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WO2025137920A1 - Composition de maquillage de matières kératiniques - Google Patents

Composition de maquillage de matières kératiniques Download PDF

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Publication number
WO2025137920A1
WO2025137920A1 PCT/CN2023/142306 CN2023142306W WO2025137920A1 WO 2025137920 A1 WO2025137920 A1 WO 2025137920A1 CN 2023142306 W CN2023142306 W CN 2023142306W WO 2025137920 A1 WO2025137920 A1 WO 2025137920A1
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WO
WIPO (PCT)
Prior art keywords
composition
glycol
present
mixtures
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/CN2023/142306
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English (en)
Inventor
Yujie Zhao
Xin Wei YU
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Priority to PCT/CN2023/142306 priority Critical patent/WO2025137920A1/fr
Priority to FR2401536A priority patent/FR3157809A3/fr
Publication of WO2025137920A1 publication Critical patent/WO2025137920A1/fr
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/732Starch; Amylose; Amylopectin; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone

Definitions

  • the present invention relates to a composition.
  • the present invention relates to a composition for making up keratin materials.
  • the present invention also relates to a process for making up keratin materials.
  • the skin is not a smooth surface of uniform color, and has reliefs or at least micro-reliefs such as pores, wrinkles, fine lines, spots, scars and dry areas, which form a somewhat bumpy surface. Further, the complexion is not always satisfactory, e.g., a dull appearance.
  • Cosmetic compositions for example foundations, are commonly used to give the skin an esthetic color, and also to enhance the beauty of irregular skin, by making it possible to hide marks and dyschromia, to reduce the visibility of relief imperfections, such as pores and wrinkles, and to conceal spots and acne marks.
  • composition which can simultaneously provide a long wearing makeup effect and desirable freshness and affinity effects, and is stable over a long period of time and a wide temperature range for storage and use.
  • composition according to the present invention The inventors have found that such a need can be achieved by the composition according to the present invention.
  • the present invention provides a composition, preferably for making up keratin materials, comprising:
  • composition according to the present invention can simultaneously provide a long wearing makeup effect and desirable freshness and affinity effects, and is stable over a long period of time and a wide temperature range for storage and use.
  • the present invention provides a process for making up keratin materials, preferably the skin, comprising:
  • the term “resin” is intended to mean a compound of which the structure is three-dimensional.
  • the letter “M” represents the monofunctional unit of formula R 1 R 2 R 3 SiO 1/2 , the silicon atom being bonded to only one oxygen atom in the polymer comprising this unit, R 1 , R 2 , and R 3 , independently of each other, represents a hydrocarbon-based group containing from 1 to 10 carbon atoms; and the letter “Q” means a tetrafunctional unit SiO 4/2 in which the silicon atom is bonded to four oxygen atoms, which are themselves bonded to the rest of the polymer.
  • the fatty acid ester of dextrin corresponds to formula (II) :
  • R 1 , R 2 and R 3 independently of each other, are chosen from hydrogen or an acyl (R-CO-) in which R is a linear or branched, saturated or unsaturated hydrocarbon-based group containing from 6 to 30, preferably from 8 to 22, more preferably from 12 to 18 carbon atoms, with the proviso that at least one of said R 1 , R 2 or R 3 is other than hydrogen, n is between 3 and 150, preferably between 10 and 100 and more preferably between 15 to 40.
  • R-CO- acyl
  • the dextrin ester is chosen from dextrin palmitate, dextrin myristate, and mixtures thereof. Some of these dextrin esters are commercially available, notably under the name Rheopearl from the company Chiba Flour Milling.
  • the dextrin ester is dextrin palmitate.
  • This product may be chosen, for example, from those sold under the names TL, KL and KL2-OR by the company Chiba Flour Milling, and mixtures thereof.
  • composition according to the present invention comprises at least one hydrophobic silica.
  • the amorphous hydrophobic silicas of fumed origin are obtained from hydrophilic silicas.
  • the latter are obtained by pyrolysis of silicon tetrachloride (SiCl 4 ) in a continuous flame at 1000°Cin the presence of hydrogen and oxygen. They are subsequently rendered hydrophobic by treatment with halogenated silanes, alkoxysilanes or silazanes.
  • the hydrophobic silicas differ from the starting hydrophilic silicas, inter alia, in a lower density of silanol and in a smaller adsorption of water vapor.
  • the hydrophobic silica used in the composition of the invention can also consist of a particle completely or partially covered with silica, in particular of an inorganic particle completely or partially covered with hydrophobic silica, such as pigments and metal oxides covered with hydrophobic silica.
  • hydrophobic silica of a hydrophobic fumed silica treated at the surface with a dimethylsiloxane, such as that sold under the name Aerosil R972 (INCI name: Silica Dimethyl Silylate) by Evonik Degussa.
  • the hydrophobic silica which can be used in the composition of the invention are aerogel particles of hydrophobic silica exhibiting a specific surface per unit of weight (SW) ranging from 500 to 1500 m 2 /g and a size, expressed as volume-average diameter (D [0.5] , also known as median particle size by volume Dv50) , ranging from 1 to 1500 ⁇ m.
  • SW specific surface per unit of weight
  • D [0.5] volume-average diameter
  • Dv50 median particle size by volume Dv50
  • Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air.
  • the aerogel particles of hydrophobic silica used in the present invention exhibit a specific surface per unit of weight (SW) ranging from 500 to 1500 m 2 /g, preferably from 600 to 1200 m 2 /g and more preferably from 600 to 800 m 2 /g, and a size, expressed as volume-average diameter (D [0.5] , also known as median particle size by volume Dv50) , ranging from 1 to 1500 ⁇ m, preferably from 1 to 1000 ⁇ m, more preferably from 1 to 100 ⁇ m, more preferably from 1 to 30 ⁇ m, still more preferably from 5 to 25 ⁇ m, even more preferably from 5 to 20 ⁇ m and most preferably from 5 to 15 ⁇ m.
  • SW specific surface per unit of weight
  • the aerogel particles of hydrophobic silica used in the present invention exhibit a size, expressed as volume-average diameter (D [0.5] , also known as median particle size by volume Dv50) , ranging from 1 to 30 ⁇ m, preferably from 5 to 25 ⁇ m, more preferably from 5 to 20 ⁇ m and even more preferably from 5 to 15 ⁇ m.
  • D [0.5] volume-average diameter
  • Dv50 median particle size by volume
  • the aerogel particles of hydrophobic silica used in the present invention exhibit a specific surface per unit of weight (SW) ranging from 600 to 800 m 2 /g and a size, expressed as volume-average diameter (D [0.5] , also known as median particle size by volume Dv50) , ranging from 5 to 20 ⁇ m and preferably from 5 to 15 ⁇ m.
  • SW specific surface per unit of weight
  • D [0.5] volume-average diameter
  • Dv50 volume-average diameter
  • the aerogel silica particles used in the present invention can advantageously exhibit a packed density ( ⁇ ) ranging from 0.04 g/cm 3 to 0.10 g/cm 3 and preferably from 0.05 g/cm 3 to 0.08 g/cm 3 .
  • the aerogel particles of hydrophobic silica according to the invention have an oil absorption capacity, measured at the wet point, ranging from 5 to 18 ml/g, preferably from 6 to 15 ml/g and more preferably from 8 to 12ml/g.
  • the absorption capacity measured at the wet point corresponds to the amount of oil which it is necessary to add to 100 g of particles in order to obtain a homogeneous paste.
  • the oil uptake corresponds to the ratio g/g.
  • the aerogels used according to the present invention are hydrophobic silica aerogels, preferably of silylated silica (INCI name: silica silylate) .
  • hydrophobic silica is understood to mean any silica whose surface is treated with silylating agents, for example with halogenated silanes, such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes, such as hexamethyldisiloxane, or silazanes, so as to functionalize the OH with silyl Si-R n , for example trimethylsilyl.
  • silylating agents for example with halogenated silanes, such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes, such as hexamethyldisiloxane, or silazanes
  • the hydrophobic silica used in the composition of the invention is aerogel particles of hydrophobic silica modified at the surface with trimethylsilyl (trimethylsiloxylated silica) .
  • hydrophobic silica aerogels which can be used in the invention, for example, of the aerogel sold under the name VM-2260 (INCI name: silica silylate) by Dow Corning, the particles of which exhibit an average size of approximately 1000 ⁇ m and a specific surface per unit of weight ranging from 600 to 800 m 2 /g.
  • Aerogel TLD 201 Mention may also be made of the aerogels sold by Cabot under the references Aerogel TLD 201, Aerogel OGD 201 and Aerogel TLD 203.
  • two or more pigments coated with isopropyl titanium triisostearate may be used in combination.
  • a single type of pigment coated with isopropyl titanium triisostearate or a combination of different types of pigments coated with isopropyl titanium triisostearate may be used.
  • pigments means white or colored, mineral or organic particles, which are insoluble in an aqueous medium, and which are intended to color and/or opacify the resulting composition.
  • the pigments used in the present invention are chosen from mineral pigments.
  • mineral pigment means any inorganic pigment.
  • the mineral pigments that are useful in the present invention are selected from metal oxides, such as zirconium oxides or cerium oxides, titanium oxides and also zinc oxides, iron oxides (black, yellow or red) or chromium oxides, as well as manganese violet, ultramarine blue, chromium hydrate and ferric blue, and metal powders, for instance aluminum powders or copper powders, or any combinations thereof.
  • the following mineral pigments may also be used: Ta 2 O 5 , Ti 3 O 5 , Ti 2 O 3 , TiO 2 , ZrO 2 as a mixture with TiO 2 , ZrO 2 , Nb 2 O 5 , CeO 2 , or ZnS.
  • the mineral pigments are more preferably iron oxides and/or titanium dioxide.
  • the pigments may also be nacres and/or particles with metallic glints.
  • nacres should be understood as meaning iridescent or non-iridescent colored particles of any shape, especially produced by certain molluscs in their shell or alternatively synthesized, which have a color effect via optical interference.
  • the pigments in the present invention are coated with isopropyl titanium triisostearate, i.e., the surface of the pigments is treated with isopropyl titanium triisostearate.
  • the surface-treated pigments may be prepared according to surface treatment techniques of chemical, electronic, mechanochemical or mechanical nature that are well known to those skilled in the art. Commercial products may also be used.
  • the surface agent of isopropyl titanium triisostearate may be absorbed, adsorbed or grafted onto the surface of the pigments by evaporation of solvent, chemical reaction and creation of a covalent bond.
  • the surface treatment with isopropyl titanium triisostearate gives the pigments a hydrophobic character. Therefore, the pigment coated with isopropyl titanium triisostearate of the present invention exhibits a hydrophobic and lipophilic nature. Accordingly, the pigment coated with isopropyl titanium triisostearate can be dispersed and included in the oily phase of the composition according to the present invention.
  • the pigment coated with isopropyl titanium triisostearate is selected from titanium dioxide coated with isopropyl titanium triisostearate, iron oxide coated with isopropyl titanium triisostearate, and a mixture thereof.
  • the titanium dioxide coated with isopropyl titanium triisostearate may be sold, for example, under the reference TIO2 CR-50 I2 by the company KOBO
  • the iron oxide coated with isopropyl titanium triisostearate may be sold, for example, under the reference BBO-HP-I2 by the company KOBO.
  • the pigment coated with isopropyl titanium triisostearate is present in an amount ranging from 0.1 wt. %to 20 wt. %, preferably from 1 wt. %to 15 wt. %, and more preferably from 4 wt. %to 10 wt. %, relative to the total weight of the composition.
  • the ester oils according to the present invention may be selected from monoesters, diesters, triesters, tetraesters and polyesters, and mixtures thereof, and preferably monoesters.
  • At least one from among the alcohol and the acid from which the esters of the present invention are derived is branched.
  • the ester oils are derived from one or more C 12 -C 22 fatty alcohol (s) and one or more C 2 -C 8 fatty acid (s) .
  • the ester oils are monoesters derived from a C 12 -C 22 fatty alcohol and a C 2 -C 8 fatty acid. Even more preferably, the ester oils are monoesters derived from a C 12 -C 22 saturated fatty alcohol and a C 2 -C 8 saturated fatty acid, at least one of the alcohols and the acid from which the esters oils are derived being branched.
  • ester oils include, but are not limited to, 2-ethylhexyl isononanoate, isononyl isononanoate, isodecyl neopentanoate, isostearyl neopentanoate, bis (2-ethylhexyl) sebacate, dioctyl adipate, bis (2-ethylhexyl) adipate, diisostearyl adipate, bis (2-ethylhexyl) maleate, triisocetyl citrate, triisostearyl citrate, trioctyldodecyl citrate, trioleyl citrate, 2-ethylhexyl hexanoate, cetyl octanoate, cetyl ethylhexanoate, octyldodecyl octanoate, myristyl propionate, 2-ethylhexy
  • preferable examples include isodecyl neopentanoate, isostearyl neopentanoate, diisostearyl adipate, triisocetyl citrate, triisostearyl citrate, trioctyldodecyl citrate, trioleyl citrate, cetyl octanoate, cetyl ethylhexanoate, octyldodecyl octanoate, myristyl propionate, isostearyl lactate, and octyldodecyl lactate, and a more preferable example is cetyl ethylhexanoate.
  • Hydrocarbon oils may be chosen from:
  • C 6 -C 16 alkanes examples include hexane, undecane, dodecane, tridecane, and isoparaffins, for instance isohexadecane, isododecane and isodecane; and
  • hydrocarbon oils As preferable examples of hydrocarbon oils, mention may be made of, for example, linear or branched hydrocarbons such as isohexadecane, isododecane, squalane, mineral oil (e.g., liquid paraffin) , and vaseline or petrolatum; hydrogenated polyisobutene, isoeicosane, and decene/butene copolymer; and mixtures thereof.
  • linear or branched hydrocarbons such as isohexadecane, isododecane, squalane, mineral oil (e.g., liquid paraffin) , and vaseline or petrolatum; hydrogenated polyisobutene, isoeicosane, and decene/butene copolymer; and mixtures thereof.
  • silicon oil means an oil comprising at least one silicon atom, and especially at least one Si-O, and more particularly an organopolysiloxane.
  • At least one pigment coated with isopropyl titanium triisostearate selected from titanium dioxide coated with isopropyl titanium triisostearate, iron oxide coated with isopropyl titanium triisostearate, and a mixture thereof;
  • composition according to the present invention can provide a long wearing makeup effect and desirable affinity and freshness effects after application.
  • composition according to the invention may be applied by any means enabling a uniform distribution, in particular using a finger, a palm, a cotton ball, or a puff.
  • the present invention relates to a process for making up keratin material, preferably the skin, comprising applying the above composition onto the keratin materials.
  • compositions were prepared from a process comprising the following steps:
  • Each composition of Inventive Example 1 and Comparative Examples 1-3 was left for two weeks at room temperature and 45°C respectively, and the appearance of each composition was then visually observed. If there is no phase separation and no demulsification of a composition at room temperature and 45°C respectively, it is deemed as stable; and if there is at least partial oily phase separated from water phase and/or demulsification of a composition at either room temperature or 45°C, it is deemed as unstable.
  • a foundation film with a thickness of 150 ⁇ m was prepared using BYK (Byko Drive XL) and a mould (Elcometer, 3540) on a contrast card (Erichsen, Type 24/5) , and was rested at 32 °C for 6h hour and then weighted to obtain the Mw (0) , the 2 kg weight with the plastic plate was disposed on the foundation film and rested for 10 seconds, during which the plastic plate directly contacted the foundation film; the contrast card with non-transferred composition was weighed to obtain Mw (6h) ;
  • the wearing makeup effect was evaluated by the weight loss of the foundation film after being placed for half an hour and six hours respectively. The less weight loss of the foundation composition, the better of the wearing makeup effect, and vice versa. When the weight loss (0.5h) ⁇ 0.1g or weight loss (6h) ⁇ 0.05g, the composition is deemed as one with long wear makeup effect.
  • each panelist was invited to evaluate the freshness effect. Specifically, each panelist applied the composition of Inventive Example 1 on face with the same and daily amount, and then gave scores (1 to 5) . The higher of the score, the better of the freshness effect, and vice versa. For the composition of Inventive Example 1, the final scores were averaged and ranked according to the following criteria:
  • composition of Inventive Example 1 comprising an MQ resin, at least 1 wt. %of an organic lipophilic gelling agent, relative to the total weight of the composition, and a hydrophobic silica, can simultaneously obtain a long wearing makeup effect and desirable freshness and affinity effects, and is stable over a long period of time, e.g., two weeks, and a wide temperature range, e.g., room temperature and 45°C.
  • composition according to the present invention can simultaneously provide a long wearing makeup effect and desirable freshness and affinity effects, and is stable over a long period of time and a wide temperature range for storage and use.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition de maquillage de matières kératiniques, comprenant : (a) au moins une résine MQ ; (b) au moins 1% en poids d'au moins un agent gélifiant lipophile organique, par rapport au poids total de la composition ; et (c) au moins une silice hydrophobe.
PCT/CN2023/142306 2023-12-27 2023-12-27 Composition de maquillage de matières kératiniques Pending WO2025137920A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/CN2023/142306 WO2025137920A1 (fr) 2023-12-27 2023-12-27 Composition de maquillage de matières kératiniques
FR2401536A FR3157809A3 (fr) 2023-12-27 2024-02-16 composition pour le maquillage de matières kératineuses

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2023/142306 WO2025137920A1 (fr) 2023-12-27 2023-12-27 Composition de maquillage de matières kératiniques

Publications (1)

Publication Number Publication Date
WO2025137920A1 true WO2025137920A1 (fr) 2025-07-03

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Application Number Title Priority Date Filing Date
PCT/CN2023/142306 Pending WO2025137920A1 (fr) 2023-12-27 2023-12-27 Composition de maquillage de matières kératiniques

Country Status (2)

Country Link
FR (1) FR3157809A3 (fr)
WO (1) WO2025137920A1 (fr)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3045334A1 (fr) * 2015-12-17 2017-06-23 Oreal Composition de type gel/gel a base de pigments enrobes hydrophobes et d'un acide gras liquide
CN107041851A (zh) * 2016-12-23 2017-08-15 广州智媛生物科技有限公司 一种深肤色用的粉底组合物及其制备方法
CN108324595A (zh) * 2018-04-18 2018-07-27 上海中翊日化有限公司 一种具备调色功能的油包水型粉底液组合形式及其使用和制备方法
CN108601716A (zh) * 2015-12-17 2018-09-28 莱雅公司 基于涂有疏水性物质的颜料和液体脂肪酸和/或二醇化合物的凝胶/凝胶型组合物
FR3121600A1 (fr) * 2021-04-08 2022-10-14 L'oreal Compositions cosmétiques pour le perfectionnement de la peau et procédés d’utilisation
CN115551597A (zh) * 2020-06-29 2022-12-30 莱雅公司 包含涂有三异硬脂酸钛酸异丙酯的颜料的组合物
JP2023097497A (ja) * 2021-12-28 2023-07-10 株式会社コーセー 化粧料
CN117017812A (zh) * 2023-07-27 2023-11-10 科玛化妆品(无锡)有限公司 一种持久防水抗晕睫毛膏及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5330747A (en) 1993-02-03 1994-07-19 Dow Corning Corporation Cosmetics with enhanced durability
DE19603357B4 (de) 1995-02-10 2004-09-23 General Electric Co. Siloxysilicatharze geringer Viskosität mit organischen, funktionellen Gruppen
DE19648798C2 (de) 1996-11-26 1998-11-19 Hoechst Ag Verfahren zur Herstellung von organisch modifizierten Aerogelen durch Oberflächenmodifikation des wäßrigen Gels (ohne vorherigen Lösungsmitteltausch) und anschließender Trocknung

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3045334A1 (fr) * 2015-12-17 2017-06-23 Oreal Composition de type gel/gel a base de pigments enrobes hydrophobes et d'un acide gras liquide
CN108601716A (zh) * 2015-12-17 2018-09-28 莱雅公司 基于涂有疏水性物质的颜料和液体脂肪酸和/或二醇化合物的凝胶/凝胶型组合物
CN107041851A (zh) * 2016-12-23 2017-08-15 广州智媛生物科技有限公司 一种深肤色用的粉底组合物及其制备方法
CN108324595A (zh) * 2018-04-18 2018-07-27 上海中翊日化有限公司 一种具备调色功能的油包水型粉底液组合形式及其使用和制备方法
CN115551597A (zh) * 2020-06-29 2022-12-30 莱雅公司 包含涂有三异硬脂酸钛酸异丙酯的颜料的组合物
FR3121600A1 (fr) * 2021-04-08 2022-10-14 L'oreal Compositions cosmétiques pour le perfectionnement de la peau et procédés d’utilisation
JP2023097497A (ja) * 2021-12-28 2023-07-10 株式会社コーセー 化粧料
CN117017812A (zh) * 2023-07-27 2023-11-10 科玛化妆品(无锡)有限公司 一种持久防水抗晕睫毛膏及其制备方法

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