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WO2025192422A1 - Method for manufacturing power storage device - Google Patents

Method for manufacturing power storage device

Info

Publication number
WO2025192422A1
WO2025192422A1 PCT/JP2025/008201 JP2025008201W WO2025192422A1 WO 2025192422 A1 WO2025192422 A1 WO 2025192422A1 JP 2025008201 W JP2025008201 W JP 2025008201W WO 2025192422 A1 WO2025192422 A1 WO 2025192422A1
Authority
WO
WIPO (PCT)
Prior art keywords
storage device
component unit
active material
continuum
energy storage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/JP2025/008201
Other languages
French (fr)
Japanese (ja)
Inventor
良一 奥山
一弥 岡部
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GS Yuasa International Ltd
Original Assignee
GS Yuasa International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GS Yuasa International Ltd filed Critical GS Yuasa International Ltd
Publication of WO2025192422A1 publication Critical patent/WO2025192422A1/en
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0585Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to a method for manufacturing an electricity storage device.
  • Patent Document 1 discloses a method for manufacturing an energy storage device that includes the steps of forming a first electrode unit with a convex portion formed on one surface of a first frame, forming a second electrode unit with a concave portion formed on the other surface of a second frame, and stacking the second electrode unit on the first electrode unit to prevent the stacking positions of the current collectors, separators, etc. from shifting from their correct positions during the stacking process for secondary batteries having a structure in which current collectors and separators are alternately stacked, and in which the convex portion of the first frame engages with the concave portion of the second frame during the stacking process.
  • Patent Document 1 In the manufacturing method for an energy storage device disclosed in Patent Document 1, convex portions are formed on the first frame and concave portions are formed on the second frame, and the convex portions of the first frame and the concave portions of the second frame are engaged to align them.
  • Patent Document 1 exemplifies the thickness of the active material layer as 2 to 150 ⁇ m and the thickness of the current collector foil as 1 to 100 ⁇ m. Based on this, the cross-sectional thickness of the spacer portion including the convex portions and concave portions needs to be approximately 5 to 400 ⁇ m, which is the sum of the combined thickness of the positive and negative electrode active material layers (4 to 300 ⁇ m) and the current collector foil thickness (1 to 100 ⁇ m).
  • the convex portions and concave portions of the engaging portion are smaller than the thickness of the spacer portion, high-precision and fine manufacturing techniques are required, and this method may not be easy to use to construct an energy storage device.
  • Engaging the first frame and second frame may be particularly difficult when the electrode unit is large (e.g., approximately 1 m square).
  • the present invention was made by the inventors by focusing on the above-mentioned problem, and aims to provide a method for manufacturing an electricity storage device that allows for easy production of an electricity storage device.
  • a manufacturing method for an energy storage device is a manufacturing method for an energy storage device having a plurality of component units stacked in a stacking direction, and includes arranging a component unit continuum in which the plurality of component units are connected by connecting portions, folding the component unit continuum at the positions of the connecting portions, and removing the connecting portions after folding the component unit continuum.
  • the method for manufacturing an electricity storage device according to the present invention makes it easy to manufacture an electricity storage device.
  • FIG. 5B is a plan view illustrating a step of arranging a separator continuous body in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 6 is a perspective view showing the configuration of a frame member used in the step of folding the member unit continuous body in the manufacturing method for the electricity storage device according to the embodiment.
  • FIG. 7A is a plan view illustrating a step of folding the member unit continuous body (after the fourth step) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 7B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the fourth step) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 8A is a plan view illustrating a step of folding the member unit continuous body (after the fifth step) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 8B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the fifth step) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 9A is a plan view illustrating a step of folding the member unit continuous body (again after completion of the third step) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 9B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the third step is completed again) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 10A is a plan view illustrating a step of folding the member unit continuous body (after the fourth step is completed again) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 10B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the fourth step is completed again) in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 11 is a perspective view showing a step of folding the member unit continuous body in the manufacturing method for the energy storage device according to the embodiment.
  • FIG. 12 is a cross-sectional view showing a step of cutting off the connection portion in the manufacturing method for the electricity storage device according to the embodiment.
  • FIG. 13A is a plan view showing the configuration of a member unit continuum according to a first modified example of the embodiment.
  • FIG. 13B is a plan view showing the configuration of the member unit continuum according to the first modification of the embodiment.
  • FIG. 14A is a plan view showing the configuration of a member unit continuum according to a second modification of the embodiment.
  • FIG. 14B is a plan view showing the configuration of a member unit continuum according to the second modification of the embodiment.
  • FIG. 15A is a plan view illustrating a step of folding a member unit continuum in a manufacturing method for an energy storage device according to a second modification of the embodiment.
  • FIG. 15B is a cross-sectional view illustrating a step of folding the member unit continuous body in the manufacturing method for an energy storage device according to the second modification of the embodiment.
  • FIG. 16 is a cross-sectional view illustrating a step of folding the member unit continuous body in a manufacturing method for an energy storage device according to a second modification of the embodiment.
  • FIG. 17 is a cross-sectional view illustrating a step of cutting off the connection portion in a manufacturing method for an electricity storage device according to the second modification of the embodiment.
  • FIG. 18 is a plan view showing the configuration of a member unit continuum according to the third modification of the embodiment.
  • FIG. 19 is a cross-sectional view illustrating a step of cutting off the connection portions after folding the member unit continuous body in a manufacturing method for an electricity storage device according to a third modified example of the embodiment.
  • FIG. 20A is a plan view showing the configuration of a member unit continuum according to a fourth modified example of the embodiment.
  • FIG. 20B is a plan view showing the configuration of a member unit continuum according to the fourth modification of the embodiment.
  • FIG. 21 is a cross-sectional view illustrating a step of cutting off the connection portions after folding the member unit continuous body in a manufacturing method for an electricity storage device according to the fourth modification of the embodiment.
  • FIG. 22 is a plan view showing the configuration of the electricity storage pack.
  • FIG. 23 is a cross-sectional view showing the configuration of the electricity storage pack.
  • FIG. 24 is a cross-sectional view showing the configuration of the electricity storage pack.
  • a manufacturing method for an energy storage device is a manufacturing method for an energy storage device including a plurality of component units stacked in a stacking direction, and includes arranging a component unit continuum in which the plurality of component units are connected by connecting portions, folding the component unit continuum at the positions of the connecting portions, and removing the connecting portions after folding the component unit continuum.
  • a method for manufacturing an electricity storage device involves preparing a component unit series in which multiple component units are connected by connecting parts, folding the component unit series at the positions of the connecting parts, and then removing the connecting parts.
  • folding the component unit series in which multiple component units are connected by connecting parts at the positions of the connecting parts multiple component units can be easily positioned and stacked.
  • removing the connecting parts after folding the component unit series it becomes possible to stack the component units in the appropriate positions, making it easy to manufacture an electricity storage device.
  • removing a connection includes cutting off the connection, removing a connection that has been joined by adhesive or the like, etc.
  • the component units that make up the component unit continuum include electrode units, separators, end units, end members, sealing members, and components that combine the functions of multiple of these components (for example, electrode units with separators, electrode units with sealing members, etc.).
  • components such as intermediate foils that do not function as components of an electricity storage device on their own are also referred to as component units.
  • an electrode unit with a sealing member will be referred to as an electrode member unit.
  • an end unit in which a sealing member has already been placed on the active material layer forming surface will also be referred to as an end unit.
  • the type of member unit used to construct the energy storage device can be selected appropriately depending on the shape of the energy storage device to be manufactured, the shape of the frame member, the design of the energy storage device, productivity, etc.
  • At least a portion of the component unit continuum may have a positive electrode active material layer disposed on one side of the current collector foil and a negative electrode active material layer disposed on the other side of the current collector foil.
  • the method for manufacturing an electricity storage device described in (2) above makes it easy to manufacture an electricity storage device (bipolar battery) in which a positive electrode active material layer is disposed on one side of the current collector foil and a negative electrode active material layer is disposed on the other side of the current collector foil.
  • the component unit continuum may be such that a plurality of component units each having a polygonal or circular shape with an even number of sides of four or more as viewed from the stacking direction are connected at the connection portions.
  • a component unit continuum in which multiple component units are linearly connected by connectors can be used as the component unit continuum used in manufacturing the storage battery device. This makes it possible to supply the component unit continuum in roll form, thereby improving productivity during mass production.
  • the component unit continuum may be polygonal when viewed from the stacking direction, and the width of the connection portion may be shorter than the length of one side of the polygon.
  • the manufacturing method for a storage device described in (4) above produces a component unit continuum in which a connecting portion with a width shorter than the length of one side of a polygonal component unit is connected to that side.
  • shortening the width of the connecting portion increases the degree of freedom in aligning the component units, and improves the alignment accuracy of the component units.
  • shortening the width of the connecting portion and lengthening the connecting portion also makes it possible to invert the component unit continuum, and to stack the component units while inverting their top and bottom surfaces.
  • the member units when folding the member unit series, the member units may be inserted into a frame member and the connection portions may be folded to cause the connection portions to protrude from the frame member, and when removing the connection portions, the connection portions protruding from the frame member may be cut.
  • the component unit series can be folded while the frame member positions the component units. Furthermore, by making the connection portions protrude from the frame member, the connection portions can be easily cut. Furthermore, by cutting the connection portions protruding from the frame member, the connection portions can be cut outside the frame member, which prevents contamination from entering the component units inside the frame member when the connection portions are cut.
  • the thickness direction of the energy storage device is defined as the Z-axis direction.
  • Two different directions that intersect with the Z-axis direction are defined as the X-axis direction and the Y-axis direction.
  • the X-axis direction, Y-axis direction, and Z-axis direction are mutually perpendicular.
  • the Z-axis direction is not the up-down direction, but for ease of explanation, the following explanation will be made assuming that the Z-axis direction is the up-down direction.
  • the positive X-axis direction refers to the direction of the X-axis arrow
  • the negative X-axis direction refers to the direction opposite to the positive X-axis direction.
  • the X-axis direction refers to both or either of the positive X-axis direction and the negative X-axis direction.
  • the term "insulation” means "electrical insulation.” It is preferable that the insulating material be formed from a material with a volume resistivity of 1 ⁇ 10 6 ⁇ m or more, more preferably 1 ⁇ 10 7 ⁇ m or more, and even more preferably 1 ⁇ 10 10 ⁇ m or more.
  • FIG. 1 is a perspective view showing the exterior of the energy storage device 1 according to the present embodiment.
  • FIG. 2 is a cross-sectional view showing the internal configuration of the energy storage device 1 according to the present embodiment.
  • FIG. 2 is a cross-sectional view of the energy storage device 1 of FIG. 1 taken along the YZ plane passing through line II-II, and shows each component included in the energy storage device 1.
  • FIG. 3A is a perspective view showing the exterior of a component unit 10 which is an electrode unit 100 including a sealing member 210
  • FIG. 3B is a cross-sectional view of the component unit 10 of FIG. 3A taken along the YZ plane passing through line IIIB-IIIB.
  • the power storage device 1 is a device that can charge with electricity from an external source and discharge electricity to the outside.
  • the power storage device 1 has a roughly hexagonal prism shape.
  • the power storage device 1 is a bipolar battery.
  • the power storage device 1 is used as a battery for driving or starting the engine of mobile objects such as automobiles, motorcycles, watercraft, ships, snowmobiles, agricultural machinery, construction machinery, automatic guided vehicles (AGVs), or electric railway rolling stock.
  • Examples of the above-mentioned automobiles include electric vehicles (EVs), hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and fossil fuel (gasoline, diesel, liquefied natural gas, etc.) vehicles.
  • Examples of the above-mentioned electric railway rolling stock include electric trains, monorails, linear motor cars, and hybrid trains equipped with both a diesel engine and an electric motor.
  • the power storage device 1 can also be used as a stationary battery for home or business use.
  • the energy storage device 1 includes components such as an electrode unit 100, a sealing member 210, a separator 140, an end unit 101, an end unit 102, an end member 300, and an outer periphery sealing member 200.
  • Some of these components, such as the electrode unit 100, the sealing member 210, and the separator 140, are required in large quantities for one energy storage device 1, while others, such as the end units 101 and 102, the end member 300, and the outer periphery sealing member 200, are required in only one or two quantities for one energy storage device 1.
  • components that are required in large quantities for one energy storage device 1 are supplied continuously as a component unit continuum 10A, with the aim of facilitating production of the energy storage device 1 and improving productivity.
  • components that are required in only one or two quantities for one energy storage device 1 are manufactured using a single battery component pre-formed to a predetermined size.
  • the questions of whether they can be supplied as a component unit continuum 10A and how many types of component unit continuum 10A can be supplied as a continuum depend on the shape of the component unit 10. If the component unit 10 is a polygon with an even number of sides (four or more) or a circle, the component unit 10 can be supplied as a continuum, and the number of component unit 10 that can be supplied as a continuum is up to two types for squares, three types for hexagons, and four types for octagons. Furthermore, if the component unit 10 is circular, by reducing the width of the connection portion 12, it is possible to supply more component unit continuums 10A.
  • component unit 10 is hexagonal in shape
  • component unit continuum 10A up to three types of component unit continuum 10A can be supplied for hexagonal shapes, but in this embodiment, a case where two types of component unit 10 are used: (i) component unit continuum 10A, and (ii) separator continuum 140A will be described.
  • the component unit 10, end unit 101, and end unit 102 are hexagonal (regular hexagonal in this embodiment) plate-like structures in a planar view, and are stacked in the Z-axis direction.
  • planar view refers to a view from the stacking direction (Z-axis direction).
  • two component units 10 are illustrated stacked between end unit 101 and end unit 102, but the number of component units 10 stacked is not particularly limited.
  • Separators 140 are arranged between component units 10, between component unit 10 and end unit 101, and between component unit 10 and end unit 102.
  • a pair of end components 300 are arranged in the stacking direction (Z-axis direction), with end unit 101 in the negative Z-axis direction and end unit 102 in the positive Z-axis direction.
  • the stack 400 of component units 10 can be integrated by joining the sealing member 210. Furthermore, the periphery (outer periphery) of the stack 400 can be covered with the peripheral sealing member 200 to form the energy storage device 1.
  • the component unit 10 is a single component unit in which active material layers are formed on both sides of a single current collector foil 110, and a sealing member 210 is disposed around the outer periphery of the active material layer.
  • Each component unit 10 includes at least the current collector foil 110, a positive electrode active material layer 120 formed on one side of the current collector foil 110, a negative electrode active material layer 130 formed on the other side of the current collector foil 110, and a sealing member 210 around the outer periphery of the positive electrode active material layer 120 and the negative electrode active material layer 130.
  • the thickness (thickness in the stacking direction) of the component unit 10 is approximately 100 ⁇ m to 400 ⁇ m. Note that, for simplicity, the sealing member 210 around the outer periphery of the negative electrode active material layer 130 is omitted in Figure 3A.
  • the sealing members 210 are provided on the collector foil 110 around the outer periphery of the positive electrode active material layer 120 and negative electrode active material layer 130 of the collector foil 110.
  • the thickness of each sealing member 210 is approximately the same as the thickness of the adjacent positive electrode active material layer 120 and negative electrode active material layer 130. This means that if the thicknesses of the positive electrode active material layer 120 and the negative electrode active material layer 130 differ significantly, the thickness of the sealing members 210 adjacent to each active material must be different.
  • the component unit 10 has active material layers formed on both sides of a single collector foil 110, and further has sealing members 210 arranged around the outer periphery of the active material layers. This increases the strength of the component unit 10 compared to when the sealing members 210 are not provided, which has the effect of reducing sheet tearing during stacking.
  • the current collector foil 110 may be a clad material in which two metal foils are bonded together, or may comprise two metal foils that are connected (contacting) without being bonded to each other.
  • the positive electrode metal layer 111 is made of a metal such as aluminum, titanium, tantalum, or stainless steel, or an alloy thereof. Among these, aluminum or an aluminum alloy is preferred for the positive electrode metal layer 111, considering the balance between high potential resistance, high conductivity, and cost.
  • the positive electrode metal layer 111 may be in the form of a plated layer, but foil is preferred for ease of processing and cost. In other words, aluminum foil is preferred for the positive electrode metal layer 111.
  • the negative electrode metal layer 112 is made of a metal such as copper, nickel, stainless steel, or nickel-plated steel, or an alloy thereof, with copper or a copper alloy being preferred.
  • the negative electrode metal layer 112 may be made of a plated layer or foil (copper foil), and examples of copper foil include rolled copper foil and electrolytic copper foil.
  • the thickness (thickness in the stacking direction) of the current collector foil 110 is approximately 10 ⁇ m to 35 ⁇ m, and preferably approximately 20 ⁇ m to 30 ⁇ m.
  • the thickness of the positive electrode metal layer 111 (thickness in the stacking direction) is approximately 5 ⁇ m to 20 ⁇ m, and the thickness of the negative electrode metal layer 112 (thickness in the stacking direction) is approximately 5 ⁇ m to 15 ⁇ m.
  • the current collecting foil 110 may be formed of a single layer (one sheet of metal foil) instead of multiple layers (two layers) of the positive electrode metal layer 111 and the negative electrode metal layer 112.
  • the current collecting foil 110 may be formed of a material that can function as both the positive electrode metal layer 111 and the negative electrode metal layer 112, such as a single sheet of stainless steel.
  • the positive electrode active material layer 120 is a positive electrode active material layer formed on one surface (the surface in the positive Z-axis direction) of the current collector foil 110. Specifically, the positive electrode active material layer 120 is formed on the positive electrode metal layer 111 (the outer surface (the surface in the positive Z-axis direction) of the positive electrode metal layer 111). A sealing member 210 is disposed on the outside of the positive electrode metal layer 111, and the positive electrode active material layer 120 is formed in a hexagonal shape (a regular hexagon in this embodiment) inside this. The thickness of the positive electrode active material layer 120 (thickness in the stacking direction) is approximately 50 ⁇ m to 100 ⁇ m.
  • the positive electrode active material layer 120 includes a positive electrode active material and, as necessary, optional components such as a conductive agent, a binder, a thickener, and a filler.
  • the positive electrode active material include layered lithium transition metal oxides having an ⁇ -NaFeO 2 crystal structure, such as LiM 1 O 2 (where M 1 is one or more metal elements selected from Li, Fe, Ni, Mn, Co, etc.), spinel-type lithium transition metal oxides, such as LiM 2 O 4 (where M 2 is one or more metal elements selected from Li, Fe, Ni, Mn, Co, etc.), and polyanion compounds, such as LiM 3 PO 4 , LiM 3 SiO 4 , and LiM 3 BO 3 (where M 3 is one or more metal elements selected from Li, Fe, Ni, Mn, Co, etc.).
  • LiM 1 O 2 where M 1 is one or more metal elements selected from Li, Fe, Ni, Mn, Co, etc.
  • spinel-type lithium transition metal oxides such as LiM 2 O
  • the positive electrode active material one of these compounds may be used alone, or two or more may be mixed and used.
  • the conductive agent contained in the positive electrode active material layer 120 is not particularly limited as long as it has conductivity.
  • Examples of the conductive agent include carbon black such as furnace black, acetylene black, and ketjen black, and natural or artificial graphite.
  • Examples of the binder (binding agent) include fluororesin (polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), etc.), sulfonated EPDM, and styrene butadiene rubber (SBR).
  • the thickener include polysaccharide polymers such as carboxymethyl cellulose (CMC) and methyl cellulose.
  • the negative electrode active material layer 130 is a negative electrode active material layer formed on the other surface (the surface facing the negative Z-axis) of the current collector foil 110. Specifically, the negative electrode active material layer 130 is formed on the negative electrode metal layer 112 (the outer surface (the surface facing the negative Z-axis) of the negative electrode metal layer 112). A sealing member 210 is disposed on the outside of the negative electrode metal layer 112, and the negative electrode active material layer 130 is formed in a hexagonal shape (a regular hexagon in this embodiment) inside this sealing member 210. The negative electrode active material layer 130 is formed to be larger in size than the positive electrode active material layer 120 when viewed transparently from the Z-axis direction.
  • “Large size” in plan view means that the area in the XY plane is large and that no portion protrudes beyond the target area when viewed transparently from the Z-axis direction.
  • the negative electrode active material layer 130 has a large area and no portion protrudes into the opposing positive electrode active material layer 120.
  • the negative electrode metal layer 112 and the negative electrode active material layer 130 have the same or similar shapes, and the thickness of the negative electrode active material layer 130 (thickness in the stacking direction) is approximately 40 ⁇ m to 60 ⁇ m.
  • the negative electrode active material layer 130 contains a negative electrode active material and, if necessary, optional components such as a conductive agent, binder, thickener, and filler.
  • the optional components such as the conductive agent, binder, thickener, and filler can be the same as those used in the positive electrode active material layer 120.
  • the negative electrode active material typically uses a material that can absorb and release lithium ions. Specific examples include metals or semi-metals such as Si and Sn; metal oxides or semi-metal oxides such as Si oxide and Sn oxide; and carbon materials such as graphite and non-graphitic carbon (easily graphitizable carbon or non-graphitizable carbon).
  • End unit 101 is positioned in the negative direction of the Z axis relative to component unit 10.
  • End unit 102 is positioned in the positive direction of the Z axis relative to component unit 10.
  • End units 101 and 102 are parts that sandwich multiple component units 10 in the Z axis direction.
  • the end unit 101 comprises at least a positive electrode metal layer 111 and a positive electrode active material layer 120 formed on the surface of the positive electrode metal layer 111 in the positive Z-axis direction.
  • the configurations of the positive electrode metal layer 111 and positive electrode active material layer 120 of the end unit 101 are the same as the configurations of the positive electrode metal layer 111 and positive electrode active material layer 120 of the current collector foil 110 of the component unit 10 described above.
  • the sealing member 210 is provided on the positive electrode metal layer 111 around the outer periphery of the positive electrode active material layer 120 on the surface of the end unit 101 on which the positive electrode active material layer 120 is provided.
  • the thickness of the sealing member 210 is approximately the same as the thickness of the positive electrode active material layer 120.
  • the end unit 102 comprises at least a current collector foil 110 and a negative electrode active material layer 130 arranged on the surface of the current collector foil 110 facing in the negative Z-axis direction.
  • the configurations of the current collector foil 110 and negative electrode active material layer 130 provided in the end unit 102 are the same as the configurations of the current collector foil 110 and negative electrode active material layer 130 provided in the component unit 10 described above.
  • the sealing member 210 is provided on the current collector foil 110 around the outer periphery of the negative electrode active material layer 130 on the surface of the end unit 102 on which the negative electrode active material layer 130 is provided.
  • the thickness of the sealing member 210 is approximately the same as the thickness of the negative electrode active material layer 130.
  • the separator 140 is a microporous sheet made of resin.
  • the separator 140 is disposed between the component units 10, between the end units 101 and the component units 10, and between the end units 102 and the component units 10.
  • the separator 140 is disposed between the positive electrode active material layer 120 and the negative electrode active material layer 130.
  • the separator 140 is formed in a hexagonal shape (a regular hexagonal shape in this embodiment) that is larger than the negative electrode active material layer 130 in a transparent planar view.
  • the size of the separator 140 is expressed as being the same as that of the current collector foil 110 in a planar view, but the size may be smaller or larger than that of the current collector foil 110 in a planar view.
  • the thickness of the separator 140 is approximately 15 ⁇ m to 20 ⁇ m.
  • Separator 140 can be made from a woven fabric, a nonwoven fabric, a porous resin film, or the like. Of these, porous resin film is preferred. From the standpoint of strength, the main component of the porous resin film is preferably a polyolefin such as polyethylene or polypropylene. Separator 140 may also be a multilayer film in which a layer containing a filler is formed on the surface of such a porous resin film.
  • the end members 300 are members that are positioned closer to the ends of the energy storage device 1 in the stacking direction (Z-axis direction) than the multiple component units 10.
  • a pair of end members 300 are positioned at the ends of the energy storage device 1 closest to the negative Z-axis direction and the positive Z-axis direction.
  • the pair of end members 300 are connected to the end units 101 and 102 (and the current collecting foils 110 provided therein). As a result, the pair of end members 300 sandwich the multiple component units 10 and end units 101 and 102 located between them from both sides in the stacking direction (Z-axis direction).
  • the end member 300 is formed from a conductive metal material such as aluminum, aluminum alloy, copper, copper alloy, or nickel, or a combination thereof, or a conductive material other than metal. Because the end member 300 is connected to the positive electrode metal layer 111, it is preferably formed from the same material as the positive electrode metal layer 111, such as aluminum.
  • the end member 300 is electrically connected to another end member 300 provided in another energy storage device 1 via another conductive member (bus bar, cooling plate, etc., not shown).
  • the thickness of the end member 300 is approximately 0.5 mm to 3 mm.
  • the energy storage device 1 may have another conductive member on the outside of the end member 300 (outside in the Z-axis direction). A mechanism for applying pressure to the end member 300 from the outside may also be provided to reduce resistance.
  • the sealing members 210 are provided on both sides of the current collector foil 110 on the outer periphery of the positive electrode active material layer 120 and/or negative electrode active material layer 130 of the component unit 10 and the end units 101, 102.
  • the thickness of each sealing member 210 is approximately the same as the thickness of the adjacent positive electrode active material layer 120 or negative electrode active material layer 130.
  • the sealing members 210 are components that join battery components together and have a hexagonal outer shape (a regular hexagon in this embodiment) in a plan view.
  • the peripheral sealing member 200 is a dense resin layer provided around (the outer periphery of) the energy storage device 1.
  • the sealing member 210 and the peripheral sealing member 200 are formed from insulating materials such as polycarbonate (PC), polypropylene (PP), polyethylene (PE), polystyrene (PS), polyphenylene sulfide resin (PPS), polyphenylene ether (PPE (including modified PPE)), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyether ether ketone (PEEK), tetrafluoroethylene perfluoroalkyl vinyl ether (PFA), polytetrafluoroethylene (PTFE), polyethersulfone (PES), polyamide (PA), ABS resin, or composite materials thereof.
  • PC polycarbonate
  • PP polypropylene
  • PE polyethylene
  • PS polystyrene
  • PPS polyphenylene sulfide resin
  • PPE polyphenylene ether
  • PET polyethylene terephthalate
  • PBT polybutylene terephthalate
  • PEEK polyether ether
  • the sealing member 210 is described as part of a component unit 10 such as the component unit 10, end units 101 and 102, but it is also possible to stack the sealing member 210 as a standalone component unit 10.
  • the positive electrode active material layer 120 and the negative electrode active material layer 130 must be approximately the same thickness. If the thicknesses of the positive electrode active material layer 120 and the negative electrode active material layer 130 differ significantly, the thickness of the sealing member 210 on the positive electrode side and the negative electrode side must be different.
  • the sealing member 210 is a member that seals between the component unit 10 and the separator 140, between the end unit 101 and the separator 140, and between the end unit 102 and the separator 140.
  • the sealing member 210 may be an adhesive or pressure-sensitive adhesive that does not adversely affect battery performance.
  • adhesives that may be used include acrylic resin-based adhesives, ⁇ -olefin-based adhesives, urethane resin-based adhesives, ether-based cellulose-based adhesives, ethylene-vinyl acetate resin emulsion adhesives, epoxy resin-based adhesives, vinyl chloride resin solvent-based adhesives, cyanoacrylate-based adhesives, silicone-based adhesives, nitrocellulose adhesives, and phenolic resin-based adhesives.
  • the sealing member 210 may be made of adhesive tape with adhesive applied to both sides of a resin tape. Using double-sided tape for the sealing member 210 allows the component units 10 to be joined together with the sealing member 210 after stacking, thereby integrating the laminate 400.
  • the peripheral sealing member 200 is a dense resin layer provided around the periphery of the energy storage device 1, and is a cylindrical (hexagonal cylindrical) member that seals the energy storage device from the outside. After stacking the battery components using the method described below and removing the connecting portions of the component units 10, the stacked body 400 is removed from the frame member 30 and the peripheral sealing member 200 is applied to its periphery, thereby covering the periphery of the energy storage device 1 with a resin layer.
  • the energy storage device 1 can be constructed by using the frame member 30 used for stacking as is, joining the peripheries of the frame member 30 and stacked body 400 with the peripheral sealing member 200, and then joining a frame member lid.
  • the terminal structure, gas exhaust valve, gas exhaust structure, cooling structure, electrolyte injection port, etc. which are essentially required for the energy storage device 1, have been omitted as they are not relevant to the spirit of the present invention.
  • the separator 140 of the energy storage device 1 is impregnated with an electrolytic solution to form an electrolyte layer (not shown).
  • the electrolyte layer is a non-aqueous liquid electrolyte (electrolytic solution), but a gel electrolyte or the like may also be used. Any known electrolyte can be used as appropriate.
  • the electrolytic solution nonaqueous electrolyte may be one in which an electrolyte salt is dissolved in a non-aqueous solvent.
  • non-aqueous solvents examples include cyclic carbonates such as ethylene carbonate (EC) and propylene carbonate (PC), and chain carbonates such as diethyl carbonate (DEC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC).
  • a lithium salt is preferred as the electrolyte salt.
  • the lithium salt include inorganic lithium salts such as LiPF 6 , LiPO 2 F 2 , LiBF 4 , LiClO 4 , LiN(SO 2 F) 2 , and LiN(SO 2 CF 3 ).
  • the separator 140, the positive electrode active material layer 120 and the negative electrode active material layer 130 sandwiching the separator 140 in the Z-axis direction, and the positive electrode metal layer 111 and the negative electrode metal layer 112 sandwiching these in the Z-axis direction may be referred to as a single energy storage element.
  • the energy storage device 1 can also be described as an energy storage element having a configuration in which multiple energy storage elements stacked in the Z-axis direction are sandwiched between a pair of end members 300 in the Z-axis direction, and the periphery of these is surrounded by a sealing member 210 and a peripheral sealing member 200.
  • connection portions 12, 21 are portions that connect the component units 10 to each other in the component unit continuous body 10A and the separator continuous body 140A. These portions do not necessarily have to be made of the same material as the respective component units 10; they may be made of a material different from the material of each component unit 10 and be adhered or bonded to each component unit 10.
  • the connection portion 12 does not have to be made of metal and may be a flexible resin film such as PET resin. Using such a resin film for the connection portion 12 can prevent metal contamination when the connection portion 12 is separated.
  • the component unit 10 and the connection portion 12 may be joined using adhesive tape or the like.
  • connection portion 12 when separating the connection portion 12, the connection portion 12 can be separated from the component unit 10 by removing the adhesive tape.
  • the material of the member units 10 and the material of the connecting portions 21 may be different, or they may be bonded or joined to the member units 10.
  • the manufacturing method for the energy storage device 1 of this embodiment consists of one process preparation step and 11 processes.
  • the components for constructing the energy storage device 1 are prepared.
  • the main components to be prepared are the frame member 30, the component unit continuous body 10A, the separator continuous body 140A, the end member 300, and the end units 101 and 102.
  • the component unit continuum 10Ad in this modified example has a configuration in which a plurality of component units 10g and a plurality of component units 10h are alternately connected by connecting portions 13.
  • Component unit 10g has a negative electrode active material layer 130 formed on the negative Z-axis surface of negative electrode metal layer 112, which is the negative electrode current collector foil of current collector foil 110, and component unit 10h has a negative electrode active material layer 130 formed on the positive Z-axis surface of negative electrode metal layer 112.
  • the component unit continuum 10Ad in this modified example also has a sealing member 210 on the outer periphery of the negative electrode active material layer 130.
  • connecting portion 13a, component unit 10g, connecting portion 13b, component unit 10h, and connecting portion 13c are arranged in a row (linearly).
  • the connecting portion 13b by bending the connecting portion 13b, the component unit string 10Ad is folded at the position of the connecting portion 13b, and component unit 10h of the component unit string 10Ad is inserted into the frame member 30, with connecting portions 13b and 13c protruding from the frame member 30.
  • the connecting portion 12b by bending the connecting portion 12b, the component unit string 10Ac is folded at the position of the connecting portion 12b, and component unit 10f of the component unit string 10Ac is inserted into the frame member 30, with connecting portions 12b and 12c protruding from the frame member 30.
  • the component unit continuum 10Ae in this modified example has a configuration in which a plurality of component units 10i and a plurality of component units 10j are alternately connected by connecting portions 12.
  • the component unit 10i has a positive electrode active material layer 120 formed on the surface of the current collector foil 110 facing in the positive Z-axis direction, and a negative electrode active material layer 130 formed on the surface facing in the negative Z-axis direction.
  • the component unit 10j has a negative electrode active material layer 130 formed on the surface of the current collector foil 110 facing in the positive Z-axis direction, and a positive electrode active material layer 120 formed on the surface facing in the negative Z-axis direction.
  • the remaining configuration of this modified example is the same as that of the above embodiment, so detailed description will be omitted.
  • the component unit continuum 10Af in this modified example has a configuration in which multiple component units 10k are connected by connecting portions 12.
  • Each component unit 10k has a positive electrode active material layer 120 formed on both sides in the Z-axis direction of a positive electrode metal layer 111, which is the positive electrode current collector foil of a current collector foil 110.
  • the component unit continuum 10Ag in this modified example has a configuration in which multiple component units 10l are connected by connecting portions 13.
  • the component unit 10l has a negative electrode active material layer 130 formed on both sides in the Z-axis direction of the negative electrode metal layer 112, which is the negative electrode current collector foil of the current collector foil 110.
  • the component unit continuum 10Af, the component unit continuum 10Ag, and the separator continuum 140A are alternately folded to place a separator 140 between the component unit 10k and the component unit 10l.
  • the component unit 10k, in which the positive electrode active material layer 120 is formed on both sides of the positive electrode metal layer 111, and the component unit 10l, in which the negative electrode active material layer 130 is formed on both sides of the negative electrode metal layer 112 are stacked via the separator 140.
  • the connection portions 12, 13, and 21 protruding from the frame member 30 are then cut off.
  • connection portion 12 remaining on the positive electrode metal layer 111 and the portion of the connection portion 13 remaining on the negative electrode metal layer 112 can be used as tabs.
  • the connection portions 12 and 13 may be cut off so that longer portions of the connection portions 12 and 13 remain on the positive electrode metal layer 111 and the negative electrode metal layer 112.
  • the component unit continuum 10A and the separator continuum 140A are arranged as the component unit continuum, but this is not limited to this.
  • the component unit continuum 10A may not be arranged, and a single component unit 10 may be arranged, or the separator continuum 140A may not be arranged, and a single separator 140 may be arranged.
  • connection portion 12 with a width shorter than the length of one side of the current collecting foil 110 is connected to that side, but a connection portion 12 with a width equal to or longer than the length of that side may also be connected.
  • a connection portion 12 with a width equal to or longer than the length of that side may also be connected. The same applies to the separator 140, etc.
  • the component unit string 10A is folded by inserting the current collecting foil 110 and the like into the frame member 30, but the component unit string 10A may also be folded without inserting the current collecting foil 110 and the like into the frame member 30.
  • the separator 140 and the like are the same applies to the separator 140 and the like.
  • connection portions 12 protruding from the frame member 30 are cut off, but the connection portions 12 may also be cut off within the frame member 30. The same applies to the separators 140, etc.
  • the positive electrode active material layer 120 and the negative electrode active material layer 130 may be interchanged.
  • the negative electrode active material layer 130 may be disposed within the through-hole of the intermediate foil 11.
  • the separator continuum 140A is folded together with the component unit continuum 10A, but the separator 140 may be attached to the negative electrode active material layer 130 or the positive electrode active material layer 120 by adhesive or the like, and then the component unit continuum 10A may be folded. In this case, the steps of folding the separator continuum 140A and cutting off the connection portions 21 can be omitted.
  • a solid electrolyte layer may be disposed in place of the separator 140. Any known solid electrolyte may be used as the solid electrolyte layer.
  • the energy storage device 1 may be used in an energy storage pack 1A as shown in FIG. 22.
  • FIG. 22 is a plan view showing the configuration of the energy storage pack 1A.
  • the energy storage pack 1A includes multiple energy storage devices 1. Because the energy storage device 1 has a regular hexagonal shape in a plan view, six energy storage devices 1 can be arranged around one energy storage device 1 in a plan view. The multiple energy storage devices 1 are connected in series or in parallel.
  • the energy storage pack 1A also includes a metal case, resin case, or the like that houses the multiple energy storage devices 1, but this is not shown in the figures.
  • the technology of the present invention may be applied to at least one energy storage device 1 included in the energy storage pack 1A.
  • the energy storage device 1 may be used in an energy storage pack 1B as shown in FIG. 23.
  • FIG. 23 is a cross-sectional view showing the configuration of the energy storage pack 1B.
  • the internal configuration of the energy storage device 1 is omitted from FIG. 23.
  • the energy storage pack 1B includes an energy storage device stack 2 in which multiple energy storage devices 1 are stacked, and a conductive member 3.
  • the technology of the present invention only needs to be applied to at least one energy storage device 1 included in the energy storage pack 1B.
  • Two adjacent energy storage devices 1 in the energy storage device stack 2 are electrically connected by contact or bonding (welding, etc.).
  • the conductive member 3 is made of a metal such as stainless steel, and the energy storage device 1 located at the end in the stacking direction (Z-axis direction) and the conductive member 3 are electrically connected by contact or bonding (welding, etc.). An adhesive may be used for bonding.
  • the multiple energy storage devices 1 in the energy storage device stack 2 are connected in series, and charging and discharging are performed via the conductive member 3.
  • the electricity storage pack 1B may be restrained in the stacking direction (Z-axis direction) using restraining members such as screws, resin bands, or metal bands.
  • the electricity storage device stack 2 and conductive member 3 may be housed in a metal or resin case.
  • Figure 24 shows a configuration in which individual electricity storage devices 1 are housed in an exterior housing 4.
  • Figure 24 is a cross-sectional view showing the configuration of an electricity storage pack 1C.
  • the electricity storage device 1 of this configuration has a connection portion 5 exposed from the exterior housing 4.
  • a laminate film or the like can be used as the exterior housing 4.
  • the connection portions 5 of adjacent electricity storage devices 1 are electrically connected by contact or bonding (welding, etc.).
  • the connection portion 5 of the electricity storage device 1 located at the end in the stacking direction (Z-axis direction) and the conductive member 3 are electrically connected by contact or bonding (welding, etc.).
  • the rest of the configuration is the same as that of the above-mentioned electricity storage pack 1B, so description will be omitted.
  • the present invention can be applied to manufacturing methods for power storage devices such as bipolar batteries.

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Abstract

Provided is a method for manufacturing a power storage device provided with a plurality of member units laminated in a lamination direction, said method including arranging a member unit continuous body in which a plurality of member units are connected by a connection part, folding the member unit continuous body at the position of the connection part, and removing the connection part after the member unit continuous body is folded.

Description

蓄電装置の製造方法Method for manufacturing an electricity storage device

 本発明は、蓄電装置の製造方法に関する。 The present invention relates to a method for manufacturing an electricity storage device.

 特許文献1では、集電体およびセパレータが交互に積層された構造を有する二次電池の積層工程において、集電体、セパレータ等の積層位置が正規の位置からずれるのを防止するため、第1枠体の一方面に凸部が形成された第1電極ユニットを形成する工程と、第2枠体の他方面に凹部が形成された第2電極ユニットを形成する工程と、第1電極ユニット上に第2電極ユニットを積層する工程と、を備え、積層する工程で第1枠体の凸部が第2枠体の凹部に係合する蓄電装置の製造方法が開示されている。 Patent Document 1 discloses a method for manufacturing an energy storage device that includes the steps of forming a first electrode unit with a convex portion formed on one surface of a first frame, forming a second electrode unit with a concave portion formed on the other surface of a second frame, and stacking the second electrode unit on the first electrode unit to prevent the stacking positions of the current collectors, separators, etc. from shifting from their correct positions during the stacking process for secondary batteries having a structure in which current collectors and separators are alternately stacked, and in which the convex portion of the first frame engages with the concave portion of the second frame during the stacking process.

特開2022-22899号公報Japanese Patent Application Laid-Open No. 2022-22899

 特許文献1に開示された蓄電装置の製造方法では、第1枠体に凸部を形成し、かつ、第2枠体に凹部を形成して、第1枠体の凸部と第2枠体の凹部を係合させて、位置合わせを行っているが、前記特許文献1には、活物質層の厚さとして2~150μm、集電箔の厚さとして1~100μmと例示されており、これより考えると、凸部と凹部を含むスペーサー部分の断面厚さは、正極及び負極の活物質層の厚さの合計値4~300μmに集電箔の厚さ1~100μmを加えた、5~400μm程度の大きさで構成する必要がある。係合部分の凸部と凹部はスペーサー部の厚さより小さくなることから、高精度かつ微細な製造技術が必要であり、この方法では、蓄電装置を容易に構成できないおそれがある。特に電極ユニットが大型の場合(1m角程度等)には、第1枠体と第2枠体との係合自体が困難であることが考えられる。 In the manufacturing method for an energy storage device disclosed in Patent Document 1, convex portions are formed on the first frame and concave portions are formed on the second frame, and the convex portions of the first frame and the concave portions of the second frame are engaged to align them. However, Patent Document 1 exemplifies the thickness of the active material layer as 2 to 150 μm and the thickness of the current collector foil as 1 to 100 μm. Based on this, the cross-sectional thickness of the spacer portion including the convex portions and concave portions needs to be approximately 5 to 400 μm, which is the sum of the combined thickness of the positive and negative electrode active material layers (4 to 300 μm) and the current collector foil thickness (1 to 100 μm). Because the convex portions and concave portions of the engaging portion are smaller than the thickness of the spacer portion, high-precision and fine manufacturing techniques are required, and this method may not be easy to use to construct an energy storage device. Engaging the first frame and second frame may be particularly difficult when the electrode unit is large (e.g., approximately 1 m square).

 本発明は、本願発明者が上記課題に新たに着目することによってなされたものであり、蓄電装置を容易に製造できる蓄電装置の製造方法を提供することを目的とする。 The present invention was made by the inventors by focusing on the above-mentioned problem, and aims to provide a method for manufacturing an electricity storage device that allows for easy production of an electricity storage device.

 本発明の一態様に係る蓄電装置の製造方法は、積層方向に積層された複数の部材ユニットを備える蓄電装置の製造方法であって、複数の前記部材ユニットを接続部で接続した部材ユニット連続体を配置することと、前記接続部の位置で前記部材ユニット連続体を折り畳むことと、前記部材ユニット連続体を折り畳んだ後に、前記接続部を取り外すことと、を含む。 A manufacturing method for an energy storage device according to one aspect of the present invention is a manufacturing method for an energy storage device having a plurality of component units stacked in a stacking direction, and includes arranging a component unit continuum in which the plurality of component units are connected by connecting portions, folding the component unit continuum at the positions of the connecting portions, and removing the connecting portions after folding the component unit continuum.

 本発明における蓄電装置の製造方法によれば、蓄電装置を容易に製造できる。 The method for manufacturing an electricity storage device according to the present invention makes it easy to manufacture an electricity storage device.

図1は、実施の形態に係る蓄電装置の外観を示す斜視図である。FIG. 1 is a perspective view showing the appearance of a power storage device according to an embodiment. 図2は、実施の形態に係る蓄電装置の内部構成を示す断面図である。FIG. 2 is a cross-sectional view showing the internal configuration of the electricity storage device according to the embodiment. 図3Aは、実施の形態に係る蓄電装置が備える部材ユニットの構成を示す斜視図である。FIG. 3A is a perspective view illustrating a configuration of a member unit included in the power storage device according to the embodiment. 図3Bは、実施の形態に係る蓄電装置が備える部材ユニットの構成を示す断面図である。FIG. 3B is a cross-sectional view showing the configuration of a member unit included in the power storage device according to the embodiment. 図4は、実施の形態に係る蓄電装置の製造方法における製造工程を示すフローチャートである。FIG. 4 is a flowchart showing manufacturing steps in the manufacturing method for the electricity storage device according to the embodiment. 図5Aは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を配置する工程を示す平面図である。FIG. 5A is a plan view illustrating a step of arranging a member unit continuum in a manufacturing method for an energy storage device according to an embodiment. 図5Bは、実施の形態に係る蓄電装置の製造方法におけるセパレータ連続体を配置する工程を示す平面図である。FIG. 5B is a plan view illustrating a step of arranging a separator continuous body in the manufacturing method for the energy storage device according to the embodiment. 図6は、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程で用いる枠部材の構成を示す斜視図である。FIG. 6 is a perspective view showing the configuration of a frame member used in the step of folding the member unit continuous body in the manufacturing method for the electricity storage device according to the embodiment. 図7Aは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(第4工程終了後)を示す平面図である。FIG. 7A is a plan view illustrating a step of folding the member unit continuous body (after the fourth step) in the manufacturing method for the energy storage device according to the embodiment. 図7Bは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(第4工程終了後)を示す断面図である。FIG. 7B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the fourth step) in the manufacturing method for the energy storage device according to the embodiment. 図8Aは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(第5工程終了後)を示す平面図である。FIG. 8A is a plan view illustrating a step of folding the member unit continuous body (after the fifth step) in the manufacturing method for the energy storage device according to the embodiment. 図8Bは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(第5工程終了後)を示す断面図である。FIG. 8B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the fifth step) in the manufacturing method for the energy storage device according to the embodiment. 図9Aは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(再度第3工程終後)を示す平面図である。FIG. 9A is a plan view illustrating a step of folding the member unit continuous body (again after completion of the third step) in the manufacturing method for the energy storage device according to the embodiment. 図9Bは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(再度第3工程終了後)を示す断面図である。FIG. 9B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the third step is completed again) in the manufacturing method for the energy storage device according to the embodiment. 図10Aは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(再度第4工程終了後)を示す平面図である。FIG. 10A is a plan view illustrating a step of folding the member unit continuous body (after the fourth step is completed again) in the manufacturing method for the energy storage device according to the embodiment. 図10Bは、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程(再度第4工程終了後)を示す断面図である。FIG. 10B is a cross-sectional view illustrating a step of folding the member unit continuous body (after the fourth step is completed again) in the manufacturing method for the energy storage device according to the embodiment. 図11は、実施の形態に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程を示す斜視図である。FIG. 11 is a perspective view showing a step of folding the member unit continuous body in the manufacturing method for the energy storage device according to the embodiment. 図12は、実施の形態に係る蓄電装置の製造方法における接続部を切り離す工程を示す断面図である。FIG. 12 is a cross-sectional view showing a step of cutting off the connection portion in the manufacturing method for the electricity storage device according to the embodiment. 図13Aは、実施の形態の変形例1に係る部材ユニット連続体の構成を示す平面図である。FIG. 13A is a plan view showing the configuration of a member unit continuum according to a first modified example of the embodiment. 図13Bは、実施の形態の変形例1に係る部材ユニット連続体の構成を示す平面図である。FIG. 13B is a plan view showing the configuration of the member unit continuum according to the first modification of the embodiment. 図14Aは、実施の形態の変形例2に係る部材ユニット連続体の構成を示す平面図である。FIG. 14A is a plan view showing the configuration of a member unit continuum according to a second modification of the embodiment. 図14Bは、実施の形態の変形例2に係る部材ユニット連続体の構成を示す平面図である。FIG. 14B is a plan view showing the configuration of a member unit continuum according to the second modification of the embodiment. 図15Aは、実施の形態の変形例2に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程を示す平面図である。FIG. 15A is a plan view illustrating a step of folding a member unit continuum in a manufacturing method for an energy storage device according to a second modification of the embodiment. 図15Bは、実施の形態の変形例2に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程を示す断面図である。FIG. 15B is a cross-sectional view illustrating a step of folding the member unit continuous body in the manufacturing method for an energy storage device according to the second modification of the embodiment. 図16は、実施の形態の変形例2に係る蓄電装置の製造方法における部材ユニット連続体を折り畳む工程を示す断面図である。FIG. 16 is a cross-sectional view illustrating a step of folding the member unit continuous body in a manufacturing method for an energy storage device according to a second modification of the embodiment. 図17は、実施の形態の変形例2に係る蓄電装置の製造方法における接続部を切り離す工程を示す断面図である。FIG. 17 is a cross-sectional view illustrating a step of cutting off the connection portion in a manufacturing method for an electricity storage device according to the second modification of the embodiment. 図18は、実施の形態の変形例3に係る部材ユニット連続体の構成を示す平面図である。FIG. 18 is a plan view showing the configuration of a member unit continuum according to the third modification of the embodiment. 図19は、実施の形態の変形例3に係る蓄電装置の製造方法における部材ユニット連続体を折り畳んだ後に接続部を切り離す工程を示す断面図である。FIG. 19 is a cross-sectional view illustrating a step of cutting off the connection portions after folding the member unit continuous body in a manufacturing method for an electricity storage device according to a third modified example of the embodiment. 図20Aは、実施の形態の変形例4に係る部材ユニット連続体の構成を示す平面図である。FIG. 20A is a plan view showing the configuration of a member unit continuum according to a fourth modified example of the embodiment. 図20Bは、実施の形態の変形例4に係る部材ユニット連続体の構成を示す平面図である。FIG. 20B is a plan view showing the configuration of a member unit continuum according to the fourth modification of the embodiment. 図21は、実施の形態の変形例4に係る蓄電装置の製造方法における部材ユニット連続体を折り畳んだ後に接続部を切り離す工程を示す断面図である。FIG. 21 is a cross-sectional view illustrating a step of cutting off the connection portions after folding the member unit continuous body in a manufacturing method for an electricity storage device according to the fourth modification of the embodiment. 図22は、蓄電パックの構成を示す平面図である。FIG. 22 is a plan view showing the configuration of the electricity storage pack. 図23は、蓄電パックの構成を示す断面図である。FIG. 23 is a cross-sectional view showing the configuration of the electricity storage pack. 図24は、蓄電パックの構成を示す断面図である。FIG. 24 is a cross-sectional view showing the configuration of the electricity storage pack.

 (1)本発明の一態様に係る蓄電装置の製造方法は、積層方向に積層された複数の部材ユニットを備える蓄電装置の製造方法であって、複数の前記部材ユニットを接続部で接続した部材ユニット連続体を配置することと、前記接続部の位置で前記部材ユニット連続体を折り畳むことと、前記部材ユニット連続体を折り畳んだ後に、前記接続部を取り外すことと、を含む。 (1) A manufacturing method for an energy storage device according to one aspect of the present invention is a manufacturing method for an energy storage device including a plurality of component units stacked in a stacking direction, and includes arranging a component unit continuum in which the plurality of component units are connected by connecting portions, folding the component unit continuum at the positions of the connecting portions, and removing the connecting portions after folding the component unit continuum.

 本発明の一態様に係る蓄電装置の製造方法によれば、複数の部材ユニットが接続部で接続された部材ユニット連続体を用意し、接続部の位置で部材ユニット連続体を折り畳み、その後、接続部を取り外す。このように、複数の部材ユニットが接続部で接続された部材ユニット連続体を接続部の位置で折り畳むことで、複数の部材ユニットを容易に位置決めしながら積層できる。さらに部材ユニット連続体を折り畳んだ後に接続部を取り外すことで、部材ユニットを適切な位置で積層することが可能となり、蓄電装置を容易に製造できる。 In accordance with one aspect of the present invention, a method for manufacturing an electricity storage device involves preparing a component unit series in which multiple component units are connected by connecting parts, folding the component unit series at the positions of the connecting parts, and then removing the connecting parts. In this way, by folding the component unit series in which multiple component units are connected by connecting parts at the positions of the connecting parts, multiple component units can be easily positioned and stacked. Furthermore, by removing the connecting parts after folding the component unit series, it becomes possible to stack the component units in the appropriate positions, making it easy to manufacture an electricity storage device.

 ここで、接続部を取り外すとは、接続部を切り離すこと、接着等で接合していた接合部を取り外すこと等を含む。 Here, removing a connection includes cutting off the connection, removing a connection that has been joined by adhesive or the like, etc.

 部材ユニット連続体を構成する部材ユニットとしては、電極ユニット、セパレータ、エンドユニット、エンド部材、シール部材、さらに、これらの複数の部材の機能を一体化した部材(例えばセパレータ付き電極ユニット、シール部材付き電極ユニット等)が挙げられる。また、本発明では単体では蓄電装置の部材としては機能を発揮しない中間箔のような部材も部材ユニットと呼ぶ。 The component units that make up the component unit continuum include electrode units, separators, end units, end members, sealing members, and components that combine the functions of multiple of these components (for example, electrode units with separators, electrode units with sealing members, etc.). In addition, in this invention, components such as intermediate foils that do not function as components of an electricity storage device on their own are also referred to as component units.

 以下、本特許ではシール部材つき電極ユニットを電極部材ユニットと呼ぶ。また、エンドユニットに関してもあらかじめ活物質層形成面にシール部材が配置されたものをエンドユニットと呼ぶ。どのような部材ユニットを用いて蓄電装置を構成するかは、製造する蓄電装置の形状、枠部材の形状、蓄電装置の設計、生産性等によって適宜選択できる。 Hereinafter, in this patent, an electrode unit with a sealing member will be referred to as an electrode member unit. Furthermore, an end unit in which a sealing member has already been placed on the active material layer forming surface will also be referred to as an end unit. The type of member unit used to construct the energy storage device can be selected appropriately depending on the shape of the energy storage device to be manufactured, the shape of the frame member, the design of the energy storage device, productivity, etc.

 (2)上記(1)に記載の蓄電装置の製造方法において、少なくとも前記部材ユニット連続体の一部は、集電箔の一方の面に正極活物質層が配置され、前記集電箔の他方の面に負極活物質層が配置されている、としてもよい。 (2) In the method for manufacturing an electricity storage device described in (1) above, at least a portion of the component unit continuum may have a positive electrode active material layer disposed on one side of the current collector foil and a negative electrode active material layer disposed on the other side of the current collector foil.

 上記(2)に記載の蓄電装置の製造方法によれば、集電箔の一方の面に正極活物質層が配置され、集電箔の他方の面に負極活物質層が配置された蓄電装置(バイポーラ電池)を容易に製造できる。 The method for manufacturing an electricity storage device described in (2) above makes it easy to manufacture an electricity storage device (bipolar battery) in which a positive electrode active material layer is disposed on one side of the current collector foil and a negative electrode active material layer is disposed on the other side of the current collector foil.

 (3)上記(1)または(2)に記載の蓄電装置の製造方法において、前記部材ユニット連続体は、前記積層方向から見て辺の数が4つ以上の偶数である多角形または円形の前記部材ユニットが前記接続部で複数接続されている、としてもよい。 (3) In the manufacturing method for a power storage device described in (1) or (2) above, the component unit continuum may be such that a plurality of component units each having a polygonal or circular shape with an even number of sides of four or more as viewed from the stacking direction are connected at the connection portions.

 上記(3)に記載の蓄電装置の製造方法によれば、蓄電装置の製造に用いる部材ユニット連続体として、複数の部材ユニットが直線状に接続部で接続された部材ユニット連続体を用いることができる。これにより、部材ユニット連続体をロール状で供給することが可能となり、量産時の生産性を高めることができる。 According to the manufacturing method for a storage battery device described in (3) above, a component unit continuum in which multiple component units are linearly connected by connectors can be used as the component unit continuum used in manufacturing the storage battery device. This makes it possible to supply the component unit continuum in roll form, thereby improving productivity during mass production.

 (4)上記(1)から(3)のいずれかひとつに記載の蓄電装置の製造方法において、前記部材ユニット連続体は、前記積層方向から見て多角形であり、前記接続部の幅は、前記多角形の一辺の長さよりも短い、としてもよい。 (4) In the method for manufacturing an energy storage device described in any one of (1) to (3) above, the component unit continuum may be polygonal when viewed from the stacking direction, and the width of the connection portion may be shorter than the length of one side of the polygon.

 上記(4)に記載の蓄電装置の製造方法によれば、多角形の部材ユニットの一辺に、当該一辺の長さよりも短い幅の接続部が接続された部材ユニット連続体が得られる。このように、接続部の幅を短くすることで、部材ユニットの位置合わせの自由度が向上し、部材ユニットの位置合わせ精度の向上を図ることができる。また、接続部の幅を短くするとともに、接続部の長さを長くすることで、部材ユニット連続体を反転することも可能となり、部材ユニットの上下面を反転させながらの積層も可能となる。 The manufacturing method for a storage device described in (4) above produces a component unit continuum in which a connecting portion with a width shorter than the length of one side of a polygonal component unit is connected to that side. In this way, shortening the width of the connecting portion increases the degree of freedom in aligning the component units, and improves the alignment accuracy of the component units. Furthermore, shortening the width of the connecting portion and lengthening the connecting portion also makes it possible to invert the component unit continuum, and to stack the component units while inverting their top and bottom surfaces.

 (5)上記(1)から(4)のいずれかひとつに記載の蓄電装置の製造方法において、前記部材ユニット連続体を折り畳む際には、前記部材ユニットを枠部材に挿入するとともに、前記接続部を折り畳んで前記接続部を前記枠部材から突出させ、前記接続部を取り外す際には、前記枠部材から突出した前記接続部を切断する、としてもよい。 (5) In the method for manufacturing an energy storage device described in any one of (1) to (4) above, when folding the member unit series, the member units may be inserted into a frame member and the connection portions may be folded to cause the connection portions to protrude from the frame member, and when removing the connection portions, the connection portions protruding from the frame member may be cut.

 上記(5)に記載の蓄電装置の製造方法によれば、部材ユニットを枠部材に挿入することで、枠部材で部材ユニットを位置決めしながら部材ユニット連続体を折り畳むことができる。また、接続部を枠部材から突出させることで、接続部を容易に切断できる。さらに、枠部材から突出した接続部を切断することで、接続部を枠部材外で切断できるため、接続部を切断した際のコンタミが枠部材内の部材ユニットに侵入するのを抑制できる。 According to the manufacturing method for an energy storage device described in (5) above, by inserting the component units into the frame member, the component unit series can be folded while the frame member positions the component units. Furthermore, by making the connection portions protrude from the frame member, the connection portions can be easily cut. Furthermore, by cutting the connection portions protruding from the frame member, the connection portions can be cut outside the frame member, which prevents contamination from entering the component units inside the frame member when the connection portions are cut.

 以下、図面を参照しながら、本発明の実施の形態(その変形例も含む)に係る蓄電装置及びその製造方法について説明する。以下で説明する実施の形態は、いずれも包括的または具体的な例を示すものである。以下の実施の形態で示される数値、形状、材料、構成要素、構成要素の配置位置及び接続形態、製造工程、製造工程の順序等は、一例であり、本発明を限定する主旨ではない。各図において、寸法等は厳密に図示したものではない。また、各図において、同一または同様な構成要素については同じ符号を付している。 Hereinafter, with reference to the drawings, a description will be given of an energy storage device and a manufacturing method thereof according to an embodiment of the present invention (including variations thereof). The embodiments described below are all comprehensive or specific examples. The numerical values, shapes, materials, components, component placement and connection configurations, manufacturing processes, and the order of manufacturing processes shown in the following embodiments are examples only and are not intended to limit the present invention. In each figure, dimensions and the like are not strictly depicted. Furthermore, in each figure, the same or similar components are designated by the same reference numerals.

 以下の説明及び図面中において、蓄電装置の厚さ方向、複数の部材ユニットの積層方向、集電箔または活物質層の厚さ方向、集電箔及び活物質層の積層方向、一対のエンド部材の並び方向、または、上下方向を、Z軸方向と定義する。Z軸方向と交差する異なる2つの方向を、X軸方向及びY軸方向と定義する。本実施の形態では、X軸方向、Y軸方向及びZ軸方向は、互いに直交する方向である。使用態様によってはZ軸方向が上下方向にならない場合も考えられるが、以下では説明の便宜のため、Z軸方向を上下方向として説明する。 In the following explanation and drawings, the thickness direction of the energy storage device, the stacking direction of multiple component units, the thickness direction of the current collector foil or active material layer, the stacking direction of the current collector foil and active material layer, the arrangement direction of a pair of end members, or the up-down direction is defined as the Z-axis direction. Two different directions that intersect with the Z-axis direction are defined as the X-axis direction and the Y-axis direction. In this embodiment, the X-axis direction, Y-axis direction, and Z-axis direction are mutually perpendicular. Depending on the usage mode, it is possible that the Z-axis direction is not the up-down direction, but for ease of explanation, the following explanation will be made assuming that the Z-axis direction is the up-down direction.

 以下の説明において、X軸プラス方向とは、X軸の矢印方向を示し、X軸マイナス方向とは、X軸プラス方向とは反対方向を示す。単にX軸方向という場合は、X軸プラス方向及びX軸マイナス方向の双方向またはいずれか一方の方向を示す。Y軸方向及びZ軸方向についても同様である。平行及び直交などの、相対的な方向または姿勢を示す表現は、厳密には、その方向または姿勢ではない場合も含む。2つの方向が平行である(または直交する)とは、当該2つの方向が完全に平行である(または直交する)ことを意味するだけでなく、実質的に平行である(または直交する)こと、すなわち、例えば数%程度の差異を含むことも意味する。以下の説明において、「絶縁」と表現する場合、「電気的な絶縁」を意味する。絶縁性を有する材料は、体積抵抗率1×10Ωm以上、より好ましくは1×10Ωm以上、さらに好ましくは1×1010Ωm以上の材料から形成されていることが好ましい。 In the following description, the positive X-axis direction refers to the direction of the X-axis arrow, and the negative X-axis direction refers to the direction opposite to the positive X-axis direction. Simply referring to the X-axis direction refers to both or either of the positive X-axis direction and the negative X-axis direction. The same applies to the Y-axis and Z-axis directions. Expressions indicating relative directions or attitudes, such as parallel and orthogonal, also include cases where the directions or attitudes are not strictly the same. Two directions being parallel (or orthogonal) not only means that the two directions are completely parallel (or orthogonal), but also means that the two directions are substantially parallel (or orthogonal), i.e., there is a difference of, for example, a few percent. In the following description, the term "insulation" means "electrical insulation." It is preferable that the insulating material be formed from a material with a volume resistivity of 1×10 6 Ωm or more, more preferably 1×10 7 Ωm or more, and even more preferably 1×10 10 Ωm or more.

 (実施の形態)
 [1 蓄電装置1の構成の説明]
 まず、本実施の形態における蓄電装置1の構成について、詳細に説明する。図1は、本実施の形態に係る蓄電装置1の外観を示す斜視図である。図2は、本実施の形態に係る蓄電装置1の内部構成を示す断面図である。図2は、図1の蓄電装置1を、II-II線を通るYZ平面の断面図であり、蓄電装置1が備える各構成要素を示している。図3Aは、シール部材210を備えた電極ユニット100である部材ユニット10の外観を示す斜視図であり、図3Bは、図3Aの部材ユニット10の、IIIB-IIIB線を通るYZ平面の断面図である。
(Embodiment)
[1. Description of the Configuration of the Energy Storage Device 1]
First, the configuration of the energy storage device 1 according to the present embodiment will be described in detail. FIG. 1 is a perspective view showing the exterior of the energy storage device 1 according to the present embodiment. FIG. 2 is a cross-sectional view showing the internal configuration of the energy storage device 1 according to the present embodiment. FIG. 2 is a cross-sectional view of the energy storage device 1 of FIG. 1 taken along the YZ plane passing through line II-II, and shows each component included in the energy storage device 1. FIG. 3A is a perspective view showing the exterior of a component unit 10 which is an electrode unit 100 including a sealing member 210, and FIG. 3B is a cross-sectional view of the component unit 10 of FIG. 3A taken along the YZ plane passing through line IIIB-IIIB.

 蓄電装置1は、外部からの電気を充電し、また外部へ電気を放電できる装置である。本実施の形態における蓄電装置1は、略六角柱形状を有している。具体的には、蓄電装置1は、バイポーラ電池である。蓄電装置1は、自動車、自動二輪車、ウォータークラフト、船舶、スノーモービル、農業機械、建設機械、無人搬送車(AGV:Automatic Guided Vehicle)、または、電気鉄道用の鉄道車両等の移動体の駆動用またはエンジン始動用等のバッテリ等として用いられる。上記の自動車としては、電気自動車(EV)、ハイブリッド電気自動車(HEV)、プラグインハイブリッド電気自動車(PHEV)、及び、化石燃料(ガソリン、軽油、液化天然ガス等)自動車が例示される。上記の電気鉄道用の鉄道車両としては、電車、モノレール、リニアモーターカー、並びに、ディーゼル機関及び電気モーターの両方を備えるハイブリッド電車が例示される。蓄電装置1は、家庭用または事業用等に使用される定置用のバッテリ等としても用いることができる。 The power storage device 1 is a device that can charge with electricity from an external source and discharge electricity to the outside. In this embodiment, the power storage device 1 has a roughly hexagonal prism shape. Specifically, the power storage device 1 is a bipolar battery. The power storage device 1 is used as a battery for driving or starting the engine of mobile objects such as automobiles, motorcycles, watercraft, ships, snowmobiles, agricultural machinery, construction machinery, automatic guided vehicles (AGVs), or electric railway rolling stock. Examples of the above-mentioned automobiles include electric vehicles (EVs), hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and fossil fuel (gasoline, diesel, liquefied natural gas, etc.) vehicles. Examples of the above-mentioned electric railway rolling stock include electric trains, monorails, linear motor cars, and hybrid trains equipped with both a diesel engine and an electric motor. The power storage device 1 can also be used as a stationary battery for home or business use.

 図1及び図2に示すように、蓄電装置1は電極ユニット100と、シール部材210と、セパレータ140と、エンドユニット101と、エンドユニット102と、エンド部材300と、外周封止部材200、などの部材を備えている。これらの部材には電極ユニット100と、シール部材210と、セパレータ140などのように一つの蓄電装置1に多数個必要な部材もあればエンドユニット101、102と、エンド部材300と、外周封止部材200などのように一つの蓄電装置1に1個もしくは2個しか必要でない部材もある。本発明ではなるべく、一つの蓄電装置1に多数個必要となる部材については部材ユニット連続体10Aとして連続的に供給して蓄電装置1の生産を容易にするとともに、生産性を向上することを目的とした。また一つの蓄電装置1に1個もしくは2個しかない部材に関しては予め所定の寸法に形成した単独の電池部材を用いて製造を行うこととした。 As shown in Figures 1 and 2, the energy storage device 1 includes components such as an electrode unit 100, a sealing member 210, a separator 140, an end unit 101, an end unit 102, an end member 300, and an outer periphery sealing member 200. Some of these components, such as the electrode unit 100, the sealing member 210, and the separator 140, are required in large quantities for one energy storage device 1, while others, such as the end units 101 and 102, the end member 300, and the outer periphery sealing member 200, are required in only one or two quantities for one energy storage device 1. In the present invention, components that are required in large quantities for one energy storage device 1 are supplied continuously as a component unit continuum 10A, with the aim of facilitating production of the energy storage device 1 and improving productivity. Furthermore, components that are required in only one or two quantities for one energy storage device 1 are manufactured using a single battery component pre-formed to a predetermined size.

 また、部材ユニット連続体10Aとして供給できるか?何種類の部材ユニット連続体10Aまで連続体として供給できるか?については部材ユニット10の形状に依存し、部材ユニット10の形状が辺の数が4つ以上の偶数の多角形もしくは円形であれば、部材ユニット10を連続体として供給が可能であり、部材ユニット10の連続体としての供給可能数は四角形では2種類、六角形で3種類、八角形で4種類までの供給が可能である。また、部材ユニット10が円形の場合には接続部12の幅を小さくすることで、より多くの部材ユニット連続体10Aからの供給が可能である。 Furthermore, the questions of whether they can be supplied as a component unit continuum 10A and how many types of component unit continuum 10A can be supplied as a continuum depend on the shape of the component unit 10. If the component unit 10 is a polygon with an even number of sides (four or more) or a circle, the component unit 10 can be supplied as a continuum, and the number of component unit 10 that can be supplied as a continuum is up to two types for squares, three types for hexagons, and four types for octagons. Furthermore, if the component unit 10 is circular, by reducing the width of the connection portion 12, it is possible to supply more component unit continuums 10A.

 以下の実施の形態では、部材ユニット10が六角形形状の場合について説明する。六角形形状では最大3種類の部材ユニット連続体10Aを供給できるが、本実施の形態では部材ユニット10として、(i)部材ユニット連続体10A、(ii)セパレータ連続体140Aの2種類を用いた場合について説明する。 In the following embodiment, a case where the component unit 10 is hexagonal in shape will be described. Up to three types of component unit continuum 10A can be supplied for hexagonal shapes, but in this embodiment, a case where two types of component unit 10 are used: (i) component unit continuum 10A, and (ii) separator continuum 140A will be described.

 部材ユニット10、エンドユニット101、及び、エンドユニット102は、平面視で六角形状(本実施の形態では正六角形状)の板状であり、Z軸方向に積層されている。ここで、本実施の形態での平面視とは、積層方向(Z軸方向)から見た場合のことをいう。また、本実施の形態では、エンドユニット101とエンドユニット102との間に、2つの部材ユニット10が積層されている状態を図示したが、部材ユニット10の積層数は特に限定されない。セパレータ140は、部材ユニット10と部材ユニット10の間、部材ユニット10とエンドユニット101の間、及び、部材ユニット10とエンドユニット102の間に配置される。一対のエンド部材300は、積層方向(Z軸方向)において、エンドユニット101のZ軸マイナス方向及びエンドユニット102のZ軸プラス方向に配置される。シール部材210は、電極ユニット100、エンドユニット101、102の正極活物質層120および負極活物質層130が設けられていない集電箔110に設けられる。ここで、それぞれのシール部材210の厚さは、近接する上記正極活物質層120もしくは上記負極活物質層130とほぼ、同じ厚さである。 The component unit 10, end unit 101, and end unit 102 are hexagonal (regular hexagonal in this embodiment) plate-like structures in a planar view, and are stacked in the Z-axis direction. Here, in this embodiment, planar view refers to a view from the stacking direction (Z-axis direction). Also, in this embodiment, two component units 10 are illustrated stacked between end unit 101 and end unit 102, but the number of component units 10 stacked is not particularly limited. Separators 140 are arranged between component units 10, between component unit 10 and end unit 101, and between component unit 10 and end unit 102. A pair of end components 300 are arranged in the stacking direction (Z-axis direction), with end unit 101 in the negative Z-axis direction and end unit 102 in the positive Z-axis direction. The sealing member 210 is provided on the current collector foil 110 on which the positive electrode active material layer 120 and negative electrode active material layer 130 of the electrode unit 100 and end units 101 and 102 are not provided. Here, the thickness of each sealing member 210 is approximately the same as the thickness of the adjacent positive electrode active material layer 120 or negative electrode active material layer 130.

 部材ユニット10の積層体400はシール部材210を接合することで一体化することができる。さらに外周封止部材200で積層体400の周囲(外周)を覆うことで、蓄電装置1を形成することができる。 The stack 400 of component units 10 can be integrated by joining the sealing member 210. Furthermore, the periphery (outer periphery) of the stack 400 can be covered with the peripheral sealing member 200 to form the energy storage device 1.

 [1.1 部材ユニット10、エンドユニット101及び102の説明]
 まず、図3A及び図3Bを用いて、部材ユニット10の構成について、詳細に説明する。部材ユニット10は、1枚の集電箔110の両面に活物質層が形成され、さらに、活物質層の外周にシール部材210を配した1単位の部材ユニットである。部材ユニット10のそれぞれは、少なくとも、集電箔110と、集電箔110の一方の面に形成された正極活物質層120と、集電箔110の他方の面に形成された負極活物質層130と、それら正極活物質層120、負極活物質層130の外周にシール部材210を備えている。本実施の形態では、部材ユニット10の厚さ(積層方向の厚さ)は、100μm~400μm程度である。なお、図3Aでは簡略化のため、負極活物質層130の外周にシール部材210の記載は省略した。
[1.1 Description of the member unit 10, end units 101 and 102]
First, the configuration of the component unit 10 will be described in detail using Figures 3A and 3B. The component unit 10 is a single component unit in which active material layers are formed on both sides of a single current collector foil 110, and a sealing member 210 is disposed around the outer periphery of the active material layer. Each component unit 10 includes at least the current collector foil 110, a positive electrode active material layer 120 formed on one side of the current collector foil 110, a negative electrode active material layer 130 formed on the other side of the current collector foil 110, and a sealing member 210 around the outer periphery of the positive electrode active material layer 120 and the negative electrode active material layer 130. In this embodiment, the thickness (thickness in the stacking direction) of the component unit 10 is approximately 100 µm to 400 µm. Note that, for simplicity, the sealing member 210 around the outer periphery of the negative electrode active material layer 130 is omitted in Figure 3A.

 ここで、シール部材210は集電箔110の正極活物質層120と負極活物質層130の外周の集電箔110に設けられる。それぞれのシール部材210の厚さは、それぞれが近接する正極活物質層120と負極活物質層130とほぼ同じ厚さである。このことは、上記正極活物質層120と上記負極活物質層130の厚さが大きく異なる場合には、それぞれの活物質と近接したシール部材210の厚さを変える必要があることを意味する。 上記のように部材ユニット10は、1枚の集電箔110の両面に活物質層が形成され、さらに、活物質層の外周にシール部材210が配されている。このため、シール部材210が無い場合と比べて部材ユニット10の強度が高められており、これにより、積層時のシートの破れ等を低減する効果がある。 Here, the sealing members 210 are provided on the collector foil 110 around the outer periphery of the positive electrode active material layer 120 and negative electrode active material layer 130 of the collector foil 110. The thickness of each sealing member 210 is approximately the same as the thickness of the adjacent positive electrode active material layer 120 and negative electrode active material layer 130. This means that if the thicknesses of the positive electrode active material layer 120 and the negative electrode active material layer 130 differ significantly, the thickness of the sealing members 210 adjacent to each active material must be different. As described above, the component unit 10 has active material layers formed on both sides of a single collector foil 110, and further has sealing members 210 arranged around the outer periphery of the active material layers. This increases the strength of the component unit 10 compared to when the sealing members 210 are not provided, which has the effect of reducing sheet tearing during stacking.

 集電箔110は、平面視が六角形状(本実施の形態では正六角形状)である板状部材であり、金属箔である。図3Bに示すように、集電箔110は、積層方向(Z軸方向)に並ぶ2つの金属層111及び112を備えている。金属層111及び112は、平面視で同じ大きさかつ同じ形状を有する板状の部位である。以下では、金属層111及び112のうちの、正極活物質層120が形成される金属層111を正極金属層111とも称し、負極活物質層130が形成される金属層112を負極金属層112とも称する。 The current collector foil 110 is a plate-like member that is hexagonal in plan view (a regular hexagonal shape in this embodiment) and is a metal foil. As shown in FIG. 3B , the current collector foil 110 has two metal layers 111 and 112 that are aligned in the stacking direction (Z-axis direction). The metal layers 111 and 112 are plate-like portions that have the same size and shape in plan view. Hereinafter, of the metal layers 111 and 112, the metal layer 111 on which the positive electrode active material layer 120 is formed will also be referred to as the positive electrode metal layer 111, and the metal layer 112 on which the negative electrode active material layer 130 is formed will also be referred to as the negative electrode metal layer 112.

 正極金属層111は、集電箔110のうちのZ軸プラス方向に位置する金属層であり、負極金属層112は、集電箔110のうちのZ軸マイナス方向に位置する金属層である。つまり、集電箔110は、正極金属層111及び負極金属層112が互いに接続(接触または接合)された状態で、正極金属層111及び負極金属層112が積層方向に積層されて形成されている。正極金属層111及び負極金属層112は、一方が金属箔であり、他方が当該金属箔にメッキされるメッキ層でもよい。または、正極金属層111及び負極金属層112の双方が金属箔でもよい。正極金属層111及び負極金属層112の双方が金属箔の場合、集電箔110は、2つの金属箔同士が接合されたクラッド材等であってもよいし、2つの金属箔同士が接合されることなく接続(接触)した状態で2つの金属箔を備えていてもよい。 The positive electrode metal layer 111 is a metal layer of the current collector foil 110 located in the positive direction of the Z axis, and the negative electrode metal layer 112 is a metal layer of the current collector foil 110 located in the negative direction of the Z axis. In other words, the current collector foil 110 is formed by stacking the positive electrode metal layer 111 and the negative electrode metal layer 112 in the stacking direction, with the positive electrode metal layer 111 and the negative electrode metal layer 112 connected (contacting or bonded) to each other. One of the positive electrode metal layer 111 and the negative electrode metal layer 112 may be a metal foil, and the other may be a plated layer plated on the metal foil. Alternatively, both the positive electrode metal layer 111 and the negative electrode metal layer 112 may be metal foil. When both the positive electrode metal layer 111 and the negative electrode metal layer 112 are metal foil, the current collector foil 110 may be a clad material in which two metal foils are bonded together, or may comprise two metal foils that are connected (contacting) without being bonded to each other.

 正極金属層111の材質としては、アルミニウム、チタン、タンタル、ステンレス鋼等の金属またはそれらの合金が用いられる。これらの中でも、耐電位性、導電性の高さ及びコストのバランスから、正極金属層111の材質としてはアルミニウムまたはアルミニウム合金が好ましい。正極金属層111の形態としては、メッキ層でもよいが、加工性、コストの面から箔が好ましい。つまり、正極金属層111としては、アルミニウム箔が好ましい。負極金属層112の材質としては、銅、ニッケル、ステンレス鋼、ニッケルメッキ鋼等の金属またはそれらの合金が用いられ、これらの中でも、銅または銅合金が用いられるのが好ましい。負極金属層112の形態としては、メッキ層または箔(銅箔)が挙げられ、銅箔としては、圧延銅箔、電解銅箔等が例示される。集電箔110の厚さ(積層方向の厚さ)は、10μm~35μm程度であり、好ましくは20μm~30μm程度である。正極金属層111の厚さ(積層方向の厚さ)は、5μm~20μm程度であり、負極金属層112の厚さ(積層方向の厚さ)は、5μm~15μm程度である。 The positive electrode metal layer 111 is made of a metal such as aluminum, titanium, tantalum, or stainless steel, or an alloy thereof. Among these, aluminum or an aluminum alloy is preferred for the positive electrode metal layer 111, considering the balance between high potential resistance, high conductivity, and cost. The positive electrode metal layer 111 may be in the form of a plated layer, but foil is preferred for ease of processing and cost. In other words, aluminum foil is preferred for the positive electrode metal layer 111. The negative electrode metal layer 112 is made of a metal such as copper, nickel, stainless steel, or nickel-plated steel, or an alloy thereof, with copper or a copper alloy being preferred. The negative electrode metal layer 112 may be made of a plated layer or foil (copper foil), and examples of copper foil include rolled copper foil and electrolytic copper foil. The thickness (thickness in the stacking direction) of the current collector foil 110 is approximately 10 μm to 35 μm, and preferably approximately 20 μm to 30 μm. The thickness of the positive electrode metal layer 111 (thickness in the stacking direction) is approximately 5 μm to 20 μm, and the thickness of the negative electrode metal layer 112 (thickness in the stacking direction) is approximately 5 μm to 15 μm.

 集電箔110は、正極金属層111及び負極金属層112の複数層(2層)ではなく、1層(1枚の金属箔)で形成されてもよい。つまり、集電箔110を、1枚のステンレス等の正極金属層111としても負極金属層112としても機能し得る素材で形成してもよい。集電箔110を1枚の金属箔で形成することで、蓄電装置1の構成を簡素化することができる。 The current collecting foil 110 may be formed of a single layer (one sheet of metal foil) instead of multiple layers (two layers) of the positive electrode metal layer 111 and the negative electrode metal layer 112. In other words, the current collecting foil 110 may be formed of a material that can function as both the positive electrode metal layer 111 and the negative electrode metal layer 112, such as a single sheet of stainless steel. By forming the current collecting foil 110 from a single sheet of metal foil, the configuration of the energy storage device 1 can be simplified.

 正極活物質層120は、集電箔110の一方の表面(Z軸プラス方向の面)に形成された正極の活物質層である。具体的には、正極活物質層120は、正極金属層111上(正極金属層111の外面(Z軸プラス方向の面))に形成されている。正極活物質層120は、正極金属層111の外側にシール部材210が配され、その内側に六角形状(本実施の形態では正六角形状)に形成されている。正極活物質層120の厚さ(積層方向の厚さ)は、50μm~100μm程度である。 The positive electrode active material layer 120 is a positive electrode active material layer formed on one surface (the surface in the positive Z-axis direction) of the current collector foil 110. Specifically, the positive electrode active material layer 120 is formed on the positive electrode metal layer 111 (the outer surface (the surface in the positive Z-axis direction) of the positive electrode metal layer 111). A sealing member 210 is disposed on the outside of the positive electrode metal layer 111, and the positive electrode active material layer 120 is formed in a hexagonal shape (a regular hexagon in this embodiment) inside this. The thickness of the positive electrode active material layer 120 (thickness in the stacking direction) is approximately 50 μm to 100 μm.

 正極活物質層120は、正極活物質を含み、必要に応じて導電剤、バインダー、増粘剤、フィラー等の任意成分を含んでいる。正極活物質としては、LiM1O2(M1はLi、Fe、Ni、Mn、Co等から選択される1種または2種以上の金属元素)等のα-NaFeO2型結晶構造を有する層状リチウム遷移金属酸化物、LiM22O4(M2はLi、Fe、Ni、Mn、Co等から選択される1種または2種以上の金属元素)等のスピネル型リチウム遷移金属酸化物、LiM3PO4、LiM3SiO4、LiM3BO3(M3はLi、Fe、Ni、Mn、Co等から選択される1種または2種以上の金属元素)等のポリアニオン化合物等が挙げられる。正極活物質として、これら化合物の1種を単独で用いてもよく、2種以上を混合して用いてもよい。正極活物質層120に含有される導電剤としては、導電性を有する限り、特に限定されない。導電剤としては、ファーネスブラック、アセチレンブラック、ケッチェンブラック等のカーボンブラック、天然または人造の黒鉛などが挙げられる。バインダー(結着剤)としては、フッ素樹脂(ポリテトラフルオロエチレン(PTFE)、ポリフッ化ビニリデン(PVDF)等)、スルホン化EPDM、スチレンブタジエンゴム(SBR)などが挙げられる。増粘剤としては、カルボキシメチルセルロース(CMC)、メチルセルロース等の多糖類高分子が挙げられる。 The positive electrode active material layer 120 includes a positive electrode active material and, as necessary, optional components such as a conductive agent, a binder, a thickener, and a filler. Examples of the positive electrode active material include layered lithium transition metal oxides having an α-NaFeO 2 crystal structure, such as LiM 1 O 2 (where M 1 is one or more metal elements selected from Li, Fe, Ni, Mn, Co, etc.), spinel-type lithium transition metal oxides, such as LiM 2 O 4 (where M 2 is one or more metal elements selected from Li, Fe, Ni, Mn, Co, etc.), and polyanion compounds, such as LiM 3 PO 4 , LiM 3 SiO 4 , and LiM 3 BO 3 (where M 3 is one or more metal elements selected from Li, Fe, Ni, Mn, Co, etc.). As the positive electrode active material, one of these compounds may be used alone, or two or more may be mixed and used. The conductive agent contained in the positive electrode active material layer 120 is not particularly limited as long as it has conductivity. Examples of the conductive agent include carbon black such as furnace black, acetylene black, and ketjen black, and natural or artificial graphite. Examples of the binder (binding agent) include fluororesin (polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), etc.), sulfonated EPDM, and styrene butadiene rubber (SBR). Examples of the thickener include polysaccharide polymers such as carboxymethyl cellulose (CMC) and methyl cellulose.

 負極活物質層130は、集電箔110の他方の表面(Z軸マイナス方向の面)に形成された負極の活物質層である。具体的には、負極活物質層130は、負極金属層112上(負極金属層112の外面(Z軸マイナス方向の面))に形成されている。負極活物質層130は、負極金属層112の外側にシール部材210が配され、その内側に六角形状(本実施の形態では正六角形状)に形成されている。負極活物質層130は、Z軸方向からの透過平面視で正極活物質層120よりもサイズが大きく形成されている。平面視でサイズが大きいとは、XY平面の面積が大きく、Z軸方向から透過的に見た場合、対象となる部位に対して、はみ出される部分がないことをいう。つまり、Z軸方向から透過的に見て、負極活物質層130は、面積が大きく、また、対向する正極活物質層120にはみ出される部分がない。Z軸方向からの透過平面視で、負極金属層112と負極活物質層130とは、同じ若しくは類似した形状であり、負極活物質層130の厚さ(積層方向の厚さ)は、40μm~60μm程度である。 The negative electrode active material layer 130 is a negative electrode active material layer formed on the other surface (the surface facing the negative Z-axis) of the current collector foil 110. Specifically, the negative electrode active material layer 130 is formed on the negative electrode metal layer 112 (the outer surface (the surface facing the negative Z-axis) of the negative electrode metal layer 112). A sealing member 210 is disposed on the outside of the negative electrode metal layer 112, and the negative electrode active material layer 130 is formed in a hexagonal shape (a regular hexagon in this embodiment) inside this sealing member 210. The negative electrode active material layer 130 is formed to be larger in size than the positive electrode active material layer 120 when viewed transparently from the Z-axis direction. "Large size" in plan view means that the area in the XY plane is large and that no portion protrudes beyond the target area when viewed transparently from the Z-axis direction. In other words, when viewed transparently from the Z-axis direction, the negative electrode active material layer 130 has a large area and no portion protrudes into the opposing positive electrode active material layer 120. When viewed transparently from the Z-axis direction, the negative electrode metal layer 112 and the negative electrode active material layer 130 have the same or similar shapes, and the thickness of the negative electrode active material layer 130 (thickness in the stacking direction) is approximately 40 μm to 60 μm.

 負極活物質層130は、負極活物質を含み、必要に応じて導電剤、バインダー、増粘剤、フィラー等の任意成分を含んでいる。導電剤、バインダー、増粘剤、フィラー等の任意成分は、正極活物質層120と同様のものを用いることができる。負極活物質としては、通常、リチウムイオンを吸蔵及び放出することができる材質が用いられる。具体的には、Si、Sn等の金属または半金属;Si酸化物、Sn酸化物等の金属酸化物または半金属酸化物;黒鉛(グラファイト)、非黒鉛質炭素(易黒鉛化性炭素または難黒鉛化性炭素)等の炭素材料などが挙げられる。 The negative electrode active material layer 130 contains a negative electrode active material and, if necessary, optional components such as a conductive agent, binder, thickener, and filler. The optional components such as the conductive agent, binder, thickener, and filler can be the same as those used in the positive electrode active material layer 120. The negative electrode active material typically uses a material that can absorb and release lithium ions. Specific examples include metals or semi-metals such as Si and Sn; metal oxides or semi-metal oxides such as Si oxide and Sn oxide; and carbon materials such as graphite and non-graphitic carbon (easily graphitizable carbon or non-graphitizable carbon).

 次に、エンドユニット101及び102の構成について説明する。エンドユニット101は、部材ユニット10よりもZ軸マイナス方向に配置される。エンドユニット102は、部材ユニット10よりもZ軸プラス方向に配置される。エンドユニット101及び102は、複数の部材ユニット10をZ軸方向で挟み込む部位である。 Next, the configuration of end units 101 and 102 will be described. End unit 101 is positioned in the negative direction of the Z axis relative to component unit 10. End unit 102 is positioned in the positive direction of the Z axis relative to component unit 10. End units 101 and 102 are parts that sandwich multiple component units 10 in the Z axis direction.

 エンドユニット101は、少なくとも、正極金属層111と、正極金属層111のZ軸プラス方向の面に形成された正極活物質層120と、を備えている。エンドユニット101が備える正極金属層111及び正極活物質層120の構成は、上述した部材ユニット10が備える集電箔110の正極金属層111及び正極活物質層120の構成と同様である。シール部材210は、エンドユニット101の正極活物質層120が設けられた面の、正極活物質層120の外周の正極金属層111上に設けられる。ここで、シール部材210の厚さは、正極活物質層120とほぼ同じ厚さである。 The end unit 101 comprises at least a positive electrode metal layer 111 and a positive electrode active material layer 120 formed on the surface of the positive electrode metal layer 111 in the positive Z-axis direction. The configurations of the positive electrode metal layer 111 and positive electrode active material layer 120 of the end unit 101 are the same as the configurations of the positive electrode metal layer 111 and positive electrode active material layer 120 of the current collector foil 110 of the component unit 10 described above. The sealing member 210 is provided on the positive electrode metal layer 111 around the outer periphery of the positive electrode active material layer 120 on the surface of the end unit 101 on which the positive electrode active material layer 120 is provided. Here, the thickness of the sealing member 210 is approximately the same as the thickness of the positive electrode active material layer 120.

 エンドユニット102は、少なくとも、集電箔110と、集電箔110のZ軸マイナス方向の面に配置された負極活物質層130と、を備えている。エンドユニット102が備える集電箔110及び負極活物質層130の構成は、上述した部材ユニット10が備える集電箔110及び負極活物質層130の構成と同様である。シール部材210は、エンドユニット102の負極活物質層130が設けられた面の、負極活物質層130の外周の集電箔110に設けられる。ここで、シール部材210の厚さは負極活物質層130とほぼ、同じ厚さである。 The end unit 102 comprises at least a current collector foil 110 and a negative electrode active material layer 130 arranged on the surface of the current collector foil 110 facing in the negative Z-axis direction. The configurations of the current collector foil 110 and negative electrode active material layer 130 provided in the end unit 102 are the same as the configurations of the current collector foil 110 and negative electrode active material layer 130 provided in the component unit 10 described above. The sealing member 210 is provided on the current collector foil 110 around the outer periphery of the negative electrode active material layer 130 on the surface of the end unit 102 on which the negative electrode active material layer 130 is provided. Here, the thickness of the sealing member 210 is approximately the same as the thickness of the negative electrode active material layer 130.

 [1.2 セパレータ140及びエンド部材300の説明]
 セパレータ140は、樹脂からなる微多孔性のシートである。セパレータ140は、部材ユニット10と部材ユニット10との間、エンドユニット101と部材ユニット10との間、及び、エンドユニット102と部材ユニット10との間に、それぞれ配置される。具体的には、セパレータ140は、正極活物質層120と負極活物質層130との間に配置される。セパレータ140は、透過平面視で負極活物質層130よりもサイズが大きい六角形状(本実施の形態では正六角形状)に形成されている。本実施の形態では、セパレータ140のサイズは、平面視で集電箔110のそれと同じに表現したが、平面視で集電箔110よりもサイズが小さくてもよいし、大きくてもよい。セパレータ140の厚さ(積層方向の厚さ)は、15μm~20μm程度である。
1.2 Description of the separator 140 and the end member 300
The separator 140 is a microporous sheet made of resin. The separator 140 is disposed between the component units 10, between the end units 101 and the component units 10, and between the end units 102 and the component units 10. Specifically, the separator 140 is disposed between the positive electrode active material layer 120 and the negative electrode active material layer 130. The separator 140 is formed in a hexagonal shape (a regular hexagonal shape in this embodiment) that is larger than the negative electrode active material layer 130 in a transparent planar view. In this embodiment, the size of the separator 140 is expressed as being the same as that of the current collector foil 110 in a planar view, but the size may be smaller or larger than that of the current collector foil 110 in a planar view. The thickness of the separator 140 (thickness in the stacking direction) is approximately 15 μm to 20 μm.

 セパレータ140の材質としては、織布、不織布、多孔質樹脂フィルム等が用いられる。これらの中でも多孔質樹脂フィルムが好ましい。多孔質樹脂フィルムの主成分としては、強度の観点から例えばポリエチレン、ポリプロピレン等のポリオレフィンが好ましい。セパレータ140として、これらの多孔質樹脂フィルムの表面にフィラーを含む層を形成した多層のフィルムであってもよい。 Separator 140 can be made from a woven fabric, a nonwoven fabric, a porous resin film, or the like. Of these, porous resin film is preferred. From the standpoint of strength, the main component of the porous resin film is preferably a polyolefin such as polyethylene or polypropylene. Separator 140 may also be a multilayer film in which a layer containing a filler is formed on the surface of such a porous resin film.

 エンド部材300は、複数の部材ユニット10よりも、蓄電装置1における積層方向(Z軸方向)の端部に配置される部材である。本実施の形態では、一対のエンド部材300が、蓄電装置1の最もZ軸マイナス方向端部及び最もZ軸プラス方向端部に配置される。一対のエンド部材300は、エンドユニット101及び102(が備える集電箔110)に接続される。これにより、一対のエンド部材300は、その間に位置する複数の部材ユニット10並びにエンドユニット101及び102を、積層方向(Z軸方向)の両側から挟み込む。 The end members 300 are members that are positioned closer to the ends of the energy storage device 1 in the stacking direction (Z-axis direction) than the multiple component units 10. In this embodiment, a pair of end members 300 are positioned at the ends of the energy storage device 1 closest to the negative Z-axis direction and the positive Z-axis direction. The pair of end members 300 are connected to the end units 101 and 102 (and the current collecting foils 110 provided therein). As a result, the pair of end members 300 sandwich the multiple component units 10 and end units 101 and 102 located between them from both sides in the stacking direction (Z-axis direction).

 エンド部材300は、アルミニウム、アルミニウム合金、銅、銅合金、ニッケル等の金属製の導電部材若しくはそれらの組み合わせ、または、金属以外の導電性の部材等で形成されている。エンド部材300は、正極金属層111と接続されるため、アルミニウムなど、正極金属層111と同じ材質で形成されるのが好ましい。エンド部材300は、他の導電部材(バスバー、冷却板等。図示せず)を介して、他の蓄電装置1が備える他のエンド部材300と電気的に接続される。エンド部材300の厚さ(積層方向の厚さ)は、0.5mm~3mm程度である。蓄電装置1は、エンド部材300の外側(Z軸方向の外側)に他の導電部材を備えていてもよい。また、抵抗低減のために、エンド部材300を外部から加圧する機構を設けても良い。 The end member 300 is formed from a conductive metal material such as aluminum, aluminum alloy, copper, copper alloy, or nickel, or a combination thereof, or a conductive material other than metal. Because the end member 300 is connected to the positive electrode metal layer 111, it is preferably formed from the same material as the positive electrode metal layer 111, such as aluminum. The end member 300 is electrically connected to another end member 300 provided in another energy storage device 1 via another conductive member (bus bar, cooling plate, etc., not shown). The thickness of the end member 300 (thickness in the stacking direction) is approximately 0.5 mm to 3 mm. The energy storage device 1 may have another conductive member on the outside of the end member 300 (outside in the Z-axis direction). A mechanism for applying pressure to the end member 300 from the outside may also be provided to reduce resistance.

 [1.3 シール部材210および外周封止部材200の説明]
 シール部材210は、部材ユニット10、エンドユニット101、102の正極活物質層120および/もしくは負極活物質層130の外周の集電箔110の両面に設けられる。それぞれのシール部材210の厚さは、それぞれ近接する正極活物質層120もしくは負極活物質層130とほぼ同じ厚さである。シール部材210は、電池部材間を接合する平面視で外形が六角形状(本実施の形態では正六角形状)となる部材である。
[1.3 Description of the sealing member 210 and the peripheral sealing member 200]
The sealing members 210 are provided on both sides of the current collector foil 110 on the outer periphery of the positive electrode active material layer 120 and/or negative electrode active material layer 130 of the component unit 10 and the end units 101, 102. The thickness of each sealing member 210 is approximately the same as the thickness of the adjacent positive electrode active material layer 120 or negative electrode active material layer 130. The sealing members 210 are components that join battery components together and have a hexagonal outer shape (a regular hexagon in this embodiment) in a plan view.

 外周封止部材200は蓄電装置1の周囲(外周)に設けられた緻密な樹脂層である。 The peripheral sealing member 200 is a dense resin layer provided around (the outer periphery of) the energy storage device 1.

 シール部材210および外周封止部材200は、ポリカーボネート(PC)、ポリプロピレン(PP)、ポリエチレン(PE)、ポリスチレン(PS)、ポリフェニレンサルファイド樹脂(PPS)、ポリフェニレンエーテル(PPE(変性PPEを含む))、ポリエチレンテレフタラート(PET)、ポリブチレンテレフタレート(PBT)、ポリエーテルエーテルケトン(PEEK)、テトラフルオロエチレン・パーフルオロアルキルビニルエーテル(PFA)、ポリテトラフルオロエチレン(PTFE)、ポリエーテルサルフォン(PES)、ポリアミド(PA)、ABS樹脂、若しくは、それらの複合材料等の絶縁部材により形成されている。 The sealing member 210 and the peripheral sealing member 200 are formed from insulating materials such as polycarbonate (PC), polypropylene (PP), polyethylene (PE), polystyrene (PS), polyphenylene sulfide resin (PPS), polyphenylene ether (PPE (including modified PPE)), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyether ether ketone (PEEK), tetrafluoroethylene perfluoroalkyl vinyl ether (PFA), polytetrafluoroethylene (PTFE), polyethersulfone (PES), polyamide (PA), ABS resin, or composite materials thereof.

 上記説明ではシール部材210は、部材ユニット10、エンドユニット101及び102などの部材ユニット10の一部分として説明したが、シール部材210を単独の部材ユニット10として、積層することも可能である。ただし、その際に正極活物質層120側のシール部材210と負極活物質層130側のシール部材210に同じものを用いる場合には、正極活物質層120と負極活物質層130が、ほぼ同じ厚さであることが必要となる。正極活物質層120と負極活物質層130の厚さが大きく異なる場合には、正極側と負極側でシール部材210の厚さを変える必要がある。 In the above explanation, the sealing member 210 is described as part of a component unit 10 such as the component unit 10, end units 101 and 102, but it is also possible to stack the sealing member 210 as a standalone component unit 10. However, if the same sealing member 210 is used for the positive electrode active material layer 120 side and the negative electrode active material layer 130 side, the positive electrode active material layer 120 and the negative electrode active material layer 130 must be approximately the same thickness. If the thicknesses of the positive electrode active material layer 120 and the negative electrode active material layer 130 differ significantly, the thickness of the sealing member 210 on the positive electrode side and the negative electrode side must be different.

 このように、シール部材210は、部材ユニット10とセパレータ140、エンドユニット101とセパレータ140、エンドユニット102とセパレータ140の間をシールする部材である。ここでシール部材210は電池性能に悪影響を与えない接着剤、粘着剤などでも良く、接着剤としてはアクリル樹脂系接着剤、α-オレフィン系接着剤、ウレタン樹脂系接着剤、エーテル系セルロース系接着剤、エチレン-酢酸ビニル樹脂エマルジョン接着剤、エポキシ樹脂系接着剤、塩化ビニル樹脂溶剤系接着剤、シアノアクリレート系接着剤、シリコーン系接着剤、ニトロセルロース接着剤、フェノール樹脂系接着剤であって良い。また、粘着剤としてはアクリル系粘着剤、シリコーン系粘着剤、ゴム系粘着剤であっても良く、また、樹脂テープの両面に粘着剤を塗布した粘着テープをシール部材210に用いても良い。両面テープをシール部材210に用いると部材ユニット10を積層した段階で、部材ユニット10間をシール部材210で接合することが可能となり、積層体400の一体化を図ることができる。 As such, the sealing member 210 is a member that seals between the component unit 10 and the separator 140, between the end unit 101 and the separator 140, and between the end unit 102 and the separator 140. The sealing member 210 may be an adhesive or pressure-sensitive adhesive that does not adversely affect battery performance. Examples of adhesives that may be used include acrylic resin-based adhesives, α-olefin-based adhesives, urethane resin-based adhesives, ether-based cellulose-based adhesives, ethylene-vinyl acetate resin emulsion adhesives, epoxy resin-based adhesives, vinyl chloride resin solvent-based adhesives, cyanoacrylate-based adhesives, silicone-based adhesives, nitrocellulose adhesives, and phenolic resin-based adhesives. Examples of pressure-sensitive adhesives include acrylic-based adhesives, silicone-based adhesives, and rubber-based adhesives. Alternatively, the sealing member 210 may be made of adhesive tape with adhesive applied to both sides of a resin tape. Using double-sided tape for the sealing member 210 allows the component units 10 to be joined together with the sealing member 210 after stacking, thereby integrating the laminate 400.

 外周封止部材200は、蓄電装置1の外周に亘って設けられた緻密な樹脂層であり、蓄電装置と外部との間を封止する筒状(六角筒状)の部材である。後述する方法によって電池部材を積層し、部材ユニット10の接続部を取り外したのち、積層体400を枠部材30から取り出し、その外周に外周封止部材200を塗布することで蓄電装置1の外周を樹脂層で被覆することができる。一方で、積層に用いた枠部材30をそのまま用いて、枠部材30と積層体400の外周を外周封止部材200で接合し、さらに、枠部材蓋を接合することによって、蓄電装置1を構成することもできる。 The peripheral sealing member 200 is a dense resin layer provided around the periphery of the energy storage device 1, and is a cylindrical (hexagonal cylindrical) member that seals the energy storage device from the outside. After stacking the battery components using the method described below and removing the connecting portions of the component units 10, the stacked body 400 is removed from the frame member 30 and the peripheral sealing member 200 is applied to its periphery, thereby covering the periphery of the energy storage device 1 with a resin layer. Alternatively, the energy storage device 1 can be constructed by using the frame member 30 used for stacking as is, joining the peripheries of the frame member 30 and stacked body 400 with the peripheral sealing member 200, and then joining a frame member lid.

 前述の本発明の説明において、本来、蓄電装置1に必要な、端子構造、ガス排出弁、ガス排出構造、冷却構造、電解液注入口、等に関しては、本発明の趣旨に関係しないため説明を省略した。 In the above description of the present invention, the terminal structure, gas exhaust valve, gas exhaust structure, cooling structure, electrolyte injection port, etc., which are essentially required for the energy storage device 1, have been omitted as they are not relevant to the spirit of the present invention.

 蓄電装置1のセパレータ140には電解液が含侵され、電解質層(図示省略)が形成される。電解質層は、本実施の形態では、非水系の液体状の電解質(電解液)であるが、ゲル状の電解質等でもよい。これら電解質としては、適宜公知のものを使用できる。電解液(非水電解質)としては、非水溶媒に電解質塩が溶解されたものを用いてもよい。非水溶媒としては、例えばエチレンカーボネート(EC)、プロピレンカーボネート(PC)、等の環状カーボネート、ジエチルカーボネート(DEC)、ジメチルカーボネート(DMC)、エチルメチルカーボネート(EMC)等の鎖状カーボネートなどが挙げられる。電解質塩としては、リチウム塩が好ましい。上記リチウム塩としては、LiPF、LiPO、LiBF、LiClO、LiN(SOF)、LiN(SOCF)等の無機リチウム塩が挙げられる。 The separator 140 of the energy storage device 1 is impregnated with an electrolytic solution to form an electrolyte layer (not shown). In this embodiment, the electrolyte layer is a non-aqueous liquid electrolyte (electrolytic solution), but a gel electrolyte or the like may also be used. Any known electrolyte can be used as appropriate. The electrolytic solution (nonaqueous electrolyte) may be one in which an electrolyte salt is dissolved in a non-aqueous solvent. Examples of non-aqueous solvents include cyclic carbonates such as ethylene carbonate (EC) and propylene carbonate (PC), and chain carbonates such as diethyl carbonate (DEC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC). A lithium salt is preferred as the electrolyte salt. Examples of the lithium salt include inorganic lithium salts such as LiPF 6 , LiPO 2 F 2 , LiBF 4 , LiClO 4 , LiN(SO 2 F) 2 , and LiN(SO 2 CF 3 ).

 以上の構成において、セパレータ140と、セパレータ140をZ軸方向で挟む正極活物質層120及び負極活物質層130と、これらをZ軸方向で挟む正極金属層111及び負極金属層112とを、1つの蓄電素子と称してもよい。この場合、蓄電装置1は、Z軸方向に積層された複数の蓄電素子がZ軸方向において一対のエンド部材300で挟まれ、これらの周囲がシール部材210、外周封止部材200で囲われた構成を有する蓄電素子としても説明できる。 In the above configuration, the separator 140, the positive electrode active material layer 120 and the negative electrode active material layer 130 sandwiching the separator 140 in the Z-axis direction, and the positive electrode metal layer 111 and the negative electrode metal layer 112 sandwiching these in the Z-axis direction may be referred to as a single energy storage element. In this case, the energy storage device 1 can also be described as an energy storage element having a configuration in which multiple energy storage elements stacked in the Z-axis direction are sandwiched between a pair of end members 300 in the Z-axis direction, and the periphery of these is surrounded by a sealing member 210 and a peripheral sealing member 200.

 [1.4 接続部12、21の説明]
 接続部12、21は、部材ユニット連続体10A、セパレータ連続体140Aにおいて部材ユニット10と部材ユニット10を接続する部位である。この部位は必ずしもそれぞれの部材ユニット10と同じ素材で形成する必要はなく各部材ユニット10の素材と異なる素材で形成し、各部材ユニット10と接着、接合されていても良い。例えば、部材ユニット10の素材は金属製の集電箔110であるが、接続部12は金属製である必要はなく、PET樹脂等の柔軟性を持つ樹脂フィルムであっても良い。このような樹脂フィルムを接続部12に採用することで、接続部12を切り離すときの金属コンタミの発生を防止することができる。また、部材ユニット10と接続部12は接着テープ等を用いて接合されていても良く、この場合には接続部12を切り離す際には、接着テープを外すことで、接続部12と部材ユニット10を切り離すことができる。セパレータ連続体140Aにおいても同様に、部材ユニット10の素材と接続部21の素材は異なっても良いし、また、部材ユニット10と接着、接合されていても良い。
[1.4 Description of connection parts 12, 21]
The connection portions 12, 21 are portions that connect the component units 10 to each other in the component unit continuous body 10A and the separator continuous body 140A. These portions do not necessarily have to be made of the same material as the respective component units 10; they may be made of a material different from the material of each component unit 10 and be adhered or bonded to each component unit 10. For example, while the component unit 10 is made of a metal current collector foil 110, the connection portion 12 does not have to be made of metal and may be a flexible resin film such as PET resin. Using such a resin film for the connection portion 12 can prevent metal contamination when the connection portion 12 is separated. Furthermore, the component unit 10 and the connection portion 12 may be joined using adhesive tape or the like. In this case, when separating the connection portion 12, the connection portion 12 can be separated from the component unit 10 by removing the adhesive tape. Similarly, in the separator continuous body 140A, the material of the member units 10 and the material of the connecting portions 21 may be different, or they may be bonded or joined to the member units 10.

 [実施例の説明]
 次に、本実施の形態における蓄電装置1の製造方法について詳細に説明する。図4は、本実施の形態に係る蓄電装置1の製造方法における製造工程を示すフローチャートである。本実施例では図4の工程順に製造工程の説明を行う。図5Aは、本実施の形態に係る蓄電装置1の製造方法における部材ユニット連続体10Aの外観を示す平面図である。図5Bは、本実施の形態に係る蓄電装置1の製造方法におけるセパレータ連続体140Aの外観を示す平面図である。図6は、本実施の形態に係る蓄電装置1の製造方法における枠部材30と、部材ユニット連続体10Aと、セパレータ連続体140Aと、の構成を示す斜視図である。
[Description of the embodiment]
Next, a method for manufacturing the energy storage device 1 according to the present embodiment will be described in detail. FIG. 4 is a flowchart showing manufacturing steps in the method for manufacturing the energy storage device 1 according to the present embodiment. In this example, the manufacturing steps will be described in the order of the steps in FIG. 4. FIG. 5A is a plan view showing the appearance of a component unit continuous body 10A in the method for manufacturing the energy storage device 1 according to the present embodiment. FIG. 5B is a plan view showing the appearance of a separator continuous body 140A in the method for manufacturing the energy storage device 1 according to the present embodiment. FIG. 6 is a perspective view showing the configurations of the frame member 30, the component unit continuous body 10A, and the separator continuous body 140A in the method for manufacturing the energy storage device 1 according to the present embodiment.

 図4に示すように本実施の形態の蓄電装置1の製造方法は1つの工程準備と11の工程によって構成される。まず、工程準備としては、蓄電装置1を構成するための部材を準備する。準備する主要な部材としては、枠部材30、部材ユニット連続体10A、セパレータ連続体140A、エンド部材300、エンドユニット101、102である。 As shown in Figure 4, the manufacturing method for the energy storage device 1 of this embodiment consists of one process preparation step and 11 processes. First, in the process preparation step, the components for constructing the energy storage device 1 are prepared. The main components to be prepared are the frame member 30, the component unit continuous body 10A, the separator continuous body 140A, the end member 300, and the end units 101 and 102.

 ここで枠部材30は、図6に示すように一対の側壁31と、一対の側壁32と、一対の側壁33と、底壁34と、を備える平面視で六角形状(正六角形状)の枠状の部材である。一対の側壁31は、部材ユニット連続体10Aに対応する位置に配置される平板状の壁部であり、部材ユニット連続体10Aの接続部12が挿入される一対の開口部31aが形成されている。一対の側壁32は、セパレータ連続体140Aに対応する位置に配置される平板状の壁部であり、セパレータ連続体140Aの一対の接続部21が挿入される一対の開口部32aが形成されている。なお、本実施の形態では、一対の側壁33には、開口部は形成されていない。本実施例では枠部材30の形状はその内部に部材ユニット10とその接続部12を係合するため、部材ユニット10と同じ形の正六角形状としたが、枠部材30の目的は部材ユニット10の位置合わせにあるため、その目的を達成できれば、部材ユニット10と同一形状である必要はない。 Here, as shown in FIG. 6, the frame member 30 is a frame-shaped member having a hexagonal (regular hexagonal) shape in a plan view, and includes a pair of side walls 31, a pair of side walls 32, a pair of side walls 33, and a bottom wall 34. The pair of side walls 31 are flat wall portions positioned corresponding to the component unit continuum 10A, and are formed with a pair of openings 31a into which the connecting portions 12 of the component unit continuum 10A are inserted. The pair of side walls 32 are flat wall portions positioned corresponding to the separator continuum 140A, and are formed with a pair of openings 32a into which the pair of connecting portions 21 of the separator continuum 140A are inserted. Note that, in this embodiment, no openings are formed in the pair of side walls 33. In this embodiment, the shape of the frame member 30 is a regular hexagon, the same shape as the component unit 10, to engage the component unit 10 and its connecting portions 12 therein. However, since the purpose of the frame member 30 is to align the component unit 10, the frame member 30 does not need to have the same shape as the component unit 10 as long as that purpose is achieved.

 枠部材30の内部空間のサイズ(一対の側壁31、一対の側壁32及び一対の側壁33の内面で形成される六角形のサイズ)は、平面視で、集電箔110(及び中間箔11)の外形のサイズと同じに形成されている。これにより、枠部材30内に集電箔110(及び中間箔11)を配置することで、集電箔110(及び中間箔11)を容易に位置決めできる。枠部材30の内部空間のサイズは、寸法公差(誤差)を考慮して、集電箔110(及び中間箔11)の外形のサイズよりも少し大きく形成されてもよい。また、枠部材30の材質としてはアルミニウム、ステンレス等の金属であっても良いが、ポリエチレン、ポリプロピレン等の樹脂材料であっても良い。 The size of the internal space of the frame member 30 (the size of the hexagon formed by the inner surfaces of a pair of side walls 31, a pair of side walls 32, and a pair of side walls 33) is formed to be the same as the external size of the current collector foil 110 (and intermediate foil 11) in a plan view. This makes it easy to position the current collector foil 110 (and intermediate foil 11) by placing the current collector foil 110 (and intermediate foil 11) within the frame member 30. The size of the internal space of the frame member 30 may be formed to be slightly larger than the external size of the current collector foil 110 (and intermediate foil 11), taking dimensional tolerances (errors) into consideration. The material of the frame member 30 may be metal such as aluminum or stainless steel, or a resin material such as polyethylene or polypropylene.

 第1工程では、枠部材30のZ軸方向からエンド部材300を挿入する。ここで、エンド部材300は予め所定の寸法に形成されており、単独の部材として、枠部材30に挿入される。 In the first step, the end member 300 is inserted into the frame member 30 from the Z-axis direction. Here, the end member 300 is pre-formed to a predetermined dimension and is inserted into the frame member 30 as a standalone member.

 枠部材30に部材ユニット10を供給する際には、部材ユニット連続体10Aとして供給する方法と、単独の部材ユニット10として設置する方法があるが、本実施例では部材ユニット10とセパレータ140のみを連続体として供給することとし、その他の部材ユニット10は単独の部材として積層することとした。 When supplying component units 10 to a frame member 30, there are two methods: supplying them as a component unit continuum 10A, or installing them as individual component units 10. In this embodiment, however, only the component units 10 and separators 140 are supplied as a continuum, and the other component units 10 are stacked as individual components.

 第2工程では、枠部材30のZ軸方向からエンドユニット101を単独部材として挿入する。ここで、エンドユニット101は、少なくとも、正極金属層111と、正極金属層111のZ軸プラス方向の面に形成された正極活物質層120と、正極活物質層120の外周に設けられたシール部材210と、を備えている。 In the second step, the end unit 101 is inserted as a separate component into the frame member 30 from the Z-axis direction. The end unit 101 includes at least a positive electrode metal layer 111, a positive electrode active material layer 120 formed on the surface of the positive electrode metal layer 111 facing in the positive Z-axis direction, and a sealing member 210 provided on the outer periphery of the positive electrode active material layer 120.

 第3工程では、枠部材30のZ軸プラス方向から、セパレータ連続体140Aを用いて、セパレータ140を挿入する。セパレータ連続体140Aは図5Bに示すように六角形のセパレータ140が接続部21によって直線状に接合された形状をしており、ロール状の連続体として枠部材30に供給することが可能である。 In the third step, separators 140 are inserted from the positive Z-axis direction of frame member 30 using separator continuum 140A. As shown in Figure 5B, separator continuum 140A has a shape in which hexagonal separators 140 are joined in a linear fashion by connecting portions 21, and can be supplied to frame member 30 as a roll-shaped continuum.

 図6に示すようにセパレータ連続体140Aのセパレータ140と接続部21は枠部材30と係合するように構成されており、セパレータ連続体140Aを枠部材30に挿入後は接続部21(図7Aでは接続部21b)および次のセパレータ140(図7Aではセパレータ140b)は枠部材30の開口部32aから枠部材30外に突出している。 As shown in Figure 6, the separator 140 and connecting portion 21 of the separator continuum 140A are configured to engage with the frame member 30, and after the separator continuum 140A is inserted into the frame member 30, the connecting portion 21 (connecting portion 21b in Figure 7A) and the next separator 140 (separator 140b in Figure 7A) protrude outside the frame member 30 through the opening 32a in the frame member 30.

 第4工程では、セパレータ140を配置した枠部材30のZ軸プラス方向から、部材ユニット連続体10Aを用いて、部材ユニット10を挿入する。本実施例の工程では、図5Aに示すように、図3Aに示した六角形状(正六角形状)の部材ユニット10と、六角形状(正六角形状)の集電箔110に六角形状の貫通孔が形成された中間箔11とが、接続部12によって交互に接続された部材ユニット連続体10Aを用いる。 In the fourth step, the component unit 10 is inserted from the positive Z-axis direction of the frame member 30 in which the separator 140 is arranged, using a component unit continuum 10A. In this step, as shown in Figure 5A, a component unit continuum 10A is used in which the hexagonal (regular hexagonal) component units 10 shown in Figure 3A and intermediate foils 11 with hexagonal through holes formed in hexagonal (regular hexagonal) current collecting foils 110 are alternately connected by connecting portions 12.

 部材ユニット10には、一方の面(Z軸プラス方向の面)に正極活物質層120が形成され、他方の面(Z軸マイナス方向の面)に負極活物質層130が形成されている。また、正極活物質層120と負極活物質層130との外周にシール部材210を備えている。 The component unit 10 has a positive electrode active material layer 120 formed on one surface (the surface facing the positive Z-axis direction) and a negative electrode active material layer 130 formed on the other surface (the surface facing the negative Z-axis direction). In addition, a sealing member 210 is provided around the outer periphery of the positive electrode active material layer 120 and the negative electrode active material layer 130.

 この部材ユニット連続体10Aは、複数の部材ユニット10と、複数の中間箔11と、これらを交互に接続する複数の接続部12と、を備えるロール状の連続体である。本実施の形態では、図5Aに示すように、Y軸方向において、接続部12a、部材ユニット10a、接続部12b、中間箔11a、接続部12c、部材ユニット10b、接続部12d、中間箔11bと一列に(直線状に)並んで配置されている。 This component unit continuum 10A is a roll-shaped continuum comprising a plurality of component units 10, a plurality of intermediate foils 11, and a plurality of connecting portions 12 that alternately connect these. In this embodiment, as shown in Figure 5A, the connecting portion 12a, component unit 10a, connecting portion 12b, intermediate foil 11a, connecting portion 12c, component unit 10b, connecting portion 12d, and intermediate foil 11b are arranged in a row (linearly) in the Y-axis direction.

 図6に示すように部材ユニット連続体10Aの部材ユニット10と接続部12は枠部材30と係合するように構成されており、部材ユニット連続体10Aを枠部材30に挿入後は接続部12(図7Aでは接続部12b)および中間箔11(図7Aでは中間箔11a)は枠部材30の開口部31aから枠部材30外に突出している。 As shown in Figure 6, the component units 10 and connection portions 12 of the component unit continuum 10A are configured to engage with the frame member 30, and after the component unit continuum 10A is inserted into the frame member 30, the connection portions 12 (connection portion 12b in Figure 7A) and intermediate foil 11 (intermediate foil 11a in Figure 7A) protrude outside the frame member 30 through the opening 31a in the frame member 30.

 本実施例の中間箔11は、集電箔110と同じ材質、かつ、集電箔110と同じ形状及び同じサイズの外形を有するとともに、中央部に大きな貫通孔が形成されていてもよい。中間箔11aには、貫通孔11a1が形成され、中間箔11bには、貫通孔11b1が形成されている。当該貫通孔(貫通孔11a1及び11b1)は、中間箔11をZ軸方向に貫通する平面視で六角形状(正六角形状)の貫通孔であり、その孔の大きさは平面視で正極活物質層120とその外周に形成されたシール部材210を合わせた部分よりもサイズが大きい。また、本実施の形態では、当該貫通孔(貫通孔11a1及び11b1)は、平面視で、負極活物質層130とその外周に形成されたシール部材210を合わせた部分よりもサイズが小さく、セパレータ140よりもサイズが小さい。このように、中間箔11は、平面視で六角形(正六角形)の環状の部材である。 In this embodiment, the intermediate foil 11 is made of the same material as the current collector foil 110, has the same shape and size as the current collector foil 110, and may have a large through-hole formed in the center. Through-hole 11a1 is formed in intermediate foil 11a, and through-hole 11b1 is formed in intermediate foil 11b. The through-holes (through-holes 11a1 and 11b1) are hexagonal (regular hexagonal) in plan view, penetrating the intermediate foil 11 in the Z-axis direction, and are larger in size than the combined part of the positive electrode active material layer 120 and the sealing member 210 formed around its periphery in plan view. In this embodiment, the through-holes (through-holes 11a1 and 11b1) are smaller in size than the combined part of the negative electrode active material layer 130 and the sealing member 210 formed around its periphery, and are smaller in size than the separator 140. In this manner, the intermediate foil 11 is a ring-shaped member that is hexagonal (regular hexagonal) in plan view.

 接続部12は、部材ユニット連続体10Aにおいて、部材ユニット10及び中間箔11の互いに対向する辺同士を接続する部位である。この部位は必ずしも部材ユニット10及び中間箔11と同じ素材で形成する必要はなく、異なる素材で形成され、部材ユニット10と中間箔11に後で接着、接合されても良い。例えば、部材ユニット10のベースとなる集電箔110の素材は金属であるが、接続部12は金属である必要はなく、PET樹脂等の柔軟性を持つ樹脂フィルムであっても良い。このように樹脂フィルムを接続部12に採用することで、接続部12を切り離すときの金属コンタミの発生を防止することができる。また、部材ユニット10と接続部12とは接着テープ等を用いて接合されていても良く、この場合には接続部12を取り外す際には、切断することなく、接着テープを外すことで、取り外すことができる。 The connection portion 12 is a portion of the component unit continuum 10A that connects the opposing edges of the component unit 10 and the intermediate foil 11. This portion does not necessarily have to be made of the same material as the component unit 10 and the intermediate foil 11; it may be made of a different material and later glued or joined to the component unit 10 and the intermediate foil 11. For example, the current collector foil 110 that forms the base of the component unit 10 is made of metal, but the connection portion 12 does not have to be metal and can be a flexible resin film such as PET resin. Using a resin film for the connection portion 12 in this way prevents metal contamination when the connection portion 12 is separated. The component unit 10 and connection portion 12 may also be joined using adhesive tape, etc. In this case, the connection portion 12 can be removed by removing the adhesive tape without cutting.

 本実施の形態では、接続部12は、六角形状(正六角形状)の集電箔110のY軸プラス方向の一辺と、六角形状(正六角形状)の中間箔11のY軸マイナス方向の一辺とを接続する。接続部12のX軸方向の幅は、集電箔110の一辺の長さよりも短く、中間箔11の一辺の長さよりも短い。つまり、接続部12のX軸方向の幅は、集電箔110のY軸プラス方向の一辺のX軸方向の長さよりも短く、中間箔11のY軸マイナス方向の一辺のX軸方向の長さよりも短い。 In this embodiment, the connection portion 12 connects one side of the hexagonal (regular hexagonal) current collector foil 110 in the positive Y-axis direction to one side of the hexagonal (regular hexagonal) intermediate foil 11 in the negative Y-axis direction. The width of the connection portion 12 in the X-axis direction is shorter than the length of one side of the current collector foil 110 and shorter than the length of one side of the intermediate foil 11. In other words, the width of the connection portion 12 in the X-axis direction is shorter than the length of one side of the current collector foil 110 in the positive Y-axis direction and shorter than the length of one side of the intermediate foil 11 in the negative Y-axis direction.

 本実施例の蓄電装置1の製造方法においては、部材ユニット連続体10Aはセパレータ連続体140Aに対してZ軸を中心に回転した状態で配置されるため、両者のX軸方向及びY軸方向が変化する。具体的には、図6に示すような正六角形状の枠部材30を用いる場合には、部材ユニット連続体10Aとセパレータ連続体140Aとは、YX平面上で概ね60°もしくは120°の角度で積層される。 In the manufacturing method of the energy storage device 1 of this embodiment, the component unit continuum 10A is positioned rotated about the Z axis relative to the separator continuum 140A, so the X-axis and Y-axis directions of both change. Specifically, when a regular hexagonal frame member 30 as shown in Figure 6 is used, the component unit continuum 10A and the separator continuum 140A are stacked at an angle of approximately 60° or 120° on the YX plane.

 図6は、本実施の形態に係る蓄電装置1の製造方法における枠部材30と、部材ユニット連続体10Aと、セパレータ連続体140Aとの構成を示す斜視図である。図7Aは、本実施の形態に係る蓄電装置1の製造方法における第4工程終了後の状態を示す平面図である。図7Bは、図7Aの構成における、VIIB-VIIB線を通るYZ平面の断面を示している。図7Bでは、説明の便宜のため、集電箔110を、正極金属層111及び負極金属層112に分けずに、正極金属層111及び負極金属層112を一体化して図示している。以降の集電箔110の図示についても同様である。また、簡略化のため、第1工程で設置した、エンド部材300、第2工程で設置したエンドユニット101は図示していない。これは以下の断面図でも同様である。 FIG. 6 is a perspective view showing the configuration of the frame member 30, component unit continuum 10A, and separator continuum 140A in the manufacturing method for the energy storage device 1 according to this embodiment. FIG. 7A is a plan view showing the state after the fourth step in the manufacturing method for the energy storage device 1 according to this embodiment. FIG. 7B shows a cross section of the YZ plane passing through line VIIB-VIIB in the configuration of FIG. 7A. For ease of explanation, in FIG. 7B, the current collector foil 110 is not separated into the positive electrode metal layer 111 and the negative electrode metal layer 112, but is shown as an integrated positive electrode metal layer 111 and negative electrode metal layer 112. The same applies to subsequent illustrations of the current collector foil 110. For simplicity, the end member 300 installed in the first step and the end unit 101 installed in the second step are not shown. This also applies to the cross-sectional views that follow.

 図6に示すように、部材ユニット連続体10Aと接続部12は枠部材30と係合するように構成されており、部材ユニット連続体10Aを枠部材30に挿入後は接続部12(図7Aでは接続部12b)および接続部12と接合された次の中間箔11(図7Aでは中間箔11a)は枠部材30の開口部31aから枠部材30外に突出している。 As shown in Figure 6, the component unit continuum 10A and the connecting portion 12 are configured to engage with the frame member 30, and after the component unit continuum 10A is inserted into the frame member 30, the connecting portion 12 (connecting portion 12b in Figure 7A) and the next intermediate foil 11 (intermediate foil 11a in Figure 7A) joined to the connecting portion 12 protrude outside the frame member 30 through the opening 31a in the frame member 30.

 第5工程では、第4工程で先に積層した部材ユニット連続体10Aの枠部材30の開口部31aからはみ出した接続部12(図7Aでは接続部12b)を折り畳み、部材ユニット連続体10Aを折り返し、中間箔11(図7Aでは中間箔11a)を枠部材30にZ軸プラス方向から挿入する。これにより、接続部12(図7Aでは接続部12c)および接続部12と接合された部材ユニット10(図7Aでは部材ユニット10b)は枠部材30の開口部31aから枠部材30外に突出する。 In the fifth step, the connection portion 12 (connection portion 12b in Figure 7A) protruding from the opening 31a of the frame member 30 of the component unit continuous body 10A previously stacked in the fourth step is folded, the component unit continuous body 10A is folded back, and the intermediate foil 11 (intermediate foil 11a in Figure 7A) is inserted into the frame member 30 from the positive direction of the Z axis. As a result, the connection portion 12 (connection portion 12c in Figure 7A) and the component unit 10 (component unit 10b in Figure 7A) joined to the connection portion 12 protrude outside the frame member 30 through the opening 31a of the frame member 30.

 図8Aは、本実施の形態に係る蓄電装置1の製造方法における第5工程終了後の状態を示す平面図である。図8Bは、図8Aの構成における、VIIIB-VIIIB線を通るYZ平面の断面を示している。 FIG. 8A is a plan view showing the state after the fifth step in the manufacturing method for the energy storage device 1 according to this embodiment. FIG. 8B shows a cross section of the configuration in FIG. 8A taken along the YZ plane passing through line VIIIB-VIIIB.

 第5工程以降の工程では電極部材ユニットの積層数に合わせて、第3工程⇒第4工程⇒第5工程を複数回繰り返す、これによって、本発明の主要な用途の一つであるバイポーラ電池の直列数を増やすことができる。図9Aは、本実施の形態に係る蓄電装置1の製造方法における第5工程終了後、再度第3工程を実施し、その終了後の状態を示す平面図である。図9Bは、図9Aの構成における、IXB-IXB線を通るYZ平面の断面を示している。図10Aは、本実施の形態に係る蓄電装置1の製造方法における第3工程の後、再び第4工程を終了した後の状態を示す平面図である。図10Bは、図10Aの構成における、XB-XB線を通るYZ平面の断面を示している。 In steps 5 and beyond, steps 3, 4, and 5 are repeated multiple times according to the number of stacked electrode member units, thereby increasing the number of series-connected bipolar batteries, which is one of the main applications of the present invention. Figure 9A is a plan view showing the state after step 3 is performed again after step 5 in the manufacturing method for energy storage device 1 according to this embodiment. Figure 9B shows a cross section in the YZ plane passing through line IXB-IXB in the configuration of Figure 9A. Figure 10A is a plan view showing the state after step 4 is performed again after step 3 in the manufacturing method for energy storage device 1 according to this embodiment. Figure 10B shows a cross section in the YZ plane passing through line XB-XB in the configuration of Figure 10A.

 図11は、本実施の形態に係る蓄電装置1の製造方法における部材ユニット連続体10Aおよびセパレータ連続体140Aを折り畳みながら、積層する工程を示す斜視図である。図11では、図を見やすくするため、枠部材30を電極部材ユニット10から分離させ、かつ、接続部12、21の長さを長く図示している。また、本図においても簡略化のため、第1工程で設置した、エンド部材300、第2工程で設置したエンドユニット101は図示していない。 Figure 11 is a perspective view showing the process of folding and stacking the component unit continuous body 10A and the separator continuous body 140A in the manufacturing method for the energy storage device 1 according to this embodiment. To make the drawing easier to see, Figure 11 shows the frame member 30 separated from the electrode component unit 10 and the lengths of the connection portions 12, 21 as being long. For simplicity's sake, the end member 300 installed in the first step and the end unit 101 installed in the second step are not shown in this drawing.

 第3工程から第5工程の複数回の繰り返しにより、目的とする積層数に達した後に第6工程として、第3工程で先に積層したセパレータ連続体140Aの枠部材30の開口部32aからはみ出した接続部21を折り畳み、セパレータ連続体140Aを折り返し、セパレータ140を枠部材30にZ軸プラス方向から、挿入する。これにより、接続部21および接続部21と接合された次のセパレータ140が枠部材30の開口部32aから枠部材30外に突出する。 After the target number of stacks has been reached by repeating steps 3 through 5 multiple times, in step 6, the connecting portions 21 of the separator continuous body 140A previously stacked in step 3 that protrude from the opening 32a of the frame member 30 are folded, the separator continuous body 140A is folded back, and the separator 140 is inserted into the frame member 30 from the positive direction of the Z axis. As a result, the connecting portions 21 and the next separator 140 joined to the connecting portions 21 protrude outside the frame member 30 through the opening 32a of the frame member 30.

 第7工程として、枠部材30のZ軸方向からエンドユニット102を単独部材として挿入する。エンドユニット102は、少なくとも、集電箔110と、集電箔110のZ軸マイナス方向の面に配置された負極活物質層130と、負極活物質層130の外周に設けられたシール部材210と、を備えている。 In the seventh step, the end unit 102 is inserted as a separate member from the Z-axis direction of the frame member 30. The end unit 102 includes at least a current collector foil 110, a negative electrode active material layer 130 disposed on the surface of the current collector foil 110 facing in the negative Z-axis direction, and a sealing member 210 provided on the outer periphery of the negative electrode active material layer 130.

 第8工程として、枠部材30のZ軸方向からエンド部材300を単独部材として挿入する。 In the eighth step, the end member 300 is inserted as a separate member from the Z-axis direction of the frame member 30.

 第9工程として、枠部材30の開口部31a、32aから突出し、折り畳まれた接続部12、21を切断する。接続部12、21は枠部材30から突出させることで、容易に切断することができる。また、枠部材30から突出した接続部12、21を切断することで、切断した際のコンタミが積層体400に侵入するのを抑制できる。図12は、本実施の形態に係る蓄電装置1の製造方法における第9工程で接続部12、21を切り離した状況を示す断面図である。(ここでは簡略化のため、積層した部材ユニット10の一部しか図示していない)また、本実施例では、一連の積層工程を終えてから、接続部12、21を切断したが、本発明はこれに限定されるものではなく、接続部12、21の切断は任意のタイミングで行うことができる。また、切り離した面には、切り離した痕が形成される。 In the ninth step, the folded connecting portions 12, 21 protruding from the openings 31a, 32a of the frame member 30 are cut. By having the connecting portions 12, 21 protruding from the frame member 30, they can be easily cut. Furthermore, by cutting the connecting portions 12, 21 protruding from the frame member 30, contamination caused by cutting can be prevented from entering the stack 400. Figure 12 is a cross-sectional view showing the state in which the connecting portions 12, 21 have been cut in the ninth step of the manufacturing method for the energy storage device 1 according to this embodiment. (For simplicity, only a portion of the stacked component units 10 is shown.) Furthermore, in this example, the connecting portions 12, 21 were cut after the series of stacking steps were completed, but the present invention is not limited to this, and the connecting portions 12, 21 can be cut at any time. Furthermore, cut marks are left on the cut surfaces.

 部材ユニット10と接続部12とは接着テープ等を用いて接合されていても良く、この場合には接続部12を取り外す際には、切断する必要はなく、接着テープを外すことで、取り外すことが可能であり、任意のタイミングで取り外すことができる。 The component unit 10 and the connection part 12 may be joined using adhesive tape or the like. In this case, there is no need to cut the connection part 12 when removing it; it can be removed by simply removing the adhesive tape, and it can be removed at any time.

 第10工程として、第9工程まで終了した積層体400を枠部材30から取り出し、外部から加熱、圧迫することで、シール部材210に熱を与え、積層体400の一体化を行う。この際、シール部材210に接着剤や粘着剤、もしくは粘着テープを使うことによって加熱を行わなくても一体化を図ることができる。また、一体化を行う順番は必ずしも、接続部12、21の切断後でなくても良く、一体化後に接続部12、21の切断を行うことも可能である。 In the tenth step, the laminate 400, which has been subjected to steps 9 and above, is removed from the frame member 30 and heated and compressed from the outside, thereby applying heat to the sealing member 210 and integrating the laminate 400. In this case, integration can be achieved without heating by using an adhesive, pressure-sensitive adhesive, or adhesive tape for the sealing member 210. Furthermore, the integration does not necessarily have to be performed after cutting the connecting portions 12 and 21; it is also possible to cut the connecting portions 12 and 21 after integration.

 第11工程として、第10工程で一体化した積層体400を枠部材30から取り出し、積層体400の外周(側面部)を外周封止部材200で封止する。これは、蓄電装置1の外周がシール部材210のままでは、大気中の水分の影響により、長期使用の際には性能低下の原因となる可能性があるためである。この目的のためには、緻密で、水分透過性の低い外周封止部材200を蓄電装置1の周囲(外周)に配し、これらの周囲(外周)を覆う必要がある。本実施の形態では、外周封止部材200は、蓄電装置1の外周に亘って設けられた緻密な樹脂層である。また、枠部材30と積層体400の外周を外周封止部材200で封止することで、枠部材30をそのまま蓄電装置1のケースとして使用してもよい。部材ユニット10等を積層した枠部材30に蓋部を接着剤等で接合することによって、蓄電装置1を構成してもよい。また、この際、枠部材30に蓋部を接着剤等で接合することによって、蓄電装置1を構成してもよい。 In step 11, the laminate 400 integrated in step 10 is removed from the frame member 30, and the outer periphery (side surface) of the laminate 400 is sealed with the outer periphery sealing member 200. This is because if the outer periphery of the energy storage device 1 is left covered with the sealing member 210, moisture in the air may affect performance during long-term use. For this purpose, a dense, low-moisture permeability outer periphery sealing member 200 must be placed around (covers) the periphery of the energy storage device 1. In this embodiment, the outer periphery sealing member 200 is a dense resin layer provided around the periphery of the energy storage device 1. Furthermore, by sealing the outer peripheries of the frame member 30 and the laminate 400 with the outer periphery sealing member 200, the frame member 30 may be used as is as a case for the energy storage device 1. The energy storage device 1 may also be constructed by joining a lid to the frame member 30, on which component units 10 and the like are stacked, with an adhesive or the like. In this case, the energy storage device 1 may be constructed by joining the lid to the frame member 30 with adhesive or the like.

 [効果の説明]
 以上のように、本発明の実施の形態に係る蓄電装置1の製造方法によれば、複数の部材ユニット10が接続部12で接続された部材ユニット連続体10Aを配置し、接続部12の位置で部材ユニット連続体10Aを折り畳み、その後、接続部12を取り外す。このように、複数の集電箔110(部材ユニット10)が接続部12で接続された部材ユニット連続体10Aを接続部12の位置で折り畳むことで、複数の集電箔110(部材ユニット10)を容易に位置決めしながら積層することができる。部材ユニット連続体10Aを折り畳んだ後に接続部12を取り外すことで、部材ユニット10を適切な位置で積層することが可能となり、蓄電装置1を容易に製造できる。
[Effect description]
As described above, according to the manufacturing method of the energy storage device 1 according to the embodiment of the present invention, a component unit string 10A in which a plurality of component units 10 are connected by the connection portions 12 is arranged, the component unit string 10A is folded at the position of the connection portions 12, and then the connection portions 12 are removed. In this manner, by folding the component unit string 10A in which a plurality of current collector foils 110 (component units 10) are connected by the connection portions 12 at the position of the connection portions 12, the plurality of current collector foils 110 (component units 10) can be easily positioned and stacked. By folding the component unit string 10A and then removing the connection portions 12, it becomes possible to stack the component units 10 in appropriate positions, and the energy storage device 1 can be easily manufactured.

 図7B等において、集電箔110として、正極金属層111及び負極金属層112を一体化して図示したが、本実施の形態では、集電箔110は、1枚のステンレス箔等の金属箔で形成してもよい。これにより、集電箔110の構成をさらに簡易にできる。 In Figure 7B and other figures, the current collector foil 110 is illustrated as an integrated positive electrode metal layer 111 and negative electrode metal layer 112, but in this embodiment, the current collector foil 110 may be formed from a single metal foil such as stainless steel foil. This further simplifies the configuration of the current collector foil 110.

 蓄電装置1の製造方法によれば、集電箔110の一方の面に正極活物質層120が配置され、集電箔110の他方の面に負極活物質層130が配置された蓄電装置1(バイポーラ電池)を容易に製造できる。このため、大きな集電箔110(部材ユニット10)を用いた場合でも、複数の集電箔110(部材ユニット10)を容易に位置決めできるため、比較的大型なバイポーラ電池を容易に製造できる。さらにロール状の部材ユニット連続体10Aを用いて、連続的な供給が可能であるので、大型バイポーラ電池の量産にも対応できる。 The manufacturing method for the energy storage device 1 makes it easy to manufacture an energy storage device 1 (bipolar battery) in which a positive electrode active material layer 120 is disposed on one side of the current collector foil 110 and a negative electrode active material layer 130 is disposed on the other side of the current collector foil 110. Therefore, even when using large current collector foils 110 (component units 10), multiple current collector foils 110 (component units 10) can be easily positioned, making it easy to manufacture relatively large bipolar batteries. Furthermore, the use of a roll-shaped component unit continuum 10A allows for continuous supply, making it possible to mass-produce large bipolar batteries.

 蓄電装置1の製造方法によれば、積層方向から見て辺の数が4つ以上の偶数である多角形(本実施の形態では六角形)または円形の部材ユニット10が接続部12で複数接続された部材ユニット連続体10Aを配置する。これにより、集電箔110(部材ユニット10)に2つの接続部12を多角形または円形の対向した位置に配置できるため、部材ユニット連続体10Aを直線状に形成できる。これにより、複数の集電箔110(部材ユニット10)を、接続部12の位置で容易に折り畳むことができる。部材ユニット連続体10Aを直線状に形成することで、部材ユニット連続体10Aをロール状で供給することが可能となり、量産時の生産性を高めることができる。 According to the manufacturing method for the energy storage device 1, a component unit continuum 10A is arranged in which multiple polygonal (hexagonal in this embodiment) or circular component units 10 with an even number of sides of four or more when viewed in the stacking direction are connected by connecting portions 12. This allows two connecting portions 12 to be arranged on the current collector foil 110 (component unit 10) at opposing positions on the polygon or circle, making it possible to form the component unit continuum 10A in a straight line. This allows multiple current collector foils 110 (component units 10) to be easily folded at the connecting portions 12. Forming the component unit continuum 10A in a straight line makes it possible to supply the component unit continuum 10A in roll form, improving productivity during mass production.

 複数のロール状の部材ユニット連続体10Aを枠部材30に供給し、接続部12を折り畳んで、枠部材30中に部材ユニット10を収納し、積層するためには、部材ユニット10の形状及び枠部材30の形状には一定の制約があり、部材ユニット10の形状は、辺の数が偶数の多角形または円形である必要がある。当該辺の数が偶数の多角形の場合、各部材ユニット10に対して2つの対向した辺に接続部12を配置できるため、部材ユニット連続体10Aを直線状に形成できる。これにより、接続部12を所定の位置で容易に折り畳むことができ、連続的に部材ユニット10を積層できる。枠部材30に部材ユニット10を供給する際には、部材ユニット連続体10Aとして供給する方法と、単独の部材ユニット10を枠部材30に設置して積層する方法があるが、最大何本の部材ユニット連続体10Aを1つの枠部材30に対して供給できるかは、部材ユニット10の形状によって決まる。部材ユニット10が四角形の場合は2本、六角形の場合は3本、八角形の場合には4本の部材ユニット連続体10Aを枠部材30に対して供給できる。部材ユニット10の形状が円形の場合、部材ユニット10の円形の大きさに対して、接続部12の幅が十分に小さければ、多くの部材ユニット連続体10Aから枠部材30に部材ユニット10を供給できるが、蓄電装置1としても円柱形状となるため、蓄電装置1を集合化して蓄電パック化する場合に、余剰空間が必要となり、蓄電パックとしてのエネルギー密度が低くなる、といった課題がある。四角形の枠部材30で積層を行う場合では電池構成部材は通常2つでは済まないため、連続供給を行う部材ユニット連続体10Aは2本として他の電池構成部材は単独で供給する必要がある。 In order to supply multiple roll-shaped component unit continuums 10A to a frame member 30, fold the connecting portions 12, and store and stack the component units 10 within the frame member 30, there are certain restrictions on the shape of the component units 10 and the shape of the frame member 30. The component units 10 must be polygonal or circular with an even number of sides. If the shape is a polygonal shape with an even number of sides, the connecting portions 12 can be placed on two opposing sides of each component unit 10, allowing the component unit continuum 10A to be formed in a straight line. This allows the connecting portions 12 to be easily folded at predetermined positions, allowing the component units 10 to be stacked continuously. When supplying component units 10 to a frame member 30, there are two methods: supplying them as component unit continuums 10A, or placing individual component units 10 on the frame member 30 and stacking them. However, the maximum number of component unit continuums 10A that can be supplied to one frame member 30 is determined by the shape of the component units 10. Two component unit strings 10A can be supplied to the frame member 30 if the component units 10 are rectangular, three if they are hexagonal, and four if they are octagonal. If the component units 10 are circular, component units 10 can be supplied to the frame member 30 from many component unit strings 10A if the width of the connection portions 12 is sufficiently small compared to the circular size of the component units 10. However, because the energy storage devices 1 also have a cylindrical shape, when the energy storage devices 1 are assembled into an energy storage pack, excess space is required, resulting in a lower energy density of the energy storage pack. When stacking with a rectangular frame member 30, more than two battery components are usually required, so two component unit strings 10A are continuously supplied, and the other battery components must be supplied individually.

 蓄電装置1の製造方法によれば、積層方向から見て多角形(本実施の形態では六角形)の集電箔110(部材ユニット10)の一辺に、当該一辺の長さよりも短い幅の接続部12が接続された部材ユニット連続体10Aを配置する。このように、接続部12の幅を短くすることで、部材ユニット10の位置合わせの自由度が向上し、位置合わせ精度の向上を図ることができる。接続部12の幅を短くすることで、接続部12を容易に切り離すことができ、また、接続部12の幅が短いことで、切り離す部分が短くなり、コンタミ(コンタミネーション、金属粉等)の発生を削減できる。 According to the manufacturing method of the energy storage device 1, a component unit continuum 10A is arranged in which a connecting portion 12 having a width shorter than the length of one side of a current collecting foil 110 (component unit 10) that is polygonal (hexagonal in this embodiment) when viewed in the stacking direction is connected to that side. In this way, shortening the width of the connecting portion 12 improves the degree of freedom in aligning the component unit 10, and improves alignment accuracy. Reducing the width of the connecting portion 12 makes it easier to separate the connecting portion 12, and the shorter width of the connecting portion 12 shortens the portion to be separated, reducing the generation of contamination (contamination, metal powder, etc.).

 蓄電装置1の製造方法によれば、部材ユニット10を枠部材30に挿入するとともに、接続部12を枠部材30から突出させる。このように、部材ユニット10を枠部材30に挿入することで、枠部材30で部材ユニット10を位置決めしながら部材ユニット連続体10Aを折り畳むことができる。枠部材30と部材ユニット10との寸法精度のコントロールによって、容易に部材ユニット10間の位置決め精度を向上できる。 According to the manufacturing method of the energy storage device 1, the component units 10 are inserted into the frame member 30, and the connection portions 12 are caused to protrude from the frame member 30. By inserting the component units 10 into the frame member 30 in this way, the component unit series 10A can be folded while the component units 10 are positioned by the frame member 30. By controlling the dimensional accuracy of the frame member 30 and the component units 10, the positioning accuracy between the component units 10 can be easily improved.

 バイポーラ構造の蓄電装置1においては、各部材ユニット10が積層方法に直列接続されているため、各部材ユニット10間の短絡を防止するため、部材ユニット連続体10Aの接続部12に導電性がある場合はこれらの導通を切り離す必要がある。枠部材30から突出した接続部12を切り離すことで、接続部12を枠部材30外で切り離すことができるため、切り離すことによるコンタミの影響を低減し、バイポーラ電池に適した蓄電装置1を構成できる。接続部12を切り離すタイミングとしては、全ての積層が終了したのちに全ての接続部12を一括して切り離してもよいし、各部材ユニット10を枠部材30に積層後に個別に接続部12を切り離してもよいし、複数の接続部12ごとに切り離してもよい。 In a bipolar structure energy storage device 1, each component unit 10 is connected in series in a stacking method. Therefore, to prevent short circuits between each component unit 10, if the connection parts 12 of the component unit series 10A are conductive, it is necessary to cut off the conductivity. By cutting off the connection parts 12 protruding from the frame member 30, the connection parts 12 can be cut off outside the frame member 30, thereby reducing the impact of contamination caused by cutting off and creating an energy storage device 1 suitable for a bipolar battery. The connection parts 12 can be cut off all at once after all the stacking is complete, or the connection parts 12 can be cut off individually after each component unit 10 is stacked on the frame member 30, or multiple connection parts 12 can be cut off at a time.

 接続部12は接着テープ等を用いて接合されていても良く、この場合には接続部12を取り外す際には、切断することなく、接着テープを外すことで、接続部12と部材ユニット10を取り外すことができる。 The connection portion 12 may be joined using adhesive tape or the like. In this case, when removing the connection portion 12, the connection portion 12 and the component unit 10 can be removed by removing the adhesive tape without cutting.

 なお、ここでは、シール部材210を備えた電極ユニット100である、部材ユニット連続体10Aの積層効果について説明したが、セパレータ連続体140Aでも同様の効果を奏する。また、エンドユニット101及びエンドユニット102、エンド部材300、シール部材210など他の部材ユニット連続体10Aを配置する場合にも同様の効果を奏する。 Note that while the stacking effect of the component unit continuum 10A, which is the electrode unit 100 equipped with the sealing member 210, has been described here, the same effect can be achieved with the separator continuum 140A. Furthermore, the same effect can be achieved when other component unit continuums 10A, such as end units 101 and 102, end members 300, and sealing members 210, are arranged.

 [4 変形例の説明]
 以上、本実施の形態に係る蓄電装置1及びその製造方法について説明したが、本発明は、上記実施の形態には限定されない。今回開示された実施の形態は、全ての点で例示であって制限的なものではなく、本発明の範囲には、特許請求の範囲と均等の意味及び範囲内での全ての変更が含まれる。
[4. Description of Modifications]
Although the energy storage device 1 and the manufacturing method thereof according to the present embodiment have been described above, the present invention is not limited to the above embodiment. The embodiment disclosed herein is illustrative in all respects and is not restrictive, and the scope of the present invention includes all modifications within the meaning and scope of the claims.

 (変形例1)
 上記実施の形態では、部材ユニット連続体10Aが備える部材ユニット10及び中間箔11は、平面視で六角形状(正六角形状)を有していることとしたが、これには限定されない。図13Aは、本実施の形態の変形例1に係る部材ユニット連続体10Aaの構成を示す平面図であり、図13Bは、本実施の形態の変形例1に係る部材ユニット連続体10Aの構成を示す平面図である。図13A及び図13Bは、図5Aに対応する図である。
(Variation 1)
In the above embodiment, the component units 10 and the intermediate foil 11 included in the component unit continuum 10A have a hexagonal shape (regular hexagonal shape) in a plan view, but are not limited to this. Fig. 13A is a plan view showing the configuration of the component unit continuum 10Aa according to Modification 1 of this embodiment, and Fig. 13B is a plan view showing the configuration of the component unit continuum 10A according to Modification 1 of this embodiment. Figs. 13A and 13B are views corresponding to Fig. 5A.

 図13Aに示すように、本変形例における部材ユニット連続体10Aaは、平面視で四角形状(正方形状)を有する部材ユニット10c及び中間箔11cを備えている。部材ユニット10cにおいて、集電箔110、正極活物質層120及び負極活物質層130についても、平面視で四角形状(正方形状)を有しており、それぞれの活物質の外周にはシール部材210を備えている。中間箔11cには、平面視で四角形状(正方形状)の貫通孔11c1が形成されている。枠部材30、セパレータ140、エンドユニット101、102、エンド部材300、についても同様に、平面視で四角形状(正方形状)を有している。本変形例のその他の構成については、上記実施の形態と同様であるため、詳細な説明は省略する。部材ユニット連続体10Aは、平面視で正方形以外の長方形でもよいし、八角形、十角形、等でもよい。 As shown in FIG. 13A, the component unit continuum 10Aa in this modified example includes component units 10c and intermediate foils 11c each having a quadrangular (square) shape in plan view. In the component unit 10c, the current collector foil 110, positive electrode active material layer 120, and negative electrode active material layer 130 also have a quadrangular (square) shape in plan view, and a sealing member 210 is provided on the outer periphery of each active material. A through-hole 11c1 having a quadrangular (square) shape in plan view is formed in the intermediate foil 11c. Similarly, the frame member 30, separator 140, end units 101, 102, and end member 300 also have a quadrangular (square) shape in plan view. The remaining configuration of this modified example is the same as that of the above-described embodiment, and therefore detailed description will be omitted. The component unit continuum 10A may have a rectangular shape other than a square in plan view, or may be an octagon, decagon, or the like.

 図13Bに示すように、本変形例における部材ユニット連続体10Abは、平面視で円形状を有する部材ユニット10d及び中間箔11dを備えているものも含まれる。部材ユニット10dにおいて、集電箔110、正極活物質層120及び負極活物質層130についても、平面視で円形状を有している。また、それぞれの活物質の外周にはリング状のシール部材210を備えている。中間箔11dには、平面視で円形状の貫通孔11d1が形成されている。枠部材30、セパレータ140、エンドユニット101、102、エンド部材300、についても同様に、平面視で円形状を有している。本変形例のその他の構成については、上記実施の形態と同様であるため、詳細な説明は省略する。部材ユニット連続体10Aは、平面視で長円形状または楕円形状等でもよい。 As shown in Figure 13B, the component unit continuum 10Ab in this modified example also includes a component unit 10d and intermediate foil 11d that are circular in plan view. In the component unit 10d, the current collector foil 110, positive electrode active material layer 120, and negative electrode active material layer 130 also have a circular shape in plan view. In addition, a ring-shaped sealing member 210 is provided on the outer periphery of each active material. A through hole 11d1 that is circular in plan view is formed in the intermediate foil 11d. The frame member 30, separator 140, end units 101, 102, and end member 300 also have a circular shape in plan view. The other configurations of this modified example are the same as those of the above embodiment, so detailed description will be omitted. The component unit continuum 10A may also have an oval or elliptical shape in plan view.

 このように、部材ユニット連続体10Aを配置することで、積層方向(Z軸方向)から見て辺の数が偶数の多角形または円形の集電箔110が接続部12で複数接続された部材ユニット連続体10Aを用いて部材ユニット10を積層することができる。 By arranging the component unit continuum 10A in this way, component units 10 can be stacked using component unit continuum 10A in which multiple polygonal or circular current collecting foils 110 with an even number of sides are connected at connecting portions 12 when viewed from the stacking direction (Z-axis direction).

 本変形例の構成によっても、上記実施の形態と同様の方法で蓄電装置を製造でき、上記実施の形態と同様の効果を奏する。つまり、蓄電装置の製造方法によれば、辺の数が4以上の偶数の多角形または円形の集電箔110が接続部12で複数接続された部材ユニット連続体10Aを配置することにより、部材ユニット10に2つの接続部12を対向した位置に配置できるため、部材ユニット連続体10A、を直線状に形成できる。これにより、複数の部材ユニット10を、接続部12の位置で容易に折り畳むことができる。部材ユニット連続体10A、を直線状に形成することで、部材ユニット連続体10Aをロールで供給することができる。 With the configuration of this modified example, an electricity storage device can be manufactured in the same manner as the above embodiment, and the same effects as the above embodiment can be achieved. In other words, according to the method for manufacturing an electricity storage device, by arranging a component unit continuum 10A in which multiple current collector foils 110, each of which is an even number of polygons with four or more sides or a circle, are connected by connecting portions 12, two connecting portions 12 can be positioned opposite each other on the component unit 10, and the component unit continuum 10A can be formed in a straight line. This allows multiple component units 10 to be easily folded at the positions of the connecting portions 12. By forming the component unit continuum 10A in a straight line, the component unit continuum 10A can be supplied in a roll.

 (変形例2)
 上記実施の形態では、部材ユニット連続体10Aは、貫通孔が形成された中間箔11を備えていることとしたが、中間箔11を備えなくてもよい。変形例2では、複数の部材ユニット連続体10Aを折り畳んでバイポーラ型の蓄電装置を製造する実施例を説明する。図14Aは、本実施の形態の変形例2に係る部材ユニット連続体10Acの構成を示す平面図であり、図14Bは、本実施の形態の変形例2に係る部材ユニット連続体10Adの構成を示す平面図である。図14A及び図14Bは、図5Aに対応する図である。図15Aは、本実施の形態の変形例2に係る蓄電装置の製造方法における部材ユニット連続体10Ac及び10Adを折り畳む工程を示す平面図である。図15Bは、本実施の形態の変形例2に係る蓄電装置の製造方法における部材ユニット連続体10Ac及び10Adを挿入し、第一層を形成した状態を示す断面図である。図15A及び図15Bは、図7A及び図7Bに対応する図である。図16は、本実施の形態の変形例2に係る蓄電装置の製造方法における部材ユニット連続体10Ac及び10Adを折り畳んだ後、枠部材30に挿入し、第二層を形成した状態を示す断面図である。図16は、図10Bに対応する図である。図17は、本実施の形態の変形例2に係る蓄電装置の製造方法における接続部12を切り離す工程を示す断面図である。図17は、図12に対応する図である。
(Variation 2)
In the above embodiment, the component unit continuum 10A includes an intermediate foil 11 having a through hole formed therein. However, the intermediate foil 11 may not be included. In Modification 2, an example of manufacturing a bipolar type energy storage device by folding a plurality of component unit continuums 10A will be described. FIG. 14A is a plan view showing the configuration of a component unit continuum 10Ac according to Modification 2 of the present embodiment, and FIG. 14B is a plan view showing the configuration of a component unit continuum 10Ad according to Modification 2 of the present embodiment. FIGS. 14A and 14B correspond to FIG. 5A. FIG. 15A is a plan view showing a step of folding the component unit continuums 10Ac and 10Ad in the manufacturing method for an energy storage device according to Modification 2 of the present embodiment. FIG. 15B is a cross-sectional view showing the state in which the component unit continuums 10Ac and 10Ad are inserted to form a first layer in the manufacturing method for an energy storage device according to Modification 2 of the present embodiment. FIGS. 15A and 15B correspond to FIGS. 7A and 7B. Fig. 16 is a cross-sectional view showing a state in which the component unit continuous bodies 10Ac and 10Ad are folded and then inserted into the frame member 30 to form a second layer in the manufacturing method for an energy storage device according to Modification 2 of the present embodiment. Fig. 16 is a view corresponding to Fig. 10B. Fig. 17 is a cross-sectional view showing a step of cutting off the connection portions 12 in the manufacturing method for an energy storage device according to Modification 2 of the present embodiment. Fig. 17 is a view corresponding to Fig. 12.

 図14Aに示すように、本変形例における部材ユニット連続体10Acは、複数の部材ユニット10eと複数の部材ユニット10fとが、接続部12によって交互に接続された構成を有している。部材ユニット10eは、集電箔110のうちの正極集電箔である正極金属層111のZ軸プラス方向の面に正極活物質層120が形成されたものであり、部材ユニット10fは、正極金属層111のZ軸マイナス方向の面に正極活物質層120が形成されたものである。本変形例の部材ユニット連続体10Acにおいても、正極活物質層120の外周部にはシール部材210を備えている。本変形例では、Y軸方向において、接続部12a、部材ユニット10e、接続部12b、部材ユニット10f、接続部12cと一列に(直線状に)並んで配置されている。 As shown in FIG. 14A, the component unit continuum 10Ac in this modified example has a configuration in which a plurality of component units 10e and a plurality of component units 10f are alternately connected by connecting portions 12. Component unit 10e has a positive electrode active material layer 120 formed on the surface of positive electrode metal layer 111, which is the positive electrode current collector foil of current collector foil 110, in the positive Z-axis direction. Component unit 10f has a positive electrode active material layer 120 formed on the surface of positive electrode metal layer 111 in the negative Z-axis direction. The component unit continuum 10Ac in this modified example also has a sealing member 210 on the outer periphery of the positive electrode active material layer 120. In this modified example, connecting portion 12a, component unit 10e, connecting portion 12b, component unit 10f, and connecting portion 12c are arranged in a row (linearly) in the Y-axis direction.

 図14Bに示すように、本変形例における部材ユニット連続体10Adは、複数の部材ユニット10gと複数の部材ユニット10hとが、接続部13によって交互に接続された構成を有している。部材ユニット10gは、集電箔110のうちの負極集電箔である負極金属層112のZ軸マイナス方向の面に負極活物質層130が形成されたものであり、部材ユニット10hは、負極金属層112のZ軸プラス方向の面に負極活物質層130が形成されたものである。本変形例の部材ユニット連続体10Adにおいても、負極活物質層130の外周部にはシール部材210を備えている。本変形例では、接続部13a、部材ユニット10g、接続部13b、部材ユニット10h、接続部13cと一列に(直線状に)並んで配置されている。 As shown in FIG. 14B, the component unit continuum 10Ad in this modified example has a configuration in which a plurality of component units 10g and a plurality of component units 10h are alternately connected by connecting portions 13. Component unit 10g has a negative electrode active material layer 130 formed on the negative Z-axis surface of negative electrode metal layer 112, which is the negative electrode current collector foil of current collector foil 110, and component unit 10h has a negative electrode active material layer 130 formed on the positive Z-axis surface of negative electrode metal layer 112. The component unit continuum 10Ad in this modified example also has a sealing member 210 on the outer periphery of the negative electrode active material layer 130. In this modified example, connecting portion 13a, component unit 10g, connecting portion 13b, component unit 10h, and connecting portion 13c are arranged in a row (linearly).

 このような構成において、図15A及び図15Bに示すように、部材ユニット連続体10Ac及び10Adを積層する工程として、枠部材30にセパレータ連続体140Aを挿入する。その後に、枠部材30に部材ユニット連続体10Adの部材ユニット10gを挿入し、その後に、枠部材30に部材ユニット連続体10Acの部材ユニット10eを挿入する。この際、部材ユニット10eに接続された接続部12a及び12bは、枠部材30の一対の側壁31の一対の開口部31aに挿入されて、一対の開口部31aからY軸方向両側(プラスおよびマイナス側)に突出する。同様に、セパレータ140aに接続された接続部21a及び21bは、枠部材30の一対の側壁32の一対の開口部32aに挿入されて、一対の開口部32aから突出する。本変形例では、枠部材30の一対の側壁33にも一対の開口部が形成されており、部材ユニット連続体10Adの部材ユニット10gに接続された接続部13a及び13bは、当該一対の側壁33の一対の開口部に挿入されて当該一対の開口部から突出する。 In this configuration, as shown in Figures 15A and 15B, the process of stacking the component unit continuum 10Ac and 10Ad involves inserting the separator continuum 140A into the frame member 30. Then, component unit 10g of component unit continuum 10Ad is inserted into the frame member 30, and then component unit 10e of component unit continuum 10Ac is inserted into the frame member 30. At this time, the connection portions 12a and 12b connected to component unit 10e are inserted into a pair of openings 31a in a pair of side walls 31 of the frame member 30, and protrude from the pair of openings 31a on both sides in the Y-axis direction (positive and negative sides). Similarly, the connection portions 21a and 21b connected to the separator 140a are inserted into a pair of openings 32a in a pair of side walls 32 of the frame member 30, and protrude from the pair of openings 32a. In this modified example, a pair of openings are also formed in the pair of side walls 33 of the frame member 30, and the connection portions 13a and 13b connected to the component unit 10g of the component unit continuum 10Ad are inserted into the pair of openings in the pair of side walls 33 and protrude from the pair of openings.

 これにより、セパレータ140a、負極活物質層130、負極金属層112、正極金属層111及び正極活物質層120が、この順にZ軸方向に並んで積層される。つまり、セパレータ140a上において、正極活物質層120及び負極活物質層130の間に、集電箔110(正極金属層111及び負極金属層112)が配置される。 As a result, the separator 140a, negative electrode active material layer 130, negative electrode metal layer 112, positive electrode metal layer 111, and positive electrode active material layer 120 are stacked in this order in the Z-axis direction. In other words, the current collecting foil 110 (positive electrode metal layer 111 and negative electrode metal layer 112) is arranged on the separator 140a between the positive electrode active material layer 120 and the negative electrode active material layer 130.

 次に、図16に示すように、部材ユニット連続体10Ac及び10Adを積層する工程として、枠部材30にセパレータ連続体140Aのセパレータ140bを挿入する。その後に、枠部材30に部材ユニット連続体10Adの部材ユニット10hを挿入し、その後に、枠部材30に部材ユニット連続体10Acの部材ユニット10fを挿入する。具体的には、接続部21bを折り曲げることで、接続部21bの位置でセパレータ連続体140Aを折り畳み、枠部材30に、セパレータ連続体140Aのセパレータ140bを挿入するとともに、接続部21b及び21cを枠部材30から突出させる。その後、接続部13bを折り曲げることで、接続部13bの位置で部材ユニット連続体10Adを折り畳み、枠部材30に、部材ユニット連続体10Adの部材ユニット10hを挿入するとともに、接続部13b及び13cを枠部材30から突出させる。その後、接続部12bを折り曲げることで、接続部12bの位置で部材ユニット連続体10Acを折り畳み、枠部材30に、部材ユニット連続体10Acの部材ユニット10fを挿入するとともに、接続部12b及び12cを枠部材30から突出させる。 Next, as shown in Figure 16, in the process of stacking the component unit continuum 10Ac and 10Ad, separator 140b of separator continuum 140A is inserted into frame member 30. Then, component unit 10h of component unit continuum 10Ad is inserted into frame member 30, and then component unit 10f of component unit continuum 10Ac is inserted into frame member 30. Specifically, by bending connection portion 21b, separator continuum 140A is folded at the position of connection portion 21b, and separator 140b of separator continuum 140A is inserted into frame member 30, with connection portions 21b and 21c protruding from frame member 30. Then, by bending the connecting portion 13b, the component unit string 10Ad is folded at the position of the connecting portion 13b, and component unit 10h of the component unit string 10Ad is inserted into the frame member 30, with connecting portions 13b and 13c protruding from the frame member 30. Then, by bending the connecting portion 12b, the component unit string 10Ac is folded at the position of the connecting portion 12b, and component unit 10f of the component unit string 10Ac is inserted into the frame member 30, with connecting portions 12b and 12c protruding from the frame member 30.

 これにより、セパレータ140a、部材ユニット10g、部材ユニット10e、セパレータ140b、部材ユニット10h、及び、部材ユニット10fが、この順にZ軸方向に並んで積層される。以上のように、セパレータ連続体140Aを接続部21の位置で折り畳み、部材ユニット連続体10Adを接続部13の位置で折り畳み、部材ユニット連続体10Acを接続部12の位置で折り畳む(部材ユニット連続体10Ac及び10Adを交互に折り畳む)ことを繰り返す。これにより、正極活物質層120及び負極活物質層130の間に集電箔110が配置された構成と、セパレータ140とが交互に積層される。このように、部材ユニット連続体10Ac及び10Adを折り畳んだ後、活物質層としての正極活物質層120及び負極活物質層130の間に集電箔110が配置されている。 As a result, separator 140a, component unit 10g, component unit 10e, separator 140b, component unit 10h, and component unit 10f are stacked in this order in the Z-axis direction. As described above, separator continuum 140A is folded at connection 21, component unit continuum 10Ad is folded at connection 13, and component unit continuum 10Ac is folded at connection 12 (combining component unit continuums 10Ac and 10Ad). This alternately stacks separators 140 and components in which current collector foil 110 is disposed between positive electrode active material layers 120 and negative electrode active material layers 130. After component unit continuums 10Ac and 10Ad are folded in this manner, current collector foil 110 is disposed between positive electrode active material layers 120 and negative electrode active material layers 130, which serve as active material layers.

 図17に示すように、セパレータ連続体140A、部材ユニット連続体10Ac及び10Adを折り畳み、積層した後に、枠部材30から突出した接続部12、13及び21を切り離す。詳細については、上記実施の形態における接続部を切り離す工程における処理と同様である。以降の処理についても、上記実施の形態における製造方法と同様である。 As shown in Figure 17, after the separator continuous body 140A and the component unit continuous bodies 10Ac and 10Ad are folded and stacked, the connecting portions 12, 13, and 21 protruding from the frame member 30 are cut off. Details are the same as in the process for cutting off the connecting portions in the above embodiment. Subsequent processes are also the same as in the manufacturing method in the above embodiment.

 (変形例3)
 上記実施の形態では、集電箔110のZ軸プラス方向の面に正極活物質層120が形成され、Z軸マイナス方向の面に負極活物質層130が形成された部材ユニット10と、その部材ユニットをZ軸上で上下反転した部材ユニットを接続部12で接合した部材ユニット連続体10Aを用いて、バイポーラ型の蓄電装置を製造する実施例を説明する。図18は、本実施の形態の変形例3に係る部材ユニット連続体10Aeの構成を示す平面図である。図18は、図5Aに対応する図である。図19は、本実施の形態の変形例3に係る蓄電装置の製造方法における部材ユニット連続体10Aeを積層した後に接続部12を切り離す工程を示す断面図である。図19は、図12に対応する図である。
(Variation 3)
In the above embodiment, an example of manufacturing a bipolar type electricity storage device will be described using a component unit 10 in which a positive electrode active material layer 120 is formed on the surface of the current collector foil 110 in the positive direction of the Z axis and a negative electrode active material layer 130 is formed on the surface in the negative direction of the Z axis, and a component unit continuum 10A in which the component unit is inverted upside down on the Z axis and joined at a connecting portion 12. FIG. 18 is a plan view showing the configuration of a component unit continuum 10Ae according to a third modification of this embodiment. FIG. 18 is a view corresponding to FIG. 5A. FIG. 19 is a cross-sectional view showing a step of separating the connecting portion 12 after stacking the component unit continuum 10Ae in the manufacturing method of an electricity storage device according to the third modification of this embodiment. FIG. 19 is a view corresponding to FIG. 12.

 図18に示すように、本変形例における部材ユニット連続体10Aeは、複数の部材ユニット10iと複数の部材ユニット10jとが、接続部12によって交互に接続された構成を有している。部材ユニット10iは、上記実施の形態における部材ユニット10と同様に、集電箔110のZ軸プラス方向の面に正極活物質層120が形成され、Z軸マイナス方向の面に負極活物質層130が形成されたものである。部材ユニット10jは、集電箔110のZ軸プラス方向の面に負極活物質層130が形成され、Z軸マイナス方向の面に正極活物質層120が形成されたものである。本変形例のその他の構成については、上記実施の形態と同様であるため、詳細な説明は省略する。 As shown in FIG. 18, the component unit continuum 10Ae in this modified example has a configuration in which a plurality of component units 10i and a plurality of component units 10j are alternately connected by connecting portions 12. Like the component unit 10 in the above embodiment, the component unit 10i has a positive electrode active material layer 120 formed on the surface of the current collector foil 110 facing in the positive Z-axis direction, and a negative electrode active material layer 130 formed on the surface facing in the negative Z-axis direction. The component unit 10j has a negative electrode active material layer 130 formed on the surface of the current collector foil 110 facing in the positive Z-axis direction, and a positive electrode active material layer 120 formed on the surface facing in the negative Z-axis direction. The remaining configuration of this modified example is the same as that of the above embodiment, so detailed description will be omitted.

 この構成において、図19に示すように、部材ユニット連続体10Aeとセパレータ連続体140Aとを交互に折り畳むことにより、部材ユニット10iと部材ユニット10jとの間にセパレータ140を配置することができる。これにより、上記実施の形態と同様の積層順で、集電箔110、正極活物質層120、負極活物質層130及びセパレータ140が積層される。その後、枠部材30から突出した接続部12及び21を切り離す。これらの詳細、及び、以降の処理については、上記実施の形態における製造方法と同様である。 In this configuration, as shown in FIG. 19, by alternately folding the component unit continuous body 10Ae and the separator continuous body 140A, the separator 140 can be placed between the component unit 10i and the component unit 10j. This results in the current collector foil 110, positive electrode active material layer 120, negative electrode active material layer 130, and separator 140 being stacked in the same stacking order as in the above embodiment. Thereafter, the connecting portions 12 and 21 protruding from the frame member 30 are cut off. These details and subsequent processing are the same as in the manufacturing method in the above embodiment.

 (変形例4)
 上記実施の形態では、蓄電装置1としてバイポーラ構造を製造することを目的としたが、本発明はこれに限定されず、モノポーラ構造も形成することができる。図20Aは、本実施の形態の変形例4に係る部材ユニット連続体10Afの構成を示す平面図であり、図20Bは、本実施の形態の変形例4に係る部材ユニット連続体10Agの構成を示す平面図である。図20A及び図20Bは、図5Aに対応する図である。図21は、本実施の形態の変形例4に係る蓄電装置の製造方法における部材ユニット連続体10Af及び10Agを折り畳んだ後に接続部12、13を切り離す工程を示す断面図である。図21は、図12に対応する図である。
(Variation 4)
In the above embodiment, the object is to manufacture a bipolar structure as the energy storage device 1, but the present invention is not limited thereto, and a monopolar structure can also be formed. Fig. 20A is a plan view showing the configuration of a component unit continuum 10Af according to Modification 4 of the present embodiment, and Fig. 20B is a plan view showing the configuration of a component unit continuum 10Ag according to Modification 4 of the present embodiment. Figs. 20A and 20B are views corresponding to Fig. 5A. Fig. 21 is a cross-sectional view showing a step of cutting off the connection portions 12, 13 after folding the component unit continuums 10Af and 10Ag in the manufacturing method of the energy storage device according to Modification 4 of the present embodiment. Fig. 21 is a view corresponding to Fig. 12.

 図20Aに示すように、本変形例における部材ユニット連続体10Afは、複数の部材ユニット10kが接続部12によって接続された構成を有している。部材ユニット10kは、集電箔110のうちの正極集電箔である正極金属層111のZ軸方向の両面に正極活物質層120が形成されたものである。 As shown in Figure 20A, the component unit continuum 10Af in this modified example has a configuration in which multiple component units 10k are connected by connecting portions 12. Each component unit 10k has a positive electrode active material layer 120 formed on both sides in the Z-axis direction of a positive electrode metal layer 111, which is the positive electrode current collector foil of a current collector foil 110.

 図20Bに示すように、本変形例における部材ユニット連続体10Agは、複数の部材ユニット10lが接続部13によって接続された構成を有している。部材ユニット10lは、集電箔110のうちの負極集電箔である負極金属層112のZ軸方向の両面に負極活物質層130が形成されたものである。 As shown in Figure 20B, the component unit continuum 10Ag in this modified example has a configuration in which multiple component units 10l are connected by connecting portions 13. The component unit 10l has a negative electrode active material layer 130 formed on both sides in the Z-axis direction of the negative electrode metal layer 112, which is the negative electrode current collector foil of the current collector foil 110.

 この構成において、図21に示すように、部材ユニット連続体10Af及び部材ユニット連続体10Agとセパレータ連続体140Aとを交互に折り畳むことにより、部材ユニット10kと部材ユニット10lとの間にセパレータ140を配置する。これにより、正極金属層111の両面に正極活物質層120が形成された部材ユニット10kと、負極金属層112の両面に負極活物質層130が形成された部材ユニット10lとが、セパレータ140を介して積層される。その後、枠部材30から突出した接続部12、13及び21を切り離す。正極金属層111に残った接続部12の一部、及び、負極金属層112に残った接続部13の一部は、タブとして用いることができる。この場合、正極金属層111及び負極金属層112に接続部12及び13が長く残るように、接続部12及び13を切り離してもよい。本変形例で構成した、電極積層体をタブで並列接続すると、これまでの実施例で説明したバイポーラ構造ではなく、モノポーラ構造を形成することができる。 In this configuration, as shown in FIG. 21 , the component unit continuum 10Af, the component unit continuum 10Ag, and the separator continuum 140A are alternately folded to place a separator 140 between the component unit 10k and the component unit 10l. As a result, the component unit 10k, in which the positive electrode active material layer 120 is formed on both sides of the positive electrode metal layer 111, and the component unit 10l, in which the negative electrode active material layer 130 is formed on both sides of the negative electrode metal layer 112, are stacked via the separator 140. The connection portions 12, 13, and 21 protruding from the frame member 30 are then cut off. The portion of the connection portion 12 remaining on the positive electrode metal layer 111 and the portion of the connection portion 13 remaining on the negative electrode metal layer 112 can be used as tabs. In this case, the connection portions 12 and 13 may be cut off so that longer portions of the connection portions 12 and 13 remain on the positive electrode metal layer 111 and the negative electrode metal layer 112. By connecting the electrode stacks constructed in this modified example in parallel with tabs, a monopolar structure can be formed, rather than the bipolar structure described in the previous examples.

 (その他の変形例)
 上記実施の形態では、部材ユニット連続体としての、部材ユニット連続体10A及びセパレータ連続体140Aが配置されることとしたが、これには限定されない。部材ユニット連続体10Aが配置されず、部材ユニット10の単体が配置されてもよいし、セパレータ連続体140Aが配置されず、セパレータ140の単体が配置されてもよい。他の部材ユニット連続体についても同様である。つまり、少なくとも1つの部材ユニット連続体が配置されればよい。
(Other Modifications)
In the above embodiment, the component unit continuum 10A and the separator continuum 140A are arranged as the component unit continuum, but this is not limited to this. The component unit continuum 10A may not be arranged, and a single component unit 10 may be arranged, or the separator continuum 140A may not be arranged, and a single separator 140 may be arranged. The same applies to other component unit continuums. In other words, it is sufficient that at least one component unit continuum is arranged.

 上記実施の形態において、集電箔110の辺の数は偶数でなくて奇数でもよく、集電箔110は、平面視で三角形状、五角形状等でもよい。中間箔11、セパレータ140等についても同様である。つまり、蓄電装置1の平面視での形状は、偶数角形、奇数角形、円形等、どのような形状でもよい。 In the above embodiment, the number of sides of the current collector foil 110 may be odd rather than even, and the current collector foil 110 may be triangular, pentagonal, etc. in plan view. The same applies to the intermediate foil 11, separator 140, etc. In other words, the shape of the energy storage device 1 in plan view may be any shape, such as an even polygon, odd polygon, or circle.

 上記実施の形態では、集電箔110の一辺に、当該一辺の長さよりも短い幅の接続部12を接続することとしたが、当該一辺の長さと同じ、または、当該一辺の長さよりも長い幅の接続部12を接続してもよい。セパレータ140等についても同様である。 In the above embodiment, a connection portion 12 with a width shorter than the length of one side of the current collecting foil 110 is connected to that side, but a connection portion 12 with a width equal to or longer than the length of that side may also be connected. The same applies to the separator 140, etc.

 上記実施の形態では、集電箔110等を枠部材30に挿入して部材ユニット連続体10Aを折り畳むこととしたが、集電箔110等を枠部材30に挿入することなく部材ユニット連続体10Aを折り畳んでもよい。セパレータ140等についても同様である。 In the above embodiment, the component unit string 10A is folded by inserting the current collecting foil 110 and the like into the frame member 30, but the component unit string 10A may also be folded without inserting the current collecting foil 110 and the like into the frame member 30. The same applies to the separator 140 and the like.

 上記実施の形態では、枠部材30から突出した接続部12を切り離すこととしたが、枠部材30内で接続部12を切り離してもよい。セパレータ140等についても同様である。 In the above embodiment, the connection portions 12 protruding from the frame member 30 are cut off, but the connection portions 12 may also be cut off within the frame member 30. The same applies to the separators 140, etc.

 上記実施の形態において、正極活物質層120と負極活物質層130とが入れ替わってもよい。この場合、中間箔11の貫通孔内に負極活物質層130が配置されてもよい。 In the above embodiment, the positive electrode active material layer 120 and the negative electrode active material layer 130 may be interchanged. In this case, the negative electrode active material layer 130 may be disposed within the through-hole of the intermediate foil 11.

 上記実施の形態では、部材ユニット連続体10Aとともにセパレータ連続体140Aを折り畳むこととしたが、負極活物質層130または正極活物質層120にセパレータ140を接着等で貼り付けておき、部材ユニット連続体10Aを折り畳んでもよい。この場合、セパレータ連続体140Aを折り畳んだり接続部21を切り離す工程を省略できる。 In the above embodiment, the separator continuum 140A is folded together with the component unit continuum 10A, but the separator 140 may be attached to the negative electrode active material layer 130 or the positive electrode active material layer 120 by adhesive or the like, and then the component unit continuum 10A may be folded. In this case, the steps of folding the separator continuum 140A and cutting off the connection portions 21 can be omitted.

 上記実施の形態において、セパレータ140に代えて、固体電解質層を配置してもよい。固体電解質層に用いられる固体電解質としては、適宜公知のものを使用できる。 In the above embodiment, a solid electrolyte layer may be disposed in place of the separator 140. Any known solid electrolyte may be used as the solid electrolyte layer.

 上記実施の形態において、蓄電装置1は、図22に示すような蓄電パック1Aに用いられてもよい。図22は、蓄電パック1Aの構成を示す平面図である。図22に示すように、蓄電パック1Aは、複数の蓄電装置1を備えている。蓄電装置1は、平面視で正六角形状を有しているため、平面視で、1つの蓄電装置1の周囲に6つの蓄電装置1を配置できる。複数の蓄電装置1は、直列接続または並列接続される。蓄電パック1Aは、複数の蓄電装置1を収容する金属ケースまたは樹脂ケース等も備えているが、図示は省略する。蓄電パック1Aに含まれる少なくとも1つの蓄電装置1に対して、本発明の技術が適用されればよい。 In the above embodiment, the energy storage device 1 may be used in an energy storage pack 1A as shown in FIG. 22. FIG. 22 is a plan view showing the configuration of the energy storage pack 1A. As shown in FIG. 22, the energy storage pack 1A includes multiple energy storage devices 1. Because the energy storage device 1 has a regular hexagonal shape in a plan view, six energy storage devices 1 can be arranged around one energy storage device 1 in a plan view. The multiple energy storage devices 1 are connected in series or in parallel. The energy storage pack 1A also includes a metal case, resin case, or the like that houses the multiple energy storage devices 1, but this is not shown in the figures. The technology of the present invention may be applied to at least one energy storage device 1 included in the energy storage pack 1A.

 蓄電装置1は、図23に示すような蓄電パック1Bに用いられてもよい。図23は、蓄電パック1Bの構成を示す断面図である。図23において、蓄電装置1の内部構成の図示は省略している。図23に示すように、蓄電パック1Bは、複数の蓄電装置1が積層された蓄電装置積層体2と、導電部材3と、を備えている。この場合、蓄電パック1Bに含まれる少なくとも1つの蓄電装置1に対して、本発明の技術が適用されればよい。蓄電装置積層体2における隣り合う2つの蓄電装置1は、接触または接合(溶接等)によって電気的に接続される。導電部材3は、ステンレス等の金属からなり、積層方向(Z軸方向)の端部に位置する蓄電装置1と導電部材3とは、接触または接合(溶接等)によって電気的に接続される。接合には接着剤を用いてもよい。蓄電装置積層体2における複数の蓄電装置1は直列に接続されており、導電部材3を介して充放電が実施される。蓄電パック1Bは、積層方向(Z軸方向)に拘束されてもよく、この場合、ネジ、樹脂バンドまたは金属バンド等の拘束部材を用いることができる。蓄電装置積層体2及び導電部材3は、金属ケースまたは樹脂ケースに収容されていてもよい。 23 。 The energy storage device 1 may be used in an energy storage pack 1B as shown in FIG. 23. FIG. 23 is a cross-sectional view showing the configuration of the energy storage pack 1B. The internal configuration of the energy storage device 1 is omitted from FIG. 23. As shown in FIG. 23, the energy storage pack 1B includes an energy storage device stack 2 in which multiple energy storage devices 1 are stacked, and a conductive member 3. In this case, the technology of the present invention only needs to be applied to at least one energy storage device 1 included in the energy storage pack 1B. Two adjacent energy storage devices 1 in the energy storage device stack 2 are electrically connected by contact or bonding (welding, etc.). The conductive member 3 is made of a metal such as stainless steel, and the energy storage device 1 located at the end in the stacking direction (Z-axis direction) and the conductive member 3 are electrically connected by contact or bonding (welding, etc.). An adhesive may be used for bonding. The multiple energy storage devices 1 in the energy storage device stack 2 are connected in series, and charging and discharging are performed via the conductive member 3. The electricity storage pack 1B may be restrained in the stacking direction (Z-axis direction) using restraining members such as screws, resin bands, or metal bands. The electricity storage device stack 2 and conductive member 3 may be housed in a metal or resin case.

 蓄電パック1Bの他の例として、個々の蓄電装置1が外装体4に収容された構成を図24に示す。図24は、蓄電パック1Cの構成を示す断面図である。図24に示すように、本構成の蓄電装置1は、外装体4から露出した接続部分5を備えている。外装体4としてラミネートフィルム等を用いることができる。隣り合う蓄電装置1の接続部分5同士が、接触または接合(溶接等)によって電気的に接続されている。積層方向(Z軸方向)の端部に位置する蓄電装置1の接続部分5と導電部材3とは、接触または接合(溶接等)によって電気的に接続されている。その他の構成は、上述の蓄電パック1Bと同様のため説明を省略する。 As another example of an electricity storage pack 1B, Figure 24 shows a configuration in which individual electricity storage devices 1 are housed in an exterior housing 4. Figure 24 is a cross-sectional view showing the configuration of an electricity storage pack 1C. As shown in Figure 24, the electricity storage device 1 of this configuration has a connection portion 5 exposed from the exterior housing 4. A laminate film or the like can be used as the exterior housing 4. The connection portions 5 of adjacent electricity storage devices 1 are electrically connected by contact or bonding (welding, etc.). The connection portion 5 of the electricity storage device 1 located at the end in the stacking direction (Z-axis direction) and the conductive member 3 are electrically connected by contact or bonding (welding, etc.). The rest of the configuration is the same as that of the above-mentioned electricity storage pack 1B, so description will be omitted.

 上記実施の形態及びその変形例に含まれる構成要素を任意に組み合わせて構築される形態も、本発明の範囲内に含まれる。 Configurations constructed by any combination of the components included in the above embodiments and their variations are also within the scope of the present invention.

 本発明は、バイポーラ電池等の蓄電装置の製造方法に適用できる。 The present invention can be applied to manufacturing methods for power storage devices such as bipolar batteries.

 1 蓄電装置
 1A、1B、1C 蓄電パック
 2 蓄電装置積層体
 3 導電部材
 4 外装体
 5 接続部分
 10、10a、10b、10c、10d、10e、10f、10g、10h、10i、10j、10k、10l 部材ユニット(電極部材ユニット)
 10A、10Aa、10Ab、10Ac、10Ad、10Ae、10Af、10Ag 部材ユニット連続体
 11、11a、11b、11c、11d 中間箔
 11a1、11b1、11c1、11d1 貫通孔
 12、12a、12b、12c、12d、13、13a、13b、13c、21、21a、21b、21c 接続部
 30 枠部材
 31、32、33 側壁
 31a、32a 開口部
 34 底壁
 100 電極ユニット
 101、102 エンドユニット
 110 集電箔
 111 正極金属層(金属層)
 112 負極金属層(金属層)
 120 正極活物質層
 130 負極活物質層
 140、140a、140b セパレータ
 140A セパレータ連続体
 200 外周封止部材
 210 シール部材
 300 エンド部材
 400 積層体
REFERENCE SIGNS LIST 1 Energy storage device 1A, 1B, 1C Energy storage pack 2 Energy storage device laminate 3 Conductive member 4 Exterior body 5 Connection portion 10, 10a, 10b, 10c, 10d, 10e, 10f, 10g, 10h, 10i, 10j, 10k, 10l Member unit (electrode member unit)
10A, 10Aa, 10Ab, 10Ac, 10Ad, 10Ae, 10Af, 10Ag Component unit continuum 11, 11a, 11b, 11c, 11d Intermediate foil 11a1, 11b1, 11c1, 11d1 Through hole 12, 12a, 12b, 12c, 12d, 13, 13a, 13b, 13c, 21, 21a, 21b, 21c Connection portion 30 Frame member 31, 32, 33 Side wall 31a, 32a Opening 34 Bottom wall 100 Electrode unit 101, 102 End unit 110 Current collecting foil 111 Positive electrode metal layer (metal layer)
112 Negative electrode metal layer (metal layer)
120 Positive electrode active material layer 130 Negative electrode active material layer 140, 140a, 140b Separator 140A Separator continuous body 200 Peripheral sealing member 210 Sealing member 300 End member 400 Laminate

Claims (5)

 積層方向に積層された複数の部材ユニットを備える蓄電装置の製造方法であって、
 複数の前記部材ユニットを接続部で接続した部材ユニット連続体を配置することと、
 前記接続部の位置で前記部材ユニット連続体を折り畳むことと、
 前記部材ユニット連続体を折り畳んだ後に、前記接続部を取り外すことと、
 を含む蓄電装置の製造方法。
A method for manufacturing an electricity storage device including a plurality of component units stacked in a stacking direction,
Arranging a member unit continuum in which a plurality of the member units are connected by connecting portions;
folding the continuous member unit body at the position of the connecting portion;
After folding the member unit continuous body, the connecting portion is removed;
A method for manufacturing an electricity storage device comprising:
 少なくとも前記部材ユニット連続体の一部は、集電箔の一方の面に正極活物質層が配置され、前記集電箔の他方の面に負極活物質層が配置されている
 請求項1に記載の蓄電装置の製造方法。
The method for manufacturing an electricity storage device according to claim 1 , wherein at least a portion of the member unit continuum has a positive electrode active material layer disposed on one surface of a current collector foil and a negative electrode active material layer disposed on the other surface of the current collector foil.
 前記部材ユニット連続体は、前記積層方向から見て辺の数が4つ以上の偶数である多角形または円形の前記部材ユニットが前記接続部で複数接続されている
 請求項1または2に記載の蓄電装置の製造方法。
The method for manufacturing an energy storage device according to claim 1 or 2, wherein the component unit continuum is made up of a plurality of polygonal or circular component units each having an even number of sides of four or more when viewed from the stacking direction, connected together at the connection portions.
 前記部材ユニット連続体は、前記積層方向から見て多角形であり、前記接続部の幅は、前記多角形の一辺の長さよりも短い
 請求項1または2に記載の蓄電装置の製造方法。
The method for manufacturing an electricity storage device according to claim 1 or 2, wherein the member unit continuum is polygonal when viewed from the stacking direction, and the width of the connection portion is shorter than the length of one side of the polygon.
 前記部材ユニット連続体を折り畳む際には、前記部材ユニットを枠部材に挿入するとともに、前記接続部を折り畳んで前記接続部を前記枠部材から突出させ、
 前記接続部を取り外す際には、前記枠部材から突出した前記接続部を切断する
 請求項1または2に記載の蓄電装置の製造方法。
When folding the member unit continuous body, the member units are inserted into a frame member, and the connecting portions are folded to project from the frame member;
The method for manufacturing an electricity storage device according to claim 1 or 2, wherein when the connecting portion is removed, the connecting portion protruding from the frame member is cut off.
PCT/JP2025/008201 2024-03-13 2025-03-06 Method for manufacturing power storage device Pending WO2025192422A1 (en)

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Citations (5)

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JP2016115471A (en) * 2014-12-12 2016-06-23 シチズンホールディングス株式会社 Flat battery
JP2018045948A (en) * 2016-09-16 2018-03-22 トヨタ自動車株式会社 Stacked battery
JP2018142534A (en) * 2017-02-24 2018-09-13 パナソニックIpマネジメント株式会社 Battery and battery manufacturing method
KR20220017760A (en) * 2020-08-05 2022-02-14 주식회사 엘지에너지솔루션 Multi-ZZS stacking method of stacked assembly and stacked assembly prepared thereby
US20220059910A1 (en) * 2020-08-19 2022-02-24 Millibatt, Inc. Three-dimensional folded battery unit and methods for manufacturing the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016115471A (en) * 2014-12-12 2016-06-23 シチズンホールディングス株式会社 Flat battery
JP2018045948A (en) * 2016-09-16 2018-03-22 トヨタ自動車株式会社 Stacked battery
JP2018142534A (en) * 2017-02-24 2018-09-13 パナソニックIpマネジメント株式会社 Battery and battery manufacturing method
KR20220017760A (en) * 2020-08-05 2022-02-14 주식회사 엘지에너지솔루션 Multi-ZZS stacking method of stacked assembly and stacked assembly prepared thereby
US20220059910A1 (en) * 2020-08-19 2022-02-24 Millibatt, Inc. Three-dimensional folded battery unit and methods for manufacturing the same

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