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WO2025191998A1 - Apparatus for manufacturing hot-dip galvanized steel sheet and method for manufacturing same - Google Patents

Apparatus for manufacturing hot-dip galvanized steel sheet and method for manufacturing same

Info

Publication number
WO2025191998A1
WO2025191998A1 PCT/JP2025/000286 JP2025000286W WO2025191998A1 WO 2025191998 A1 WO2025191998 A1 WO 2025191998A1 JP 2025000286 W JP2025000286 W JP 2025000286W WO 2025191998 A1 WO2025191998 A1 WO 2025191998A1
Authority
WO
WIPO (PCT)
Prior art keywords
molten zinc
steel sheet
hot
sink roll
dip galvanized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/JP2025/000286
Other languages
French (fr)
Japanese (ja)
Inventor
優汰 中村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
JFE Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JFE Steel Corp filed Critical JFE Steel Corp
Publication of WO2025191998A1 publication Critical patent/WO2025191998A1/en
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon

Definitions

  • the present invention relates to a manufacturing apparatus for hot-dip galvanized steel sheets, and more specifically to a manufacturing apparatus for hot-dip galvanized steel sheets that produces plated steel sheets with fewer surface defects, and to a manufacturing method for hot-dip galvanized steel sheets using the apparatus.
  • Hot-dip metal coated steel sheets are widely used in fields such as building materials, automobiles, and home appliances. These applications require hot-dip galvanized steel sheets to have excellent appearance, whether painted or not. Since the appearance of unpainted steel sheets, as well as painted steel sheets, is strongly affected by surface defects such as scratches and foreign matter, it is important that these surface defects are absent.
  • Hot-dip galvanized steel sheets are generally produced in continuous hot-dip galvanizing equipment by immersing the steel sheet in a molten zinc bath (hereinafter referred to as the "bath” or “bath”).
  • the bath contains a sink roll and support rolls, which come into contact with the steel sheet.
  • the steel sheet to be plated is annealed in an annealing furnace, then immersed in the molten zinc bath via a snout.
  • the coating amount is controlled using a gas wiping device, and the plating process is carried out. During this process, oxides of the molten zinc generated in the snout can adhere to the material, resulting in defects.
  • Patent Document 1 is an example of a technology for controlling the flow of the molten zinc bath.
  • Patent Document 1 discloses a device installed above the sink roll, which controls the flow of molten zinc in the molten zinc vessel and prevents dross from being entrained by the support rolls.
  • Patent Document 1 controls the flow of bottom dross, which has a higher density than molten zinc and is more likely to settle, on the surface of the coating bath.
  • the flow generated by the collision between the accompanying flow of the steel sheet entering the molten zinc bath and the accompanying flow caused by the rotation of the sink roll is called the "impingement flow.”
  • Patent Document 1 does not take into consideration ash generated in the snout and carried by the impingement flow. In particular, the distance between the lower end of the straightening plate and the surface of the sink roll is large, and the impingement flow cannot be prevented from flowing toward the support roll relative to the straightening plate. This results in the problem of ash coming into contact with the steel sheet being pulled up, resulting in surface defects.
  • the present invention was made to solve the above problems, and its purpose is to provide an apparatus for manufacturing hot-dip galvanized steel sheets with fewer surface defects and reduced ash defect generation. Furthermore, it also aims to propose a method for manufacturing hot-dip galvanized steel sheets using this manufacturing apparatus.
  • the inventors conducted a flow analysis of a manufacturing device for hot-dip galvanized steel sheets. As a result, they discovered that the flow within the molten zinc bath changes depending on the relative positions of the flow straighteners and sink rolls. In particular, they discovered that it is possible to suppress the flow that causes zinc oxide generated within the snout to adhere to the steel strip surface.
  • the manufacturing apparatus for hot-dip galvanized steel sheets of the present invention which advantageously solves the above-mentioned problems, is a manufacturing apparatus for hot-dip galvanized steel sheets in which a steel sheet to be plated is immersed in a molten zinc bath and molten zinc is deposited on the surface to form a coating layer, and is equipped with a molten zinc container for storing molten zinc, a snout which is arranged so that its end is immersed in the molten zinc bath in the molten zinc container and supplies the steel sheet to be plated into the molten zinc bath, a sink roll which is arranged so that it is immersed in the molten zinc bath in the molten zinc container and around which the steel sheet to be plated is wrapped, a support roll which is arranged above the sink roll so that it is immersed in the molten zinc bath and is positioned in contact with one or both sides of the steel sheet to be plated on the pull-up side, and a straightening plate which is arranged above
  • the manufacturing apparatus for hot-dip galvanized steel sheet comprises: (a) the width of the straightening plate is equal to or greater than the width of the steel sheet to be plated; (b) the rectifying plate has a plate thickness of 9 mm or more and has ribs; would be a more preferable solution.
  • the method for manufacturing hot-dip galvanized steel sheet according to the present invention which advantageously solves the above-mentioned problems, is characterized by including the steps of immersing a steel sheet to be plated in a hot-dip galvanizing bath using any of the hot-dip galvanized steel sheet manufacturing apparatuses described above, and depositing molten zinc on the surface of the steel sheet to form a coating layer.
  • the lower end of the straightening plate installed above the sink roll of the molten zinc bath is positioned closer to the sink roll, thereby suppressing the flow that causes zinc oxide generated in the snout to adhere to the surface of the steel strip at the exit of the molten zinc bath.
  • zinc oxide can be prevented from adhering to the steel strip, and the incidence of ash defects can be significantly reduced, improving productivity and providing industrial usefulness.
  • FIG. 1 is a schematic conceptual diagram showing a manufacturing apparatus for a hot-dip galvanized steel sheet according to an embodiment of the present invention.
  • FIG. 2 is a schematic conceptual diagram illustrating the flow of a molten zinc bath according to the embodiment.
  • FIG. 1 is a schematic conceptual diagram illustrating the flow of a molten zinc bath on a conventional flow straightening ramp.
  • FIG. 1 shows a schematic diagram of a hot-dip galvanized steel sheet manufacturing apparatus according to one embodiment of the present invention.
  • the hot-dip galvanized steel sheet manufacturing apparatus 10 comprises a molten zinc container 1 for storing molten zinc Z, a snout 2 with its end immersed in the molten zinc bath, and a sink roll 4 and support rolls 5 and 6 immersed in the molten zinc bath.
  • the apparatus is equipped with a straightening plate 7 having a straightening mechanism for controlling the flow of molten zinc within the molten zinc container 1.
  • the hot-dip galvanized steel sheet manufacturing apparatus 10 may also be equipped with a coil payoff device, payoff reel, annealing furnace, gas wiping device, alloying furnace, coil winding device, and other accessories not shown.
  • the steel sheet 3 to be plated is continuously supplied from inside the snout 2 to the molten zinc bath stored in the molten zinc vessel 1.
  • the steel sheet 3 to be plated is wrapped around the sink roll 4, changing its course from the approach direction to the pull-up direction.
  • the back side support roll 5, which is on the inward winding side of the sink roll 4 of the steel sheet 3 to be plated being pulled up, and the front side support roll 6, which is on the outside, are arranged to contact the steel sheet 3 to be plated.
  • the back side of the steel sheet to be plated is referred to as side B, and the front side is also referred to as side F.
  • the support rolls 5 and 6 are arranged above the sink roll 4, and may be on one side of the steel sheet 3 to be plated.
  • the current plate 7 installed above the sink roll 4 is characterized in the following manner. 1)
  • the shortest distance a from the lower end position of the straightening plate 7 to the surface of the sink roll 4 is in the range of more than 0 mm and not more than 50 mm.
  • the lower end position of the straightening plate 7 is in the range from the horizontal end of the snout side of the sink roll to the central axis CL of the sink roll 4.
  • the distance b between the horizontal lower end position of the straightening plate 7 and the horizontal end of the snout side of the sink roll 4 is greater than or equal to 0 and less than the radius of the sink roll 4, with the direction toward the central axis CL being positive.
  • Figure 2 is a schematic diagram conceptually showing the flow of the molten zinc bath with the straightening vane 7 positioned according to this embodiment.
  • Figure 3 is a schematic diagram conceptually showing the flow of the molten zinc bath with the conventional straightening vane position, where ash defects occur.
  • Zinc oxide generated within the snout 2 enters the molten zinc bath on the accompanying flow of the steel sheet 3 to be plated as it enters the bath.
  • This zinc oxide has a lower specific gravity than molten zinc, so it floats in the molten zinc bath and moves with the flow. It is thought that the zinc oxide then adheres to the steel sheet to be plated and is pressed against the roll, becoming an ash defect.
  • the flow accompanying the steel sheet 3 to be plated supplied from the snout 2 collides with the flow accompanying it on the upper surface as the sink roll 4 rotates, forming a collision flow that sprays upward. This collision flow contains zinc oxide.
  • the lower end of the conventional straightening plate 7A is in contact with the impinging flow, distributing the flow of the molten zinc bath toward the support roll.
  • the impinging flow is not distributed toward the support roll, and zinc oxide can be floated to the bath surface 8 between the snout 2 and the straightening plate 7 on an extension line. This reduces ash defects.
  • the material for the straightening plate 7 is preferably SUS316L.
  • the thickness of the straightening plate 7 is preferably 9 mm or more from the viewpoint of preventing deformation.
  • an excessively heavy straightening plate 7 may make installation difficult, so a thickness of 15 mm or less is preferable.
  • the thickness of the steel sheet 3 to be plated is not particularly limited, but is, for example, 0.4 to 3.5 mm.
  • Example 1 Using a manufacturing apparatus for hot-dip galvanized steel sheets configured according to Figure 1, the rate of ash defect occurrence on the steel sheet surface was investigated by changing the lower end position of the straightening plate. The results are summarized in Table 1. The rate of ash defect occurrence was calculated using flow analysis software to calculate the trajectory of the zinc oxide simulant particles, and the rate was calculated as the percentage of particles that reached the steel sheet to be plated relative to the total number of particles. The results in Table 1 show that the invention examples were able to significantly reduce the rate of ash defect occurrence compared to the comparative examples.
  • Example 2 Next, the deformation of the plate, i.e., the amount of warpage, was investigated for each plate thickness under the arrangement of the straightening plates under condition No. 3 in Table 1. The amount of warpage of the plated steel plate after passing through 20,000 tons is summarized in Table 2. By setting the plate thickness to 9.0 mm, the deformation of the straightening plates was significantly reduced.
  • the unit of mass "t" is 1000 kg.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Abstract

Provided is a technology for manufacturing a hot-dip galvanized steel sheet with few surface defects. This apparatus for manufacturing a hot-dip galvanized steel sheet comprises: a molten zinc container for storing molten zinc; a snout which is provided so that an end part thereof is immersed in a molten zinc bath in the molten zinc container and which supplies a steel sheet into the molten zinc bath; a sink roll which is provided so as to be immersed in the molten zinc bath in the molten zinc container and on which the steel sheet is rolled up; a support roll which is provided above the sink roll so as to be immersed in the molten zinc bath and which is disposed so as to be in contact with one side or both sides of the steel sheet on the side pulled up; and a flow regulating plate which is provided above the sink roll and which has a flow regulating mechanism for regulating a molten zinc flow in the molten zinc container, wherein the flow regulating plate is installed so that the shortest distance from the lower end position to the sink roll surface falls within the range of more than 0 mm and 50 mm or less, and the lower end position is located in the range from the end part of the sink roll on the snout side in the horizontal direction to the center axis of the sink roll in the top view.

Description

溶融亜鉛めっき鋼板の製造装置およびその製造方法Manufacturing apparatus for hot-dip galvanized steel sheet and manufacturing method thereof

 本発明は、溶融亜鉛めっき鋼板の製造装置に関し、詳しくは、表面欠陥の少ないめっき鋼板を製造する溶融亜鉛めっき鋼板の製造装置に関し、その装置を用いた溶融亜鉛めっき鋼板の製造方法に関するものである。 The present invention relates to a manufacturing apparatus for hot-dip galvanized steel sheets, and more specifically to a manufacturing apparatus for hot-dip galvanized steel sheets that produces plated steel sheets with fewer surface defects, and to a manufacturing method for hot-dip galvanized steel sheets using the apparatus.

 溶融金属めっき鋼板、特に、溶融亜鉛めっき鋼板は、建材、自動車、家電等の分野で広く使用されている。そして、これらの用途では、塗装の有無に係わらず外観に優れることが溶融亜鉛めっき鋼板に対して要求される。ここで、無塗装の場合はもちろんのこと、塗装後の外観は、疵や異物付着等の表面欠陥の影響を強く受けるため、これらの表面欠陥が存在しないことが重要である。 Hot-dip metal coated steel sheets, especially hot-dip galvanized steel sheets, are widely used in fields such as building materials, automobiles, and home appliances. These applications require hot-dip galvanized steel sheets to have excellent appearance, whether painted or not. Since the appearance of unpainted steel sheets, as well as painted steel sheets, is strongly affected by surface defects such as scratches and foreign matter, it is important that these surface defects are absent.

 溶融亜鉛めっき鋼板は、一般的には、連続溶融亜鉛めっき設備において、溶融亜鉛浴(以下、めっき浴、または、浴と称することもある)中に鋼板を浸漬して製造される。めっき浴槽中には、シンクロール、サポートロールが存在し、鋼板と接触している。被めっき材である鋼板を焼鈍炉で焼鈍し、スナウトを経由して溶融亜鉛浴に鋼板を浸漬し、ガスワイピング装置にて付着量を制御しめっき処理を行っている。このとき、スナウト内で発生する溶融亜鉛の酸化物が被めっき材に付着することで欠陥となる問題がある。以下、この欠陥をアッシュ欠陥と称する。このアッシュ欠陥を防止するには、溶融亜鉛浴の流動を制御し、亜鉛酸化物が被めっき材に付着する流れを抑止する必要がある。溶融亜鉛浴の流動を制御する技術として、たとえば、特許文献1があげられる。特許文献1には、シンクロールの上方に設けられ、溶融亜鉛容器内の溶融亜鉛流を制御する整流機構を有し、サポートロールでのドロス巻き込みの抑制が可能な装置が開示されている Hot-dip galvanized steel sheets are generally produced in continuous hot-dip galvanizing equipment by immersing the steel sheet in a molten zinc bath (hereinafter referred to as the "bath" or "bath"). The bath contains a sink roll and support rolls, which come into contact with the steel sheet. The steel sheet to be plated is annealed in an annealing furnace, then immersed in the molten zinc bath via a snout. The coating amount is controlled using a gas wiping device, and the plating process is carried out. During this process, oxides of the molten zinc generated in the snout can adhere to the material, resulting in defects. These defects are referred to as "ash defects." To prevent these ash defects, it is necessary to control the flow of the molten zinc bath and prevent zinc oxides from adhering to the material. Patent Document 1, for example, is an example of a technology for controlling the flow of the molten zinc bath. Patent Document 1 discloses a device installed above the sink roll, which controls the flow of molten zinc in the molten zinc vessel and prevents dross from being entrained by the support rolls.

特開2013-224457号公報JP 2013-224457 A

 しかしながら、上記従来技術には以下のような解決しなければならない課題がある。
 すなわち、特許文献1に記載の技術は、溶融亜鉛より密度が大きく沈降しやすい、いわゆる、ボトムドロスに対するめっき浴面側の流れを制御するものである。ここで、溶融亜鉛浴に進入する鋼板の随伴流とシンクロールの回転による随伴流との衝突によって発生する流れを「衝突流」と称する。特許文献1には、スナウト内で発生し、衝突流に載って運ばれるアッシュについては考慮されていない。とくに、整流板の下端とシンクロールの表面との距離が大きく、整流板に対しサポートロール側に衝突流が流れることを抑止できていない。そのため、アッシュが引き上げられる鋼板に接触して、表面欠陥となる問題がある。
However, the above-mentioned conventional techniques have the following problems to be solved.
That is, the technology described in Patent Document 1 controls the flow of bottom dross, which has a higher density than molten zinc and is more likely to settle, on the surface of the coating bath. Here, the flow generated by the collision between the accompanying flow of the steel sheet entering the molten zinc bath and the accompanying flow caused by the rotation of the sink roll is called the "impingement flow." Patent Document 1 does not take into consideration ash generated in the snout and carried by the impingement flow. In particular, the distance between the lower end of the straightening plate and the surface of the sink roll is large, and the impingement flow cannot be prevented from flowing toward the support roll relative to the straightening plate. This results in the problem of ash coming into contact with the steel sheet being pulled up, resulting in surface defects.

 本発明は上記課題を解決するためになされたものであり、その目的とするところは、アッシュ欠陥の発生を低減した表面欠陥の少ない溶融亜鉛めっき鋼板を製造する装置を提供することである。さらには、その製造装置を用いて溶融亜鉛めっき鋼板を製造する方法を提案することである。 The present invention was made to solve the above problems, and its purpose is to provide an apparatus for manufacturing hot-dip galvanized steel sheets with fewer surface defects and reduced ash defect generation. Furthermore, it also aims to propose a method for manufacturing hot-dip galvanized steel sheets using this manufacturing apparatus.

 発明者は、溶融亜鉛めっき鋼板の製造装置において、流動解析を行った。その結果、整流板とシンクロールとの位置関係により、溶融亜鉛浴内の流動に変化があることを知見した。とくに、スナウト内で発生する酸化亜鉛が鋼帯表面に付着する原因となる流れを抑止することが可能であることを知見した。 The inventors conducted a flow analysis of a manufacturing device for hot-dip galvanized steel sheets. As a result, they discovered that the flow within the molten zinc bath changes depending on the relative positions of the flow straighteners and sink rolls. In particular, they discovered that it is possible to suppress the flow that causes zinc oxide generated within the snout to adhere to the steel strip surface.

 上記課題を有利に解決する本発明にかかる溶融亜鉛めっき鋼板の製造装置は、溶融亜鉛浴中に被めっき鋼板を浸漬し、その表面に溶融亜鉛を付着させてめっき層を形成する溶融亜鉛めっき鋼板の製造装置であって、溶融亜鉛を貯留する溶融亜鉛容器と、端部が前記溶融亜鉛容器内の溶融亜鉛浴に浸漬するように設けられ、溶融亜鉛浴中に被めっき鋼板を供給するスナウトと、前記溶融亜鉛容器内の溶融亜鉛浴に浸漬するように設けられ、被めっき鋼板が巻き掛けられるシンクロールと、該シンクロールの上方に前記溶融亜鉛浴に浸漬するように設けられ、被めっき鋼板の引上げ側の片面または両面に接して配置されるサポートロールと、前記シンクロールの上方に設けられ、前記溶融亜鉛容器内の溶融亜鉛流を制御する整流機構を有する整流板と、を具備し、前記整流板は、下端位置からシンクロール表面までの最短距離が0mm超え50mm以下の範囲にあり、上面視で下端位置がシンクロールのスナウト側水平方向端部からシンクロールの中心軸までの範囲にあるように設置されたことを特徴とする。 The manufacturing apparatus for hot-dip galvanized steel sheets of the present invention, which advantageously solves the above-mentioned problems, is a manufacturing apparatus for hot-dip galvanized steel sheets in which a steel sheet to be plated is immersed in a molten zinc bath and molten zinc is deposited on the surface to form a coating layer, and is equipped with a molten zinc container for storing molten zinc, a snout which is arranged so that its end is immersed in the molten zinc bath in the molten zinc container and supplies the steel sheet to be plated into the molten zinc bath, a sink roll which is arranged so that it is immersed in the molten zinc bath in the molten zinc container and around which the steel sheet to be plated is wrapped, a support roll which is arranged above the sink roll so that it is immersed in the molten zinc bath and is positioned in contact with one or both sides of the steel sheet to be plated on the pull-up side, and a straightening plate which is arranged above the sink roll and has a straightening mechanism for controlling the flow of molten zinc in the molten zinc container, and is characterized in that the shortest distance from the lower end position to the sink roll surface is in the range of more than 0 mm and not more than 50 mm, and the lower end position of the straightening plate is installed so that it is in the range from the horizontal end of the snout side of the sink roll to the central axis of the sink roll when viewed from above.

 なお、本発明にかかる溶融亜鉛めっき鋼板の製造装置は、
(a)前記整流板の幅が、被めっき鋼板の板幅以上であること、
(b)前記整流板は、板厚が9mm以上であり、リブを有すること、
などがより好ましい解決手段になる。
The manufacturing apparatus for hot-dip galvanized steel sheet according to the present invention comprises:
(a) the width of the straightening plate is equal to or greater than the width of the steel sheet to be plated;
(b) the rectifying plate has a plate thickness of 9 mm or more and has ribs;
would be a more preferable solution.

上記課題を有利に解決する本発明にかかる溶融亜鉛めっき鋼板の製造方法は、上記いずれかにかかる溶融亜鉛めっき鋼板の製造装置を用いて、溶融亜鉛めっき浴中に被めっき鋼板を浸漬し、該被めっき鋼板の表面に溶融亜鉛を付着させてめっき層を形成する工程を含むことを特徴とする。 The method for manufacturing hot-dip galvanized steel sheet according to the present invention, which advantageously solves the above-mentioned problems, is characterized by including the steps of immersing a steel sheet to be plated in a hot-dip galvanizing bath using any of the hot-dip galvanized steel sheet manufacturing apparatuses described above, and depositing molten zinc on the surface of the steel sheet to form a coating layer.

 本発明によれば、溶融亜鉛浴のシンクロールの上方に設けた整流板の下端位置をシンクロールに近づけたので、スナウト内で発生する酸化亜鉛が溶融亜鉛浴の出側鋼帯の表面に付着する原因となる流れを抑止することができる。その結果、酸化亜鉛の鋼帯付着を防止でき、アッシュ欠陥の発生率を大きく低減することができるようになったので生産性が向上し、産業上有用である。 According to the present invention, the lower end of the straightening plate installed above the sink roll of the molten zinc bath is positioned closer to the sink roll, thereby suppressing the flow that causes zinc oxide generated in the snout to adhere to the surface of the steel strip at the exit of the molten zinc bath. As a result, zinc oxide can be prevented from adhering to the steel strip, and the incidence of ash defects can be significantly reduced, improving productivity and providing industrial usefulness.

本発明の一実施形態にかかる溶融亜鉛めっき鋼板の製造装置を示す模式概念図である。1 is a schematic conceptual diagram showing a manufacturing apparatus for a hot-dip galvanized steel sheet according to an embodiment of the present invention. 上記実施形態にかかる溶融亜鉛浴の流れを例示する模式概念図である。FIG. 2 is a schematic conceptual diagram illustrating the flow of a molten zinc bath according to the embodiment. 従来の整流坂にかかる溶融亜鉛浴の流れを例示する模式概念図である。FIG. 1 is a schematic conceptual diagram illustrating the flow of a molten zinc bath on a conventional flow straightening ramp.

 以下、本発明の実施の形態について具体的に説明する。なお、各図面は模式的なものであって、現実のものとは異なる場合がある。また、以下の実施形態は、本発明の技術的思想を具体化するための装置や方法を例示するものであり、構成を下記のものに特定するものでない。すなわち、本発明の技術的思想は、特許請求の範囲に記載された技術的範囲内において、種々の変更を加えることができる。 The following describes in detail the embodiments of the present invention. Note that the drawings are schematic and may differ from the actual product. Furthermore, the following embodiments exemplify devices and methods that embody the technical concepts of the present invention, and are not intended to limit the configuration to those described below. In other words, the technical concepts of the present invention can be modified in various ways within the technical scope set forth in the claims.

 図1に本発明の一実施形態にかかる溶融亜鉛めっき鋼板の製造装置を模式概略図で示す。溶融亜鉛めっき鋼板の製造装置10は、溶融亜鉛Zを貯留する溶融亜鉛容器1と、端部が溶融亜鉛浴に浸漬するように設けられたスナウト2と、溶融亜鉛浴内に浸漬されたシンクロール4およびサポートロール5、6と、を具備する。本実施形態では、溶融亜鉛容器1内の溶融亜鉛流を制御する整流機構を有する整流板7を具備する。溶融亜鉛めっき鋼板の製造装置10は図示しないコイル払出装置やペイオフリール、焼鈍炉、ガスワイピング装置、合金化炉、コイル巻取装置などが付帯していてもよい。 FIG. 1 shows a schematic diagram of a hot-dip galvanized steel sheet manufacturing apparatus according to one embodiment of the present invention. The hot-dip galvanized steel sheet manufacturing apparatus 10 comprises a molten zinc container 1 for storing molten zinc Z, a snout 2 with its end immersed in the molten zinc bath, and a sink roll 4 and support rolls 5 and 6 immersed in the molten zinc bath. In this embodiment, the apparatus is equipped with a straightening plate 7 having a straightening mechanism for controlling the flow of molten zinc within the molten zinc container 1. The hot-dip galvanized steel sheet manufacturing apparatus 10 may also be equipped with a coil payoff device, payoff reel, annealing furnace, gas wiping device, alloying furnace, coil winding device, and other accessories not shown.

 被めっき鋼板3はスナウト2内から溶融亜鉛容器1内に貯留された溶融亜鉛浴に連続的に供給される。シンクロール4には、被めっき鋼板3が巻き掛けられて、進入方向から引上げ方向に進路が変えられる。図1の例では引き上げられる被めっき鋼板3のシンクロール4に対して内巻き側になる裏面側サポートロール5と外側になる表面側サポートロール6が被めっき鋼板3に接するように配置されている。被めっき鋼板の裏面側をB側と称し、表面側をF側とも称する。サポートロール5、6はシンクロール4より上方に配置され、被めっき鋼板3の片側であってもよい。 The steel sheet 3 to be plated is continuously supplied from inside the snout 2 to the molten zinc bath stored in the molten zinc vessel 1. The steel sheet 3 to be plated is wrapped around the sink roll 4, changing its course from the approach direction to the pull-up direction. In the example of Figure 1, the back side support roll 5, which is on the inward winding side of the sink roll 4 of the steel sheet 3 to be plated being pulled up, and the front side support roll 6, which is on the outside, are arranged to contact the steel sheet 3 to be plated. The back side of the steel sheet to be plated is referred to as side B, and the front side is also referred to as side F. The support rolls 5 and 6 are arranged above the sink roll 4, and may be on one side of the steel sheet 3 to be plated.

 本実施形態では、シンクロール4の上方に設置した整流板7が以下の態様であることを特徴とする。
1)整流板7の下端位置からシンクロール4の表面までの最短距離aが0mm超え50mm以下の範囲にあること。
2)上面視で整流板7の下端位置がシンクロールのスナウト側水平方向端部からシンクロール4の中心軸CLまでの範囲にあること。つまり、水平方向の整流板7の下端位置とシンクロール4のスナウト側水平方向端部との距離bが中心軸CLに向かう方向を正として、0以上、シンクロール4の半径以下にあること。
In this embodiment, the current plate 7 installed above the sink roll 4 is characterized in the following manner.
1) The shortest distance a from the lower end position of the straightening plate 7 to the surface of the sink roll 4 is in the range of more than 0 mm and not more than 50 mm.
2) When viewed from above, the lower end position of the straightening plate 7 is in the range from the horizontal end of the snout side of the sink roll to the central axis CL of the sink roll 4. In other words, the distance b between the horizontal lower end position of the straightening plate 7 and the horizontal end of the snout side of the sink roll 4 is greater than or equal to 0 and less than the radius of the sink roll 4, with the direction toward the central axis CL being positive.

 発明者は、特許文献1に記載するような従来の整流板ではアッシュ欠陥を抑止できないことから、実機の観察および流動シミュレーションを行った。その結果、整流板7の下端位置がアッシュ欠陥の抑制に関係があることを突き止めた。そのメカニズムは以下のように考えている。図2は本実施形態にかかる整流板7の配置での溶融亜鉛浴の流れを概念的に示す模式図である。図3はアッシュ欠陥が発生した従来の整流板配置での溶融亜鉛浴の流れを概念的に示す模式図である。 The inventors observed the actual equipment and conducted flow simulations because conventional straightening vanes such as those described in Patent Document 1 were unable to suppress ash defects. As a result, they discovered that the lower end position of the straightening vane 7 is related to the suppression of ash defects. The mechanism behind this is thought to be as follows: Figure 2 is a schematic diagram conceptually showing the flow of the molten zinc bath with the straightening vane 7 positioned according to this embodiment. Figure 3 is a schematic diagram conceptually showing the flow of the molten zinc bath with the conventional straightening vane position, where ash defects occur.

 スナウト2内で発生する酸化亜鉛が溶融亜鉛浴に進入する被めっき鋼板3の随伴流に載って溶融亜鉛浴に侵入する。その酸化亜鉛は溶融亜鉛より比重が小さく、溶融亜鉛浴内に浮遊して、流れに載って移動する。そして、酸化亜鉛は、被めっき鋼板に付着して、ロールに押し付けられて、アッシュ欠陥になると考えられる。図2や3に示すように、スナウト2から供給された被めっき鋼板3に随伴する流れと、シンクロール4の回転に伴い上面側で随伴する流れが衝突し、上方に噴き上げる衝突流となる。この衝突流には、酸化亜鉛が含まれている。 Zinc oxide generated within the snout 2 enters the molten zinc bath on the accompanying flow of the steel sheet 3 to be plated as it enters the bath. This zinc oxide has a lower specific gravity than molten zinc, so it floats in the molten zinc bath and moves with the flow. It is thought that the zinc oxide then adheres to the steel sheet to be plated and is pressed against the roll, becoming an ash defect. As shown in Figures 2 and 3, the flow accompanying the steel sheet 3 to be plated supplied from the snout 2 collides with the flow accompanying it on the upper surface as the sink roll 4 rotates, forming a collision flow that sprays upward. This collision flow contains zinc oxide.

 図3に示すように、従来の整流板7Aは、下端位置がこの衝突流にあたり、溶融亜鉛浴の流れをサポートロール側に分配するようになっていた。本実施形態では、整流板7を上記範囲に設置することで、図2に示すように、衝突流がサポートロール側に分配されることなくスナウト2と整流板7の延長線上の間の浴面8に酸化亜鉛を浮上させることができる。もって、アッシュ欠陥を低減できる。 As shown in Figure 3, the lower end of the conventional straightening plate 7A is in contact with the impinging flow, distributing the flow of the molten zinc bath toward the support roll. In this embodiment, by installing the straightening plate 7 in the above range, as shown in Figure 2, the impinging flow is not distributed toward the support roll, and zinc oxide can be floated to the bath surface 8 between the snout 2 and the straightening plate 7 on an extension line. This reduces ash defects.

 本実施形態が満足する整流板7の下端位置の条件は、亜鉛めっき鋼板の製造にかかる操業のすべての期間で満足する必要がある。たとえば、シンクロール4は、操業中に減肉し、半径が15mm程度減少する。また、整流板7は、シンクロール4に接触しないように近づけて設置するため、溶融亜鉛の随伴流によって、常に荷重がかけられた状態であり、スナウト側に40mm程度変形することがある。整流板7の移動装置を設置することには制限が多い。つまり、溶融亜鉛めっき鋼板の製造装置10の溶融亜鉛容器1の周辺には付帯設備が多く、整流板7の移動装置の設置が物理的に困難であったり、投資額が過大となったりする問題がある。そこで、シンクロール4の減肉や整流板7の変形を考慮して、初期に設置する整流板7の下端位置を水平方向でシンクロール4の中心軸CL側に所定量だけ移動することが好ましい。このように整流板7を設計することで、メンテナンスフリーで表面欠陥の少ない亜鉛めっき鋼板を製造することができる。 The conditions for the lower end position of the straightening plate 7 satisfied by this embodiment must be met throughout the entire period of operation related to the production of galvanized steel sheets. For example, the sink roll 4 thins during operation, reducing its radius by approximately 15 mm. Furthermore, because the straightening plate 7 is installed close to the sink roll 4 so as not to come into contact with it, it is constantly under load due to the accompanying flow of molten zinc, which can cause it to deform approximately 40 mm toward the snout. There are many limitations to installing a moving device for the straightening plate 7. In other words, there is a lot of ancillary equipment around the molten zinc vessel 1 of the hot-dip galvanized steel sheet manufacturing apparatus 10, making installation of a moving device for the straightening plate 7 physically difficult and requiring excessive investment. Therefore, taking into account the thinning of the sink roll 4 and deformation of the straightening plate 7, it is preferable to move the lower end position of the straightening plate 7, which is initially installed, horizontally by a predetermined amount toward the center axis CL of the sink roll 4. Designing the straightening plate 7 in this manner enables the production of maintenance-free galvanized steel sheets with few surface defects.

 なお、整流板7の材質はSUS316Lが好ましい。整流板7の板厚は、変形抑止の観点から9mm以上とすることが好ましい。一方、過大な重量の整流板7は設置時の取付などが困難となるおそれがあるので板厚15mm以下であることが好ましい。整流板7には、被めっき鋼板3の板幅方向に延伸する補強リブを有することが変形防止の観点で好ましい。 The material for the straightening plate 7 is preferably SUS316L. The thickness of the straightening plate 7 is preferably 9 mm or more from the viewpoint of preventing deformation. On the other hand, an excessively heavy straightening plate 7 may make installation difficult, so a thickness of 15 mm or less is preferable. From the viewpoint of preventing deformation, it is preferable for the straightening plate 7 to have reinforcing ribs extending in the width direction of the plated steel sheet 3.

 また、被めっき鋼板3の板厚は特に制限されないが、一例として、0.4~3.5mmである。被めっき鋼板3の板厚が薄いほど、被めっき鋼板3の通板速度は速くなり、衝突流の速度も速くなるため、アッシュ欠陥が発生しやすい。そのため、被めっき鋼板3の板厚が0.4~1.2mmの場合、より本発明の効果を発揮しやすい。 Furthermore, the thickness of the steel sheet 3 to be plated is not particularly limited, but is, for example, 0.4 to 3.5 mm. The thinner the thickness of the steel sheet 3 to be plated, the faster the passing speed of the steel sheet 3 to be plated and the faster the speed of the impinging flow, making it more likely that ash defects will occur. Therefore, the effects of the present invention are more easily achieved when the thickness of the steel sheet 3 to be plated is 0.4 to 1.2 mm.

(実施例1)
 図1に従う構成の溶融亜鉛めっき鋼板の製造装置を用い、整流板の下端位置を変えて、鋼板表面へのアッシュ欠陥発生率を調査した。結果を表1にまとめた。アッシュ欠陥発生率は、流動解析ソフトを用いて、酸化亜鉛模擬粒子の軌道を計算し、全粒子に対する被めっき鋼板へ到達する粒子の割合とした。表1の結果から、発明例は比較例に比べ格段にアッシュ欠陥発生率を低減できることがわかる。
Example 1
Using a manufacturing apparatus for hot-dip galvanized steel sheets configured according to Figure 1, the rate of ash defect occurrence on the steel sheet surface was investigated by changing the lower end position of the straightening plate. The results are summarized in Table 1. The rate of ash defect occurrence was calculated using flow analysis software to calculate the trajectory of the zinc oxide simulant particles, and the rate was calculated as the percentage of particles that reached the steel sheet to be plated relative to the total number of particles. The results in Table 1 show that the invention examples were able to significantly reduce the rate of ash defect occurrence compared to the comparative examples.

(実施例2)
 次に、表1の条件No.3の整流板配置で、板厚ごとの板変形、つまり、反り量を調査した。表2に被めっき鋼板の20,000t通過後の反り量をまとめた。板厚を9.0mmとすることで整流坂の変形が大幅に低減できている。
Example 2
Next, the deformation of the plate, i.e., the amount of warpage, was investigated for each plate thickness under the arrangement of the straightening plates under condition No. 3 in Table 1. The amount of warpage of the plated steel plate after passing through 20,000 tons is summarized in Table 2. By setting the plate thickness to 9.0 mm, the deformation of the straightening plates was significantly reduced.

 本明細書中で、質量の単位「t」は1000kgとする。 In this specification, the unit of mass "t" is 1000 kg.

10 (溶融亜鉛めっき鋼板の)製造装置
1 溶融亜鉛容器
2 スナウト
3 (被めっき)鋼板(被めっき材)
4 シンクロール
5 (裏面側)サポートロール
6 (表面側)サポートロール
7 整流板
7A (従来の)整流板
8 浴面
CL (シンクロールの)中心軸
Z 溶融亜鉛

 
10 (hot-dip galvanized steel sheet) manufacturing apparatus 1 molten zinc container 2 snout 3 (to be plated) steel sheet (material to be plated)
4 Sink roll 5 (back side) support roll 6 (front side) support roll 7 Straightening plate 7A (conventional) Straightening plate 8 Bath surface CL (of sink roll) Central axis Z Molten zinc

Claims (5)

溶融亜鉛浴中に被めっき鋼板を浸漬し、その表面に溶融亜鉛を付着させてめっき層を形成する溶融亜鉛めっき鋼板の製造装置であって、
溶融亜鉛を貯留する溶融亜鉛容器と、
端部が前記溶融亜鉛容器内の溶融亜鉛浴に浸漬するように設けられ、溶融亜鉛浴中に被めっき鋼板を供給するスナウトと、
前記溶融亜鉛容器内の溶融亜鉛浴に浸漬するように設けられ、被めっき鋼板が巻き掛けられるシンクロールと、
該シンクロールの上方に前記溶融亜鉛浴に浸漬するように設けられ、被めっき鋼板の引上げ側の片面または両面に接して配置されるサポートロールと、
前記シンクロールの上方に設けられ、前記溶融亜鉛容器内の溶融亜鉛流を制御する整流機構を有する整流板と、
を具備し、
前記整流板は、下端位置からシンクロール表面までの最短距離が0mm超え50mm以下の範囲にあり、上面視で下端位置がシンクロールのスナウト側水平方向端部からシンクロールの中心軸までの範囲にあるように設置された、溶融亜鉛めっき鋼板の製造装置。
A manufacturing apparatus for hot-dip galvanized steel sheets, which immerses a steel sheet to be plated in a molten zinc bath and deposits molten zinc on the surface of the steel sheet to form a coating layer,
a molten zinc container for storing molten zinc;
a snout having an end immersed in the molten zinc bath in the molten zinc container, for supplying a steel sheet to be plated into the molten zinc bath;
a sink roll that is provided so as to be immersed in the molten zinc bath in the molten zinc container and around which the steel sheet to be plated is wound;
a support roll provided above the sink roll so as to be immersed in the molten zinc bath and placed in contact with one or both surfaces of the steel sheet to be plated on the lifting side;
A flow straightening plate provided above the sink roll and having a flow straightening mechanism for controlling the flow of molten zinc in the molten zinc container;
Equipped with
The straightening plate is installed in a manufacturing apparatus for hot-dip galvanized steel sheets so that the shortest distance from its lower end position to the surface of the sink roll is in the range of more than 0 mm and not more than 50 mm, and its lower end position, when viewed from above, is in the range from the horizontal end of the snout side of the sink roll to the central axis of the sink roll.
前記整流板の幅が、被めっき鋼板の板幅以上である、請求項1に記載の溶融亜鉛めっき鋼板の製造装置。 The hot-dip galvanized steel sheet manufacturing apparatus of claim 1, wherein the width of the straightening plate is equal to or greater than the width of the steel sheet to be plated. 前記整流板は、板厚が9mm以上であり、リブを有する、請求項1に記載の溶融亜鉛めっき鋼板の製造装置。 The hot-dip galvanized steel sheet manufacturing apparatus of claim 1, wherein the straightening plate has a thickness of 9 mm or more and has ribs. 前記整流板は、板厚が9mm以上であり、リブを有する、請求項2に記載の溶融亜鉛めっき鋼板の製造装置。 The hot-dip galvanized steel sheet manufacturing apparatus of claim 2, wherein the straightening plate has a thickness of 9 mm or more and has ribs. 請求項1~4のいずれか1項に記載の溶融亜鉛めっき鋼板の製造装置を用いて、溶融亜鉛めっき浴中に被めっき鋼板を浸漬し、該被めっき鋼板の表面に溶融亜鉛を付着させてめっき層を形成する工程を含む、溶融亜鉛めっき鋼板の製造方法。 A method for producing hot-dip galvanized steel sheet, comprising the steps of immersing a steel sheet to be plated in a hot-dip galvanizing bath using the hot-dip galvanized steel sheet manufacturing apparatus described in any one of claims 1 to 4, and depositing molten zinc on the surface of the steel sheet to form a coating layer.
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JP2021127483A (en) * 2020-02-13 2021-09-02 日本製鉄株式会社 Method of manufacturing hot-dip galvanized steel sheet and hot-dip metal-plated steel sheet

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