 110b1.
- the first recess 110b1 is provided at a position corresponding to the first protrusion 110b0.
- the difficulty of forming the first protrusion 110b0 can be reduced and material costs can be saved.
- the space of the first recess 110b1 can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell 10, or the first deformable member 15 and the first electrode terminal 13 can utilize the space of the first recess 110b1 to reduce the occupation of the internal space of the battery cell 10; if the first recess 110b1 is located on the outer side of the first wall 110, the space of the first recess 110b1 can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
- the first protrusion 110b0 is located outside the first wall 110 and is formed with a first positioning groove 110b2 that receives the first portion 130 to restrict its movement.
- the first protrusion 110 b 0 is located on the outer side of the first wall 110 , and the first portion 130 may be disposed on the first protrusion 110 b 0 .
- First positioning groove 110b2 is a groove structure formed in first protrusion 110b0, and first portion 130 is located in first positioning groove 110b2.
- first protrusion 110b0 has a top surface facing away from electrode assembly 12.
- First positioning groove 110b2 is a square groove formed in this top surface. Square-shaped first portion 130 and a portion of first insulating portion 14 are located in first positioning groove 110b2. First insulating portion 14 is sandwiched between the groove wall of first positioning groove 110b2 and the outer peripheral surface of first portion 130.
- the first electrode terminal 13 can be effectively positioned and the displacement of the first electrode terminal 13 can be limited.
- the risk of the first electrode terminal 13 being separated from the internal electrical connection component of the battery cell 10 and causing internal short circuit of the battery cell 10 is reduced.
- the first electrode terminal 13 can be effectively cooperated with the first deformable member 15 to play the role of overcharge protection and improve the reliability of the battery.
- the first protrusion 110b0 is located outside the first wall 110, and along the thickness direction z of the first wall, the dimension of the first protrusion 110b0 protruding from the main body 110a is greater than or equal to 0.1 mm and less than or equal to 5 mm.
- the first protrusion 110b0 protrudes from the main body 110a by a dimension L1, where L1 is greater than or equal to 0.1 mm and less than or equal to 5 mm.
- L1 is 0.1 mm, 0.2 mm, 0.3 mm, 0.4 mm, 0.5 mm, 0.6 mm, ... 2.9 mm, 3 mm, 3.1 mm, 3.2 mm, 3.3 mm, ... 4.7 mm, 4.8 mm, 4.9 mm, 5 mm, or any value in between.
- the protrusion of the first protrusion 110b0 from the main body 110a is set to be greater than or equal to 0.1mm, the structural strength of the first wall 110 can be effectively improved, allowing the first deformable member 15 to effectively contact the first electrode terminal 13 when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold, thereby providing overcharge protection and thereby improving the reliability of the battery.
- the protrusion of the first protrusion 110b0 from the main body 110a to be less than or equal to 5mm, the space occupied by the first protrusion 110b0 can be reduced, thereby reducing its impact on the battery's volumetric energy density.
- the protrusion of the first protrusion 110b0 from the main body 110a is set to be greater than or equal to 0.1mm and less than or equal to 5mm, both the reliability of the battery cell 10's overcharge protection and the battery's volumetric energy density can be achieved.
- a dimension of the first protrusion 110b0 protruding from the main body 110a is greater than or equal to 0.5 mm and less than or equal to 3 mm.
- the first protrusion 110b0 protrudes from the main body 110a by a dimension L1, where L1 is greater than or equal to 0.5 mm and less than or equal to 3 mm.
- L1 is 0.5 mm, 0.6 mm, 0.7 mm, 0.8 mm, 0.9 mm, 1 mm, 2.5 mm, 2.6 mm, 2.7 mm, 2.8 mm, 2.9 mm, 3 mm, or any value in between.
- the protrusion of the first protrusion 110b0 from the main body 110a is set to be greater than or equal to 0.5mm, the structural strength of the first wall 110 is further improved, allowing the first deformable member 15 to efficiently contact the first electrode terminal 13 when the internal pressure of the battery cell 10 reaches the first threshold, thereby providing overcharge protection and improving the reliability of the battery.
- the protrusion of the first protrusion 110b0 from the main body 110a is less than or equal to 3mm, the space occupied by the first protrusion 110b0 can be effectively reduced, thereby reducing its impact on the battery's volumetric energy density.
- the protrusion of the first protrusion 110b0 from the main body 110a is set to be greater than or equal to 0.5mm and less than or equal to 3mm, both the reliability of the battery cell 10's overcharge protection and the battery's volumetric energy density can be achieved.
- the first insulating portion 14 includes a first insulating member 140, at least a portion of the first insulating member 140 is arranged between the first portion 130 of the first electrode terminal 13 located on the outside of the first wall 110 and the first wall 110, and the first insulating member 140 is formed with a third through hole 14001 and a fourth through hole 14002.
- the third through hole 14001 is arranged opposite to the first through hole 1100
- the fourth through hole 14002 is arranged opposite to the second through hole 1101.
- the first insulating member 140 can be considered plate-shaped and is disposed between the first portion 130 and the first wall 110 to insulate and isolate the first portion 130 from the first wall 110.
- the first insulating member 140 has a third through hole 14001 and a fourth through hole 14002 extending through the first wall along the thickness direction z.
- the third through hole 14001 is provided corresponding to the first through hole 1100 for the first electrode terminal 13 to pass through.
- the fourth through hole 14002 is provided corresponding to the second through hole 1101 for the first deformable member 15 to pass through after deformation to contact the first portion 130.
- the third through hole 14001 may be a square hole, a circular hole, or other shapes.
- the fourth through hole 14002 may be a square hole, a circular hole, or other shapes.
- the third through hole 14001 and the first through hole 1100 may be circular holes, and the diameter of the third through hole 14001 may be smaller than or equal to the diameter of the first through hole 1100.
- the fourth through hole 14002 and the second through hole 1101 may be circular holes, and the diameter of the fourth through hole 14002 may be smaller than or equal to the diameter of the second through hole 1101.
- the material of the first insulating member 140 may include insulating PPS (polyphenylene sulfide).
- the first insulating member 140 may also be made of other insulating materials such as polypropylene and polyethylene.
- the resistance of the first insulating member 140 in the battery cell 10 may be greater than or equal to 200 M ⁇ .
- the first insulating member 140 has a simple structure.
- the first electrode terminal 13 is allowed to pass through the third through hole 14001, so that the first electrode terminal 13 is electrically connected to the electrode assembly 12 and external charging and discharging is realized.
- the first deformable member 15 is allowed to deform through the fourth through hole 14002 so as to be able to contact the first part 130 to achieve overcharge protection; on the other hand, the first insulating member 140 can effectively insulate and isolate the first part 130 and the first wall 110, reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first part 130 and the first wall 110, thereby making the battery highly reliable.
- the first insulating member 140 includes a first body 1400 and a first flange 1401 , the first body 1400 is located between the first portion 130 and the first wall 110 , the first flange 1401 is arranged on a surface of the first body 1400 facing away from the first wall 110 , and the first flange 1401 surrounds at least a portion of the outer peripheral surface of the first portion 130 .
- the first body 1400 is sandwiched between the first portion 130 and the first wall 110 , and the first body 1400 is flat in shape.
- the first flange 1401 is protruded from the surface of the first body 1400 and surrounds the outer circumference of the first portion 130 .
- the first flange 1401 surrounds at least a portion of the outer circumference of the first part 130 can be understood as the first flange 1401 being able to completely cover the outer circumference of the first part 130 or the first flange 1401 being able to partially cover the outer circumference of the first part 130 .
- the first insulating member 140 wraps the first portion 130 and is located in the first positioning groove 110 b 2 , and the first flange 1401 is located between the outer circumference of the first portion 130 and the groove wall of the first positioning groove 110 b 2 .
- the first wall 110 and the first part 130 can be effectively insulated and isolated, so that there is a longer creepage distance between the first part 130 and the first wall 110, and the first insulating member 140 has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first wall 110 and the first electrode terminal 13, so that the reliability of the battery is high.
- the first insulating member 140 further includes a second flange 1402 .
- the second flange 1402 is disposed around the third through hole 14001 and is located between the hole wall of the first through hole 1100 and the first electrode terminal 13 .
- the second flange 1402 is part of the first insulating member 140.
- the second flange 1402 is connected to the first body 1400 and disposed around the third through-hole 14001. Along the thickness direction z of the first wall, the second flange 1402 protrudes toward the first through-hole 1100 to cover a portion of the wall of the first through-hole 1100, thereby insulating and isolating the first electrode terminal 13 from the wall of the first through-hole 1100.
- the second flange 1402 also serves as a positioning mechanism. By aligning the second flange 1402 with the first through-hole 1100, the first insulating member 140 can be quickly assembled to the first wall 110.
- the second flange 1402 may partially or completely cover the hole wall of the first through hole 1100 .
- the hole wall of the first through hole 1100 and the first electrode terminal 13 can be effectively insulated and isolated, reducing the risk of the first electrode terminal 13 contacting the hole wall of the first through hole 1100 and causing an internal short circuit in the battery cell 10, thereby effectively improving the reliability of the battery.
- the first insulating portion 14 may further include a first sealing portion 141.
- the first sealing portion 141 may be sleeved on the second portion 131, and a portion of the first sealing portion 141 may be clamped between the first through hole 1100 and the second portion 131. Another portion of the first sealing portion 141 may be clamped between the surface of the first wall 110 facing away from the first portion 130 and the second portion 131.
- Figure 12 is a schematic diagram of the first wall and the second electrode terminal in some embodiments of the present application
- Figure 13 is a schematic diagram of the second deformation member 18 in some embodiments of the present application.
- the battery cell 10 also includes a second electrode terminal 16, a second insulating portion 17, and a second deformable member 18.
- the second electrode terminal 16 is disposed on the first wall 110 and electrically connected to the electrode assembly 12.
- the second electrode terminal 16 is used for inputting and outputting electrical energy, and the polarity of the second electrode terminal 16 and the first electrode terminal 13 are opposite.
- the second insulating portion 17 is disposed between the first wall 110 and the second electrode terminal 16 to insulate and isolate the second electrode terminal 16 from the first wall 110.
- the second deformable member 18 is electrically connected to the first wall 110 and is configured to deform into contact with the second electrode terminal 16 to electrically connect the second electrode terminal 16 to the first wall 110.
- the second electrode terminal 16 is a component mounted on the first wall 110.
- the second electrode terminal 16 is used to electrically connect to the electrode assembly 12, allowing current to flow into or out of the second electrode tab 121 through the second electrode terminal 16.
- the second electrode terminal 16 and the second electrode tab 121 have the same polarity.
- the first electrode terminal 13 is a positive electrode terminal
- the second electrode terminal 16 is a negative electrode terminal.
- the second electrode terminal 16 is a positive electrode terminal.
- the second electrode terminal 16 is made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal.
- the second electrode terminal 16 can be connected to the second electrode tab 121 via a second adapter 124.
- the second electrode tab 121 of the electrode assembly 12 is composed of a plurality of second sub-electrode tabs stacked together. After welding one end of the second adapter 124 to the second electrode tab 121, the other end of the second adapter 124 can be welded to the second electrode terminal 16.
- the second insulating portion 17 has a high resistance, insulating the second electrode terminal 16 from the first wall 110.
- the second electrode terminal 16 has an exposed third portion 160.
- the second insulating portion 17 can be disposed between the outer side of the first wall 110 and the third portion 160 to insulate the second electrode terminal 16 from the first wall 110.
- the second insulating portion 17 can cover the outer periphery of the third portion 160 to increase the creepage distance between the second electrode terminal 16 and the first wall 110.
- a fifth through-hole 1102 is formed in the first wall 110.
- the second electrode terminal 16 can pass through the fifth through-hole 1102 to form a third portion 160 on the outside and a fourth portion 161 on the inside.
- the third portion 160 is used to connect to an external electrical connection member, and the fourth portion 161 is used to electrically connect to the electrode assembly 12.
- the second insulating portion 17 has a seventh through-hole 17001 formed therein, corresponding to the fifth through-hole 1102, for the second electrode terminal 16 to pass through.
- a major portion of the second insulating portion 17 is located between the third portion 160 and the first wall 110, while some portion of the second insulating portion 17 may be located between the fifth through-hole 1102 and the second electrode terminal 16.
- a major portion of the second insulating portion 17 is located between the third portion 160 and the first wall 110, while some portion of the second insulating portion 17 may be located between the fifth through-hole 1102 and the second electrode terminal 16, and the remaining portion of the second insulating portion 17 may also be located between the first wall 110 and the fourth portion 161.
- the second insulating portion 17 may be in a plate shape as a whole, and its two opposite surfaces are relatively flat so as to be stably positioned between the second electrode terminal 16 and the first wall 110 .
- the second insulating portion 17 can be made of a material with a relatively high resistance, such as an organic insulating material, an inorganic insulating material, or a mixed insulating material.
- the material of the second insulating portion 17 can include an insulating PPS (polyphenylene sulfide) material.
- the second insulating portion 17 can also be made of other materials with insulating properties, such as polypropylene and polyethylene.
- the resistance value of the second insulating portion 17 can be measured in megohms (M ⁇ ).
- M ⁇ megohms
- the resistance value of the second insulating portion 17 can be greater than or equal to 200 M ⁇ .
- the resistance value of the second insulating portion 17 can be other values, such as 1 M ⁇ , 10 M ⁇ , 20 M ⁇ , 30 M ⁇ , 40 M ⁇ , 50 M ⁇ , 60 M ⁇ , 70 M ⁇ , 80 M ⁇ , 90 M ⁇ , 100 M ⁇ , 110 M ⁇ , 120 M ⁇ , 130 M ⁇ ...210 M ⁇ , 220 M ⁇ , 230 M ⁇ , etc.
- the second deformable member 18 is mounted on the first wall 110 and is electrically connected to the first wall 110.
- the second deformable member 18 can be made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal.
- the second deformable member 18 can be welded to the inner side of the first wall 110.
- the second deformable member 18 is a structural member that deforms due to the internal pressure of the battery cell 10.
- the second deformable member 18 is used to protect the battery cell 10 from overcharge. For example, when the battery cell 10 is subjected to an abusive operating condition such as overcharge, the internal pressure increases. When the internal pressure reaches a certain level, such as a second threshold, the second deformable member 18 deforms to contact the second electrode terminal 16, thereby electrically connecting the first wall 110 to the second electrode terminal 16, short-circuiting the positive and negative electrodes within the battery cell 10.
- a certain level such as a second threshold
- the portion of the second deformable member 18 that is deformed by pressure to contact the second electrode terminal 16 can be the inner portion of the second electrode terminal 16 on the first wall 110, or the portion of the second electrode terminal 16 on the outer side of the first wall 110.
- the second deformable member 18 can be deformed and connected to the fourth portion 161 when the internal pressure of the battery cell 10 reaches the second threshold value.
- the second deformable member 18 can be deformed and connected to the third portion 160 when the internal pressure of the battery cell 10 reaches the second threshold value.
- the second deformable member 18 may be a flip sheet that flips under pressure.
- the second deformable member 18 has a disc-shaped outer profile and comprises, from the outside inward, a second skirt 180, a second flip foil 181, and a second electrical connection portion 182.
- the second skirt 180 may be connected to the first wall 110.
- the second flip foil 181 is relatively thin and is designed to deform and flip under pressure. After the second flip foil 181 flips, it can push the second electrical connection portion 182 toward the second electrode terminal 16, thereby bringing the second electrical connection portion 182 into contact with the second electrode terminal 16.
- the first wall 110 has a sixth through hole 1103, and the second skirt 180 is welded to the first wall 110, so that the second deformable member 18 closes the sixth through hole 1103.
- the second flip foil 181 is collapsed away from the first wall 110.
- the second flip foil 181 flips toward the first wall 110 to push the second electrical connection portion 182, thereby allowing the second electrical connection portion 182 to pass through the sixth through hole 1103 and contact the third portion 160.
- the internal pressure of the battery cell 10 increases.
- the first deformable member 15 deforms, short-circuiting the first electrode terminal 13 and the outer casing 11.
- the second deformable member 18 deforms, short-circuiting the second electrode terminal 16 and the outer casing 11, thereby short-circuiting the positive and negative electrodes within the battery cell 10 and creating an internal short circuit.
- the resulting high current can melt the electrical connections within the battery cell 10, severing the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection.
- the fused electrical connections can include the first adapter 123 and/or the second adapter 124.
- the first adapter 123 has a first fuse portion, the flow area of which can be smaller than the flow area of the remaining portions of the first adapter 123. This allows the first fuse portion to melt when a large current flows, thereby severing the current path between the first tab 120 and the first electrode terminal 13.
- the second adapter 124 has a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the rest of the second adapter 124, so that when a larger current passes through, the second fuse portion can be melted, thereby disconnecting the current path between the second electrode tab 121 and the second electrode terminal 16.
- the first wall 110 and the second electrode terminal 16 can be effectively insulated and isolated, thereby reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first wall 110 and the second electrode terminal 16, thereby improving the reliability of the battery;
- the second deformable member 18 when the internal pressure of the battery cell 10 reaches a certain level, such as the second threshold value, the second deformable member 18 is deformed to contact the second electrode terminal 16, thereby electrically connecting the second electrode terminal 16 to the second wall, and cooperating with the short circuit of the first deformable member 15 and the first electrode terminal 13, the internal pressure of the battery cell 10 is reduced.
- the electrical connection component is melted due to the large current generated by the short circuit, so as to cut off the charge and discharge circuit of the battery cell 10, thereby playing the role of overcharge protection and reducing the risk of thermal runaway of the battery cell 10, thereby making the battery have higher reliability; on the other hand, because the first electrode terminal 13 and the second electrode terminal 16 are insulated and isolated from the first wall 110 under non-abuse conditions, the shell 11 of the battery cell 10 can be uncharged, so that the battery cell 10 constitutes an energy storage device, which reduces the risk of ignition and breakdown between two adjacent battery cells 10 in the energy storage device. At the same time, by providing the second deformable member 18, the overcharge protection function can be effectively achieved, so that the energy storage device has high reliability.
- the second electrode terminal 16 is a negative electrode terminal, so that the minimum pressure value for deforming the second deformable member 18 is greater than the minimum pressure value for deforming the first deformable member 15 .
- the first deforming member 15 deforms.
- the second deforming member deforms.
- the second threshold may be greater than the first threshold.
- the second electrode terminal 16 is a negative electrode terminal, that is, the second electrode terminal 16 is electrically connected to the negative electrode tab of the electrode assembly 12 .
- the second threshold is greater than the first threshold can be understood as the second deformable member 18 is less susceptible to deformation than the first deformable member 15 , that is, the second deformable member 18 deforms only when the internal pressure of the battery cell 10 further increases and exceeds the first threshold.
- the manufacturing material or structure of the second deformable member 18 can be modified to make the second deformable member 18 less susceptible to deformation than the first deformable member 15.
- the thickness of the second flip foil 181 of the second deformable member 18 is greater than the thickness of the first flip foil 151 of the first deformable member 15, so that the second deformable member 18 deforms to contact the second electrode terminal 16 only when subjected to greater pressure.
- a reinforcing structure such as a reinforcing rib or a reinforcing concave-convex portion, is provided on the second flip foil 181, so that the second deformable member 18 deforms to contact the second electrode terminal 16 only when subjected to greater pressure.
- the second threshold is greater than the first threshold can be understood to mean that the second deformable member 18 requires a greater pressure than the first deformable member 15 to contact the second electrode terminal 16.
- the second deformable member 18 only contacts the second electrode terminal 16 when the internal pressure of the battery cell 10 further increases and exceeds the first threshold.
- the distance between the second deformable member 18 and the second electrode terminal 16 can be increased so that the second deformable member 18 requires a greater amount of deformation to contact the second electrode terminal 16.
- the distance between the second electrical connection portion 182 and the second electrode terminal 16 is greater than the distance between the first electrical connection portion 152 and the first electrode terminal 13; for another example, in a natural state, the second flip foil 181 is further away from the first wall 110 than the first flip foil 151.
- the second deformable member 18 when the second electrode terminal 16 is a negative electrode terminal, by setting the second threshold value to be greater than the first threshold value, the second deformable member 18 can be deformed when the pressure inside the battery cell 10 is greater than that of the first deformable member 15.
- the battery cell 10 can have an overcharge protection function.
- it can reduce the risk of gas production inside the battery cell 10 causing the second deformable member 18 to flip over, resulting in the outer shell 11 being negatively charged and corroded by the electrolyte under non-overcharge abuse conditions, thereby ensuring the integrity of the outer shell 11 to a certain extent, reducing the risk of electrolyte leakage, and thus improving the reliability of the battery.
- the negative charge of the shell 11 will cause an electrochemical reaction with the electrolyte, causing the shell 11 to be corroded, and there is a risk of leakage.
- the second threshold value larger than the first threshold value, the probability of the shell 11 being negatively charged due to non-overcharge and other conditions can be reduced, thereby improving the integrity of the shell 11 and improving the reliability of the battery.
- the magnitude relationship between the first threshold and the second threshold is not limited.
- the first threshold may be equal to the second threshold.
- Figure 14 is a partial schematic diagram of the first wall 110 in some embodiments of the present application.
- the first wall 110 is formed with a fifth through-hole 1102 and a sixth through-hole 1103.
- the second electrode terminal 16 passes through the fifth through-hole 1102.
- the second deformable member 18 closes the sixth through-hole 1103.
- the second deformable member 18 is configured to deform to partially pass through the sixth through-hole 1103 and contact the second electrode terminal 16.
- the first wall 110 may be an end cap of the housing 11 and may be plate-shaped.
- a fifth through-hole 1102 and a sixth through-hole 1103 are formed along the thickness direction z of the first wall 110.
- the fifth through-hole 1102 allows the second electrode terminal 16 to pass through, while the sixth through-hole 1103 allows the second deformable member 18 to pass through.
- the second electrode terminal 16 includes a third portion 160 and a fourth portion 161.
- the third portion 160 is located outside the first wall 110 and can be flat for electrical connection to external structures.
- a portion of the fourth portion 161 is located inside the first wall 110 for electrical connection to the electrode assembly 12.
- Another portion of the fourth portion 161 is connected to the third portion 160 through a fifth through-hole 1102.
- Connections between the fourth portion 161 and the third portion 160 include, but are not limited to, welding, bonding, riveting, or screwing.
- the third portion 160 can be partially located outside the first wall 110, with another portion of the third portion 160 connected to the fourth portion 161 through the fifth through-hole 1102.
- the third portion 160 can be partially located outside the first wall 110, while a portion of the fourth portion 161 is located inside the first wall 110. Another portion of the third portion 160 and another portion of the fourth portion 161 are located within the fifth through-hole 1102 and connected to each other.
- “Second deformable member 18 closes sixth through hole 1103” may mean that second deformable member 18 closes sixth through hole 1103, thereby enclosing electrode assembly 12 and electrolyte.
- second skirt 180 of second deformable member 18 is disposed around the edge of sixth through hole 1103 and welded to the inner side of first wall 110.
- the second deformation member 18 when the internal pressure of the battery cell 10 reaches a certain level, such as a second threshold, the second deformation member 18 can be deformed toward the third portion 160 to pass through the sixth through hole 1103 and contact the third portion 160 .
- the sixth through hole 1103 can be a stepped hole shape, which can provide a connection portion for the second skirt 180 of the second deformable member 18, so that the second skirt 180 can be accommodated in the sixth through hole 1103, reducing the occupation of the internal space of the battery cell 10 by the second deformable member 18.
- the internal pressure of the battery cell 10 when the internal pressure of the battery cell 10 reaches a certain level, such as the second threshold value, the internal pressure of the battery cell 10 can act on the second deformable member 18, so that the second deformable member 18 is deformed toward the outside of the first wall 110 to effectively contact the third part 160 of the second electrode terminal 16, and cooperates with the first deformable member 15 to contact the first electrode terminal 13, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, so as to cut off the charging and discharging circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
- a certain level such as the second threshold value
- the projection of the third portion 160 of the second electrode terminal 16 located outside the first wall 110 at least partially overlaps with the projection of the second deformable member 18 .
- the third part 160 is larger in size, and along the thickness direction z of the first wall, a portion of the third part 160 can be set opposite the fourth part 161 to be connected to the fourth part 161, and a portion of the third part 160 can be opposite the second deforming member 18 to directly contact the second deforming member 18 when the second deforming member 18 is deformed.
- the projection of the second deformable member 18 may entirely fall on the third portion 160. In other embodiments, along the thickness direction z of the first wall, the projection of the second deformable member 18 may partially fall on the third portion 160, while another portion may be offset from the third portion 160.
- the third part 160 can be quickly contacted with a smaller deformation amount, thereby quickly electrically connecting the second electrode terminal 16 and the first wall 110, and cooperating with the first deformable member 15 to contact the first electrode terminal 13, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
- the first wall 110 includes a main body portion 110 a and a second reinforcement portion 110 c connected to each other, and the third portion 160 of the second electrode terminal 16 located outside the first wall 110 is disposed on the second reinforcement portion 110 c.
- the second reinforcement portion 110c is used to strengthen the overall structural strength of the first wall 110 or to strengthen the local structural strength of the first wall 110, thereby enhancing the impact resistance of the first wall 110 and reducing the risk of deformation of the first wall 110.
- the second reinforcement portion 110c may be a reinforcing rib, a concave-convex structure, or the like.
- the first wall 110 includes a main body portion 110a and a second reinforcement portion 110c stacked on the surface of the main body portion 110a.
- the material of the second reinforcement portion 110c is the same as that of the main body portion 110a.
- the thickness of the first wall 110 is larger at the location of the second reinforcement portion 110c, so that this portion has greater structural strength.
- the first wall 110 includes a main body portion 110 a , which is punched to form a convex portion on one side and a concave portion on the other side of the main body portion 110 a , and the portions where the convex portion and the concave portion are located form the second reinforcement portion 110 c .
- the first wall 110 includes a main body portion 110a and a second reinforcement portion 110c, the main body portion 110a is arranged around the edge of the second reinforcement portion 110c, the material of the second reinforcement portion 110c and the material of the main body portion 110a can be the same or different, and the structural strength of the second reinforcement portion 110c is greater than that of the main body portion 110a.
- the third portion 160 is disposed on the second reinforcement portion 110 c ” can be understood as that the portion of the first wall 110 used to support the third portion 160 is the portion of the first wall 110 with greater structural strength.
- the overall strength of the first wall 110 can be improved, and the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the second deformable member 18 to be unable to effectively contact the third part 160 to conduct electricity between the second electrode terminal 16 and the first wall 110, can be reduced.
- the second deformable member 18 can effectively contact the second electrode terminal 16 under abuse conditions such as overcharging of the battery cell 10, thereby effectively playing the role of overcharge protection, reducing the risk of thermal runaway of the battery cell 10, and making the battery have higher reliability.
- the second reinforcement portion 110 c is less susceptible to deformation than the main body portion 110 a , thereby being able to provide effective support for the third portion 160 .
- the main body portion 110 a may be disposed around an edge of the second reinforcement portion 110 c .
- the second reinforcement portion 110c can be concave or convex relative to the main body portion 110a, such that the structural strength of the second reinforcement portion 110c is greater than that of the main body portion 110a.
- the thickness of the second reinforcement portion 110c can be greater than that of the main body portion 110a, such that the structural strength of the second reinforcement portion 110c is greater than that of the main body portion 110a.
- the second reinforcing portion 110 c includes a second protrusion 110 c 0 , which protrudes from a surface of the main body 110 a along the thickness direction z of the first wall.
- the second reinforcement portion 110c includes a second protrusion 110c0 protruding from the surface of the first wall 110.
- the second protrusion 110c0 protrudes from the outer side of the first wall 110; or the first protrusion 110b0 protrudes from the inner side of the first wall 110.
- the first wall 110 may include a main body 110a, which defines a second reinforcement region.
- the second protrusion 110c0 may be disposed in the second reinforcement region, and the portion where the second reinforcement region is located may be considered the second reinforcement portion 110c.
- the third portion 160 may be disposed in the second reinforcement region.
- the third portion 160 may be disposed on a surface of the second protrusion 110c0 facing away from the main body 110a, or in a portion of the main body 110a facing away from the second protrusion 110c0.
- the second protrusion 110c0 and the main body 110a may be separate structures, such as being stacked on the main body 110a.
- connection between the second protrusion 110c0 and the main body 110a includes, but is not limited to, bonding, welding, riveting, or screwing.
- the second protrusion 110c0 and the main body 110a may be an integral structure, formed integrally by stamping, casting, or other processes.
- the second protrusion 110c0 to strengthen the structural strength of the first wall 110, the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the second deformable member 18 to be unable to effectively contact the third part 160 to conduct electricity between the second electrode terminal 16 and the first wall 110, can be effectively reduced, thereby making the battery have higher reliability.
- the second reinforcement portion 110c further includes a second recess 110c1, which is arranged on another surface of the main body portion 110a along the thickness direction z of the first wall, and the second recess 110c1 is arranged opposite to the second protrusion 110c0.
- the second concave portion 110c1 corresponds to the second convex portion 110c0.
- the second concave portion 110c1 is located on the inside of the first wall 110; conversely, when the second convex portion 110c0 is located on the inside of the first wall 110, the second concave portion 110c1 is located on the outside of the first wall 110.
- the first wall 110 may be formed by stamping to form the second convex portion 110c0 and the second concave portion 110c1. For example, along the thickness direction z of the first wall, a punch presses the first wall 110 from the inside to the outside of the first wall 110 to form the second convex portion 110c0 on the outside of the first wall 110 and the second concave portion 110c1 on the inside of the first wall 110.
- the second recess 110c1 is located on the inner side of the first wall 110 , and at least part of the second deformable member 18 and the fourth portion 161 is located in the second recess 110c1 .
- the second recess 110c1 is provided at a position corresponding to the second protrusion 110c0.
- the difficulty of forming the second protrusion 110c0 can be reduced and material costs can be saved.
- the space of the second recess 110c1 can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell 10.
- the space of the second recess 110c1 can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
- the second protrusion 110c0 is located on the outside of the first wall 110 , and the second protrusion 110c0 is formed with a second positioning groove 110c2 , which accommodates the third portion 160 to limit the movement of the third portion 160 .
- the second protrusion 110 c 0 is located on the outer side of the first wall 110 , and the third portion 160 may be disposed on the second protrusion 110 c 0 .
- Second positioning groove 110c2 is a groove structure formed in second protrusion 110c0, and third portion 160 is located in second positioning groove 110c2.
- second protrusion 110c0 has a top surface facing away from electrode assembly 12.
- Second positioning groove 110c2 is a square groove formed in this top surface.
- the square-shaped third portion 160 and a portion of second insulating portion 17 are located in second positioning groove 110c2.
- Second insulating portion 17 is sandwiched between the groove wall of second positioning groove 110c2 and the outer peripheral surface of third portion 160.
- the second electrode terminal 16 can be effectively positioned and the displacement of the second electrode terminal 16 can be limited.
- the risk of the second electrode terminal 16 being separated from the internal electrical connection component of the battery cell 10 and causing internal short circuit of the battery cell 10 is reduced.
- the second electrode terminal 16 can be effectively matched with the second deformable member 18 to play the role of overcharge protection and improve the reliability of the battery.
- the second protrusion 110c0 is located outside the first wall 110, and along the thickness direction z of the first wall, the dimension of the second protrusion 110c0 protruding from the main body 110a is greater than or equal to 0.1 mm and less than or equal to 5 mm.
- the second protrusion 110c0 protrudes from the main body 110a by a dimension L2, where L2 is greater than or equal to 0.1 mm and less than or equal to 5 mm.
- L2 is 0.1 mm, 0.2 mm, 0.3 mm, 0.4 mm, 0.5 mm, 0.6 mm, ... 2.9 mm, 3 mm, 3.1 mm, 3.2 mm, 3.3 mm, ... 4.7 mm, 4.8 mm, 4.9 mm, 5 mm, or any value in between.
- the protrusion of the second protrusion 110c0 from the main body 110a is set to be greater than or equal to 0.1 mm, the structural strength of the first wall 110 can be effectively improved, allowing the second deformable member 18 to effectively contact the second electrode terminal 16 when the internal pressure of the battery cell 10 reaches the second threshold, thereby providing overcharge protection and improving the reliability of the battery.
- the protrusion of the second protrusion 110c0 from the main body 110a to be less than or equal to 5 mm, the space occupied by the second protrusion 110c0 can be reduced, thereby reducing the impact on the battery's volumetric energy density.
- the protrusion of the second protrusion 110c0 from the main body 110a is set to be greater than or equal to 0.1 mm and less than or equal to 5 mm, both the reliability of the overcharge protection of the battery cell 10 and the volumetric energy density of the battery can be achieved.
- a dimension of the second protrusion 110c0 protruding from the main body 110a is greater than or equal to 0.5 mm and less than or equal to 3 mm.
- the second protrusion 110c0 protrudes from the main body 110a by a dimension L2, where L2 is greater than or equal to 0.5 mm and less than or equal to 3 mm.
- L2 is 0.5 mm, 0.6 mm, 0.7 mm, 0.8 mm, 0.9 mm, 1 mm, 2.5 mm, 2.6 mm, 2.7 mm, 2.8 mm, 2.9 mm, 3 mm, or any value in between.
- the protrusion of the second protrusion 110c0 from the main body 110a is set to be greater than or equal to 0.5mm, the structural strength of the first wall 110 is further improved, allowing the second deformable member 18 to effectively contact the second electrode terminal 16 when the internal pressure of the battery cell 10 reaches the second threshold, thereby providing overcharge protection and improving the reliability of the battery.
- the protrusion of the second protrusion 110c0 from the main body 110a is less than or equal to 3mm, the space occupied by the second protrusion 110c0 can be effectively reduced, thereby reducing the impact on the battery's volumetric energy density.
- the protrusion of the second protrusion 110c0 from the main body 110a is greater than or equal to 0.5mm and less than or equal to 3mm, the reliability of the overcharge protection of the battery cell 10 and the volumetric energy density of the battery can be balanced.
- the second insulating portion 17 includes a second insulating member 170, at least a portion of the second insulating member 170 is arranged between the third portion 160 and the first wall 110, and the second insulating member 170 is formed with a seventh through hole 17001 and an eighth through hole 17002.
- the seventh through hole 17001 is arranged opposite to the fifth through hole 1102
- the eighth through hole 17002 is arranged opposite to the sixth through hole 1103.
- the second insulating member 170 can be considered plate-shaped and is disposed between the third portion 160 and the first wall 110 to insulate and isolate the third portion 160 from the first wall 110.
- the second insulating member 170 has a seventh through hole 17001 and an eighth through hole 17002 extending through the first wall along the thickness direction z.
- the seventh through hole 17001 is provided corresponding to the fifth through hole 1102 for allowing the second electrode terminal 16 to pass through.
- the eighth through hole 17002 is provided corresponding to the sixth through hole 1103 for allowing the second deformable member 18 to pass through after deformation to contact the third portion 160.
- the seventh through hole 17001 may be a square hole, a circular hole, or other shapes.
- the eighth through hole 17002 may be a square hole, a circular hole, or other shapes.
- the seventh through hole 17001 and the fifth through hole 1102 may be circular holes, and the diameter of the seventh through hole 17001 may be smaller than or equal to the diameter of the fifth through hole 1102.
- the eighth through hole 17002 and the sixth through hole 1103 may be circular holes, and the diameter of the eighth through hole 17002 may be smaller than or equal to the diameter of the sixth through hole 1103.
- the material of the second insulating member 170 may include insulating PPS (polyphenylene sulfide).
- the second insulating member 170 may also be made of other insulating materials such as polypropylene and polyethylene.
- the resistance of the second insulating member 170 in the battery cell 10 may be greater than or equal to 200 M ⁇ .
- the second insulating member 170 has a simple structure.
- the second electrode terminal 16 is allowed to pass through the seventh through hole 17001, so that the second electrode terminal 16 is electrically connected to the electrode assembly 12 and external charging and discharging is realized.
- the second deformable member 18 is allowed to deform through the eighth through hole 17002 so as to be able to contact the third part 160 to achieve overcharge protection; on the other hand, the second insulating member 170 can effectively insulate and isolate the third part 160 and the first wall 110, reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the third part 160 and the first wall 110, so that the reliability of the battery is high.
- the second insulating member 170 includes a second body 1700 and a third flange 1701, the second body 1700 is located between the third portion 160 and the first wall 110, the third flange 1701 is arranged on a surface of the second body 1700 facing away from the first wall 110, and the third flange 1701 surrounds at least a portion of the outer peripheral surface of the third portion 160.
- the second body 1700 is sandwiched between the third portion 160 and the first wall 110 , and the second body 1700 is flat.
- the third flange 1701 is protruded from the surface of the second body and surrounds the outer circumference of the third portion 160 .
- the third flange 1701 surrounds at least a portion of the outer circumference of the third part 160 ” can be understood as the third flange 1701 can completely cover the outer circumference of the third part 160 or the third flange 1701 can partially cover the outer circumference of the third part 160 .
- the second insulating member 170 wraps the third portion 160 and is located in the second positioning groove 110 c 2 , and the third flange 1701 is located between the outer circumference of the third portion 160 and the wall of the first positioning groove.
- the first wall 110 and the third part 160 can be effectively insulated and isolated, so that there is a longer creepage distance between the third part 160 and the first wall 110, and the second insulating member 170 has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first wall 110 and the second electrode terminal 16, so that the reliability of the battery is high.
- the second insulating member 170 further includes a fourth flange 1702 .
- the fourth flange 1702 is disposed around the seventh through hole 17001 and is located between the hole wall of the fifth through hole 1102 and the second electrode terminal 16 .
- the fourth flange 1702 is part of the second insulating member 170. It is connected to the second body 1700 and disposed around the seventh through-hole 17001. Along the thickness direction z of the first wall, the fourth flange 1702 protrudes toward the fifth through-hole 1102 to cover a portion of the wall of the fifth through-hole 1102, thereby insulating and isolating the second electrode terminal 16 from the wall of the fifth through-hole 1102.
- the fourth flange 1702 also serves as a positioning mechanism. By aligning the fourth flange 1702 with the fifth through-hole 1102, the second insulating member 170 can be quickly assembled to the first wall 110.
- the fourth flange 1702 may partially or completely cover the hole wall of the fifth through hole 1102 .
- the hole wall of the fifth through hole 1102 and the second electrode terminal 16 can be effectively insulated and isolated, reducing the risk of the second electrode terminal 16 contacting the hole wall of the fifth through hole 1102 and causing an internal short circuit in the battery cell 10, thereby effectively improving the reliability of the battery.
- the second insulating portion 17 may further include a second sealing portion 171, which may be sleeved on the fourth portion 161, with a portion of the second sealing portion 171 clamped between the fifth through hole 1102 and the fourth portion 161, and another portion of the second sealing portion 171 clamped between the surface of the first wall 110 facing away from the third portion 160 and the fourth portion 161.
- the resistance value of the second insulating portion 17 is greater than or equal to 200 megohms.
- a second insulating portion 17 having a resistance greater than or equal to 200 megohms may be provided between the first wall 110 and the second electrode terminal 16. That is, in some embodiments, the resistance of the second insulating portion 17 may be 200 megohms, 210 megohms, 220 megohms, or greater.
- the resistance of the second insulating portion 17 can be measured by a multimeter test method, a bridge measurement method, a volt-ampere method, an ohmmeter method, etc. In some embodiments, the resistance of the second insulating portion 17 can be measured by a megohmmeter.
- the resistance value of the second insulating portion 17 to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the second electrode terminal 16 and the first wall 110 can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the second insulating portion 17 and conducting the first wall 110 and the second electrode terminal 16, causing an internal short circuit in the battery cell 10, so that the energy storage device has higher reliability.
- the resistance of the first insulating portion 14 is greater than or equal to 200 megohms.
- a first insulating portion 14 having a resistance greater than or equal to 200 megohms may be provided between the first wall 110 and the first electrode terminal 13. That is, in some embodiments, the resistance of the first insulating portion 14 may be 200 megohms, 210 megohms, 220 megohms, or greater.
- the resistance of the first insulating portion 14 can be measured using a multimeter, bridge measurement, volt-ampere method, ohmmeter method, etc. In some embodiments, the resistance of the second insulating portion 14 can be measured using a megohmmeter.
- the resistance value of the first insulating part 14 is set to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the first electrode terminal 13 and the first wall 110 can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the first insulating part 14 to conduct the first wall 110 and the first electrode terminal 13, causing an internal short circuit in the battery cell 10, so that the energy storage device has higher reliability.
- Figure 15 is a schematic diagram of the housing 111 and electrode assembly 12 in some embodiments of the present application.
- the housing 11 includes a housing 111 and an end cap.
- the housing 111 has an opening.
- the first wall 110 is the end cap, which is connected to the housing 111 and closes the opening.
- the housing 11 includes a shell 111 and an end cap.
- a housing cavity is formed inside the shell 111, and the housing cavity is used to accommodate the electrode assembly 12.
- the shell 111 has an opening connected to the housing cavity.
- the end cap is covered on the opening of the shell 111 and forms a sealed connection to form a sealed space for accommodating the electrode assembly 12 and the electrolyte.
- the end cap can be connected to the shell 111 by welding, bonding, clamping or other connection methods.
- the shell 11 may further include a bottom plate, and openings are formed at both ends of the shell 111, one of the openings is closed by the end cap, and the other opening is closed by the bottom plate.
- the material of the shell 11 can be metal or a combination of metal and non-metal.
- the shell 11 can be made of metal, such as aluminum, copper, iron, steel or aluminum alloy; for example, part of the shell 11 can be made of metal, and the rest can be made of non-metal, such as the end cover of the shell 11 can be made of metal, and the shell 111 or other parts of the shell 11 can be made of non-metallic materials.
- the housing 111 may be an aluminum shell.
- the end cap, the first electrode terminal 13 , the second electrode terminal 16 , the first insulating portion 14 , the second insulating portion 17 and other structures may be assembled into an end cap assembly first, and then the end cap assembly may be assembled to the housing 111 .
- the housing 11 has a simple structure, which facilitates the assembly of the battery cell 10 and helps improve the battery manufacturing efficiency.
- Figure 16 is a schematic diagram of the shell 111 and the first insulating layer 19 in some embodiments of the present application.
- the inner wall of the housing 111 is provided with a first insulating layer 19 .
- the first insulating layer 19 is provided on the inner wall of the shell 111, and can insulate and protect the inner wall of the shell 111.
- the first insulating layer 19 is provided on the inner wall of the shell 111, and can insulate and protect the inner wall of the shell 111.
- the outer shell 11 is negatively charged due to the deformation of the first deformable member 15 or the second deformable member 18, the outer shell 11 will be electrochemically corroded, and the lithium of the negative electrode will be embedded in the outer shell 11.
- a first insulating layer 19 is provided on the inner wall of the shell 111, which can cut off the ion path between the outer shell 11 and the negative electrode, thereby cutting off the electrochemical corrosion reaction.
- a first insulating layer 19 is provided on the inner wall of the shell 111.
- the first insulating layer 19 plays a protective role and can improve the problem of metal particles conducting electricity between the shell 111 and the negative electrode.
- the inner wall of the housing 111 includes the inner surface of the side wall of the housing 111 and also includes the inner surface of the bottom wall of the housing 111 .
- the first insulating layer 19 is a layered structure provided on the inner wall of the housing 111 and has insulating properties.
- the first insulating layer 19 can be a coating or a thin plate-like, layered structure provided on the inner wall of the housing 111.
- the electrolyte inside the shell 111 can be effectively insulated and isolated from the inner wall of the shell 111, thereby reducing the risk of the shell 111 being corroded by the electrolyte and the risk of electrolytic wire leakage, so that the battery has higher reliability.
- the first insulating layer 19 is an insulating coating provided on the inner wall of the housing 111 .
- the insulating coating material may include epoxy resin, polyurethane, acrylic resin, polyimide, phenolic resin, etc.
- the first insulating layer 19 may be coated on the inner wall of the housing 111 by dipping, spraying, electroplating, anodizing, etc.
- the electrolyte and the shell 111 can be effectively separated, the electrolyte ion path between the motor assembly and the shell 111 can be cut off, and the risk of corrosion of the shell 111 can be reduced;
- the first insulating layer 19 can be efficiently formed on the inner wall of the shell 111 by spraying or the like, so that the manufacturing efficiency of the battery is high;
- the insulating coating has high mechanical strength, which can effectively reduce the puncture of metal particles introduced by the manufacturing process, resulting in the electrode assembly 12 and the shell 11 being electrically connected to each other, causing the risk of internal short circuit of the battery cell 10 or the risk of corrosion of the shell 11, so that the reliability of the battery is high.
- the inner wall of the shell 111 includes a blank area 19b and an insulating area connected in sequence, the insulating area is provided with a first insulating layer 19, the blank area 19b is connected to the first wall 110, and the first direction y is parallel to the first wall 110 and points to the direction of the electrode assembly 12.
- the first direction y may be parallel to the direction of the first wall 110 pointing toward the electrode assembly 12 , and the first direction y may be the thickness direction z of the first wall.
- the inner wall of the housing 111 includes a blank area 19b and an insulating area, which are connected in sequence.
- the blank area 19b may not be provided with the first insulating layer 19, and the blank area 19b may be connected to the first wall 110, for example, by welding the blank area 19b to the outer peripheral surface of the first wall 110.
- the insulating area is located below the first wall 110 and is provided with the first insulating layer 19.
- the housing 111 includes side walls and a bottom wall, the first wall 110 being an end cap, the blank area 19b being formed at the top of the inner surface of the side wall, and the insulating area being formed at the remaining position of the inner surface of the side wall and the inner surface of the bottom wall.
- the size of the blank area 19b in the first direction y can be greater than or equal to 5 mm, that is, it can be understood that the blank area 19b can provide the end cover with an area greater than or equal to 5 mm in the first direction y to facilitate welding of the shell 111 and the end cover.
- the blank area 19b may be formed by applying glue to set a non-coating area before preparing the insulating coating, or by cleaning the blank area 19b later through a laser cleaning process.
- the effect of the first insulating layer 19 on the connection between the housing 111 and the first wall 110 can be reduced.
- the first wall 110 and the housing 111 are welded to each other, and by providing the blank area 19b, good welding quality can be achieved between the first wall 110 and the housing 111, thereby improving the quality of the battery.
- the projection of the electrode assembly 12 on the inner wall of the shell 111 does not overlap with the blank area 19 b , and the second direction x is perpendicular to the first direction y.
- the second direction x is perpendicular to the first direction y.
- the first direction y is considered to be the height direction
- the second direction x can be the horizontal direction.
- "Along the second direction x, the projection of the electrode assembly 12 on the inner wall of the housing 111 does not overlap with the blank area 19b" can be understood to mean that the blank area 19b is located on the side of the electrode assembly 12 closest to the end cap.
- the thickness of the first insulating layer 19 is greater than or equal to 60 ⁇ m and less than or equal to 200 ⁇ m.
- the thickness of the first insulating layer 19 is M, and the value of M can be greater than or equal to 60 ⁇ m and less than or equal to 200 ⁇ m.
- the value of M can be 60 ⁇ m, 70 ⁇ m, 80 ⁇ m, 90 ⁇ m, 100 ⁇ m, ..., 180 ⁇ m, 190 ⁇ m, 200 ⁇ m, or any value between two adjacent values.
- the first insulating layer 19 can have high mechanical strength and insulation properties, effectively isolating the housing 111 from the electrolyte, reducing the risk of the housing 111 being corroded by the electrolyte due to negative charge, and thus making the battery more reliable.
- the first insulating layer 19 can effectively reduce the internal space occupied by the battery cell 10, making the battery cell 10 have a higher volumetric energy density, and thus making the battery have a higher volumetric energy density.
- both battery reliability and volumetric energy density can be taken into account.
- the thickness of the first insulating layer 19 is greater than or equal to 80 ⁇ m and less than or equal to 130 ⁇ m.
- the thickness of the first insulating layer 19 is M, which may be greater than or equal to 80 ⁇ m and less than or equal to 130 ⁇ m.
- M may be 80 ⁇ m, 90 ⁇ m, 100 ⁇ m, 110 ⁇ m, 120 ⁇ m, 130 ⁇ m, or any value between two adjacent values.
- the first insulating layer 19 can further have higher mechanical strength and insulation performance, effectively isolating the housing 111 from the electrolyte, reducing the risk of the housing 111 being corroded by the electrolyte due to negative charge, and thus making the battery more reliable.
- the first insulating layer 19 can further reduce the space occupied by the first insulating layer 19 in the internal space of the battery cell 10, so that the battery cell 10 has a higher volumetric energy density, and the battery has a higher volumetric energy density.
- the thickness of the first insulating layer 19 is greater than or equal to 80 ⁇ m and less than or equal to 130 ⁇ m, it is possible to effectively balance the reliability and volumetric energy density of the battery.
- Figure 17 is a schematic diagram of the housing 111 and the first insulating layer 19 in other embodiments of the present application.
- the outer surface of the housing 111 is provided with a second insulating layer 19a.
- the outer surface of the shell 111 is the surface of the shell 111 that contacts the outside world.
- the outer surface of the shell 111 includes the outer surface of the side wall of the shell 111 and the outer surface of the bottom wall of the shell 111 .
- the second insulating layer 19a is a layered structure provided on the outer surface of the housing 111 and has insulating properties.
- the second insulating layer 19a can be a coating or a thin plate-like, layered structure provided on the outer surface of the housing 111.
- the second insulating layer 19a may be an insulating coating, and the insulating coating may be made of epoxy resin, polyurethane, acrylic resin, polyimide, phenolic resin, etc.
- the second insulating layer 19a may be coated on the outer surface of the housing 111 by dipping, spraying, electroplating, anodizing, or other processes.
- the shell 111 can be effectively insulated and protected, reducing the risk of corrosion by the electrolyte due to negative charge of the shell 111, so that the battery has higher reliability.
- a battery is further provided, comprising the battery cell 10 described above.
- the battery 100 includes the battery cell 10 and a housing 20 , wherein the battery cell 10 is housed within the housing 20 .
- the housing 20 is used to accommodate the battery cell 10 and can have various structures.
- each battery cell 10 may be fixed to the case 20 via a connector (such as a bolt), or each battery cell 10 may be fixed to the case 20 by bonding.
- an energy storage device is further provided, and the energy storage device includes the battery cell 10 described above.
- battery cells 10 are first formed into a battery, and one or more of these cells are then used in an energy storage device.
- energy storage device 2000 may include a cabinet 2001 and multiple batteries 100. Multiple batteries 100 may be housed within cabinet 2001. Multiple batteries 100 may be connected in series, parallel, or in a hybrid configuration.
- an electric device comprising the above-described battery cell 10.
- the battery cell 10 first forms a battery 100, and one or more batteries 100 are then used in the electric device.
- the electrical device is a vehicle 1000 .
- a controller 200 , a motor 300 , and a battery 100 may be provided inside the vehicle 1000 .
- the controller 200 is used to control the battery 100 to supply power to the motor 300 .
- a battery cell 10 is provided, see Figures 4 to 17 .
- the battery cell 10 includes a housing 11 , an electrode assembly 12 , a first electrode terminal 13 , a first insulating portion 14 , a first deformable member 15 , a second electrode terminal 16 , a second insulating portion 17 , and a second deformable member 18 .
- the housing 11 includes a shell 111 and an end cap.
- the shell 111 has an interior formed with a receiving cavity for receiving the electrode assembly 12.
- the shell 111 has an opening communicating with the receiving cavity.
- the end cap closes the opening of the shell 111, so that the electrode assembly 12 is in a closed space.
- the end cap includes a main body 110a, a first reinforcement portion 110b, and a second reinforcement portion 110c.
- the first reinforcement portion 110b includes a first protrusion 110b0 located outside the main body 110a and a first recess 110b1 located inside the main body 110a.
- the first protrusion 110b0 and the first recess 110b1 are arranged opposite each other in the thickness direction of the end cap.
- the second reinforcement portion 110c includes a second protrusion 110c0 located outside the main body 110a and a second recess 110c1 located inside the main body 110a.
- the first protrusion 110b0 is formed with a first positioning groove 110b2, and the second protrusion 110c0 is formed with a second positioning groove 110c2.
- the first positioning groove 110b2 is formed with a first through hole 1100 and a second through hole 1101, while the second positioning groove 110c2 is formed with a fifth through hole 1102 and a sixth through hole 1103.
- the protrusion height of the first protrusion 110b0 may be greater than or equal to 0.5 mm and less than or equal to 3 mm. In some embodiments, the protrusion height of the second protrusion 110c0 may be greater than or equal to 0.5 mm and less than or equal to 3 mm.
- the first electrode terminal 13 is mounted in the first through-hole 1100.
- the first electrode terminal 13 includes a first portion 130 located on the outside of the end cap and a second portion 131 located at least partially on the inside of the end cap.
- the first portion 130 is used for electrical connection to external components, while the second portion 131 is electrically connected to the first tab 120 of the electrode assembly 12 via the first adapter 123.
- the first insulating portion 14 includes a first insulating member 140.
- the resistance of the first insulating member 140 is at least 200 megohms or greater.
- the first insulating member 140 includes a first body 1400, a first flange 1401, and a second flange 1402.
- the first body 1400 is located between the first portion 130 and the end cap.
- the first body 1400 is formed with a third through-hole 14001 and a fourth through-hole 14002.
- the third through-hole 14001 corresponds to the first through-hole 1100 and is provided for the first electrode terminal 13 to pass through.
- the fourth through-hole 14002 corresponds to the second through-hole 1101.
- the first flange 1401 is disposed on the surface of the first body 1400 away from the end cap and surrounds the outer circumference of the first portion 130.
- the second flange 1402 is disposed around the third through hole 14001 and is located between the hole wall of the first through hole 1100 and the first electrode terminal 13.
- the first deformable member 15 is welded to the inner side of the end cap and seals the second through-hole 1101.
- the first deformable member 15 may be a flip tab.
- the first deformable member 15 is configured to deform to partially pass through the second through-hole 1101 and contact the first portion 130.
- the first deformable member 15 is configured to deform to partially pass through the second through-hole 1101 and contact the first portion 130 when the internal pressure of the battery cell 10 reaches a first threshold.
- the second electrode terminal 16 is mounted in the fifth through-hole 1102.
- the second electrode terminal 16 includes a third portion 160 located on the outside of the end cap and a fourth portion 161 located at least partially on the inside of the end cap.
- the fourth portion 161 is connected to the second tab 121 of the electrode assembly 12 via the second adapter 124.
- the second insulating portion 17 includes a second insulating member 170.
- the resistance of the second insulating member 170 is at least 200 megohms or greater.
- the second insulating member 170 includes a second body 1700, a third flange 1701, and a fourth flange 1702. The second body 1700 is located between the third portion 160 and the end cap.
- the second body 1700 is formed with a seventh through-hole 17001 and an eighth through-hole 17002.
- the seventh through-hole 17001 corresponds to the fifth through-hole 1102 and is provided for the second electrode terminal 16 to pass through.
- the eighth through-hole 17002 corresponds to the sixth through-hole 1103.
- the third flange 1701 is disposed on the surface of the second body 1700 away from the end cap and surrounds the outer circumference of the third portion 160.
- the fourth flange 1702 is disposed around the seventh through hole 17001 and is located between the hole wall of the fifth through hole 1102 and the second electrode terminal 16.
- the second deformable member 18 is welded to the inner side of the end cap and closes the sixth through hole 1103.
- the second deformable member 18 can be a flip tab.
- the second deformable member 18 is configured to deform when the internal pressure of the battery cell 10 reaches a first level, such as a second threshold, so as to partially pass through the sixth through hole 1103 and contact the third portion 160.
- the second threshold value when the second electrode terminal 16 is a negative electrode terminal, the second threshold value may be greater than the first threshold value.
- the internal pressure of the battery cell 10 increases.
- the first deformable member 15 deforms, short-circuiting the first electrode terminal 13 and the outer casing 11.
- the second deformable member 18 deforms, short-circuiting the second electrode terminal 16 and the outer casing 11, thereby short-circuiting the positive and negative electrodes within the battery cell 10 and creating an internal short circuit.
- the resulting high current can melt the electrical connections within the battery cell 10, severing the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection.
- the fused electrical connections can include the first adapter 123 and/or the second adapter 124.
- the first adapter 123 has a first fuse portion, the flow area of which can be smaller than the flow area of the remaining portions of the first adapter 123. This allows the first fuse portion to melt when a large current flows, thereby severing the current path between the first tab 120 and the first electrode terminal 13.
- the second adapter 124 has a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the rest of the second adapter 124, so that when a larger current passes through, the second fuse portion can be melted, thereby disconnecting the current path between the second electrode tab 121 and the second electrode terminal 16.
- the provision of the first insulating portion 14 and the second insulating portion 17 effectively insulates and isolates the end cap from the first electrode terminal 13, as well as the second electrode terminal 16. This reduces the risk of internal short circuits in the battery cell 10 due to short circuits between the end cap and the electrode terminal, thereby enhancing battery reliability.
- the provision of the first insulating portion 14 and the second insulating portion 17 effectively reduces the risk of thermal runaway of the energy storage device due to the runaway of the remaining battery cells 10 in the battery, which could cause the outer casing 11 to be charged with high voltage, leading to high voltage conduction between the end cap and the electrode terminal, and thus causing internal short circuits in the battery cell 10.
- the inner wall of the housing 111 is provided with a first insulating layer 19, which may be an insulating coating.
- the insulating coating may be made of epoxy resin, polyurethane, acrylic resin, polyimide, phenolic resin, etc.
- the first insulating layer 19 may be applied to the inner wall of the housing 111 by a process such as dipping, spraying, electroplating, or anodizing.
- the insulation resistance of the first insulating layer 19 can meet 1000V, 5s, >1G ⁇ .
- the first insulating layer 19 is an insulating coating, which can meet the following conditions: electrolyte resistance at 60°C without swelling.
- the interior of the shell 111 can be set in a blank area 19b, where the first insulating layer 19 is not set, and the blank area 19b and the end cap are welded to each other.
- the electrolyte and the shell 111 can be effectively separated, the electrolyte ion path between the motor assembly and the shell 111 can be cut off, and the risk of corrosion of the shell 111 can be reduced;
- the first insulating layer 19 can be efficiently formed on the inner wall of the shell 111 by spraying or the like, so that the manufacturing efficiency of the battery is high;
- the insulating coating has high mechanical strength, which can effectively reduce the puncture of metal particles introduced by the manufacturing process, resulting in the electrode assembly 12 and the shell 11 being electrically connected to each other, causing the risk of internal short circuit of the battery cell 10 or the risk of corrosion of the shell 11, so that the reliability of the battery is high.
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Abstract
Description
相关申请的交叉引用CROSS-REFERENCE TO RELATED APPLICATIONS
本申请要求享有于2024年04月08日提交的名称为“电池单体、电池、储能装置和用电装置”的中国专利申请202410417335.7的优先权,上述申请的全部内容通过引用并入本文中。This application claims priority to Chinese patent application No. 202410417335.7 filed on April 8, 2024, entitled “Battery Cell, Battery, Energy Storage Device and Electrical Device,” and the entire contents of the above application are incorporated herein by reference.
本申请涉及电池技术领域,具体而言,涉及一种电池单体、电池、储能装置和用电装置。The present application relates to the field of battery technology, and in particular to a battery cell, a battery, an energy storage device, and an electrical device.
节能减排是汽车产业可持续发展的关键,电动车辆由于其节能环保的优势成为汽车产业可持续发展的重要组成部分。对于电动车辆而言,电池技术又是关乎其发展的一项重要因素。Energy conservation and emission reduction are key to the sustainable development of the automotive industry. Electric vehicles, due to their energy-saving and environmentally friendly advantages, have become an important component of the sustainable development of the automotive industry. For electric vehicles, battery technology is a key factor in their development.
在电池技术的发展中,如何提高电池的可靠性,是电池技术中一个亟需解决的技术问题。In the development of battery technology, how to improve battery reliability is a technical problem that needs to be solved urgently.
本申请提供了一种电池单体、电池、储能装置和用电装置,本申请提供的技术方案能够有效地提高电池的可靠性。The present application provides a battery cell, a battery, an energy storage device and an electrical device. The technical solution provided in the present application can effectively improve the reliability of the battery.
第一方面,本申请提供一种电池单体。电池单体包括外壳、电极组件、第一电极端子和第一绝缘部。外壳具有第一壁。电极组件设置于外壳内。第一电极端子设置于第一壁并与电极组件电连接,第一电极端子用于电能的输入和输出。第一绝缘部设置于第一壁和第一电极端子之间,用于绝缘隔离第一电极端子和第一壁。In a first aspect, the present application provides a battery cell. The battery cell includes a housing, an electrode assembly, a first electrode terminal, and a first insulating portion. The housing has a first wall. The electrode assembly is disposed within the housing. The first electrode terminal is disposed on the first wall and electrically connected to the electrode assembly, and is used for inputting and outputting electrical energy. The first insulating portion is disposed between the first wall and the first electrode terminal to insulate and isolate the first electrode terminal from the first wall.
上述方案中,通过在第一壁和第一电极端子之间设置第一绝缘部,能够有效地绝缘隔离第一壁和第一电极端子,降低因第一壁和第一电极端子之间短接导致电池单体内部短路的风险,使得电池的可靠性高。特别是在工作电压较高的储能装置中,通过在第一壁和第一电极端子之间设置第一绝缘部,能够有效地降低因电池中的其余电池单体失控而外壳带高压电,导致高压电导通第一壁和电极端子使得电池单体内部短路,致使储能装置热失控的风险。In the above solution, by providing the first insulating portion between the first wall and the first electrode terminal, the first wall and the first electrode terminal can be effectively insulated and isolated, reducing the risk of internal short circuits in the battery cells due to a short circuit between the first wall and the first electrode terminal, thereby enhancing battery reliability. In particular, in energy storage devices operating at higher voltages, providing the first insulating portion between the first wall and the first electrode terminal can effectively reduce the risk of thermal runaway of the energy storage device due to the remaining battery cells in the battery running out of control, causing the outer casing to be charged with high voltage, resulting in the high voltage electricity flowing through the first wall and the electrode terminal, causing an internal short circuit in the battery cells.
根据本申请的一些实施例,电池单体还包括第一变形件,第一变形件与第一壁电连接,第一变形件被配置为可以变形以与第一电极端子接触,以将第一电极端子与第一壁电连接。According to some embodiments of the present application, the battery cell further includes a first deformable member electrically connected to the first wall, and the first deformable member is configured to be deformable to contact the first electrode terminal to electrically connect the first electrode terminal to the first wall.
上述方案中,通过设置第一变形件,能够在电池单体内部压力达到一定程度,例如第一阈值时,通过第一变形件的变形以与第一电极端子接触,从而使得第一电极端子与第一壁电连接,实现电池单体内部短路,使得电池单体内部的电连接构件因短路产生的大电流而熔断,以切断电池单体的充放电回路,从而起到过充保护的作用,以及起到降低电池单体热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, by providing a first deformable member, when the internal pressure of the battery cell reaches a certain level, for example, a first threshold value, the first deformable member can be deformed to contact the first electrode terminal, thereby electrically connecting the first electrode terminal to the first wall, thereby realizing an internal short circuit in the battery cell, so that the electrical connection components inside the battery cell are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell, thereby playing a role in overcharge protection, and playing a role in reducing the risk of thermal runaway of the battery cell, thereby making the battery have higher reliability.
根据本申请的一些实施例,第一壁形成有第一通孔和第二通孔,第一电极端子穿过第一通孔。第一变形件封闭第二通孔,第一变形件被配置为可以变形以部分穿过第二通孔与第一电极端子接触。According to some embodiments of the present application, the first wall is formed with a first through hole and a second through hole, the first electrode terminal passes through the first through hole, the first deformable member closes the second through hole, and the first deformable member is configured to be deformable to partially pass through the second through hole to contact the first electrode terminal.
上述方案中,在电池单体内部压力达到一定程度,例如第一阈值时,电池单体的内部压力能够作用于第一变形件,使得第一变形件朝向第一壁的外侧变形以有效地接触第一电极端子的第一部分,从而有效地实现电池单体内部短路,使得电池单体内部的电连接构件因短路产生的大电流而熔断,以切断电池单体的充放电回路,从而起到降低电池单体热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, when the internal pressure of the battery cell reaches a certain level, such as the first threshold value, the internal pressure of the battery cell can act on the first deformable member, so that the first deformable member deforms toward the outside of the first wall to effectively contact the first part of the first electrode terminal, thereby effectively realizing an internal short circuit of the battery cell, so that the electrical connection components inside the battery cell are melted due to the large current generated by the short circuit, so as to cut off the charge and discharge circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
根据本申请的一些实施例,沿第一壁的厚度方向,第一电极端子位于第一壁的外侧的第一部分的投影与第一变形件的投影至少部分重叠。According to some embodiments of the present application, along the thickness direction of the first wall, a projection of a first portion of the first electrode terminal located outside the first wall at least partially overlaps with a projection of the first deformable member.
上述方案中,通过将第一变形件沿第一壁的厚度方向对应于第一部分设置,能够在电池单体内部压力达到一定程度,例如第一阈值时,以较小的变形量快速地接触第一部分,从而快速地使得第一电极端子和第一壁电连接,从而有效地实现电池单体内部短路,使得电池单体内部的电连接构件因短路产生的大电流而熔断,以切断电池单体的充放电回路,从而起到降低电池单体热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, by arranging the first deformable member corresponding to the first part along the thickness direction of the first wall, it is possible to quickly contact the first part with a smaller deformation amount when the internal pressure of the battery cell reaches a certain level, such as the first threshold value, so that the first electrode terminal and the first wall are quickly electrically connected, thereby effectively realizing an internal short circuit of the battery cell, so that the electrical connection components inside the battery cell are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
根据本申请的一些实施例,第一壁包括彼此连接的本体部和第一加强部,第一部分设置于第一加强部。According to some embodiments of the present application, the first wall includes a main body portion and a first reinforcement portion connected to each other, and the first portion is provided on the first reinforcement portion.
上述方案中,通过设置第一加强部,能够提高第一壁的整体强度,能够降低因电池单体内部压力或者外部冲击作用下,导致第一壁形变,致使第一变形件无法有效与第一部分接触以导通第一电极端子和第一壁的风险,能够使得第一变形件在电池单体过充等滥用工况下有效地与第一电极端子接触,从而有效地起到过充保护的作用,降低电池单体热失控的风险,使得电池具有较高的可靠性。In the above scheme, by providing the first reinforcement portion, the overall strength of the first wall can be improved, and the risk of deformation of the first wall due to internal pressure of the battery cell or external impact, which causes the first deformable member to be unable to effectively contact the first part to conduct electricity between the first electrode terminal and the first wall, can be reduced. The first deformable member can effectively contact the first electrode terminal under abuse conditions such as overcharging of the battery cell, thereby effectively playing the role of overcharging protection, reducing the risk of thermal runaway of the battery cell, and making the battery have higher reliability.
根据本申请的一些实施例,第一壁的长度大于或等于150mm,所述第一壁的宽度大于或等于45mm。According to some embodiments of the present application, the length of the first wall is greater than or equal to 150 mm, and the width of the first wall is greater than or equal to 45 mm.
根据本申请的一些实施例,第一加强部包括第一凸部,沿第一壁的厚度方向,第一凸部凸出于本体部沿第一壁的厚度方向上的一个表面。According to some embodiments of the present application, the first reinforcement portion includes a first protrusion, which protrudes from a surface of the main body portion along the thickness direction of the first wall.
上述方案中,通过设置第一凸部以加强第一壁的结构强度,能够有效地降低因电池单体内部压力或者外部冲击作用下,导致第一壁形变,致使第一变形件无法有效与第一部分接触以导通第一电极端子和第一壁的风险,使得电池具有较高的可靠性。In the above solution, by providing a first protrusion to strengthen the structural strength of the first wall, the risk of deformation of the first wall due to internal pressure of the battery cell or external impact, which causes the first deformable member to be unable to effectively contact the first part to conduct electricity between the first electrode terminal and the first wall, can be effectively reduced, thereby making the battery more reliable.
根据本申请的一些实施例,第一加强部还包括第一凹部,沿第一壁的厚度方向,第一凹部设置于本体部的另一个表面,且第一凹部与第一凸部相对设置。According to some embodiments of the present application, the first reinforcement portion further includes a first recessed portion, which is arranged on another surface of the main body portion along the thickness direction of the first wall, and the first recessed portion is arranged opposite to the first protruding portion.
上述方案中,在对应于第一凸部的位置设置第一凹部,一方面,能够降低第一凸部的成型难度并节省材料成本,另一方面,若第一凹部处于第一壁内侧时,则可以利用第一凹部的空间容纳更多的活性物质或者电解液,利于电池单体的能量密度或充放电性能的提高,若第一凹部处于第一壁外侧时,则可以利用第一凹部的空间容纳外部的结构件,利于电池体积能量密度的提高。In the above scheme, the first recess is provided at a position corresponding to the first protrusion. On the one hand, the difficulty of forming the first protrusion can be reduced and material costs can be saved. On the other hand, if the first recess is on the inner side of the first wall, the space of the first recess can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell. If the first recess is on the outer side of the first wall, the space of the first recess can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
根据本申请的一些实施例,第一凸部位于第一壁的外侧,第一凸部形成有第一定位槽,第一定位槽容纳第一部分以限制第一部分活动。According to some embodiments of the present application, the first protrusion is located on the outside of the first wall, and a first positioning groove is formed on the first protrusion. The first positioning groove accommodates the first part to limit the movement of the first part.
上述方案中,通过设置第一定位槽,能够有效地定位第一电极端子,限制第一电极端子的位移,一方面降低第一电极端子与电池单体的内部电连接构件脱离导致电池单体内部断路的风险,另一方面能够使得第一电极端子有效地与第一变形件配合,起到过充保护的作用,提高电池的可靠性。In the above scheme, by setting the first positioning groove, the first electrode terminal can be effectively positioned and the displacement of the first electrode terminal can be limited. On the one hand, the risk of the first electrode terminal being separated from the internal electrical connection component of the battery cell and causing internal short circuit of the battery cell is reduced. On the other hand, the first electrode terminal can be effectively cooperated with the first deformable member to play the role of overcharge protection and improve the reliability of the battery.
根据本申请的一些实施例,第一凸部位于第一壁的外侧,沿第一壁的厚度方向,第一凸部的凸出于本体部的尺寸大于等于0.1mm,且小于等于5mm。According to some embodiments of the present application, the first protrusion is located on the outside of the first wall, and along the thickness direction of the first wall, the dimension of the first protrusion protruding from the main body is greater than or equal to 0.1 mm and less than or equal to 5 mm.
上述方案中,通过将第一凸部的凸出于本体部的尺寸设置为大于等于0.1mm,能够有效地提高第一壁的结构强度,使得第一变形件在电池单体内部压力达到一定程度,例如第一阈值时有效地与第一电极端子接触,起到过充保护的作用,进而提高电池的可靠性;通过将第一凸部的凸出于本体部的尺寸设置为小于等于5mm,能够降低第一凸部对空间的占用,降低对电池体积能量密度的影响。为此,通过将第一凸部的凸出于本体部的尺寸设置为大于等于0.1mm且小于等于5mm,能够兼顾电池单体的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.1mm, the structural strength of the first wall can be effectively improved, allowing the first deformable member to effectively contact the first electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the first threshold, to provide overcharge protection, thereby improving the reliability of the battery. By setting the protrusion of the first protrusion from the main body to be less than or equal to 5mm, the space occupied by the first protrusion can be reduced, thereby reducing the impact on the battery's volumetric energy density. To this end, by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.1mm and less than or equal to 5mm, the reliability of the battery cell's overcharge protection and the battery's volumetric energy density can be balanced.
根据本申请的一些实施例,沿第一壁的厚度方向,第一凸部的凸出于本体部的尺寸大于等于0.5mm,且小于等于3mm。According to some embodiments of the present application, along the thickness direction of the first wall, the dimension of the first protrusion protruding from the main body is greater than or equal to 0.5 mm and less than or equal to 3 mm.
上述方案中,通过将第一凸部的凸出于本体部的尺寸设置为大于等于0.5mm,进一步地提高第一壁的结构强度,使得第一变形件在电池单体内部压力达到一定程度,例如第一阈值时高效地与第一电极端子接触,起到过充保护的作用,进而提高电池的可靠性;通过将第一凸部的凸出于本体部的尺寸设置为小于等于3mm,能够有效地降低第一凸部对空间的占用,降低对电池体积能量密度的影响。为此,通过将第一凸部的凸出于本体部的尺寸设置为大于等于0.5mm且小于等于3mm,能够兼顾电池单体的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.5mm, the structural strength of the first wall is further improved, allowing the first deformable member to efficiently contact the first electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the first threshold, thereby providing overcharge protection and thereby improving the reliability of the battery. By setting the protrusion of the first protrusion from the main body to be less than or equal to 3mm, the space occupied by the first protrusion can be effectively reduced, thereby reducing the impact on the battery's volumetric energy density. To this end, by setting the protrusion of the first protrusion from the main body to be greater than or equal to 0.5mm and less than or equal to 3mm, the reliability of the battery cell's overcharge protection and the battery's volumetric energy density can be balanced.
根据本申请的一些实施例,第一绝缘部包括第一绝缘件,第一绝缘件的至少部分设置于第一电极端子位于第一壁的外侧的第一部分和第一壁之间,第一绝缘件形成有第三通孔和第四通孔,沿第一壁的厚度方向,第三通孔与第一通孔相对设置,第四通孔与第二通孔相对设置。According to some embodiments of the present application, the first insulating portion includes a first insulating member, at least a portion of which is arranged between a first portion of the first electrode terminal located on the outside of the first wall and the first wall, and the first insulating member is formed with a third through hole and a fourth through hole, and along the thickness direction of the first wall, the third through hole is arranged opposite to the first through hole, and the fourth through hole is arranged opposite to the second through hole.
上述方案中,第一绝缘件结构简单,一方面通过第三通孔供第一电极端子穿过,使得第一电极端子与电极组件的电连接以及实现对外充放电,通过第四通孔供第一变形件变形以能够接触第一部分,实现过充保护;另一方面,第一绝缘件能够有效地绝缘隔离第一部分和第一壁,降低因第一部分与第一壁短接导致电池单体内部短路的风险,使得电池的可靠性高。In the above scheme, the first insulating member has a simple structure. On the one hand, the first electrode terminal is allowed to pass through the third through hole, so that the first electrode terminal is electrically connected to the electrode assembly and external charging and discharging is realized. The first deformable member is allowed to deform through the fourth through hole so as to contact the first part to realize overcharge protection. On the other hand, the first insulating member can effectively insulate and isolate the first part and the first wall, reducing the risk of internal short circuit of the battery cell due to short circuit between the first part and the first wall, thereby making the battery highly reliable.
根据本申请的一些实施例,第一绝缘件包括第一本体和第一凸缘,第一本体位于第一部分和第一壁之间,第一凸缘设置于第一本体背离于第一壁的表面,第一凸缘围设第一部分的外周面的至少部分。According to some embodiments of the present application, the first insulating member includes a first body and a first flange, the first body is located between the first part and the first wall, the first flange is arranged on the surface of the first body facing away from the first wall, and the first flange surrounds at least part of the outer peripheral surface of the first part.
上述方案中,通过设置第一本体和第一凸缘,能够有效地绝缘隔离第一壁和第一部分,使得第一部分与第一壁之间具有较远的爬电距离,使得第一绝缘件具有较高的绝缘性能,有效降低因第一壁和第一电极端子之间短接导致电池单体内部短路的风险,使得电池的可靠性高。In the above solution, by setting the first body and the first flange, the first wall and the first part can be effectively insulated and isolated, so that there is a longer creepage distance between the first part and the first wall, and the first insulating member has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell due to short circuit between the first wall and the first electrode terminal, so that the battery has high reliability.
根据本申请的一些实施例,第一绝缘件还包括第二凸缘,第二凸缘绕第三通孔设置,且位于第一通孔的孔壁和第一电极端子之间。According to some embodiments of the present application, the first insulating member further includes a second flange, which is disposed around the third through hole and is located between a hole wall of the first through hole and the first electrode terminal.
上述方案中,通过设置第二凸缘,能够有效地绝缘隔离第一通孔的孔壁和第一电极端子,降低第一电极端子与第一通孔的孔壁接触导致电池单体内部短路的风险,有效地提高电池的可靠性。In the above solution, by providing the second flange, the hole wall of the first through hole and the first electrode terminal can be effectively insulated and isolated, reducing the risk of the first electrode terminal contacting the hole wall of the first through hole and causing internal short circuit in the battery cell, thereby effectively improving the reliability of the battery.
根据本申请的一些实施例,电池单体还包括第二电极端子、第二绝缘部和第二变形件。第二电极端子设置于第一壁并与电极组件电连接,第二电极端子用于电能的输入和输出,第二电极端子和第一电极端子的极性相反。第二绝缘部设置于第一壁和第二电极端子之间,用于绝缘隔离第二电极端子和第一壁。第二变形件与第一壁电连接,第二变形件被配置为可以变形以与第二电极端子接触,以将第二电极端子与第一壁电连接。According to some embodiments of the present application, the battery cell further includes a second electrode terminal, a second insulating portion, and a second deformable member. The second electrode terminal is disposed on the first wall and electrically connected to the electrode assembly. The second electrode terminal is used for input and output of electrical energy, and the second electrode terminal and the first electrode terminal have opposite polarities. The second insulating portion is disposed between the first wall and the second electrode terminal to insulate and isolate the second electrode terminal from the first wall. The second deformable member is electrically connected to the first wall and is configured to be deformable to contact the second electrode terminal to electrically connect the second electrode terminal to the first wall.
上述方案中,一方面,通过在第一壁和第二电极端子之间设置第二绝缘部,能够有效地绝缘隔离第一壁和第二电极端子,降低因第一壁和第二电极端子之间短接导致电池单体内部短路的风险,使得电池的可靠性高;另一方面,通过设置第二变形件,在电池单体内部压力达到一定程度,例如第二阈值时,通过第二变形件的变形以与第二电极端子接触,从而使得第二电极端子与第二壁电连接,配合第一变形件与第一电极端子的短接,使得电池单体内部的电连接构件因短路产生的大电流而熔断,以切断电池单体的充放电回路,从而起到过充保护的作用,以及起到降低电池单体热失控的风险的作用,进而使得电池具有较高的可靠性;再一方面,因第一电极端子和第二电极端子在未滥用工况下均与第一壁绝缘隔离,故电池单体的外壳可以不带电,以利于该电池单体构成储能装置,使得储能装置中相邻的两个电池单体之间打火击穿的风险小,同时,通过设置第二变形件以能够有效地实现过充保护的作用,使得该储能装置可靠性高。In the above scheme, on the one hand, by providing a second insulating portion between the first wall and the second electrode terminal, the first wall and the second electrode terminal can be effectively insulated and isolated, thereby reducing the risk of internal short circuit of the battery cell due to short circuit between the first wall and the second electrode terminal, and making the battery highly reliable; on the other hand, by providing a second deformable member, when the internal pressure of the battery cell reaches a certain level, such as a second threshold value, the second deformable member is deformed to contact the second electrode terminal, thereby electrically connecting the second electrode terminal to the second wall, and cooperating with the short circuit between the first deformable member and the first electrode terminal, the electrical connection component inside the battery cell is not short-circuited. The large current generated by the short circuit causes the fuse to cut off the charge and discharge circuit of the battery cell, thereby playing a role in overcharge protection and reducing the risk of thermal runaway of the battery cell, thereby making the battery have higher reliability; on the other hand, because the first electrode terminal and the second electrode terminal are both insulated and isolated from the first wall under non-abuse conditions, the outer shell of the battery cell can be uncharged, which is conducive to the battery cell forming an energy storage device, so that the risk of ignition and breakdown between two adjacent battery cells in the energy storage device is small. At the same time, by providing the second deformable member, the overcharge protection function can be effectively achieved, so that the energy storage device has high reliability.
根据本申请的一些实施例,第二电极端子为负极电极端子,使得所述第二变形件变形的最小压力值大于使得所述第一变形件变形的最小压力值。According to some embodiments of the present application, the second electrode terminal is a negative electrode terminal, so that the minimum pressure value for deformation of the second deformation member is greater than the minimum pressure value for deformation of the first deformation member.
上述方案中,在第二电极端子为负极电极端子时,通过将使得第二变形件变形的最小压力值大于使得第一变形件变形的最小压力值,能够使得第二变形件较第一变形件在电池单体内部压力更大的时候变形,一方面,能够使得电池单体具有过充保护功能,另一方面,能够降低在非过充滥用工况下,在电池单体内部产气导致第二变形件翻转致使外壳带负电而被电解液腐蚀的风险,从而一定程度上保证外壳的完整性,降低电解液泄露的风险,进而提供电池的可靠性。In the above scheme, when the second electrode terminal is the negative electrode terminal, by making the minimum pressure value that causes the second deforming member to deform greater than the minimum pressure value that causes the first deforming member to deform, the second deforming member can be deformed when the pressure inside the battery cell is greater than that of the first deforming member. On the one hand, the battery cell can have an overcharge protection function. On the other hand, it can reduce the risk of gas production inside the battery cell causing the second deforming member to flip over, resulting in the shell being negatively charged and corroded by the electrolyte under non-overcharge abuse conditions, thereby ensuring the integrity of the shell to a certain extent, reducing the risk of electrolyte leakage, and thus improving the reliability of the battery.
根据本申请的一些实施例,第一壁形成有第五通孔和第六通孔,第二电极端子穿过第五通孔。第二变形件封闭第六通孔,第二变形件被配置为可以变形以部分穿过第六通孔与第二电极端子接触。According to some embodiments of the present application, the first wall is formed with a fifth through hole and a sixth through hole, the second electrode terminal passes through the fifth through hole, the second deformable member closes the sixth through hole, and the second deformable member is configured to be deformable to partially pass through the sixth through hole to contact the second electrode terminal.
上述方案中,在电池单体内部压力达到一定程度,例如第二阈值时,电池单体的内部压力能够作用于第二变形件,使得第二变形件朝向第一壁的外侧变形以有效地接触第二电极端子的第三部分,配合第一变形件与第一电极端子接触,使得电池单体内部的电连接构件因短路产生的大电流而熔断,以切断电池单体的充放电回路,从而起到降低电池单体热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, when the internal pressure of the battery cell reaches a certain level, such as the second threshold value, the internal pressure of the battery cell can act on the second deformable member, so that the second deformable member deforms toward the outside of the first wall to effectively contact the third part of the second electrode terminal, and cooperates with the first deformable member to contact the first electrode terminal, so that the electrical connection component inside the battery cell is melted due to the large current generated by the short circuit, so as to cut off the charging and discharging circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
根据本申请的一些实施例,沿第一壁的厚度方向,第二电极端子位于第一壁的外侧的第三部分的投影与第二变形件的投影至少部分重叠。According to some embodiments of the present application, along the thickness direction of the first wall, a projection of a third portion of the second electrode terminal located outside the first wall at least partially overlaps with a projection of the second deformable member.
上述方案中,通过将第二变形件沿第一壁的厚度方向对应于第三部分设置,能够在电池单体内部压力达到一定程度,例如第二阈值,以较小的变形量快速地接触第三部分,从而快速地使得第二电极端子和第一壁电连接,配合第一变形件与第一电极端子接触,使得电池单体内部的电连接构件因短路产生的大电流而熔断,以切断电池单体的充放电回路,从而起到降低电池单体热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, by arranging the second deformable member corresponding to the third part along the thickness direction of the first wall, when the pressure inside the battery cell reaches a certain level, such as the second threshold, the third part can be quickly contacted with a smaller deformation amount, thereby quickly electrically connecting the second electrode terminal and the first wall, and cooperating with the first deformable member to contact the first electrode terminal, the electrical connection component inside the battery cell is melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell, thereby reducing the risk of thermal runaway of the battery cell, and thus making the battery have higher reliability.
根据本申请的一些实施例,第一壁包括彼此连接的本体部和第二加强部,第二电极端子位于第一壁的外侧的第三部分设置于第二加强部。According to some embodiments of the present application, the first wall includes a main body portion and a second reinforcement portion connected to each other, and the third portion of the second electrode terminal located outside the first wall is disposed on the second reinforcement portion.
上述方案中,通过设置第二加强部,能够提高第一壁的整体强度,能够降低因电池单体内部压力或者外部冲击作用下,导致第一壁形变,致使第二变形件无法有效与第三部分接触以导通第二电极端子和第一壁的风险,能够使得第二变形件在电池单体过充等滥用工况下有效地与第二电极端子接触,从而有效地起到过充保护的作用,降低电池单体热失控的风险,使得电池具有较高的可靠性。In the above scheme, by providing a second reinforcement portion, the overall strength of the first wall can be improved, and the risk of deformation of the first wall due to internal pressure of the battery cell or external impact, which causes the second deformable member to be unable to effectively contact the third part to conduct electricity between the second electrode terminal and the first wall, can be reduced. The second deformable member can effectively contact the second electrode terminal under abuse conditions such as overcharging of the battery cell, thereby effectively playing a role in overcharging protection, reducing the risk of thermal runaway of the battery cell, and making the battery have higher reliability.
根据本申请的一些实施例,第二加强部包括第二凸部,第二凸部凸出于本体部沿第一壁的厚度方向上的一个表面。According to some embodiments of the present application, the second reinforcing portion includes a second protrusion protruding from a surface of the body portion along the thickness direction of the first wall.
上述方案中,通过设置第二凸部以加强第一壁的结构强度,能够有效地降低因电池单体内部压力或者外部冲击作用下,导致第一壁形变,致使第二变形件无法有效与第三部分接触以导通第二电极端子和第一壁的风险,使得电池具有较高的可靠性。In the above solution, by providing a second protrusion to strengthen the structural strength of the first wall, the risk of deformation of the first wall due to internal pressure of the battery cell or external impact, which causes the second deformable member to be unable to effectively contact the third part to conduct electricity between the second electrode terminal and the first wall, can be effectively reduced, thereby making the battery more reliable.
根据本申请的一些实施例,第二加强部还包括第二凹部,沿第一壁的厚度方向,第二凹部设置于本体部的另一个表面,且第二凹部与第二凸部相对设置。According to some embodiments of the present application, the second reinforcement portion further includes a second recessed portion, which is arranged on another surface of the main body portion along the thickness direction of the first wall, and the second recessed portion is arranged opposite to the second protruding portion.
上述方案中,在对应于第二凸部的位置设置第二凹部,一方面,能够降低第二凸部的成型难度并节省材料成本,另一方面,若第二凹部处于第一壁内侧时,则可以利用第二凹部的空间容纳更多的活性物质或者电解液,利于电池单体的能量密度或充放电性能的提高,若第二凹部处于第一壁外侧时,则可以利用第二凹部的空间容纳外部的结构件,利于电池体积能量密度的提高。In the above scheme, a second recess is provided at a position corresponding to the second protrusion. On the one hand, the difficulty of forming the second protrusion can be reduced and material costs can be saved. On the other hand, if the second recess is on the inner side of the first wall, the space of the second recess can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell. If the second recess is on the outer side of the first wall, the space of the second recess can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
根据本申请的一些实施例,第二凸部位于第一壁的外侧,第二凸部形成有第二定位槽,第二定位槽容纳第三部分以限制第三部分活动。According to some embodiments of the present application, the second protrusion is located on the outside of the first wall, and a second positioning groove is formed on the second protrusion. The second positioning groove accommodates the third part to limit the movement of the third part.
上述方案中,通过设置第二定位槽,能够有效地定位第二电极端子,限制第二电极端子的位移,一方面降低第二电极端子与电池单体的内部电连接构件脱离导致电池单体内部断路的风险,另一方面能够使得第二电极端子有效地与第二变形件配合,起到过充保护的作用,提高电池的可靠性。In the above scheme, by setting the second positioning groove, the second electrode terminal can be effectively positioned and the displacement of the second electrode terminal can be limited. On the one hand, the risk of the second electrode terminal being separated from the internal electrical connection component of the battery cell and causing internal short circuit of the battery cell is reduced. On the other hand, the second electrode terminal can be effectively cooperated with the second deformable member to play the role of overcharge protection and improve the reliability of the battery.
根据本申请的一些实施例,第二凸部位于第一壁的外侧,沿第一壁的厚度方向,第二凸部的凸出于本体部的尺寸大于等于0.1mm,且小于等于5mm。According to some embodiments of the present application, the second protrusion is located on the outside of the first wall, and along the thickness direction of the first wall, the dimension of the second protrusion protruding from the main body is greater than or equal to 0.1 mm and less than or equal to 5 mm.
上述方案中,通过将第二凸部的凸出于本体部的尺寸设置为大于等于0.1mm,能够有效地提高第一壁的结构强度,使得第二变形件在电池单体内部压力达到一定程度,例如第二阈值时有效地与第二电极端子接触,起到过充保护的作用,进而提高电池的可靠性;通过将第二凸部的凸出于本体部的尺寸设置为小于等于5mm,能够降低第二凸部对空间的占用,降低对电池体积能量密度的影响。为此,通过将第二凸部的凸出于本体部的尺寸设置为大于等于0.1mm且小于等于5mm,能够兼顾电池单体的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.1mm, the structural strength of the first wall can be effectively improved, allowing the second deformable member to effectively contact the second electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the second threshold, to provide overcharge protection, thereby improving the reliability of the battery. By setting the protrusion of the second protrusion from the main body to be less than or equal to 5mm, the space occupied by the second protrusion can be reduced, thereby reducing the impact on the battery's volumetric energy density. To this end, by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.1mm and less than or equal to 5mm, the reliability of the battery cell overcharge protection and the battery's volumetric energy density can be balanced.
根据本申请的一些实施例,沿第一壁的厚度方向,第二凸部的凸出于本体部的尺寸大于等于0.5mm,且小于等于3mm。According to some embodiments of the present application, along the thickness direction of the first wall, the dimension of the second protrusion protruding from the main body is greater than or equal to 0.5 mm and less than or equal to 3 mm.
上述方案中,通过将第二凸部的凸出于本体部的尺寸设置为大于等于0.5mm,进一步地提高第一壁的结构强度,使得第二变形件在电池单体内部压力达到一定程度,例如第二阈值时高效地与第二电极端子接触,起到过充保护的作用,进而提高电池的可靠性;通过将第二凸部的凸出于本体部的尺寸设置为小于等于3mm,能够有效地降低第二凸部对空间的占用,降低对电池体积能量密度的影响。为此,通过将第二凸部的凸出于本体部的尺寸设置为大于等于0.5mm且小于等于3mm,能够兼顾电池单体的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.5mm, the structural strength of the first wall is further improved, allowing the second deformable member to effectively contact the second electrode terminal when the internal pressure of the battery cell reaches a certain level, such as the second threshold, to provide overcharge protection, thereby improving the reliability of the battery. By setting the protrusion of the second protrusion from the main body to be less than or equal to 3mm, the space occupied by the second protrusion can be effectively reduced, thereby reducing the impact on the battery's volumetric energy density. To this end, by setting the protrusion of the second protrusion from the main body to be greater than or equal to 0.5mm and less than or equal to 3mm, the reliability of the battery cell overcharge protection and the volumetric energy density of the battery can be balanced.
根据本申请的一些实施例,第二绝缘部包括第二绝缘件,第二绝缘件的至少部分设置于第三部分和第一壁之间,第二绝缘件形成有第七通孔和第八通孔,沿第一壁的厚度方向,第七通孔与第五通孔相对设置,第八通孔与第六通孔相对设置。According to some embodiments of the present application, the second insulating portion includes a second insulating member, at least a portion of which is arranged between the third portion and the first wall, and the second insulating member is formed with a seventh through hole and an eighth through hole. Along the thickness direction of the first wall, the seventh through hole is arranged opposite to the fifth through hole, and the eighth through hole is arranged opposite to the sixth through hole.
上述方案中,第二绝缘件结构简单,一方面通过第七通孔供第二电极端子穿过,使得第二电极端子与电极组件的电连接以及实现对外充放电,通过第八通孔供第二变形件变形以能够接触第三部分,实现过充保护;另一方面,第二绝缘件能够有效地绝缘隔离第三部分和第一壁,降低因第三部分与第一壁短接导致电池单体内部短路的风险,使得电池的可靠性高。In the above scheme, the second insulating member has a simple structure. On the one hand, the second electrode terminal is allowed to pass through the seventh through hole, so that the second electrode terminal is electrically connected to the electrode assembly and external charging and discharging is realized. The second deformable member is allowed to deform through the eighth through hole so as to contact the third part to achieve overcharge protection. On the other hand, the second insulating member can effectively insulate and isolate the third part and the first wall, reducing the risk of internal short circuit of the battery cell due to short circuit between the third part and the first wall, thereby making the battery highly reliable.
根据本申请的一些实施例,第二绝缘件包括第二本体和第三凸缘,第二本体位于第三部分和第一壁之间,第三凸缘设置于第二本体背离于第一壁的表面,第三凸缘围设第三部分的外周面的至少部分。According to some embodiments of the present application, the second insulating member includes a second body and a third flange, the second body is located between the third part and the first wall, the third flange is arranged on the surface of the second body facing away from the first wall, and the third flange surrounds at least part of the outer peripheral surface of the third part.
上述方案中,通过设置第二本体和第三凸缘,能够有效地绝缘隔离第一壁和第三部分,使得第三部分与第一壁之间具有较远的爬电距离,使得第二绝缘件具有较高的绝缘性能,有效降低因第一壁和第二电极端子之间短接导致电池单体内部短路的风险,使得电池的可靠性高。In the above solution, by providing the second body and the third flange, the first wall and the third part can be effectively insulated and isolated, so that there is a longer creepage distance between the third part and the first wall, and the second insulating member has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell due to short circuit between the first wall and the second electrode terminal, thereby increasing the reliability of the battery.
根据本申请的一些实施例,第二绝缘件还包括第四凸缘,第四凸缘绕第七通孔设置,且位于第五通孔的孔壁和第二电极端子之间。According to some embodiments of the present application, the second insulating member further includes a fourth flange, which is arranged around the seventh through hole and is located between the hole wall of the fifth through hole and the second electrode terminal.
上述方案中,通过设置第四凸缘,能够有效地绝缘隔离第五通孔的孔壁和第二电极端子,降低第二电极端子与第五通孔的孔壁接触导致电池单体内部短路的风险,有效地提高电池的可靠性。In the above solution, by providing the fourth flange, the hole wall of the fifth through hole and the second electrode terminal can be effectively insulated and isolated, reducing the risk of the second electrode terminal contacting the hole wall of the fifth through hole and causing internal short circuit in the battery cell, thereby effectively improving the reliability of the battery.
根据本申请的一些实施例,第二绝缘部的电阻值大于等于200兆欧。According to some embodiments of the present application, the resistance value of the second insulating portion is greater than or equal to 200 megohms.
上述方案中,通过将第二绝缘部的电阻值设置为大于等于200兆欧,能够有效地提高第二电极端子和第一壁之间的绝缘耐高压性,能够有效适应储能装置的绝缘耐压需求,降低外部电压击穿第二绝缘部导通第一壁和第二电极端子,致使电池单体内部短路的风险,使得储能装置具有较高的可靠性。In the above solution, by setting the resistance value of the second insulating portion to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the second electrode terminal and the first wall can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the second insulating portion and conducting the first wall and the second electrode terminal, causing an internal short circuit in the battery cell, thereby making the energy storage device more reliable.
根据本申请的一些实施例,第一绝缘部的电阻值大于等于200兆欧。According to some embodiments of the present application, the resistance value of the first insulating portion is greater than or equal to 200 megohms.
上述方案中,通过将第一绝缘部的电阻值设置为大于等于200兆欧,能够有效地提高第一电极端子和第一壁之间的绝缘耐高压性,能够有效适应储能装置的绝缘耐压需求,降低外部电压击穿第一绝缘部导通第一壁和第一电极端子,致使电池单体内部短路的风险,使得储能装置具有较高的可靠性。In the above solution, by setting the resistance value of the first insulating portion to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the first electrode terminal and the first wall can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the first insulating portion, connecting the first wall and the first electrode terminal, and causing an internal short circuit in the battery cell, thereby making the energy storage device more reliable.
根据本申请的一些实施例,外壳包括壳体和端盖,壳体具有开口。第一壁为端盖,端盖与壳体连接并封闭开口。According to some embodiments of the present application, the housing includes a shell and an end cover, wherein the shell has an opening. The first wall is the end cover, which is connected to the shell and closes the opening.
上述方案中,外壳结构简单,便于电池单体的装配,利于电池制造效率的提升。In the above solution, the shell structure is simple, which facilitates the assembly of battery cells and helps improve battery manufacturing efficiency.
根据本申请的一些实施例,壳体的内壁设置有第一绝缘层。According to some embodiments of the present application, a first insulating layer is provided on the inner wall of the shell.
上述方案中,通过在壳体的内部设置第一绝缘层,能够有效地绝缘隔离壳体内部的电解液与壳体的内壁,从而降低壳体被电解液腐蚀的风险,降低电解线泄漏的风险,使得电池具有较高的可靠性。In the above solution, by providing a first insulating layer inside the shell, the electrolyte inside the shell can be effectively insulated and isolated from the inner wall of the shell, thereby reducing the risk of the shell being corroded by the electrolyte and the risk of electrolytic wire leakage, making the battery more reliable.
根据本申请的一些实施例,第一绝缘层为设置于壳体内壁的绝缘涂层。According to some embodiments of the present application, the first insulating layer is an insulating coating provided on the inner wall of the shell.
上述方案中,通过在壳体的内壁设置绝缘涂层,一方面能够有效地分隔电解液和壳体,切断电机组件与壳体之间的电解液离子通路,降低壳体被腐蚀的风险;另一方面采用喷涂等方式能够高效地在壳体内壁形成第一绝缘层,使得电池的制造效率高;再一方面,绝缘涂层具有较高的机械强度,能够有效地降低有制造工艺引入的金属颗粒刺穿,导致电极组件和外壳相互电连接,致使电池单体内部短路的风险或者致使外壳被腐蚀的风险,使得电池的可靠性高。In the above scheme, by providing an insulating coating on the inner wall of the shell, on the one hand, the electrolyte and the shell can be effectively separated, the electrolyte ion path between the motor assembly and the shell can be cut off, and the risk of shell corrosion can be reduced; on the other hand, the first insulating layer can be efficiently formed on the inner wall of the shell by spraying or other methods, so that the manufacturing efficiency of the battery is high; on the other hand, the insulating coating has high mechanical strength, which can effectively reduce the puncture of metal particles introduced by the manufacturing process, resulting in electrical connection between the electrode assembly and the shell, causing the risk of internal short circuit of the battery cell or the risk of corrosion of the shell, so that the battery has high reliability.
根据本申请的一些实施例,沿第一方向,壳体的内壁包括依次连接的留白区和绝缘区,绝缘区设置有第一绝缘层,留白区与第一壁连接,第一方向平行于第一壁指向电极组件的方向。According to some embodiments of the present application, along the first direction, the inner wall of the shell includes a blank area and an insulating area connected in sequence, the insulating area is provided with a first insulating layer, the blank area is connected to the first wall, and the first direction is parallel to the first wall and points to the direction of the electrode assembly.
上述方案中,通过设置留白区,能够降低第一绝缘层对壳体和第一壁相互连接部位的影响。示例性地,第一壁与壳体相互焊接,通过设置留白区,能够使得第一壁和壳体之间具有良好的焊接质量,进而使得电池的质量高。In the above solution, by providing a blank area, the effect of the first insulating layer on the connection between the shell and the first wall can be reduced. For example, the first wall and the shell are welded to each other, and by providing a blank area, the welding quality between the first wall and the shell can be improved, thereby improving the quality of the battery.
根据本申请的一些实施例,沿第二方向,电极组件落在壳体的内壁的投影与留白区不重合,第二方向与第一方向垂直。According to some embodiments of the present application, along the second direction, the projection of the electrode assembly on the inner wall of the shell does not overlap with the blank area, and the second direction is perpendicular to the first direction.
上述方案中,通过将电极组件与留白区错位设置,能够降低电极组件与留白区搭接导致电池单体内部短路或者外壳因带负电而被电解液腐蚀的风险,能够有效地提高电池单体的可靠性,进而提高电池的可靠性。In the above scheme, by staggering the electrode assembly and the blank area, the risk of internal short circuit of the battery cell or corrosion of the outer shell by the electrolyte due to negative charge caused by overlapping of the electrode assembly and the blank area can be reduced, which can effectively improve the reliability of the battery cell and thus improve the reliability of the battery.
根据本申请的一些实施例,第一绝缘层的厚度大于等于60μm,且小于等于200μm。According to some embodiments of the present application, the thickness of the first insulating layer is greater than or equal to 60 μm and less than or equal to 200 μm.
上述方案中,通过将第一绝缘层的厚度设置为大于或等于60μm,能够使得第一绝缘层具有较高的机械强度和绝缘性能,有效地隔离壳体和电解液,降低壳体因带负电而被电解液腐蚀的风险,使得电池具有较高的可靠性;通过将第一绝缘层的厚度设置为小于等于200μm,能够有效地降低第一绝缘层对电池单体内部空间的占用,使得电池单体具有较高的体积能量密度,使得电池具有较高的体积能量密度。为此,通过将第一绝缘层的厚度设置为大于或等于60μm,且小于等于200μm,能够兼顾电池的可靠性和体积能量密度。In the above solution, by setting the thickness of the first insulating layer to be greater than or equal to 60μm, the first insulating layer can have high mechanical strength and insulation performance, effectively isolating the shell from the electrolyte, reducing the risk of the shell being corroded by the electrolyte due to negative charge, and thus making the battery more reliable. By setting the thickness of the first insulating layer to be less than or equal to 200μm, the first insulating layer can effectively reduce the internal space occupied by the battery cell, making the battery cell have a higher volumetric energy density, and thus the battery has a higher volumetric energy density. To this end, by setting the thickness of the first insulating layer to be greater than or equal to 60μm and less than or equal to 200μm, both battery reliability and volumetric energy density can be taken into account.
根据本申请的一些实施例,第一绝缘层的厚度大于等于80μm,且小于等于130μm。According to some embodiments of the present application, the thickness of the first insulating layer is greater than or equal to 80 μm and less than or equal to 130 μm.
上述方案中,通过将第一绝缘层的厚度设置为大于或等于80μm,能够进一步地使得第一绝缘层具有较高的机械强度和绝缘性能,有效地隔离壳体和电解液,降低壳体因带负电而被电解液腐蚀的风险,使得电池具有较高的可靠性;通过将第一绝缘层的厚度设置为小于等于130μm,能够进一步地降低第一绝缘层对电池单体内部空间的占用,使得电池单体具有较高的体积能量密度,使得电池具有较高的体积能量密度。为此,通过将第一绝缘层的厚度设置为大于或等于80μm,且小于等于130μm,能够有效地兼顾电池的可靠性和体积能量密度。In the above solution, by setting the thickness of the first insulating layer to be greater than or equal to 80μm, the first insulating layer can further have higher mechanical strength and insulation performance, effectively isolating the shell and the electrolyte, reducing the risk of the shell being corroded by the electrolyte due to negative charge, and making the battery more reliable. By setting the thickness of the first insulating layer to be less than or equal to 130μm, the first insulating layer can further reduce the internal space occupied by the battery cell, making the battery cell have a higher volume energy density, and thus the battery has a higher volume energy density. To this end, by setting the thickness of the first insulating layer to be greater than or equal to 80μm and less than or equal to 130μm, it is possible to effectively balance the reliability and volume energy density of the battery.
根据本申请的一些实施例,壳体的外表面设置有第二绝缘层。According to some embodiments of the present application, a second insulating layer is provided on the outer surface of the shell.
上述方案中,通过在壳体的外表面设置第二绝缘层,能够有效地对壳体起到绝缘保护的效果,降低因壳体带负电导致被电解液腐蚀的风险,使得电池具有较高的可靠性。In the above solution, by providing a second insulating layer on the outer surface of the shell, the shell can be effectively insulated and protected, reducing the risk of corrosion by the electrolyte due to negative charge of the shell, so that the battery has higher reliability.
第二方面,本申请一些实施例提供一种电池,包括权利要求第一方面提供的电池单体。In a second aspect, some embodiments of the present application provide a battery, comprising the battery cell provided in the first aspect of claim 1.
第三方面,本申请一些实施例提供一种储能装置,包括第一方面提供的电池单体。In a third aspect, some embodiments of the present application provide an energy storage device comprising the battery cell provided in the first aspect.
第四方面,本申请一些实施例提供一种用电装置,包括第一方面提供的电池单体,电池单体用于提供电能。In a fourth aspect, some embodiments of the present application provide an electrical device, comprising the battery cell provided in the first aspect, wherein the battery cell is used to provide electrical energy.
本申请的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本申请的实践了解到。Additional aspects and advantages of the present application will be given in part in the description below, and in part will become obvious from the description below, or will be learned through practice of the present application.
为了更清楚地说明本申请实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本申请的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present application, the following is a brief introduction to the drawings required for use in the embodiments. It should be understood that the following drawings only show certain embodiments of the present application and therefore should not be regarded as limiting the scope. For ordinary technicians in this field, other relevant drawings can be obtained based on these drawings without creative work.
图1为本申请一些实施例中车辆的示意图;FIG1 is a schematic diagram of a vehicle in some embodiments of the present application;
图2为本申请一些实施例中储能装置的示意图;FIG2 is a schematic diagram of an energy storage device in some embodiments of the present application;
图3为本申请一些实施例中电池的立体分解图;FIG3 is an exploded perspective view of a battery in some embodiments of the present application;
图4为本申请一些实施例中电池单体的立体分解图;FIG4 is an exploded perspective view of a battery cell in some embodiments of the present application;
图5为本申请一些实施例中电池单体的局部结构的立体分解图;FIG5 is a perspective exploded view of a partial structure of a battery cell in some embodiments of the present application;
图6为本申请一些实施例中电池单体的局部结构的俯视图;FIG6 is a top view of a partial structure of a battery cell in some embodiments of the present application;
图7为图6中A-A视向的剖视图;FIG7 is a cross-sectional view taken along the line A-A in FIG6 ;
图8为本申请一些实施例中第一壁和第一电极端子的示意图;FIG8 is a schematic diagram of a first wall and a first electrode terminal in some embodiments of the present application;
图9为本申请一些实施例中第一变形件的示意图;FIG9 is a schematic diagram of a first deformable member in some embodiments of the present application;
图10为本申请一些实施例中第一壁的立体图;FIG10 is a perspective view of a first wall in some embodiments of the present application;
图11为本申请一些实施例中第一壁的局部结构示意图;FIG11 is a schematic diagram of a partial structure of a first wall in some embodiments of the present application;
图12为本申请一些实施例中第一壁和第二电极端子的示意图;FIG12 is a schematic diagram of a first wall and a second electrode terminal in some embodiments of the present application;
图13为本申请一些实施例中第二变形件的示意图;FIG13 is a schematic diagram of a second deformable member in some embodiments of the present application;
图14为本申请一些实施例中第一壁的局部示意图;FIG14 is a partial schematic diagram of the first wall in some embodiments of the present application;
图15为本申请一些实施例中壳体和电极组件的示意图;FIG15 is a schematic diagram of a housing and an electrode assembly in some embodiments of the present application;
图16为本申请一些实施例中壳体和第一绝缘层的示意图;FIG16 is a schematic diagram of a housing and a first insulating layer in some embodiments of the present application;
图17为本申请另一些实施例中壳体和第一绝缘层的示意图。FIG17 is a schematic diagram of the shell and the first insulating layer in some other embodiments of the present application.
图标:10-电池单体;11-外壳;110-第一壁;111-壳体;1100-第一通孔;1101-第二通孔;1102-第五通孔;1103-第六通孔;110a-本体部;110b-第一加强部;110b0-第一凸部;110b1-第一凹部;110b2-第一定位槽;110c-第二加强部;110c0-第二凸部;110c1-第二凹部;110c2-第二定位槽;12-电极组件;120-第一极耳;121-第二极耳;123-第一转接件;124-第二转接件;13-第一电极端子;130-第一部分;131-第二部分;14-第一绝缘部;140-第一绝缘件;1400-第一本体;14001-第三通孔;14002-第四通孔;1401-第一凸缘;1402-第二凸缘;141-第一密封部;15-第一变形件;150-第一裙边;151-第一翻转箔;152-第一电连接部;16-第二电极端子;160-第三部分;161-第四部分;17-第二绝缘部;170-第二绝缘件;1700-第二本体;17001-第七通孔;17002-第八通孔;1701-第三凸缘;1702-第四凸缘;171-第二密封部;18-第二变形件;180-第二裙边;181-第二翻转箔;182-第二电连接部;19-第一绝缘层;19a-第二绝缘层;19b-留白区;z-第一壁的厚度方向;y-第一方向;x-第二方向;1000-车辆;100-电池;200-控制器;300-马达;2000-储能装置;2001-柜体;20-箱体;21-第一箱体部;22-第二箱体部。Icons: 10 - battery cell; 11 - housing; 110 - first wall; 111 - housing; 1100 - first through hole; 1101 - second through hole; 1102 - fifth through hole; 1103 - sixth through hole; 110a - body; 110b - first reinforcement; 110b0 - first convex portion; 110b1 - first concave portion; 110b2 - first positioning groove; 110c - second reinforcement; 110c0 - second convex portion; 110c1 - second concave portion; 110c2 - second positioning groove; 12 - electrode assembly; 120 - first electrode tab; 121 - second electrode tab; 123 - first adapter; 124 - second adapter; 13 - first electrode terminal; 130 - first portion; 131 - second portion; 14 - first insulating portion; 140 - first insulating member; 1400 - first body; 14001 - third through hole; 14002 - fourth through hole; 1401 - first flange; 1402 - second flange; 14 1-first sealing portion; 15-first deforming member; 150-first skirt; 151-first flip foil; 152-first electrical connection portion; 16-second electrode terminal; 160-third portion; 161-fourth portion; 17-second insulating portion; 170-second insulating member; 1700-second body; 17001-seventh through hole; 17002-eighth through hole; 1701-third flange; 1702-fourth flange; 171-second sealing portion; 18- Second deformable member; 180-second skirt; 181-second flip foil; 182-second electrical connection portion; 19-first insulating layer; 19a-second insulating layer; 19b-blank area; z-thickness direction of the first wall; y-first direction; x-second direction; 1000-vehicle; 100-battery; 200-controller; 300-motor; 2000-energy storage device; 2001-cabinet; 20-box; 21-first box part; 22-second box part.
下面将结合附图对本申请技术方案的实施例进行详细的描述。以下实施例仅用于更加清楚地说明本申请的技术方案,因此只作为示例,而不能以此来限制本申请的保护范围。The following embodiments of the technical solution of the present application will be described in detail with reference to the accompanying drawings. The following embodiments are only used to more clearly illustrate the technical solution of the present application and are therefore only examples and are not intended to limit the scope of protection of the present application.
除非另有定义,本文所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同;本文中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请;本申请的说明书和权利要求书及上述附图说明中的术语“包括”和“具有”以及它们的任何变形,意图在于覆盖不排他的包含。Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by those skilled in the art to which this application belongs; the terms used herein are only for the purpose of describing specific embodiments and are not intended to limit this application; the terms "including" and "having" and any variations thereof in the specification and claims of this application and the above-mentioned figure descriptions are intended to cover non-exclusive inclusions.
在本申请实施例的描述中,技术术语“第一”“第二”等仅用于区别不同对象,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量、特定顺序或主次关系。在本申请实施例的描述中,“多个”的含义是两个以上,除非另有明确具体的限定。In the description of the embodiments of this application, the technical terms "first" and "second" are used only to distinguish different objects and should not be understood to indicate or imply relative importance or implicitly specify the quantity, specific order, or primary and secondary relationship of the indicated technical features. In the description of the embodiments of this application, the meaning of "plurality" is more than two, unless otherwise clearly and specifically defined.
在本文中提及“实施例”意味着,结合实施例描述的特定特征、结构或特性可以包含在本申请的至少一个实施例中。在说明书中的各个位置出现该短语并不一定均是指相同的实施例,也不是与其它实施例互斥的独立的或备选的实施例。本领域技术人员显式地和隐式地理解的是,本文所描述的实施例可以与其它实施例相结合。References herein to "embodiments" mean that a particular feature, structure, or characteristic described in connection with the embodiments may be included in at least one embodiment of the present application. The appearance of this phrase in various places in the specification does not necessarily refer to the same embodiment, nor does it constitute an independent or alternative embodiment that is mutually exclusive of other embodiments. It is understood, both explicitly and implicitly, by those skilled in the art that the embodiments described herein may be combined with other embodiments.
在本申请实施例的描述中,术语“和/或”仅仅是一种描述关联对象的关联关系,表示可以存在三种关系,例如A和/或B,可以表示:存在A,同时存在A和B,存在B这三种情况。另外,本文中字符“/”,一般表示前后关联对象是一种“或”的关系。In the description of the embodiments of this application, the term "and/or" is simply a description of the association relationship between associated objects, indicating that three relationships can exist. For example, A and/or B can represent the following three situations: A exists, A and B exist at the same time, and B exists. In addition, the character "/" in this document generally indicates that the associated objects are in an "or" relationship.
在本申请实施例的描述中,术语“多个”指的是两个以上(包括两个),同理,“多组”指的是两组以上(包括两组),“多片”指的是两片以上(包括两片)。In the description of the embodiments of the present application, the term "multiple" refers to more than two (including two). Similarly, "multiple groups" refers to more than two groups (including two groups), and "multiple pieces" refers to more than two pieces (including two pieces).
在本申请实施例的描述中,技术术语“中心”“纵向”“横向”“长度”“宽度”“厚度”“上”“下”“前”“后”“左”“右”“竖直”“水平”“顶”“底”“内”“外”“顺时针”“逆时针”“轴向”“径向”“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请实施例和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请实施例的限制。In the description of the embodiments of the present application, the technical terms "center", "longitudinal", "lateral", "length", "width", "thickness", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", "clockwise", "counterclockwise", "axial", "radial", "circumferential", etc., indicating the orientation or position relationship, are based on the orientation or position relationship shown in the accompanying drawings, and are only for the convenience of describing the embodiments of the present application and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the embodiments of the present application.
在本申请实施例的描述中,除非另有明确的规定和限定,技术术语“安装”“相连”“连接”“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;也可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请实施例中的具体含义。In the description of the embodiments of the present application, unless otherwise expressly specified or limited, technical terms such as "installed," "connected," "connected," and "fixed" should be understood in a broad sense. For example, they can refer to fixed connections, detachable connections, or integration; mechanical connections or electrical connections; direct connections or indirect connections through an intermediate medium; internal connections between two components or interactions between two components. Those skilled in the art can understand the specific meanings of the above terms in the embodiments of the present application based on specific circumstances.
本申请中,电池单体可以包括锂离子二次电池、锂离子一次电池、锂硫电池、钠锂离子电池、钠离子电池或镁离子电池等,本申请实施例对此并不限定。电池单体可呈长方体或其它形状等,本申请实施例对此也不限定。本申请的实施例所提到的电池是指包括一个或多个电池单体以提供更高的电压和容量的单一的物理模块。电池一般包括用于封装一个或多个电池单体的箱体。箱体可以避免液体或其他异物影响电池单体的充电或放电。In the present application, battery cells may include lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-lithium-ion batteries, sodium-ion batteries or magnesium-ion batteries, etc., which are not limited in the embodiments of the present application. Battery cells may be rectangular or in other shapes, etc., which are not limited in the embodiments of the present application. The battery mentioned in the embodiments of the present application refers to a single physical module that includes one or more battery cells to provide higher voltage and capacity. The battery generally includes a casing for encapsulating one or more battery cells. The casing can prevent liquids or other foreign matter from affecting the charging or discharging of the battery cells.
电池单体包括电极组件和电解液,电极组件由正极片、负极片和隔膜组成。电池单体主要依靠金属离子在正极片和负极片之间移动(例如脱嵌)来工作。正极片包括正极集流体和正极活性物质层,正极活性物质层涂覆于正极集流体的表面,未涂敷正极活性物质层的正极集流体凸出于已涂覆正极活性物质层的正极集流体,未涂敷正极活性物质层的正极集流体作为正极耳。以锂离子电池为例,正极集流体的材料可以为铝,正极活性物质可以为钴酸锂、磷酸铁锂、三元锂或锰酸锂等。负极片包括负极集流体和负极活性物质层,负极活性物质层涂覆于负极集流体的表面,未涂敷负极活性物质层的负极集流体凸出于已涂覆负极活性物质层的负极集流体,未涂敷负极活性物质层的负极集流体作为负极耳。负极集流体的材料可以为铜,负极活性物质可以为碳或硅等。为了一定程度上保证通过大电流而不发生熔断,正极耳的数量为多个且层叠在一起,负极耳的数量为多个且层叠在一起。隔离膜的材质可以为PP(polypropylene,聚丙烯)或PE(polyethylene,聚乙烯)等。此外,电极组件可以是卷绕式结构,也可以是叠片式结构,本申请实施例并不限于此。A battery cell includes an electrode assembly and an electrolyte. The electrode assembly consists of a positive electrode sheet, a negative electrode sheet, and a separator. A battery cell primarily operates by the movement (e.g., deintercalation) of metal ions between the positive and negative electrode sheets. The positive electrode sheet includes a positive current collector and a positive active material layer. The positive active material layer is coated on the surface of the positive electrode collector. The positive electrode collector not coated with the positive active material layer protrudes from the positive electrode collector coated with the positive active material layer, and the positive electrode collector not coated with the positive active material layer serves as the positive electrode tab. For lithium-ion batteries, for example, the positive electrode current collector can be made of aluminum, and the positive electrode active material can be lithium cobalt oxide, lithium iron phosphate, ternary lithium, or lithium manganese oxide. The negative electrode sheet includes a negative current collector and a negative active material layer. The negative active material layer is coated on the surface of the negative electrode collector. The negative electrode collector not coated with the negative active material layer protrudes from the negative electrode collector coated with the negative active material layer, and the negative electrode collector not coated with the negative active material layer serves as the negative electrode tab. The negative electrode current collector can be made of copper, and the negative electrode active material can be carbon or silicon, among others. To ensure that high currents can flow without fusing, multiple positive electrode tabs are stacked together, and multiple negative electrode tabs are stacked together. The separator can be made of materials such as PP (polypropylene) or PE (polyethylene). Furthermore, the electrode assembly can be a wound or laminated structure, although the embodiments of the present application are not limited thereto.
电池单体还包括外壳,电极组件和电解液设置于外壳的内部。外壳具有第一壁,第一壁设置有电极端子,电极端子与电极组件连接,电极端子用于电能的输入和输出。The battery cell also includes a housing, an electrode assembly and an electrolyte disposed inside the housing. The housing has a first wall, and the first wall is provided with an electrode terminal connected to the electrode assembly, and the electrode terminal is used for input and output of electrical energy.
电池技术的发展要同时考虑多方面的设计因素,例如,能量密度、循环寿命、放电容量、充放电倍率等性能参数,另外,还需要考虑电池的可靠性。The development of battery technology must take into account multiple design factors at the same time, such as energy density, cycle life, discharge capacity, charge and discharge rate and other performance parameters. In addition, battery reliability must also be considered.
随电池技术的发展,电池的工作电压越来越大。对于单个的电池单体,较大的电压容易导通第一壁和电极端子,造成电池单体内部短路,影响电池的可靠性。With the development of battery technology, the operating voltage of batteries is getting higher and higher. For a single battery cell, the high voltage can easily conduct the first wall and the electrode terminal, causing an internal short circuit in the battery cell and affecting the reliability of the battery.
鉴于此,为改善第一壁和电极端子短接,导致电池单体内部短路,影响电池可靠性的问题,本申请一些实施例提供一种电池单体。电池单体包括外壳、电极组件、第一电极端子和第一绝缘部。外壳具有第一壁。电极组件设置于外壳内。第一电极端子设置于第一壁并与电极组件电连接,第一电极端子用于电能的输入和输出。第一绝缘部设置于第一壁和第一电极端子之间,用于绝缘隔离第一电极端子和第一壁。In view of this, in order to improve the problem of short circuit between the first wall and the electrode terminal, which causes an internal short circuit in the battery cell and affects the reliability of the battery, some embodiments of the present application provide a battery cell. The battery cell includes a housing, an electrode assembly, a first electrode terminal and a first insulating portion. The housing has a first wall. The electrode assembly is disposed within the housing. The first electrode terminal is disposed on the first wall and electrically connected to the electrode assembly, and the first electrode terminal is used for input and output of electrical energy. The first insulating portion is disposed between the first wall and the first electrode terminal to insulate and isolate the first electrode terminal from the first wall.
上述方案中,通过在第一壁和第一电极端子之间设置第一绝缘部,能够有效地绝缘隔离第一壁和第一电极端子,降低因第一壁和第一电极端子之间短接导致电池单体内部短路的风险,使得电池的可靠性高。特别是在工作电压较高的储能装置中,通过在第一壁和第一电极端子之间设置第一绝缘部,能够有效地降低因电池中的其余电池单体失控而外壳带高压电,导致高压电导通第一壁和电极端子使得电池单体内部短路,致使储能装置热失控的风险。In the above solution, by providing the first insulating portion between the first wall and the first electrode terminal, the first wall and the first electrode terminal can be effectively insulated and isolated, reducing the risk of internal short circuits in the battery cells due to a short circuit between the first wall and the first electrode terminal, thereby enhancing battery reliability. In particular, in energy storage devices operating at higher voltages, providing the first insulating portion between the first wall and the first electrode terminal can effectively reduce the risk of thermal runaway of the energy storage device due to the remaining battery cells in the battery running out of control, causing the outer casing to be charged with high voltage, resulting in the high voltage electricity flowing through the first wall and the electrode terminal, causing an internal short circuit in the battery cells.
本申请实施例描述的技术方案适用于电池以及使用电池的储能装置以及使用电池的用电装置。The technical solutions described in the embodiments of the present application are applicable to batteries, energy storage devices using batteries, and electrical devices using batteries.
储能装置可以包括储能集装箱、储能电柜等。示例性地,储能电柜可以包括柜体以及设置于柜体上的一个或者多个电池。The energy storage device may include an energy storage container, an energy storage cabinet, etc. For example, the energy storage cabinet may include a cabinet body and one or more batteries disposed on the cabinet body.
用电装置可以是车辆、手机、便携式设备、笔记本电脑、轮船、航天器、电动玩具和电动工具等等。车辆可以是新能源汽车,新能源汽车可以是纯电动汽车、混合动力汽车或增程式汽车等;航天器包括飞机、火箭、航天飞机和宇宙飞船等等;电动玩具包括固定式或移动式的电动玩具,例如,游戏机、电动汽车玩具、电动轮船玩具和电动飞机玩具等等;电动工具包括金属切削电动工具、研磨电动工具、装配电动工具和铁道用电动工具,例如,电钻、电动砂轮机、电动扳手、电动螺丝刀、电锤、冲击电钻、混凝土振动器和电刨等等。本申请实施例中的用电装置包括但不限于上述提到的。The electrical device can be a vehicle, a mobile phone, a portable device, a laptop computer, a ship, a spacecraft, an electric toy, an electric tool, etc. The vehicle can be a new energy vehicle, which can be a pure electric vehicle, a hybrid vehicle, or an extended-range vehicle, etc. The spacecraft includes airplanes, rockets, space shuttles, and spacecraft, etc. The electric toys include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, and electric airplane toys, etc. The electric tools include metal cutting electric tools, grinding electric tools, assembly electric tools, and railway electric tools, such as electric drills, electric grinders, electric wrenches, electric screwdrivers, electric hammers, impact drills, concrete vibrators, and electric planers, etc. The electrical devices in the embodiments of the present application include but are not limited to those mentioned above.
以下实施例为了方便说明,以用电装置为车辆为例进行说明。For the convenience of description, the following embodiments are described by taking a vehicle as an example of an electrical device.
图1为本申请一些实施例中车辆的示意图。FIG1 is a schematic diagram of a vehicle in some embodiments of the present application.
车辆1000的内部可以设置控制器200、马达300和电池100,控制器200用来控制电池100为马达300供电。例如,在车辆1000的底部或车头或车尾可以设置电池100。电池100可以用于车辆1000的供电,例如,电池100可以作为车辆1000的操作电源,用于车辆1000的电路系统,例如,用于车辆1000的启动、导航和运行时的工作用电需求。在本申请的另一实施例中,电池100不仅仅可以作为车辆1000的操作电源,还可以作为车辆1000的驱动电源,替代或部分地替代燃油或天然气为车辆1000提供驱动动力。A controller 200, a motor 300, and a battery 100 may be provided inside the vehicle 1000. The controller 200 is used to control the battery 100 to power the motor 300. For example, the battery 100 may be provided at the bottom, front, or rear of the vehicle 1000. The battery 100 may be used to power the vehicle 1000. For example, the battery 100 may serve as an operating power source for the vehicle 1000 and for the circuit system of the vehicle 1000, for example, for the starting, navigation, and operating power requirements of the vehicle 1000. In another embodiment of the present application, the battery 100 may serve not only as an operating power source for the vehicle 1000, but also as a driving power source for the vehicle 1000, replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000.
请参见图2,图2为本申请一些实施例中储能装置的示意图。Please refer to FIG2 , which is a schematic diagram of an energy storage device in some embodiments of the present application.
储能装置2000可以包括柜体2001以及多个电池100。多个电池100可以设置于柜体2001内。多个电池100之间可以相互串联、并联或者混联。The energy storage device 2000 may include a cabinet 2001 and a plurality of batteries 100. The plurality of batteries 100 may be disposed in the cabinet 2001. The plurality of batteries 100 may be connected in series, in parallel, or in a mixed manner.
请参见图3,图3为本申请一些实施例中电池100的立体分解图。Please refer to FIG3 , which is a three-dimensional exploded view of the battery 100 in some embodiments of the present application.
电池100包括电池单体10和箱体20,电池单体10容纳于箱体20内。其中,箱体20用于为电池单体10提供容纳空间,箱体20可以采用多种结构。在一些实施例中,箱体20可以包括第一箱体部21和第二箱体部22,第一箱体部21与第二箱体部22相互盖合,第一箱体部21和第二箱体部22共同限定出用于容纳电池单体10的容纳空间。第二箱体部22可以为一端开口的空心结构,第一箱体部21可以为板状结构,第一箱体部21盖合于第二箱体部22的开口侧,以使第一箱体部21与第二箱体部22共同限定出容纳空间;第一箱体部21和第二箱体部22也可以是均为一侧开口的空心结构,第一箱体部21的开口侧盖合于第二箱体部22的开口侧。当然,第一箱体部21和第二箱体部22形成的箱体20可以是多种形状,比如,圆柱体、长方体等。The battery 100 includes a battery cell 10 and a housing 20, wherein the battery cell 10 is housed within the housing 20. The housing 20 is used to provide a storage space for the battery cell 10, and the housing 20 can adopt a variety of structures. In some embodiments, the housing 20 can include a first housing portion 21 and a second housing portion 22, wherein the first housing portion 21 and the second housing portion 22 overlap each other, and the first housing portion 21 and the second housing portion 22 jointly define a storage space for accommodating the battery cell 10. The second housing portion 22 can be a hollow structure with one end open, and the first housing portion 21 can be a plate-like structure, with the first housing portion 21 overlapping the open side of the second housing portion 22, so that the first housing portion 21 and the second housing portion 22 jointly define a storage space; the first housing portion 21 and the second housing portion 22 can also be hollow structures with one end open, with the open side of the first housing portion 21 overlapping the open side of the second housing portion 22. Of course, the box body 20 formed by the first box body portion 21 and the second box body portion 22 can be in various shapes, such as a cylinder, a cuboid, etc.
在电池100中,电池单体10可以是一个也可以是多个,且各电池单体10可以通过连接件(如螺栓)固定于箱体20,或者各电池单体10可以通过粘接的方式固定于箱体20。In the battery 100 , there may be one or more battery cells 10 , and each battery cell 10 may be fixed to the case 20 via a connector (such as a bolt), or each battery cell 10 may be fixed to the case 20 by bonding.
请参见图4-图8,图4为本申请一些实施例中电池单体10的立体分解图,图5为本申请一些实施例中电池单体10的局部结构的立体分解图,图6为本申请一些实施例中电池单体10的局部结构的俯视图,图7为图6中A-A视向的剖视图,图8为本申请一些实施例中第一壁和第一电极端子的示意图。Please refer to Figures 4 to 8. Figure 4 is a three-dimensional exploded view of the battery cell 10 in some embodiments of the present application, Figure 5 is a three-dimensional exploded view of the local structure of the battery cell 10 in some embodiments of the present application, Figure 6 is a top view of the local structure of the battery cell 10 in some embodiments of the present application, Figure 7 is a cross-sectional view taken along the A-A direction in Figure 6, and Figure 8 is a schematic diagram of the first wall and the first electrode terminal in some embodiments of the present application.
电池单体10包括外壳11、电极组件12、第一电极端子13和第一绝缘部14。外壳11具有第一壁110。电极组件12设置于外壳11内。第一电极端子13设置于第一壁110并与电极组件12电连接,第一电极端子13用于电能的输入和输出。第一绝缘部14设置于第一壁110和第一电极端子13之间,用于绝缘隔离第一电极端子13和第一壁110。The battery cell 10 includes a housing 11, an electrode assembly 12, a first electrode terminal 13, and a first insulating portion 14. The housing 11 has a first wall 110. The electrode assembly 12 is disposed within the housing 11. The first electrode terminal 13 is disposed on the first wall 110 and electrically connected to the electrode assembly 12. The first electrode terminal 13 is used for inputting and outputting electrical energy. The first insulating portion 14 is disposed between the first wall 110 and the first electrode terminal 13 to insulate and isolate the first electrode terminal 13 from the first wall 110.
外壳11为用于容纳电极组件12的部件,外壳11还可以用于容纳电解质,比如电解液。请参见图4,在一些实施例中,外壳11包括壳体111和端盖。壳体111的内部形成有容纳腔,容纳腔用于容纳电极组件12,壳体111具有连通容纳腔的开口,端盖盖合于壳体111的开口处并形成密封连接,以形成用于容纳电极组件12和电解质的密封空间。端盖可以通过焊接、粘接、卡接或者其他连接方式与壳体111连接。可选地,外壳11还可以包括底板,壳体111的两端分别形成有开口,其中一个开口被端盖封闭,另一个开口被底板封闭。The housing 11 is a component for accommodating the electrode assembly 12. The housing 11 can also be used to accommodate an electrolyte, such as an electrolyte. Referring to Figure 4, in some embodiments, the housing 11 includes a shell 111 and an end cap. A accommodating cavity is formed inside the shell 111, and the accommodating cavity is used to accommodate the electrode assembly 12. The shell 111 has an opening connected to the accommodating cavity. The end cap is covered at the opening of the shell 111 and forms a sealed connection to form a sealed space for accommodating the electrode assembly 12 and the electrolyte. The end cap can be connected to the shell 111 by welding, bonding, clamping or other connection methods. Optionally, the housing 11 may also include a bottom plate, and openings are respectively formed at both ends of the shell 111, one of the openings is closed by the end cap, and the other opening is closed by the bottom plate.
在一些实施例中,外壳11的材质可以金属或者金属与非金属的组合,例如,外壳11可以为金属制得,如铝、铜、铁、钢或铝合金等;又例如外壳11的部分可以通过金属制得,其余部分可以通过非金属制得,如外壳11的端盖可以通过金属制得,外壳11的壳体111或者其他部位可以通过非金属材料制得。In some embodiments, the material of the shell 11 can be metal or a combination of metal and non-metal. For example, the shell 11 can be made of metal, such as aluminum, copper, iron, steel or aluminum alloy; for example, part of the shell 11 can be made of metal, and the rest can be made of non-metal, such as the end cover of the shell 11 can be made of metal, and the shell 111 or other parts of the shell 11 can be made of non-metallic materials.
在一些实施例中,在组装电池单体10时,可以先将电极组件12放入壳体111内,并向壳体111内填充电解液,之后再将端盖盖合于壳体111的开口,以完成电池单体10的组装。或者,在一些实施例中,在组装电池单体10时,可以先将电极组件12放入壳体111内,再将端盖盖合于壳体111的开口,再通过端盖上的注液孔向壳体111内填充电解液,随后封闭注液孔以完成电池单体10的组装。In some embodiments, when assembling the battery cell 10, the electrode assembly 12 may be placed in the housing 111 first, and the housing 111 may be filled with electrolyte, and then the end cap may be attached to the opening of the housing 111 to complete the assembly of the battery cell 10. Alternatively, in some embodiments, when assembling the battery cell 10, the electrode assembly 12 may be placed in the housing 111 first, and then the end cap may be attached to the opening of the housing 111, and then the housing 111 may be filled with electrolyte through the injection hole on the end cap, and then the injection hole may be closed to complete the assembly of the battery cell 10.
外壳11可以是多种形状,比如,圆柱体或棱柱结构等。外壳11的形状可根据电极组件12的具体形状来确定。比如,若电极组件12为圆柱体结构,则可选用圆柱体结构的外壳11。若电极组件12为扁平状的结构,则外壳11可以为方形。The housing 11 can have various shapes, such as a cylindrical or prismatic structure. The shape of the housing 11 can be determined based on the specific shape of the electrode assembly 12. For example, if the electrode assembly 12 has a cylindrical structure, a cylindrical housing 11 can be selected. If the electrode assembly 12 has a flat structure, the housing 11 can be square.
第一壁110为外壳11的部分结构。第一壁110可以用于承载支撑第一电极端子13,使得第一电极端子13处于稳定地状态以实现电能的输入和输出。在一些实施例中,第一壁110可以为壳体111的部分,例如壳体111的侧壁或者底壁。在一些实施例中,第一壁110可以端盖。First wall 110 is part of the housing 11. It can support first electrode terminal 13, ensuring a stable ground state for electrical energy input and output. In some embodiments, first wall 110 can be part of housing 111, such as a side wall or bottom wall of housing 111. In some embodiments, first wall 110 can serve as an end cap.
第一电极端子13为安装于第一壁110的部件,第一电极端子13用于与电极组件12电连接,用于使得电流经第一电极端子13流入或者流出于第一极耳120。第一电极端子13和第一极耳120的极性相同。在一些实施例中,第一电极端子13为金属材料制得,例如通过铝、铜、铁、铝、钢、合金或者复合金属制得。在一些实施例中,第一电极端子13可以通过第一转接件123与第一极耳120连接。示例性地,电极组件12的第一极耳120由多个第一子极耳层叠构成,可以向将第一转接件123的一端与第一极耳120焊接后,再将第一转接件123的另一端与第一电极端子13焊接。The first electrode terminal 13 is a component mounted on the first wall 110. The first electrode terminal 13 is used to electrically connect to the electrode assembly 12 so that current flows into or out of the first electrode tab 120 through the first electrode terminal 13. The polarity of the first electrode terminal 13 and the first electrode tab 120 is the same. In some embodiments, the first electrode terminal 13 is made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal. In some embodiments, the first electrode terminal 13 can be connected to the first electrode tab 120 through a first adapter 123. Exemplarily, the first electrode tab 120 of the electrode assembly 12 is composed of a plurality of first sub-tabs stacked together. After welding one end of the first adapter 123 to the first electrode tab 120, the other end of the first adapter 123 can be welded to the first electrode terminal 13.
第一绝缘部14具有较高电阻值,能够使得第一电极端子13与第一壁110相互绝缘。示例性地,请参见图5,第一电极端子13具有暴露于外的第一部分130,第一绝缘部14可以设置于第一壁110的外侧面和第一部分130之间以绝缘隔离第一电极端子13和第一壁110。在一些实施例中,第一绝缘部14可以包覆第一部分130的外周,提高第一电极端子13与第一壁110的爬电距离。The first insulating portion 14 has a high resistance, insulating the first electrode terminal 13 from the first wall 110. For example, referring to FIG5 , the first electrode terminal 13 has an exposed first portion 130. The first insulating portion 14 can be disposed between the outer side of the first wall 110 and the first portion 130 to insulate the first electrode terminal 13 from the first wall 110. In some embodiments, the first insulating portion 14 can cover the outer periphery of the first portion 130 to increase the creepage distance between the first electrode terminal 13 and the first wall 110.
示例性地,在一些实施例中,第一壁110上形成有第一通孔1100,第一电极端子13可以穿过第一通孔1100以在外侧形成第一部分130,在内侧形成第二部分131,第一部分130用于与外部电连接构件连接,第二部分131用于与电极组件12电连接。第一绝缘部14对应于第一通孔1100形成有第三通孔14001,以供第一电极端子13穿过。可选地,第一绝缘部14的主要部分位于第一部分130和第一壁110之间,第一绝缘部14的一些部分可以位于第一通孔1100和第一电极端子13之间。可选地,第一绝缘部14的主要部分位于第一部分130和第一壁110之间,第一绝缘部14的一些部分可以位于第一通孔1100和第一电极端子13之间,第一绝缘部14的剩余部分还可以位于第一壁110和第二部分131之间。For example, in some embodiments, a first through-hole 1100 is formed in the first wall 110. The first electrode terminal 13 can pass through the first through-hole 1100 to form a first portion 130 on the outside and a second portion 131 on the inside. The first portion 130 is used to connect to an external electrical connection member, and the second portion 131 is used to electrically connect to the electrode assembly 12. The first insulating portion 14 has a third through-hole 14001 formed in correspondence with the first through-hole 1100 for the first electrode terminal 13 to pass through. Alternatively, a major portion of the first insulating portion 14 is located between the first portion 130 and the first wall 110, while some portion of the first insulating portion 14 may be located between the first through-hole 1100 and the first electrode terminal 13. Alternatively, a major portion of the first insulating portion 14 is located between the first portion 130 and the first wall 110, while some portion of the first insulating portion 14 may be located between the first through-hole 1100 and the first electrode terminal 13, with the remaining portion of the first insulating portion 14 further located between the first wall 110 and the second portion 131.
在一些实施例中,第一绝缘部14整体可以呈板状,其相对的两个表面均较为平整,以稳定地处于第一电极端子13和第一壁110之间。In some embodiments, the first insulating portion 14 may be in a plate shape as a whole, and its two opposite surfaces are relatively flat so as to be stably positioned between the first electrode terminal 13 and the first wall 110 .
在一些实施例中,第一绝缘部14可以通过较高电阻值的材料制得,如有机绝缘材料、无机绝缘材料或者混合绝缘材料等。示例性地,本申请一些实施例中,第一绝缘部14的材料可以包括绝缘PPS(聚苯硫醚)材料。在其他一些实施例中,第一绝缘部14还可以为聚丙烯、聚乙烯等其他具有绝缘特性的材料制得。In some embodiments, the first insulating portion 14 can be made of a material with a relatively high resistance, such as an organic insulating material, an inorganic insulating material, or a mixed insulating material. For example, in some embodiments of the present application, the material of the first insulating portion 14 can include an insulating PPS (polyphenylene sulfide) material. In other embodiments, the first insulating portion 14 can also be made of other materials with insulating properties, such as polypropylene and polyethylene.
在一些实施例中,第一绝缘部14的电阻值可以以兆欧(MΩ)为单元。示例性地,本申请一些实施例提供的电池单体10中,第一绝缘部14的电阻值可以大于或者等于200MΩ。在其他一些实施例中,第一绝缘部14的电阻值的取值可以为其他数值,例如1MΩ、10MΩ、20MΩ、30MΩ、40MΩ、50MΩ、60MΩ、70MΩ、80MΩ、90MΩ、100MΩ、110MΩ、120MΩ、130MΩ…210MΩ、220MΩ、230MΩ等数值。In some embodiments, the resistance value of the first insulating portion 14 can be measured in megohms (MΩ). For example, in the battery cell 10 provided in some embodiments of the present application, the resistance value of the first insulating portion 14 can be greater than or equal to 200 MΩ. In other embodiments, the resistance value of the first insulating portion 14 can be other values, such as 1 MΩ, 10 MΩ, 20 MΩ, 30 MΩ, 40 MΩ, 50 MΩ, 60 MΩ, 70 MΩ, 80 MΩ, 90 MΩ, 100 MΩ, 110 MΩ, 120 MΩ, 130 MΩ…210 MΩ, 220 MΩ, 230 MΩ, etc.
上述方案中,通过在第一壁110和第一电极端子13之间设置第一绝缘部14,能够有效地绝缘隔离第一壁110和第一电极端子13,降低因第一壁110和第一电极端子13之间短接导致电池单体10内部短路的风险,使得电池的可靠性高。特别是在工作电压较高的储能装置中,通过在第一壁110和第一电极端子13之间设置第一绝缘部14,能够有效地降低因电池中的其余电池单体10失控而外壳11带高压电,导致高压电导通第一壁110和电极端子使得电池单体10内部短路,致使储能装置热失控的风险。In the above solution, by providing the first insulating portion 14 between the first wall 110 and the first electrode terminal 13, the first wall 110 and the first electrode terminal 13 can be effectively insulated and isolated, reducing the risk of internal short circuits in the battery cells 10 due to a short circuit between the first wall 110 and the first electrode terminal 13, thereby enhancing battery reliability. In particular, in energy storage devices operating at higher voltages, providing the first insulating portion 14 between the first wall 110 and the first electrode terminal 13 can effectively reduce the risk of thermal runaway of the energy storage device due to the remaining battery cells 10 in the battery running out of control, causing the outer casing 11 to be charged with high voltage, resulting in the high voltage electricity flowing through the first wall 110 and the electrode terminal, causing an internal short circuit in the battery cells 10.
根据本申请的一些实施例,请参见图5、图8以及图9,图9为本申请一些实施例中第一变形件15的示意图。电池单体10还包括第一变形件15,第一变形件15与第一壁110电连接,第一变形件15被配置为可以变形以与第一电极端子13接触,以将第一电极端子13与第一壁110电连接。According to some embodiments of the present application, please refer to Figures 5, 8, and 9. Figure 9 is a schematic diagram of the first deformable member 15 in some embodiments of the present application. The battery cell 10 also includes the first deformable member 15, which is electrically connected to the first wall 110. The first deformable member 15 is configured to be deformable to contact the first electrode terminal 13 to electrically connect the first electrode terminal 13 to the first wall 110.
第一变形件15安装于第一壁110,且第一变形件15与第一壁110电连接。在一些实施例中,第一变形件15可以为金属材料制得,例如第一变形件15通过铝、铜、铁、铝、钢、合金或者复合金属制得。在一些实施例中,第一变形件15可以焊接于第一壁110的内侧面。The first deformable member 15 is mounted on the first wall 110 and is electrically connected to the first wall 110. In some embodiments, the first deformable member 15 can be made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal. In some embodiments, the first deformable member 15 can be welded to the inner side of the first wall 110.
第一变形件15为受电池单体10内部压力而变形的结构件。第一变形件15用于电池单体10的过充保护,示例性地,在电池单体10处于过充等滥用工况时,内部压力增高,内部压力到达第一阈值时,第一变形件15变形以接触第一电极端子13,从而导通第一壁110和第一电极端子13,使得电池单体10内部正负极短接。The first deformable member 15 is a structural member that deforms due to the internal pressure of the battery cell 10. The first deformable member 15 is used to protect the battery cell 10 from overcharge. For example, when the battery cell 10 is subjected to an abuse condition such as overcharge, the internal pressure increases. When the internal pressure reaches a first threshold, the first deformable member 15 deforms to contact the first electrode terminal 13, thereby electrically connecting the first wall 110 and the first electrode terminal 13, short-circuiting the positive and negative electrodes within the battery cell 10.
在一些实施例中,第一变形件15受压力变形以与第一电极端子13接触的部位,可以为第一电极端子13处于第一壁110的内侧部分,也可以为第一电极端子13处于第一壁110的外侧的部分,例如第一变形件15在电池单体10内部压力达到第一阈值时变形能够与第二部分131连接,又例如,第一变形件15在电池单体10内部压力达到第一阈值时变形能够与第一部分130连接。In some embodiments, the portion of the first deformable member 15 that is deformed by pressure to contact the first electrode terminal 13 may be the inner portion of the first electrode terminal 13 on the first wall 110, or the portion of the first electrode terminal 13 on the outer side of the first wall 110. For example, the first deformable member 15 can be deformed and connected to the second portion 131 when the internal pressure of the battery cell 10 reaches the first threshold value. For another example, the first deformable member 15 can be deformed and connected to the first portion 130 when the internal pressure of the battery cell 10 reaches the first threshold value.
在一些实施例中,第一变形件15可以为翻转片,翻转片受压力作用而翻转。示例性地,请参见图5和图9,第一变形件15外轮廓呈圆盘状,由外向内包括依次连接的第一裙边150、第一翻转箔151以及第一电连接部152,第一裙边150可以与第一壁110连接,第一翻转箔151的厚度较薄,用于受压力而形变翻转。第一翻转箔151翻转后,能够将第一电连接部152向第一电极端子13推动,从而使得第一电连接部152与第一电极端子13接触。In some embodiments, the first deformable member 15 may be a flip sheet that flips under pressure. For example, referring to Figures 5 and 9 , the first deformable member 15 has a disc-shaped outer profile and comprises, from the outside inward, a first skirt 150, a first flip foil 151, and a first electrical connection portion 152, which are sequentially connected. The first skirt 150 can be connected to the first wall 110. The first flip foil 151 is relatively thin and is designed to deform and flip under pressure. After the first flip foil 151 flips, it can push the first electrical connection portion 152 toward the first electrode terminal 13, thereby bringing the first electrical connection portion 152 into contact with the first electrode terminal 13.
示例性地,第一壁110具有第二通孔1101,第一裙边150焊接于第一壁110,使得第一变形件15将第二通孔1101封闭。第一翻转箔151在自然状态时呈向背离于第一壁110的方向塌陷的状态,第一翻转箔151在电池单体10内部压力达到一定程度,例如第一阈值时,朝向面向第一壁110的方向翻转,以将第一电连接部152推动,从而使得第一电连接部152穿过第二通孔1101与第一部分130接触。For example, the first wall 110 has a second through hole 1101, and the first skirt 150 is welded to the first wall 110, so that the first deformable member 15 closes the second through hole 1101. In its natural state, the first flip foil 151 is collapsed away from the first wall 110. When the pressure inside the battery cell 10 reaches a certain level, such as a first threshold, the first flip foil 151 flips toward the first wall 110 to push the first electrical connection portion 152, thereby allowing the first electrical connection portion 152 to pass through the second through hole 1101 and contact the first portion 130.
在一些实施例中,第一电极端子13通过第一转接件123与第一极耳120电连接,电极组件12的第二极耳121可以与外壳11电连接,第二极耳121与第一极耳120极性相反,例如第二极耳121直接或者通过第二转接件124与外壳11连接,或者外壳11上设置第二电极端子16,第二电极端子16与外壳11电连接,第二极耳121直接或者通过第二转接件124与第二电极端子16连接。在电池单体10内部压力达到第一阈值时,第一变形件15变形,将第一电极端子13和外壳11短接,从而使得电池单体10内部正负极短接以内部短路,瞬时产生的大电流可以将电池单体10内部的电连接构件熔断,切断电池单体10的充放电回路,从而起到过充保护的作用。熔断的电连接构件可以包括第一转接件123和/或第二转接件124。示例性地,第一转接件123具有第一熔断部,第一熔断部的过流面积可以小于第一转接件123的其余部分的过流面积,以在较大电流经过时,能使得第一熔断部熔断,从而断开第一极耳120和第一电极端子13的电流路径。示例性地,第二转接件124具有第二熔断部,第二熔断部的过流面积可以小于第二转接件124的其余部分的过流面积,以在较大电流经过时,能使得第二熔断部熔断,从而断开第二极耳121和第二电极端子16或外壳11的电流路径。In some embodiments, the first electrode terminal 13 is electrically connected to the first tab 120 via a first adapter 123. The second tab 121 of the electrode assembly 12 can be electrically connected to the outer casing 11. The second tab 121 has opposite polarity to the first tab 120. For example, the second tab 121 is connected to the outer casing 11 directly or via a second adapter 124, or the outer casing 11 is provided with a second electrode terminal 16, which is electrically connected to the outer casing 11, and the second tab 121 is connected to the second electrode terminal 16 directly or via a second adapter 124. When the internal pressure of the battery cell 10 reaches a first threshold, the first deformable member 15 deforms, short-circuiting the first electrode terminal 13 and the outer casing 11. This creates an internal short circuit between the positive and negative electrodes of the battery cell 10. The instantaneous high current generated can melt the electrical connection components within the battery cell 10, severing the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection. The melted electrical connection components may include the first adapter 123 and/or the second adapter 124. Illustratively, the first adapter 123 includes a first fuse portion, and the flow area of the first fuse portion can be smaller than the flow area of the remaining portion of the first adapter 123. This allows the first fuse portion to melt when a relatively large current flows through it, thereby disconnecting the current path between the first tab 120 and the first electrode terminal 13. Illustratively, the second adapter 124 includes a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the remaining portion of the second adapter 124. This allows the second fuse portion to melt when a relatively large current flows through it, thereby disconnecting the current path between the second tab 121 and the second electrode terminal 16 or the housing 11.
在另一些实施例中,第一电极端子13通过第一转接件123与第一极耳120电连接,电极组件12的第二极耳121可以与第二电极端子16电连接,第二极耳121与第一极耳120极性相反,第二电极端子16可以绝缘安装于外壳11,例如绝缘安装于外壳11的第一壁110。第二极耳121可以通过第二转接件124与第二电极端子16电连接。第二电极端子16对应设置有第二变形件18,第二变形件18电连接于外壳11,第二变形件18被配置为可以变形以与第二电极端子16接触,以将第二电极端子16与外壳11电连接。例如,第二变形件18被配置为在电池单体10内部压力达到第二阈值时变形以与第二电极端子16接触,以将第二电极端子16与外壳11电连接。In other embodiments, the first electrode terminal 13 is electrically connected to the first electrode tab 120 via a first adapter 123, and the second electrode tab 121 of the electrode assembly 12 can be electrically connected to the second electrode terminal 16. The second electrode tab 121 has an opposite polarity to the first electrode tab 120, and the second electrode terminal 16 can be insulated and mounted to the housing 11, for example, to the first wall 110 of the housing 11. The second electrode tab 121 can be electrically connected to the second electrode terminal 16 via a second adapter 124. A second deformable member 18 is provided corresponding to the second electrode terminal 16. The second deformable member 18 is electrically connected to the housing 11 and is configured to deform to contact the second electrode terminal 16 to electrically connect the second electrode terminal 16 to the housing 11. For example, the second deformable member 18 is configured to deform to contact the second electrode terminal 16 when the internal pressure of the battery cell 10 reaches a second threshold value to electrically connect the second electrode terminal 16 to the housing 11.
在电池单体10内部压力达到一定程度,例如第一阈值时,第一变形件15变形,将第一电极端子13和外壳11短接,在电池单体10内部压力达到第二阈值时,第二变形件18变形,将第二电极端子16与外壳11短接,从而使得电池单体10内部正负极短接以内部短路,瞬时产生的大电流可以将电池单体10内部的电连接构件熔断,切断电池单体10的充放电回路,从而起到过充保护的作用。熔断的电连接构件可以包括第一转接件123和/或第二转接件124。示例性地,第一转接件123具有第一熔断部,第一熔断部的过流面积可以小于第一转接件123的其余部分的过流面积,以在较大电流经过时,能使得第一熔断部熔断,从而断开第一极耳120和第一电极端子13的电流路径。示例性地,第二转接件124具有第二熔断部,第二熔断部的过流面积可以小于第二转接件124的其余部分的过流面积,以在较大电流经过时,能使得第二熔断部熔断,从而断开第二极耳121和第二电极端子16的电流路径。When the internal pressure of the battery cell 10 reaches a certain level, such as a first threshold, the first deformable member 15 deforms, short-circuiting the first electrode terminal 13 and the outer shell 11. When the internal pressure of the battery cell 10 reaches a second threshold, the second deformable member 18 deforms, short-circuiting the second electrode terminal 16 and the outer shell 11, thereby short-circuiting the positive and negative electrodes within the battery cell 10 and creating an internal short circuit. The large current generated instantaneously can melt the electrical connection components within the battery cell 10, cutting off the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection. The fused electrical connection components can include the first adapter 123 and/or the second adapter 124. For example, the first adapter 123 has a first fuse portion, the flow area of which can be smaller than the flow area of the remaining portions of the first adapter 123, so that when a large current passes through, the first fuse portion can melt, thereby disconnecting the current path between the first tab 120 and the first electrode terminal 13. Exemplarily, the second adapter 124 has a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the rest of the second adapter 124, so that when a larger current passes through, the second fuse portion can be melted, thereby disconnecting the current path between the second electrode tab 121 and the second electrode terminal 16.
上述方案中,通过设置第一变形件15,在电池单体10内部压力达到一定程度,例如第一阈值时,通过第一变形件15的变形以与第一电极端子13接触,从而使得第一电极端子13与第一壁110电连接,实现电池单体10内部短路,使得电池单体10内部的电连接构件因短路产生的大电流而熔断,以切断电池单体10的充放电回路,从而起到过充保护的作用,以及起到降低电池单体10热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, by providing the first deformable member 15, when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold value, the first deformable member 15 is deformed to contact the first electrode terminal 13, so that the first electrode terminal 13 is electrically connected to the first wall 110, thereby realizing an internal short circuit of the battery cell 10, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell 10, thereby playing a role of overcharge protection, and playing a role of reducing the risk of thermal runaway of the battery cell 10, thereby making the battery have higher reliability.
根据本申请的一些实施例,请结合图8、图10和图11,图10为本申请一些实施例中第一壁110的立体图,图11为本申请一些实施例中第一壁110的局部结构示意图。According to some embodiments of the present application, please refer to Figures 8, 10 and 11. Figure 10 is a three-dimensional diagram of the first wall 110 in some embodiments of the present application, and Figure 11 is a schematic diagram of the local structure of the first wall 110 in some embodiments of the present application.
第一壁110形成有第一通孔1100和第二通孔1101,第一电极端子13穿过第一通孔1100。第一变形件15封闭第二通孔1101,第一变形件15被配置可以变形以部分穿过第二通孔1101与第一电极端子13接触。The first wall 110 is formed with a first through hole 1100 and a second through hole 1101 through which the first electrode terminal 13 passes. The first deformable member 15 closes the second through hole 1101 and is configured to be deformable to partially pass through the second through hole 1101 and contact the first electrode terminal 13.
在一些实施例中,沿第一壁的厚度方向z,第一电极端子13包括位于第一壁110的外侧的第一部分130以及至少部分位于第一壁110的内侧的第二部分131。第二部分131用于与电池单体10的电极组件12电连接。In some embodiments, along the thickness direction z of the first wall, the first electrode terminal 13 includes a first portion 130 located outside the first wall 110 and a second portion 131 at least partially located inside the first wall 110. The second portion 131 is used to electrically connect to the electrode assembly 12 of the battery cell 10.
在一些实施例中,第一壁110可以为外壳11的端盖,第一壁110可以呈板状。沿第一壁的厚度方向z,第一壁110形成有贯通的第一通孔1100和第二通孔1101。第一通孔1100供第一电极端子13穿过,第二通孔1101用于第一变形件15的穿过。In some embodiments, the first wall 110 may be an end cap of the housing 11 and may be plate-shaped. A first through-hole 1100 and a second through-hole 1101 are formed along the thickness direction z of the first wall 110. The first through-hole 1100 allows the first electrode terminal 13 to pass through, while the second through-hole 1101 allows the first deformable member 15 to pass through.
示例性地,请参见图8,第一电极端子13包括第一部分130和第二部分131,第一部分130处于第一壁110的外侧,第一部分130可以呈平板状以与外部结构电连接。第二部分131的部分处于第一壁110的内侧以与电极组件12电连接,第二部分131的另一部分穿过第一通孔1100与第一部分130连接。第二部分131与第一部分130的连接关系包括但不限于焊接、粘接、铆接或者螺纹件连接等。在另一些实施例中,第一部分130可以部分位于第一壁110的外侧,第一部分130的另一部分可以穿过第一通孔1100与第二部分131连接。在另一些实施例中,第一部分130可以部位位于第一壁110的外侧,第二部分131的部分位于第一壁110的内侧,第一部分130的另一部分和第二部分131的另一部分位于第一通孔1100内并相互连接。For example, referring to FIG8 , the first electrode terminal 13 includes a first portion 130 and a second portion 131. The first portion 130 is located outside the first wall 110 and can be flat for electrical connection to external structures. A portion of the second portion 131 is located inside the first wall 110 for electrical connection to the electrode assembly 12, while another portion of the second portion 131 passes through a first through-hole 1100 to connect to the first portion 130. The connection between the second portion 131 and the first portion 130 includes, but is not limited to, welding, bonding, riveting, or screwing. In other embodiments, the first portion 130 can be partially located outside the first wall 110, while another portion of the first portion 130 passes through the first through-hole 1100 to connect to the second portion 131. In other embodiments, the first portion 130 can be partially located outside the first wall 110, while a portion of the second portion 131 is located inside the first wall 110. Another portion of the first portion 130 and another portion of the second portion 131 are located within the first through-hole 1100 and connected to each other.
“第一变形件15封闭第二通孔1101”可以指第一变形件15将第二通孔1101封闭,使得电极组件12和电解液处于封闭的空间中。在一些实施例中,第一变形件15的第一裙边150围设于第二通孔1101的边缘设置并焊接于第一壁110的内侧。"First deformable member 15 encloses second through-hole 1101" may mean that first deformable member 15 closes second through-hole 1101, thereby enclosing electrode assembly 12 and electrolyte. In some embodiments, first skirt 150 of first deformable member 15 is disposed around the edge of second through-hole 1101 and welded to the inner side of first wall 110.
在一些实施例中,当电池单体10内部压力达到第一阈值时,第一变形件15能够朝向第一部分130变形以穿过第二通孔1101与第一部分130接触。In some embodiments, when the internal pressure of the battery cell 10 reaches a first threshold, the first deformation member 15 can be deformed toward the first portion 130 to pass through the second through hole 1101 and contact the first portion 130 .
在一些实施例中,第二通孔1101可以为阶梯孔状,能够为第一变形件15的第一裙边150提供连接部位,使得第一裙边150能够容纳于第二通孔1101中,降低第一变形件15对电池单体10内部空间的占用。In some embodiments, the second through hole 1101 can be a stepped hole, which can provide a connection portion for the first skirt 150 of the first deformable member 15, so that the first skirt 150 can be accommodated in the second through hole 1101, reducing the occupation of the internal space of the battery cell 10 by the first deformable member 15.
上述方案中,在电池单体10内部压力达到一定程度,例如第一阈值时,电池单体10的内部压力能够作用于第一变形件15,使得第一变形件15朝向第一壁110的外侧变形以有效地接触第一电极端子13的第一部分130,从而有效地实现电池单体10内部短路,使得电池单体10内部的电连接构件因短路产生的大电流而熔断,以切断电池单体10的充放电回路,从而起到降低电池单体10热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold value, the internal pressure of the battery cell 10 can act on the first deformable member 15, so that the first deformable member 15 is deformed toward the outside of the first wall 110 to effectively contact the first part 130 of the first electrode terminal 13, thereby effectively realizing an internal short circuit of the battery cell 10, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, so as to cut off the charge and discharge circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
根据本申请的一些实施例,请参见图8,沿第一壁的厚度方向z,第一电极端子13位于第一壁110的外侧的第一部分130的投影与第一变形件15的投影至少部分重叠。According to some embodiments of the present application, referring to FIG. 8 , along the thickness direction z of the first wall, the projection of the first portion 130 of the first electrode terminal 13 located outside the first wall 110 at least partially overlaps with the projection of the first deformable member 15 .
在一些实施例中,第一部分130尺寸较大,沿着第一壁的厚度方向z,第一部分130的部分可以正对第二部分131设置以与第二部分131连接,第一部分130的部分可以正对第一变形件15,以在第一变形件15变形时与第一变形件15直接接触。In some embodiments, the first part 130 is larger in size, and along the thickness direction z of the first wall, a portion of the first part 130 can be set opposite the second part 131 to be connected to the second part 131, and a portion of the first part 130 can be opposite the first deformable member 15 to directly contact the first deformable member 15 when the first deformable member 15 is deformed.
在一些实施例中,沿第一壁的厚度方向z,第一变形件15的投影可以全部地落在第一部分130上。在另一些实施例中,沿第一壁的厚度方向z,第一变形件15的投影可以部分地落在第一部分130上,另一部分与第一部分130错开。In some embodiments, along the thickness direction z of the first wall, the projection of the first deformable member 15 may entirely fall on the first portion 130. In other embodiments, along the thickness direction z of the first wall, the projection of the first deformable member 15 may partially fall on the first portion 130, while another portion may be offset from the first portion 130.
上述方案中,通过将第一变形件15沿第一壁的厚度方向z对应于第一部分130设置,能够在电池单体10内部压力达到一定程度,例如第一阈值时,以较小的变形量快速地接触第一部分130,从而快速地使得第一电极端子13和第一壁110电连接,从而有效地实现电池单体10内部短路,使得电池单体10内部的电连接构件因短路产生的大电流而熔断,以切断电池单体10的充放电回路,从而起到降低电池单体10热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, by arranging the first deformable member 15 along the thickness direction z of the first wall corresponding to the first part 130, when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold, it can quickly contact the first part 130 with a smaller deformation amount, thereby quickly electrically connecting the first electrode terminal 13 and the first wall 110, thereby effectively realizing an internal short circuit of the battery cell 10, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
根据本申请的一些实施例,请参见图10和图11,第一壁110包括彼此连接的本体部110a和第一加强部110b,第一部分130设置于第一加强部110b。According to some embodiments of the present application, referring to FIG. 10 and FIG. 11 , the first wall 110 includes a main body portion 110 a and a first reinforcement portion 110 b connected to each other, and the first portion 130 is disposed on the first reinforcement portion 110 b .
在一些实施例中,第一加强部110b的作用在于使得第一壁110的整体结构强度加强或者使得第一壁110的局部结构强度加强,使得第一壁110具有较高的抗冲击能力,降低第一壁110形变的风险。在一些实施例中,第一加强部110b可以为加强筋、凹凸结构等结构。In some embodiments, the first reinforcement portion 110b serves to strengthen the overall structural strength of the first wall 110 or to strengthen the local structural strength of the first wall 110, thereby increasing the impact resistance of the first wall 110 and reducing the risk of deformation of the first wall 110. In some embodiments, the first reinforcement portion 110b may be a reinforcing rib, a concave-convex structure, or the like.
在一些实施例中,第一壁110包括本体部110a以及层叠设置于本体部110a表面的第一加强部110b,第一加强部110b的材料与本体部110a的材料相同,在第一加强部110b所在的部位第一壁110的厚度较大,从而该部位具有较大的结构强度。In some embodiments, the first wall 110 includes a main body portion 110a and a first reinforcement portion 110b stacked on the surface of the main body portion 110a. The material of the first reinforcement portion 110b is the same as that of the main body portion 110a. The thickness of the first wall 110 is larger at the location of the first reinforcement portion 110b, so that this location has greater structural strength.
在一些实施例中,第一壁110包括本体部110a,对本体部110a进行冲压以在本体部110a的一侧形成凸包另一侧形成凹部,该凸部和凹部所在的部位形成第一加强部110b。In some embodiments, the first wall 110 includes a main body portion 110 a , which is punched to form a convex portion on one side and a concave portion on the other side of the main body portion 110 a , and the portions where the convex portion and the concave portion are located form the first reinforcement portion 110 b .
在另一些实施例中,第一壁110包括本体部110a和第一加强部110b,本体部110a围设于第一加强部110b的边缘,第一加强部110b的材料和本体部110a的材料可以相同也可以不同,第一加强部110b的结构强度大于本体部110a。In other embodiments, the first wall 110 includes a main body portion 110a and a first reinforcement portion 110b, the main body portion 110a is arranged around the edge of the first reinforcement portion 110b, the material of the first reinforcement portion 110b and the material of the main body portion 110a can be the same or different, and the structural strength of the first reinforcement portion 110b is greater than that of the main body portion 110a.
“第一部分130设置于第一加强部110b”可以理解为,第一壁110用于支撑第一部分130的部位为第一壁110的结构强度较大的部分。“The first portion 130 is disposed on the first reinforcement portion 110 b ” can be understood as that the portion of the first wall 110 used to support the first portion 130 is the portion of the first wall 110 with greater structural strength.
上述方案中,通过设置第一加强部110b,能够提高第一壁110的整体强度,能够降低因电池单体10内部压力或者外部冲击作用下,导致第一壁110形变,致使第一变形件15无法有效与第一部分130接触以导通第一电极端子13和第一壁110的风险,能够使得第一变形件15在电池单体10过充等滥用工况下有效地与第一电极端子13接触,从而有效地起到过充保护的作用,降低电池单体10热失控的风险,使得电池具有较高的可靠性。In the above scheme, by providing the first reinforcement portion 110b, the overall strength of the first wall 110 can be improved, and the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the first deformable member 15 to be unable to effectively contact the first part 130 to conduct electricity between the first electrode terminal 13 and the first wall 110, can be reduced. The first deformable member 15 can effectively contact the first electrode terminal 13 under abuse conditions such as overcharging of the battery cell 10, thereby effectively playing the role of overcharge protection, reducing the risk of thermal runaway of the battery cell 10, and making the battery have higher reliability.
在一些实施例中,本体部110a可以围绕于第一加强部110b的边缘设置。In some embodiments, the main body portion 110 a may be disposed around an edge of the first reinforcement portion 110 b .
在一些实施例中,第一加强部110b可以相对于本体部110a凹凸以使得第一加强部110b的结构强度大于本体部110a的结构强度。在另一些实施例中,第一加强部110b的厚度可以大于本体部110a的厚度,以使得第一加强部110b的结构强度大于本体部110a的结构强度。通过将第一加强部110b的结构强度设置为大于本体部110a的结构强度,一方面能够有效地提高第一壁110的整体强度,另一方面,能够使得第一壁110的对应于第一部分130的局部部分具有较强的结构强度,使得第一部分130有效地与第一变形件15配合,提高过充保护的可靠性。In some embodiments, the first reinforcement portion 110b can be concave or convex relative to the main body portion 110a, such that the structural strength of the first reinforcement portion 110b is greater than that of the main body portion 110a. In other embodiments, the thickness of the first reinforcement portion 110b can be greater than that of the main body portion 110a, such that the structural strength of the first reinforcement portion 110b is greater than that of the main body portion 110a. By setting the structural strength of the first reinforcement portion 110b to be greater than that of the main body portion 110a, the overall strength of the first wall 110 can be effectively improved. Furthermore, the local portion of the first wall 110 corresponding to the first portion 130 can have greater structural strength, allowing the first portion 130 to effectively cooperate with the first deformable member 15, thereby improving the reliability of overcharge protection.
根据本申请的一些实施例,请参见图6,所述第一壁的长度大于或等于150mm,所述第一壁的宽度大于或等于45mm。According to some embodiments of the present application, referring to FIG. 6 , the length of the first wall is greater than or equal to 150 mm, and the width of the first wall is greater than or equal to 45 mm.
在一些实施例中,电池单体10可以为方形电池单体,第一壁110可以为外壳11的端盖。为使得电池单体10具有更大的电容量,外壳11的体积可以设计得更大,为此端盖的尺寸更大。在一些实施例中,参见图6,端盖在其长度方向上的尺寸标记为C,也即第一壁110的长度C的数值可以大于或等于150mm,例如C的取值为150mm、160mm、170mm、180mm、更大的数值或者相邻两个数值之间的任意值。端盖在其宽度方向上的尺寸标记为D,也即第一壁110的宽度D的数值可以大于或等于45mm,例如D的取值为45mm、55mm、65mm、75mm、更大的数值或者相邻两个数值之间的任意值。In some embodiments, the battery cell 10 may be a square battery cell, and the first wall 110 may be an end cap of the outer shell 11. In order to make the battery cell 10 have a larger capacity, the volume of the outer shell 11 may be designed to be larger, and for this purpose, the size of the end cap is larger. In some embodiments, referring to FIG6 , the dimension of the end cap in its length direction is marked as C, that is, the value of the length C of the first wall 110 may be greater than or equal to 150 mm, for example, the value of C is 150 mm, 160 mm, 170 mm, 180 mm, a larger value, or any value between two adjacent values. The dimension of the end cap in its width direction is marked as D, that is, the value of the width D of the first wall 110 may be greater than or equal to 45 mm, for example, the value of D is 45 mm, 55 mm, 65 mm, 75 mm, a larger value, or any value between two adjacent values.
端盖的长度方可以为端盖的尺寸最大的方向,端盖的宽度方向可以为尺寸较小的方向,端盖的宽度方向、端盖的长度方向以及端盖的厚度方向可以两两相互垂直。The length direction of the end cap may be the direction of the largest size of the end cap, the width direction of the end cap may be the direction of the smallest size, and the width direction of the end cap, the length direction of the end cap and the thickness direction of the end cap may be perpendicular to each other.
上述方案中,通过在尺寸较大的第一壁110上设置第一加强部110b,能够有效地补偿因提高第一壁110的尺寸导致其损失的结构强度,能够提高第一壁110的整体强度,能够降低因电池单体10内部压力或者外部冲击作用下,导致第一壁110形变,致使第一变形件15无法有效与第一部分130接触以导通第一电极端子13和第一壁110的风险,能够使得第一变形件15在电池单体10过充等滥用工况下有效地与第一电极端子13接触,从而有效地起到过充保护的作用,降低电池单体10热失控的风险,使得电池具有较高的可靠性。In the above scheme, by providing the first reinforcing portion 110b on the larger first wall 110, the structural strength lost due to the increase in the size of the first wall 110 can be effectively compensated, the overall strength of the first wall 110 can be improved, and the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the first deformable member 15 to be unable to effectively contact the first portion 130 to conduct electricity between the first electrode terminal 13 and the first wall 110, can be reduced. The first deformable member 15 can effectively contact the first electrode terminal 13 under abuse conditions such as overcharging of the battery cell 10, thereby effectively playing the role of overcharge protection, reducing the risk of thermal runaway of the battery cell 10, and making the battery have higher reliability.
根据本申请的一些实施例,请参见图10,第一加强部110b包括第一凸部110b0,沿第一壁的厚度方向z,第一凸部110b0凸出于本体部110a沿第一壁的厚度方向z上的一个表面。According to some embodiments of the present application, referring to FIG. 10 , the first reinforcement portion 110b includes a first protrusion 110b0 , which protrudes from a surface of the main body portion 110a along the thickness direction z of the first wall.
在一些实施例中,第一加强部110b包括第一凸部110b0,第一凸部110b0凸部于第一壁110的表面。示例性地,第一凸部110b0凸出于第一壁110的外侧面;或者第一凸部110b0凸出于第一壁110的内侧面。In some embodiments, the first reinforcement portion 110b includes a first protrusion 110b0 protruding from the surface of the first wall 110. For example, the first protrusion 110b0 protrudes from the outer side of the first wall 110; or the first protrusion 110b0 protrudes from the inner side of the first wall 110.
在一些实施例中,第一壁110可以包括本体部110a,本体部110a上限定有第一加强区,第一凸部110b0可以设置于第一加强区,第一加强区所在的部位可以看作第一加强部110b。第一部分130可以设置于第一加强区,例如第一部分130设置于第一凸部110b0背离于本体部110a的表面,又例如第一部分130可以设置于本体部110a的背离于第一凸部110b0的部位。在一些实施例中,第一凸部110b0与本体部110a可以互为分体结构,如第一凸部110b0层叠设置于本体部110a,第一凸部110b0与本体部110a的连接关系包括但不限于粘接、焊接、铆接或者螺纹件连接等。在一些实施例中,第一凸部110b0与本体部110a可以为一体结构,其通过冲压、铸造或者其他工艺一体成型。In some embodiments, the first wall 110 may include a main body 110a, which defines a first reinforcement region. The first protrusion 110b0 may be disposed in the first reinforcement region, and the portion where the first reinforcement region is located may be considered the first reinforcement portion 110b. The first portion 130 may be disposed in the first reinforcement region, for example, the first portion 130 may be disposed on a surface of the first protrusion 110b0 facing away from the main body 110a, or in a portion of the main body 110a facing away from the first protrusion 110b0. In some embodiments, the first protrusion 110b0 and the main body 110a may be separate structures, such as the first protrusion 110b0 being stacked on the main body 110a. The connection between the first protrusion 110b0 and the main body 110a includes, but is not limited to, bonding, welding, riveting, or screwing. In some embodiments, the first protrusion 110b0 and the main body 110a may be a unitary structure, formed integrally by stamping, casting, or other processes.
上述方案中,通过设置第一凸部110b0以加强第一壁110的结构强度,能够有效地降低因电池单体10内部压力或者外部冲击作用下,导致第一壁110形变,致使第一变形件15无法有效与第一部分130接触以导通第一电极端子13和第一壁110的风险,使得电池具有较高的可靠性。In the above solution, by providing the first protrusion 110b0 to strengthen the structural strength of the first wall 110, the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the first deformable member 15 to be unable to effectively contact the first part 130 to conduct electricity between the first electrode terminal 13 and the first wall 110, can be effectively reduced, thereby making the battery have higher reliability.
根据本申请的一些实施例,请参见图11,第一加强部110b还包括第一凹部110b1,沿第一壁的厚度方向z,第一凹部110b1设置于本体部110a的另一个表面,且第一凹部110b1与第一凸部110b0相对设置。According to some embodiments of the present application, referring to FIG. 11 , the first reinforcement portion 110b further includes a first recess 110b1 , which is disposed on another surface of the main body portion 110a along the thickness direction z of the first wall, and the first recess 110b1 is disposed opposite to the first protrusion 110b0 .
第一凹部110b1为对应于第一凸部110b0的部位。示例性地,当第一凸部110b0位于第一壁110的外侧时,第一凹部110b1位于第一壁110的内侧;反之,第一凸部110b0位于第一壁110的内侧时,第一凹部110b1位于第一壁110的外侧。The first concave portion 110b1 corresponds to the first convex portion 110b0. For example, when the first convex portion 110b0 is located on the outside of the first wall 110, the first concave portion 110b1 is located on the inside of the first wall 110; conversely, when the first convex portion 110b0 is located on the inside of the first wall 110, the first concave portion 110b1 is located on the outside of the first wall 110.
在一些实施例中,第一壁110可以通过冲压的方式成型出第一凸部110b0和第一凹部110b1。例如,沿第一壁的厚度方向z,冲压头由第一壁110的内侧向外侧冲压第一壁110,以在第一壁110的外侧形成第一凸部110b0,在第一壁110的内侧形成第一凹部110b1。In some embodiments, the first wall 110 may be formed by stamping to form the first convex portion 110b0 and the first concave portion 110b1. For example, along the thickness direction z of the first wall, a punch presses the first wall 110 from the inside to the outside of the first wall 110 to form the first convex portion 110b0 on the outside of the first wall 110 and the first concave portion 110b1 on the inside of the first wall 110.
本申请一些实施例中,第一凹部110b1位于第一壁110的内侧,第一变形件15和第二部分131的至少部分位于第一凹部110b1中。In some embodiments of the present application, the first recess 110b1 is located on the inner side of the first wall 110, and at least part of the first deformable member 15 and the second portion 131 are located in the first recess 110b1.
上述方案中,在对应于第一凸部110b0的位置设置第一凹部110b1,一方面,能够降低第一凸部110b0的成型难度并节省材料成本,另一方面,若第一凹部110b1处于第一壁110内侧时,则可以利用第一凹部110b1的空间容纳更多的活性物质或者电解液,利于电池单体10的能量密度或充放电性能的提高,或者使得第一变形件15和第一电极端子13能够利用第一凹部110b1的空间,降低对电池单体10内部空间的占用;若第一凹部110b1处于第一壁110外侧时,则可以利用第一凹部110b1的空间容纳外部的结构件,利于电池体积能量密度的提高。In the above scheme, the first recess 110b1 is provided at a position corresponding to the first protrusion 110b0. On the one hand, the difficulty of forming the first protrusion 110b0 can be reduced and material costs can be saved. On the other hand, if the first recess 110b1 is located on the inner side of the first wall 110, the space of the first recess 110b1 can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell 10, or the first deformable member 15 and the first electrode terminal 13 can utilize the space of the first recess 110b1 to reduce the occupation of the internal space of the battery cell 10; if the first recess 110b1 is located on the outer side of the first wall 110, the space of the first recess 110b1 can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
根据本申请的一些实施例,请结合图8和图11。第一凸部110b0位于第一壁110的外侧,第一凸部110b0形成有第一定位槽110b2,第一定位槽110b2容纳第一部分130以限制第一部分130活动。According to some embodiments of the present application, referring to Figures 8 and 11 , the first protrusion 110b0 is located outside the first wall 110 and is formed with a first positioning groove 110b2 that receives the first portion 130 to restrict its movement.
在一些实施例中,第一凸部110b0位于第一壁110的外侧,第一部分130可以设置于第一凸部110b0上。In some embodiments, the first protrusion 110 b 0 is located on the outer side of the first wall 110 , and the first portion 130 may be disposed on the first protrusion 110 b 0 .
第一定位槽110b2为形成于第一凸部110b0的槽结构,第一部分130位于第一定位槽110b2中。示例性地,第一凸部110b0具有背离于电极组件12的顶面,第一定位槽110b2为形成于该顶面的方形槽,呈方形状的第一部分130和第一绝缘部14的部分位于第一定位槽110b2中。第一绝缘部14被第一定位槽110b2的槽壁和第一部分130的外周面夹持。First positioning groove 110b2 is a groove structure formed in first protrusion 110b0, and first portion 130 is located in first positioning groove 110b2. For example, first protrusion 110b0 has a top surface facing away from electrode assembly 12. First positioning groove 110b2 is a square groove formed in this top surface. Square-shaped first portion 130 and a portion of first insulating portion 14 are located in first positioning groove 110b2. First insulating portion 14 is sandwiched between the groove wall of first positioning groove 110b2 and the outer peripheral surface of first portion 130.
上述方案中,通过设置第一定位槽110b2,能够有效地定位第一电极端子13,限制第一电极端子13的位移,一方面降低第一电极端子13与电池单体10的内部电连接构件脱离导致电池单体10内部断路的风险,另一方面能够使得第一电极端子13有效地与第一变形件15配合,起到过充保护的作用,提高电池的可靠性。In the above scheme, by setting the first positioning groove 110b2, the first electrode terminal 13 can be effectively positioned and the displacement of the first electrode terminal 13 can be limited. On the one hand, the risk of the first electrode terminal 13 being separated from the internal electrical connection component of the battery cell 10 and causing internal short circuit of the battery cell 10 is reduced. On the other hand, the first electrode terminal 13 can be effectively cooperated with the first deformable member 15 to play the role of overcharge protection and improve the reliability of the battery.
根据本申请的一些实施例,第一凸部110b0位于第一壁110的外侧,沿第一壁的厚度方向z,第一凸部110b0的凸出于本体部110a的尺寸大于等于0.1mm,且小于等于5mm。According to some embodiments of the present application, the first protrusion 110b0 is located outside the first wall 110, and along the thickness direction z of the first wall, the dimension of the first protrusion 110b0 protruding from the main body 110a is greater than or equal to 0.1 mm and less than or equal to 5 mm.
在一些实施例中,参见图11,沿第一壁的厚度方向z,第一凸部110b0凸出于本体部110a的尺寸为L1,L1的取值大于等于0.1mm,且小于等于5mm。示例性地,L1的取值为0.1mm、0.2mm、0.3mm、0.4mm、0.5mm、0.6mm…2.9mm、3mm、3.1mm、3.2mm、3.3mm…4.7mm、4.8mm、4.9mm、5mm或者相邻两个数值之间的任意值。In some embodiments, referring to FIG. 11 , along the thickness direction z of the first wall, the first protrusion 110b0 protrudes from the main body 110a by a dimension L1, where L1 is greater than or equal to 0.1 mm and less than or equal to 5 mm. For example, L1 is 0.1 mm, 0.2 mm, 0.3 mm, 0.4 mm, 0.5 mm, 0.6 mm, ... 2.9 mm, 3 mm, 3.1 mm, 3.2 mm, 3.3 mm, ... 4.7 mm, 4.8 mm, 4.9 mm, 5 mm, or any value in between.
上述方案中,通过将第一凸部110b0的凸出于本体部110a的尺寸设置为大于等于0.1mm,能够有效地提高第一壁110的结构强度,使得第一变形件15在电池单体10内部压力达到一定程度,例如第一阈值时有效地与第一电极端子13接触,起到过充保护的作用,进而提高电池的可靠性;通过将第一凸部110b0的凸出于本体部110a的尺寸设置为小于等于5mm,能够降低第一凸部110b0对空间的占用,降低对电池体积能量密度的影响。为此,通过将第一凸部110b0的凸出于本体部110a的尺寸设置为大于等于0.1mm且小于等于5mm,能够兼顾电池单体10的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the first protrusion 110b0 from the main body 110a to be greater than or equal to 0.1mm, the structural strength of the first wall 110 can be effectively improved, allowing the first deformable member 15 to effectively contact the first electrode terminal 13 when the internal pressure of the battery cell 10 reaches a certain level, such as the first threshold, thereby providing overcharge protection and thereby improving the reliability of the battery. By setting the protrusion of the first protrusion 110b0 from the main body 110a to be less than or equal to 5mm, the space occupied by the first protrusion 110b0 can be reduced, thereby reducing its impact on the battery's volumetric energy density. To this end, by setting the protrusion of the first protrusion 110b0 from the main body 110a to be greater than or equal to 0.1mm and less than or equal to 5mm, both the reliability of the battery cell 10's overcharge protection and the battery's volumetric energy density can be achieved.
根据本申请的一些实施例,沿第一壁的厚度方向z,第一凸部110b0的凸出于本体部110a的尺寸大于等于0.5mm,且小于等于3mm。According to some embodiments of the present application, along the thickness direction z of the first wall, a dimension of the first protrusion 110b0 protruding from the main body 110a is greater than or equal to 0.5 mm and less than or equal to 3 mm.
在一些实施例中,沿第一壁的厚度方向z,第一凸部110b0凸出于本体部110a的尺寸为L1,L1的取值大于等于0.5mm,且小于等于3mm。示例性地,L1的取值为0.5mm、0.6mm、0.7mm、0.8mm、0.9mm、1mm…2.5mm、2.6mm、2.7mm、2.8mm、2.9mm、3mm或者相邻两个数值之间的任意值。In some embodiments, along the thickness direction z of the first wall, the first protrusion 110b0 protrudes from the main body 110a by a dimension L1, where L1 is greater than or equal to 0.5 mm and less than or equal to 3 mm. For example, L1 is 0.5 mm, 0.6 mm, 0.7 mm, 0.8 mm, 0.9 mm, 1 mm, 2.5 mm, 2.6 mm, 2.7 mm, 2.8 mm, 2.9 mm, 3 mm, or any value in between.
上述方案中,通过将第一凸部110b0的凸出于本体部110a的尺寸设置为大于等于0.5mm,进一步地提高第一壁110的结构强度,使得第一变形件15在电池单体10内部压力达到第一阈值时高效地与第一电极端子13接触,起到过充保护的作用,进而提高电池的可靠性;通过将第一凸部110b0的凸出于本体部110a的尺寸设置为小于等于3mm,能够有效地降低第一凸部110b0对空间的占用,降低对电池体积能量密度的影响。为此,通过将第一凸部110b0的凸出于本体部110a的尺寸设置为大于等于0.5mm且小于等于3mm,能够兼顾电池单体10的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the first protrusion 110b0 from the main body 110a to be greater than or equal to 0.5mm, the structural strength of the first wall 110 is further improved, allowing the first deformable member 15 to efficiently contact the first electrode terminal 13 when the internal pressure of the battery cell 10 reaches the first threshold, thereby providing overcharge protection and improving the reliability of the battery. By setting the protrusion of the first protrusion 110b0 from the main body 110a to be less than or equal to 3mm, the space occupied by the first protrusion 110b0 can be effectively reduced, thereby reducing its impact on the battery's volumetric energy density. To this end, by setting the protrusion of the first protrusion 110b0 from the main body 110a to be greater than or equal to 0.5mm and less than or equal to 3mm, both the reliability of the battery cell 10's overcharge protection and the battery's volumetric energy density can be achieved.
根据本申请的一些实施例,请参见图5、图7和图8,第一绝缘部14包括第一绝缘件140,第一绝缘件140的至少部分设置于第一电极端子13位于第一壁110的外侧的第一部分130和第一壁110之间,第一绝缘件140形成有第三通孔14001和第四通孔14002,沿第一壁的厚度方向z,第三通孔14001与第一通孔1100相对设置,第四通孔14002与第二通孔1101相对设置。According to some embodiments of the present application, referring to Figures 5, 7 and 8, the first insulating portion 14 includes a first insulating member 140, at least a portion of the first insulating member 140 is arranged between the first portion 130 of the first electrode terminal 13 located on the outside of the first wall 110 and the first wall 110, and the first insulating member 140 is formed with a third through hole 14001 and a fourth through hole 14002. Along the thickness direction z of the first wall, the third through hole 14001 is arranged opposite to the first through hole 1100, and the fourth through hole 14002 is arranged opposite to the second through hole 1101.
在一些实施例中,参见图5,第一绝缘件140可以看作板状,设置于第一部分130和第一壁110之间以绝缘隔离第一部分130和第一壁110。第一绝缘件140具有沿第一壁的厚度方向z贯通的第三通孔14001和第四通孔14002,第三通孔14001对应于第一通孔1100设置以供第一电极端子13穿过,第四通孔14002对应于第二通孔1101设置以供第一变形件15在变形后穿过以与第一部分130接触。In some embodiments, referring to FIG5 , the first insulating member 140 can be considered plate-shaped and is disposed between the first portion 130 and the first wall 110 to insulate and isolate the first portion 130 from the first wall 110. The first insulating member 140 has a third through hole 14001 and a fourth through hole 14002 extending through the first wall along the thickness direction z. The third through hole 14001 is provided corresponding to the first through hole 1100 for the first electrode terminal 13 to pass through. The fourth through hole 14002 is provided corresponding to the second through hole 1101 for the first deformable member 15 to pass through after deformation to contact the first portion 130.
在一些实施例中,第三通孔14001可以为方形孔、圆形孔或者其他形状。第四通孔14002可以为方形孔、圆形孔或者其他形状。In some embodiments, the third through hole 14001 may be a square hole, a circular hole, or other shapes. The fourth through hole 14002 may be a square hole, a circular hole, or other shapes.
在一些实施例中,第三通孔14001和第一通孔1100可以为圆形孔,第三通孔14001的孔径可以小于或者等于第一通孔1100的孔径。在一些实施例中,第四通孔14002和第二通孔1101可以为圆形孔,第四通孔14002的孔径可以小于或者等于第二通孔1101的孔径。In some embodiments, the third through hole 14001 and the first through hole 1100 may be circular holes, and the diameter of the third through hole 14001 may be smaller than or equal to the diameter of the first through hole 1100. In some embodiments, the fourth through hole 14002 and the second through hole 1101 may be circular holes, and the diameter of the fourth through hole 14002 may be smaller than or equal to the diameter of the second through hole 1101.
示例性地,本申请一些实施例中,第一绝缘件140的材料可以包括绝缘PPS(聚苯硫醚)材料。在其他一些实施例中,第一绝缘件140还可以为聚丙烯、聚乙烯等其他具有绝缘特性的材料制得。示例性地,本申请一些实施例提供的电池单体10中,第一绝缘件140的电阻值可以大于或者等于200MΩ。For example, in some embodiments of the present application, the material of the first insulating member 140 may include insulating PPS (polyphenylene sulfide). In other embodiments, the first insulating member 140 may also be made of other insulating materials such as polypropylene and polyethylene. For example, in some embodiments of the present application, the resistance of the first insulating member 140 in the battery cell 10 may be greater than or equal to 200 MΩ.
上述方案中,第一绝缘件140结构简单,一方面通过第三通孔14001供第一电极端子13穿过,使得第一电极端子13与电极组件12的电连接以及实现对外充放电,通过第四通孔14002供第一变形件15变形以能够接触第一部分130,实现过充保护;另一方面,第一绝缘件140能够有效地绝缘隔离第一部分130和第一壁110,降低因第一部分130与第一壁110短接导致电池单体10内部短路的风险,使得电池的可靠性高。In the above scheme, the first insulating member 140 has a simple structure. On the one hand, the first electrode terminal 13 is allowed to pass through the third through hole 14001, so that the first electrode terminal 13 is electrically connected to the electrode assembly 12 and external charging and discharging is realized. The first deformable member 15 is allowed to deform through the fourth through hole 14002 so as to be able to contact the first part 130 to achieve overcharge protection; on the other hand, the first insulating member 140 can effectively insulate and isolate the first part 130 and the first wall 110, reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first part 130 and the first wall 110, thereby making the battery highly reliable.
根据本申请的一些实施例,参见图8,第一绝缘件140包括第一本体1400和第一凸缘1401,第一本体1400位于第一部分130和第一壁110之间,第一凸缘1401设置于第一本体1400背离于第一壁110的表面,第一凸缘1401围设第一部分130的外周面的至少部分。According to some embodiments of the present application, referring to FIG8 , the first insulating member 140 includes a first body 1400 and a first flange 1401 , the first body 1400 is located between the first portion 130 and the first wall 110 , the first flange 1401 is arranged on a surface of the first body 1400 facing away from the first wall 110 , and the first flange 1401 surrounds at least a portion of the outer peripheral surface of the first portion 130 .
在一些实施例中,第一本体1400夹设在第一部分130和第一壁110之间,第一本体1400整体呈平板状。第一凸缘1401凸设于第一本体1400的表面且围设于第一部分130的外周面。In some embodiments, the first body 1400 is sandwiched between the first portion 130 and the first wall 110 , and the first body 1400 is flat in shape. The first flange 1401 is protruded from the surface of the first body 1400 and surrounds the outer circumference of the first portion 130 .
“第一凸缘1401围设第一部分130的外周面的至少部分”可以理解为,第一凸缘1401能够将第一部分130的外周面全部包覆或者第一凸缘1401能够将第一部分130的外周面部分包覆。“The first flange 1401 surrounds at least a portion of the outer circumference of the first part 130 ” can be understood as the first flange 1401 being able to completely cover the outer circumference of the first part 130 or the first flange 1401 being able to partially cover the outer circumference of the first part 130 .
在一些实施例中,请参见图8,第一绝缘件140将第一部分130包裹并处于第一定位槽110b2中,第一凸缘1401处于第一部分130的外周面和第一定位槽110b2的槽壁之间。In some embodiments, referring to FIG. 8 , the first insulating member 140 wraps the first portion 130 and is located in the first positioning groove 110 b 2 , and the first flange 1401 is located between the outer circumference of the first portion 130 and the groove wall of the first positioning groove 110 b 2 .
上述方案中,通过设置第一本体1400和第一凸缘1401,能够有效地绝缘隔离第一壁110和第一部分130,使得第一部分130与第一壁110之间具有较远的爬电距离,使得第一绝缘件140具有较高的绝缘性能,有效降低因第一壁110和第一电极端子13之间短接导致电池单体10内部短路的风险,使得电池的可靠性高。In the above scheme, by setting the first body 1400 and the first flange 1401, the first wall 110 and the first part 130 can be effectively insulated and isolated, so that there is a longer creepage distance between the first part 130 and the first wall 110, and the first insulating member 140 has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first wall 110 and the first electrode terminal 13, so that the reliability of the battery is high.
根据本申请的一些实施例,请参见图8,第一绝缘件140还包括第二凸缘1402,第二凸缘1402绕第三通孔14001设置,且位于第一通孔1100的孔壁和第一电极端子13之间。According to some embodiments of the present application, referring to FIG. 8 , the first insulating member 140 further includes a second flange 1402 . The second flange 1402 is disposed around the third through hole 14001 and is located between the hole wall of the first through hole 1100 and the first electrode terminal 13 .
第二凸缘1402为第一绝缘件140的部分结构,第二凸缘1402与第一本体1400连接且绕第三通孔14001设置,沿第一壁的厚度方向z,第二凸缘1402朝向第一通孔1100凸出以覆盖第一通孔1100的孔壁的部分,从而将第一电极端子13与第一通孔1100的孔壁绝缘隔离。在一些实施例中,第二凸缘1402还具有定位的作用,通过第二凸缘1402与第一通孔1100的相互定位,使得第一绝缘件140快速地装配于第一壁110上。The second flange 1402 is part of the first insulating member 140. The second flange 1402 is connected to the first body 1400 and disposed around the third through-hole 14001. Along the thickness direction z of the first wall, the second flange 1402 protrudes toward the first through-hole 1100 to cover a portion of the wall of the first through-hole 1100, thereby insulating and isolating the first electrode terminal 13 from the wall of the first through-hole 1100. In some embodiments, the second flange 1402 also serves as a positioning mechanism. By aligning the second flange 1402 with the first through-hole 1100, the first insulating member 140 can be quickly assembled to the first wall 110.
在一些实施例中,第二凸缘1402可以将第一通孔1100的孔壁局部或者全部覆盖。In some embodiments, the second flange 1402 may partially or completely cover the hole wall of the first through hole 1100 .
上述方案中,通过设置第二凸缘1402,能够有效地绝缘隔离第一通孔1100的孔壁和第一电极端子13,降低第一电极端子13与第一通孔1100的孔壁接触导致电池单体10内部短路的风险,有效地提高电池的可靠性。In the above solution, by providing the second flange 1402, the hole wall of the first through hole 1100 and the first electrode terminal 13 can be effectively insulated and isolated, reducing the risk of the first electrode terminal 13 contacting the hole wall of the first through hole 1100 and causing an internal short circuit in the battery cell 10, thereby effectively improving the reliability of the battery.
在一些实施例中,请参见图5和图8,第一绝缘部14还可以包括第一密封部141,第一密封部141可以套设于第二部分131,第一密封部141的部分夹持于第一通孔1100和第二部分131之间,第一密封部141的另一部分可以夹持于第一壁110的背离于第一部分130的表面和第二部分131之间。In some embodiments, referring to Figures 5 and 8, the first insulating portion 14 may further include a first sealing portion 141. The first sealing portion 141 may be sleeved on the second portion 131, and a portion of the first sealing portion 141 may be clamped between the first through hole 1100 and the second portion 131. Another portion of the first sealing portion 141 may be clamped between the surface of the first wall 110 facing away from the first portion 130 and the second portion 131.
根据本申请的一些实施例,请参见图4-图13,图12为本申请一些实施例中第一壁和第二电极端子的示意图,图13为本申请一些实施例中第二变形件18的示意图。According to some embodiments of the present application, please refer to Figures 4 to 13. Figure 12 is a schematic diagram of the first wall and the second electrode terminal in some embodiments of the present application, and Figure 13 is a schematic diagram of the second deformation member 18 in some embodiments of the present application.
电池单体10还包括第二电极端子16、第二绝缘部17和第二变形件18。第二电极端子16设置于第一壁110并与电极组件12电连接,第二电极端子16用于电能的输入和输出,第二电极端子16和第一电极端子13的极性相反。第二绝缘部17设置于第一壁110和第二电极端子16之间,用于绝缘隔离第二电极端子16和第一壁110。第二变形件18与第一壁110电连接,第二变形件18被配置可以变形以与第二电极端子16接触,以将第二电极端子16与第一壁110电连接。The battery cell 10 also includes a second electrode terminal 16, a second insulating portion 17, and a second deformable member 18. The second electrode terminal 16 is disposed on the first wall 110 and electrically connected to the electrode assembly 12. The second electrode terminal 16 is used for inputting and outputting electrical energy, and the polarity of the second electrode terminal 16 and the first electrode terminal 13 are opposite. The second insulating portion 17 is disposed between the first wall 110 and the second electrode terminal 16 to insulate and isolate the second electrode terminal 16 from the first wall 110. The second deformable member 18 is electrically connected to the first wall 110 and is configured to deform into contact with the second electrode terminal 16 to electrically connect the second electrode terminal 16 to the first wall 110.
第二电极端子16为安装于第一壁110的部件,第二电极端子16用于与电极组件12电连接,用于使得电流经第二电极端子16流入或者流出于第二极耳121。第二电极端子16和第二极耳121的极性相同。在一些实施例中,当第一电极端子13为正极电极端子时,第二电极端子16为负极电极端子。当第一电极端子13为负极电极端子时,第二电极端子16为正极电极端子。The second electrode terminal 16 is a component mounted on the first wall 110. The second electrode terminal 16 is used to electrically connect to the electrode assembly 12, allowing current to flow into or out of the second electrode tab 121 through the second electrode terminal 16. The second electrode terminal 16 and the second electrode tab 121 have the same polarity. In some embodiments, when the first electrode terminal 13 is a positive electrode terminal, the second electrode terminal 16 is a negative electrode terminal. When the first electrode terminal 13 is a negative electrode terminal, the second electrode terminal 16 is a positive electrode terminal.
在一些实施例中,第二电极端子16为金属材料制得,例如通过铝、铜、铁、铝、钢、合金或者复合金属制得。在一些实施例中,第二电极端子16可以通过第二转接件124与第二极耳121连接。示例性地,电极组件12的第二极耳121由多个第二子极耳层叠构成,可以向将第二转接件124的一端与第二极耳121焊接后,再将第二转接件124的另一端与第二电极端子16焊接。In some embodiments, the second electrode terminal 16 is made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal. In some embodiments, the second electrode terminal 16 can be connected to the second electrode tab 121 via a second adapter 124. For example, the second electrode tab 121 of the electrode assembly 12 is composed of a plurality of second sub-electrode tabs stacked together. After welding one end of the second adapter 124 to the second electrode tab 121, the other end of the second adapter 124 can be welded to the second electrode terminal 16.
第二绝缘部17具有较高电阻值,能够使得第二电极端子16与第一壁110相互绝缘。示例性地,请参见图5,第二电极端子16具有暴露于外的第三部分160,第二绝缘部17可以设置于第一壁110的外侧面和第三部分160之间以绝缘隔离第二电极端子16和第一壁110。在一些实施例中,第二绝缘部17可以包覆第三部分160的外周,提高第二电极端子16与第一壁110的爬电距离。The second insulating portion 17 has a high resistance, insulating the second electrode terminal 16 from the first wall 110. For example, referring to FIG. 5 , the second electrode terminal 16 has an exposed third portion 160. The second insulating portion 17 can be disposed between the outer side of the first wall 110 and the third portion 160 to insulate the second electrode terminal 16 from the first wall 110. In some embodiments, the second insulating portion 17 can cover the outer periphery of the third portion 160 to increase the creepage distance between the second electrode terminal 16 and the first wall 110.
示例性地,在一些实施例中,第一壁110上形成有第五通孔1102,第二电极端子16可以穿过第五通孔1102以在外侧形成第三部分160,在内侧形成第四部分161,第三部分160用于与外部电连接构件连接,第四部分161用于与电极组件12电连接。第二绝缘部17对应于第五通孔1102形成有第七通孔17001,以供第二电极端子16穿过。可选地,第二绝缘部17的主要部分位于第三部分160和第一壁110之间,第二绝缘部17的一些部分可以位于第五通孔1102和第二电极端子16之间。可选地,第二绝缘部17的主要部分位于第三部分160和第一壁110之间,第二绝缘部17的一些部分可以位于第五通孔1102和第二电极端子16之间,第二绝缘部17的剩余部分还可以位于第一壁110和第四部分161之间。For example, in some embodiments, a fifth through-hole 1102 is formed in the first wall 110. The second electrode terminal 16 can pass through the fifth through-hole 1102 to form a third portion 160 on the outside and a fourth portion 161 on the inside. The third portion 160 is used to connect to an external electrical connection member, and the fourth portion 161 is used to electrically connect to the electrode assembly 12. The second insulating portion 17 has a seventh through-hole 17001 formed therein, corresponding to the fifth through-hole 1102, for the second electrode terminal 16 to pass through. Alternatively, a major portion of the second insulating portion 17 is located between the third portion 160 and the first wall 110, while some portion of the second insulating portion 17 may be located between the fifth through-hole 1102 and the second electrode terminal 16. Alternatively, a major portion of the second insulating portion 17 is located between the third portion 160 and the first wall 110, while some portion of the second insulating portion 17 may be located between the fifth through-hole 1102 and the second electrode terminal 16, and the remaining portion of the second insulating portion 17 may also be located between the first wall 110 and the fourth portion 161.
在一些实施例中,第二绝缘部17整体可以呈板状,其相对的两个表面均较为平整,以稳定地处于第二电极端子16和第一壁110之间。In some embodiments, the second insulating portion 17 may be in a plate shape as a whole, and its two opposite surfaces are relatively flat so as to be stably positioned between the second electrode terminal 16 and the first wall 110 .
在一些实施例中,第二绝缘部17可以通过较高电阻值的材料制得,如有机绝缘材料、无机绝缘材料或者混合绝缘材料等。示例性地,本申请一些实施例中,第二绝缘部17的材料可以包括绝缘PPS(聚苯硫醚)材料。在其他一些实施例中,第二绝缘部17还可以为聚丙烯、聚乙烯等其他具有绝缘特性的材料制得。In some embodiments, the second insulating portion 17 can be made of a material with a relatively high resistance, such as an organic insulating material, an inorganic insulating material, or a mixed insulating material. For example, in some embodiments of the present application, the material of the second insulating portion 17 can include an insulating PPS (polyphenylene sulfide) material. In other embodiments, the second insulating portion 17 can also be made of other materials with insulating properties, such as polypropylene and polyethylene.
在一些实施例中,第二绝缘部17的电阻值可以以兆欧(MΩ)为单元。示例性地,本申请一些实施例提供的电池单体10中,第二绝缘部17的电阻值可以大于或者等于200MΩ。在其他一些实施例中,第二绝缘部17的电阻值的取值可以为其他数值,例如1MΩ、10MΩ、20MΩ、30MΩ、40MΩ、50MΩ、60MΩ、70MΩ、80MΩ、90MΩ、100MΩ、110MΩ、120MΩ、130MΩ…210MΩ、220MΩ、230MΩ等数值。In some embodiments, the resistance value of the second insulating portion 17 can be measured in megohms (MΩ). For example, in the battery cell 10 provided in some embodiments of the present application, the resistance value of the second insulating portion 17 can be greater than or equal to 200 MΩ. In other embodiments, the resistance value of the second insulating portion 17 can be other values, such as 1 MΩ, 10 MΩ, 20 MΩ, 30 MΩ, 40 MΩ, 50 MΩ, 60 MΩ, 70 MΩ, 80 MΩ, 90 MΩ, 100 MΩ, 110 MΩ, 120 MΩ, 130 MΩ…210 MΩ, 220 MΩ, 230 MΩ, etc.
第二变形件18安装于第一壁110,且第二变形件18与第一壁110电连接。在一些实施例中,第二变形件18可以为金属材料制得,例如第二变形件18通过铝、铜、铁、铝、钢、合金或者复合金属制得。在一些实施例中,第二变形件18可以焊接于第一壁110的内侧面。The second deformable member 18 is mounted on the first wall 110 and is electrically connected to the first wall 110. In some embodiments, the second deformable member 18 can be made of a metal material, such as aluminum, copper, iron, aluminum, steel, an alloy, or a composite metal. In some embodiments, the second deformable member 18 can be welded to the inner side of the first wall 110.
第二变形件18为受电池单体10内部压力而变形的结构件。第二变形件18用于电池单体10的过充保护,示例性地,在电池单体10处于过充等滥用工况时,内部压力增高,内部压力到达一定程度,例如第二阈值时,第二变形件18变形以接触第二电极端子16,从而导通第一壁110和第二电极端子16,使得电池单体10内部正负极短接。The second deformable member 18 is a structural member that deforms due to the internal pressure of the battery cell 10. The second deformable member 18 is used to protect the battery cell 10 from overcharge. For example, when the battery cell 10 is subjected to an abusive operating condition such as overcharge, the internal pressure increases. When the internal pressure reaches a certain level, such as a second threshold, the second deformable member 18 deforms to contact the second electrode terminal 16, thereby electrically connecting the first wall 110 to the second electrode terminal 16, short-circuiting the positive and negative electrodes within the battery cell 10.
在一些实施例中,第二变形件18受压力变形以与第二电极端子16接触的部位,可以为第二电极端子16处于第一壁110的内侧部分,也可以为第二电极端子16处于第一壁110的外侧的部分,例如第二变形件18在电池单体10内部压力达到第二阈值时变形能够与第四部分161连接,又例如,第二变形件18在电池单体10内部压力达到第二阈值时变形能够与第三部分160连接。In some embodiments, the portion of the second deformable member 18 that is deformed by pressure to contact the second electrode terminal 16 can be the inner portion of the second electrode terminal 16 on the first wall 110, or the portion of the second electrode terminal 16 on the outer side of the first wall 110. For example, the second deformable member 18 can be deformed and connected to the fourth portion 161 when the internal pressure of the battery cell 10 reaches the second threshold value. For another example, the second deformable member 18 can be deformed and connected to the third portion 160 when the internal pressure of the battery cell 10 reaches the second threshold value.
在一些实施例中,第二变形件18可以为翻转片,翻转片受压力作用而翻转。示例性地,请参见图5和图13,第二变形件18外轮廓呈圆盘状,由外向内包括依次连接的第二裙边180、第二翻转箔181以及第二电连接部182,第二裙边180可以与第一壁110连接,第二翻转箔181的厚度较薄,用于受压力而形变翻转。第二翻转箔181翻转后,能够将第二电连接部182向第二电极端子16推动,从而使得第二电连接部182与第二电极端子16接触。In some embodiments, the second deformable member 18 may be a flip sheet that flips under pressure. For example, referring to Figures 5 and 13 , the second deformable member 18 has a disc-shaped outer profile and comprises, from the outside inward, a second skirt 180, a second flip foil 181, and a second electrical connection portion 182. The second skirt 180 may be connected to the first wall 110. The second flip foil 181 is relatively thin and is designed to deform and flip under pressure. After the second flip foil 181 flips, it can push the second electrical connection portion 182 toward the second electrode terminal 16, thereby bringing the second electrical connection portion 182 into contact with the second electrode terminal 16.
示例性地,第一壁110具有第六通孔1103,第二裙边180焊接于第一壁110,使得第二变形件18将第六通孔1103封闭。第二翻转箔181在自然状态时呈向背离于第一壁110的方向塌陷的状态,第二翻转箔181在电池单体10内部压力达到第二阈值时,朝向面向第一壁110的方向翻转,以将第二电连接部182推动,从而使得第二电连接部182穿过第六通孔1103与第三部分160接触。Illustratively, the first wall 110 has a sixth through hole 1103, and the second skirt 180 is welded to the first wall 110, so that the second deformable member 18 closes the sixth through hole 1103. In its natural state, the second flip foil 181 is collapsed away from the first wall 110. When the internal pressure of the battery cell 10 reaches a second threshold, the second flip foil 181 flips toward the first wall 110 to push the second electrical connection portion 182, thereby allowing the second electrical connection portion 182 to pass through the sixth through hole 1103 and contact the third portion 160.
在一些实施例中,电池单体10因过充等情况处于滥用工况时,电池单体10内部压力增长,在电池单体10内部压力达到一定程度,例如第一阈值时,第一变形件15变形,将第一电极端子13和外壳11短接,在电池单体10内部压力达到第二阈值时,第二变形件18变形,将第二电极端子16与外壳11短接,从而使得电池单体10内部正负极短接以内部短路,瞬时产生的大电流可以将电池单体10内部的电连接构件熔断,切断电池单体10的充放电回路,从而起到过充保护的作用。熔断的电连接构件可以包括第一转接件123和/或第二转接件124。示例性地,第一转接件123具有第一熔断部,第一熔断部的过流面积可以小于第一转接件123的其余部分的过流面积,以在较大电流经过时,能使得第一熔断部熔断,从而断开第一极耳120和第一电极端子13的电流路径。示例性地,第二转接件124具有第二熔断部,第二熔断部的过流面积可以小于第二转接件124的其余部分的过流面积,以在较大电流经过时,能使得第二熔断部熔断,从而断开第二极耳121和第二电极端子16的电流路径。In some embodiments, when a battery cell 10 is subjected to abuse due to overcharging or other conditions, the internal pressure of the battery cell 10 increases. When the internal pressure of the battery cell 10 reaches a certain level, such as a first threshold, the first deformable member 15 deforms, short-circuiting the first electrode terminal 13 and the outer casing 11. When the internal pressure of the battery cell 10 reaches a second threshold, the second deformable member 18 deforms, short-circuiting the second electrode terminal 16 and the outer casing 11, thereby short-circuiting the positive and negative electrodes within the battery cell 10 and creating an internal short circuit. The resulting high current can melt the electrical connections within the battery cell 10, severing the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection. The fused electrical connections can include the first adapter 123 and/or the second adapter 124. For example, the first adapter 123 has a first fuse portion, the flow area of which can be smaller than the flow area of the remaining portions of the first adapter 123. This allows the first fuse portion to melt when a large current flows, thereby severing the current path between the first tab 120 and the first electrode terminal 13. Exemplarily, the second adapter 124 has a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the rest of the second adapter 124, so that when a larger current passes through, the second fuse portion can be melted, thereby disconnecting the current path between the second electrode tab 121 and the second electrode terminal 16.
上述方案中,一方面,通过在第一壁110和第二电极端子16之间设置第二绝缘部17,能够有效地绝缘隔离第一壁110和第二电极端子16,降低因第一壁110和第二电极端子16之间短接导致电池单体10内部短路的风险,使得电池的可靠性高;另一方面,通过设置第二变形件18,在电池单体10内部压力达到一定程度,例如第二阈值时,通过第二变形件18的变形以与第二电极端子16接触,从而使得第二电极端子16与第二壁电连接,配合第一变形件15与第一电极端子13的短接,使得电池单体10内部的电连接构件因短路产生的大电流而熔断,以切断电池单体10的充放电回路,从而起到过充保护的作用,以及起到降低电池单体10热失控的风险的作用,进而使得电池具有较高的可靠性;再一方面,因第一电极端子13和第二电极端子16在未滥用工况下均与第一壁110绝缘隔离,故电池单体10的外壳11可以不带电,以利于该电池单体10构成储能装置,使得储能装置中相邻的两个电池单体10之间打火击穿的风险小,同时,通过设置第二变形件18以能够有效地实现过充保护的作用,使得该储能装置可靠性高。In the above solution, on the one hand, by providing the second insulating portion 17 between the first wall 110 and the second electrode terminal 16, the first wall 110 and the second electrode terminal 16 can be effectively insulated and isolated, thereby reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first wall 110 and the second electrode terminal 16, thereby improving the reliability of the battery; on the other hand, by providing the second deformable member 18, when the internal pressure of the battery cell 10 reaches a certain level, such as the second threshold value, the second deformable member 18 is deformed to contact the second electrode terminal 16, thereby electrically connecting the second electrode terminal 16 to the second wall, and cooperating with the short circuit of the first deformable member 15 and the first electrode terminal 13, the internal pressure of the battery cell 10 is reduced. The electrical connection component is melted due to the large current generated by the short circuit, so as to cut off the charge and discharge circuit of the battery cell 10, thereby playing the role of overcharge protection and reducing the risk of thermal runaway of the battery cell 10, thereby making the battery have higher reliability; on the other hand, because the first electrode terminal 13 and the second electrode terminal 16 are insulated and isolated from the first wall 110 under non-abuse conditions, the shell 11 of the battery cell 10 can be uncharged, so that the battery cell 10 constitutes an energy storage device, which reduces the risk of ignition and breakdown between two adjacent battery cells 10 in the energy storage device. At the same time, by providing the second deformable member 18, the overcharge protection function can be effectively achieved, so that the energy storage device has high reliability.
根据本申请的一些实施例,第二电极端子16为负极电极端子,使得第二变形件18变形的最小压力值大于使得第一变形件15变形的最小压力值。According to some embodiments of the present application, the second electrode terminal 16 is a negative electrode terminal, so that the minimum pressure value for deforming the second deformable member 18 is greater than the minimum pressure value for deforming the first deformable member 15 .
在一些实施例中,在电池单体10内部压力达到第一阈值时,第一变形件15变形。在电池单体10内部压力达到第二阈值时,第二变形件变形。第二阈值可以大于第一阈值。In some embodiments, when the internal pressure of the battery cell 10 reaches a first threshold, the first deforming member 15 deforms. When the internal pressure of the battery cell 10 reaches a second threshold, the second deforming member deforms. The second threshold may be greater than the first threshold.
在一些实施例中,第二电极端子16为负极电极端子,也即第二电极端子16与电极组件12的负极耳电连接。In some embodiments, the second electrode terminal 16 is a negative electrode terminal, that is, the second electrode terminal 16 is electrically connected to the negative electrode tab of the electrode assembly 12 .
“第二阈值大于第一阈值”可以理解为,第二变形件18较第一变形件15更不易变形,也即在电池单体10内部压力进一步增长且超过第一阈值时,才使得第二变形件18变形。“The second threshold is greater than the first threshold” can be understood as the second deformable member 18 is less susceptible to deformation than the first deformable member 15 , that is, the second deformable member 18 deforms only when the internal pressure of the battery cell 10 further increases and exceeds the first threshold.
在一些实施例中,可以对第二变形件18的制造材料或者结构进行改变,以使得第二变形件18较第一变形件15更不易变形。示例性地,在一些实施例中,第二变形件18的第二翻转箔181的厚度较第一变形件15的第一翻转箔151的厚度大,以使得第二变形件18承受更大压力时才变形以与第二电极端子16接触。或者,在一些实施例中,在第二翻转箔181上设置加强结构,例如加强筋、加强凹凸部等结构,以使得第二变形件18承受更大压力时才变形以与第二电极端子16接触。In some embodiments, the manufacturing material or structure of the second deformable member 18 can be modified to make the second deformable member 18 less susceptible to deformation than the first deformable member 15. For example, in some embodiments, the thickness of the second flip foil 181 of the second deformable member 18 is greater than the thickness of the first flip foil 151 of the first deformable member 15, so that the second deformable member 18 deforms to contact the second electrode terminal 16 only when subjected to greater pressure. Alternatively, in some embodiments, a reinforcing structure, such as a reinforcing rib or a reinforcing concave-convex portion, is provided on the second flip foil 181, so that the second deformable member 18 deforms to contact the second electrode terminal 16 only when subjected to greater pressure.
在一些实施例中,“第二阈值大于第一阈值”可以理解为,第二变形件18较第一变形件15需要再更大的压力作用下才与第二电极端子16接触,也即在电池单体10内部压力进一步增长且超过第一阈值时,才使得第二变形件18与第二电极端子16接触。示例性地,可以提高第二变形件18与第二电极端子16之间的距离,以使得第二变形件18需要在做出更大变形量的条件下才能与第二电极端子16接触。例如,第二电连接部182与第二电极端子16之间的距离大于第一电连接部152与第一电极端子13之间的距离;又例如,在自然状态下,第二翻转箔181较第一翻转箔151更远离第一壁110。In some embodiments, "the second threshold is greater than the first threshold" can be understood to mean that the second deformable member 18 requires a greater pressure than the first deformable member 15 to contact the second electrode terminal 16. In other words, the second deformable member 18 only contacts the second electrode terminal 16 when the internal pressure of the battery cell 10 further increases and exceeds the first threshold. For example, the distance between the second deformable member 18 and the second electrode terminal 16 can be increased so that the second deformable member 18 requires a greater amount of deformation to contact the second electrode terminal 16. For example, the distance between the second electrical connection portion 182 and the second electrode terminal 16 is greater than the distance between the first electrical connection portion 152 and the first electrode terminal 13; for another example, in a natural state, the second flip foil 181 is further away from the first wall 110 than the first flip foil 151.
上述方案中,在第二电极端子16为负极电极端子时,通过将第二阈值设置为大于第一阈值,能够使得第二变形件18较第一变形件15在电池单体10内部压力更大的时候变形,一方面,能够使得电池单体10具有过充保护功能,另一方面,能够降低在非过充滥用工况下,在电池单体10内部产气导致第二变形件18翻转致使外壳11带负电而被电解液腐蚀的风险,从而一定程度上保证外壳11的完整性,降低电解液泄露的风险,进而提高电池的可靠性。In the above scheme, when the second electrode terminal 16 is a negative electrode terminal, by setting the second threshold value to be greater than the first threshold value, the second deformable member 18 can be deformed when the pressure inside the battery cell 10 is greater than that of the first deformable member 15. On the one hand, the battery cell 10 can have an overcharge protection function. On the other hand, it can reduce the risk of gas production inside the battery cell 10 causing the second deformable member 18 to flip over, resulting in the outer shell 11 being negatively charged and corroded by the electrolyte under non-overcharge abuse conditions, thereby ensuring the integrity of the outer shell 11 to a certain extent, reducing the risk of electrolyte leakage, and thus improving the reliability of the battery.
“能够降低在非过充滥用工况下,在电池单体10内部产气导致第二变形件18翻转致使外壳11带负电而被电解液腐蚀的风险”可以理解为,随电池单体10充放电次数的增加,电池单体10内部产气也随之增加,在电池单体10的全生命末期,内部气体多致使内部压力大,此时电池不处于过充的情况但其内部压力过大,可能导致第二变形件18变形以导通电极组件12的负极耳与外壳11,使得外壳11带负电,然而外壳11带负电会导致与电解液发生电化学反应,造成外壳11被腐蚀,存在漏液的风险。为此,通过将第二阈值设置的较第一阈值大,能够降低因非过充等情况导致外壳11带负电的概率,从而提高外壳11的完整性,提高电池的可靠性。"It can reduce the risk of gas production inside the battery cell 10 causing the second deformable member 18 to flip over, resulting in the shell 11 being negatively charged and corroded by the electrolyte under non-overcharge abuse conditions" can be understood as follows: as the number of charge and discharge times of the battery cell 10 increases, the gas production inside the battery cell 10 also increases. At the end of the life of the battery cell 10, the internal gas is high, resulting in high internal pressure. At this time, the battery is not in an overcharged state, but its internal pressure is too high, which may cause the second deformable member 18 to deform to connect the negative ear of the electrode assembly 12 and the shell 11, making the shell 11 negatively charged. However, the negative charge of the shell 11 will cause an electrochemical reaction with the electrolyte, causing the shell 11 to be corroded, and there is a risk of leakage. To this end, by setting the second threshold value larger than the first threshold value, the probability of the shell 11 being negatively charged due to non-overcharge and other conditions can be reduced, thereby improving the integrity of the shell 11 and improving the reliability of the battery.
在其他一些实施例中,不限制第一阈值和第二阈值的大小关系,例如第一阈值可以等于第二阈值。In some other embodiments, the magnitude relationship between the first threshold and the second threshold is not limited. For example, the first threshold may be equal to the second threshold.
根据本申请的一些实施例,请参见图10、图12以及图14,图14为本申请一些实施例中第一壁110的局部示意图。第一壁110形成有第五通孔1102和第六通孔1103,第二电极端子16穿过第五通孔1102,沿第一壁的厚度方向z,第二变形件18封闭第六通孔1103,第二变形件18被配置可以变形以部分穿过第六通孔1103与第二电极端子16接触。According to some embodiments of the present application, please refer to Figures 10, 12, and 14. Figure 14 is a partial schematic diagram of the first wall 110 in some embodiments of the present application. The first wall 110 is formed with a fifth through-hole 1102 and a sixth through-hole 1103. The second electrode terminal 16 passes through the fifth through-hole 1102. Along the thickness direction z of the first wall, the second deformable member 18 closes the sixth through-hole 1103. The second deformable member 18 is configured to deform to partially pass through the sixth through-hole 1103 and contact the second electrode terminal 16.
在一些实施例中,第一壁110可以为外壳11的端盖,第一壁110可以呈板状。沿第一壁的厚度方向z,第一壁110形成有贯通的第五通孔1102和第六通孔1103。第五通孔1102供第二电极端子16穿过,第六通孔1103用于第二变形件18的穿过。In some embodiments, the first wall 110 may be an end cap of the housing 11 and may be plate-shaped. A fifth through-hole 1102 and a sixth through-hole 1103 are formed along the thickness direction z of the first wall 110. The fifth through-hole 1102 allows the second electrode terminal 16 to pass through, while the sixth through-hole 1103 allows the second deformable member 18 to pass through.
示例性地,请参见图12,第二电极端子16包括第三部分160和第四部分161,第三部分160处于第一壁110的外侧,第三部分160可以呈平板状以与外部结构电连接。第四部分161的部分处于第一壁110的内侧以与电极组件12电连接,第四部分161的另一部分穿过第五通孔1102与第三部分160连接。第四部分161与第三部分160的连接关系包括但不限于焊接、粘接、铆接或者螺纹件连接等。在另一些实施例中,第三部分160可以部分位于第一壁110的外侧,第三部分160的另一部分可以穿过第五通孔1102与第四部分161连接。在另一些实施例中,第三部分160可以部位位于第一壁110的外侧,第四部分161的部分位于第一壁110的内侧,第三部分160的另一部分和第四部分161的另一部分位于第五通孔1102内并相互连接。For example, referring to FIG. 12 , the second electrode terminal 16 includes a third portion 160 and a fourth portion 161. The third portion 160 is located outside the first wall 110 and can be flat for electrical connection to external structures. A portion of the fourth portion 161 is located inside the first wall 110 for electrical connection to the electrode assembly 12. Another portion of the fourth portion 161 is connected to the third portion 160 through a fifth through-hole 1102. Connections between the fourth portion 161 and the third portion 160 include, but are not limited to, welding, bonding, riveting, or screwing. In other embodiments, the third portion 160 can be partially located outside the first wall 110, with another portion of the third portion 160 connected to the fourth portion 161 through the fifth through-hole 1102. In other embodiments, the third portion 160 can be partially located outside the first wall 110, while a portion of the fourth portion 161 is located inside the first wall 110. Another portion of the third portion 160 and another portion of the fourth portion 161 are located within the fifth through-hole 1102 and connected to each other.
“第二变形件18封闭第六通孔1103”可以指第二变形件18将第六通孔1103封闭,使得电极组件12和电解液处于封闭的空间中。在一些实施例中,第二变形件18的第二裙边180围设于第六通孔1103的边缘设置并焊接于第一壁110的内侧。"Second deformable member 18 closes sixth through hole 1103" may mean that second deformable member 18 closes sixth through hole 1103, thereby enclosing electrode assembly 12 and electrolyte. In some embodiments, second skirt 180 of second deformable member 18 is disposed around the edge of sixth through hole 1103 and welded to the inner side of first wall 110.
在一些实施例中,当电池单体10内部压力达到一定程度,例如第二阈值时,第二变形件18能够朝向第三部分160变形以穿过第六通孔1103与第三部分160接触。In some embodiments, when the internal pressure of the battery cell 10 reaches a certain level, such as a second threshold, the second deformation member 18 can be deformed toward the third portion 160 to pass through the sixth through hole 1103 and contact the third portion 160 .
在一些实施例中,第六通孔1103可以为阶梯孔状,能够为第二变形件18的第二裙边180提供连接部位,使得第二裙边180能够容纳于第六通孔1103中,降低第二变形件18对电池单体10内部空间的占用。In some embodiments, the sixth through hole 1103 can be a stepped hole shape, which can provide a connection portion for the second skirt 180 of the second deformable member 18, so that the second skirt 180 can be accommodated in the sixth through hole 1103, reducing the occupation of the internal space of the battery cell 10 by the second deformable member 18.
上述方案中,在电池单体10内部压力达到一定程度,例如第二阈值时,电池单体10的内部压力能够作用于第二变形件18,使得第二变形件18朝向第一壁110的外侧变形以有效地接触第二电极端子16的第三部分160,配合第一变形件15与第一电极端子13接触,使得电池单体10内部的电连接构件因短路产生的大电流而熔断,以切断电池单体10的充放电回路,从而起到降低电池单体10热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, when the internal pressure of the battery cell 10 reaches a certain level, such as the second threshold value, the internal pressure of the battery cell 10 can act on the second deformable member 18, so that the second deformable member 18 is deformed toward the outside of the first wall 110 to effectively contact the third part 160 of the second electrode terminal 16, and cooperates with the first deformable member 15 to contact the first electrode terminal 13, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, so as to cut off the charging and discharging circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
根据本申请的一些实施例,请参见图12,沿第一壁的厚度方向z,第二电极端子16位于第一壁110的外侧的第三部分160的投影与第二变形件18的投影至少部分重叠。According to some embodiments of the present application, referring to FIG. 12 , along the thickness direction z of the first wall, the projection of the third portion 160 of the second electrode terminal 16 located outside the first wall 110 at least partially overlaps with the projection of the second deformable member 18 .
在一些实施例中,第三部分160尺寸较大,沿着第一壁的厚度方向z,第三部分160的部分可以正对第四部分161设置以与第四部分161连接,第三部分160的部分可以正对第二变形件18,以在第二变形件18变形时与第二变形件18直接接触。In some embodiments, the third part 160 is larger in size, and along the thickness direction z of the first wall, a portion of the third part 160 can be set opposite the fourth part 161 to be connected to the fourth part 161, and a portion of the third part 160 can be opposite the second deforming member 18 to directly contact the second deforming member 18 when the second deforming member 18 is deformed.
在一些实施例中,沿第一壁的厚度方向z,第二变形件18的投影可以全部地落在第三部分160上。在另一些实施例中,沿第一壁的厚度方向z,第二变形件18的投影可以部分地落在第三部分160上,另一部分与第三部分160错开。In some embodiments, along the thickness direction z of the first wall, the projection of the second deformable member 18 may entirely fall on the third portion 160. In other embodiments, along the thickness direction z of the first wall, the projection of the second deformable member 18 may partially fall on the third portion 160, while another portion may be offset from the third portion 160.
上述方案中,通过将第二变形件18沿第一壁的厚度方向z对应于第三部分160设置,能够在电池单体10内部压力达到一定程度,例如第二阈值,以较小的变形量快速地接触第三部分160,从而快速地使得第二电极端子16和第一壁110电连接,配合第一变形件15与第一电极端子13接触,使得电池单体10内部的电连接构件因短路产生的大电流而熔断,以切断电池单体10的充放电回路,从而起到降低电池单体10热失控的风险的作用,进而使得电池具有较高的可靠性。In the above scheme, by arranging the second deformable member 18 along the thickness direction z of the first wall corresponding to the third part 160, when the pressure inside the battery cell 10 reaches a certain level, such as the second threshold, the third part 160 can be quickly contacted with a smaller deformation amount, thereby quickly electrically connecting the second electrode terminal 16 and the first wall 110, and cooperating with the first deformable member 15 to contact the first electrode terminal 13, so that the electrical connection components inside the battery cell 10 are melted due to the large current generated by the short circuit, thereby cutting off the charge and discharge circuit of the battery cell 10, thereby reducing the risk of thermal runaway of the battery cell 10, and thus making the battery have higher reliability.
根据本申请的一些实施例,请参见图10,第一壁110包括彼此连接的本体部110a和第二加强部110c,第二电极端子16位于第一壁110的外侧的第三部分160设置于第二加强部110c。According to some embodiments of the present application, referring to FIG. 10 , the first wall 110 includes a main body portion 110 a and a second reinforcement portion 110 c connected to each other, and the third portion 160 of the second electrode terminal 16 located outside the first wall 110 is disposed on the second reinforcement portion 110 c.
在一些实施例中,第二加强部110c的作用在于使得第一壁110的整体结构强度加强或者使得第一壁110的局部结构强度加强,使得第一壁110具有较高的抗冲击能力,降低第一壁110形变的风险。在一些实施例中,第二加强部110c可以为加强筋、凹凸结构等结构。In some embodiments, the second reinforcement portion 110c is used to strengthen the overall structural strength of the first wall 110 or to strengthen the local structural strength of the first wall 110, thereby enhancing the impact resistance of the first wall 110 and reducing the risk of deformation of the first wall 110. In some embodiments, the second reinforcement portion 110c may be a reinforcing rib, a concave-convex structure, or the like.
在一些实施例中,第一壁110包括本体部110a以及层叠设置于本体部110a表面的第二加强部110c,第二加强部110c的材料与本体部110a的材料相同,在第二加强部110c所在的部位第一壁110的厚度较大,从而该部位具有较大的结构强度。In some embodiments, the first wall 110 includes a main body portion 110a and a second reinforcement portion 110c stacked on the surface of the main body portion 110a. The material of the second reinforcement portion 110c is the same as that of the main body portion 110a. The thickness of the first wall 110 is larger at the location of the second reinforcement portion 110c, so that this portion has greater structural strength.
在一些实施例中,第一壁110包括本体部110a,对本体部110a进行冲压以在本体部110a的一侧形成凸包另一侧形成凹部,该凸部和凹部所在的部位形成第二加强部110c。In some embodiments, the first wall 110 includes a main body portion 110 a , which is punched to form a convex portion on one side and a concave portion on the other side of the main body portion 110 a , and the portions where the convex portion and the concave portion are located form the second reinforcement portion 110 c .
在另一些实施例中,第一壁110包括本体部110a和第二加强部110c,本体部110a围设于第二加强部110c的边缘,第二加强部110c的材料和本体部110a的材料可以相同也可以不同,第二加强部110c的结构强度大于本体部110a。In other embodiments, the first wall 110 includes a main body portion 110a and a second reinforcement portion 110c, the main body portion 110a is arranged around the edge of the second reinforcement portion 110c, the material of the second reinforcement portion 110c and the material of the main body portion 110a can be the same or different, and the structural strength of the second reinforcement portion 110c is greater than that of the main body portion 110a.
“第三部分160设置于第二加强部110c”可以理解为,第一壁110用于支撑第三部分160的部位为第一壁110的结构强度较大的部分。“The third portion 160 is disposed on the second reinforcement portion 110 c ” can be understood as that the portion of the first wall 110 used to support the third portion 160 is the portion of the first wall 110 with greater structural strength.
上述方案中,通过设置第二加强部110c,能够提高第一壁110的整体强度,能够降低因电池单体10内部压力或者外部冲击作用下,导致第一壁110形变,致使第二变形件18无法有效与第三部分160接触以导通第二电极端子16和第一壁110的风险,能够使得第二变形件18在电池单体10过充等滥用工况下有效地与第二电极端子16接触,从而有效地起到过充保护的作用,降低电池单体10热失控的风险,使得电池具有较高的可靠性。In the above scheme, by providing the second reinforcement portion 110c, the overall strength of the first wall 110 can be improved, and the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the second deformable member 18 to be unable to effectively contact the third part 160 to conduct electricity between the second electrode terminal 16 and the first wall 110, can be reduced. The second deformable member 18 can effectively contact the second electrode terminal 16 under abuse conditions such as overcharging of the battery cell 10, thereby effectively playing the role of overcharge protection, reducing the risk of thermal runaway of the battery cell 10, and making the battery have higher reliability.
在一些实施例中,第二加强部110c较本体部110a更不易变形,以能够为第三部分160提供有效地支撑。In some embodiments, the second reinforcement portion 110 c is less susceptible to deformation than the main body portion 110 a , thereby being able to provide effective support for the third portion 160 .
在一些实施例中,本体部110a可以围绕于第二加强部110c的边缘设置。In some embodiments, the main body portion 110 a may be disposed around an edge of the second reinforcement portion 110 c .
在一些实施例中,第二加强部110c可以相对于本体部110a凹凸以使得第二加强部110c的结构强度大于本体部110a的结构强度。在另一些实施例中,第二加强部110c的厚度可以大于本体部110a的厚度,以使得第二加强部110c的结构强度大于本体部110a的结构强度。通过将第二加强部110c的结构强度设置为大于本体部110a的结构强度,一方面能够有效地提高第一壁110的整体强度,另一方面,能够使得第一壁110的对应于第三部分160的局部部分具有较强的结构强度,使得第三部分160有效地与第二变形件18配合,提高过充保护的可靠性。In some embodiments, the second reinforcement portion 110c can be concave or convex relative to the main body portion 110a, such that the structural strength of the second reinforcement portion 110c is greater than that of the main body portion 110a. In other embodiments, the thickness of the second reinforcement portion 110c can be greater than that of the main body portion 110a, such that the structural strength of the second reinforcement portion 110c is greater than that of the main body portion 110a. By setting the structural strength of the second reinforcement portion 110c to be greater than that of the main body portion 110a, the overall strength of the first wall 110 can be effectively improved. Furthermore, the local portion of the first wall 110 corresponding to the third portion 160 can have greater structural strength, allowing the third portion 160 to effectively cooperate with the second deformable member 18, thereby improving the reliability of overcharge protection.
根据本申请的一些实施例,请参见图10和图14,第二加强部110c包括第二凸部110c0,第二凸部110c0凸出于本体部110a沿第一壁的厚度方向z上的一个表面。According to some embodiments of the present application, referring to FIG. 10 and FIG. 14 , the second reinforcing portion 110 c includes a second protrusion 110 c 0 , which protrudes from a surface of the main body 110 a along the thickness direction z of the first wall.
在一些实施例中,第二加强部110c包括第二凸部110c0,第二凸部110c0凸部于第一壁110的表面。示例性地,第二凸部110c0凸出于第一壁110的外侧面;或者第一凸部110b0凸出于第一壁110的内侧面。In some embodiments, the second reinforcement portion 110c includes a second protrusion 110c0 protruding from the surface of the first wall 110. For example, the second protrusion 110c0 protrudes from the outer side of the first wall 110; or the first protrusion 110b0 protrudes from the inner side of the first wall 110.
在一些实施例中,第一壁110可以包括本体部110a,本体部110a上限定有第二加强区,第二凸部110c0可以设置于第二加强区,第二加强区所在的部位可以看作第二加强部110c。第三部分160可以设置于第二加强区,例如第三部分160设置于第二凸部110c0背离于本体部110a的表面,又例如第三部分160可以设置于本体部110a的背离于第二凸部110c0的部位。在一些实施例中,第二凸部110c0与本体部110a可以互为分体结构,如第二凸部110c0层叠设置于本体部110a,第二凸部110c0与本体部110a的连接关系包括但不限于粘接、焊接、铆接或者螺纹件连接等。在一些实施例中,第二凸部110c0与本体部110a可以为一体结构,其通过冲压、铸造或者其他工艺一体成型。In some embodiments, the first wall 110 may include a main body 110a, which defines a second reinforcement region. The second protrusion 110c0 may be disposed in the second reinforcement region, and the portion where the second reinforcement region is located may be considered the second reinforcement portion 110c. The third portion 160 may be disposed in the second reinforcement region. For example, the third portion 160 may be disposed on a surface of the second protrusion 110c0 facing away from the main body 110a, or in a portion of the main body 110a facing away from the second protrusion 110c0. In some embodiments, the second protrusion 110c0 and the main body 110a may be separate structures, such as being stacked on the main body 110a. The connection between the second protrusion 110c0 and the main body 110a includes, but is not limited to, bonding, welding, riveting, or screwing. In some embodiments, the second protrusion 110c0 and the main body 110a may be an integral structure, formed integrally by stamping, casting, or other processes.
上述方案中,通过设置第二凸部110c0以加强第一壁110的结构强度,能够有效地降低因电池单体10内部压力或者外部冲击作用下,导致第一壁110形变,致使第二变形件18无法有效与第三部分160接触以导通第二电极端子16和第一壁110的风险,使得电池具有较高的可靠性。In the above solution, by providing the second protrusion 110c0 to strengthen the structural strength of the first wall 110, the risk of deformation of the first wall 110 due to internal pressure of the battery cell 10 or external impact, which causes the second deformable member 18 to be unable to effectively contact the third part 160 to conduct electricity between the second electrode terminal 16 and the first wall 110, can be effectively reduced, thereby making the battery have higher reliability.
根据本申请的一些实施例,第二加强部110c还包括第二凹部110c1,沿第一壁的厚度方向z,第二凹部110c1设置于本体部110a的另一个表面,且第二凹部110c1与第二凸部110c0相对设置。According to some embodiments of the present application, the second reinforcement portion 110c further includes a second recess 110c1, which is arranged on another surface of the main body portion 110a along the thickness direction z of the first wall, and the second recess 110c1 is arranged opposite to the second protrusion 110c0.
第二凹部110c1为对应于第二凸部110c0的部位。示例性地,当第二凸部110c0位于第一壁110的外侧时,第二凹部110c1位于第一壁110的内侧;反之,第二凸部110c0位于第一壁110的内侧时,第二凹部110c1位于第一壁110的外侧。The second concave portion 110c1 corresponds to the second convex portion 110c0. For example, when the second convex portion 110c0 is located on the outside of the first wall 110, the second concave portion 110c1 is located on the inside of the first wall 110; conversely, when the second convex portion 110c0 is located on the inside of the first wall 110, the second concave portion 110c1 is located on the outside of the first wall 110.
在一些实施例中,第一壁110可以通过冲压的方式成型出第二凸部110c0和第二凹部110c1。例如,沿第一壁的厚度方向z,冲压头由第一壁110的内侧向外侧冲压第一壁110,以在第一壁110的外侧形成第二凸部110c0,在第一壁110的内侧形成第二凹部110c1。In some embodiments, the first wall 110 may be formed by stamping to form the second convex portion 110c0 and the second concave portion 110c1. For example, along the thickness direction z of the first wall, a punch presses the first wall 110 from the inside to the outside of the first wall 110 to form the second convex portion 110c0 on the outside of the first wall 110 and the second concave portion 110c1 on the inside of the first wall 110.
本申请一些实施例中,第二凹部110c1位于第一壁110的内侧,第二变形件18和第四部分161的至少部分位于第二凹部110c1中。In some embodiments of the present application, the second recess 110c1 is located on the inner side of the first wall 110 , and at least part of the second deformable member 18 and the fourth portion 161 is located in the second recess 110c1 .
上述方案中,在对应于第二凸部110c0的位置设置第二凹部110c1,一方面,能够降低第二凸部110c0的成型难度并节省材料成本,另一方面,若第二凹部110c1处于第一壁110内侧时,则可以利用第二凹部110c1的空间容纳更多的活性物质或者电解液,利于电池单体10的能量密度或充放电性能的提高,若第二凹部110c1处于第一壁110外侧时,则可以利用第二凹部110c1的空间容纳外部的结构件,利于电池体积能量密度的提高。In the above solution, the second recess 110c1 is provided at a position corresponding to the second protrusion 110c0. On the one hand, the difficulty of forming the second protrusion 110c0 can be reduced and material costs can be saved. On the other hand, if the second recess 110c1 is located on the inner side of the first wall 110, the space of the second recess 110c1 can be used to accommodate more active substances or electrolytes, which is beneficial to the improvement of the energy density or charge and discharge performance of the battery cell 10. If the second recess 110c1 is located on the outer side of the first wall 110, the space of the second recess 110c1 can be used to accommodate external structural parts, which is beneficial to the improvement of the battery volume energy density.
根据本申请的一些实施例,请参见图12和图14,第二凸部110c0位于第一壁110的外侧,第二凸部110c0形成有第二定位槽110c2,第二定位槽110c2容纳第三部分160以限制第三部分160活动。According to some embodiments of the present application, referring to FIG. 12 and FIG. 14 , the second protrusion 110c0 is located on the outside of the first wall 110 , and the second protrusion 110c0 is formed with a second positioning groove 110c2 , which accommodates the third portion 160 to limit the movement of the third portion 160 .
在一些实施例中,第二凸部110c0位于第一壁110的外侧,第三部分160可以设置于第二凸部110c0上。In some embodiments, the second protrusion 110 c 0 is located on the outer side of the first wall 110 , and the third portion 160 may be disposed on the second protrusion 110 c 0 .
第二定位槽110c2为形成于第二凸部110c0的槽结构,第三部分160位于第二定位槽110c2中。示例性地,第二凸部110c0具有背离于电极组件12的顶面,第二定位槽110c2为形成于该顶面的方形槽,呈方形状的第三部分160和第二绝缘部17的部分位于第二定位槽110c2中。第二绝缘部17被第二定位槽110c2的槽壁和第三部分160的外周面夹持。Second positioning groove 110c2 is a groove structure formed in second protrusion 110c0, and third portion 160 is located in second positioning groove 110c2. Exemplarily, second protrusion 110c0 has a top surface facing away from electrode assembly 12. Second positioning groove 110c2 is a square groove formed in this top surface. The square-shaped third portion 160 and a portion of second insulating portion 17 are located in second positioning groove 110c2. Second insulating portion 17 is sandwiched between the groove wall of second positioning groove 110c2 and the outer peripheral surface of third portion 160.
上述方案中,通过设置第二定位槽110c2,能够有效地定位第二电极端子16,限制第二电极端子16的位移,一方面降低第二电极端子16与电池单体10的内部电连接构件脱离导致电池单体10内部断路的风险,另一方面能够使得第二电极端子16有效地与第二变形件18配合,起到过充保护的作用,提高电池的可靠性。In the above scheme, by providing the second positioning groove 110c2, the second electrode terminal 16 can be effectively positioned and the displacement of the second electrode terminal 16 can be limited. On the one hand, the risk of the second electrode terminal 16 being separated from the internal electrical connection component of the battery cell 10 and causing internal short circuit of the battery cell 10 is reduced. On the other hand, the second electrode terminal 16 can be effectively matched with the second deformable member 18 to play the role of overcharge protection and improve the reliability of the battery.
根据本申请的一些实施例,第二凸部110c0位于第一壁110的外侧,沿第一壁的厚度方向z,第二凸部110c0的凸出于本体部110a的尺寸大于等于0.1mm,且小于等于5mm。According to some embodiments of the present application, the second protrusion 110c0 is located outside the first wall 110, and along the thickness direction z of the first wall, the dimension of the second protrusion 110c0 protruding from the main body 110a is greater than or equal to 0.1 mm and less than or equal to 5 mm.
在一些实施例中,参见图14,沿第一壁的厚度方向z,第二凸部110c0凸出于本体部110a的尺寸为L2,L2的取值大于等于0.1mm,且小于等于5mm。示例性地,L2的取值为0.1mm、0.2mm、0.3mm、0.4mm、0.5mm、0.6mm…2.9mm、3mm、3.1mm、3.2mm、3.3mm…4.7mm、4.8mm、4.9mm、5mm或者相邻两个数值之间的任意值。In some embodiments, referring to FIG. 14 , along the thickness direction z of the first wall, the second protrusion 110c0 protrudes from the main body 110a by a dimension L2, where L2 is greater than or equal to 0.1 mm and less than or equal to 5 mm. For example, L2 is 0.1 mm, 0.2 mm, 0.3 mm, 0.4 mm, 0.5 mm, 0.6 mm, ... 2.9 mm, 3 mm, 3.1 mm, 3.2 mm, 3.3 mm, ... 4.7 mm, 4.8 mm, 4.9 mm, 5 mm, or any value in between.
上述方案中,通过将第二凸部110c0的凸出于本体部110a的尺寸设置为大于等于0.1mm,能够有效地提高第一壁110的结构强度,使得第二变形件18在电池单体10内部压力达到第二阈值时有效地与第二电极端子16接触,起到过充保护的作用,进而提高电池的可靠性;通过将第二凸部110c0的凸出于本体部110a的尺寸设置为小于等于5mm,能够降低第二凸部110c0对空间的占用,降低对电池体积能量密度的影响。为此,通过将第二凸部110c0的凸出于本体部110a的尺寸设置为大于等于0.1mm且小于等于5mm,能够兼顾电池单体10的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the second protrusion 110c0 from the main body 110a to be greater than or equal to 0.1 mm, the structural strength of the first wall 110 can be effectively improved, allowing the second deformable member 18 to effectively contact the second electrode terminal 16 when the internal pressure of the battery cell 10 reaches the second threshold, thereby providing overcharge protection and improving the reliability of the battery. By setting the protrusion of the second protrusion 110c0 from the main body 110a to be less than or equal to 5 mm, the space occupied by the second protrusion 110c0 can be reduced, thereby reducing the impact on the battery's volumetric energy density. To this end, by setting the protrusion of the second protrusion 110c0 from the main body 110a to be greater than or equal to 0.1 mm and less than or equal to 5 mm, both the reliability of the overcharge protection of the battery cell 10 and the volumetric energy density of the battery can be achieved.
根据本申请的一些实施例,沿第一壁的厚度方向z,第二凸部110c0的凸出于本体部110a的尺寸大于等于0.5mm,且小于等于3mm。According to some embodiments of the present application, along the thickness direction z of the first wall, a dimension of the second protrusion 110c0 protruding from the main body 110a is greater than or equal to 0.5 mm and less than or equal to 3 mm.
在一些实施例中,沿第一壁的厚度方向z,第二凸部110c0凸出于本体部110a的尺寸为L2,L2的取值大于等于0.5mm,且小于等于3mm。示例性地,L2的取值为0.5mm、0.6mm、0.7mm、0.8mm、0.9mm、1mm…2.5mm、2.6mm、2.7mm、2.8mm、2.9mm、3mm或者相邻两个数值之间的任意值。In some embodiments, along the thickness direction z of the first wall, the second protrusion 110c0 protrudes from the main body 110a by a dimension L2, where L2 is greater than or equal to 0.5 mm and less than or equal to 3 mm. For example, L2 is 0.5 mm, 0.6 mm, 0.7 mm, 0.8 mm, 0.9 mm, 1 mm, 2.5 mm, 2.6 mm, 2.7 mm, 2.8 mm, 2.9 mm, 3 mm, or any value in between.
上述方案中,通过将第二凸部110c0的凸出于本体部110a的尺寸设置为大于等于0.5mm,进一步地提高第一壁110的结构强度,使得第二变形件18在电池单体10内部压力达到第二阈值时高效地与第二电极端子16接触,起到过充保护的作用,进而提高电池的可靠性;通过将第二凸部110c0的凸出于本体部110a的尺寸设置为小于等于3mm,能够有效地降低第二凸部110c0对空间的占用,降低对电池体积能量密度的影响。为此,通过将第二凸部110c0的凸出于本体部110a的尺寸设置为大于等于0.5mm且小于等于3mm,能够兼顾电池单体10的过充保护的可靠性以及电池的体积能量密度。In the above solution, by setting the protrusion of the second protrusion 110c0 from the main body 110a to be greater than or equal to 0.5mm, the structural strength of the first wall 110 is further improved, allowing the second deformable member 18 to effectively contact the second electrode terminal 16 when the internal pressure of the battery cell 10 reaches the second threshold, thereby providing overcharge protection and improving the reliability of the battery. By setting the protrusion of the second protrusion 110c0 from the main body 110a to be less than or equal to 3mm, the space occupied by the second protrusion 110c0 can be effectively reduced, thereby reducing the impact on the battery's volumetric energy density. To this end, by setting the protrusion of the second protrusion 110c0 from the main body 110a to be greater than or equal to 0.5mm and less than or equal to 3mm, the reliability of the overcharge protection of the battery cell 10 and the volumetric energy density of the battery can be balanced.
根据本申请的一些实施例,请参见图5、图7以及图11,第二绝缘部17包括第二绝缘件170,第二绝缘件170的至少部分设置于第三部分160和第一壁110之间,第二绝缘件170形成有第七通孔17001和第八通孔17002,沿第一壁的厚度方向z,第七通孔17001与第五通孔1102相对设置,第八通孔17002与第六通孔1103相对设置。According to some embodiments of the present application, referring to Figures 5, 7 and 11, the second insulating portion 17 includes a second insulating member 170, at least a portion of the second insulating member 170 is arranged between the third portion 160 and the first wall 110, and the second insulating member 170 is formed with a seventh through hole 17001 and an eighth through hole 17002. Along the thickness direction z of the first wall, the seventh through hole 17001 is arranged opposite to the fifth through hole 1102, and the eighth through hole 17002 is arranged opposite to the sixth through hole 1103.
在一些实施例中,参见图5,第二绝缘件170可以看作板状,设置于第三部分160和第一壁110之间以绝缘隔离第三部分160和第一壁110。第二绝缘件170具有沿第一壁的厚度方向z贯通的第七通孔17001和第八通孔17002,第七通孔17001对应于第五通孔1102设置以供第二电极端子16穿过,第八通孔17002对应于第六通孔1103设置以供第二变形件18在变形后穿过以与第三部分160接触。In some embodiments, referring to FIG5 , the second insulating member 170 can be considered plate-shaped and is disposed between the third portion 160 and the first wall 110 to insulate and isolate the third portion 160 from the first wall 110. The second insulating member 170 has a seventh through hole 17001 and an eighth through hole 17002 extending through the first wall along the thickness direction z. The seventh through hole 17001 is provided corresponding to the fifth through hole 1102 for allowing the second electrode terminal 16 to pass through. The eighth through hole 17002 is provided corresponding to the sixth through hole 1103 for allowing the second deformable member 18 to pass through after deformation to contact the third portion 160.
在一些实施例中,第七通孔17001可以为方形孔、圆形孔或者其他形状。第八通孔17002可以为方形孔、圆形孔或者其他形状。In some embodiments, the seventh through hole 17001 may be a square hole, a circular hole, or other shapes. The eighth through hole 17002 may be a square hole, a circular hole, or other shapes.
在一些实施例中,第七通孔17001和第五通孔1102可以为圆形孔,第七通孔17001的孔径可以小于或者等于第五通孔1102的孔径。在一些实施例中,第八通孔17002和第六通孔1103可以为圆形孔,第八通孔17002的孔径可以小于或者等于第六通孔1103的孔径。In some embodiments, the seventh through hole 17001 and the fifth through hole 1102 may be circular holes, and the diameter of the seventh through hole 17001 may be smaller than or equal to the diameter of the fifth through hole 1102. In some embodiments, the eighth through hole 17002 and the sixth through hole 1103 may be circular holes, and the diameter of the eighth through hole 17002 may be smaller than or equal to the diameter of the sixth through hole 1103.
示例性地,本申请一些实施例中,第二绝缘件170的材料可以包括绝缘PPS(聚苯硫醚)材料。在其他一些实施例中,第二绝缘件170还可以为聚丙烯、聚乙烯等其他具有绝缘特性的材料制得。示例性地,本申请一些实施例提供的电池单体10中,第二绝缘件170的电阻值可以大于或者等于200MΩ。For example, in some embodiments of the present application, the material of the second insulating member 170 may include insulating PPS (polyphenylene sulfide). In other embodiments, the second insulating member 170 may also be made of other insulating materials such as polypropylene and polyethylene. For example, in some embodiments of the present application, the resistance of the second insulating member 170 in the battery cell 10 may be greater than or equal to 200 MΩ.
上述方案中,第二绝缘件170结构简单,一方面通过第七通孔17001供第二电极端子16穿过,使得第二电极端子16与电极组件12的电连接以及实现对外充放电,通过第八通孔17002供第二变形件18变形以能够接触第三部分160,实现过充保护;另一方面,第二绝缘件170能够有效地绝缘隔离第三部分160和第一壁110,降低因第三部分160与第一壁110短接导致电池单体10内部短路的风险,使得电池的可靠性高。In the above scheme, the second insulating member 170 has a simple structure. On the one hand, the second electrode terminal 16 is allowed to pass through the seventh through hole 17001, so that the second electrode terminal 16 is electrically connected to the electrode assembly 12 and external charging and discharging is realized. The second deformable member 18 is allowed to deform through the eighth through hole 17002 so as to be able to contact the third part 160 to achieve overcharge protection; on the other hand, the second insulating member 170 can effectively insulate and isolate the third part 160 and the first wall 110, reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the third part 160 and the first wall 110, so that the reliability of the battery is high.
根据本申请的一些实施例,参见图12,第二绝缘件170包括第二本体1700和第三凸缘1701,第二本体1700位于第三部分160和第一壁110之间,第三凸缘1701设置于第二本体1700背离于第一壁110的表面,第三凸缘1701围设第三部分160的外周面的至少部分。According to some embodiments of the present application, referring to FIG. 12 , the second insulating member 170 includes a second body 1700 and a third flange 1701, the second body 1700 is located between the third portion 160 and the first wall 110, the third flange 1701 is arranged on a surface of the second body 1700 facing away from the first wall 110, and the third flange 1701 surrounds at least a portion of the outer peripheral surface of the third portion 160.
在一些实施例中,第二本体1700夹设在第三部分160和第一壁110之间,第二本体1700整体呈平板状。第三凸缘1701凸设于第额本体的表面且围设于第三部分160的外周面。In some embodiments, the second body 1700 is sandwiched between the third portion 160 and the first wall 110 , and the second body 1700 is flat. The third flange 1701 is protruded from the surface of the second body and surrounds the outer circumference of the third portion 160 .
“第三凸缘1701围设第三部分160的外周面的至少部分”可以理解为,第三凸缘1701能够将第三部分160的外周面全部包覆或者第三凸缘1701能够将第三部分160的外周面部分包覆。“The third flange 1701 surrounds at least a portion of the outer circumference of the third part 160 ” can be understood as the third flange 1701 can completely cover the outer circumference of the third part 160 or the third flange 1701 can partially cover the outer circumference of the third part 160 .
在一些实施例中,请参见图12,第二绝缘件170将第三部分160包裹并处于第二定位槽110c2中,第三凸缘1701处于第三部分160的外周面和第额定位槽的槽壁之间。In some embodiments, referring to FIG. 12 , the second insulating member 170 wraps the third portion 160 and is located in the second positioning groove 110 c 2 , and the third flange 1701 is located between the outer circumference of the third portion 160 and the wall of the first positioning groove.
上述方案中,通过设置第二本体1700和第三凸缘1701,能够有效地绝缘隔离第一壁110和第三部分160,使得第三部分160与第一壁110之间具有较远的爬电距离,使得第二绝缘件170具有较高的绝缘性能,有效降低因第一壁110和第二电极端子16之间短接导致电池单体10内部短路的风险,使得电池的可靠性高。In the above scheme, by setting the second body 1700 and the third flange 1701, the first wall 110 and the third part 160 can be effectively insulated and isolated, so that there is a longer creepage distance between the third part 160 and the first wall 110, and the second insulating member 170 has higher insulation performance, effectively reducing the risk of internal short circuit of the battery cell 10 due to short circuit between the first wall 110 and the second electrode terminal 16, so that the reliability of the battery is high.
根据本申请的一些实施例,参见图12,第二绝缘件170还包括第四凸缘1702,第四凸缘1702绕第七通孔17001设置,且位于第五通孔1102的孔壁和第二电极端子16之间。According to some embodiments of the present application, referring to FIG. 12 , the second insulating member 170 further includes a fourth flange 1702 . The fourth flange 1702 is disposed around the seventh through hole 17001 and is located between the hole wall of the fifth through hole 1102 and the second electrode terminal 16 .
第四凸缘1702为第二绝缘件170的部分结构,第四凸缘1702与第二本体1700连接且绕第七通孔17001设置,沿第一壁的厚度方向z,第四凸缘1702朝向第五通孔1102凸出以覆盖第五通孔1102的孔壁的部分,从而将第二电极端子16与第五通孔1102的孔壁绝缘隔离。在一些实施例中,第四凸缘1702还具有定位的作用,通过第四凸缘1702与第五通孔1102的相互定位,使得第二绝缘件170快速地装配于第一壁110上。The fourth flange 1702 is part of the second insulating member 170. It is connected to the second body 1700 and disposed around the seventh through-hole 17001. Along the thickness direction z of the first wall, the fourth flange 1702 protrudes toward the fifth through-hole 1102 to cover a portion of the wall of the fifth through-hole 1102, thereby insulating and isolating the second electrode terminal 16 from the wall of the fifth through-hole 1102. In some embodiments, the fourth flange 1702 also serves as a positioning mechanism. By aligning the fourth flange 1702 with the fifth through-hole 1102, the second insulating member 170 can be quickly assembled to the first wall 110.
在一些实施例中,第四凸缘1702可以将第五通孔1102的孔壁局部或者全部覆盖。In some embodiments, the fourth flange 1702 may partially or completely cover the hole wall of the fifth through hole 1102 .
上述方案中,通过设置第四凸缘1702,能够有效地绝缘隔离第五通孔1102的孔壁和第二电极端子16,降低第二电极端子16与第五通孔1102的孔壁接触导致电池单体10内部短路的风险,有效地提高电池的可靠性。In the above solution, by providing the fourth flange 1702, the hole wall of the fifth through hole 1102 and the second electrode terminal 16 can be effectively insulated and isolated, reducing the risk of the second electrode terminal 16 contacting the hole wall of the fifth through hole 1102 and causing an internal short circuit in the battery cell 10, thereby effectively improving the reliability of the battery.
在一些实施例中,请参见图5和图12,第二绝缘部17还可以包括第二密封部171,第二密封部171可以套设于第四部分161,第二密封部171的部分夹持于第五通孔1102和第四部分161之间,第二密封部171的另一部分可以夹持于第一壁110的背离于第三部分160的表面和第四部分161之间。In some embodiments, referring to Figures 5 and 12, the second insulating portion 17 may further include a second sealing portion 171, which may be sleeved on the fourth portion 161, with a portion of the second sealing portion 171 clamped between the fifth through hole 1102 and the fourth portion 161, and another portion of the second sealing portion 171 clamped between the surface of the first wall 110 facing away from the third portion 160 and the fourth portion 161.
根据本申请的一些实施例,第二绝缘部17的电阻值大于等于200兆欧。According to some embodiments of the present application, the resistance value of the second insulating portion 17 is greater than or equal to 200 megohms.
在一些实施例中,可以在第一壁110和第二电极端子16之间设置电阻值大于或等于200兆欧的第二绝缘部17。也即,在一些实施例中,第二绝缘部17的电阻值可以取值为200兆欧、210兆欧、220兆欧或者更大。In some embodiments, a second insulating portion 17 having a resistance greater than or equal to 200 megohms may be provided between the first wall 110 and the second electrode terminal 16. That is, in some embodiments, the resistance of the second insulating portion 17 may be 200 megohms, 210 megohms, 220 megohms, or greater.
在一些实施例中,可以通过万用表测试法、桥式测量法、伏安法、欧姆表法等测试方法测量第二绝缘部17的电阻值。在一些实施例中,可以通过兆欧表测量第二绝缘部17的电阻值。In some embodiments, the resistance of the second insulating portion 17 can be measured by a multimeter test method, a bridge measurement method, a volt-ampere method, an ohmmeter method, etc. In some embodiments, the resistance of the second insulating portion 17 can be measured by a megohmmeter.
上述方案中,通过将第二绝缘部17的电阻值设置为大于等于200兆欧,能够有效地提高第二电极端子16和第一壁110之间的绝缘耐高压性,能够有效适应储能装置的绝缘耐压需求,降低外部电压击穿第二绝缘部17导通第一壁110和第二电极端子16,致使电池单体10内部短路的风险,使得储能装置具有较高的可靠性。In the above scheme, by setting the resistance value of the second insulating portion 17 to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the second electrode terminal 16 and the first wall 110 can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the second insulating portion 17 and conducting the first wall 110 and the second electrode terminal 16, causing an internal short circuit in the battery cell 10, so that the energy storage device has higher reliability.
根据本申请的一些实施例,第一绝缘部14的电阻值大于等于200兆欧。According to some embodiments of the present application, the resistance of the first insulating portion 14 is greater than or equal to 200 megohms.
在一些实施例中,可以在第一壁110和第一电极端子13之间设置电阻值大于或等于200兆欧的第一绝缘部14。也即,在一些实施例中,第一绝缘部14的电阻值可以取值为200兆欧、210兆欧、220兆欧或者更大。In some embodiments, a first insulating portion 14 having a resistance greater than or equal to 200 megohms may be provided between the first wall 110 and the first electrode terminal 13. That is, in some embodiments, the resistance of the first insulating portion 14 may be 200 megohms, 210 megohms, 220 megohms, or greater.
在一些实施例中,可以通过万用表测试法、桥式测量法、伏安法、欧姆表法等测试方法测量第一绝缘部14的电阻值。在一些实施例中,可以通过兆欧表测量第二绝缘部14的电阻值。In some embodiments, the resistance of the first insulating portion 14 can be measured using a multimeter, bridge measurement, volt-ampere method, ohmmeter method, etc. In some embodiments, the resistance of the second insulating portion 14 can be measured using a megohmmeter.
上述方案中,通过将第一绝缘部14的电阻值设置为大于等于200兆欧,能够有效地提高第一电极端子13和第一壁110之间的绝缘耐高压性,能够有效适应储能装置的绝缘耐压需求,降低外部电压击穿第一绝缘部14导通第一壁110和第一电极端子13,致使电池单体10内部短路的风险,使得储能装置具有较高的可靠性。In the above solution, by setting the resistance value of the first insulating part 14 to be greater than or equal to 200 megohms, the high-voltage insulation resistance between the first electrode terminal 13 and the first wall 110 can be effectively improved, which can effectively meet the insulation voltage requirements of the energy storage device and reduce the risk of external voltage breaking through the first insulating part 14 to conduct the first wall 110 and the first electrode terminal 13, causing an internal short circuit in the battery cell 10, so that the energy storage device has higher reliability.
根据本申请的一些实施例,请参见图4和图15,图15为本申请一些实施例中壳体111和电极组件12的示意图。外壳11包括壳体111和端盖,壳体111具有开口。第一壁110为端盖,端盖与壳体111连接并封闭开口。According to some embodiments of the present application, please refer to Figures 4 and 15. Figure 15 is a schematic diagram of the housing 111 and electrode assembly 12 in some embodiments of the present application. The housing 11 includes a housing 111 and an end cap. The housing 111 has an opening. The first wall 110 is the end cap, which is connected to the housing 111 and closes the opening.
在一些实施例中,外壳11包括壳体111和端盖。壳体111的内部形成有容纳腔,容纳腔用于容纳电极组件12,壳体111具有连通容纳腔的开口,端盖盖合于壳体111的开口处并形成密封连接,以形成用于容纳电极组件12和电解质的密封空间。端盖可以通过焊接、粘接、卡接或者其他连接方式与壳体111连接。可选地,外壳11还可以包括底板,壳体111的两端分别形成有开口,其中一个开口被端盖封闭,另一个开口被底板封闭。In some embodiments, the housing 11 includes a shell 111 and an end cap. A housing cavity is formed inside the shell 111, and the housing cavity is used to accommodate the electrode assembly 12. The shell 111 has an opening connected to the housing cavity. The end cap is covered on the opening of the shell 111 and forms a sealed connection to form a sealed space for accommodating the electrode assembly 12 and the electrolyte. The end cap can be connected to the shell 111 by welding, bonding, clamping or other connection methods. Optionally, the shell 11 may further include a bottom plate, and openings are formed at both ends of the shell 111, one of the openings is closed by the end cap, and the other opening is closed by the bottom plate.
在一些实施例中,外壳11的材质可以金属或者金属与非金属的组合,例如,外壳11可以为金属制得,如铝、铜、铁、钢或铝合金等;又例如外壳11的部分可以通过金属制得,其余部分可以通过非金属制得,如外壳11的端盖可以通过金属制得,外壳11的壳体111或者其他部位可以通过非金属材料制得。In some embodiments, the material of the shell 11 can be metal or a combination of metal and non-metal. For example, the shell 11 can be made of metal, such as aluminum, copper, iron, steel or aluminum alloy; for example, part of the shell 11 can be made of metal, and the rest can be made of non-metal, such as the end cover of the shell 11 can be made of metal, and the shell 111 or other parts of the shell 11 can be made of non-metallic materials.
在本申请的一些实施例中,壳体111可以为铝壳。In some embodiments of the present application, the housing 111 may be an aluminum shell.
在一些实施例中,端盖、第一电极端子13、第二电极端子16、第一绝缘部14、第二绝缘部17等结构可以先装配为端盖组件,再将端盖组件组件装配于壳体111。In some embodiments, the end cap, the first electrode terminal 13 , the second electrode terminal 16 , the first insulating portion 14 , the second insulating portion 17 and other structures may be assembled into an end cap assembly first, and then the end cap assembly may be assembled to the housing 111 .
上述方案中,外壳11结构简单,便于电池单体10的装配,利于电池制造效率的提升。In the above solution, the housing 11 has a simple structure, which facilitates the assembly of the battery cell 10 and helps improve the battery manufacturing efficiency.
根据本申请的一些实施例,请参见图15和图16,图16为本申请一些实施例中壳体111和第一绝缘层19的示意图。According to some embodiments of the present application, please refer to Figures 15 and 16. Figure 16 is a schematic diagram of the shell 111 and the first insulating layer 19 in some embodiments of the present application.
壳体111的内壁设置有第一绝缘层19。The inner wall of the housing 111 is provided with a first insulating layer 19 .
第一绝缘层19设置在壳体111的内壁,能够对壳体111的内壁进行绝缘保护。在一些实施例中,在电池单体10的生命使用末期,由于电池单体10内部充放电循环产气,存在触发第一变形件15或第二变形件18的误触事件,若外壳11因与第一变形件15或第二变形的变形而带负电,则会导致外壳11被电化学腐蚀反应,负极的锂会嵌入至外壳11中。外壳11嵌锂后,体积膨胀,形成多孔结构,最终发生腐蚀漏液,进而引发绝缘实现,甚至导致更恶劣的问题。为此,在壳体111的内壁设置第一绝缘层19,能够切断外壳11与负极之间的离子通路,进而切断电化学腐蚀反应。The first insulating layer 19 is provided on the inner wall of the shell 111, and can insulate and protect the inner wall of the shell 111. In some embodiments, at the end of the life of the battery cell 10, due to the gas generation caused by the internal charge and discharge cycle of the battery cell 10, there is a false touch event that triggers the first deformable member 15 or the second deformable member 18. If the outer shell 11 is negatively charged due to the deformation of the first deformable member 15 or the second deformable member 18, the outer shell 11 will be electrochemically corroded, and the lithium of the negative electrode will be embedded in the outer shell 11. After the outer shell 11 is embedded with lithium, its volume expands to form a porous structure, which eventually causes corrosion and leakage, thereby causing insulation failure and even worse problems. To this end, a first insulating layer 19 is provided on the inner wall of the shell 111, which can cut off the ion path between the outer shell 11 and the negative electrode, thereby cutting off the electrochemical corrosion reaction.
在一些实施例中,在电极组件12装配于壳体111的过程中,存在因制造工艺导致金属颗粒刺穿电极组件12的隔膜,使得金属颗粒导通壳体111和负极的情况,为此,在壳体111的内壁设置第一绝缘层19,第一绝缘层19起防护作用,能够改善金属颗粒导通壳体111和负极的问题。In some embodiments, during the process of assembling the electrode assembly 12 in the shell 111, there is a situation where metal particles pierce the diaphragm of the electrode assembly 12 due to the manufacturing process, causing the metal particles to conduct electricity between the shell 111 and the negative electrode. For this reason, a first insulating layer 19 is provided on the inner wall of the shell 111. The first insulating layer 19 plays a protective role and can improve the problem of metal particles conducting electricity between the shell 111 and the negative electrode.
在一些实施例中,壳体111的内壁包括壳体111侧壁的内表面,也包括壳体111的底壁的内表面。In some embodiments, the inner wall of the housing 111 includes the inner surface of the side wall of the housing 111 and also includes the inner surface of the bottom wall of the housing 111 .
在一些实施例中,第一绝缘层19为设置于壳体111的内壁的层状结构,其具有绝缘性能。示例性地,第一绝缘层19可以为涂层也可以设置于壳体111内壁的板状、层状等厚度较薄的结构。In some embodiments, the first insulating layer 19 is a layered structure provided on the inner wall of the housing 111 and has insulating properties. For example, the first insulating layer 19 can be a coating or a thin plate-like, layered structure provided on the inner wall of the housing 111.
上述方案中,通过在壳体111的内部设置第一绝缘层19,能够有效地绝缘隔离壳体111内部的电解液与壳体111的内壁,从而降低壳体111被电解液腐蚀的风险,降低电解线泄漏的风险,使得电池具有较高的可靠性。In the above solution, by providing a first insulating layer 19 inside the shell 111, the electrolyte inside the shell 111 can be effectively insulated and isolated from the inner wall of the shell 111, thereby reducing the risk of the shell 111 being corroded by the electrolyte and the risk of electrolytic wire leakage, so that the battery has higher reliability.
根据本申请的一些实施例,第一绝缘层19为设置于壳体111内壁的绝缘涂层。According to some embodiments of the present application, the first insulating layer 19 is an insulating coating provided on the inner wall of the housing 111 .
在一些实施例中,绝缘涂层的材料可以包括环氧树脂、聚氨酯、丙烯酸树脂、聚酰亚胺、酚醛树脂等。第一绝缘层19可以采用浸涂、喷涂、电镀、阳极氧化等工艺涂覆在壳体111的内壁上。In some embodiments, the insulating coating material may include epoxy resin, polyurethane, acrylic resin, polyimide, phenolic resin, etc. The first insulating layer 19 may be coated on the inner wall of the housing 111 by dipping, spraying, electroplating, anodizing, etc.
上述方案中,通过在壳体111的内壁设置绝缘涂层,一方面能够有效地分隔电解液和壳体111,切断电机组件与壳体111之间的电解液离子通路,降低壳体111被腐蚀的风险;另一方面采用喷涂等方式能够高效地在壳体111内壁形成第一绝缘层19,使得电池的制造效率高;再一方面,绝缘涂层具有较高的机械强度,能够有效地降低有制造工艺引入的金属颗粒刺穿,导致电极组件12和外壳11相互电连接,致使电池单体10内部短路的风险或者致使外壳11被腐蚀的风险,使得电池的可靠性高。In the above scheme, by providing an insulating coating on the inner wall of the shell 111, on the one hand, the electrolyte and the shell 111 can be effectively separated, the electrolyte ion path between the motor assembly and the shell 111 can be cut off, and the risk of corrosion of the shell 111 can be reduced; on the other hand, the first insulating layer 19 can be efficiently formed on the inner wall of the shell 111 by spraying or the like, so that the manufacturing efficiency of the battery is high; on the other hand, the insulating coating has high mechanical strength, which can effectively reduce the puncture of metal particles introduced by the manufacturing process, resulting in the electrode assembly 12 and the shell 11 being electrically connected to each other, causing the risk of internal short circuit of the battery cell 10 or the risk of corrosion of the shell 11, so that the reliability of the battery is high.
根据本申请的一些实施例,请参见图16,沿第一方向y,壳体111的内壁包括依次连接的留白区19b和绝缘区,绝缘区设置有第一绝缘层19,留白区19b与第一壁110连接,第一方向y平行于第一壁110指向电极组件12的方向。According to some embodiments of the present application, please refer to Figure 16. Along the first direction y, the inner wall of the shell 111 includes a blank area 19b and an insulating area connected in sequence, the insulating area is provided with a first insulating layer 19, the blank area 19b is connected to the first wall 110, and the first direction y is parallel to the first wall 110 and points to the direction of the electrode assembly 12.
在一些实施例中,第一方向y可以平行于第一壁110指向电极组件12的方向,第一方向y可以为第一壁的厚度方向z。In some embodiments, the first direction y may be parallel to the direction of the first wall 110 pointing toward the electrode assembly 12 , and the first direction y may be the thickness direction z of the first wall.
在一些实施例中,沿第一方向y,壳体111的内壁包括依次连接的留白区19b和绝缘区,留白区19b可不设置第一绝缘层19,留白区19b可以与第一壁110连接,例如留白区19b与第一壁110的外周面焊接。沿第一方向y,绝缘区位于第一壁110之下,绝缘区设置有第一绝缘层19。示例性地,壳体111包括侧壁和底壁,第一壁110为端盖,留白区19b形成于侧壁内表面的顶部,绝缘区形成于侧壁内表面的剩余位置以及底壁的内表面。In some embodiments, along the first direction y, the inner wall of the housing 111 includes a blank area 19b and an insulating area, which are connected in sequence. The blank area 19b may not be provided with the first insulating layer 19, and the blank area 19b may be connected to the first wall 110, for example, by welding the blank area 19b to the outer peripheral surface of the first wall 110. Along the first direction y, the insulating area is located below the first wall 110 and is provided with the first insulating layer 19. Exemplarily, the housing 111 includes side walls and a bottom wall, the first wall 110 being an end cap, the blank area 19b being formed at the top of the inner surface of the side wall, and the insulating area being formed at the remaining position of the inner surface of the side wall and the inner surface of the bottom wall.
在一些实施例中,留白区19b在第一方向y上的尺寸可以大于或等于5mm,也即可以理解为,留白区19b能够为端盖在第一方向y提供尺寸大于或者等于5mm的区域以便于壳体111和端盖相互焊接。In some embodiments, the size of the blank area 19b in the first direction y can be greater than or equal to 5 mm, that is, it can be understood that the blank area 19b can provide the end cover with an area greater than or equal to 5 mm in the first direction y to facilitate welding of the shell 111 and the end cover.
在一些实施例中,留白区19b的成型方式可以包括,在制备绝缘涂层前提前贴胶设置非涂层区域,或者通过激光清洗工艺,后期清洗出该留白区19b。In some embodiments, the blank area 19b may be formed by applying glue to set a non-coating area before preparing the insulating coating, or by cleaning the blank area 19b later through a laser cleaning process.
上述方案中,通过设置留白区19b,能够降低第一绝缘层19对壳体111和第一壁110相互连接部位的影响。示例性地,第一壁110与壳体111相互焊接,通过设置留白区19b,能够使得第一壁110和壳体111之间具有良好的焊接质量,进而使得电池的质量高。In the above solution, by providing the blank area 19b, the effect of the first insulating layer 19 on the connection between the housing 111 and the first wall 110 can be reduced. For example, the first wall 110 and the housing 111 are welded to each other, and by providing the blank area 19b, good welding quality can be achieved between the first wall 110 and the housing 111, thereby improving the quality of the battery.
根据本申请的一些实施例,沿第二方向x,电极组件12落在壳体111的内壁的投影与留白区19b不重合,第二方向x与第一方向y垂直。According to some embodiments of the present application, along the second direction x, the projection of the electrode assembly 12 on the inner wall of the shell 111 does not overlap with the blank area 19 b , and the second direction x is perpendicular to the first direction y.
第二方向x与第一方向y相互垂直。在一些实施例中,将第一方向y看作高度方向,第二方向x可以为水平方向。“沿第二方向x,电极组件12落在壳体111的内壁的投影与留白区19b不重合”可以理解为,留白区19b处于电极组件12的靠近端盖的一侧。The second direction x is perpendicular to the first direction y. In some embodiments, the first direction y is considered to be the height direction, and the second direction x can be the horizontal direction. "Along the second direction x, the projection of the electrode assembly 12 on the inner wall of the housing 111 does not overlap with the blank area 19b" can be understood to mean that the blank area 19b is located on the side of the electrode assembly 12 closest to the end cap.
上述方案中,通过将电极组件12与留白区19b错位设置,能够降低电极组件12与留白区19b搭接导致电池单体10内部短路或者外壳11因带负电而被电解液腐蚀的风险,能够有效地提高电池单体10的可靠性,进而提高电池的可靠性。In the above scheme, by staggering the electrode assembly 12 and the blank area 19b, the risk of the electrode assembly 12 and the blank area 19b overlapping and causing internal short circuit in the battery cell 10 or the risk of the outer shell 11 being corroded by the electrolyte due to negative charge can be reduced, which can effectively improve the reliability of the battery cell 10 and thus improve the reliability of the battery.
根据本申请的一些实施例,第一绝缘层19的厚度大于等于60μm,且小于等于200μm。According to some embodiments of the present application, the thickness of the first insulating layer 19 is greater than or equal to 60 μm and less than or equal to 200 μm.
请参见图16,第一绝缘层19的厚度为M,M的取值可以大于等于60μm,且小于等于200μm。示例性地,M的取值可以为60μm、70μm、80μm、90μm、100μm…180μm、190μm、200μm或者相邻两个数值之间的任意值。16 , the thickness of the first insulating layer 19 is M, and the value of M can be greater than or equal to 60 μm and less than or equal to 200 μm. For example, the value of M can be 60 μm, 70 μm, 80 μm, 90 μm, 100 μm, ..., 180 μm, 190 μm, 200 μm, or any value between two adjacent values.
上述方案中,通过将第一绝缘层19的厚度设置为大于或等于60μm,能够使得第一绝缘层19具有较高的机械强度和绝缘性能,有效地隔离壳体111和电解液,降低壳体111因带负电而被电解液腐蚀的风险,使得电池具有较高的可靠性;通过将第一绝缘层19的厚度设置为小于等于200μm,能够有效地降低第一绝缘层19对电池单体10内部空间的占用,使得电池单体10具有较高的体积能量密度,使得电池具有较高的体积能量密度。为此,通过将第一绝缘层19的厚度设置为大于或等于60μm,且小于等于200μm,能够兼顾电池的可靠性和体积能量密度。In the above solution, by setting the thickness of the first insulating layer 19 to be greater than or equal to 60μm, the first insulating layer 19 can have high mechanical strength and insulation properties, effectively isolating the housing 111 from the electrolyte, reducing the risk of the housing 111 being corroded by the electrolyte due to negative charge, and thus making the battery more reliable. By setting the thickness of the first insulating layer 19 to be less than or equal to 200μm, the first insulating layer 19 can effectively reduce the internal space occupied by the battery cell 10, making the battery cell 10 have a higher volumetric energy density, and thus making the battery have a higher volumetric energy density. To this end, by setting the thickness of the first insulating layer 19 to be greater than or equal to 60μm and less than or equal to 200μm, both battery reliability and volumetric energy density can be taken into account.
根据本申请的一些实施例,第一绝缘层19的厚度大于等于80μm,且小于等于130μm。According to some embodiments of the present application, the thickness of the first insulating layer 19 is greater than or equal to 80 μm and less than or equal to 130 μm.
第一绝缘层19的厚度为M,M的取值可以大于等于80μm,且小于等于130μm。示例性地,M的取值可以为80μm、90μm、100μm、110μm、120μm、130μm或者相邻两个数值之间的任意值。The thickness of the first insulating layer 19 is M, which may be greater than or equal to 80 μm and less than or equal to 130 μm. For example, M may be 80 μm, 90 μm, 100 μm, 110 μm, 120 μm, 130 μm, or any value between two adjacent values.
上述方案中,通过将第一绝缘层19的厚度设置为大于或等于80μm,能够进一步地使得第一绝缘层19具有较高的机械强度和绝缘性能,有效地隔离壳体111和电解液,降低壳体111因带负电而被电解液腐蚀的风险,使得电池具有较高的可靠性;通过将第一绝缘层19的厚度设置为小于等于130μm,能够进一步地降低第一绝缘层19对电池单体10内部空间的占用,使得电池单体10具有较高的体积能量密度,使得电池具有较高的体积能量密度。为此,通过将第一绝缘层19的厚度设置为大于或等于80μm,且小于等于130μm,能够有效地兼顾电池的可靠性和体积能量密度。In the above solution, by setting the thickness of the first insulating layer 19 to be greater than or equal to 80 μm, the first insulating layer 19 can further have higher mechanical strength and insulation performance, effectively isolating the housing 111 from the electrolyte, reducing the risk of the housing 111 being corroded by the electrolyte due to negative charge, and thus making the battery more reliable. By setting the thickness of the first insulating layer 19 to be less than or equal to 130 μm, the first insulating layer 19 can further reduce the space occupied by the first insulating layer 19 in the internal space of the battery cell 10, so that the battery cell 10 has a higher volumetric energy density, and the battery has a higher volumetric energy density. To this end, by setting the thickness of the first insulating layer 19 to be greater than or equal to 80 μm and less than or equal to 130 μm, it is possible to effectively balance the reliability and volumetric energy density of the battery.
根据本申请的另一些实施例,请参见图17,图17为本申请另一些实施例中壳体111和第一绝缘层19的示意图。壳体111的外表面设置有第二绝缘层19a。According to other embodiments of the present application, please refer to Figure 17, which is a schematic diagram of the housing 111 and the first insulating layer 19 in other embodiments of the present application. The outer surface of the housing 111 is provided with a second insulating layer 19a.
在一些实施例中,壳体111的外表面为壳体111的与外界接触的表面,例如壳体111的外表面包括壳体111的侧壁的外表面和壳体111的底壁的外表面。In some embodiments, the outer surface of the shell 111 is the surface of the shell 111 that contacts the outside world. For example, the outer surface of the shell 111 includes the outer surface of the side wall of the shell 111 and the outer surface of the bottom wall of the shell 111 .
在一些实施例中,第二绝缘层19a为设置于壳体111的外表面的层状结构,其具有绝缘性能。示例性地,第二绝缘层19a可以为涂层也可以设置于壳体111外表面的板状、层状等厚度较薄的结构。In some embodiments, the second insulating layer 19a is a layered structure provided on the outer surface of the housing 111 and has insulating properties. For example, the second insulating layer 19a can be a coating or a thin plate-like, layered structure provided on the outer surface of the housing 111.
示例性地,第二绝缘层19a可以为绝缘涂层,绝缘涂层的材料可以包括环氧树脂、聚氨酯、丙烯酸树脂、聚酰亚胺、酚醛树脂等。第二绝缘层19a可以采用浸涂、喷涂、电镀、阳极氧化等工艺涂覆在壳体111的外表面上。For example, the second insulating layer 19a may be an insulating coating, and the insulating coating may be made of epoxy resin, polyurethane, acrylic resin, polyimide, phenolic resin, etc. The second insulating layer 19a may be coated on the outer surface of the housing 111 by dipping, spraying, electroplating, anodizing, or other processes.
上述方案中,通过在壳体111的外表面设置第二绝缘层19a,能够有效地对壳体111起到绝缘保护的效果,降低因壳体111带负电导致被电解液腐蚀的风险,使得电池具有较高的可靠性。In the above solution, by providing a second insulating layer 19a on the outer surface of the shell 111, the shell 111 can be effectively insulated and protected, reducing the risk of corrosion by the electrolyte due to negative charge of the shell 111, so that the battery has higher reliability.
根据本申请的一些实施例,还提供一种电池,电池具有上文描述的电池单体10。请参见图3,电池100包括电池单体10和箱体20,电池单体10容纳于箱体20内。其中,箱体20用于为电池单体10提供容纳空间,箱体20可以采用多种结构。According to some embodiments of the present application, a battery is further provided, comprising the battery cell 10 described above. Referring to FIG3 , the battery 100 includes the battery cell 10 and a housing 20 , wherein the battery cell 10 is housed within the housing 20 . The housing 20 is used to accommodate the battery cell 10 and can have various structures.
在电池100中,电池单体10可以是一个也可以是多个,且各电池单体10可以通过连接件(如螺栓)固定于箱体20,或者各电池单体10可以通过粘接的方式固定于箱体20。In the battery 100 , there may be one or more battery cells 10 , and each battery cell 10 may be fixed to the case 20 via a connector (such as a bolt), or each battery cell 10 may be fixed to the case 20 by bonding.
根据本申请的一些实施例,还提供一种储能装置,储能装置包括上文描述的电池单体10。According to some embodiments of the present application, an energy storage device is further provided, and the energy storage device includes the battery cell 10 described above.
在一些实施例中,电池单体10先构成电池,一个或多个电池再应用于储能装置。请参见图2,储能装置2000可以包括柜体2001以及多个电池100。多个电池100可以设置于柜体2001内。多个电池100之间可以相互串联、并联或者混联。In some embodiments, battery cells 10 are first formed into a battery, and one or more of these cells are then used in an energy storage device. Referring to Figure 2 , energy storage device 2000 may include a cabinet 2001 and multiple batteries 100. Multiple batteries 100 may be housed within cabinet 2001. Multiple batteries 100 may be connected in series, parallel, or in a hybrid configuration.
根据本申请的一些实施例,还提供一种用电装置,用电装置包括上文描述的电池单体10。在一些实施例中,电池单体10先构成电池100,一个或多个电池100再应用于用电装置中。According to some embodiments of the present application, an electric device is further provided, comprising the above-described battery cell 10. In some embodiments, the battery cell 10 first forms a battery 100, and one or more batteries 100 are then used in the electric device.
在一些实施例中,参见图1,用电装置为车辆1000。车辆1000的内部可以设置控制器200、马达300和电池100,控制器200用来控制电池100为马达300供电。In some embodiments, referring to FIG1 , the electrical device is a vehicle 1000 . A controller 200 , a motor 300 , and a battery 100 may be provided inside the vehicle 1000 . The controller 200 is used to control the battery 100 to supply power to the motor 300 .
根据本申请的一些实施例,提供一种电池单体10,请参见图4-图17。According to some embodiments of the present application, a battery cell 10 is provided, see Figures 4 to 17 .
电池单体10包括外壳11、电极组件12、第一电极端子13、第一绝缘部14、第一变形件15、第二电极端子16、第二绝缘部17以及第二变形件18。The battery cell 10 includes a housing 11 , an electrode assembly 12 , a first electrode terminal 13 , a first insulating portion 14 , a first deformable member 15 , a second electrode terminal 16 , a second insulating portion 17 , and a second deformable member 18 .
外壳11包括壳体111和端盖。壳体111的内部形成有容纳腔,容纳腔用于容纳电极组件12,壳体111具有连通容纳腔的开口,端盖封闭壳体111的开口,使得电极组件12处于封闭的空间中。The housing 11 includes a shell 111 and an end cap. The shell 111 has an interior formed with a receiving cavity for receiving the electrode assembly 12. The shell 111 has an opening communicating with the receiving cavity. The end cap closes the opening of the shell 111, so that the electrode assembly 12 is in a closed space.
端盖包括本体部110a、第一加强部110b和第二加强部110c。第一加强部110b包括位于本体部110a外侧的第一凸部110b0和位于本体部110a内侧的第一凹部110b1,第一凸部110b0和第一凹部110b1在端盖的厚度方向上相对设置。第二加强部110c包括位于本体部110a外侧的第二凸部110c0和位于本体部110a内侧的第二凹部110c1。第一凸部110b0形成有第一定位槽110b2,第二凸部110c0形成有第二定位槽110c2。第一定位槽110b2形成有第一通孔1100和第二通孔1101,第二定位槽110c2形成有第五通孔1102和第六通孔1103。The end cap includes a main body 110a, a first reinforcement portion 110b, and a second reinforcement portion 110c. The first reinforcement portion 110b includes a first protrusion 110b0 located outside the main body 110a and a first recess 110b1 located inside the main body 110a. The first protrusion 110b0 and the first recess 110b1 are arranged opposite each other in the thickness direction of the end cap. The second reinforcement portion 110c includes a second protrusion 110c0 located outside the main body 110a and a second recess 110c1 located inside the main body 110a. The first protrusion 110b0 is formed with a first positioning groove 110b2, and the second protrusion 110c0 is formed with a second positioning groove 110c2. The first positioning groove 110b2 is formed with a first through hole 1100 and a second through hole 1101, while the second positioning groove 110c2 is formed with a fifth through hole 1102 and a sixth through hole 1103.
在一些实施例中,第一凸部110b0的凸出高度可以为大于等于0.5mm,且小于等于3mm。在一些实施例中,第二凸部110c0的凸出高度可以为大于等于0.5mm,且小于等于3mm。In some embodiments, the protrusion height of the first protrusion 110b0 may be greater than or equal to 0.5 mm and less than or equal to 3 mm. In some embodiments, the protrusion height of the second protrusion 110c0 may be greater than or equal to 0.5 mm and less than or equal to 3 mm.
第一电极端子13安装于第一通孔1100,沿端盖的厚度方向,第一电极端子13包括位于端盖的外侧的第一部分130以及至少部分位于端盖的内侧的第二部分131,第一部分130用于与外部构件电连接,第二部分131通过第一转接件123与电极组件12的第一极耳120电连接。第一绝缘部14包括第一绝缘件140,在一些实施例中,第一绝缘件140的电阻值至少为200兆欧或者更大。第一绝缘件140包括第一本体1400、第一凸缘1401和第二凸缘1402。第一本体1400位于第一部分130和端盖之间,第一本体1400形成有第三通孔14001和第四通孔14002,第三通孔14001与第一通孔1100对应,供第一电极端子13穿过,第四通孔14002对应于第二通孔1101设置。第一凸缘1401设置于第一本体1400背离于端盖的表面,第一凸缘1401围设第一部分130的外周面的部分。第二凸缘1402绕第三通孔14001设置,且位于第一通孔1100的孔壁和第一电极端子13之间。The first electrode terminal 13 is mounted in the first through-hole 1100. Along the thickness of the end cap, the first electrode terminal 13 includes a first portion 130 located on the outside of the end cap and a second portion 131 located at least partially on the inside of the end cap. The first portion 130 is used for electrical connection to external components, while the second portion 131 is electrically connected to the first tab 120 of the electrode assembly 12 via the first adapter 123. The first insulating portion 14 includes a first insulating member 140. In some embodiments, the resistance of the first insulating member 140 is at least 200 megohms or greater. The first insulating member 140 includes a first body 1400, a first flange 1401, and a second flange 1402. The first body 1400 is located between the first portion 130 and the end cap. The first body 1400 is formed with a third through-hole 14001 and a fourth through-hole 14002. The third through-hole 14001 corresponds to the first through-hole 1100 and is provided for the first electrode terminal 13 to pass through. The fourth through-hole 14002 corresponds to the second through-hole 1101. The first flange 1401 is disposed on the surface of the first body 1400 away from the end cap and surrounds the outer circumference of the first portion 130. The second flange 1402 is disposed around the third through hole 14001 and is located between the hole wall of the first through hole 1100 and the first electrode terminal 13.
第一变形件15焊接于端盖的内侧且封闭第二通孔1101,第一变形件15可以为翻转片。第一变形件15被配置可以变形以部分穿过第二通孔1101与第一部分130接触。例如,第一变形件15被配置为在电池单体10内部压力达到第一阈值时变形以部分穿过第二通孔1101与第一部分130接触。The first deformable member 15 is welded to the inner side of the end cap and seals the second through-hole 1101. The first deformable member 15 may be a flip tab. The first deformable member 15 is configured to deform to partially pass through the second through-hole 1101 and contact the first portion 130. For example, the first deformable member 15 is configured to deform to partially pass through the second through-hole 1101 and contact the first portion 130 when the internal pressure of the battery cell 10 reaches a first threshold.
第二电极端子16安装于第五通孔1102,沿端盖的厚度方向,第二电极端子16包括位于端盖的外侧的第三部分160以及至少部分位于端盖的内侧的第四部分161,第四部分161通过第二转接件124与电极组件12的第二极耳121连接。第二绝缘部17包括第二绝缘件170,在一些实施例中,第二绝缘件170的电阻值至少为200兆欧或者更大。第二绝缘件170包括第二本体1700、第三凸缘1701和第四凸缘1702。第二本体1700位于第三部分160和端盖之间,第二本体1700形成有第七通孔17001和第八通孔17002,第七通孔17001与第五通孔1102对应,供第二电极端子16穿过,第八通孔17002对应于第六通孔1103设置。第三凸缘1701设置于第二本体1700背离于端盖的表面,第三凸缘1701围设第三部分160的外周面的部分。第四凸缘1702绕第七通孔17001设置,且位于第五通孔1102的孔壁和第二电极端子16之间。The second electrode terminal 16 is mounted in the fifth through-hole 1102. Along the thickness of the end cap, the second electrode terminal 16 includes a third portion 160 located on the outside of the end cap and a fourth portion 161 located at least partially on the inside of the end cap. The fourth portion 161 is connected to the second tab 121 of the electrode assembly 12 via the second adapter 124. The second insulating portion 17 includes a second insulating member 170. In some embodiments, the resistance of the second insulating member 170 is at least 200 megohms or greater. The second insulating member 170 includes a second body 1700, a third flange 1701, and a fourth flange 1702. The second body 1700 is located between the third portion 160 and the end cap. The second body 1700 is formed with a seventh through-hole 17001 and an eighth through-hole 17002. The seventh through-hole 17001 corresponds to the fifth through-hole 1102 and is provided for the second electrode terminal 16 to pass through. The eighth through-hole 17002 corresponds to the sixth through-hole 1103. The third flange 1701 is disposed on the surface of the second body 1700 away from the end cap and surrounds the outer circumference of the third portion 160. The fourth flange 1702 is disposed around the seventh through hole 17001 and is located between the hole wall of the fifth through hole 1102 and the second electrode terminal 16.
第二变形件18焊接于端盖的内侧且封闭第六通孔1103,第二变形件18可以为翻转片。第二变形件18被配置为在电池单体10内部压力达到第一程度,例如第二阈值时变形以部分穿过第六通孔1103与第三部分160接触。The second deformable member 18 is welded to the inner side of the end cap and closes the sixth through hole 1103. The second deformable member 18 can be a flip tab. The second deformable member 18 is configured to deform when the internal pressure of the battery cell 10 reaches a first level, such as a second threshold, so as to partially pass through the sixth through hole 1103 and contact the third portion 160.
在一些实施例中,当第二电极端子16为负极电极端子时,第二阈值可以大于第一阈值。In some embodiments, when the second electrode terminal 16 is a negative electrode terminal, the second threshold value may be greater than the first threshold value.
在一些实施例中,电池单体10因过充等情况处于滥用工况时,电池单体10内部压力增长,在电池单体10内部压力达到一定程度,例如第一阈值时,第一变形件15变形,将第一电极端子13和外壳11短接,在电池单体10内部压力达到第二阈值时,第二变形件18变形,将第二电极端子16与外壳11短接,从而使得电池单体10内部正负极短接以内部短路,瞬时产生的大电流可以将电池单体10内部的电连接构件熔断,切断电池单体10的充放电回路,从而起到过充保护的作用。熔断的电连接构件可以包括第一转接件123和/或第二转接件124。示例性地,第一转接件123具有第一熔断部,第一熔断部的过流面积可以小于第一转接件123的其余部分的过流面积,以在较大电流经过时,能使得第一熔断部熔断,从而断开第一极耳120和第一电极端子13的电流路径。示例性地,第二转接件124具有第二熔断部,第二熔断部的过流面积可以小于第二转接件124的其余部分的过流面积,以在较大电流经过时,能使得第二熔断部熔断,从而断开第二极耳121和第二电极端子16的电流路径。In some embodiments, when a battery cell 10 is subjected to abuse due to overcharging or other conditions, the internal pressure of the battery cell 10 increases. When the internal pressure of the battery cell 10 reaches a certain level, such as a first threshold, the first deformable member 15 deforms, short-circuiting the first electrode terminal 13 and the outer casing 11. When the internal pressure of the battery cell 10 reaches a second threshold, the second deformable member 18 deforms, short-circuiting the second electrode terminal 16 and the outer casing 11, thereby short-circuiting the positive and negative electrodes within the battery cell 10 and creating an internal short circuit. The resulting high current can melt the electrical connections within the battery cell 10, severing the charge and discharge circuit of the battery cell 10, thereby providing overcharge protection. The fused electrical connections can include the first adapter 123 and/or the second adapter 124. For example, the first adapter 123 has a first fuse portion, the flow area of which can be smaller than the flow area of the remaining portions of the first adapter 123. This allows the first fuse portion to melt when a large current flows, thereby severing the current path between the first tab 120 and the first electrode terminal 13. Exemplarily, the second adapter 124 has a second fuse portion, and the flow area of the second fuse portion can be smaller than the flow area of the rest of the second adapter 124, so that when a larger current passes through, the second fuse portion can be melted, thereby disconnecting the current path between the second electrode tab 121 and the second electrode terminal 16.
上述方案中,通过设置第一绝缘部14和第二绝缘部17,能够有效地绝缘隔离端盖和第一电极端子13,以及绝缘隔离端盖和第二电极端子16,降低因端盖和电极端子之间短接导致电池单体10内部短路的风险,使得电池的可靠性高。特别是在工作电压较高的储能装置中,通过设置第一绝缘部14和第二绝缘部17,能够有效地降低因电池中的其余电池单体10失控而外壳11带高压电,导致高压电导通端盖和电极端子使得电池单体10内部短路,致使储能装置热失控的风险。In the above solution, the provision of the first insulating portion 14 and the second insulating portion 17 effectively insulates and isolates the end cap from the first electrode terminal 13, as well as the second electrode terminal 16. This reduces the risk of internal short circuits in the battery cell 10 due to short circuits between the end cap and the electrode terminal, thereby enhancing battery reliability. In particular, in energy storage devices with higher operating voltages, the provision of the first insulating portion 14 and the second insulating portion 17 effectively reduces the risk of thermal runaway of the energy storage device due to the runaway of the remaining battery cells 10 in the battery, which could cause the outer casing 11 to be charged with high voltage, leading to high voltage conduction between the end cap and the electrode terminal, and thus causing internal short circuits in the battery cell 10.
在一些实施例中,壳体111的内壁设置有第一绝缘层19,第一绝缘层19可以为绝缘涂层。绝缘涂层的材料可以包括环氧树脂、聚氨酯、丙烯酸树脂、聚酰亚胺、酚醛树脂等。第一绝缘层19可以采用浸涂、喷涂、电镀、阳极氧化等工艺涂覆在壳体111的内壁上。In some embodiments, the inner wall of the housing 111 is provided with a first insulating layer 19, which may be an insulating coating. The insulating coating may be made of epoxy resin, polyurethane, acrylic resin, polyimide, phenolic resin, etc. The first insulating layer 19 may be applied to the inner wall of the housing 111 by a process such as dipping, spraying, electroplating, or anodizing.
在一些实施例中,第一绝缘层19的绝缘阻抗可以满足1000V,5s,>1GΩ。在一些实施例中,第一绝缘层19为绝缘涂层,该绝缘涂层可以满足以下条件:60℃耐电解液无溶胀。In some embodiments, the insulation resistance of the first insulating layer 19 can meet 1000V, 5s, >1GΩ. In some embodiments, the first insulating layer 19 is an insulating coating, which can meet the following conditions: electrolyte resistance at 60°C without swelling.
在一些实施例中,为使得端盖与壳体111之间具有较高的焊接质量,壳体111的内部可以设置于留白区19b,留白区19b未设置第一绝缘层19,留白区19b与端盖相互焊接。In some embodiments, to ensure higher welding quality between the end cap and the shell 111, the interior of the shell 111 can be set in a blank area 19b, where the first insulating layer 19 is not set, and the blank area 19b and the end cap are welded to each other.
上述方案中,通过在壳体111的内壁设置绝缘涂层,一方面能够有效地分隔电解液和壳体111,切断电机组件与壳体111之间的电解液离子通路,降低壳体111被腐蚀的风险;另一方面采用喷涂等方式能够高效地在壳体111内壁形成第一绝缘层19,使得电池的制造效率高;再一方面,绝缘涂层具有较高的机械强度,能够有效地降低有制造工艺引入的金属颗粒刺穿,导致电极组件12和外壳11相互电连接,致使电池单体10内部短路的风险或者致使外壳11被腐蚀的风险,使得电池的可靠性高。In the above scheme, by providing an insulating coating on the inner wall of the shell 111, on the one hand, the electrolyte and the shell 111 can be effectively separated, the electrolyte ion path between the motor assembly and the shell 111 can be cut off, and the risk of corrosion of the shell 111 can be reduced; on the other hand, the first insulating layer 19 can be efficiently formed on the inner wall of the shell 111 by spraying or the like, so that the manufacturing efficiency of the battery is high; on the other hand, the insulating coating has high mechanical strength, which can effectively reduce the puncture of metal particles introduced by the manufacturing process, resulting in the electrode assembly 12 and the shell 11 being electrically connected to each other, causing the risk of internal short circuit of the battery cell 10 or the risk of corrosion of the shell 11, so that the reliability of the battery is high.
以上所述仅为本申请的优选实施例而已,并不用于限制本申请,对于本领域的技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本申请的保护范围之内。The above description is merely a preferred embodiment of the present application and is not intended to limit the present application. Various modifications and variations are possible for those skilled in the art. Any modifications, equivalent substitutions, or improvements made within the spirit and principles of the present application shall be included within the scope of protection of the present application.
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| CN207038570U (en) * | 2017-08-02 | 2018-02-23 | 宁德时代新能源科技股份有限公司 | Secondary battery top cover assembly and secondary battery |
| CN207381439U (en) * | 2017-10-20 | 2018-05-18 | 宁德时代新能源科技股份有限公司 | Secondary battery top cover assembly and secondary battery |
| WO2018090180A1 (en) * | 2016-11-15 | 2018-05-24 | 宁德时代新能源科技股份有限公司 | Secondary battery |
| CN108428820A (en) * | 2017-02-14 | 2018-08-21 | 宁德时代新能源科技股份有限公司 | Power battery top cover structure and power battery |
| CN109285974A (en) * | 2017-07-20 | 2019-01-29 | 宁德时代新能源科技股份有限公司 | Secondary cell top cap subassembly and secondary cell |
| WO2024016158A1 (en) * | 2022-07-19 | 2024-01-25 | 宁德时代新能源科技股份有限公司 | Battery cell end cover assembly, battery cell, battery, and electric device |
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| WO2018090180A1 (en) * | 2016-11-15 | 2018-05-24 | 宁德时代新能源科技股份有限公司 | Secondary battery |
| CN108428820A (en) * | 2017-02-14 | 2018-08-21 | 宁德时代新能源科技股份有限公司 | Power battery top cover structure and power battery |
| CN109285974A (en) * | 2017-07-20 | 2019-01-29 | 宁德时代新能源科技股份有限公司 | Secondary cell top cap subassembly and secondary cell |
| CN207038570U (en) * | 2017-08-02 | 2018-02-23 | 宁德时代新能源科技股份有限公司 | Secondary battery top cover assembly and secondary battery |
| CN207381439U (en) * | 2017-10-20 | 2018-05-18 | 宁德时代新能源科技股份有限公司 | Secondary battery top cover assembly and secondary battery |
| WO2024016158A1 (en) * | 2022-07-19 | 2024-01-25 | 宁德时代新能源科技股份有限公司 | Battery cell end cover assembly, battery cell, battery, and electric device |
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