WO2025205485A1 - Processed oil and fat - Google Patents
Processed oil and fatInfo
- Publication number
- WO2025205485A1 WO2025205485A1 PCT/JP2025/011181 JP2025011181W WO2025205485A1 WO 2025205485 A1 WO2025205485 A1 WO 2025205485A1 JP 2025011181 W JP2025011181 W JP 2025011181W WO 2025205485 A1 WO2025205485 A1 WO 2025205485A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oil
- beverage
- fat
- weight
- processed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings or cooking oils
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/02—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof containing fruit or vegetable juices
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/52—Adding ingredients
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/52—Adding ingredients
- A23L2/60—Sweeteners
Definitions
- the present invention relates to processed oils and fats.
- Non-sugar sweeteners which are low-calorie sweeteners that can replace sugar, are sometimes used.
- Non-sugar sweeteners are used in many beverages, but many of them have a unique, unpleasant taste, which can pose challenges in the design of beverage products.
- various improved methods have been proposed.
- Patent Document 1 states that by incorporating gentiooligosaccharides, it is possible to solve the flavor issues associated with high-intensity non-sugar sweeteners.
- Patent Document 1 The technology of Patent Document 1 is a useful approach in that it can solve the flavor issues of beverages containing high-intensity sweeteners that are non-carbohydrate sweeteners by incorporating gentiooligosaccharides.
- the present inventors have investigated ways to solve the flavor problem using a different approach.
- the inventors have come to realize that one of the causes of the off-taste that is a problem with beverages containing non-sugar sweeteners is that the sweetness of non-sugar sweeteners is different in quality from the sweetness of sugar. Specifically, they have come to realize that beverages containing non-sugar sweeteners are accompanied by an excessive sweetness and unpleasant bitterness that are unique to non-sugar sweeteners, and that the excessive sweetness felt particularly when used in beverages results in a bad aftertaste.
- the off-flavor that is a problem with beverages containing such non-sugar sweeteners is an obstacle to the design of beverage products that are both healthy and delicious, and there is a demand in the market for a solution to this problem.
- the present inventors have investigated means for reducing off-tastes even in beverages containing non-sugar sweeteners.
- the inventors conducted extensive research to solve the above-mentioned problems and discovered that by blending specific processed oils and fats with beverages containing at least a non-sugar sweetener, the off-flavors caused by the non-sugar sweetener can be reduced, leading to the completion of the present invention.
- (A) The iodine value is 125 or less.
- (B) The triglyceride composition is randomized.
- the iodine value is 125 or less.
- the triglyceride composition is randomized.
- the total content of palmitic acid and stearic acid is 10% by weight or more.
- the non-sugar sweetener is one or more selected from the group consisting of stevia, sucralose, acesulfame potassium, advantame, thaumatin, and swingle extract.
- the beverage according to [2] or [3], wherein the content of the processed oil or fat in the beverage is 0.005% by weight or more.
- the present invention provides a processed oil and fat that satisfies all of the following requirements (A) to (C):
- A) The iodine value is 125 or less.
- B) The triglyceride composition is randomized.
- the processed fat or oil of the present invention has a randomized triglyceride composition (B).
- the randomized triglyceride composition can be obtained, for example, by a random interesterification process in which fatty acids are first separated from triglycerides using a chemical catalyst or an enzyme catalyst and then recombined.
- the random interesterification step may be interesterification using a chemical catalyst or interesterification using a lipase.
- interesterification using a chemical catalyst for example, sodium methylate can be used.
- the reaction can be carried out by adding 0.1 to 0.5% by weight of sodium methylate to the oil/fat raw material.
- any lipase can be used as long as it exhibits random interesterification activity.
- 1 to 5% by weight of lipase derived from various microorganisms can be added to the oil/fat raw material, and the reaction can be carried out at 40 to 70°C for 16 to 48 hours.
- the total content of palmitic acid and stearic acid in the constituent fatty acid composition (C) is 10% by weight or more.
- the lower limit of this total content is preferably 11% by weight, more preferably 12% by weight, even more preferably 13% by weight, and most preferably 14% by weight.
- the processed oil and fat of the present invention preferably has (D) a slip melting point of 45° C. or less.
- the upper limit of the slip melting point is more preferably 40° C., even more preferably 35° C., 30° C., 29° C., or 28° C., and most preferably 27° C. If this range is appropriate, the inclusion of the processed oil or fat in a beverage containing at least a non-sugar sweetener can further reduce the unpleasant taste caused by the non-sugar sweetener.
- the processed oil and fat of the present invention preferably has a medium-chain fatty acid content of 1% by weight or more in the constituent fatty acid composition (E).
- medium-chain fatty acids refer to saturated fatty acids having 10 or fewer carbon atoms.
- the lower limit of the content is more preferably 2% by weight, even more preferably 3%, 4%, 5%, 8%, 10%, 11%, 15%, or 17% by weight, and most preferably 19% by weight. If this range is appropriate, the inclusion of the processed oil or fat in a beverage containing at least a non-sugar sweetener can further reduce the unpleasant taste caused by the non-sugar sweetener.
- the processed oils and fats of the present invention are not particularly limited as long as they satisfy the above requirements (A) to (C).
- the processed oils and fats are obtained by subjecting one or more oils and fats selected from the group consisting of vegetable oils and fats, animal oils and fats, algae oils, and oils and fats derived from microbial fermentation to one or more processes selected from the group consisting of mixing, fractionation, hydrogenation, and interesterification, or that the processed oils and fats are mixed oils and fats thereof.
- Examples of the vegetable oils and fats include palm oil, rapeseed oil, high erucic rapeseed oil, sunflower oil, high oleic sunflower oil, soybean oil, rice bran oil, corn oil, cottonseed oil, peanut oil, safflower oil, olive oil, sesame oil, linseed oil, palm kernel oil, coconut oil, medium-chain triglycerides (MCT), shea butter, and monkey fat.
- the animal fats and oils include milk fat, beef tallow, lard, fish oil, and whale oil.
- the processed oil and fat is preferably a processed oil and fat that has been at least interesterified, more preferably an interesterified oil and fat, and further preferably, the raw material thereof is made solely of the vegetable oil and fat.
- the processed oil or fat of the present invention may be an interesterified oil or fat obtained by interesterifying a mixed oil containing palm fractionated oil.
- the processed oil or fat is preferably an interesterified oil or fat obtained by interesterifying a mixed oil containing a low-melting point palm fraction. More preferably, the processed oil or fat is an interesterified oil or fat obtained by interesterifying only the low-melting point palm fraction.
- the processed oil or fat of the present invention may be an interesterified oil or fat obtained by interesterifying a mixed oil containing MCT.
- the embodiment is preferably an interesterified oil or fat obtained by interesterifying a mixed oil containing, in addition to MCT, a lauric oil or a liquid oil.
- the lauric fat refers to a fat containing lauric acid as the main constituent fatty acid. More specifically, it refers to a fat having a fatty acid content of 12 carbon atoms in the constituent fatty acid composition of 30% by weight or more. The content is preferably 35 to 65% by weight, more preferably 40 to 60% by weight, and even more preferably 40 to 50% by weight.
- the lauric fat used in the above embodiment is more preferably palm kernel oil or palm kernel oil subjected to one or more of fractionation and hardening. More preferably, it is palm kernel high melting point fraction or palm kernel high melting point fraction extremely hardened oil. Most preferably, it is palm kernel high melting point fraction extremely hardened oil.
- the liquid oil refers to an oil or fat that has fluidity at 20° C.
- the liquid oil used in the embodiment is more preferably one or more selected from the group consisting of rapeseed oil, sunflower oil, soybean oil, and corn oil. Corn oil is even more preferred.
- the processed oil or fat of the present invention may be an interesterified oil or fat obtained by interesterifying a mixed oil containing a lauric oil or fat.
- the processed oil or fat is preferably an interesterified oil or fat obtained by interesterifying palm kernel oil or coconut oil. More preferably, the processed oil or fat is an interesterified oil or fat obtained by interesterifying palm kernel oil.
- optional ingredients such as food additives, colorants, emulsifiers, antioxidants, and flavors can be added as appropriate within a range that does not impair the effects of the present invention.
- the emulsifier include glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, glycerin organic acid fatty acid esters, polyglycerin fatty acid esters, and lecithin.
- non-carbohydrate sweetener By appropriately selecting the non-carbohydrate sweetener to be contained in the beverage of the present invention, it is possible to obtain the effect of further reducing the unpleasant taste caused by the non-carbohydrate sweetener in the beverage containing at least the processed oil and fat and the non-carbohydrate sweetener, which is preferable.
- the sweetness intensity of the non-sugar sweetener contained at least in the beverage of the present invention is not particularly limited, but is preferably 1 to 1000.
- the upper limit of the sweetness intensity is more preferably 900, even more preferably 800, 700, or 650, and most preferably 600.
- the lower limit of the sweetness intensity is more preferably 1.5, even more preferably 2, 2.5, 3, 3.5, or 4, and most preferably 4.5.
- the content of the processed oil or fat in the beverage of the present invention is preferably 0.005% by weight or more.
- the upper limit of the content is preferably 1% by weight, more preferably 0.8% by weight, even more preferably 0.5% by weight, 0.4% by weight, 0.3% by weight, 0.2% by weight, and most preferably 0.1% by weight.
- the lower limit of the content is more preferably 0.01% by weight, even more preferably 0.03% by weight, 0.05% by weight, 0.06% by weight, 0.07% by weight, 0.08% by weight, 0.09% by weight, and most preferably 0.1% by weight. It is preferable that the processed oil and fat contained in the beverage of the present invention is contained in an amount of 0.005% by weight or more relative to the beverage, in that this further reduces the unpleasant taste caused by the non-sugar sweetener.
- the sweetness level of the non-carbohydrate sweetener contained at least in the beverage is S
- the content of the non-carbohydrate sweetener in the beverage is x% by weight
- the content of the processed oil or fat of the present invention contained at least in the beverage is y% by weight
- the "sweetness of non-sugar sweeteners" is a value set by a manufacturer or distributor of the non-sugar sweeteners.
- the relationship between the sweetness level S and content x of the non-sugar sweetener contained in the beverage of the present invention, and the content y of the processed oil/fat of the present invention contained in the beverage of the present invention, satisfies the above formula (1), in that this has the effect of further reducing the unpleasant taste caused by the non-sugar sweetener in the beverage containing at least the processed oil/fat and the non-sugar sweetener.
- the beverage of the present invention can be blended with auxiliary ingredients as needed.
- dairy ingredients raw milk, cow's milk, concentrated skim milk, skim milk powder, fresh cream, butter, etc.
- carbohydrate sweeteners sucgar, starch syrup, fructose, glucose, sugar alcohols, trehalose, etc.
- stabilizers guar gum, locust bean gum, xanthan gum, gum arabic, carrageenan, sodium alginate, CMC, water-soluble cellulose, gelatin, pectin, etc.
- starch starch derived from grains such as rice, wheat, and rice, starch derived from corn, starch derived from potatoes such as potato and tapioca, or modified starches of these, etc.
- emulsifiers include lecithin, sucrose fatty acid esters, propylene glycol fatty acid esters, sorbitan fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, organic acid monog
- the beverage of the present invention refers to all beverages and is not particularly limited.
- the method for producing the beverage of the present invention is not particularly limited, and the beverage can be produced by a known method.
- One example is a method in which additives are added as needed while heating water to 60 to 70°C, and stirred to prepare a dissolved or dispersed aqueous phase, and then an oil phase prepared in advance containing an oil-soluble component is added and pre-emulsified, and after pre-emulsification, the mixture is homogenized in a homogenizer, sterilized by batch sterilization or UHT sterilization using an indirect heating method or a direct heating method, and then homogenized again in a homogenizer and cooled.
- the effects of the present invention are not limited to beverages containing at least a non-sugar sweetener, but can also be achieved in any food or beverage containing at least a non-sugar sweetener.
- the water content of the food or beverage is preferably 0.1% by weight or more, more preferably 1% by weight or more, 3% by weight or more, or 5% by weight or more.
- the water source can be water.
- the water source can be water contained in the raw materials of the food or beverage.
- the food and drink products may include any beverages, foods, etc., and are not particularly limited.
- Examples of products that may be included in the food and drink products include beverages such as cafe au lait, vegetable juice, soy milk beverages, dairy beverages, and soft drinks; desserts such as pudding, bavarois, jelly, frozen desserts, and soft mixes; creams such as whipped cream, pre-whipped cream, and cooking cream; fillings; whiteners; fermented foods such as yogurt, cheese, and fermented beverages; thick liquid foods; bakery products such as biscuits, cookies, breads, and cakes; chocolate products such as hydrated chocolate; spread products such as margarine and butter; seasoning products such as mayonnaise, dressings, sauces, dashi, and seasoned soups; soup products such as corn soup and clam chowder; and prepared foods such as fried foods, fish paste products, and poultry, animal, and fish products.
- beverages such as cafe au lait, vegetable juice, soy milk beverages, dairy beverages, and soft drinks
- desserts such as pudding, bavarois, jelly, frozen desserts, and soft mixes
- creams such as whipped cream, pre-whipped
- ⁇ Method for measuring fatty acid composition The constituent fatty acid composition of processed fats and oils was measured by preparing fatty acid methyl esters in accordance with "Standard Methods for Analysis of Fats, Oils, and Related Materials, 2.4.1.2 Methyl Esterification Method (Boron Trifluoride Methanol Method)" established by the Japan Oil Chemists' Society, and measuring them in accordance with “Standard Methods for Analysis of Fats, Oils, and Related Materials, 2.4.2.3 Fatty Acid Composition (Capillary Gas Chromatography Method)" established by the Japan Oil Chemists' Society.
- Processed oil and fat example 1 Palm olein with an iodine value of 56 was used as the raw oil, and 0.2% by weight of sodium methylate was added as a catalyst to carry out random interesterification at 80°C for 30 minutes. After that, the oil was washed with water, bleached, and deodorized according to conventional methods. This was designated as processed oil and fat Example 1.
- Example 2 was prepared in the same manner as Example 1, except that a mixed oil consisting of 80 parts by weight of extremely hardened palm kernel stearin oil (high melting point fractionated palm kernel oil) and 20 parts by weight of medium-chain fatty acid-bound triglyceride was used as the raw oil for the interesterified oil.
- a mixed oil consisting of 80 parts by weight of extremely hardened palm kernel stearin oil (high melting point fractionated palm kernel oil) and 20 parts by weight of medium-chain fatty acid-bound triglyceride was used as the raw oil for the interesterified oil.
- Example 3 was prepared in the same manner as Example 1, except that a mixed oil consisting of 95 parts by weight of corn oil and 5 parts by weight of medium-chain fatty acid-bound triglyceride was used as the raw oil for the interesterified oil.
- Processed oil and fat example 4 Example 4 was prepared in the same manner as in Processed Oil and Fat Example 1, except that palm kernel oil having an iodine value of 17.5 was used as the raw material oil for the interesterified oil and fat.
- Palm olein fractionated palm oil
- Palm stearin fractionated palm oil
- ⁇ Oil reference example 4 Medium-chain fatty acid-linked triglyceride (manufactured by Fuji Oil Co., Ltd.) was used.
- Flavor evaluation method Flavor evaluation was carried out by five trained panelists who are engaged in the research and development of beverage products on a daily basis. Evaluation was conducted according to the following "Flavor Evaluation Criteria" and judged by consensus. A score of 3 or higher was considered a pass.
- ⁇ Table 2-1 Granulated sugar from Wada Sugar Co., Ltd. was used.
- - For the almond paste we used dehulled almond paste from Tokai Nuts Co., Ltd.
- Non-sugar sweetener A was "Steviron SG" (product sweetness level 200), a stevia extract from Morita Chemical Industry Co., Ltd.
- the sweetness of the non-sugar sweetener is S
- the content of the non-sugar sweetener in the beverage is x% by weight
- the content of the processed oil or fat in the beverage is y% by weight
- the relationship between S, x, and y conforms to the above formula (1)
- the relationship between S, x, and y does not conform to the above formula (1), and no reduction effect of off-tastes derived from non-sugar sweeteners was observed.
- a correlation was observed between suitability for the formula (1) and the effect of reducing off-tastes derived from non-sugar sweeteners.
- the present invention can provide beverages that reduce the off-flavors associated with the non-sugar sweetener, making it extremely useful industrially.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
Description
関連出願
この出願は、令和6年3月27日に出願された日本国特許出願2024-051705号の優先権の利益を主張する。優先権基礎出願はその全体について、出典明示により本明細書の一部とする。
Related Applications This application claims the benefit of priority from Japanese Patent Application No. 2024-051705, filed on March 27, 2024. The entire priority application is hereby incorporated by reference into this specification.
本発明は、加工油脂に関する。 The present invention relates to processed oils and fats.
近年の健康需要の高まりから、飲料の分野においても、低カロリーや低糖質の飲料に対する要望が高まっている。かかる需要に対応するため、砂糖に代わる低カロリー甘味料である、非糖質系甘味料を使用する場合がある。非糖質系甘味料は、多くの飲料に使用されているが、その多くが独特の異味を伴うものであり、飲料商品の設計に課題を抱える場合があった。
かかる課題を解決するため、これまでも改良法が提案されている。
Due to the recent increase in health demand, there has been an increasing demand for low-calorie and low-sugar beverages in the beverage industry. To meet this demand, non-sugar sweeteners, which are low-calorie sweeteners that can replace sugar, are sometimes used. Non-sugar sweeteners are used in many beverages, but many of them have a unique, unpleasant taste, which can pose challenges in the design of beverage products.
To solve this problem, various improved methods have been proposed.
例えば、特許文献1においては、ゲンチオオリゴ糖を配合することにより、非糖質系甘味料である高甘味度甘味料の有する風味面の課題を解決できる旨記載されている。 For example, Patent Document 1 states that by incorporating gentiooligosaccharides, it is possible to solve the flavor issues associated with high-intensity non-sugar sweeteners.
特許文献1の技術は、ゲンチオオリゴ糖を配合することにより、非糖質系甘味料である高甘味度甘味料を含む飲料の風味面の課題を解決できる点で、有用なアプローチである。
本発明者らは、異なるアプローチにより、風味面の課題を解決できる方策を検討した。
The technology of Patent Document 1 is a useful approach in that it can solve the flavor issues of beverages containing high-intensity sweeteners that are non-carbohydrate sweeteners by incorporating gentiooligosaccharides.
The present inventors have investigated ways to solve the flavor problem using a different approach.
本発明者らは、検討を進める中で、非糖質系甘味料を含む飲料の課題である異味の要因の一つとして、非糖質系甘味料の有する甘味が、砂糖の有する甘味とは質が異なることを認識するようになった。具体的には、非糖質系甘味料を含む飲料が、非糖質系甘味料独特の過度な甘さや不快な苦さを伴うこと、加えて、飲料に用いた場合に特に感じる過度な甘さが結果として後味の悪さを引き起こしていることを、認識するようになった。
かかる非糖質系甘味料を含む飲料の課題である異味は、健康と美味しさを両立させた飲料商品の設計の妨げとなっていることから、市場において解決する手段が求められている。
本発明者らは、非糖質系甘味料を含む飲料であっても、異味を低減させることができる手段を検討した。
In the course of their investigations, the inventors have come to realize that one of the causes of the off-taste that is a problem with beverages containing non-sugar sweeteners is that the sweetness of non-sugar sweeteners is different in quality from the sweetness of sugar. Specifically, they have come to realize that beverages containing non-sugar sweeteners are accompanied by an excessive sweetness and unpleasant bitterness that are unique to non-sugar sweeteners, and that the excessive sweetness felt particularly when used in beverages results in a bad aftertaste.
The off-flavor that is a problem with beverages containing such non-sugar sweeteners is an obstacle to the design of beverage products that are both healthy and delicious, and there is a demand in the market for a solution to this problem.
The present inventors have investigated means for reducing off-tastes even in beverages containing non-sugar sweeteners.
本発明者らは、上記課題を解決すべく鋭意検討を行ったところ、非糖質系甘味料を少なくとも含有する飲料に、特定の加工油脂を配合させることにより、非糖質系甘味料に由来する異味を低減させることができるという知見を見出し、本発明を完成させた。 The inventors conducted extensive research to solve the above-mentioned problems and discovered that by blending specific processed oils and fats with beverages containing at least a non-sugar sweetener, the off-flavors caused by the non-sugar sweetener can be reduced, leading to the completion of the present invention.
すなわち、本発明は、下記を包含するものである。
[1] 非糖質系甘味料を少なくとも含有する飲料に用いるための、以下(A)~(C)の要件全てを満たす、加工油脂。
(A)ヨウ素価が125以下である
(B)トリグリセリド組成がランダム化されている
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である
[2] 以下(A)~(C)の要件全てを満たす加工油脂と、非糖質系甘味料と、を少なくとも含有する、飲料。
(A)ヨウ素価が125以下である
(B)トリグリセリド組成がランダム化されている
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である
[3] 前記非糖質系甘味料がステビア、スクラロース、アセスルファムカリウム、アドバンテーム、ソーマチン、及びラカンカ抽出物、からなる群から選ばれる1以上である、[2]記載の飲料。
[4] 前記飲料に占める前記加工油脂の含有量が0.005重量%以上である、[2]又は[3]記載の飲料。
[5] 前記非糖質系甘味料の甘味度をS、前記飲料に占める前記非糖質系甘味料の含有量をx重量%とする場合において、前記飲料に占める前記加工油脂の含有量y重量%が下記式(1)を満たす、[2]又は[3]記載の飲料。
S×x/10000+0.004≦ y ≦S×x/1000+1 ・・・(1)
[6] 前記非糖質系甘味料の甘味度をS、前記飲料に占める前記非糖質系甘味料の含有量をx重量%とする場合において、前記飲料に占める前記加工油脂の含有量y重量%が下記式(1)を満たす、[4]記載の飲料。
S×x/10000+0.004≦ y ≦S×x/1000+1 ・・・(1)
[7] 非糖質系甘味料を少なくとも含有する飲料に対し、以下(A)~(C)の要件全てを満たす加工油脂を含有させることによる、前記飲料より発生する、前記非糖質系甘味料に由来する異味を低減させる方法。
(A)ヨウ素価が125以下である
(B)トリグリセリド組成がランダム化されている
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である
That is, the present invention encompasses the following.
[1] A processed oil or fat for use in a beverage containing at least a non-sugar sweetener, which satisfies all of the following requirements (A) to (C):
(A) The iodine value is 125 or less. (B) The triglyceride composition is randomized. (C) In the constituent fatty acid composition, the total content of palmitic acid and stearic acid is 10% by weight or more [2]. A beverage containing at least a processed oil or fat that satisfies all of the following requirements (A) to (C), and a non-sugar sweetener.
(A) The iodine value is 125 or less. (B) The triglyceride composition is randomized. (C) In the constituent fatty acid composition, the total content of palmitic acid and stearic acid is 10% by weight or more. [3] The beverage according to [2], wherein the non-sugar sweetener is one or more selected from the group consisting of stevia, sucralose, acesulfame potassium, advantame, thaumatin, and swingle extract.
[4] The beverage according to [2] or [3], wherein the content of the processed oil or fat in the beverage is 0.005% by weight or more.
[5] A beverage according to [2] or [3], in which, when the sweetness of the non-sugar sweetener is S and the content of the non-sugar sweetener in the beverage is x% by weight, the content of the processed oil or fat in the beverage is y% by weight, satisfies the following formula (1):
S×x/10000+0.004≦y≦S×x/1000+1 ・・・(1)
[6] The beverage described in [4], wherein the sweetness of the non-sugar sweetener is S, the content of the non-sugar sweetener in the beverage is x% by weight, and the content of the processed oil/fat in the beverage is y% by weight, satisfies the following formula (1):
S×x/10000+0.004≦y≦S×x/1000+1 ・・・(1)
[7] A method for reducing an unpleasant taste resulting from a non-sugar sweetener generated in a beverage containing at least the non-sugar sweetener by adding processed oils and fats that satisfy all of the following requirements (A) to (C) to the beverage:
(A) The iodine value is 125 or less. (B) The triglyceride composition is randomized. (C) In the constituent fatty acid composition, the total content of palmitic acid and stearic acid is 10% by weight or more.
本発明により、非糖質系甘味料を少なくとも含有する飲料において、非糖質系甘味料に由来する異味を低減させることができる。
好ましい態様として、本発明により、非糖質系甘味料を少なくとも含有する飲料において、非糖質系甘味料に由来する異味を低減させることにより、飲料全体として良好な甘味を有する飲料を提供することができる。
According to the present invention, in a beverage containing at least a non-sugar sweetener, the off-taste caused by the non-sugar sweetener can be reduced.
In a preferred embodiment, the present invention can provide a beverage that contains at least a non-sugar sweetener by reducing the off-flavor caused by the non-sugar sweetener, thereby providing a beverage that has a good overall sweetness.
以下、本発明をより詳細に説明する。
なお、数値範囲の上限値及び下限値を示した時は、上限値及び下限値を適宜組み合わせることができ、それにより得られた数値範囲も開示しているものとする。
The present invention will now be described in more detail.
When an upper limit and a lower limit of a numerical range are indicated, the upper limit and the lower limit can be combined as appropriate, and the resulting numerical range is also considered to be disclosed.
本発明により、非糖質系甘味料を少なくとも含有する飲料において、特定の加工油脂を含有させることにより、非糖質系甘味料に由来する異味を低減させることができる。ここでいう「非糖質系甘味料に由来する異味」とは、飲料に非糖質系甘味料を添加することに由来する、独特の不快な甘みや苦み、過度な甘さ、後味の悪さなどとして、認識することができるものである。前記異味は、例えば前記飲料と、同程度の甘味度となるように砂糖を調整し添加した飲料とを比較することによっても、認識することができるものである。
好ましい態様として、本発明により、非糖質系甘味料を少なくとも含有する飲料において、特定の加工油脂を含有させることにより、非糖質系甘味料に由来する異味を低減させることができ、これにより、飲料全体として良好な甘味を有する飲料を提供することができる。前記異味は、殺菌などを目的とした加熱工程を経ずに製造された飲料でも認識できるものである。即ち、飲料の製造工程において、殺菌などを目的とした加熱工程を経て製造される場合に発生し得る異風味とは、異なるものである。
According to the present invention, by adding a specific processed oil or fat to a beverage containing at least a non-sugar sweetener, the off-taste caused by the non-sugar sweetener can be reduced. The "off-taste caused by the non-sugar sweetener" referred to here refers to a distinctive, unpleasant sweetness or bitterness, excessive sweetness, or a bad aftertaste that results from adding a non-sugar sweetener to a beverage. The off-taste can also be recognized, for example, by comparing the beverage with a beverage containing sugar adjusted to achieve the same level of sweetness.
In a preferred embodiment, the present invention allows a beverage containing at least a non-sugar sweetener to contain a specific processed oil or fat, thereby reducing the off-flavor caused by the non-sugar sweetener, thereby providing a beverage with a good overall sweetness. The off-flavor can be recognized even in beverages produced without undergoing a heating step for the purpose of sterilization or the like. In other words, it is different from the off-flavor that can occur when a beverage is produced through a heating step for the purpose of sterilization or the like in the production process.
本発明は、以下(A)~(C)の要件全てを満たす、加工油脂である。前記加工油脂を含有させることにより、非糖質系甘味料を含有する飲料において、前記非糖質系甘味料に由来する異味を低減させることができる。
(A)ヨウ素価が125以下である
(B)トリグリセリド組成がランダム化されている
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である
The present invention provides a processed oil and fat that satisfies all of the following requirements (A) to (C): By incorporating the processed oil and fat, it is possible to reduce the off-flavor caused by a non-sugar sweetener in a beverage that contains the non-sugar sweetener.
(A) The iodine value is 125 or less. (B) The triglyceride composition is randomized. (C) In the constituent fatty acid composition, the total content of palmitic acid and stearic acid is 10% by weight or more.
本発明の加工油脂は、(A)ヨウ素価が125以下である。ヨウ素価の上限は、好ましくは100であり、より好ましくは90であり、さらに好ましくは80、75、70、65、60、55、50、45、40、35、30、25、20、15であり、最も好ましくは10以下である。ヨウ素価の下限は、好ましくは0.1である。 The processed oil and fat of the present invention has (A) an iodine value of 125 or less. The upper limit of the iodine value is preferably 100, more preferably 90, even more preferably 80, 75, 70, 65, 60, 55, 50, 45, 40, 35, 30, 25, 20, or 15, and most preferably 10 or less. The lower limit of the iodine value is preferably 0.1.
本発明の加工油脂は、(B)トリグリセリド組成がランダム化されている。ランダム化されたトリグリセリド組成は、一例として、化学触媒或いは酵素触媒によりトリグリセリドから脂肪酸を一度切り離したのち再結合する、ランダムエステル交換工程を経ることにより、得ることができる。
前記ランダムエステル交換工程は、化学触媒によるエステル交換でもあっても、リパーゼによるエステル交換であってもよい。化学触媒によるエステル交換にあっては、例えばナトリウムメチラートを使用することができる。例えば、油脂原料に対して、ナトリウムメチラートを0.1~0.5重量%添加することにより、反応させることができる。リパーゼによるエステル交換にあっては、ランダムエステル交換活性を示すものであれば、あらゆるリパーゼを使用することができる。例えば、油脂原料に対して、各種微生物由来のリパーゼを、1~5重量%添加し、40~70℃、16~48時間反応させることができる。
The processed fat or oil of the present invention has a randomized triglyceride composition (B). The randomized triglyceride composition can be obtained, for example, by a random interesterification process in which fatty acids are first separated from triglycerides using a chemical catalyst or an enzyme catalyst and then recombined.
The random interesterification step may be interesterification using a chemical catalyst or interesterification using a lipase. In interesterification using a chemical catalyst, for example, sodium methylate can be used. For example, the reaction can be carried out by adding 0.1 to 0.5% by weight of sodium methylate to the oil/fat raw material. In interesterification using lipase, any lipase can be used as long as it exhibits random interesterification activity. For example, 1 to 5% by weight of lipase derived from various microorganisms can be added to the oil/fat raw material, and the reaction can be carried out at 40 to 70°C for 16 to 48 hours.
本発明の加工油脂は、(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である。前記含有量の合計の下限は、好ましくは11重量%であり、より好ましくは12重量%であり、さらに好ましくは13重量%であり、最も好ましくは14重量%である。 In the processed oil and fat of the present invention, the total content of palmitic acid and stearic acid in the constituent fatty acid composition (C) is 10% by weight or more. The lower limit of this total content is preferably 11% by weight, more preferably 12% by weight, even more preferably 13% by weight, and most preferably 14% by weight.
本発明の加工油脂は、(D)上昇融点が45℃以下であることが好ましい。前記上昇融点の上限は、より好ましくは40℃であり、さらに好ましくは35℃、30℃、29℃、28℃であり、最も好ましくは27℃である。
この範囲が適当であると、非糖質系甘味料を少なくとも含有する飲料において、前記加工油脂を含有させることにより、非糖質系甘味料に由来する異味をさらに低減させることができる。
The processed oil and fat of the present invention preferably has (D) a slip melting point of 45° C. or less. The upper limit of the slip melting point is more preferably 40° C., even more preferably 35° C., 30° C., 29° C., or 28° C., and most preferably 27° C.
If this range is appropriate, the inclusion of the processed oil or fat in a beverage containing at least a non-sugar sweetener can further reduce the unpleasant taste caused by the non-sugar sweetener.
本発明の加工油脂は、(E)構成脂肪酸組成中の中鎖脂肪酸の含有量が1重量%以上であることが好ましい。ただし、中鎖脂肪酸とは、炭素数が10以下の飽和脂肪酸を示す。前記含有量の下限は、より好ましくは2重量%であり、さらに好ましくは3重量%、4重量%、5重量%、8重量%、10重量%、11重量%、15重量%、17重量%であり、最も好ましくは19重量%である。
この範囲が適当であると、非糖質系甘味料を少なくとも含有する飲料において、前記加工油脂を含有させることにより、非糖質系甘味料に由来する異味をさらに低減させることができる。
The processed oil and fat of the present invention preferably has a medium-chain fatty acid content of 1% by weight or more in the constituent fatty acid composition (E). Here, medium-chain fatty acids refer to saturated fatty acids having 10 or fewer carbon atoms. The lower limit of the content is more preferably 2% by weight, even more preferably 3%, 4%, 5%, 8%, 10%, 11%, 15%, or 17% by weight, and most preferably 19% by weight.
If this range is appropriate, the inclusion of the processed oil or fat in a beverage containing at least a non-sugar sweetener can further reduce the unpleasant taste caused by the non-sugar sweetener.
本発明の加工油脂は、前記要件(A)~(C)を満たすものであれば特に限定されるものではないが、植物性油脂、動物性油脂、藻類油、又は微生物発酵由来の油脂、からなる群より選択される1以上の油脂に対し、混合、分別、水素添加、エステル交換からなる群より選択される1以上の加工を施した加工油脂であるか、さらにこれらの混合油脂等であることが好ましい。
前記植物性油脂として、例えば、パーム油、菜種油、ハイエルシン菜種油、ヒマワリ油、ハイオレイックヒマワリ油、大豆油、こめ油、コーン油、綿実油、落花生油、サフラワー油、オリーブ油、ゴマ油、亜麻仁油、パーム核油、ヤシ油、中鎖脂肪酸結合トリグリセリド(MCT)、シア脂、サル脂等を挙げることができる。
前記動物性油脂として、乳脂、牛脂、ラード、魚油、鯨油等を挙げることができる。
前記加工油脂は、少なくともエステル交換を施した加工油脂であることが好ましく、より好ましくはエステル交換油脂である。さらに、その原料は前記植物性油脂のみからなることがさらに好ましい。
The processed oils and fats of the present invention are not particularly limited as long as they satisfy the above requirements (A) to (C). However, it is preferable that the processed oils and fats are obtained by subjecting one or more oils and fats selected from the group consisting of vegetable oils and fats, animal oils and fats, algae oils, and oils and fats derived from microbial fermentation to one or more processes selected from the group consisting of mixing, fractionation, hydrogenation, and interesterification, or that the processed oils and fats are mixed oils and fats thereof.
Examples of the vegetable oils and fats include palm oil, rapeseed oil, high erucic rapeseed oil, sunflower oil, high oleic sunflower oil, soybean oil, rice bran oil, corn oil, cottonseed oil, peanut oil, safflower oil, olive oil, sesame oil, linseed oil, palm kernel oil, coconut oil, medium-chain triglycerides (MCT), shea butter, and monkey fat.
Examples of the animal fats and oils include milk fat, beef tallow, lard, fish oil, and whale oil.
The processed oil and fat is preferably a processed oil and fat that has been at least interesterified, more preferably an interesterified oil and fat, and further preferably, the raw material thereof is made solely of the vegetable oil and fat.
本発明の加工油脂は、ある実施形態において、パーム分別油を含む混合油にエステル交換を施したエステル交換油脂であり得る。前記実施形態は、好ましくは、パーム分別低融点部を含む混合油にエステル交換を施したエステル交換油脂である。より好ましくは、パーム分別低融点部のみにエステル交換を施したエステル交換油脂である。 In one embodiment, the processed oil or fat of the present invention may be an interesterified oil or fat obtained by interesterifying a mixed oil containing palm fractionated oil. In this embodiment, the processed oil or fat is preferably an interesterified oil or fat obtained by interesterifying a mixed oil containing a low-melting point palm fraction. More preferably, the processed oil or fat is an interesterified oil or fat obtained by interesterifying only the low-melting point palm fraction.
本発明の加工油脂は、ある実施形態において、MCTを含む混合油にエステル交換を施したエステル交換油脂であり得る。前記実施形態は、好ましくは、MCTに加え、ラウリン系油脂又は液状油を含む混合油にエステル交換を施したエステル交換油脂である。
前記ラウリン系油脂とは、ラウリン酸を主要な構成脂肪酸として含む油脂をいう。より詳しくは、構成脂肪酸組成中の炭素数12の脂肪酸含有量が30重量%以上である油脂をいう。前記含有量は、35~65重量%であることが好ましく、40~60重量%であることがより好ましく、40~50重量%であることがさらに好ましい。具体的には、パーム核油、ヤシ油、又は、パーム核油若しくはヤシ油の1種以上の油脂に対して、分別、硬化、エステル交換の1つ以上の加工を経た油脂を挙げることができる。前記実施形態において用いるラウリン系油脂は、パーム核油、又はパーム核油に対して分別又は硬化の1つ以上の加工を経た油脂であることがより好ましい。さらに好ましくは、パーム核分別高融点部、又は、パーム核分別高融点部極度硬化油である。最も好ましくは、パーム核分別高融点部極度硬化油である。
前記液状油とは、20℃において流動性を有する油脂をいう。前記実施形態において用いる液状油は、菜種油、ヒマワリ油、大豆油、又はコーン油からなる群から選ばれる1以上であることがより好ましい。さらに好ましくは、コーン油である。
In one embodiment, the processed oil or fat of the present invention may be an interesterified oil or fat obtained by interesterifying a mixed oil containing MCT. The embodiment is preferably an interesterified oil or fat obtained by interesterifying a mixed oil containing, in addition to MCT, a lauric oil or a liquid oil.
The lauric fat refers to a fat containing lauric acid as the main constituent fatty acid. More specifically, it refers to a fat having a fatty acid content of 12 carbon atoms in the constituent fatty acid composition of 30% by weight or more. The content is preferably 35 to 65% by weight, more preferably 40 to 60% by weight, and even more preferably 40 to 50% by weight. Specific examples include palm kernel oil, coconut oil, or fats obtained by subjecting one or more of palm kernel oil and coconut oil to one or more of fractionation, hardening, and interesterification. The lauric fat used in the above embodiment is more preferably palm kernel oil or palm kernel oil subjected to one or more of fractionation and hardening. More preferably, it is palm kernel high melting point fraction or palm kernel high melting point fraction extremely hardened oil. Most preferably, it is palm kernel high melting point fraction extremely hardened oil.
The liquid oil refers to an oil or fat that has fluidity at 20° C. The liquid oil used in the embodiment is more preferably one or more selected from the group consisting of rapeseed oil, sunflower oil, soybean oil, and corn oil. Corn oil is even more preferred.
本発明の加工油脂は、ある実施形態において、ラウリン系油脂を含む混合油にエステル交換を施したエステル交換油脂であり得る。前記実施形態は、好ましくは、パーム核油、又はヤシ油にエステル交換を施したエステル交換油脂である。より好ましくは、パーム核油にエステル交換を施したエステル交換油脂である。 In one embodiment, the processed oil or fat of the present invention may be an interesterified oil or fat obtained by interesterifying a mixed oil containing a lauric oil or fat. In this embodiment, the processed oil or fat is preferably an interesterified oil or fat obtained by interesterifying palm kernel oil or coconut oil. More preferably, the processed oil or fat is an interesterified oil or fat obtained by interesterifying palm kernel oil.
本発明の加工油脂は、前記要件(A)~(C)を満たす限り、本発明の効果を損なわない範囲で、食品添加物をはじめとする、着色料、乳化剤、酸化防止剤、香料等の任意成分を適宜添加することができる。
また前記乳化剤としては、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン有機酸脂肪酸エステル、ポリグリセリン脂肪酸エステル、レシチン、等を挙げることができる。
As long as the processed oil and fat of the present invention satisfies the above requirements (A) to (C), optional ingredients such as food additives, colorants, emulsifiers, antioxidants, and flavors can be added as appropriate within a range that does not impair the effects of the present invention.
Examples of the emulsifier include glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, glycerin organic acid fatty acid esters, polyglycerin fatty acid esters, and lecithin.
本発明の飲料に少なくとも含有される前記非糖質系甘味料は、ステビア、スクラロース、アセスルファムカリウム、アドバンテーム、ソーマチン、及びラカンカ抽出物、からなる群から選ばれる1以上であることが好ましい。より好ましくは、ステビア、スクラロース、ラカンカ抽出物、からなる群より選ばれる1以上である。さらに好ましくは、ステビア、スクラロース、からなる群より選ばれる1以上である。最も好ましくは、ステビアである。
なお、ステビアとして、具体的には、ステビア抽出物、酵素処理ステビア、ステビオサイド、レバウディオサイドなどを挙げることができる。
本発明の飲料に少なくとも含有される前記非糖質系甘味料を適当に選択することにより、前記加工油脂と前記非糖質系甘味料を少なくとも含有する前記飲料において、前記非糖質系甘味料に由来する異味をさらに低減させる効果が得られる点で好ましい。
The non-sugar sweetener contained at least in the beverage of the present invention is preferably one or more selected from the group consisting of stevia, sucralose, acesulfame potassium, advantame, thaumatin, and Momordica flower extract. More preferably, it is one or more selected from the group consisting of stevia, sucralose, and Momordica flower extract. Even more preferably, it is one or more selected from the group consisting of stevia and sucralose. Most preferably, it is stevia.
Specific examples of stevia include stevia extract, enzyme-treated stevia, stevioside, and rebaudioside.
By appropriately selecting the non-carbohydrate sweetener to be contained in the beverage of the present invention, it is possible to obtain the effect of further reducing the unpleasant taste caused by the non-carbohydrate sweetener in the beverage containing at least the processed oil and fat and the non-carbohydrate sweetener, which is preferable.
本発明の飲料に少なくとも含有される前記非糖質系甘味料の甘味度は、特に限定されるものではないが、好ましくは1~1000である。前記甘味度の上限は、より好ましくは900であり、さらに好ましくは800、700、650であり、最も好ましくは600である。前記甘味度の下限は、より好ましくは1.5であり、さらに好ましくは2、2.5、3、3.5、4であり、最も好ましくは4.5である。
本発明の飲料に少なくとも含有される前記非糖質系甘味料の甘味度が1~1000であることで、本発明の加工油脂を含有させることによる、前記非糖質系甘味料に由来する異味を低減させる効果を、十分に確認することができる。
なお、本明細書及び本特許請求の範囲における「非糖質系甘味料の甘味度」とは、前記非糖質系甘味料を業として製造販売する者が設定した数値とする。
The sweetness intensity of the non-sugar sweetener contained at least in the beverage of the present invention is not particularly limited, but is preferably 1 to 1000. The upper limit of the sweetness intensity is more preferably 900, even more preferably 800, 700, or 650, and most preferably 600. The lower limit of the sweetness intensity is more preferably 1.5, even more preferably 2, 2.5, 3, 3.5, or 4, and most preferably 4.5.
By setting the sweetness level of at least the non-sugar sweetener contained in the beverage of the present invention to 1 to 1000, the effect of adding the processed oil or fat of the present invention in reducing the unpleasant taste caused by the non-sugar sweetener can be fully confirmed.
In this specification and claims, the term "sweetness of a non-sugar sweetener" refers to a value set by a manufacturer or distributor of the non-sugar sweetener.
本発明の飲料に少なくとも含有される前記非糖質系甘味料は、前記飲料に対し0.0005重量%以上含有されていることが好ましい。より好ましくは0.001重量%以上であり、さらに好ましくは0.005重量%以上であり、最も好ましくは0.01重量%以上である。
本発明の飲料に少なくとも含有される前記非糖質系甘味料が、前記飲料に対し0.0005重量%以上含有されることで、本発明の加工油脂を含有させることによる、前記非糖質系甘味料に由来する異味を低減させる効果を、十分に確認することができる。
The non-sugar sweetener contained in the beverage of the present invention is preferably contained in an amount of 0.0005% by weight or more, more preferably 0.001% by weight or more, even more preferably 0.005% by weight or more, and most preferably 0.01% by weight or more, based on the weight of the beverage.
By ensuring that the non-carbohydrate sweetener contained in the beverage of the present invention is present in an amount of 0.0005% by weight or more relative to the beverage, the effect of containing the processed oil or fat of the present invention in reducing the unpleasant taste caused by the non-carbohydrate sweetener can be fully confirmed.
本発明の飲料に占める前記加工油脂の含有量は、0.005重量%以上であることが好ましい。前記含有量の上限は、好ましくは1重量%であり、より好ましくは0.8重量%であり、さらに好ましくは0.5重量%、0.4重量%、0.3重量%、0.2重量%であり、最も好ましくは0.1重量%である。前記含有量の下限は、より好ましくは0.01重量%であり、さらに好ましくは0.03重量%、0.05重量%、0.06重量%、0.07重量%、0.08重量%、0.09重量%であり、最も好ましくは0.1重量%である。
本発明の飲料に少なくとも含有される前記加工油脂が、前記飲料に対し0.005重量%以上含有されていることにより、前記非糖質系甘味料に由来する異味をさらに低減させることができる点で好ましい。
The content of the processed oil or fat in the beverage of the present invention is preferably 0.005% by weight or more. The upper limit of the content is preferably 1% by weight, more preferably 0.8% by weight, even more preferably 0.5% by weight, 0.4% by weight, 0.3% by weight, 0.2% by weight, and most preferably 0.1% by weight. The lower limit of the content is more preferably 0.01% by weight, even more preferably 0.03% by weight, 0.05% by weight, 0.06% by weight, 0.07% by weight, 0.08% by weight, 0.09% by weight, and most preferably 0.1% by weight.
It is preferable that the processed oil and fat contained in the beverage of the present invention is contained in an amount of 0.005% by weight or more relative to the beverage, in that this further reduces the unpleasant taste caused by the non-sugar sweetener.
本発明の飲料は、前記飲料に少なくとも含有される非糖質系甘味料の甘味度をS、前記飲料に占める前記非糖質系甘味料の含有量をx重量%とし、さらに、前記飲料に占める、前記飲料に少なくとも含有される本発明の加工油脂の含有量をy重量%とする場合において、S、x、及びyの関係が下記式(1)を満たすことが好ましい。
S×x/10000+0.004≦ y ≦S×x/1000+1 ・・・(1)
なお、前記「非糖質系甘味料の甘味度」は、前記非糖質系甘味料を業として製造販売する者が設定した数値とする。
本発明の飲料に含有される前記非糖質系甘味料の甘味度S、含有量x、及び、本発明の飲料に含有される本発明の加工油脂の含有量yの関係が上記式(1)を満たすことにより、前記加工油脂と前記非糖質系甘味料を少なくとも含有する前記飲料において、前記非糖質系甘味料に由来する異味をさらに低減させる効果が得られる点で好ましい。
In the beverage of the present invention, when the sweetness level of the non-carbohydrate sweetener contained at least in the beverage is S, the content of the non-carbohydrate sweetener in the beverage is x% by weight, and the content of the processed oil or fat of the present invention contained at least in the beverage is y% by weight, it is preferable that the relationship between S, x, and y satisfy the following formula (1).
S×x/10000+0.004≦y≦S×x/1000+1 ・・・(1)
The "sweetness of non-sugar sweeteners" is a value set by a manufacturer or distributor of the non-sugar sweeteners.
It is preferable that the relationship between the sweetness level S and content x of the non-sugar sweetener contained in the beverage of the present invention, and the content y of the processed oil/fat of the present invention contained in the beverage of the present invention, satisfies the above formula (1), in that this has the effect of further reducing the unpleasant taste caused by the non-sugar sweetener in the beverage containing at least the processed oil/fat and the non-sugar sweetener.
本発明の飲料は、必要に応じて副原料を配合することができる。例えば、乳原料(生乳、牛乳、脱脂濃縮乳、脱脂粉乳、生クリーム、バター等)や、糖質甘味料(砂糖、水あめ、果糖、ぶどう糖、糖アルコール、トレハロース等)や、安定剤(グアーガム、ローカストビーンガム、キサンタンガム、アラビアガム、カラギナン、アルギン酸ナトリウム、CMC、水溶性セルロース、ゼラチン、ペクチン等)や、澱粉(イネ・小麦・米等の穀類由来の澱粉や、トウモロコシ由来の澱粉や、馬鈴薯・タピオカ等のいも類由来の澱粉等、もしくはこれらの加工澱粉や化工澱粉等)や、乳化剤(レシチン、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、有機酸モノグリセリド等)や、食塩や、着香料や、着色料や、酸味料や、風味原料(コーヒー、ココア、茶類、チョコレート原料、果汁、果肉、種実類、蜂蜜、メープルシロップ、酒類等)や、各種栄養素(蛋白質や、アミノ酸や、ポリデキストロース、イヌリン、難消化性デキストリンなどの食物繊維や、ビタミン類や、ミネラル類等)等が挙げられる。 The beverage of the present invention can be blended with auxiliary ingredients as needed. For example, dairy ingredients (raw milk, cow's milk, concentrated skim milk, skim milk powder, fresh cream, butter, etc.), carbohydrate sweeteners (sugar, starch syrup, fructose, glucose, sugar alcohols, trehalose, etc.), stabilizers (guar gum, locust bean gum, xanthan gum, gum arabic, carrageenan, sodium alginate, CMC, water-soluble cellulose, gelatin, pectin, etc.), starch (starch derived from grains such as rice, wheat, and rice, starch derived from corn, starch derived from potatoes such as potato and tapioca, or modified starches of these, etc.), emulsifiers ( These include lecithin, sucrose fatty acid esters, propylene glycol fatty acid esters, sorbitan fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, organic acid monoglycerides, etc.), salt, flavorings, colorings, acidulants, flavoring ingredients (coffee, cocoa, tea, chocolate ingredients, fruit juice, fruit pulp, nuts and seeds, honey, maple syrup, alcoholic beverages, etc.), and various nutrients (protein, amino acids, dietary fiber such as polydextrose, inulin, and indigestible dextrin, vitamins, minerals, etc.).
本発明の飲料は、飲料すべてを指し、特に限定されるものではない。
本発明の飲料の製造方法は、特に限定されるものではなく、公知の方法によって製造することができる。一例として、水を60~70℃に加熱しながら必要に応じて添加物を加えて攪拌し、溶解あるいは分散させた水相を調整後、あらかじめ油溶性成分を含め調合した油相を添加し、予備乳化を行い、予備乳化後、ホモゲナイザーにて均質化し、バッチ式殺菌法、または間接加熱方式あるいは直接加熱方式によるUHT滅菌処理法にて滅菌し、再びホモゲナイザーにて均質化し冷却する方法を挙げることができる。
The beverage of the present invention refers to all beverages and is not particularly limited.
The method for producing the beverage of the present invention is not particularly limited, and the beverage can be produced by a known method. One example is a method in which additives are added as needed while heating water to 60 to 70°C, and stirred to prepare a dissolved or dispersed aqueous phase, and then an oil phase prepared in advance containing an oil-soluble component is added and pre-emulsified, and after pre-emulsification, the mixture is homogenized in a homogenizer, sterilized by batch sterilization or UHT sterilization using an indirect heating method or a direct heating method, and then homogenized again in a homogenizer and cooled.
本発明は、非糖質系甘味料を少なくとも含有する飲料に対し、以下(A)~(C)の要件全てを満たす加工油脂を含有させることによる、前記飲料に発生する、前記非糖質系甘味料に由来する異味を低減させる方法である。
(A)ヨウ素価が125以下である
(B)トリグリセリド組成がランダム化されている
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である
The present invention provides a method for reducing the unpleasant taste that occurs in a beverage containing at least a non-sugar sweetener and that is derived from the non-sugar sweetener, by adding processed oils and fats that satisfy all of the following requirements (A) to (C) to the beverage:
(A) The iodine value is 125 or less. (B) The triglyceride composition is randomized. (C) In the constituent fatty acid composition, the total content of palmitic acid and stearic acid is 10% by weight or more.
本発明の効果は、非糖質系甘味料を少なくとも含有する飲料に限定されるものではなく、非糖質系甘味料を少なくとも含有する、あらゆる飲食品においても発揮され得る。前記飲食品に含まれる水分量は、0.1重量%以上であることが好ましく、より好ましくは1重量%以上、3重量%以上、5重量%以上である。水分の供給源としては、ある実施形態では水が挙げられる。またある実施形態では、前記飲食品の原材料自身に含まれる水が挙げられる。
前記飲食品は、任意の飲料、食品等を包含し得るものであり、特に限定されるものではない。前記飲食品に包含し得る製品として、例えば、カフェオレ、野菜ジュース、豆乳飲料,乳飲料や清涼飲料等の飲料;プリン,ババロア,ゼリー,冷菓やソフトミックス等のデザート;ホイップクリーム,ホイップ済クリームや調理用クリーム等のクリーム類;フィリング;ホワイトナー;ヨーグルト,チーズや発酵飲料等の発酵食品;濃厚流動食;ビスケット,クッキー,パン類やケーキ等のベーカリー製品;含水チョコレート等のチョコレート製品;マーガリン、バター等のスプレッド製品;マヨネーズ,ドレッシング,タレ,ソース,ダシ,調味スープ等の調味料製品;コーンスープ,クラムチャウダー等のスープ製品;フライ食品、水産練製品、鳥獣魚肉製品等の総菜;などの製品が挙げられる。
The effects of the present invention are not limited to beverages containing at least a non-sugar sweetener, but can also be achieved in any food or beverage containing at least a non-sugar sweetener. The water content of the food or beverage is preferably 0.1% by weight or more, more preferably 1% by weight or more, 3% by weight or more, or 5% by weight or more. In one embodiment, the water source can be water. In another embodiment, the water source can be water contained in the raw materials of the food or beverage.
The food and drink products may include any beverages, foods, etc., and are not particularly limited. Examples of products that may be included in the food and drink products include beverages such as cafe au lait, vegetable juice, soy milk beverages, dairy beverages, and soft drinks; desserts such as pudding, bavarois, jelly, frozen desserts, and soft mixes; creams such as whipped cream, pre-whipped cream, and cooking cream; fillings; whiteners; fermented foods such as yogurt, cheese, and fermented beverages; thick liquid foods; bakery products such as biscuits, cookies, breads, and cakes; chocolate products such as hydrated chocolate; spread products such as margarine and butter; seasoning products such as mayonnaise, dressings, sauces, dashi, and seasoned soups; soup products such as corn soup and clam chowder; and prepared foods such as fried foods, fish paste products, and poultry, animal, and fish products.
以下に本発明の実施例を示し、本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中%、部、及び比はいずれも重量基準を意味する。 The present invention will be explained in more detail below using examples, but the spirit of the present invention is not limited to the following examples. In the examples, percentages, parts, and ratios are all by weight.
■脂肪酸組成の測定方法
加工油脂又は油脂の構成脂肪酸組成は、日本油化学会制定「基準油脂分析試験法2.4.1.2 メチルエステル化法(三フッ化ホウ素メタノール法)」に準じて脂肪酸メチルエステルを調製し、日本油化学協会制定「基準油脂分析試験法2.4.2.3 脂肪酸組成(キャピラリーガスクロマトグラフ法)」に準じて測定した。(ヨウ素価の測定方法)
■ヨウ素価の測定方法
加工油脂又は油脂のヨウ素価は、基準油脂分析試験法2.3.4.1-2013により測定した。
■融点の測定方法
加工油脂又は油脂の融点は、基準油脂分析試験法2.2.4.2-1996により測定した。
■Method for measuring fatty acid composition The constituent fatty acid composition of processed fats and oils was measured by preparing fatty acid methyl esters in accordance with "Standard Methods for Analysis of Fats, Oils, and Related Materials, 2.4.1.2 Methyl Esterification Method (Boron Trifluoride Methanol Method)" established by the Japan Oil Chemists' Society, and measuring them in accordance with "Standard Methods for Analysis of Fats, Oils, and Related Materials, 2.4.2.3 Fatty Acid Composition (Capillary Gas Chromatography Method)" established by the Japan Oil Chemists' Society. (Method for measuring iodine value)
■Method for measuring iodine value The iodine value of processed fats and oils was measured according to the Standard Method for Analysis of Fats and Oils 2.3.4.1-2013.
(ii) Method for measuring melting point The melting point of processed fats and oils was measured in accordance with the Standard Method for Analysis of Fats, Oils and Related Materials 2.2.4.2-1996.
■加工油脂実施例1
ヨウ素価56のパームオレインを原料油として、ナトリウムメチラートを触媒として0.2重量%添加し、80℃にて30分ランダムエステル交換を行った後、常法に従い水洗、脱色、脱臭を行った。これを加工油脂実施例1とした。
Processed oil and fat example 1
Palm olein with an iodine value of 56 was used as the raw oil, and 0.2% by weight of sodium methylate was added as a catalyst to carry out random interesterification at 80°C for 30 minutes. After that, the oil was washed with water, bleached, and deodorized according to conventional methods. This was designated as processed oil and fat Example 1.
■加工油脂実施例2
エステル交換油脂の原料油として、80重量部のパーム核ステアリン極度硬化油(パーム核分別高融点部極度硬化油)、及び20重量部の中鎖脂肪酸結合トリグリセリドからなる混合油を用いる以外は、加工油脂実施例1と同様にして、同実施例2とした。
Processed oil and fat example 2
Example 2 was prepared in the same manner as Example 1, except that a mixed oil consisting of 80 parts by weight of extremely hardened palm kernel stearin oil (high melting point fractionated palm kernel oil) and 20 parts by weight of medium-chain fatty acid-bound triglyceride was used as the raw oil for the interesterified oil.
■加工油脂実施例3
エステル交換油脂の原料油として、95重量部のコーン油、及び5重量部の中鎖脂肪酸結合トリグリセリドからなる混合油を用いる以外は、加工油脂実施例1と同様にして、同実施例3とした。
Processed oil and fat example 3
Example 3 was prepared in the same manner as Example 1, except that a mixed oil consisting of 95 parts by weight of corn oil and 5 parts by weight of medium-chain fatty acid-bound triglyceride was used as the raw oil for the interesterified oil.
■加工油脂実施例4
エステル交換油脂の原料油として、ヨウ素価17.5のパーム核油を用いる以外は、加工油脂実施例1と同様にして、同実施例4とした。
Processed oil and fat example 4
Example 4 was prepared in the same manner as in Processed Oil and Fat Example 1, except that palm kernel oil having an iodine value of 17.5 was used as the raw material oil for the interesterified oil and fat.
■加工油脂実施例5
エステル交換油脂の原料油として、ヨウ素価8.5のヤシ油を用いる以外は、加工油脂実施例1と同様にして、同実施例5とした。
Processed oil and fat example 5
Example 5 was prepared in the same manner as in Processed Oil and Fat Example 1, except that palm oil having an iodine value of 8.5 was used as the raw material oil for the interesterified oil and fat.
■加工油脂比較例1
ヨウ素価56のパームオレイン(パーム分別油)を用いた。
■Processed oil and fat comparison example 1
Palm olein (fractionated palm oil) with an iodine value of 56 was used.
■加工油脂比較例2
ヨウ素価31のパームステアリン(パーム分別油)を用いた。
■Processed oil and fat comparison example 2
Palm stearin (fractionated palm oil) with an iodine value of 31 was used.
■加工油脂比較例3
80重量部のパーム核ステアリン極度硬化油(パーム核分別高融点部極度硬化油)、及び20重量部の中鎖脂肪酸結合トリグリセリドからなる混合油を用いた。
■Processed oil and fat comparison example 3
A mixed oil consisting of 80 parts by weight of extremely hardened palm kernel stearin oil (high melting point fractionated palm kernel oil) and 20 parts by weight of medium-chain fatty acid-linked triglyceride was used.
■加工油脂比較例4
95重量部のコーン油、及び5重量部の中鎖脂肪酸結合トリグリセリドからなる混合油を用いた。
■Processed oil comparative example 4
A mixed oil consisting of 95 parts by weight of corn oil and 5 parts by weight of medium-chain fatty acid-bound triglyceride was used.
■油脂参考例1
ヨウ素価17.5の精製パーム核油(不二製油株式会社製)を用いた。
■Oil reference example 1
Refined palm kernel oil (manufactured by Fuji Oil Co., Ltd.) with an iodine value of 17.5 was used.
■油脂参考例2
ヨウ素価8.5の精製ヤシ油(不二製油株式会社製)を用いた。
■Oil reference example 2
Refined coconut oil (manufactured by Fuji Oil Co., Ltd.) with an iodine value of 8.5 was used.
■油脂参考例3
ヨウ素価52の精製パーム油(不二製油株式会社製)を用いた。
■Oil reference example 3
Refined palm oil (manufactured by Fuji Oil Co., Ltd.) with an iodine value of 52 was used.
■油脂参考例4
中鎖脂肪酸結合トリグリセリド(不二製油株式会社製)を用いた。
■Oil reference example 4
Medium-chain fatty acid-linked triglyceride (manufactured by Fuji Oil Co., Ltd.) was used.
以上の加工油脂実施例1~5、及び同比較例1~4、並びに油脂参考例1~4の分析値を表1-1~表1-2に示す。
なお、表中の融点は上昇融点を示す。
The analytical values of the above processed fats and oils Examples 1 to 5, comparative examples 1 to 4, and reference fats and oils Examples 1 to 4 are shown in Tables 1-1 and 1-2.
The melting points in the table indicate slip melting points.
■表1-1
■Table 1-1
■表1-2
■Table 1-2
■検討1 ステビア抽出物を含有する飲料
表2-1または表2-2の配合に従い、ステビア抽出物を含有する飲料である、アーモンドミルクを製造し、加工油脂又は油脂による効果を検証した。
温水に、加工油脂又は油脂を除く各種の原料を加え、ミキサー等で撹拌し溶解させた。次に、加工油脂又は油脂を加え分散させ、最後に温水にて水分調整を行い、調合液を得た。前記調合液を高圧ホモゲナイザー等で均質化し、レトルトパウチに充填し、レトルト殺菌(121℃・30分)を行った。
■ Study 1 Beverage containing stevia extract According to the formulation in Table 2-1 or Table 2-2, almond milk, a beverage containing stevia extract, was produced and the effects of processed fats or oils were examined.
The processed oil or fat or various raw materials excluding the oil and fat were added to warm water and stirred and dissolved using a mixer or the like. Next, the processed oil or fat or fat was added and dispersed, and finally, the moisture content was adjusted using warm water to obtain a preparation. The preparation was homogenized using a high-pressure homogenizer or the like, filled into a retort pouch, and subjected to retort sterilization (121°C, 30 minutes).
■風味評価の方法
風味評価は、日々、飲料製品の研究開発に従事する訓練されたパネリスト5名で実施した。以下の「風味評価の評価基準」に従い評価し、合議により判定した。評点3以上となるものを合格とした。
Flavor evaluation method Flavor evaluation was carried out by five trained panelists who are engaged in the research and development of beverage products on a daily basis. Evaluation was conducted according to the following "Flavor Evaluation Criteria" and judged by consensus. A score of 3 or higher was considered a pass.
■風味評価の評価基準
5点:飲料に、非糖質系甘味料に由来する異味が感じられない。
4点:飲料に、非糖質系甘味料に由来する異味がわずかに感じられる。
3点:飲料に、非糖質系甘味料に由来する異味が弱く感じられる。
2点:飲料に、非糖質系甘味料に由来する異味が感じられる。
1点:飲料に、非糖質系甘味料に由来する異味が強く感じられる。
■Flavor evaluation criteria 5 points: The beverage does not have any off-flavors derived from non-sugar sweeteners.
4 points: The beverage has a slight off-flavor derived from non-sugar sweeteners.
3 points: The beverage has a weak off-flavor caused by non-sugar sweeteners.
2 points: The beverage has an unpleasant taste due to the non-sugar sweetener.
1 point: The beverage has a strong off-flavor caused by non-sugar sweeteners.
■表2-1
・砂糖は、和田製糖株式会社のグラニュー糖を用いた。
・アーモンドペーストは、東海ナッツ株式会社の脱皮アーモンドペーストを用いた。
・非糖質系甘味料Aは、守田化学工業株式会社のステビア抽出物である、「ステビロンSG」(製品甘味度200)を用いた。
■Table 2-1
- Granulated sugar from Wada Sugar Co., Ltd. was used.
- For the almond paste, we used dehulled almond paste from Tokai Nuts Co., Ltd.
- Non-sugar sweetener A was "Steviron SG" (product sweetness level 200), a stevia extract from Morita Chemical Industry Co., Ltd.
■表2-2
■Table 2-2
■検討1の考察
表2-1~表2-2の結果より、加工油脂実施例1~5と非糖質系甘味料A(ステビア抽出物)を含有する飲料において、非糖質系甘味料に由来する異味を低減させることができた。
■Discussion of Study 1 The results in Tables 2-1 to 2-2 show that in beverages containing processed oils and fats Examples 1 to 5 and non-sugar sweetener A (stevia extract), the off-flavor caused by the non-sugar sweetener was reduced.
■検討2 非糖質系甘味料(ステビア抽出物)を含有する飲料中の加工油脂の含有量
表3の配合に従い、検討1と同様の手順で、ステビア抽出物を含有する飲料である、カフェラテを製造し、飲料中の加工油脂の含有量が風味評価に与える影響を検証した。
製造したカフェラテは、検討1の「風味評価の方法」及び「風味評価の評価基準」に従い、風味評価を行った。
■Study 2 Content of processed fats in beverages containing non-sugar sweeteners (stevia extract) A cafe latte, a beverage containing stevia extract, was produced using the same procedure as in Study 1 according to the formulation in Table 3, and the effect of the content of processed fats in the beverage on flavor evaluation was examined.
The produced cafe latte was subjected to a flavor evaluation in accordance with the "Method for flavor evaluation" and "Evaluation criteria for flavor evaluation" in Study 1.
■表3
・牛乳は、株式会社明治の「おいしい牛乳」(登録商標)を用いた。
・コーヒーエキスは、高砂香料工業株式会社の「コーヒーエキスBRA-19」を用いた。
・脱脂粉乳は、よつ葉乳業株式会社製を用いた。
・乳化剤は、三菱ケミカル株式会社の「CP-Y040」を用いた。
・pH調整剤は、キシダ化学株式会社の重曹を用いた。
・非糖質系甘味料Aは、守田化学工業株式会社のステビア抽出物である、「ステビロンSG」(甘味度200)を用いた。
■Table 3
- The milk used was Meiji Co., Ltd.'s "Oishii Gyunyu" (registered trademark).
The coffee extract used was "Coffee Extract BRA-19" from Takasago International Corporation.
- Skim milk powder manufactured by Yotsuba Dairy Co., Ltd. was used.
The emulsifier used was "CP-Y040" manufactured by Mitsubishi Chemical Corporation.
The pH adjuster used was baking soda from Kishida Chemical Co., Ltd.
- Non-sugar sweetener A was "Steviron SG" (sweetness level 200), a stevia extract from Morita Chemical Industry Co., Ltd.
■検討2の考察
表3の結果より、加工油脂実施例2又は同実施例3と、非糖質系甘味料A(ステビア抽出物)を含有する飲料において、飲料中の加工油脂の含有量が0.01重量%以上である場合、非糖質系甘味料に由来する異味を低減させることができた。
■Discussion of Study 2 The results in Table 3 show that in beverages containing processed oil/fat Example 2 or Example 3 and non-sugar sweetener A (stevia extract), when the content of processed oil/fat in the beverage is 0.01% by weight or more, the unpleasant taste caused by the non-sugar sweetener could be reduced.
■検討3 飲料に含まれる非糖質系甘味料の種類
表4-1~表4-3の配合に従い、検討1と同様の手順で、各種非糖質系甘味料を含むカフェラテを製造し、加工油脂有無による効果を検証した。各種非糖質系甘味料の配合率は、製品甘味度を参考に調整した。
製造したカフェラテは、検討1の「風味評価の方法」及び「風味評価の評価基準」に従い、風味評価を行った。
この際に、前記非糖質系甘味料の甘味度をS、前記飲料に占める前記非糖質系甘味料の含有量をx重量%、前記飲料に占める前記加工油脂の含有量をy重量%とする場合、S、x、yの関係が下記式(1)に適合するか検証した。
S×x/10000+0.004≦ y ≦S×x/1000+1 ・・・(1)
風味評価の結果、及び式(1)の検証結果について、表4-1~表4-3に示した。各試験区が式(1)を満たす場合は、適合性を「○」とし、式(1)を満たさない場合は、適合性を「×」とした。
■ Study 3: Types of non-sugar sweeteners contained in beverages According to the formulations in Tables 4-1 to 4-3, cafe lattes containing various non-sugar sweeteners were produced using the same procedures as in Study 1, and the effects of the presence or absence of processed fats and oils were examined. The blending ratios of the various non-sugar sweeteners were adjusted based on the sweetness of the product.
The produced cafe latte was subjected to a flavor evaluation in accordance with the "Method for flavor evaluation" and "Evaluation criteria for flavor evaluation" in Study 1.
In this case, when the sweetness of the non-sugar sweetener is S, the content of the non-sugar sweetener in the beverage is x% by weight, and the content of the processed oil or fat in the beverage is y% by weight, we verified whether the relationship between S, x, and y conforms to the following formula (1).
S×x/10000+0.004≦y≦S×x/1000+1 ・・・(1)
The results of the flavor evaluation and the verification results of formula (1) are shown in Tables 4-1 to 4-3. When each test plot satisfied formula (1), the suitability was marked as "○", and when formula (1) was not satisfied, the suitability was marked as "×".
■表4-1
・非糖質系甘味料Bは、日本製紙株式会社の酵素処理ステビアである、「ステビアフィンH」(甘味度200)を用いた。
・非糖質系甘味料Cは、日本製紙株式会社の酵素処理ステビアである、「ステビアフィンHN5-J」(甘味度200)を用いた。
■Table 4-1
- Non-sugar sweetener B was "Steviafin H" (sweetness level 200), an enzyme-treated stevia from Nippon Paper Industries Co., Ltd.
Non-sugar sweetener C was "Steviafin HN5-J" (sweetness level 200), an enzyme-treated stevia from Nippon Paper Industries Co., Ltd.
■表4-2
・非糖質系甘味料Dは、池田糖化工業株式会社の酵素処理ステビアである、「ハイステビアM-K」(甘味度200)を用いた。
・非糖質系甘味料Eは、三菱商事ライフサイエンス株式会社のアセスルファムカリウムである、「サネット」(甘味度200)を用いた。
・非糖質系甘味料Fは、三栄源エフ・エフ・アイ株式会社のラカンカ抽出物である、「サンナチュレM30」(甘味度150)を用いた。
■Table 4-2
- Non-sugar sweetener D was "Histevia MK" (sweetness level 200), an enzyme-treated stevia from Ikeda Tohka Kogyo Co., Ltd.
- Non-sugar sweetener E was "Sunet" (sweetness level 200), which is acesulfame potassium from Mitsubishi Corporation Life Sciences Co., Ltd.
- The non-sugar sweetener F used was "Sunnature M30" (sweetness level 150), a Luo Han Guo extract from San-Ei Gen F.F.I. Co., Ltd.
■表4-3
・非糖質系甘味料Gは、三栄源エフ・エフ・アイ株式会社のスクラロース(甘味度600)を用いた。
・非糖質系甘味料Hは、三栄源エフ・エフ・アイ株式会社のソーチマン製剤である、「ネオサンマルクAG」(甘味度4.5)を用いた。
・非糖質系甘味料Iは、三栄源エフ・エフ・アイ株式会社のアドバンテーム製剤である、「スイートアップV-30」(甘味度30)を用いた。
■Table 4-3
- Non-sugar sweetener G was sucralose (sweetness level 600) manufactured by San-Ei Gen F.F.I. Co., Ltd.
- The non-sugar sweetener H used was "Neo Sanmarc AG" (sweetness level 4.5), a Sauerman formulation from San-Ei Gen F.F.I. Co., Ltd.
- Non-sugar sweetener I was "Sweet Up V-30" (sweetness level 30), an Advantame preparation from San-Ei Gen F.F.I. Co., Ltd.
■検討3の考察
表4-1~表4-3の結果より、幅広い種類の非糖質系甘味料を含有する飲料においても、加工油脂実施例2と同様に、非糖質系甘味料に由来する異味を低減させる効果が得られた。
前記非糖質系甘味料の甘味度をS、前記飲料に占める前記非糖質系甘味料の含有量をx重量%、前記飲料に占める前記加工油脂の含有量をy重量%とする場合、実施例に相当する試験区では、S、x、yの関係は前記式(1)に適合するものであり、比較例に相当する試験区では、S、x、yの関係は前記式(1)に適合せず、非糖質系甘味料に由来する異味の低減効果が観察されなかった。前記式(1)への適当性と、非糖質系甘味料に由来する異味の低減効果には相関がみられた。
■Discussion of Study 3 The results of Tables 4-1 to 4-3 show that, similar to processed oil and fat Example 2, the effect of reducing the unpleasant taste caused by non-sugar sweeteners was achieved even in beverages containing a wide variety of non-sugar sweeteners.
When the sweetness of the non-sugar sweetener is S, the content of the non-sugar sweetener in the beverage is x% by weight, and the content of the processed oil or fat in the beverage is y% by weight, in the test plots corresponding to the Examples, the relationship between S, x, and y conforms to the above formula (1), whereas in the test plots corresponding to the Comparative Examples, the relationship between S, x, and y does not conform to the above formula (1), and no reduction effect of off-tastes derived from non-sugar sweeteners was observed. A correlation was observed between suitability for the formula (1) and the effect of reducing off-tastes derived from non-sugar sweeteners.
■検討4 ほうじ茶ラテによる効果の検証
表5の配合に従い、検討1と同様の手順で、非糖質系甘味料を含むほうじ茶ラテを製造し、加工油脂有無による効果を検証した。
製造したほうじ茶ラテは、検討1の「風味評価の方法」及び「風味評価の評価基準」に従い、風味評価を行った。
■Study 4: Verification of the effects of roasted green tea latte Using the formula in Table 5 and the same procedure as in Study 1, roasted green tea latte containing a non-sugar sweetener was produced, and the effects of the presence or absence of processed fats and oils were verified.
The roasted green tea latte thus produced was subjected to a flavor evaluation in accordance with the "Method for flavor evaluation" and "Evaluation criteria for flavor evaluation" in Study 1.
■表5
・ほうじ茶パウダーは、株式会社あいやの「ほうじ茶パウダーFJ-DR」を用いた。
■Table 5
- The roasted green tea powder used was "Hojicha Powder FJ-DR" from AIYA Co., Ltd.
■検討5の考察
表5の結果より、検討3までで確認できた効果が、他の飲料であるほうじ茶ラテを製造した場合であっても確認できた。
■Discussion of Study 5 From the results in Table 5, the effects confirmed up to Study 3 were confirmed even when producing another beverage, roasted green tea latte.
■検討6 野菜ジュースによる効果の検証
表6の配合に従い、非糖質系甘味料を含む野菜ジュースを製造し、加工油脂有無による効果を検証した。
製造した野菜ジュースは、検討1の「風味評価の方法」及び「風味評価の評価基準」に従い、風味評価を行った。
■ Study 6: Verification of the effects of vegetable juice Vegetable juice containing non-sugar sweeteners was produced according to the formulation in Table 6, and the effects of the presence or absence of processed fats and oils were verified.
The produced vegetable juice was subjected to flavor evaluation in accordance with the "Method for flavor evaluation" and "Evaluation criteria for flavor evaluation" in Study 1.
■表6
・野菜ジュースは、カゴメ株式会社の「野菜生活100パープル(3倍濃縮)」を用いた。
■Table 6
- For the vegetable juice, Kagome Co., Ltd.'s "Vegetable Life 100 Purple (3x concentrated)" was used.
■検討6の考察
表6の結果より、検討3までで確認できた効果が、他の飲料である野菜ジュースを製造した場合であっても確認できた。
■Discussion of Study 6 From the results in Table 6, the effects confirmed up to Study 3 were confirmed even when producing another beverage, vegetable juice.
■検討7 清涼飲料水による効果の検証
表7の配合に従い、非糖質系甘味料を含む清涼飲料水を製造し、加工油脂有無による効果を検証した。
市販の清涼飲料水を60℃に温調し、非糖質系甘味料、加工油脂を加え、ミキサー等で撹拌し溶解させた。これを高圧ホモジナイザー等で均質化し、5℃に冷却し、清涼飲料水を製造した。
製造した清涼飲料水は、検討1の「風味評価の方法」及び「風味評価の評価基準」に従い、風味評価を行った。
■ Study 7 Verification of the effects of soft drinks Soft drinks containing non-sugar sweeteners were produced according to the formulation in Table 7, and the effects of the presence or absence of processed fats and oils were verified.
A commercially available soft drink was adjusted to a temperature of 60°C, and a non-sugar sweetener and processed oil and fat were added and dissolved by stirring using a mixer, etc. The mixture was then homogenized using a high-pressure homogenizer, etc., and cooled to 5°C to produce a soft drink.
The soft drinks produced were evaluated for flavor in accordance with the "Method for flavor evaluation" and "Evaluation criteria for flavor evaluation" in Study 1.
■表7
・清涼飲料水市販品は、日本コカ・コーラ株式会社の「アクエリアス」を用いた。
■Table 7
The commercially available soft drink used was "Aquarius" from Coca-Cola Japan Co., Ltd.
■検討7の考察
表7の結果より、検討3までで確認できた効果が、他の飲料である清涼飲料水を製造した場合であっても確認できた。
■Discussion of Study 7 From the results in Table 7, the effects confirmed up to Study 3 were confirmed even when producing a different type of beverage, a soft drink.
本発明により、非糖質系甘味料を少なくとも含有する飲料において、特定の加工油脂を含有させることにより、非糖質系甘味料に由来する異味を低減させた飲料を提供することができ、産業上極めて有用である。 By incorporating specific processed oils and fats into beverages that contain at least a non-sugar sweetener, the present invention can provide beverages that reduce the off-flavors associated with the non-sugar sweetener, making it extremely useful industrially.
Claims (7)
(A)ヨウ素価が125以下である
(B)トリグリセリド組成がランダム化されている
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である A processed oil or fat for use in a beverage containing at least a non-sugar sweetener, which satisfies all of the following requirements (A) to (C):
(A) The iodine value is 125 or less. (B) The triglyceride composition is randomized. (C) In the constituent fatty acid composition, the total content of palmitic acid and stearic acid is 10% by weight or more.
(A)ヨウ素価が125以下である
(B)ランダム化されたトリグリセリド組成を有する
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である A beverage containing at least a processed oil or fat that satisfies all of the following requirements (A) to (C) and a non-sugar sweetener.
(A) an iodine value of 125 or less; (B) a randomized triglyceride composition; and (C) a total content of palmitic acid and stearic acid in the constituent fatty acid composition of 10% by weight or more.
S×x/10000+0.004≦ y ≦S×x/1000+1 ・・・(1) A beverage according to claim 2 or claim 3, wherein when the sweetness of the non-carbohydrate sweetener is S and the content of the non-carbohydrate sweetener in the beverage is x% by weight, the content of the processed oil or fat in the beverage is y% by weight, and the content of the processed oil or fat in the beverage satisfies the following formula (1):
S×x/10000+0.004≦y≦S×x/1000+1 ・・・(1)
S×x/10000+0.004≦ y ≦S×x/1000+1 ・・・(1) The beverage according to claim 4, wherein when the sweetness of the non-carbohydrate sweetener is S and the content of the non-carbohydrate sweetener in the beverage is x% by weight, the content of the processed oil/fat in the beverage is y% by weight, and the content of the processed oil/fat in the beverage satisfies the following formula (1):
S×x/10000+0.004≦y≦S×x/1000+1 ・・・(1)
(A)ヨウ素価が125以下である
(B)トリグリセリド組成がランダム化されている
(C)構成脂肪酸組成中、パルミチン酸とステアリン酸の含有量の合計が10重量%以上である A method for reducing the unpleasant taste caused by a non-sugar sweetener in a beverage by adding processed oils and fats that satisfy all of the following requirements (A) to (C) to the beverage containing at least the non-sugar sweetener.
(A) The iodine value is 125 or less. (B) The triglyceride composition is randomized. (C) In the constituent fatty acid composition, the total content of palmitic acid and stearic acid is 10% by weight or more.
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