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WO2025154509A1 - Steel sheet, component including same, and method for manufacturing steel sheet - Google Patents

Steel sheet, component including same, and method for manufacturing steel sheet

Info

Publication number
WO2025154509A1
WO2025154509A1 PCT/JP2024/045817 JP2024045817W WO2025154509A1 WO 2025154509 A1 WO2025154509 A1 WO 2025154509A1 JP 2024045817 W JP2024045817 W JP 2024045817W WO 2025154509 A1 WO2025154509 A1 WO 2025154509A1
Authority
WO
WIPO (PCT)
Prior art keywords
less
ferrite
rolling
cooling
steel plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/JP2024/045817
Other languages
French (fr)
Japanese (ja)
Inventor
真一 村田
隆 安富
栄作 桜田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP2025544965A priority Critical patent/JPWO2025154509A1/ja
Publication of WO2025154509A1 publication Critical patent/WO2025154509A1/en
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese

Definitions

  • the present invention relates to a steel plate, a part including the steel plate, and a method for manufacturing the steel plate.
  • Patent Document 1 describes a high-strength cold-rolled steel sheet coil made of a dual-phase steel sheet mainly composed of ferrite and martensite, which has a structural morphology in which the volume fraction of the total structure is 10-40% ferrite and 60-90% martensite, and in which the ferrite fractions (shown in "area %) at the four corners and center of gravity of an 800 mm x 800 mm steel sheet cut out from any position on the coil are V ⁇ 1, V ⁇ 2, V ⁇ 3, V ⁇ 4, V ⁇ 5, respectively, and when the average value of these five points is V ⁇ m, all of the ferrite fractions V ⁇ 1, V ⁇ 2, V ⁇ 3, V ⁇ 4, V ⁇ 5 are within the range of V ⁇ m ⁇ 5 (area %).
  • Patent Document 1 also teaches that by strictly specifying the conditions for heat treatment of the base steel sheet (cold-rolled steel sheet), a high-strength cold-rolled steel sheet coil with small variation in the ferrite fraction within the coil can be obtained, which in turn makes it possible to realize a high-strength cold-rolled steel sheet coil with small strength variation within the coil and a tensile strength of 980 MPa or more, and that such a high-strength cold-rolled steel sheet coil can be stably formed into automotive steel sheets, and specifically discloses in the examples that in addition to improving tensile strength, total elongation and hole expandability are also improved.
  • the chemical composition is, in mass%, B: 0.0001 to 0.0030%, Cr: 0.001-0.70%, Mo: 0.001-0.12%, Cu: 0.001-0.40%, Ni: 0.001 to 0.30%, V: 0.001-0.300%, Sn: 0.001 to 0.040%, As: 0.001 to 0.100%, Zr: 0.001 to 0.050%, Ca: 0.0001 to 0.0010%, Mg: 0.0001 to 0.0010%, Bi: 0.001 to 0.010%, Co: 0.001 to 0.010%, W: 0.001-0.100%, Zn: 0.001 to 0.010%, and REM: 0.0001 to 0.0100%
  • the steel sheet according to (1) above characterized in that it contains at least one of the following: (3)
  • a hot rolling process including finish rolling the slab using a tandem rolling mill having four or more rolling stands, the hot rolling process satisfying the following conditions (a) to (c): (a) the rolling temperature in each of the rolling passes in the two stages immediately preceding the latter two stages is 960 to 1080°C, and the rolling reduction in each of the rolling passes is 30 to 50%; (b) cooling the rolled material to a cooling stop temperature of 800 to 910°C within 0.20 seconds after the rolling passes of the two rolling passes immediately preceding the latter two rolling passes; and (c) a rolling reduction rate in each rolling pass of the latter two rolling passes is 10 to 40%.
  • the present invention provides a steel plate that has high strength, high uniform elongation, hole expandability, and yield ratio, and is capable of suppressing load reduction during a collision, as well as a part that includes the steel plate and a method for manufacturing the steel plate.
  • FIGS. 1A and 1B are schematic diagrams for explaining characteristics related to the number density of ferrite, in which (a) shows an example that does not satisfy the characteristics related to the number density of ferrite according to the present invention, and (b) shows an example that satisfies the characteristics.
  • the steel sheet according to the embodiment of the present invention has a chemical composition in mass%: C: 0.060-0.300%, Si: 0.30-1.50%, Mn: 1.00-2.70%, P: 0.100% or less, S: 0.0300% or less, sol.
  • the properties such as hole expandability decrease with increasing strength of steel.
  • a steel plate with excellent hole expandability while maintaining high strength for example, a tensile strength of 1180 MPa or more that enables weight reduction.
  • the metal structure of the steel plate is composed mainly of martensite.
  • martensitic steel has excellent strength, excessive inclusion of martensitic steel reduces properties such as uniform elongation, so that there is a problem that it is generally poor in workability.
  • the inventors have found that the yield ratio can be increased and the hole expandability can be significantly improved by utilizing precipitation strengthening through the addition of Ti.
  • the improvement in hole expandability due to such precipitation strengthening is due to the reduction in the hardness difference between ferrite and martensite in the metal structure.
  • the metal structure is composed mainly of ferrite and martensite, and the soft structure ferrite can be contained up to 40% by area. In this case, the hardness difference between ferrite and martensite in the metal structure increases, and the hole expandability decreases.
  • the soft structure of ferrite is precipitation strengthened by Ti precipitates, thereby reducing the hardness difference between ferrite and martensite in the metal structure, and therefore it is believed that the hole expandability can be significantly improved.
  • the inventors conducted a study on the assumption that in order to maintain a high and stable load even during a collision and suppress the occurrence of fracture, it is necessary to suppress the work softening after uniform elongation, which corresponds to the elongation at the maximum load point in a uniaxial tensile test. This is because by suppressing the work softening after uniform elongation, it is possible to effectively absorb the collision energy from the maximum load to fracture during a collision by the plastic deformation of the steel sheet.
  • the inventors have found that the absolute value of the work softening rate after uniform elongation in a uniaxial tensile test can be reliably reduced to 250,000 MPa or less by uniformly distributing ferrite in the thickness direction of the steel plate, more specifically, by uniformly dividing a 150 ⁇ m ⁇ 150 ⁇ m region at 1/4 of the thickness position of a cross section perpendicular to the plate surface of the steel plate into nine parts, calculating the number density of ferrite in each divided region, and arranging ferrite uniformly in the metal structure so that the absolute value of the difference in the number density of ferrite in each divided region adjacent to each other in the thickness direction is N ⁇ m ⁇ 0.60 or less when the average value of the ferrite density in each divided region adjacent to each other in the thickness direction is N ⁇ m ⁇ 0.60 or less.
  • the inventors have found that even when the steel plate is formed into a part, particularly a part having a complex shape such as a lower arm or a trailing arm, the load reduction during a collision can be suppressed and the occurrence of fracture can be significantly suppressed.
  • Fig. 1 is a schematic diagram for explaining the characteristics of the number density of ferrite
  • Fig. 1(a) shows an example that does not satisfy the characteristics of the number density of ferrite according to the present invention, that is, "When a 150 ⁇ m ⁇ 150 ⁇ m region at the 1/4 position of the plate thickness of a cross section perpendicular to the plate surface is evenly divided into nine, the number density of ferrite is calculated in each divided region, and the average value is N ⁇ m, the difference in the number density of ferrite in each divided region adjacent in the plate thickness direction is all N ⁇ m ⁇ 0.60 or less", and Fig. 1(b) shows an example that satisfies the characteristics. Referring to Fig.
  • the differences in the number density of ferrite in each divided region adjacent in the plate thickness direction are calculated (i.e., the difference between N ⁇ 1 and N ⁇ 4 (0.045 pieces/ ⁇ m2 ), the difference between N ⁇ 4 and N ⁇ 7 (0.033 pieces/ ⁇ m2 ), the difference between N ⁇ 2 and N ⁇ 5 (0.017 pieces/ ⁇ m2 ), the difference between N ⁇ 5 and N ⁇ 8 (0.012 pieces/ ⁇ m2 ), the difference between N ⁇ 3 and N ⁇ 6 (0.008 pieces/ ⁇ m2 ), and the difference between N ⁇ 6 and N ⁇ 9 (0.014 pieces/ ⁇ m2 ) ( Figure 1 (a) (ii)).
  • the absolute value of the work softening rate after uniform elongation in the uniaxial tensile test can be reliably reduced to 250,000 MPa or less, and therefore, even when the steel sheet is formed into a part having a complex shape such as a lower arm or a trailing arm, it becomes possible to significantly suppress the occurrence of fracture during a collision.
  • the work softening rate after uniform elongation can be reduced by uniformly arranging ferrite in the plate thickness direction of a steel plate composed mainly of a structure of ferrite and martensite, and further the fact that the occurrence of fracture during a collision can be significantly suppressed thereby, was not known in the past, and was revealed for the first time by the present inventors. Therefore, according to the embodiment of the present invention, for example, despite the high strength of the tensile strength of 1180 MPa or more, it is possible to have high uniform elongation, hole expandability and yield ratio, and to significantly suppress the occurrence of fracture accompanied by load reduction during a collision, and therefore the steel plate according to the embodiment of the present invention is particularly useful for use in the automotive field.
  • C is an element effective in increasing the strength of the steel plate.
  • C forms carbides and/or carbonitrides with Nb in the steel, and also contributes to refining the structure due to the pinning effect of the precipitates formed.
  • the C content is set to 0.060% or more.
  • the C content may be 0.070% or more, 0.080% or more, 0.100% or more, 0.120% or more, or 0.150% or more.
  • the C content is set to 0.300% or less.
  • the C content may be 0.280% or less, 0.250% or less, 0.200% or less, 0.180% or less, or 0.160% or less.
  • Si is an element that suppresses the formation of iron carbides and contributes to improving strength and formability.
  • the Si content is set to 0.30% or more.
  • the Si content may be 0.40% or more, 0.50% or more, 0.60% or more, 0.70% or more, or 0.80% or more.
  • the Si content is set to 1.50% or less.
  • the Si content may be 1.40% or less, 1.20% or less, 1.10% or less, 1.00% or less, or 0.90% or less.
  • the P content is set to 0.100% or less.
  • the P content may be 0.050% or less, 0.030% or less, 0.020% or less, or 0.015% or less.
  • the lower limit of the P content is not particularly limited and may be 0%, but excessive reduction will lead to an increase in costs. Therefore, the P content may be 0.0001% or more, 0.001% or more, or 0.005% or more.
  • Sol. Al is an element that acts as a deoxidizer for molten steel. In order to obtain such an effect, the sol. Al content is set to 0.001% or more. The sol. Al content may be 0.010% or more, 0.020% or more, 0.030% or more, 0.050% or more, or 0.100% or more. On the other hand, if sol. Al is contained excessively, the ferrite fraction becomes high, which may cause a large difference in hardness between ferrite and martensite, resulting in a decrease in hole expandability. Therefore, the sol. Al content is set to 0.500% or less. The sol. Al content may be 0.400% or less, 0.300% or less, or 0.200% or less. Sol. Al means acid-soluble Al, and refers to solid-solution Al present in the steel in a solid solution state.
  • N 0.0070% or less
  • the N content may be 0.0050% or less, 0.0040% or less, or 0.0030% or less.
  • the lower limit of the N content is not particularly limited and may be 0%, but excessive reduction will lead to an increase in costs. Therefore, the N content may be 0.0001% or more, or 0.0005% or more.
  • Ti is an element that precipitates in steel as Ti carbides such as TiC, strengthens soft structures such as ferrite by precipitation strengthening, and contributes to improving strength and yield ratio. Furthermore, Ti can reduce the hardness difference between ferrite and martensite in the metal structure due to precipitation strengthening, so it is also effective in improving hole expandability. In order to fully obtain these effects, the Ti content is 0.070% or more. The Ti content may be 0.080% or more, 0.090% or more, 0.100% or more, or 0.120% or more. On the other hand, if Ti is contained excessively, coarse carbides and the like are generated in the steel, which may cause slab cracks during hot rolling or reduce the workability of the steel sheet. Therefore, the Ti content is 0.170% or less. The Ti content may be 0.160% or less, 0.150% or less, 0.140% or less, or 0.130% or less.
  • Nb is an element that forms carbides, nitrides and/or carbonitrides in steel and contributes to the refinement of prior austenite grains and thus to the high strength of steel sheet by the pinning effect.
  • the Nb content is set to 0.001% or more.
  • the Nb content may be 0.005% or more, 0.010% or more, 0.030% or more, 0.050% or more, 0.080% or more, or 0.100% or more.
  • the Nb content is set to 1.000% or less.
  • the Nb content may be 0.800% or less, 0.600% or less, 0.500% or less, 0.400% or less, 0.300% or less, or 0.200% or less.
  • the basic chemical composition of the steel plate according to the embodiment of the present invention is as described above. Furthermore, the steel plate may contain at least one of the following elements in place of a portion of the remaining Fe, as necessary.
  • Cr is an element that enhances the hardenability of steel and contributes to improving strength and/or corrosion resistance.
  • the Cr content may be 0%, but in order to obtain these effects, the Cr content is preferably 0.001% or more, and may be 0.01% or more, 0.05% or more, or 0.10% or more.
  • the Cr content is preferably 0.70% or less, and may be 0.60% or less, 0.50% or less, 0.40% or less, or 0.30% or less.
  • Mo is an element that enhances the hardenability of steel and contributes to improving strength.
  • the Mo content may be 0%, but in order to obtain such an effect, the Mo content is preferably 0.001% or more.
  • the Mo content may be 0.01% or more, 0.02% or more, or 0.03% or more.
  • the Mo content is preferably 0.12% or less.
  • the Mo content may be 0.10% or less, 0.08% or less, 0.06% or less, or 0.05% or less.
  • Cu is an element that contributes to improving strength by precipitation strengthening or solid solution strengthening.
  • the Cu content may be 0%, but in order to obtain such an effect, the Cu content is preferably 0.001% or more.
  • the Cu content may be 0.01% or more, 0.03% or more, or 0.05% or more.
  • the Cu content is preferably 0.40% or less.
  • the Cu content may be 0.30% or less, 0.20% or less, 0.10% or less, or 0.08% or less.
  • Ni is an element that contributes to improving strength by precipitation strengthening or solid solution strengthening.
  • the Ni content may be 0%, but in order to obtain such an effect, the Ni content is preferably 0.001% or more.
  • the Ni content may be 0.01% or more, 0.03% or more, or 0.05% or more.
  • the Ni content is preferably 0.30% or less.
  • the Ni content may be 0.20% or less, 0.15% or less, 0.10% or less, or 0.08% or less.
  • Sn 0 to 0.040%, As: 0 to 0.100%, Zr: 0 to 0.050%, Ca: 0 to 0.0010%, Mg: 0 to 0.0010%, Bi: 0-0.010%, Co: 0-0.010%, W: 0-0.100%, Zn: 0-0.010%, and REM: 0-0.0100%]
  • Sn, As, Zr, Ca, Mg, Bi, Co, W, Zn, and REM may be contained in the steel sheet as optional elements or may be present in the steel sheet as tramp elements.
  • the contents of these elements may be as follows: Sn: 0-0.040% or 0.020%, As: 0-0.100% or 0.050%, Zr: 0-0.050% or 0.030%, Ca: 0-0.0010% or 0.0008%, Mg: 0-0.0010% or 0.0008%, Bi: 0-0.010%, Co: 0-0.010%, W: 0-0.100% or 0.050%, Zn: 0-0.010%, and REM: 0-0.0100% or 0.0050%.
  • the Sn, As, Zr, Bi, Co, W and Zn contents may be 0.001% or more, 0.005% or more, or 0.008% or more, respectively.
  • the Ca, Mg and REM contents may be 0.0001% or more, 0.0002% or more, or 0.0005% or more.
  • the remainder other than the above elements consists of Fe and impurities.
  • Impurities are components that are mixed in due to various factors in the manufacturing process, including raw materials such as ores and scraps, when the steel plate is industrially manufactured.
  • the chemical composition of the steel plate according to the embodiment of the present invention may be measured by a general analytical method.
  • the chemical composition of the steel plate may be measured using inductively coupled plasma atomic emission spectrometry (ICP-AES).
  • C and S may be measured using the combustion-infrared absorption method
  • N may be measured using the inert gas fusion-thermal conductivity method
  • O may be measured using the inert gas fusion-non-dispersive infrared absorption method.
  • the metal structure of the steel plate according to the embodiment of the present invention contains ferrite: 10 to 40% in area%.
  • the desired uniform elongation can be achieved by containing 10% or more of ferrite, which is a soft structure, in area%. From the viewpoint of further improving the uniform elongation, the higher the area ratio of ferrite, the more preferable, for example, 12% or more, 15% or more, 18% or more, 20% or more, 22% or more, or 25% or more.
  • the area ratio of ferrite is set to 40% or less. From the viewpoint of further increasing the strength, yield ratio, and/or hole expandability, the lower the area ratio of ferrite, the more preferable, for example, 38% or less, 35% or less, 32% or less, 30% or less, 28% or less, or 26% or less.
  • the metal structure of the steel plate according to the embodiment of the present invention contains, in terms of area%, 60 to 90% martensite.
  • high strength for example, high strength with a tensile strength of 1180 MPa or more
  • the higher the area ratio of martensite the more preferable it is, and for example, it may be 65% or more, 68% or more, 70% or more, 72% or more, or 75% or more.
  • the area ratio of martensite becomes too high, uniform elongation may decrease.
  • the metal structure of the steel plate according to the embodiment of the present invention may contain bainite.
  • the area ratio of bainite is set to 10% or less, and may be, for example, 9% or less, 8% or less, 6% or less, 5% or less, or 3% or less.
  • the lower limit is not particularly limited, and the area ratio of bainite may be 0%, and may be, for example, 0.5% or more, 1% or more, or 2% or more.
  • the remaining structure other than ferrite, martensite, and bainite may be 0% in terms of area percent, but if a remaining structure exists, the remaining structure may be at least one of pearlite and retained austenite. If the area ratio of at least one of pearlite and retained austenite exceeds 5% in total, it may lead to a decrease in uniform elongation, or it may become impossible to control ferrite and/or martensite within a desired range. Therefore, the total area ratio of at least one of pearlite and retained austenite is 5% or less, and may be, for example, 4% or less, 3% or less, or 2% or less. On the other hand, the lower limit is not particularly limited, and the total area ratio of at least one of pearlite and retained austenite may be 0%, for example, 0.1% or more, 0.5% or more, or 1% or more.
  • the plate thickness cross section is preferably parallel to the rolling direction, in cases where the rolling direction of the steel plate cannot be specified, the plate thickness cross section does not necessarily need to be parallel to the rolling direction.
  • a test piece is taken from the steel plate, and the cross section of the test piece is polished using silicon carbide paper of #600 to #1500, and then finished to a mirror surface using a dilution solution such as alcohol or a liquid in which diamond powder with a grain size of 1 to 6 ⁇ m is dispersed in pure water.
  • this cross section is polished for 8 minutes at room temperature using colloidal silica with a grain size of 0.25 ⁇ m that does not contain an alkaline solution, to remove the strain introduced into the surface layer of the test piece.
  • a rectangular area of 150 ⁇ m in the plate thickness direction and 150 ⁇ m in the direction perpendicular to the plate thickness direction, centered at 1/4 of the plate thickness position from the steel surface, is measured by electron backscatter diffraction at measurement intervals of 0.1 ⁇ m to obtain crystal orientation information.
  • an EBSD device consisting of a thermal field emission scanning electron microscope (JSM-7001F manufactured by JEOL) and an EBSD detector (DVC5 type detector manufactured by TSL).
  • JSM-7001F thermal field emission scanning electron microscope
  • DVC5 type detector DVC5 type detector manufactured by TSL
  • the degree of vacuum in the EBSD device is 9.6 ⁇ 10 ⁇ 5 Pa or less
  • the acceleration voltage is 15 kV
  • the irradiation current level is 13
  • the electron beam irradiation level is 62
  • other observation conditions are preferably as follows.
  • Objective aperture number 4 Number of pixels: 4096 x 5120 pixels
  • the regions with a bcc crystal structure are judged to be "ferrite, martensite, bainite, and pearlite".
  • the grain average misorientation (GAM value: Grain Average Misorientation) is calculated using the software "OIM Analysis (registered trademark)" attached to the EBSD analyzer.
  • the regions with a GAM value of 0.5° or less are identified as ferrite, and their area ratio is calculated.
  • the "GAM value” is the average misorientation between adjacent pixels in a region surrounded by grain boundaries with a misorientation of 15° or more.
  • the pearlite area ratio is calculated by performing image analysis on a structure photograph obtained by using the FE-SEM in the same region as the EBSD measurement region, that is, a rectangular region 150 ⁇ m in the plate thickness direction and 150 ⁇ m in the direction perpendicular to the plate thickness direction, centered at a 1/4 position of the plate thickness from the steel plate surface.
  • a structure in which plate-shaped ferrite and Fe-based carbides are layered is regarded as pearlite.
  • the area ratio of martensite is calculated by subtracting the area ratios of the retained austenite, ferrite, bainite, and pearlite from 100%. Metal structures other than martensite are sequentially identified, and the last remaining metal structure is regarded as martensite.
  • the absolute value of the work softening rate after uniform elongation in the uniaxial tensile test can be reliably reduced to 250,000 MPa or less, thereby making it possible to suppress the load reduction during a collision.
  • an automobile suspension part such as a lower arm or a trailing arm having a complex shape, it is possible to significantly suppress the occurrence of fracture during a collision.
  • the difference in number density of ferrite in each divided region adjacent in the plate thickness direction is as small as possible.
  • the difference in number density of ferrite in each divided region adjacent in the plate thickness direction may all be N ⁇ m ⁇ 0.55 or less, N ⁇ m ⁇ 0.50 or less, N ⁇ m ⁇ 0.50 or less, N ⁇ m ⁇ 0.45 or less, N ⁇ m ⁇ 0.40 or less, N ⁇ m ⁇ 0.35 or less, or N ⁇ m ⁇ 0.30 or less.
  • N ⁇ m is 0.050 pieces/ ⁇ m 2 or more.
  • N ⁇ m is 0.050 pieces/ ⁇ m 2 or more.
  • the ferrite grains are made finer, the number density of ferrite naturally increases. Therefore, by increasing the number density of ferrite, the difference in the number density of ferrite in each divided region adjacent to each other in the plate thickness direction is reduced, and the load reduction at the time of collision is suppressed.
  • the region with a GAM value of 0.5° or less is identified as ferrite, and the number of ferrite particles in each of the divided regions into which the 150 ⁇ m ⁇ 150 ⁇ m region is equally divided into 9 is counted to calculate the number density N ⁇ 1 to N ⁇ 9, and the average value thereof is determined as N ⁇ m (FIGS. 1(a)(i) and (b)(i)).
  • the number density of ferrite is calculated by counting all the number of ferrite particles detected and identified under the above measurement conditions. When counting, if ferrite exists on the boundary between multiple divided regions or in multiple divided regions across the boundary, the ferrite is counted in each of the multiple divided regions.
  • the difference in number density of ferrite in each divided region adjacent in the plate thickness direction is calculated (FIGS. 1(a)(ii) and (b)(ii)), and it is determined whether the value obtained by dividing the difference in number density by N ⁇ m satisfies the requirement of 0.60 or less (FIGS. 1(a)(iii) and (b)(iii)).
  • the steel sheet according to the embodiment of the present invention generally has a sheet thickness of 1.0 to 8.0 mm, although it is not particularly limited thereto.
  • the sheet thickness may be 1.2 mm or more, 1.6 mm or more, or 2.0 mm or more, and/or 7.0 mm or less, 6.0 mm or less, 5.5 mm or less, 5.0 mm or less, 4.4 mm or less, 4.2 mm or less, or 4.0 mm or less.
  • the steel plate according to the embodiment of the present invention has high uniform elongation, hole expandability and yield ratio despite its high strength, and can significantly suppress the occurrence of fracture accompanied by load reduction during collision, and in particular, it is possible to suppress the occurrence of fracture accompanied by load reduction during collision even when forming a part having a complex shape. Therefore, the steel plate according to the embodiment of the present invention can reliably achieve a high level of the contradictory properties of high strength and excellent workability, and can achieve excellent impact resistance. Therefore, the steel plate according to the embodiment of the present invention is useful for use in parts in technical fields where these properties are required, and is particularly useful in the automotive field.
  • an automotive part particularly an automotive suspension part
  • automotive suspension parts include lower arms and trailing arms.
  • These automotive parts, particularly automotive suspension parts only need to include the steel plate according to the embodiment of the present invention in at least a part of these parts, and therefore at least a part of these parts satisfy the above-mentioned chemical composition and metal structure characteristics. In areas of steel sheets that do not come into direct contact with the die during press forming or other forming processes and that are relatively lightly processed, the characteristics of the metal structure do not change significantly before and after forming.
  • the upper limit of the tensile strength is not particularly limited, but for example, the tensile strength of the steel plate may be 1780 MPa or less, 1470 MPa or less, 1400 MPa or less, or 1300 MPa or less.
  • a high uniform elongation can be achieved, specifically a uniform elongation of 5.0% or more can be achieved.
  • the uniform elongation is preferably 5.2% or more, 5.5% or more, 5.8% or more, or 6.0% or more.
  • the upper limit of the uniform elongation is not particularly limited, but for example, the uniform elongation of the steel sheet may be 15.0% or less, 10.0% or less, 8.0% or less, or 7.0% or less.
  • the tensile strength and uniform elongation are measured by taking a JIS No. 5 test piece from a direction in which the longitudinal direction of the test piece is preferably parallel to the rolling direction perpendicular to the rolling direction of the steel sheet (C direction) and performing a tensile test in accordance with JIS Z 2241:2022.
  • the JIS No. 5 test piece may be taken from any direction within the surface of the steel sheet.
  • the initial hole is expanded with a conical punch with an apex angle of 60° until a crack penetrating the plate thickness occurs, and the hole diameter d1 mm at the time of crack occurrence is measured, and the hole expansion ratio ⁇ (%) of each test piece is calculated by the following formula.
  • yield ratio (YR) According to the steel plate having the above chemical composition and metal structure, in addition to high tensile strength, the yield ratio can be increased, and more specifically, a yield ratio of 75% or more can be achieved.
  • the yield ratio is preferably 78% or more or 80% or more, more preferably 82% or more or 84% or more.
  • the upper limit is not particularly limited, but for example, the yield ratio may be 95% or less, 92% or less, 90% or less, or 88% or less.
  • the yield ratio is determined by the following formula based on the tensile strength and 0.2% proof stress measured by taking a JIS No.
  • the method for producing a steel sheet according to an embodiment of the present invention comprises: A heating step comprising heating a slab having the chemical composition described above in relation to the steel plate and holding it at a temperature of 1180-1350°C for at least 6000 seconds; A hot rolling process including finish rolling the slab using a tandem rolling mill having four or more rolling stands, the hot rolling process satisfying the following conditions (a) to (c): (a) the rolling temperature in each of the rolling passes in the two stages immediately preceding the latter two stages is 960 to 1080°C, and the rolling reduction in each of the rolling passes is 30 to 50%; (b) cooling the rolled material to a cooling stop temperature of 800 to 910 ° C.
  • the method is characterized by including a cooling step including water-cooling the finish-rolled steel plate, cooling it to a temperature range of 600 to 750 ° C. within 4.0 seconds from the start of water cooling, then air-cooling in the temperature range for 2.0 to 8.0 seconds, and water-cooling the steel plate to 50 ° C. or less within 13 seconds after air-cooling.
  • a cooling step including water-cooling the finish-rolled steel plate, cooling it to a temperature range of 600 to 750 ° C. within 4.0 seconds from the start of water cooling, then air-cooling in the temperature range for 2.0 to 8.0 seconds, and water-cooling the steel plate to 50 ° C. or less within 13 seconds after air-cooling.
  • the temperatures described for the slab and steel plate refer to the surface temperature of the slab and the surface temperature of the steel plate, respectively.
  • the coarse carbides present in the structure can be completely solid-dissolved, and the starting point of cracks can be eliminated. If the holding temperature is less than 1180 ° C or the holding time is less than 6000 seconds, the solid-dissolution of the coarse carbides is incomplete. If the solid solution of the coarse carbides is incomplete, the area ratio of martensite may become less than 60% due to the occurrence of ferrite or bainite transformation originating from such carbides in the cooling process described below, and as a result, the desired strength may not be obtained.
  • the upper limit of the heating temperature of the slab is set to 1350°C or less from the viewpoint of the capacity and productivity of the heating equipment.
  • the upper limit of the holding time in the temperature range of 1180 to 1350°C is preferably 10000 seconds or less.
  • the heated slab may be subjected to rough rolling before finish rolling in order to adjust the plate thickness, etc.
  • the conditions of the rough rolling are not particularly limited as long as the desired sheet bar dimensions can be secured.
  • the rolling temperature in each rolling pass of the two stages immediately preceding the last two stages is controlled to 960 to 1080°C, and similarly, the reduction ratio in each rolling pass of the two stages immediately preceding the last two stages is controlled to 30 to 50%.
  • the sixth and seventh rolling passes correspond to the "rolling passes of the last two stages”. Therefore, in this case, the "rolling passes of the two stages immediately preceding the last two stages" refers to the fourth and fifth rolling passes.
  • the rolling temperature in each of the rolling passes immediately before the last two stages exceeds 1080°C, the austenite grains after recrystallization become coarse, the number of austenite grain boundaries decreases, and the ferrite nucleation sites decrease. As a result, the number density of ferrite in the final metal structure cannot be sufficiently uniform in the thickness direction, and similarly, work softening after uniform elongation becomes significant.
  • the rolling temperature in each of the rolling passes in the two stages immediately preceding the last two stages is 1000 to 1060°C.
  • the rolled material is cooled to a cooling stop temperature of 800 to 910 ° C. within 0.20 seconds after the rolling pass of the two stages immediately before the latter two stages.
  • the time to cool to a cooling stop temperature of 800 to 910 ° C. after the rolling pass of the two stages immediately before the latter two stages exceeds 0.20 seconds or the cooling stop temperature is higher than 910 ° C., the grain growth of the austenite grains after recrystallization cannot be sufficiently suppressed, and even if appropriate cooling is performed in the subsequent cooling process, the number density of ferrite cannot be controlled within a desired range in the plate thickness direction.
  • the cooling stop temperature is lower than 800 ° C., excessive generation of ferrite may occur in the finally obtained metal structure. If excessive ferrite is formed, the strength may decrease, or the difference in hardness between ferrite and martensite may not be sufficiently reduced even by precipitation strengthening due to Ti precipitates, resulting in a decrease in hole expandability.
  • the reduction rate of each rolling pass of the latter two stages exceeds 40%, the driving force of ferrite transformation becomes too large, which may lead to excessive generation of ferrite in the finally obtained metal structure. If ferrite is excessively generated, the strength may decrease, or the hardness difference between ferrite and martensite may not be sufficiently reduced even by precipitation strengthening due to Ti precipitates, and the hole expansion property may decrease.
  • the reduction rate in each rolling pass of the latter two stages of finish rolling is 15 to 38%.
  • the transformation to ferrite can be promoted and Ti precipitates can be properly precipitated. Therefore, the air-cooling operation for 2.0 to 8.0 seconds in the temperature range of 600 to 750°C after water cooling is important not only for the proper generation of ferrite, but also from the viewpoint of the improvement effect of hole expandability due to precipitation strengthening caused by Ti precipitates. For example, if the air-cooling temperature is less than 600°C, the transformation to ferrite cannot be sufficiently promoted, while a relatively large amount of bainite may be generated. In such a case, the generation of a large amount of bainite reduces the uniform elongation, and further, the generation of martensite associated with the generation of bainite reduces the generation of sufficient strength, which may result in insufficient strength being obtained.
  • the air cooling temperature exceeds 750°C or the air cooling time is less than 2.0 seconds, the transformation to ferrite cannot be sufficiently promoted, and uniform elongation decreases.
  • the air cooling time exceeds 8.0 seconds, a relatively large amount of ferrite may be generated. In such cases, the strength decreases, and the precipitation strengthening caused by Ti precipitates cannot sufficiently reduce the hardness difference between ferrite and martensite, and the hole expansion ability may decrease.
  • the air cooling temperature is preferably 620 to 730°C, and the air cooling time is preferably 3.0 to 6.0 seconds.
  • the metal structure is composed of a structure containing, in terms of area percentage, 10-40% ferrite and 60-90% martensite, so that high strength, for example, high strength with a tensile strength of 1180 MPa or more, can be achieved while significantly improving uniform elongation. Furthermore, by controlling the Ti content in the steel to 0.070 mass% or more, the soft structure of ferrite is precipitation strengthened by Ti precipitates, thereby increasing the yield ratio and reducing the hardness difference between ferrite and martensite in the metal structure, and therefore it is possible to significantly improve the hole expandability.
  • the number density of ferrite in the thickness direction of the steel plate is made uniform within a predetermined range, so that the load reduction during collision can be suppressed. Therefore, the steel plate manufactured by the above manufacturing method has high uniform elongation, hole expandability, and yield ratio despite its high strength, and can significantly suppress the occurrence of fracture accompanied by a load reduction during collision. Therefore, steel sheets manufactured by the above manufacturing method reliably achieve a high level of both the opposing properties of high strength and excellent workability, while also achieving excellent impact resistance, making them particularly useful in the automotive field where these properties are required.
  • steel sheets according to the embodiments of the present invention were manufactured under various conditions, and the tensile strength (TS), yield ratio (YR), uniform elongation (uEl), hole expansion ratio ( ⁇ ), and work softening rate after uniform elongation of the obtained steel sheets were investigated.
  • molten steel was cast by continuous casting to form slabs with various chemical compositions shown in Tables 1 and 2. These slabs were heated to a temperature of 1180 to 1350°C and held for a time of 6000 to 10000 seconds, and then hot-rolled. Hot rolling was performed by rough rolling and finish rolling. More specifically, the rough rolling conditions were the same in all examples and comparative examples, and the finish rolling was performed under the conditions shown in Table 3 using a tandem rolling mill consisting of five rolling stands. Next, the finish-rolled steel plate was water-cooled, air-cooled, and water-cooled under the conditions shown in Table 3, and then coiled to obtain a steel plate having a thickness of 2.4 to 3.4 mm.
  • the burr was placed on the die side, and the initial hole was pushed out with a conical punch having an apex angle of 60 ° until a crack penetrating the plate thickness occurred, and the hole diameter d1 mm at the time of the crack occurrence was measured, and the hole expansion ratio ⁇ (%) of each test piece was calculated using the following formula.
  • Maximum difference in number density of ferrite/N ⁇ m in Table 4 means the maximum value of the six number density differences shown in Figure 1, i.e., the difference between N ⁇ 1 and N ⁇ 4, the difference between N ⁇ 4 and N ⁇ 7, the difference between N ⁇ 2 and N ⁇ 5, the difference between N ⁇ 5 and N ⁇ 8, the difference between N ⁇ 3 and N ⁇ 6, and the difference between N ⁇ 6 and N ⁇ 9, divided by N ⁇ m. Therefore, if this value is 0.60 or less, the requirement that "the difference in number density of ferrite in each divided region adjacent in the plate thickness direction is all N ⁇ m ⁇ 0.60 or less" is met. Also, in the metal structure shown in Table 4, the remaining structure was at least one of pearlite and retained austenite.

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Abstract

Provided is a steel sheet characterized by having a prescribed chemical composition and in that: the metal structure thereof contains, in terms of area%, 10-40% of ferrite, 60-90% of martensite, 0-10% of bainite, and a total of 0-5% of at least one among pearlite and retained austenite; and when a 150 μm × 150 μm region at a position at 1/4 of the sheet thickness in a cross section perpendicular to the sheet surface is equally divided into nine regions, the number density of ferrite in each of the divided regions is calculated, and the average value thereof is indicated by Nαm, the difference in the number density of ferrite between divided regions adjacent to each other in the sheet thickness direction is Nαm × 0.60 or less in all cases. Also provided are a component including the steel sheet, and a method for manufacturing the steel sheet.

Description

鋼板、それを含む部品及び鋼板の製造方法Steel plate, part including same, and method for manufacturing steel plate

 本発明は、鋼板、それを含む部品及び鋼板の製造方法に関する。 The present invention relates to a steel plate, a part including the steel plate, and a method for manufacturing the steel plate.

 近年、環境問題への対応のため、CO2ガスの排出低減や燃費向上を目的として自動車部品の軽量化が望まれている。一方で、衝突安全性向上に対する社会的要求もますます高くなっている。軽量化と衝突安全性向上を両立させるためには鋼材の高強度化が有効な手段である。しかしながら、通常は鋼材を高強度化すると加工性が低下するため、強度と加工性を同時に向上させる鋼材が必要とされている。 In recent years, in order to address environmental issues, there has been a demand for weight reduction in automotive parts in order to reduce CO2 gas emissions and improve fuel efficiency. At the same time, social demands for improved collision safety are also increasing. In order to achieve both weight reduction and improved collision safety, increasing the strength of steel materials is an effective means. However, increasing the strength of steel materials usually reduces their workability, so there is a need for steel materials that simultaneously improve both strength and workability.

 強度と加工性の向上に関連して、例えば、特許文献1では、フェライトとマルテンサイトを主体とする複合組織鋼板からなる冷延鋼板コイルであって、全組織に対する占積率でフェライト:10~40%、マルテンサイト:60~90%である組織形態を有すると共に、コイルの任意の位置から切り出した800mm×800mmの鋼板の4角および重心の位置のフェライト分率(「面積%」で示す)を、夫々Vα1、Vα2、Vα3、Vα4、Vα5、およびそれら5点の平均値をVαmとしたとき、上記フェライト分率Vα1、Vα2、Vα3、Vα4、Vα5のいずれもがVαm±5(面積%)の範囲内にあることを特徴とする高強度冷延鋼板コイルが記載されている。また、特許文献1では、素地鋼板(冷延鋼板)の熱処理する際の条件を厳密に規定することによって、コイル内でのフェライト分率のばらつきが小さい高強度冷延鋼板コイルが得られ、これによってコイル内での強度ばらつきが小さく引張強度が980MPa以上の高強度冷延鋼板コイルが実現でき、こうした高強度冷延鋼板コイルは自動車用鋼板として安定的な成形加工が実現できると教示され、実施例において引張強度の向上に加えて全伸び及び穴広げ性が改善されることが具体的に開示されている。 In relation to improvements in strength and workability, for example, Patent Document 1 describes a high-strength cold-rolled steel sheet coil made of a dual-phase steel sheet mainly composed of ferrite and martensite, which has a structural morphology in which the volume fraction of the total structure is 10-40% ferrite and 60-90% martensite, and in which the ferrite fractions (shown in "area %) at the four corners and center of gravity of an 800 mm x 800 mm steel sheet cut out from any position on the coil are Vα1, Vα2, Vα3, Vα4, Vα5, respectively, and when the average value of these five points is Vαm, all of the ferrite fractions Vα1, Vα2, Vα3, Vα4, Vα5 are within the range of Vαm ±5 (area %). Patent Document 1 also teaches that by strictly specifying the conditions for heat treatment of the base steel sheet (cold-rolled steel sheet), a high-strength cold-rolled steel sheet coil with small variation in the ferrite fraction within the coil can be obtained, which in turn makes it possible to realize a high-strength cold-rolled steel sheet coil with small strength variation within the coil and a tensile strength of 980 MPa or more, and that such a high-strength cold-rolled steel sheet coil can be stably formed into automotive steel sheets, and specifically discloses in the examples that in addition to improving tensile strength, total elongation and hole expandability are also improved.

特開2010-159453号公報JP 2010-159453 A

 上記のとおり、高強度化とともに鋼材の加工性は低下し、特許文献1で記載されるような穴広げ性などの特性が低下することが知られている。穴広げ性が低下すると、例えば、自動車の足回り部品などにおいて所望の形状に加工することができない場合がある。このため、高強度鋼板の開発においては、用途に応じた特性、例えば上記の穴広げ性以外にも均一伸びなどの特性を一定以上確保しつつ高強度化を図ることが重要である。例えば、自動車の足回り部品などのうちロアアームやトレーリングアーム等の複雑な形状を有する部品では、高強度化に伴って鋼材自体の加工性が低下したり、複雑な形状へと成形する際に加工硬化が生じたりすることで部品成形後に最大荷重付近までひずみが付与されている場合がある。したがって、従来と同等又はそれ以上の高強度化を行った場合においても、衝突時に高く安定した荷重を維持し、それゆえ荷重低下を伴う破断を発生させないか又は発生させにくい材料に対して依然として高いニーズがある。 As mentioned above, it is known that the workability of steel decreases with increasing strength, and properties such as hole expandability as described in Patent Document 1 decrease. If the hole expandability decreases, it may not be possible to process the desired shape, for example, in automobile suspension parts. For this reason, in the development of high-strength steel sheets, it is important to increase strength while ensuring a certain level of properties according to the application, such as uniform elongation in addition to the hole expandability mentioned above. For example, in automobile suspension parts and other parts having complex shapes such as lower arms and trailing arms, the workability of the steel itself may decrease with increasing strength, or work hardening may occur when forming into a complex shape, causing strain to be applied to the vicinity of the maximum load after part formation. Therefore, even when the strength is increased to the same level or higher than before, there is still a high demand for materials that maintain a high and stable load during a collision and therefore do not or are less likely to cause fracture accompanied by a decrease in load.

 また、耐衝撃性が求められる部材については、降伏強さを超える衝撃を受けると塑性変形が生じることから、自動車の衝突安全性を確保する観点からは、引張強さだけでなく降伏強さについても向上させることが求められており、それゆえ降伏強さと引張強さの比である降伏比を高めることが求められている。 In addition, for components that require impact resistance, plastic deformation occurs when they receive an impact that exceeds their yield strength. Therefore, from the perspective of ensuring the crash safety of automobiles, it is necessary to improve not only the tensile strength but also the yield strength, and therefore there is a demand to increase the yield ratio, which is the ratio of yield strength to tensile strength.

 本発明は、このような実情に鑑みてなされたものであり、その目的とするところは、新規な構成により、高強度でかつ高い均一伸び、穴広げ性及び降伏比を有するとともに、衝突時の荷重低下を抑制することができる鋼板、それを含む部品及び鋼板の製造方法を提供することにある。 The present invention was made in consideration of these circumstances, and its purpose is to provide a steel plate with a new structure that has high strength, high uniform elongation, hole expandability, and yield ratio, and that can suppress load reduction during a collision, as well as a part that includes the same, and a method for manufacturing the steel plate.

 本発明者らは、上記目的を達成するために、鋼板、特には熱延鋼板の金属組織に着目して検討を行った。その結果、本発明者らは、所定の化学組成を有する熱延鋼板の金属組織を、主としてフェライトとマルテンサイトを主体とする組織により構成しかつTiの添加による析出強化を利用することで、強度、均一伸び及び降伏比を向上させるとともに、フェライトとマルテンサイトとの硬度差を低減して穴広げ性を改善することができ、さらには板厚方向にフェライトを均一に配置すること、より具体的には鋼板の板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差が全てNαm×0.60以下となるように金属組織中でフェライトを均一に配置することで、均一伸び以降の荷重低下を顕著に抑制することができることを見出し、本発明を完成させた。 In order to achieve the above object, the inventors conducted a study focusing on the metal structure of steel plate, particularly hot-rolled steel plate. As a result, the inventors discovered that by forming the metal structure of a hot-rolled steel plate having a predetermined chemical composition mainly from ferrite and martensite and utilizing precipitation strengthening by adding Ti, it is possible to improve the strength, uniform elongation and yield ratio, and reduce the difference in hardness between ferrite and martensite to improve hole expandability, and further, by uniformly distributing ferrite in the plate thickness direction, more specifically, by equally dividing a 150 μm×150 μm region at 1/4 of the plate thickness position on a cross section perpendicular to the plate surface of the steel plate into nine parts, calculating the number density of ferrite in each divided region, and taking the average value of these as Nαm, it is possible to significantly suppress the load reduction after uniform elongation by uniformly distributing ferrite in the metal structure so that the difference in the number density of ferrite in each divided region adjacent to each other in the plate thickness direction is Nαm×0.60 or less, and thus completed the present invention.

 上記目的を達成し得た本発明は下記のとおりである。
 (1)化学組成が、質量%で、
 C:0.060~0.300%、
 Si:0.30~1.50%、
 Mn:1.00~2.70%、
 P:0.100%以下、
 S:0.0300%以下、
 sol.Al:0.001~0.500%、
 O:0.0100%以下、
 N:0.0070%以下、
 Ti:0.070~0.170%、
 Nb:0.001~1.000%、
 B:0~0.0030%、
 Cr:0~0.70%、
 Mo:0~0.12%、
 Cu:0~0.40%、
 Ni:0~0.30%、
 V:0~0.300%、
 Sn:0~0.040%、
 As:0~0.100%、
 Zr:0~0.050%、
 Ca:0~0.0010%、
 Mg:0~0.0010%、
 Bi:0~0.010%、
 Co:0~0.010%、
 W:0~0.100%、
 Zn:0~0.010%、
 REM:0~0.0100%、並びに
 残部:Fe及び不純物であり、
 金属組織が、面積%で、
 フェライト:10~40%、
 マルテンサイト:60~90%、
 ベイナイト:0~10%、並びに
 パーライト及び残留オーステナイトの少なくとも1種:合計で0~5%であり、
 板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差が全てNαm×0.60以下であることを特徴とする、鋼板。
 (2)前記化学組成が、質量%で、
 B:0.0001~0.0030%、
 Cr:0.001~0.70%、
 Mo:0.001~0.12%、
 Cu:0.001~0.40%、
 Ni:0.001~0.30%、
 V:0.001~0.300%、
 Sn:0.001~0.040%、
 As:0.001~0.100%、
 Zr:0.001~0.050%、
 Ca:0.0001~0.0010%、
 Mg:0.0001~0.0010%、
 Bi:0.001~0.010%、
 Co:0.001~0.010%、
 W:0.001~0.100%、
 Zn:0.001~0.010%、及び
 REM:0.0001~0.0100%
のうち少なくとも1種を含むことを特徴とする、上記(1)に記載の鋼板。
 (3)Nαmが0.050個/μm2以上であることを特徴とする、上記(1)又は(2)に記載の鋼板。
 (4)1180MPa以上の引張強さを有することを特徴とする、上記(1)~(3)のいずれか1項に記載の鋼板。
 (5)1.0~8.0mmの板厚を有することを特徴とする、上記(1)~(4)のいずれか1項に記載の鋼板。
 (6)上記(1)~(5)のいずれか1項に記載の鋼板を含むことを特徴とする、部品。
 (7)上記(1)又は(2)に記載の化学組成を有するスラブを加熱し、1180~1350℃の温度で6000秒以上保持することを含む加熱工程、
 前記スラブを4基以上の圧延スタンドからなるタンデム圧延機を用いて仕上げ圧延することを含み、下記(a)~(c)の条件を満足する熱間圧延工程、
  (a)後段2段の直前2段の各圧延パスにおける圧延温度が960~1080℃であり、前記各圧延パスにおける圧下率が30~50%であること、
  (b)前記後段2段の直前2段の圧延パス後0.20秒以内に圧延材を800~910℃の冷却停止温度まで冷却すること、及び
  (c)後段2段の各圧延パスにおける圧下率が10~40%であること
 仕上げ圧延された鋼板を水冷し、水冷開始から4.0秒以内に600~750℃の温度域まで冷却し、次いで前記温度域にて2.0~8.0秒の空冷を実施し、空冷後13秒以内に前記鋼板を50℃以下まで水冷することを含む冷却工程
を含む、鋼板の製造方法。
The present invention, which has achieved the above object, is as follows.
(1) Chemical composition, in mass%,
C: 0.060-0.300%,
Si: 0.30-1.50%,
Mn: 1.00-2.70%,
P: 0.100% or less,
S: 0.0300% or less,
sol. Al: 0.001 to 0.500%,
O: 0.0100% or less,
N: 0.0070% or less,
Ti: 0.070 to 0.170%,
Nb: 0.001-1.000%,
B: 0 to 0.0030%,
Cr: 0-0.70%,
Mo: 0 to 0.12%,
Cu: 0 to 0.40%,
Ni: 0 to 0.30%,
V: 0-0.300%,
Sn: 0 to 0.040%,
As: 0 to 0.100%,
Zr: 0 to 0.050%,
Ca: 0-0.0010%,
Mg: 0 to 0.0010%,
Bi: 0 to 0.010%,
Co: 0 to 0.010%,
W: 0-0.100%,
Zn: 0 to 0.010%,
REM: 0 to 0.0100%, and the balance: Fe and impurities;
The metal structure is, in area percent,
Ferrite: 10-40%,
Martensite: 60-90%,
Bainite: 0 to 10%, and at least one of pearlite and retained austenite: 0 to 5% in total;
A steel plate characterized in that, when a 150 μm x 150 μm region at 1/4 of the plate thickness position on a cross section perpendicular to the plate surface is equally divided into nine, the number density of ferrite is calculated in each divided region, and the average value of these is taken as Nαm, the difference in number density of ferrite in each divided region adjacent to each other in the plate thickness direction is all Nαm x 0.60 or less.
(2) The chemical composition is, in mass%,
B: 0.0001 to 0.0030%,
Cr: 0.001-0.70%,
Mo: 0.001-0.12%,
Cu: 0.001-0.40%,
Ni: 0.001 to 0.30%,
V: 0.001-0.300%,
Sn: 0.001 to 0.040%,
As: 0.001 to 0.100%,
Zr: 0.001 to 0.050%,
Ca: 0.0001 to 0.0010%,
Mg: 0.0001 to 0.0010%,
Bi: 0.001 to 0.010%,
Co: 0.001 to 0.010%,
W: 0.001-0.100%,
Zn: 0.001 to 0.010%, and REM: 0.0001 to 0.0100%
The steel sheet according to (1) above, characterized in that it contains at least one of the following:
(3) The steel sheet according to (1) or (2) above, characterized in that Nαm is 0.050 pieces/μm2 or more .
(4) The steel plate according to any one of (1) to (3) above, characterized in that it has a tensile strength of 1180 MPa or more.
(5) The steel sheet according to any one of (1) to (4) above, characterized in that it has a sheet thickness of 1.0 to 8.0 mm.
(6) A part, comprising the steel sheet according to any one of (1) to (5) above.
(7) A heating step including heating a slab having the chemical composition described in (1) or (2) above and holding it at a temperature of 1180 to 1350° C. for 6000 seconds or more;
A hot rolling process including finish rolling the slab using a tandem rolling mill having four or more rolling stands, the hot rolling process satisfying the following conditions (a) to (c):
(a) the rolling temperature in each of the rolling passes in the two stages immediately preceding the latter two stages is 960 to 1080°C, and the rolling reduction in each of the rolling passes is 30 to 50%;
(b) cooling the rolled material to a cooling stop temperature of 800 to 910°C within 0.20 seconds after the rolling passes of the two rolling passes immediately preceding the latter two rolling passes; and (c) a rolling reduction rate in each rolling pass of the latter two rolling passes is 10 to 40%. A method for producing a steel plate, comprising a cooling step including: water-cooling the finish-rolled steel plate, cooling it to a temperature range of 600 to 750°C within 4.0 seconds from the start of water cooling, then air-cooling it in said temperature range for 2.0 to 8.0 seconds, and water-cooling the steel plate to 50°C or less within 13 seconds after air-cooling.

 本発明によれば、高強度でかつ高い均一伸び、穴広げ性及び降伏比を有するとともに、衝突時の荷重低下を抑制することができる鋼板、それを含む部品及び鋼板の製造方法を提供することができる。 The present invention provides a steel plate that has high strength, high uniform elongation, hole expandability, and yield ratio, and is capable of suppressing load reduction during a collision, as well as a part that includes the steel plate and a method for manufacturing the steel plate.

フェライトの個数密度に関する特徴を説明する模式図であり、(a)は本発明に係るフェライトの個数密度に関する特徴を満足しない例を示し、(b)は当該特徴を満足する例を示している。1A and 1B are schematic diagrams for explaining characteristics related to the number density of ferrite, in which (a) shows an example that does not satisfy the characteristics related to the number density of ferrite according to the present invention, and (b) shows an example that satisfies the characteristics.

<鋼板>
 本発明の実施形態に係る鋼板は、特に熱延鋼板は、化学組成が、質量%で、
 C:0.060~0.300%、
 Si:0.30~1.50%、
 Mn:1.00~2.70%、
 P:0.100%以下、
 S:0.0300%以下、
 sol.Al:0.001~0.500%、
 O:0.0100%以下、
 N:0.0070%以下、
 Ti:0.070~0.170%、
 Nb:0.001~1.000%、
 B:0~0.0030%、
 Cr:0~0.70%、
 Mo:0~0.12%、
 Cu:0~0.40%、
 Ni:0~0.30%、
 V:0~0.300%、
 Sn:0~0.040%、
 As:0~0.100%、
 Zr:0~0.050%、
 Ca:0~0.0010%、
 Mg:0~0.0010%、
 Bi:0~0.010%、
 Co:0~0.010%、
 W:0~0.100%、
 Zn:0~0.010%、
 REM:0~0.0100%、並びに
 残部:Fe及び不純物であり、
 金属組織が、面積%で、
 フェライト:10~40%、
 マルテンサイト:60~90%、
 ベイナイト:0~10%、並びに
 パーライト及び残留オーステナイトの少なくとも1種:合計で0~5%であり、
 板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差が全てNαm×0.60以下であることを特徴としている。
<Steel plate>
The steel sheet according to the embodiment of the present invention, particularly the hot-rolled steel sheet, has a chemical composition in mass%:
C: 0.060-0.300%,
Si: 0.30-1.50%,
Mn: 1.00-2.70%,
P: 0.100% or less,
S: 0.0300% or less,
sol. Al: 0.001 to 0.500%,
O: 0.0100% or less,
N: 0.0070% or less,
Ti: 0.070 to 0.170%,
Nb: 0.001-1.000%,
B: 0 to 0.0030%,
Cr: 0-0.70%,
Mo: 0 to 0.12%,
Cu: 0 to 0.40%,
Ni: 0 to 0.30%,
V: 0-0.300%,
Sn: 0 to 0.040%,
As: 0 to 0.100%,
Zr: 0 to 0.050%,
Ca: 0-0.0010%,
Mg: 0 to 0.0010%,
Bi: 0 to 0.010%,
Co: 0 to 0.010%,
W: 0-0.100%,
Zn: 0 to 0.010%,
REM: 0 to 0.0100%, and the balance: Fe and impurities;
The metal structure is, in area percent,
Ferrite: 10-40%,
Martensite: 60-90%,
Bainite: 0 to 10%, and at least one of pearlite and retained austenite: 0 to 5% in total;
A 150 μm x 150 μm region at 1/4 of the plate thickness on a cross section perpendicular to the plate surface is equally divided into nine portions, the number density of ferrite is calculated in each divided region, and the average value of these is taken as Nαm. In this case, the difference in the number density of ferrite in adjacent divided regions in the plate thickness direction is all Nαm x 0.60 or less.

 先に述べたとおり、鋼材の高強度化とともに穴広げ性などの特性が低下することが知られている。例えば、自動車の足回り部品のうちロアアームやトレーリングアーム等の複雑な形状を有する部品を製造するためには、高強度、例えば軽量化を可能とする引張強さが1180MPa以上の高強度を確保しつつ、優れた穴広げ性を有する鋼板が求められる。高強度化の観点から、鋼板の金属組織はマルテンサイトを主体とする組織によって構成することが好ましい。しかしながら、マルテンサイト鋼は強度には優れるものの、過度に含むことで均一伸び等の特性が低下するため、一般に加工性が低いという問題がある。また、ロアアームやトレーリングアーム等の複雑な形状を有する部品では、高強度化に伴って鋼材自体の加工性が低下したり、複雑な形状へと成形する際に加工硬化が生じたりすることで部品成形後に最大荷重付近までひずみが付与されている場合がある。したがって、穴広げ性や均一伸びなどの特性を改善するとともに、複雑な形状を有する部品を成形した場合においても、衝突時に高く安定した荷重を維持し、それゆえ荷重低下を伴う破断の発生を抑制することができ、さらには自動車の衝突安全性等の観点から高い降伏比を有する高強度鋼板に対して依然として高いニーズがある。 As mentioned above, it is known that the properties such as hole expandability decrease with increasing strength of steel. For example, in order to manufacture parts with complex shapes such as lower arms and trailing arms among the suspension parts of automobiles, a steel plate with excellent hole expandability while maintaining high strength, for example, a tensile strength of 1180 MPa or more that enables weight reduction, is required. From the viewpoint of increasing strength, it is preferable that the metal structure of the steel plate is composed mainly of martensite. However, although martensitic steel has excellent strength, excessive inclusion of martensitic steel reduces properties such as uniform elongation, so that there is a problem that it is generally poor in workability. In addition, in parts with complex shapes such as lower arms and trailing arms, the workability of the steel itself decreases with increasing strength, and work hardening occurs when forming into a complex shape, so that strain may be applied to near the maximum load after part forming. Therefore, there remains a strong need for high-strength steel plates that have improved properties such as hole expandability and uniform elongation, can maintain a high and stable load during a collision even when forming parts with complex shapes, and therefore can suppress the occurrence of fractures accompanied by a drop in load, and also have a high yield ratio from the perspective of automobile collision safety, etc.

 そこで、本発明者らは、鋼板の化学組成を適切なものとすることに加えて、特に当該鋼板の金属組織に着目して検討を行った。まず、本発明者らは、所定の化学組成を有する鋼板の金属組織を、軟質なフェライトと硬質なマルテンサイトを主体とする組織、より具体的には面積%で、フェライト:10~40%及びマルテンサイト:60~90%を含む組織によって構成することで、いわゆるDP(Dual Phase)鋼の作用機構により強度と均一伸びを改善することができることを見出した。 The inventors therefore conducted research focusing on the metal structure of the steel plate, in addition to determining the appropriate chemical composition of the steel plate. First, the inventors discovered that by configuring the metal structure of a steel plate having a specified chemical composition to a structure mainly composed of soft ferrite and hard martensite, more specifically, a structure containing, by area percentage, 10-40% ferrite and 60-90% martensite, it is possible to improve strength and uniform elongation through the action mechanism of so-called DP (Dual Phase) steel.

 一方で、DP鋼は一般に低降伏比であることから、本発明者らは、Tiの添加による析出強化を利用することで降伏比を高めるとともに、穴広げ性を顕著に向上させることができることを見出した。何ら特定の理論に束縛されることを意図するものではないが、このような析出強化による穴広げ性の向上は、金属組織におけるフェライトとマルテンサイトとの硬度差の低減に起因しているものと考えられる。より詳しく説明すると、本発明の実施形態に係る鋼板では、上記のとおり金属組織がフェライトとマルテンサイトを主体とする組織で構成され、軟質組織であるフェライトを面積%で最大40%まで含み得る。この場合には、金属組織におけるフェライトとマルテンサイトとの硬度差が高くなり、穴広げ性が低下することになる。しかしながら、本発明の実施形態に係る鋼板では、鋼中のTi含有量を0.070質量%以上に制御することで、Ti析出物によってフェライトの軟質組織を析出強化し、それによって金属組織におけるフェライトとマルテンサイトとの硬度差を低減することができ、それゆえ穴広げ性を顕著に向上させることができるものと考えられる。 On the other hand, since DP steel generally has a low yield ratio, the inventors have found that the yield ratio can be increased and the hole expandability can be significantly improved by utilizing precipitation strengthening through the addition of Ti. Although it is not intended to be bound by any particular theory, it is believed that the improvement in hole expandability due to such precipitation strengthening is due to the reduction in the hardness difference between ferrite and martensite in the metal structure. To explain in more detail, in the steel sheet according to the embodiment of the present invention, as described above, the metal structure is composed mainly of ferrite and martensite, and the soft structure ferrite can be contained up to 40% by area. In this case, the hardness difference between ferrite and martensite in the metal structure increases, and the hole expandability decreases. However, in the steel sheet according to the embodiment of the present invention, by controlling the Ti content in the steel to 0.070 mass% or more, the soft structure of ferrite is precipitation strengthened by Ti precipitates, thereby reducing the hardness difference between ferrite and martensite in the metal structure, and therefore it is believed that the hole expandability can be significantly improved.

 次に、本発明者らは、衝突時においても高く安定した荷重を維持して破断の発生を抑制するためには、単軸引張試験における最大荷重点の伸びに相当する均一伸び以降の加工軟化を抑制する必要があると考えて検討を行った。というのも、均一伸び以降の加工軟化を抑制することで、衝突時における最大荷重から破断までの衝突エネルギーを鋼板の塑性変形によって効果的に吸収することが可能になるからである。まず、本発明者らによる実験で、均一伸び以降の加工軟化率(d2σ/dε2)(σ:真応力、ε:真ひずみ)の絶対値を250000MPa以下に制御した場合には、成形後の部品を落錘試験に供した際にも破断の発生を完全に又は顕著に抑制できることがわかった。そこで、本発明者らは、このような加工軟化率を安定的に実現すべく、衝突時に変形が集中しやすい軟質組織のフェライトに着目してさらに検討を行った。その結果、本発明者らは、鋼板の板厚方向にフェライトを均一に配置すること、より具体的には鋼板の板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差、より詳しくは板厚方向に隣接する各分割領域におけるフェライトの個数密度の差の絶対値が全てNαm×0.60以下となるように金属組織中でフェライトを均一に配置することにより、単軸引張試験における均一伸び以降の加工軟化率の絶対値を確実に250000MPa以下に低減することができることを見出した。これに関連して、本発明者らは、当該鋼板を部品、とりわけロアアームやトレーリングアーム等の複雑な形状を有する部品に成形した場合においても、衝突時の荷重低下を抑制して破断の発生を顕著に抑制することができることを見出した。 Next, the inventors conducted a study on the assumption that in order to maintain a high and stable load even during a collision and suppress the occurrence of fracture, it is necessary to suppress the work softening after uniform elongation, which corresponds to the elongation at the maximum load point in a uniaxial tensile test. This is because by suppressing the work softening after uniform elongation, it is possible to effectively absorb the collision energy from the maximum load to fracture during a collision by the plastic deformation of the steel sheet. First, in an experiment conducted by the inventors, it was found that when the absolute value of the work softening rate after uniform elongation ( d2σ / dε2 ) (σ: true stress, ε: true strain) is controlled to 250,000 MPa or less, the occurrence of fracture can be completely or significantly suppressed even when the formed part is subjected to a drop weight test. Therefore, in order to stably realize such a work softening rate, the inventors conducted further studies focusing on ferrite, a soft structure in which deformation is likely to concentrate during a collision. As a result, the inventors have found that the absolute value of the work softening rate after uniform elongation in a uniaxial tensile test can be reliably reduced to 250,000 MPa or less by uniformly distributing ferrite in the thickness direction of the steel plate, more specifically, by uniformly dividing a 150 μm×150 μm region at 1/4 of the thickness position of a cross section perpendicular to the plate surface of the steel plate into nine parts, calculating the number density of ferrite in each divided region, and arranging ferrite uniformly in the metal structure so that the absolute value of the difference in the number density of ferrite in each divided region adjacent to each other in the thickness direction is Nαm×0.60 or less when the average value of the ferrite density in each divided region adjacent to each other in the thickness direction is Nαm×0.60 or less. In relation to this, the inventors have found that even when the steel plate is formed into a part, particularly a part having a complex shape such as a lower arm or a trailing arm, the load reduction during a collision can be suppressed and the occurrence of fracture can be significantly suppressed.

 図1は、フェライトの個数密度に関する特徴を説明する模式図であり、図1(a)は本発明に係るフェライトの個数密度に関する特徴、すなわち「板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差が全てNαm×0.60以下である」との特徴を満足しない例を示し、図1(b)は当該特徴を満足する例を示している。図1(a)を参照すると、まず、鋼板の板面に垂直な断面の板厚1/4位置における150μm×150μmの領域が均等に9分割され、各分割領域、すなわちNα1~Nα9のそれぞれにおいてフェライトの個数密度が算出され、それらの平均値Nαm=0.058個/μm2が決定される(図1(a)(i))。次に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差、すなわち、Nα1とNα4の差(0.045個/μm2)、Nα4とNα7の差(0.033個/μm2)、Nα2とNα5の差(0.017個/μm2)、Nα5とNα8の差(0.012個/μm2)、Nα3とNα6の差(0.008個/μm2)、及びNα6とNα9の差(0.014個/μm2)が算出される(図1(a)(ii))。これら6つの個数密度の差の全てが平均値Nαm(0.058個/μm2)の0.60倍以下(Nαm×0.60以下)である場合、すなわち各個数密度の差をNαmで除した値が全て0.60以下である場合には、本発明に係るフェライトの個数密度に関する特徴を満足することになる。しかしながら、図1(a)では、Nα1とNα4の差(0.045個/μm2)をNαm(0.058個/μm2)で除した値が0.78となり、当該特徴を満足しないことがわかる。 Fig. 1 is a schematic diagram for explaining the characteristics of the number density of ferrite, and Fig. 1(a) shows an example that does not satisfy the characteristics of the number density of ferrite according to the present invention, that is, "When a 150 μm × 150 μm region at the 1/4 position of the plate thickness of a cross section perpendicular to the plate surface is evenly divided into nine, the number density of ferrite is calculated in each divided region, and the average value is Nαm, the difference in the number density of ferrite in each divided region adjacent in the plate thickness direction is all Nαm × 0.60 or less", and Fig. 1(b) shows an example that satisfies the characteristics. Referring to Fig. 1(a), first, a 150 μm × 150 μm region at the 1/4 position of the plate thickness of a cross section perpendicular to the plate surface of the steel plate is evenly divided into nine, and the number density of ferrite is calculated in each divided region, i.e., Nα1 to Nα9, and the average value Nαm = 0.058 / μm 2 is determined (Fig. 1(a) (i)). Next, the differences in the number density of ferrite in each divided region adjacent in the plate thickness direction are calculated (i.e., the difference between Nα1 and Nα4 (0.045 pieces/ μm2 ), the difference between Nα4 and Nα7 (0.033 pieces/ μm2 ), the difference between Nα2 and Nα5 (0.017 pieces/ μm2 ), the difference between Nα5 and Nα8 (0.012 pieces/ μm2 ), the difference between Nα3 and Nα6 (0.008 pieces/ μm2 ), and the difference between Nα6 and Nα9 (0.014 pieces/ μm2 ) (Figure 1 (a) (ii)). If all of the differences in number density among these six are 0.60 times or less (Nαm × 0.60 or less) the average value Nαm (0.058 particles/ μm2 ), that is, if the values obtained by dividing the differences in number density by Nαm are all 0.60 or less, the feature regarding number density of ferrite according to the present invention is satisfied. However, in Fig. 1(a), the value obtained by dividing the difference between Nα1 and Nα4 (0.045 particles/ μm2 ) by Nαm (0.058 particles/ μm2 ) is 0.78, which does not satisfy the feature.

 一方で、図1(b)を参照すると、同様に算出した板厚方向に隣接する各分割領域におけるフェライトの個数密度の差の全てが平均値Nαm(0.056個/μm2)の0.60倍以下(Nαm×0.60以下)となっており、それゆえ本発明に係るフェライトの個数密度に関する特徴を満足していることがわかる。本発明の実施形態においては、このように鋼板の板厚方向においてフェライトの個数密度を均一化すること、すなわち鋼板の板厚方向においてフェライトを均一に配置することにより、単軸引張試験における均一伸び以降の加工軟化率の絶対値を確実に250000MPa以下に低減することができ、それゆえ当該鋼板をロアアームやトレーリングアーム等の複雑な形状を有する部品に成形した場合においても、衝突時の破断の発生を顕著に抑制することが可能となる。 1(b), all of the differences in number density of ferrite in each divided region adjacent to each other in the sheet thickness direction calculated in the same manner are 0.60 times or less (Nαm×0.60 or less) the average value Nαm (0.056 particles/μm 2 ), and therefore satisfy the feature regarding the number density of ferrite according to the present invention. In the embodiment of the present invention, by thus homogenizing the number density of ferrite in the sheet thickness direction of the steel sheet, that is, by uniformly disposing the ferrite in the sheet thickness direction of the steel sheet, the absolute value of the work softening rate after uniform elongation in the uniaxial tensile test can be reliably reduced to 250,000 MPa or less, and therefore, even when the steel sheet is formed into a part having a complex shape such as a lower arm or a trailing arm, it becomes possible to significantly suppress the occurrence of fracture during a collision.

 何ら特定の理論に束縛されることを意図するものではないが、フェライトを金属組織中に均一に分散して配置することで、衝突時においても局所的な変形を抑制することができ、それによって衝突時の荷重低下を抑えて高く安定した荷重を維持し、その結果として破断の発生を顕著に抑制することが可能になるものと考えられる。より詳しく説明すると、鋼板を軟質なフェライトと硬質なマルテンサイトを主体とする組織によって構成する場合には、一般的には硬質なマルテンサイトによって強度を確保し、軟質なフェライトによって変形を担うことになる。このため、衝突時における変形は軟質組織であるフェライトに集中しやすい。このような場合に、フェライトが金属組織中で局所的に比較的多く存在する領域があると、このような領域に変形時のひずみが集中してしまうと考えられる。その結果として、局所的な変形を抑制することができず、このような変形に起因して衝突時の荷重が低下してしまうものと考えられる。ここで、衝突時の変形モードを考慮すると、衝突時には特に曲げ変形における荷重低下を抑制することが重要であり、また、曲げ変形においては、鋼板の表層を起点として板厚方向に破断が生じる。このため、衝突時の荷重低下を抑制するためには、金属組織中で特に板厚方向におけるフェライトの配置を均一にすることが有効であると考えられる。実際、図1に示すように鋼板の板厚方向にフェライトを均一に配置することで、単軸引張試験における均一伸び以降の加工軟化率の絶対値を確実に250000MPa以下に低減することができ、当該鋼板をロアアームやトレーリングアーム等の複雑な形状を有する部品に成形した場合においても、衝突時の破断の発生を顕著に抑制することが可能となることが見出された。フェライトとマルテンサイトを主体とする組織により構成される鋼板の板厚方向にフェライトを均一に配置することで、均一伸び以降の加工軟化率を低減することができるという事実、さらにはそれによって衝突時の破断の発生を顕著に抑制することができるという事実は従来知られておらず、今回、本発明者らによって初めて明らかにされたことである。したがって、本発明の実施形態によれば、例えば、引張強さが1180MPa以上の高強度であるにもかかわらず、高い均一伸び、穴広げ性及び降伏比を有するとともに、衝突時の荷重低下を伴う破断の発生を顕著に抑制することができ、よって本発明の実施形態に係る鋼板は自動車分野の使用において特に有用である。 Without intending to be bound by any particular theory, it is believed that by distributing ferrite uniformly in the metal structure, it is possible to suppress local deformation even during a collision, thereby suppressing the load drop during the collision and maintaining a high and stable load, and as a result, it is possible to significantly suppress the occurrence of fracture. To explain in more detail, when a steel plate is composed of a structure mainly composed of soft ferrite and hard martensite, the strength is generally ensured by the hard martensite, and deformation is borne by the soft ferrite. For this reason, deformation during a collision tends to concentrate in the ferrite, which is a soft structure. In such a case, if there is an area in which ferrite is relatively abundant locally in the metal structure, it is believed that strain during deformation will concentrate in such an area. As a result, it is not possible to suppress local deformation, and it is believed that the load during the collision will decrease due to such deformation. Here, considering the deformation mode during a collision, it is important to suppress the load drop during bending deformation in particular during a collision, and in bending deformation, fracture occurs in the thickness direction of the steel plate starting from the surface layer. For this reason, in order to suppress the load reduction during a collision, it is considered effective to uniformly arrange ferrite in the metal structure, particularly in the plate thickness direction. In fact, it has been found that by uniformly arranging ferrite in the plate thickness direction of the steel plate as shown in FIG. 1, the absolute value of the work softening rate after uniform elongation in a uniaxial tensile test can be reliably reduced to 250,000 MPa or less, and even when the steel plate is formed into a part having a complex shape such as a lower arm or a trailing arm, it is possible to significantly suppress the occurrence of fracture during a collision. The fact that the work softening rate after uniform elongation can be reduced by uniformly arranging ferrite in the plate thickness direction of a steel plate composed mainly of a structure of ferrite and martensite, and further the fact that the occurrence of fracture during a collision can be significantly suppressed thereby, was not known in the past, and was revealed for the first time by the present inventors. Therefore, according to the embodiment of the present invention, for example, despite the high strength of the tensile strength of 1180 MPa or more, it is possible to have high uniform elongation, hole expandability and yield ratio, and to significantly suppress the occurrence of fracture accompanied by load reduction during a collision, and therefore the steel plate according to the embodiment of the present invention is particularly useful for use in the automotive field.

 以下、本発明の実施形態に係る鋼板についてより詳しく説明する。以下の説明において、各元素の含有量の単位である「%」は、特に断りがない限り「質量%」を意味するものである。また、本明細書において、数値範囲を示す「~」とは、特に断りがない場合、その前後に記載される数値を下限値及び上限値として含む意味で使用される。 Below, the steel sheet according to the embodiment of the present invention will be described in more detail. In the following description, the unit of content of each element, "%", means "mass %" unless otherwise specified. Furthermore, in this specification, "to" indicating a numerical range is used to mean that the numerical values written before and after it are included as the lower and upper limits, unless otherwise specified.

[C:0.060~0.300%]
 Cは、鋼板の強度を高めるのに有効な元素である。また、Cは、鋼中でNbと炭化物及び/又は炭窒化物を形成し、形成した析出物のピン止め効果による組織の微細化にも寄与する。これらの効果を十分に得るために、C含有量は0.060%以上とする。C含有量は0.070%以上、0.080%以上、0.100%以上、0.120%以上又は0.150%以上であってもよい。一方で、Cを過度に含有すると、均一伸びが低下する場合がある。したがって、C含有量は0.300%以下とする。C含有量は0.280%以下、0.250%以下、0.200%以下、0.180%以下又は0.160%以下であってもよい。
[C:0.060-0.300%]
C is an element effective in increasing the strength of the steel plate. In addition, C forms carbides and/or carbonitrides with Nb in the steel, and also contributes to refining the structure due to the pinning effect of the precipitates formed. In order to fully obtain these effects, the C content is set to 0.060% or more. The C content may be 0.070% or more, 0.080% or more, 0.100% or more, 0.120% or more, or 0.150% or more. On the other hand, if C is contained excessively, the uniform elongation may decrease. Therefore, the C content is set to 0.300% or less. The C content may be 0.280% or less, 0.250% or less, 0.200% or less, 0.180% or less, or 0.160% or less.

[Si:0.30~1.50%]
 Siは、鉄炭化物の生成を抑制し、強度と成形性の向上に寄与する元素である。このような効果を十分に得るために、Si含有量は0.30%以上とする。Si含有量は0.40%以上、0.50%以上、0.60%以上、0.70%以上又は0.80%以上であってもよい。一方で、Siを過度に含有すると、フェライト分率が高くなり、これに起因してフェライトとマルテンサイトとの硬度差が大きくなり、穴広げ性が低下する場合がある。したがって、Si含有量は1.50%以下とする。Si含有量は1.40%以下、1.20%以下、1.10%以下、1.00%以下又は0.90%以下であってもよい。
[Si: 0.30-1.50%]
Si is an element that suppresses the formation of iron carbides and contributes to improving strength and formability. In order to fully obtain such effects, the Si content is set to 0.30% or more. The Si content may be 0.40% or more, 0.50% or more, 0.60% or more, 0.70% or more, or 0.80% or more. On the other hand, if Si is contained excessively, the ferrite fraction becomes high, which may cause a large difference in hardness between ferrite and martensite, resulting in a decrease in hole expandability. Therefore, the Si content is set to 1.50% or less. The Si content may be 1.40% or less, 1.20% or less, 1.10% or less, 1.00% or less, or 0.90% or less.

[Mn:1.00~2.70%]
 Mnは、焼入れ性及び固溶強化元素として強度上昇に有効な元素である。これらの効果を十分に得るために、Mn含有量は1.00%以上とする。Mn含有量は1.20%以上、1.50%以上、1.60%以上、1.80%以上又は2.00%以上であってもよい。一方で、Mnを過度に含有すると、焼入れ性の過度な向上に起因してフェライト分率が低下し、均一伸びが低下する場合がある。したがって、Mn含有量は2.70%以下とする。Mn含有量は2.60%以下、2.50%以下、2.40%以下、2.30%以下又は2.20%以下であってもよい。
[Mn: 1.00-2.70%]
Mn is an element that is effective in increasing strength as a hardenability and solid solution strengthening element. In order to fully obtain these effects, the Mn content is set to 1.00% or more. The Mn content may be 1.20% or more, 1.50% or more, 1.60% or more, 1.80% or more, or 2.00% or more. On the other hand, if Mn is contained excessively, the ferrite fraction may decrease due to excessive improvement in hardenability, and uniform elongation may decrease. Therefore, the Mn content is set to 2.70% or less. The Mn content may be 2.60% or less, 2.50% or less, 2.40% or less, 2.30% or less, or 2.20% or less.

[P:0.100%以下]
 Pは、過度に含有すると粒界偏析等により加工性が低下する場合がある。したがって、P含有量は0.100%以下とする。P含有量は0.050%以下、0.030%以下、0.020%以下又は0.015%以下であってもよい。P含有量の下限は特に限定されず0%であってもよいが、過度な低減はコストの上昇を招く。したがって、P含有量は0.0001%以上、0.001%以上又は0.005%以上であってもよい。
[P: 0.100% or less]
If P is contained excessively, workability may decrease due to grain boundary segregation, etc. Therefore, the P content is set to 0.100% or less. The P content may be 0.050% or less, 0.030% or less, 0.020% or less, or 0.015% or less. The lower limit of the P content is not particularly limited and may be 0%, but excessive reduction will lead to an increase in costs. Therefore, the P content may be 0.0001% or more, 0.001% or more, or 0.005% or more.

[S:0.0300%以下]
 Sは、過度に含有するとMnS等の硫化物が多く生成して加工性を低下させる場合がある。したがって、S含有量は0.0300%以下とする。S含有量は0.0200%以下、0.0100%以下又は0.0050%以下であってもよい。S含有量の下限は特に限定されず0%であってもよいが、過度な低減はコストの上昇を招く。したがって、S含有量は0.0001%以上、0.0010%以上又は0.0030%以上であってもよい。
[S: 0.0300% or less]
If S is contained excessively, a large amount of sulfides such as MnS may be generated, which may reduce workability. Therefore, the S content is set to 0.0300% or less. The S content may be 0.0200% or less, 0.0100% or less, or 0.0050% or less. The lower limit of the S content is not particularly limited and may be 0%, but excessive reduction will lead to an increase in costs. Therefore, the S content may be 0.0001% or more, 0.0010% or more, or 0.0030% or more.

[sol.Al:0.001~0.500%]
 sol.Alは、溶鋼の脱酸剤として作用する元素である。このような効果を得るために、sol.Al含有量は0.001%以上とする。sol.Al含有量は0.010%以上、0.020%以上、0.030%以上、0.050%以上又は0.100%以上であってもよい。一方で、sol.Alを過度に含有すると、フェライト分率が高くなり、これに起因してフェライトとマルテンサイトとの硬度差が大きくなり、穴広げ性が低下する場合がある。したがって、sol.Al含有量は0.500%以下とする。sol.Al含有量は0.400%以下、0.300%以下又は0.200%以下であってもよい。sol.Alとは酸可溶性Alを意味し、固溶状態で鋼中に存在する固溶Alのことを示す。
[sol. Al: 0.001 to 0.500%]
Sol. Al is an element that acts as a deoxidizer for molten steel. In order to obtain such an effect, the sol. Al content is set to 0.001% or more. The sol. Al content may be 0.010% or more, 0.020% or more, 0.030% or more, 0.050% or more, or 0.100% or more. On the other hand, if sol. Al is contained excessively, the ferrite fraction becomes high, which may cause a large difference in hardness between ferrite and martensite, resulting in a decrease in hole expandability. Therefore, the sol. Al content is set to 0.500% or less. The sol. Al content may be 0.400% or less, 0.300% or less, or 0.200% or less. Sol. Al means acid-soluble Al, and refers to solid-solution Al present in the steel in a solid solution state.

[O:0.0100%以下]
 Oは、製造工程で混入する元素である。Oを過度に含有すると、粗大な介在物が形成して鋼板の加工性を低下させる場合がある。したがって、O含有量は0.0100%以下とする。O含有量は0.0080%以下、0.0060%以下又は0.0040%以下であってもよい。O含有量の下限は特に限定されず0%であってもよいが、0.0001%未満に低減するためには精錬に時間を要し、生産性の低下を招く。したがって、O含有量は0.0001%以上又は0.0005%以上であってもよい。
[O: 0.0100% or less]
O is an element that is mixed in during the manufacturing process. If O is contained excessively, coarse inclusions may be formed, which may reduce the workability of the steel sheet. Therefore, the O content is set to 0.0100% or less. The O content may be 0.0080% or less, 0.0060% or less, or 0.0040% or less. The lower limit of the O content is not particularly limited and may be 0%, but reducing the O content to less than 0.0001% requires a long time for refining, which leads to a decrease in productivity. Therefore, the O content may be 0.0001% or more, or 0.0005% or more.

[N:0.0070%以下]
 Nは、過度に含有すると粗大な窒化物を形成し、熱間圧延中にスラブ割れが生じる場合がある。したがって、N含有量は0.0070%以下とする。N含有量は0.0050%以下、0.0040%以下又は0.0030%以であってもよい。N含有量の下限は特に限定されず0%であってもよいが、過度な低減はコストの上昇を招く。したがって、N含有量は0.0001%以上又は0.0005%以上であってもよい。
[N: 0.0070% or less]
If N is contained excessively, coarse nitrides are formed, and slab cracks may occur during hot rolling. Therefore, the N content is set to 0.0070% or less. The N content may be 0.0050% or less, 0.0040% or less, or 0.0030% or less. The lower limit of the N content is not particularly limited and may be 0%, but excessive reduction will lead to an increase in costs. Therefore, the N content may be 0.0001% or more, or 0.0005% or more.

[Ti:0.070~0.170%]
 Tiは、TiC等のTi炭化物として鋼中に析出し、析出強化によりフェライト等の軟質組織を強化し、強度及び降伏比の向上に寄与する元素である。さらに、Tiは、析出強化に起因して金属組織におけるフェライトとマルテンサイトとの硬度差を低減させることができるので、穴広げ性を向上させる上でも有効である。これらの効果を十分に得るために、Ti含有量は0.070%以上とする。Ti含有量は0.080%以上、0.090%以上、0.100%以上又は0.120%以上であってもよい。一方で、Tiを過度に含有すると、鋼中に粗大な炭化物等が生成し、熱間圧延中にスラブ割れが生じたり、鋼板の加工性が低下したりする場合がある。したがって、Ti含有量は0.170%以下とする。Ti含有量は0.160%以下、0.150%以下、0.140%以下又は0.130%以下であってもよい。
[Ti: 0.070 to 0.170%]
Ti is an element that precipitates in steel as Ti carbides such as TiC, strengthens soft structures such as ferrite by precipitation strengthening, and contributes to improving strength and yield ratio. Furthermore, Ti can reduce the hardness difference between ferrite and martensite in the metal structure due to precipitation strengthening, so it is also effective in improving hole expandability. In order to fully obtain these effects, the Ti content is 0.070% or more. The Ti content may be 0.080% or more, 0.090% or more, 0.100% or more, or 0.120% or more. On the other hand, if Ti is contained excessively, coarse carbides and the like are generated in the steel, which may cause slab cracks during hot rolling or reduce the workability of the steel sheet. Therefore, the Ti content is 0.170% or less. The Ti content may be 0.160% or less, 0.150% or less, 0.140% or less, or 0.130% or less.

[Nb:0.001~1.000%]
 Nbは、鋼中に炭化物、窒化物及び/又は炭窒化物を形成してピン止め効果により旧オーステナイト粒の微細化、ひいては鋼板の高強度化に寄与する元素である。このような効果を十分に得るために、Nb含有量は0.001%以上とする。Nb含有量は0.005%以上、0.010%以上、0.030%以上、0.050%以上、0.080%以上又は0.100%以上であってもよい。一方で、Nbを過度に含有すると、鋼中に粗大な炭化物等が生成して鋼板の加工性が低下する場合がある。したがって、Nb含有量は1.000%以下とする。Nb含有量は0.800%以下、0.600%以下、0.500%以下、0.400%以下、0.300%以下又は0.200%以下であってもよい。
[Nb: 0.001 to 1.000%]
Nb is an element that forms carbides, nitrides and/or carbonitrides in steel and contributes to the refinement of prior austenite grains and thus to the high strength of steel sheet by the pinning effect. In order to fully obtain such effects, the Nb content is set to 0.001% or more. The Nb content may be 0.005% or more, 0.010% or more, 0.030% or more, 0.050% or more, 0.080% or more, or 0.100% or more. On the other hand, if Nb is excessively contained, coarse carbides and the like may be generated in the steel, which may reduce the workability of the steel sheet. Therefore, the Nb content is set to 1.000% or less. The Nb content may be 0.800% or less, 0.600% or less, 0.500% or less, 0.400% or less, 0.300% or less, or 0.200% or less.

 本発明の実施形態に係る鋼板の基本化学組成は上記のとおりである。さらに、当該鋼板は、必要に応じて、残部のFeの一部に代えて以下の元素のうち少なくとも1種を含有してもよい。 The basic chemical composition of the steel plate according to the embodiment of the present invention is as described above. Furthermore, the steel plate may contain at least one of the following elements in place of a portion of the remaining Fe, as necessary.

[B:0~0.0030%]
 Bは、鋼の焼入れ性を高め、強度の向上に寄与する元素である。B含有量は0%であってもよいが、このような効果を得るためには、B含有量は0.0001%以上であることが好ましい。B含有量は0.0002%以上、0.0003%以上又は0.0005%以上であってもよい。一方で、Bを過度に含有しても効果が飽和し、製造コストの上昇を招く虞がある。したがって、B含有量は0.0030%以下であることが好ましい。B含有量は0.0025%以下、0.0020%以下、0.0015%以下又は0.0010%以下であってもよい。
[B: 0 to 0.0030%]
B is an element that improves the hardenability of steel and contributes to improving strength. The B content may be 0%, but in order to obtain such an effect, the B content is preferably 0.0001% or more. The B content may be 0.0002% or more, 0.0003% or more, or 0.0005% or more. On the other hand, even if B is contained excessively, the effect is saturated and there is a risk of increasing the manufacturing cost. Therefore, the B content is preferably 0.0030% or less. The B content may be 0.0025% or less, 0.0020% or less, 0.0015% or less, or 0.0010% or less.

[Cr:0~0.70%]
 Crは、鋼の焼入れ性を高め、強度及び/又は耐食性の向上に寄与する元素である。Cr含有量は0%であってもよいが、これらの効果を得るためには、Cr含有量は0.001%以上であることが好ましく、0.01%以上、0.05%以上又は0.10%以上であってもよい。一方で、Crを過度に含有しても効果が飽和し、製造コストの上昇を招く虞がある。したがって、Cr含有量は0.70%以下であることが好ましく、0.60%以下、0.50%以下、0.40%以下又は0.30%以下であってもよい。
[Cr: 0-0.70%]
Cr is an element that enhances the hardenability of steel and contributes to improving strength and/or corrosion resistance. The Cr content may be 0%, but in order to obtain these effects, the Cr content is preferably 0.001% or more, and may be 0.01% or more, 0.05% or more, or 0.10% or more. On the other hand, even if Cr is contained excessively, the effect is saturated and there is a risk of increasing the manufacturing cost. Therefore, the Cr content is preferably 0.70% or less, and may be 0.60% or less, 0.50% or less, 0.40% or less, or 0.30% or less.

[Mo:0~0.12%]
 Moは、鋼の焼入れ性を高め、強度の向上に寄与する元素である。Mo含有量は0%であってもよいが、このような効果を得るためには、Mo含有量は0.001%以上であることが好ましい。Mo含有量は0.01%以上、0.02%以上又は0.03%以上であってもよい。一方で、Moを過度に含有すると、熱間加工時の変形抵抗が増大し、設備負荷が大きくなる場合がある。したがって、Mo含有量は0.12%以下であることが好ましい。Mo含有量は0.10%以下、0.08%以下、0.06%以下又は0.05%以下であってもよい。
[Mo: 0 to 0.12%]
Mo is an element that enhances the hardenability of steel and contributes to improving strength. The Mo content may be 0%, but in order to obtain such an effect, the Mo content is preferably 0.001% or more. The Mo content may be 0.01% or more, 0.02% or more, or 0.03% or more. On the other hand, if Mo is contained excessively, the deformation resistance during hot working may increase, and the equipment load may become large. Therefore, the Mo content is preferably 0.12% or less. The Mo content may be 0.10% or less, 0.08% or less, 0.06% or less, or 0.05% or less.

[Cu:0~0.40%]
 Cuは、析出強化又は固溶強化により強度の向上に寄与する元素である。Cu含有量は0%であってもよいが、このような効果を得るためには、Cu含有量は0.001%以上であることが好ましい。Cu含有量は0.01%以上、0.03%以上又は0.05%以上であってもよい。一方で、これらの元素を過度に含有しても効果が飽和し、製造コストの上昇を招く虞がある。したがって、Cu含有量は0.40%以下であることが好ましい。Cu含有量は0.30%以下、0.20%以下、0.10%以下又は0.08%以下であってもよい。
[Cu: 0-0.40%]
Cu is an element that contributes to improving strength by precipitation strengthening or solid solution strengthening. The Cu content may be 0%, but in order to obtain such an effect, the Cu content is preferably 0.001% or more. The Cu content may be 0.01% or more, 0.03% or more, or 0.05% or more. On the other hand, even if these elements are contained excessively, the effect is saturated and there is a risk of increasing the manufacturing cost. Therefore, the Cu content is preferably 0.40% or less. The Cu content may be 0.30% or less, 0.20% or less, 0.10% or less, or 0.08% or less.

[Ni:0~0.30%]
 Niは、析出強化又は固溶強化により強度の向上に寄与する元素である。Ni含有量は0%であってもよいが、このような効果を得るためには、Ni含有量は0.001%以上であることが好ましい。Ni含有量は0.01%以上、0.03%以上又は0.05%以上であってもよい。一方で、これらの元素を過度に含有しても効果が飽和し、製造コストの上昇を招く虞がある。したがって、Ni含有量は0.30%以下であることが好ましい。Ni含有量は0.20%以下、0.15%以下、0.10%以下又は0.08%以下であってもよい。
[Ni: 0-0.30%]
Ni is an element that contributes to improving strength by precipitation strengthening or solid solution strengthening. The Ni content may be 0%, but in order to obtain such an effect, the Ni content is preferably 0.001% or more. The Ni content may be 0.01% or more, 0.03% or more, or 0.05% or more. On the other hand, even if these elements are contained excessively, the effect is saturated and there is a risk of increasing the manufacturing cost. Therefore, the Ni content is preferably 0.30% or less. The Ni content may be 0.20% or less, 0.15% or less, 0.10% or less, or 0.08% or less.

[V:0~0.300%]
 Vは、析出強化等により強度の向上に寄与する元素である。V含有量は0%であってもよいが、このような効果を得るためには、V含有量は0.001%以上であることが好ましい。V含有量は0.010%以上、0.030%以上又は0.050%以上であってもよい。一方で、Vを過度に含有しても効果が飽和し、製造コストの上昇を招く虞がある。したがって、V含有量は0.300%以下であることが好ましい。V含有量は0.200%以下、0.100%以下又は0.080%以下であってもよい。
[V: 0-0.300%]
V is an element that contributes to improving strength by precipitation strengthening, etc. The V content may be 0%, but in order to obtain such an effect, the V content is preferably 0.001% or more. The V content may be 0.010% or more, 0.030% or more, or 0.050% or more. On the other hand, even if V is contained excessively, the effect is saturated and there is a risk of increasing the manufacturing cost. Therefore, the V content is preferably 0.300% or less. The V content may be 0.200% or less, 0.100% or less, or 0.080% or less.

[Sn:0~0.040%、As:0~0.100%、Zr:0~0.050%、Ca:0~0.0010%、Mg:0~0.0010%、Bi:0~0.010%、Co:0~0.010%、W:0~0.100%、Zn:0~0.010%、及びREM:0~0.0100%]
 Sn、As、Zr、Ca、Mg、Bi、Co、W、Zn、及びREMは、任意選択元素として鋼板中に含有されていてもよく、又はトランプエレメントとして鋼板中に存在する場合がある。これらの元素の含有量は、Sn:0~0.040%又は0.020%、As:0~0.100%又は0.050%、Zr:0~0.050%又は0.030%、Ca:0~0.0010%又は0.0008%、Mg:0~0.0010%又は0.0008%、Bi:0~0.010%、Co:0~0.010%、W:0~0.100%又は0.050%、Zn:0~0.010%、及びREM:0~0.0100%又は0.0050%であってもよい。これらの元素の下限値については、例えば、Sn、As、Zr、Bi、Co、W及びZn含有量はそれぞれ0.001%以上、0.005%以上又は0.008%以上であってもよい。同様に、Ca、Mg及びREM含有量は0.0001%以上、0.0002%以上又は0.0005%以上であってもよい。
[Sn: 0 to 0.040%, As: 0 to 0.100%, Zr: 0 to 0.050%, Ca: 0 to 0.0010%, Mg: 0 to 0.0010%, Bi: 0-0.010%, Co: 0-0.010%, W: 0-0.100%, Zn: 0-0.010%, and REM: 0-0.0100%]
Sn, As, Zr, Ca, Mg, Bi, Co, W, Zn, and REM may be contained in the steel sheet as optional elements or may be present in the steel sheet as tramp elements. The contents of these elements may be as follows: Sn: 0-0.040% or 0.020%, As: 0-0.100% or 0.050%, Zr: 0-0.050% or 0.030%, Ca: 0-0.0010% or 0.0008%, Mg: 0-0.0010% or 0.0008%, Bi: 0-0.010%, Co: 0-0.010%, W: 0-0.100% or 0.050%, Zn: 0-0.010%, and REM: 0-0.0100% or 0.0050%. Regarding the lower limit of these elements, for example, the Sn, As, Zr, Bi, Co, W and Zn contents may be 0.001% or more, 0.005% or more, or 0.008% or more, respectively. Similarly, the Ca, Mg and REM contents may be 0.0001% or more, 0.0002% or more, or 0.0005% or more.

 本発明の実施形態に係る鋼板において、上記の元素以外の残部は、Fe及び不純物からなる。不純物とは、鋼板を工業的に製造する際に、鉱石やスクラップ等のような原料を始めとして、製造工程の種々の要因によって混入する成分等である。 In the steel plate according to the embodiment of the present invention, the remainder other than the above elements consists of Fe and impurities. Impurities are components that are mixed in due to various factors in the manufacturing process, including raw materials such as ores and scraps, when the steel plate is industrially manufactured.

 本発明の実施形態に係る鋼板の化学組成は、一般的な分析方法によって測定すればよい。例えば、当該鋼板の化学組成は、誘導結合プラズマ発光分光分析(ICP-AES:Inductively Coupled Plasma-Atomic Emission Spectrometry)を用いて測定すればよい。C及びSは燃焼-赤外線吸収法を用い、Nは不活性ガス融解-熱伝導度法を用い、Oは不活性ガス融解-非分散型赤外線吸収法を用いて測定すればよい。 The chemical composition of the steel plate according to the embodiment of the present invention may be measured by a general analytical method. For example, the chemical composition of the steel plate may be measured using inductively coupled plasma atomic emission spectrometry (ICP-AES). C and S may be measured using the combustion-infrared absorption method, N may be measured using the inert gas fusion-thermal conductivity method, and O may be measured using the inert gas fusion-non-dispersive infrared absorption method.

[金属組織]
[フェライト:10~40%]
 本発明の実施形態に係る鋼板の金属組織は、面積%で、フェライト:10~40%を含む。軟質組織であるフェライトを面積%で10%以上含むことで所望の均一伸びを達成することができる。均一伸びをさらに改善する観点からは、フェライトの面積率は高いほど好ましく、例えば12%以上、15%以上、18%以上、20%以上、22%以上又は25%以上であってもよい。一方で、フェライトの面積率が高くなりすぎると、強度及び/又は降伏比が低下したり、Ti析出物に起因する析出強化によってもフェライトとマルテンサイトとの硬度差を十分に低減することができず、穴広げ性が低下したりする場合がある。したがって、フェライトの面積率は40%以下とする。強度、降伏比及び/又は穴広げ性をより高める観点からは、フェライトの面積率は低いほど好ましく、例えば38%以下、35%以下、32%以下、30%以下、28%以下又は26%以下であってもよい。
[Metal structure]
[Ferrite: 10-40%]
The metal structure of the steel plate according to the embodiment of the present invention contains ferrite: 10 to 40% in area%. The desired uniform elongation can be achieved by containing 10% or more of ferrite, which is a soft structure, in area%. From the viewpoint of further improving the uniform elongation, the higher the area ratio of ferrite, the more preferable, for example, 12% or more, 15% or more, 18% or more, 20% or more, 22% or more, or 25% or more. On the other hand, if the area ratio of ferrite becomes too high, the strength and/or yield ratio may decrease, or the hardness difference between ferrite and martensite may not be sufficiently reduced even by precipitation strengthening due to Ti precipitates, and the hole expandability may decrease. Therefore, the area ratio of ferrite is set to 40% or less. From the viewpoint of further increasing the strength, yield ratio, and/or hole expandability, the lower the area ratio of ferrite, the more preferable, for example, 38% or less, 35% or less, 32% or less, 30% or less, 28% or less, or 26% or less.

[マルテンサイト:60~90%]
 本発明の実施形態に係る鋼板の金属組織は、面積%で、マルテンサイト:60~90%を含む。鋼板の金属組織を硬質のマルテンサイトをこのような範囲内で含む組織によって構成することで、高強度、例えば引張強さが1180MPa以上の高強度を達成することができる。さらなる高強度化の観点からは、マルテンサイトの面積率は高いほど好ましく、例えば65%以上、68%以上、70%以上、72%以上又は75%以上であってもよい。一方で、マルテンサイトの面積率が高くなりすぎると、均一伸びが低下する場合がある。したがって、マルテンサイトの面積率は90%以下とし、例えば88%以下、85%以下、82%以下、80%以下又は78%以下であってもよい。本発明において、「マルテンサイト」とは、焼入れままマルテンサイト(いわゆるフレッシュマルテンサイト)だけでなく、焼戻しマルテンサイトをも包含するものである。
[Martensite: 60-90%]
The metal structure of the steel plate according to the embodiment of the present invention contains, in terms of area%, 60 to 90% martensite. By configuring the metal structure of the steel plate with a structure containing hard martensite within such a range, high strength, for example, high strength with a tensile strength of 1180 MPa or more, can be achieved. From the viewpoint of further increasing strength, the higher the area ratio of martensite, the more preferable it is, and for example, it may be 65% or more, 68% or more, 70% or more, 72% or more, or 75% or more. On the other hand, if the area ratio of martensite becomes too high, uniform elongation may decrease. Therefore, the area ratio of martensite is 90% or less, and may be, for example, 88% or less, 85% or less, 82% or less, 80% or less, or 78% or less. In the present invention, "martensite" includes not only as-quenched martensite (so-called fresh martensite) but also tempered martensite.

[ベイナイト:0~10%]
 本発明の実施形態に係る鋼板の金属組織は、ベイナイトを含んでいてもよい。しかしながら、ベイナイトの面積率が高くなりすぎると、均一伸びが低下する場合がある。したがって、ベイナイトの面積率は10%以下とし、例えば9%以下、8%以下、6%以下、5%以下又は3%以下であってもよい。一方で、下限は特に限定されず、ベイナイトの面積率は0%であってもよく、例えば0.5%以上、1%以上又は2%以上であってもよい。
[Bainite: 0 to 10%]
The metal structure of the steel plate according to the embodiment of the present invention may contain bainite. However, if the area ratio of bainite is too high, the uniform elongation may decrease. Therefore, the area ratio of bainite is set to 10% or less, and may be, for example, 9% or less, 8% or less, 6% or less, 5% or less, or 3% or less. On the other hand, the lower limit is not particularly limited, and the area ratio of bainite may be 0%, and may be, for example, 0.5% or more, 1% or more, or 2% or more.

[残部組織]
 フェライト、マルテンサイト及びベイナイト以外の残部組織は、面積%で0%であってもよいが、残部組織が存在する場合には、当該残部組織は、パーライト及び残留オーステナイトの少なくとも1種であってよい。パーライト及び残留オーステナイトの少なくとも1種の面積率が合計で5%を超えると、均一伸びなどの低下を招いたり、フェライト及び/又はマルテンサイトを所望の範囲内に制御することができなくなったりする場合がある。したがって、パーライト及び残留オーステナイトの少なくとも1種の合計の面積率は5%以下とし、例えば4%以下、3%以下又は2%以下であってもよい。一方で、下限は特に限定されず、パーライト及び残留オーステナイトの少なくとも1種の合計の面積率は0%であってもよく、例えば0.1%以上、0.5%以上又は1%以上であってもよい。
[Remaining organization]
The remaining structure other than ferrite, martensite, and bainite may be 0% in terms of area percent, but if a remaining structure exists, the remaining structure may be at least one of pearlite and retained austenite. If the area ratio of at least one of pearlite and retained austenite exceeds 5% in total, it may lead to a decrease in uniform elongation, or it may become impossible to control ferrite and/or martensite within a desired range. Therefore, the total area ratio of at least one of pearlite and retained austenite is 5% or less, and may be, for example, 4% or less, 3% or less, or 2% or less. On the other hand, the lower limit is not particularly limited, and the total area ratio of at least one of pearlite and retained austenite may be 0%, for example, 0.1% or more, 0.5% or more, or 1% or more.

[金属組織の同定及び面積率の算出]
 次に、金属の同定及び面積率の算出について説明する。組織観察は、板面に垂直な方向の板厚断面に対して行われる。板厚断面は圧延方向に平行であることが好ましいものの、鋼板の圧延方向を特定できない場合などには、板厚断面は必ずしも圧延方向に平行である必要はない。具体的には、まず、鋼板から試験片を採取し、試験片の断面を#600から#1500の炭化珪素ペーパーを使用して研磨し、次いで粒度1~6μmのダイヤモンドパウダーをアルコール等の希釈液又は純水に分散させた液体を使用して鏡面に仕上げる。次に、この断面を室温においてアルカリ性溶液を含まない粒径0.25μmのコロイダルシリカを用いて8分間研磨し、試験片の表層に導入されたひずみを除去する。次いで、鋼表面から板厚の1/4位置を中心に板厚方向に150μm、板厚方向と垂直な方向に150μmの矩形領域に対して、0.1μmの測定間隔で電子後方散乱回折法により測定して結晶方位情報を得る。
[Identification of metal structure and calculation of area ratio]
Next, the identification of metals and the calculation of the area ratio will be described. The structure observation is performed on the plate thickness cross section in the direction perpendicular to the plate surface. Although the plate thickness cross section is preferably parallel to the rolling direction, in cases where the rolling direction of the steel plate cannot be specified, the plate thickness cross section does not necessarily need to be parallel to the rolling direction. Specifically, first, a test piece is taken from the steel plate, and the cross section of the test piece is polished using silicon carbide paper of #600 to #1500, and then finished to a mirror surface using a dilution solution such as alcohol or a liquid in which diamond powder with a grain size of 1 to 6 μm is dispersed in pure water. Next, this cross section is polished for 8 minutes at room temperature using colloidal silica with a grain size of 0.25 μm that does not contain an alkaline solution, to remove the strain introduced into the surface layer of the test piece. Next, a rectangular area of 150 μm in the plate thickness direction and 150 μm in the direction perpendicular to the plate thickness direction, centered at 1/4 of the plate thickness position from the steel surface, is measured by electron backscatter diffraction at measurement intervals of 0.1 μm to obtain crystal orientation information.

 測定には、サーマル電界放射型走査電子顕微鏡(JEOL製JSM-7001F)とEBSD検出器(TSL製DVC5型検出器)とで構成されたEBSD装置を用いることが好ましい。この際、EBSD装置内の真空度は9.6×10-5Pa以下、加速電圧は15kV、照射電流レベルは13、電子線の照射レベルは62とすることが好ましく、その他の観察条件は以下の通りとすることが好ましい。
 電子銃種:ショットキー
 WD(ワーキングディスタンス):15mm
 対物絞り番号:4
 ピクセル数:4096×5120 pix
For the measurement, it is preferable to use an EBSD device consisting of a thermal field emission scanning electron microscope (JSM-7001F manufactured by JEOL) and an EBSD detector (DVC5 type detector manufactured by TSL). In this case, it is preferable that the degree of vacuum in the EBSD device is 9.6×10 −5 Pa or less, the acceleration voltage is 15 kV, the irradiation current level is 13, and the electron beam irradiation level is 62, and other observation conditions are preferably as follows.
Electron gun type: Schottky WD (working distance): 15 mm
Objective aperture number: 4
Number of pixels: 4096 x 5120 pixels

[残留オーステナイトの同定及び面積率の算出]
 得られた結晶方位情報から、EBSD解析装置に付属のソフトウェア「OIM Analysis(登録商標)」に搭載された「Phase Map」機能を用いて、結晶構造がfccである領域を特定し、この領域の面積率を算出する。これにより、残留オーステナイトの面積率を得る。
[Identification of retained austenite and calculation of area ratio]
From the obtained crystal orientation information, the "Phase Map" function installed in the software "OIM Analysis (registered trademark)" attached to the EBSD analyzer is used to identify the region having the fcc crystal structure, and the area ratio of this region is calculated, thereby obtaining the area ratio of the retained austenite.

[フェライトの同定及び面積率の算出]
 次に、結晶構造がbccであるものを「フェライト、マルテンサイト、ベイナイト及びパーライト」と判断する。これらの領域について、EBSD解析装置に付属のソフトウェア「OIM Analysis(登録商標)」を用いて、粒内の方位差(GAM値:Grain Average Misorientation)を算出する。最後に、GAM値が0.5°以下の領域をフェライトと同定し、その面積率を算出する。ここで、「GAM値」とは、方位差が15°以上の粒界で囲まれた領域において、隣接するピクセル間の方位差を平均した値である。
[Identification of ferrite and calculation of area ratio]
Next, the regions with a bcc crystal structure are judged to be "ferrite, martensite, bainite, and pearlite". For these regions, the grain average misorientation (GAM value: Grain Average Misorientation) is calculated using the software "OIM Analysis (registered trademark)" attached to the EBSD analyzer. Finally, the regions with a GAM value of 0.5° or less are identified as ferrite, and their area ratio is calculated. Here, the "GAM value" is the average misorientation between adjacent pixels in a region surrounded by grain boundaries with a misorientation of 15° or more.

[ベイナイトの同定及び面積率の算出]
 続いて、残部領域(「GAM値」が0.5°超の領域)の内、結晶方位差が15°の境界を結晶粒界とみなす条件下で、フェライト領域の「Grain Average IQ」の最大値をIαとしたとき、Iα/2超となる領域を「ベイナイト」、Iα/2以下となる領域を「マルテンサイト及びパーライト」として抽出する。抽出したベイナイトの面積率を算出することで、ベイナイトの面積率を得る。
[Identification of bainite and calculation of area ratio]
Next, in the remaining region (region with a "GAM value" exceeding 0.5°), under the condition that the boundary with a crystal orientation difference of 15° is regarded as a grain boundary, when the maximum value of the "Grain Average IQ" of the ferrite region is Iα, the region exceeding Iα/2 is extracted as "bainite" and the region with Iα/2 or less is extracted as "martensite and pearlite." The area ratio of bainite is obtained by calculating the area ratio of the extracted bainite.

[パーライトの同定及び面積率の算出]
 パーライトの面積率の算出は、ナイタール試薬を用いた腐食後のFE-SEMによる二次電子像の観察によって行われる。EBSD測定領域と同領域に対して、FE-SEMによる二次電子像の観察を行うために、観察位置近傍にビッカース圧痕を打刻する。その後、観察面の組織を残して、表層のコンタミを研磨除去し、ナイタールエッチングする。次に、EBSD観察面と同一視野をFE-SEMにより例えば倍率800倍で観察する。FE-SEMを用いてEBSD測定領域と同領域、すなわち鋼板表面から板厚の1/4位置を中心に板厚方向に150μm、板厚方向と垂直な方向に150μmの矩形領域で得られた組織写真に対して画像解析を行うことにより、パーライトの面積率を算出する。ここで、板状のフェライトとFe系炭化物とが層状に重なっている組織をパーライトとみなす。
[Identification of pearlite and calculation of area ratio]
The pearlite area ratio is calculated by observing a secondary electron image by FE-SEM after corrosion using a Nital reagent. In order to observe a secondary electron image by FE-SEM in the same region as the EBSD measurement region, a Vickers indentation is stamped near the observation position. Then, the surface contamination is polished away, leaving the structure of the observation surface, and Nital etching is performed. Next, the same field of view as the EBSD observation surface is observed by FE-SEM at, for example, 800 times magnification. The pearlite area ratio is calculated by performing image analysis on a structure photograph obtained by using the FE-SEM in the same region as the EBSD measurement region, that is, a rectangular region 150 μm in the plate thickness direction and 150 μm in the direction perpendicular to the plate thickness direction, centered at a 1/4 position of the plate thickness from the steel plate surface. Here, a structure in which plate-shaped ferrite and Fe-based carbides are layered is regarded as pearlite.

[マルテンサイトの同定及び面積率の算出]
 マルテンサイトの面積率の算出は、得られた残留オーステナイトの面積率、フェライトの面積率、ベイナイトの面積率、及びパーライトの面積率を100%から差し引くことによって、マルテンサイトの面積率を算出する。マルテンサイト以外の金属組織を順次特定していき、最後に残った金属組織をマルテンサイトとみなす。
[Identification of martensite and calculation of area ratio]
The area ratio of martensite is calculated by subtracting the area ratios of the retained austenite, ferrite, bainite, and pearlite from 100%. Metal structures other than martensite are sequentially identified, and the last remaining metal structure is regarded as martensite.

[板厚方向に隣接する各分割領域におけるフェライトの個数密度の差:全てNαm×0.60以下]
 本発明の実施形態に係る鋼板においては、板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差、より詳しくは板厚方向に隣接する各分割領域におけるフェライトの個数密度の差の絶対値が全てNαm×0.60以下に制御される。鋼板の板厚方向においてフェライトをこのように均一に配置することで、単軸引張試験における均一伸び以降の加工軟化率の絶対値を確実に250000MPa以下に低減することができ、それによって衝突時の荷重低下を抑制することが可能となる。その結果として、本発明の実施形態に係る鋼板を、自動車部品、とりわけ自動車の足回り部品、例えばロアアームやトレーリングアーム等の複雑な形状を有する自動車の足回り部品に成形した場合においても、衝突時の破断の発生を顕著に抑制することが可能となる。
[Difference in number density of ferrite in adjacent divided regions in the plate thickness direction: all Nαm×0.60 or less]
In the steel plate according to the embodiment of the present invention, when a 150 μm×150 μm region at the 1/4 position of the plate thickness in a cross section perpendicular to the plate surface is divided into nine equal parts, the number density of ferrite is calculated in each divided region, and the average value of the ferrite is taken as Nαm, the difference in the number density of ferrite in each divided region adjacent to each other in the plate thickness direction, more specifically, the absolute value of the difference in the number density of ferrite in each divided region adjacent to each other in the plate thickness direction is all controlled to be Nαm×0.60 or less. By uniformly disposing the ferrite in the plate thickness direction of the steel plate in this manner, the absolute value of the work softening rate after uniform elongation in the uniaxial tensile test can be reliably reduced to 250,000 MPa or less, thereby making it possible to suppress the load reduction during a collision. As a result, even when the steel plate according to the embodiment of the present invention is formed into an automobile part, particularly an automobile suspension part, such as a lower arm or a trailing arm having a complex shape, it is possible to significantly suppress the occurrence of fracture during a collision.

 衝突時の荷重低下をさらに抑制する観点からは、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差は小さいほど好ましい。例えば、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差は全てNαm×0.55以下、Nαm×0.50以下、Nαm×0.50以下、Nαm×0.45以下、Nαm×0.40以下、Nαm×0.35以下、又はNαm×0.30以下であってもよい。下限は特に限定されないが、例えば、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差は全てNαm×0.03以上、Nαm×0.05以上、Nαm×0.08以上、又はNαm×0.10以上であってもよい。 From the viewpoint of further suppressing load reduction during a collision, it is preferable that the difference in number density of ferrite in each divided region adjacent in the plate thickness direction is as small as possible. For example, the difference in number density of ferrite in each divided region adjacent in the plate thickness direction may all be Nαm×0.55 or less, Nαm×0.50 or less, Nαm×0.50 or less, Nαm×0.45 or less, Nαm×0.40 or less, Nαm×0.35 or less, or Nαm×0.30 or less. There is no particular lower limit, but for example, the difference in number density of ferrite in each divided region adjacent in the plate thickness direction may all be Nαm×0.03 or more, Nαm×0.05 or more, Nαm×0.08 or more, or Nαm×0.10 or more.

[Nαm:0.050個/μm2以上]
 本発明の好ましい実施形態によれば、Nαmは0.050個/μm2以上である。本発明の実施形態に係る鋼板においては、上記のように、鋼板の板厚方向においてフェライトを均一に配置することが重要であり、フェライトの配置の均一性を高める観点からは、フェライト粒は微細化することが好ましい。フェライト粒を微細化すると、当然ながらフェライトの個数密度は高くなる。したがって、フェライトの個数密度を高くすることで、結果的に板厚方向に隣接する各分割領域におけるフェライトの個数密度の差を低減して、衝突時の荷重低下を抑制する方向に作用することとなる。このような効果をより顕著にする観点からは、Nαmは高いほど好ましく、例えば0.055個/μm2以上、0.060個/μm2以上、0.065個/μm2以上、0.070個/μm2以上、0.075個/μm2以上又は0.080個/μm2以上であってもよい。上限は特に限定されないが、例えば、Nαmは0.200個/μm2以下、0.150個/μm2以下又は0.120個/μm2以下であってもよい。
[Nαm: 0.050 pieces/μm 2 or more]
According to a preferred embodiment of the present invention, Nαm is 0.050 pieces/μm 2 or more. In the steel plate according to the embodiment of the present invention, as described above, it is important to uniformly arrange ferrite in the plate thickness direction of the steel plate, and from the viewpoint of increasing the uniformity of the arrangement of ferrite, it is preferable to make the ferrite grains finer. When the ferrite grains are made finer, the number density of ferrite naturally increases. Therefore, by increasing the number density of ferrite, the difference in the number density of ferrite in each divided region adjacent to each other in the plate thickness direction is reduced, and the load reduction at the time of collision is suppressed. From the viewpoint of making such an effect more remarkable, the higher Nαm is preferable, and may be, for example, 0.055 pieces/μm 2 or more, 0.060 pieces/μm 2 or more, 0.065 pieces/μm 2 or more, 0.070 pieces/μm 2 or more, 0.075 pieces/μm 2 or more, or 0.080 pieces/μm 2 or more. The upper limit is not particularly limited, but may be, for example, 0.200 particles/μm 2 or less, 0.150 particles/μm 2 or less, or 0.120 particles/μm 2 or less.

[Nαm及び各分割領域におけるフェライトの個数密度の測定]
 Nαm及び各分割領域におけるフェライトの個数密度の測定は、フェライトの同定及び面積率の算出の場合と同様にEBSDにより以下のようにして行われる。具体的には、まず、板面に垂直な方向の板厚断面が観察面となるように鋼板から試料を採取する。板厚断面は圧延方向に平行であることが好ましいものの、鋼板の圧延方向を特定できない場合などには、板厚断面は必ずしも圧延方向に平行である必要はない。次いで、鋼板表面から板厚の1/4位置を中心に板厚方向に150μm、板厚方向と垂直な方向に150μmの矩形領域に対して0.1μmの測定間隔でEBSD解析して、この矩形領域の結晶方位情報を得る。EBSD解析は、サーマル電界放射型走査電子顕微鏡(JEOL製JSM-7001F)とEBSD検出器(TSL製HIKARI検出器)で構成された装置を用い、50~300点/秒の解析速度で実施する。次に、この矩形領域の結晶方位情報から、EBSD解析装置に付属のソフトウェア「OIM Analysis(登録商標)」を用いて、粒内の方位差(GAM値)を算出する。次に、GAM値が0.5°以下の領域をフェライトと同定し、150μm×150μmの領域を均等に9分割した各分割領域でのフェライトの個数をカウントして個数密度Nα1~Nα9を算出し、それらの平均値をNαmとして決定する(図1(a)(i)及び(b)(i))。フェライトの個数密度は上記の測定条件において検出及び同定されるフェライトの個数を全てカウントすることにより算出される。カウントの際、複数の分割領域の境界上又は当該境界に跨がって複数の分割領域にフェライトが存在する場合には、そのフェライトについては当該複数の分割領域のそれぞれにおいてカウントすることとする。例えば、2つの分割領域A及びBの境界上又は当該境界に跨がって分割領域A及びBに1個のフェライトが存在する場合、当該1個のフェライトは分割領域A及びBの両方においてカウントすることとする。同様に、3つの分割領域A、B及びCの境界上又は当該境界に跨がって分割領域A、B及びCに1個のフェライトが存在する場合、当該1個のフェライトは分割領域A、B及びCのそれぞれにおいてカウントすることとする。最後に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差を算出し(図1(a)(ii)及び(b)(ii))、それらの個数密度の差をNαmで除した値が0.60以下の要件を満たすか否かを判断する(図1(a)(iii)及び(b)(iii))。
[Measurement of Nαm and number density of ferrite in each divided region]
The measurement of Nαm and the number density of ferrite in each divided region is performed by EBSD in the same manner as in the case of the identification of ferrite and the calculation of the area ratio, as follows. Specifically, first, a sample is taken from the steel plate so that the plate thickness cross section perpendicular to the plate surface is the observation surface. Although the plate thickness cross section is preferably parallel to the rolling direction, in cases where the rolling direction of the steel plate cannot be specified, the plate thickness cross section does not necessarily have to be parallel to the rolling direction. Next, EBSD analysis is performed at a measurement interval of 0.1 μm on a rectangular region of 150 μm in the plate thickness direction and 150 μm in the direction perpendicular to the plate thickness direction, centered on a 1/4 position of the plate thickness from the steel plate surface, to obtain crystal orientation information of this rectangular region. The EBSD analysis is performed at an analysis speed of 50 to 300 points/second using an apparatus consisting of a thermal field emission scanning electron microscope (JSM-7001F manufactured by JEOL) and an EBSD detector (HIKARI detector manufactured by TSL). Next, from the crystal orientation information of this rectangular region, the orientation difference (GAM value) within the grain is calculated using the software "OIM Analysis (registered trademark)" attached to the EBSD analysis device. Next, the region with a GAM value of 0.5° or less is identified as ferrite, and the number of ferrite particles in each of the divided regions into which the 150 μm×150 μm region is equally divided into 9 is counted to calculate the number density Nα1 to Nα9, and the average value thereof is determined as Nαm (FIGS. 1(a)(i) and (b)(i)). The number density of ferrite is calculated by counting all the number of ferrite particles detected and identified under the above measurement conditions. When counting, if ferrite exists on the boundary between multiple divided regions or in multiple divided regions across the boundary, the ferrite is counted in each of the multiple divided regions. For example, if one ferrite exists in the divided regions A and B on the boundary between the two divided regions A and B or across the boundary, the one ferrite is counted in both divided regions A and B. Similarly, if one ferrite exists in the divided regions A, B, and C on the boundary between the three divided regions A, B, and C or across the boundary, the one ferrite is counted in each of the divided regions A, B, and C. Finally, the difference in number density of ferrite in each divided region adjacent in the plate thickness direction is calculated (FIGS. 1(a)(ii) and (b)(ii)), and it is determined whether the value obtained by dividing the difference in number density by Nαm satisfies the requirement of 0.60 or less (FIGS. 1(a)(iii) and (b)(iii)).

[板厚]
 本発明の実施形態に係る鋼板は、特に限定されないが、一般的には1.0~8.0mmの板厚を有する。例えば、板厚は1.2mm以上、1.6mm以上若しくは2.0mm以上であってもよく、及び/又は7.0mm以下、6.0mm以下、5.5mm以下、5.0mm以下、4.4mm以下、4.2mm以下若しくは4.0mm以下であってもよい。
[Thickness]
The steel sheet according to the embodiment of the present invention generally has a sheet thickness of 1.0 to 8.0 mm, although it is not particularly limited thereto. For example, the sheet thickness may be 1.2 mm or more, 1.6 mm or more, or 2.0 mm or more, and/or 7.0 mm or less, 6.0 mm or less, 5.5 mm or less, 5.0 mm or less, 4.4 mm or less, 4.2 mm or less, or 4.0 mm or less.

 本発明の実施形態に係る鋼板は、上記のとおり、高強度であるにもかかわらず、高い均一伸び、穴広げ性及び降伏比を有するとともに、衝突時の荷重低下を伴う破断の発生を顕著に抑制することができ、とりわけ複雑な形状を有する部品を成形した場合においても衝突時の荷重低下を伴う破断の発生を抑制することが可能である。したがって、本発明の実施形態に係る鋼板は、高強度と優れた加工性の相反する特性を高いレベルで確実に両立させるとともに、優れた耐衝撃性を達成することができる。それゆえ、本発明の実施形態に係る鋼板は、これらの特性が求められる技術分野の部品などにおいて使用するのに有用であり、自動車分野の使用において特に有用である。好ましい実施形態においては、本発明の実施形態に係る鋼板を含む自動車部品、特には自動車の足回り部品が提供される。自動車の足回り部品の一例としては、ロアアームやトレーリングアーム等が挙げられる。これらの自動車部品、特には自動車の足回り部品は、これらの部品の少なくとも一部において本発明の実施形態に係る鋼板を含んでいればよく、それゆえこれらの部品の少なくとも一部において先に述べた化学組成及び金属組織の特徴を満たすものである。プレス成形等の成形において金型と直接接触せず、加工の程度も比較的低い鋼板の部位では、金属組織の特徴は成形前後において特に変化しない。 As described above, the steel plate according to the embodiment of the present invention has high uniform elongation, hole expandability and yield ratio despite its high strength, and can significantly suppress the occurrence of fracture accompanied by load reduction during collision, and in particular, it is possible to suppress the occurrence of fracture accompanied by load reduction during collision even when forming a part having a complex shape. Therefore, the steel plate according to the embodiment of the present invention can reliably achieve a high level of the contradictory properties of high strength and excellent workability, and can achieve excellent impact resistance. Therefore, the steel plate according to the embodiment of the present invention is useful for use in parts in technical fields where these properties are required, and is particularly useful in the automotive field. In a preferred embodiment, an automotive part, particularly an automotive suspension part, is provided that includes the steel plate according to the embodiment of the present invention. Examples of automotive suspension parts include lower arms and trailing arms. These automotive parts, particularly automotive suspension parts, only need to include the steel plate according to the embodiment of the present invention in at least a part of these parts, and therefore at least a part of these parts satisfy the above-mentioned chemical composition and metal structure characteristics. In areas of steel sheets that do not come into direct contact with the die during press forming or other forming processes and that are relatively lightly processed, the characteristics of the metal structure do not change significantly before and after forming.

[機械特性]
[引張強さ(TS)及び均一伸び(uEl)]
 上記の化学組成及び金属組織を有する鋼板によれば、高い引張強さ、具体的には1180MPa以上の引張強さを達成することができる。引張強さは、好ましくは1200MPa以上、1220MPa以上又は1240MPa以上である。本発明の実施形態に係る鋼板によれば、このような非常に高い引張強さを有するにもかかわらず、上で説明した化学組成と金属組織の特定の組み合わせにより、均一伸び及び穴広げ性を改善しつつ、衝突時の荷重低下を顕著に抑制することができる。引張強さの上限は特に限定されないが、例えば、鋼板の引張強さは1780MPa以下、1470MPa以下、1400MPa以下又は1300MPa以下であってもよい。また、本発明の実施形態に係る鋼板によれば、高い均一伸びを達成することができ、具体的には5.0%以上の均一伸びを達成することができる。均一伸びは、好ましくは5.2%以上、5.5%以上、5.8%以上又は6.0%以上である。均一伸びの上限は特に限定されないが、例えば、鋼板の均一伸びは15.0%以下、10.0%以下、8.0%以下又は7.0%以下であってもよい。引張強さ及び均一伸びは、試験片の長手方向が好ましくは鋼板の圧延直角方向と平行になる向き(C方向)からJIS5号試験片を採取し、JIS Z 2241:2022に準拠した引張試験を行うことで測定される。鋼板の圧延方向を特定できない場合には、鋼板の板面内における任意の方向からJIS5号試験片を採取してもよい。
[Mechanical properties]
[Tensile strength (TS) and uniform elongation (uEl)]
According to the steel plate having the above chemical composition and metal structure, a high tensile strength, specifically a tensile strength of 1180 MPa or more can be achieved. The tensile strength is preferably 1200 MPa or more, 1220 MPa or more, or 1240 MPa or more. According to the steel plate according to the embodiment of the present invention, despite having such a very high tensile strength, the specific combination of the chemical composition and metal structure described above can significantly suppress the load drop during collision while improving the uniform elongation and hole expandability. The upper limit of the tensile strength is not particularly limited, but for example, the tensile strength of the steel plate may be 1780 MPa or less, 1470 MPa or less, 1400 MPa or less, or 1300 MPa or less. In addition, according to the steel plate according to the embodiment of the present invention, a high uniform elongation can be achieved, specifically a uniform elongation of 5.0% or more can be achieved. The uniform elongation is preferably 5.2% or more, 5.5% or more, 5.8% or more, or 6.0% or more. The upper limit of the uniform elongation is not particularly limited, but for example, the uniform elongation of the steel sheet may be 15.0% or less, 10.0% or less, 8.0% or less, or 7.0% or less. The tensile strength and uniform elongation are measured by taking a JIS No. 5 test piece from a direction in which the longitudinal direction of the test piece is preferably parallel to the rolling direction perpendicular to the rolling direction of the steel sheet (C direction) and performing a tensile test in accordance with JIS Z 2241:2022. When the rolling direction of the steel sheet cannot be specified, the JIS No. 5 test piece may be taken from any direction within the surface of the steel sheet.

[穴広げ率(λ)]
 上記の化学組成及び金属組織を有する鋼板によれば、高い穴広げ性、具体的には40%以上の穴広げ率を達成することができる。穴広げ率は、好ましくは42%以上、より好ましくは45%以上又は50%以上であってもよい。穴広げ率の上限は特に限定されないが、例えば、穴広げ率は150%以下、100%以下又は70%以下であってもよい。穴広げ率は以下のようにして決定される。まず、鋼板から幅100mm×長さ100mmの試験片を採取し、ポンチ径:10mm及びダイス径:10.25~11.5mm(クリアランス12.5%)の打ち抜き工具を用いて打ち抜き穴(初期穴:穴径d0=10mm)を作製する。次いで、かえり(バリ)がダイ側となるようにし、頂角60°の円錐ポンチにて板厚を貫通する割れが発生するまで初期穴を押し広げ、割れ発生時の穴径d1mmを測定して、下記式にて各試験片の穴広げ率λ(%)を求める。この穴広げ試験を3回実施し、それらの平均値を穴広げ率λとして決定する。
   λ=100×{(d1-d0)/d0}
[Hole expansion ratio (λ)]
According to the steel plate having the above chemical composition and metal structure, high hole expandability, specifically, a hole expansion ratio of 40% or more can be achieved. The hole expansion ratio may be preferably 42% or more, more preferably 45% or more or 50% or more. The upper limit of the hole expansion ratio is not particularly limited, but for example, the hole expansion ratio may be 150% or less, 100% or less, or 70% or less. The hole expansion ratio is determined as follows. First, a test piece having a width of 100 mm and a length of 100 mm is taken from the steel plate, and a punch hole (initial hole: hole diameter d0 = 10 mm) is made using a punching tool with a punch diameter of 10 mm and a die diameter of 10.25 to 11.5 mm (clearance 12.5%). Next, the initial hole is expanded with a conical punch with an apex angle of 60° until a crack penetrating the plate thickness occurs, and the hole diameter d1 mm at the time of crack occurrence is measured, and the hole expansion ratio λ (%) of each test piece is calculated by the following formula. This hole expanding test is carried out three times, and the average value thereof is determined as the hole expanding ratio λ.
λ=100×{(d1-d0)/d0}

[降伏比(YR)]
 上記の化学組成及び金属組織を有する鋼板によれば、高い引張強さに加えて、降伏比を高めることもでき、より具体的には75%以上の降伏比を達成することができる。降伏比は、好ましくは78%以上又は80%以上、より好ましくは82%以上又は84%以上である。上限は特に限定されないが、例えば、降伏比は95%以下、92%以下、90%以下又は88%以下であってもよい。降伏比は、試験片の長手方向が好ましくは鋼板の圧延直角方向と平行になる向き(C方向)からJIS5号試験片を採取し、JIS Z 2241:2022に準拠した引張試験を行うことで測定した引張強さ及び0.2%耐力に基づき、下記式により決定される。鋼板の圧延方向を特定できない場合には、鋼板の板面内における任意の方向からJIS5号試験片を採取してもよい。
  降伏比YR=0.2%耐力/引張強さTS×100
[Yield ratio (YR)]
According to the steel plate having the above chemical composition and metal structure, in addition to high tensile strength, the yield ratio can be increased, and more specifically, a yield ratio of 75% or more can be achieved. The yield ratio is preferably 78% or more or 80% or more, more preferably 82% or more or 84% or more. The upper limit is not particularly limited, but for example, the yield ratio may be 95% or less, 92% or less, 90% or less, or 88% or less. The yield ratio is determined by the following formula based on the tensile strength and 0.2% proof stress measured by taking a JIS No. 5 test piece from a direction (C direction) in which the longitudinal direction of the test piece is preferably parallel to the rolling perpendicular direction of the steel plate and performing a tensile test in accordance with JIS Z 2241:2022. When the rolling direction of the steel plate cannot be specified, the JIS No. 5 test piece may be taken from any direction in the plate plane of the steel plate.
Yield ratio YR = 0.2% yield strength / tensile strength TS x 100

<鋼板の製造方法>
 次に、本発明の実施形態に係る鋼板の好ましい製造方法について説明する。以下の説明は、本発明の実施形態に係る鋼板、特に好ましい特性を有する鋼板を製造するための特徴的な方法の例示を意図するものであって、当該鋼板を以下に説明するような製造方法によって製造されるものに限定することを意図するものではない。より具体的には、以下では、熱延鋼板の製造について具体的に示されるが、本発明の実施形態に係る鋼板は、上で説明した化学組成及び金属組織を有する任意の鋼板、すなわち熱延鋼板だけでなく、冷延鋼板、めっき鋼板等をも包含するものである。したがって、以下の記載は、本発明の実施形態に係る鋼板が熱延鋼板である場合の好ましい製造方法の一例を説明するものにすぎない。
<Method of manufacturing steel sheet>
Next, a preferred method for manufacturing the steel sheet according to the embodiment of the present invention will be described. The following description is intended to exemplify a characteristic method for manufacturing the steel sheet according to the embodiment of the present invention, particularly a steel sheet having preferred properties, and is not intended to limit the steel sheet to one manufactured by the manufacturing method described below. More specifically, the following will specifically show the manufacture of a hot-rolled steel sheet, but the steel sheet according to the embodiment of the present invention includes any steel sheet having the above-described chemical composition and metal structure, i.e., not only a hot-rolled steel sheet but also a cold-rolled steel sheet, a plated steel sheet, and the like. Therefore, the following description merely describes one example of a preferred manufacturing method when the steel sheet according to the embodiment of the present invention is a hot-rolled steel sheet.

 本発明の実施形態に係る鋼板の製造方法は、
 鋼板に関連して上で説明した化学組成を有するスラブを加熱し、1180~1350℃の温度で6000秒以上保持することを含む加熱工程、
 前記スラブを4基以上の圧延スタンドからなるタンデム圧延機を用いて仕上げ圧延することを含み、下記(a)~(c)の条件を満足する熱間圧延工程、
  (a)後段2段の直前2段の各圧延パスにおける圧延温度が960~1080℃であり、前記各圧延パスにおける圧下率が30~50%であること、
  (b)前記後段2段の直前2段の圧延パス後0.20秒以内に圧延材を800~910℃の冷却停止温度まで冷却すること、及び
  (c)後段2段の各圧延パスにおける圧下率が10~40%であること
 仕上げ圧延された鋼板を水冷し、水冷開始から4.0秒以内に600~750℃の温度域まで冷却し、次いで前記温度域にて2.0~8.0秒の空冷を実施し、空冷後13秒以内に前記鋼板を50℃以下まで水冷することを含む冷却工程
を含むことを特徴としている。上記の製造方法において、スラブ及び鋼板について記載する温度は、それぞれスラブの表面温度及び鋼板の表面温度をいうものである。以下、各工程について詳しく説明する。
The method for producing a steel sheet according to an embodiment of the present invention comprises:
A heating step comprising heating a slab having the chemical composition described above in relation to the steel plate and holding it at a temperature of 1180-1350°C for at least 6000 seconds;
A hot rolling process including finish rolling the slab using a tandem rolling mill having four or more rolling stands, the hot rolling process satisfying the following conditions (a) to (c):
(a) the rolling temperature in each of the rolling passes in the two stages immediately preceding the latter two stages is 960 to 1080°C, and the rolling reduction in each of the rolling passes is 30 to 50%;
(b) cooling the rolled material to a cooling stop temperature of 800 to 910 ° C. within 0.20 seconds after the rolling passes of the two stages immediately preceding the latter two stages, and (c) the rolling reduction in each rolling pass of the latter two stages is 10 to 40%. The method is characterized by including a cooling step including water-cooling the finish-rolled steel plate, cooling it to a temperature range of 600 to 750 ° C. within 4.0 seconds from the start of water cooling, then air-cooling in the temperature range for 2.0 to 8.0 seconds, and water-cooling the steel plate to 50 ° C. or less within 13 seconds after air-cooling. In the above manufacturing method, the temperatures described for the slab and steel plate refer to the surface temperature of the slab and the surface temperature of the steel plate, respectively. Each step will be described in detail below.

[加熱工程]
 まず、鋼板に関連して上で説明した化学組成を有するスラブが加熱され、1180~1350℃の温度域で6000秒以上保持される。スラブは、生産性の観点から連続鋳造により得られたスラブを使用することが好ましいが、鋳造・分塊により得られたスラブを使用することもでき、必要に応じてそれらに熱間加工又は冷間加工を加えたものを使用してもよい。本製造方法において、1180~1350℃の温度域での保持とは、スラブの温度が1180~1350℃の範囲内の一定の温度で保持する場合だけでなく、スラブの温度が1180~1350℃の範囲内で変動して保持する場合をも包含するものである。スラブを1180~1350℃の温度域で6000秒以上保持することで、組織内に存在する粗大な炭化物を完全に固溶させることができ、亀裂の起点をなくすことができる。保持温度が1180℃未満であるか又は保持時間が6000秒未満であると、粗大な炭化物の固溶が不完全となる。粗大な炭化物の固溶が不完全であると、後述する冷却工程にて、このような炭化物を起点としたフェライトやベイナイト変態が生じることでマルテンサイトの面積率が60%未満となり、結果として所望の強度を得ることができなくなる場合がある。スラブの加熱温度の上限は、加熱設備の能力や生産性の観点から1350℃以下とする。1180~1350℃の温度域での保持時間の上限は、好ましくは10000秒以下である。
[Heating process]
First, a slab having the chemical composition described above in relation to the steel plate is heated and held at a temperature range of 1180 to 1350 ° C for 6000 seconds or more. From the viewpoint of productivity, it is preferable to use a slab obtained by continuous casting, but a slab obtained by casting and blooming can also be used, and if necessary, a slab obtained by hot working or cold working may be used. In this manufacturing method, holding at a temperature range of 1180 to 1350 ° C includes not only the case where the temperature of the slab is held at a constant temperature within the range of 1180 to 1350 ° C, but also the case where the temperature of the slab is held while fluctuating within the range of 1180 to 1350 ° C. By holding the slab at a temperature range of 1180 to 1350 ° C for 6000 seconds or more, the coarse carbides present in the structure can be completely solid-dissolved, and the starting point of cracks can be eliminated. If the holding temperature is less than 1180 ° C or the holding time is less than 6000 seconds, the solid-dissolution of the coarse carbides is incomplete. If the solid solution of the coarse carbides is incomplete, the area ratio of martensite may become less than 60% due to the occurrence of ferrite or bainite transformation originating from such carbides in the cooling process described below, and as a result, the desired strength may not be obtained. The upper limit of the heating temperature of the slab is set to 1350°C or less from the viewpoint of the capacity and productivity of the heating equipment. The upper limit of the holding time in the temperature range of 1180 to 1350°C is preferably 10000 seconds or less.

[熱間圧延工程]
[粗圧延]
 本製造方法では、例えば、加熱されたスラブに対し、板厚調整等のために、仕上げ圧延の前に粗圧延を施してもよい。粗圧延は、所望のシートバー寸法が確保できればよく、その条件は特に限定されない。
[Hot rolling process]
[Rough rolling]
In the present manufacturing method, for example, the heated slab may be subjected to rough rolling before finish rolling in order to adjust the plate thickness, etc. The conditions of the rough rolling are not particularly limited as long as the desired sheet bar dimensions can be secured.

[仕上げ圧延]
[(a)後段2段の直前2段の各圧延パスにおける圧延温度:960~1080℃、及び直前2段の各圧延パスにおける圧下率:30~50%]
 加熱されたスラブ又はそれに加えて必要に応じて粗圧延されたスラブは、次に仕上げ圧延を施される。本製造方法では、仕上げ圧延は、4基以上の圧延スタンドからなるタンデム圧延機を用いて行われる。本製造方法では、加熱されたスラブに対して行われる仕上げ圧延において、後段2段の直前2段の各圧延パスにおける圧延温度及び圧下率を適切に制御する必要があり、具体的には後段2段の直前2段の各圧延パスにおける圧延温度が960~1080℃に制御され、同様に後段2段の直前2段の各圧延パスにおける圧下率が30~50%に制御される。ここで、例えば、7基の圧延スタンドからなるタンデム圧延機を使用する場合には、第6及び7番目の圧延パスが「後段2段の圧延パス」に該当する。したがって、この場合、「後段2段の直前2段の各圧延パス」とは、第4及び5番目の圧延パスをいうものである。後段2段の直前2段の各圧延パスにおける比較的高温の条件下で比較的高圧下の圧延を施すことで、再結晶を促進してオーステナイト粒を微細化することができる。これに関連して、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に所望のレベルで均一化することが可能となる。より詳しく説明すると、フェライトは主としてオーステナイト粒界から核生成する。このため、再結晶を促進してオーステナイト粒を微細化することでオーステナイト粒界の数を増加させてフェライトの核生成サイトを増やすことができる。その結果として、金属組織中でより多くのフェライトを均一に分散して生成させることができ、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に所望のレベルで均一化することが可能となる。
[Finish rolling]
[(a) Rolling temperature in each rolling pass of the two stages immediately preceding the last two stages: 960 to 1080° C., and rolling reduction in each rolling pass of the two stages immediately preceding the last two stages: 30 to 50%]
The heated slab or the slab that has been rough-rolled as necessary is then subjected to finish rolling. In this manufacturing method, the finish rolling is performed using a tandem rolling mill consisting of four or more rolling stands. In this manufacturing method, in the finish rolling performed on the heated slab, it is necessary to appropriately control the rolling temperature and the reduction ratio in each rolling pass of the two stages immediately preceding the last two stages, specifically, the rolling temperature in each rolling pass of the two stages immediately preceding the last two stages is controlled to 960 to 1080°C, and similarly, the reduction ratio in each rolling pass of the two stages immediately preceding the last two stages is controlled to 30 to 50%. Here, for example, when a tandem rolling mill consisting of seven rolling stands is used, the sixth and seventh rolling passes correspond to the "rolling passes of the last two stages". Therefore, in this case, the "rolling passes of the two stages immediately preceding the last two stages" refers to the fourth and fifth rolling passes. By performing rolling under relatively high pressure under relatively high temperature conditions in each of the rolling passes of the two stages immediately preceding the latter two stages, it is possible to promote recrystallization and refine the austenite grains. In relation to this, it is possible to uniformize the number density of ferrite in the plate thickness direction at a desired level in the finally obtained metal structure. To explain in more detail, ferrite mainly nucleates from austenite grain boundaries. Therefore, by promoting recrystallization and refining the austenite grains, it is possible to increase the number of austenite grain boundaries and increase the number of ferrite nucleation sites. As a result, it is possible to generate more ferrite in a uniformly dispersed manner in the metal structure, and it is possible to uniformize the number density of ferrite in the plate thickness direction at a desired level in the finally obtained metal structure.

 これに対し、後段2段の直前2段の各圧延パスにおける圧延温度が960℃未満であるか、及び/又は当該各圧延パスにおける圧下率が30%未満であると、再結晶が十分に促進されず、部分的に未再結晶粒が残ってしまい、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができなくなる。その結果として、均一伸び以降の加工軟化率が低下し、すなわち均一伸び以降の加工軟化が顕著となる。一方で、後段2段の直前2段の各圧延パスにおける圧下率が50%超であると、過度なひずみの導入に起因して扁平なオーステナイト粒が形成されてしまい、最終的に得られる金属組織において同様にフェライトの個数密度を板厚方向に十分に均一化することができなくなる。その結果として、同様に均一伸び以降の加工軟化が顕著となる。また、後段2段の直前2段の各圧延パスにおける圧延温度が1080℃を超えると、再結晶後のオーステナイト粒が粗大化し、オーステナイト粒界の数が減少してフェライトの核生成サイトが減少してしまう。その結果として、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができなくなり、同様に均一伸び以降の加工軟化が顕著となる。好ましくは、後段2段の直前2段の各圧延パスにおける圧延温度は1000~1060℃である。 On the other hand, if the rolling temperature in each of the rolling passes immediately before the last two stages is less than 960°C and/or the reduction ratio in each rolling pass is less than 30%, recrystallization is not sufficiently promoted, unrecrystallized grains remain partially, and the number density of ferrite cannot be sufficiently uniformed in the thickness direction in the finally obtained metal structure. As a result, the work softening rate after uniform elongation decreases, that is, the work softening after uniform elongation becomes noticeable. On the other hand, if the rolling reduction ratio in each of the rolling passes immediately before the last two stages exceeds 50%, flat austenite grains are formed due to the introduction of excessive strain, and the number density of ferrite cannot be sufficiently uniformed in the thickness direction in the finally obtained metal structure. As a result, the work softening after uniform elongation becomes noticeable. In addition, if the rolling temperature in each of the rolling passes immediately before the last two stages exceeds 1080°C, the austenite grains after recrystallization become coarse, the number of austenite grain boundaries decreases, and the ferrite nucleation sites decrease. As a result, the number density of ferrite in the final metal structure cannot be sufficiently uniform in the thickness direction, and similarly, work softening after uniform elongation becomes significant. Preferably, the rolling temperature in each of the rolling passes in the two stages immediately preceding the last two stages is 1000 to 1060°C.

[(b)後段2段の直前2段の圧延パス後0.20秒以内に800~910℃の冷却停止温度まで冷却]
 本製造方法においては、後段2段の直前2段の圧延パス後0.20秒以内に圧延材が800~910℃の冷却停止温度まで冷却される。後段2段の直前2段の圧延パス後、このように比較的早く800~910℃の冷却停止温度まで圧延材を冷却することで、再結晶後のオーステナイト粒の粒成長を抑制することができ、それによって最終的に得られる金属組織においてフェライトの個数密度を板厚方向に所望のレベルで均一化することが可能となる。後段2段の直前2段の圧延パス後800~910℃の冷却停止温度まで冷却する時間が0.20秒超であるか又は冷却停止温度が910℃よりも高いと、再結晶後のオーステナイト粒の粒成長を十分に抑制することできなくなり、その後の冷却工程において適切な冷却を施してもフェライトの個数密度を板厚方向において所望の範囲内に制御することができなくなる。一方で、冷却停止温度が800℃よりも低いと、最終的に得られる金属組織においてフェライトの過度な生成を招く場合がある。フェライトが過度に生成すると、強度が低下したり、Ti析出物に起因する析出強化によってもフェライトとマルテンサイトとの硬度差を十分に低減することができず、穴広げ性が低下したりする場合がある。
[(b) Cooling to a cooling stop temperature of 800 to 910 ° C. within 0.20 seconds after the rolling passes of the last two stages immediately before the last two stages]
In this manufacturing method, the rolled material is cooled to a cooling stop temperature of 800 to 910 ° C. within 0.20 seconds after the rolling pass of the two stages immediately before the latter two stages. By cooling the rolled material to a cooling stop temperature of 800 to 910 ° C. relatively quickly after the rolling pass of the two stages immediately before the latter two stages, the grain growth of the austenite grains after recrystallization can be suppressed, and the number density of ferrite in the finally obtained metal structure can be made uniform at a desired level in the plate thickness direction. If the time to cool to a cooling stop temperature of 800 to 910 ° C. after the rolling pass of the two stages immediately before the latter two stages exceeds 0.20 seconds or the cooling stop temperature is higher than 910 ° C., the grain growth of the austenite grains after recrystallization cannot be sufficiently suppressed, and even if appropriate cooling is performed in the subsequent cooling process, the number density of ferrite cannot be controlled within a desired range in the plate thickness direction. On the other hand, if the cooling stop temperature is lower than 800 ° C., excessive generation of ferrite may occur in the finally obtained metal structure. If excessive ferrite is formed, the strength may decrease, or the difference in hardness between ferrite and martensite may not be sufficiently reduced even by precipitation strengthening due to Ti precipitates, resulting in a decrease in hole expandability.

[(c)後段2段の各圧延パスにおける圧下率:10~40%]
 本製造方法においては、仕上げ圧延の後段2段の各圧延パスにおける圧下率が10~40%に制御される。後段2段の各圧延パスにおいてこのような適度な圧下率にてひずみを導入することで、その後の冷却工程におけるフェライト変態の駆動力を高めることが可能となる。後段2段の各圧延パスの圧下率が10%未満であると、その後の冷却工程におけるフェライト変態の駆動力を十分に高めることができず、最終的に得られる金属組織において所望のフェライト面積率を達成することができなくなる。その結果として、均一伸びが低下する。一方で、後段2段の各圧延パスの圧下率が40%を超えると、フェライト変態の駆動力が大きくなりすぎてしまい、最終的に得られる金属組織においてフェライトの過度な生成を招く場合がある。フェライトが過度に生成すると、強度が低下したり、Ti析出物に起因する析出強化によってもフェライトとマルテンサイトとの硬度差を十分に低減することができず、穴広げ性が低下したりする場合がある。好ましくは、仕上げ圧延の後段2段の各圧延パスにおける圧下率が15~38%である。
[(c) Reduction rate in each rolling pass in the latter two stages: 10 to 40%]
In this manufacturing method, the reduction rate in each rolling pass of the latter two stages of finish rolling is controlled to 10 to 40%. By introducing strain at such a moderate reduction rate in each rolling pass of the latter two stages, it is possible to increase the driving force of ferrite transformation in the subsequent cooling process. If the reduction rate of each rolling pass of the latter two stages is less than 10%, the driving force of ferrite transformation in the subsequent cooling process cannot be sufficiently increased, and the desired ferrite area ratio cannot be achieved in the finally obtained metal structure. As a result, the uniform elongation decreases. On the other hand, if the reduction rate of each rolling pass of the latter two stages exceeds 40%, the driving force of ferrite transformation becomes too large, which may lead to excessive generation of ferrite in the finally obtained metal structure. If ferrite is excessively generated, the strength may decrease, or the hardness difference between ferrite and martensite may not be sufficiently reduced even by precipitation strengthening due to Ti precipitates, and the hole expansion property may decrease. Preferably, the reduction rate in each rolling pass of the latter two stages of finish rolling is 15 to 38%.

[冷却工程]
[水冷開始から4.0秒以内に600~750℃の温度域まで冷却し、次いで2.0~8.0秒空冷]
 仕上げ圧延された鋼板は、次の冷却工程において水冷され、水冷開始から4.0秒以内に600~750℃の温度域まで冷却され、次いでこの温度域にて2.0~8.0秒間にわたり空冷される。まず、水冷開始から4.0秒以内に600~750℃の温度域まで冷却することで、とりわけパーライト及びベイナイトの生成を確実に抑制することができ、したがって最終的に得られる鋼板において所望の金属組織の面積分率を達成することが可能となる。これに対し、水冷開始から600~750℃の温度域までの時間が4.0秒を超えると、フェライトが比較的多く生成してしまい、その結果として強度及び/又は穴広げ性が低下する場合がある。
[Cooling process]
[Cool to a temperature range of 600 to 750 ° C. within 4.0 seconds from the start of water cooling, then air cool for 2.0 to 8.0 seconds]
The finish-rolled steel sheet is water-cooled in the next cooling step, cooled to a temperature range of 600 to 750 ° C. within 4.0 seconds from the start of water cooling, and then air-cooled in this temperature range for 2.0 to 8.0 seconds. First, by cooling to a temperature range of 600 to 750 ° C. within 4.0 seconds from the start of water cooling, it is possible to reliably suppress the generation of pearlite and bainite, and therefore it is possible to achieve the desired area fraction of the metal structure in the finally obtained steel sheet. On the other hand, if the time from the start of water cooling to the temperature range of 600 to 750 ° C. exceeds 4.0 seconds, a relatively large amount of ferrite is generated, which may result in a decrease in strength and/or hole expansibility.

 また、水冷後、600~750℃の温度域にて2.0~8.0秒間にわたり空冷することで、フェライトへの変態を促進させるとともに、Ti析出物を適切に析出させることができる。したがって、水冷後の600~750℃の温度域における2.0~8.0秒間の空冷操作は、フェライトの適切な生成だけでなく、Ti析出物に起因する析出強化による穴広げ性等の向上効果の観点でも重要である。例えば、空冷温度が600℃未満であると、フェライトへの変態を十分に促進させることができず、一方でベイナイトが比較的多く生成する場合がある。このような場合には、ベイナイトが多く生成することで均一伸びが低下し、さらにはベイナイトの生成に関連してマルテンサイトの生成が少なくなり、十分な強度が得られなくなることがある。 Furthermore, by air-cooling for 2.0 to 8.0 seconds in the temperature range of 600 to 750°C after water cooling, the transformation to ferrite can be promoted and Ti precipitates can be properly precipitated. Therefore, the air-cooling operation for 2.0 to 8.0 seconds in the temperature range of 600 to 750°C after water cooling is important not only for the proper generation of ferrite, but also from the viewpoint of the improvement effect of hole expandability due to precipitation strengthening caused by Ti precipitates. For example, if the air-cooling temperature is less than 600°C, the transformation to ferrite cannot be sufficiently promoted, while a relatively large amount of bainite may be generated. In such a case, the generation of a large amount of bainite reduces the uniform elongation, and further, the generation of martensite associated with the generation of bainite reduces the generation of sufficient strength, which may result in insufficient strength being obtained.

 また、空冷温度が750℃を超えるか又は空冷時間が2.0秒未満であると、同様に、フェライトへの変態を十分に促進させることができず、均一伸びが低下してしまう。一方で、空冷時間が8.0秒を超えると、フェライトが比較的多く生成する場合がある。このような場合には、強度が低下するとともに、Ti析出物に起因する析出強化によってもフェライトとマルテンサイトとの硬度差を十分に低減することができず、穴広げ性が低下する場合がある。空冷温度は、好ましくは620~730℃であり、空冷時間は、好ましくは3.0~6.0秒である。 Furthermore, if the air cooling temperature exceeds 750°C or the air cooling time is less than 2.0 seconds, the transformation to ferrite cannot be sufficiently promoted, and uniform elongation decreases. On the other hand, if the air cooling time exceeds 8.0 seconds, a relatively large amount of ferrite may be generated. In such cases, the strength decreases, and the precipitation strengthening caused by Ti precipitates cannot sufficiently reduce the hardness difference between ferrite and martensite, and the hole expansion ability may decrease. The air cooling temperature is preferably 620 to 730°C, and the air cooling time is preferably 3.0 to 6.0 seconds.

[空冷後13秒以内に50℃以下まで水冷]
 600~750℃の温度域における2.0~8.0秒間の空冷後すなわち空冷終了後、鋼板は13秒以内に50℃以下まで水冷される。このような急冷を施すことでマルテンサイトを所望の面積率の範囲内で生成させることができる。50℃以下までの水冷が13秒を超えるか又は冷却停止温度が50℃よりも高くなると、ベイナイトが比較的多く生成する場合がある。このような場合には、所望の均一伸びを達成することができなくなる。水冷時間の下限は特に限定されないが、例えば、空冷後50℃以下までの水冷時間は4秒以上又は5秒以上であってもよい。また、水冷停止温度の下限も特に限定されないが、例えば、水冷停止温度は20℃以上又は25℃以上であってもよい。水冷された鋼板は、最後に、熱延コイルの形態に巻き取ることができる。巻き取りの条件は特に限定されず、任意の適切な温度条件下、例えば室温等で実施することができる。
[Water-cool to 50°C or less within 13 seconds after air-cooling]
After air cooling for 2.0 to 8.0 seconds in the temperature range of 600 to 750 ° C., that is, after air cooling is completed, the steel sheet is water-cooled to 50 ° C. or less within 13 seconds. By performing such rapid cooling, martensite can be generated within the desired area ratio range. If the water cooling to 50 ° C. or less exceeds 13 seconds or the cooling stop temperature is higher than 50 ° C., a relatively large amount of bainite may be generated. In such a case, the desired uniform elongation cannot be achieved. The lower limit of the water cooling time is not particularly limited, but for example, the water cooling time to 50 ° C. or less after air cooling may be 4 seconds or more or 5 seconds or more. In addition, the lower limit of the water cooling stop temperature is not particularly limited, but for example, the water cooling stop temperature may be 20 ° C. or more or 25 ° C. or more. The water-cooled steel sheet can finally be wound into the form of a hot-rolled coil. The winding conditions are not particularly limited, and the winding can be performed under any appropriate temperature conditions, for example, at room temperature.

 上記の製造方法によって製造された鋼板によれば、金属組織を、面積%で、フェライト:10~40%及びマルテンサイト:60~90%を含む組織によって構成することで、高強度、例えば引張強さが1180MPa以上の高強度を達成しつつ、均一伸びを顕著に改善することができる。さらに、鋼中のTi含有量を0.070質量%以上に制御することで、Ti析出物によってフェライトの軟質組織を析出強化し、それによって降伏比を高めるとともに、金属組織におけるフェライトとマルテンサイトとの硬度差を低減することができ、それゆえ穴広げ性を顕著に向上させることが可能となる。加えて、鋼板の板厚方向においてフェライトの個数密度を所定の範囲内に均一化することにより衝突時の荷重低下を抑制することができる。したがって、上記の製造方法によって製造された鋼板は、高強度であるにもかかわらず、高い均一伸び、穴広げ性及び降伏比を有するとともに、衝突時の荷重低下を伴う破断の発生を顕著に抑制することができる。それゆえ、上記の製造方法によって製造された鋼板は、高強度と優れた加工性の相反する特性を高いレベルで確実に両立させるとともに、優れた耐衝撃性を実現することができるので、これらの特性が求められる自動車分野の使用において特に有用である。  With the steel plate manufactured by the above manufacturing method, the metal structure is composed of a structure containing, in terms of area percentage, 10-40% ferrite and 60-90% martensite, so that high strength, for example, high strength with a tensile strength of 1180 MPa or more, can be achieved while significantly improving uniform elongation. Furthermore, by controlling the Ti content in the steel to 0.070 mass% or more, the soft structure of ferrite is precipitation strengthened by Ti precipitates, thereby increasing the yield ratio and reducing the hardness difference between ferrite and martensite in the metal structure, and therefore it is possible to significantly improve the hole expandability. In addition, the number density of ferrite in the thickness direction of the steel plate is made uniform within a predetermined range, so that the load reduction during collision can be suppressed. Therefore, the steel plate manufactured by the above manufacturing method has high uniform elongation, hole expandability, and yield ratio despite its high strength, and can significantly suppress the occurrence of fracture accompanied by a load reduction during collision. Therefore, steel sheets manufactured by the above manufacturing method reliably achieve a high level of both the opposing properties of high strength and excellent workability, while also achieving excellent impact resistance, making them particularly useful in the automotive field where these properties are required.

 以下、実施例によって本発明をより詳細に説明するが、本発明はこれらの実施例に何ら限定されるものではない。 The present invention will be explained in more detail below with reference to examples, but the present invention is not limited to these examples in any way.

 以下の実施例では、本発明の実施形態に係る鋼板、特に熱延鋼板を種々の条件下で製造し、得られた鋼板の引張強さ(TS)、降伏比(YR)、均一伸び(uEl)、穴広げ率(λ)及び均一伸び以降の加工軟化率について調べた。 In the following examples, steel sheets according to the embodiments of the present invention, particularly hot-rolled steel sheets, were manufactured under various conditions, and the tensile strength (TS), yield ratio (YR), uniform elongation (uEl), hole expansion ratio (λ), and work softening rate after uniform elongation of the obtained steel sheets were investigated.

 まず、溶鋼を連続鋳造法にて鋳造して表1及び2に示す種々の化学組成を有するスラブを形成し、これらのスラブを1180~1350℃の温度に加熱して6000~10000秒の時間にわたり保持し、次いで熱間圧延を行った。熱間圧延は、粗圧延と仕上げ圧延を行うことにより実施した。より具体的には、粗圧延は全ての実施例及び比較例で同じ条件であり、仕上げ圧延は5基の圧延スタンドからなるタンデム圧延機を用いて表3に示す条件下で実施した。次に、仕上げ圧延された鋼板を、表3に示す条件下で水冷、空冷及び水冷を実施して巻き取り、2.4~3.4mmの板厚を有する鋼板を得た。 First, molten steel was cast by continuous casting to form slabs with various chemical compositions shown in Tables 1 and 2. These slabs were heated to a temperature of 1180 to 1350°C and held for a time of 6000 to 10000 seconds, and then hot-rolled. Hot rolling was performed by rough rolling and finish rolling. More specifically, the rough rolling conditions were the same in all examples and comparative examples, and the finish rolling was performed under the conditions shown in Table 3 using a tandem rolling mill consisting of five rolling stands. Next, the finish-rolled steel plate was water-cooled, air-cooled, and water-cooled under the conditions shown in Table 3, and then coiled to obtain a steel plate having a thickness of 2.4 to 3.4 mm.

 得られた鋼板の特性は以下の方法によって測定及び評価した。 The properties of the resulting steel plates were measured and evaluated using the following methods.

[引張強さ(TS)及び均一伸び(uEl)]
 引張強さ(TS)及び均一伸び(uEl)は、試験片の長手方向が鋼板の圧延直角方向と平行になる向き(C方向)からJIS5号試験片を採取し、JIS Z 2241:2022に準拠した引張試験を行うことで測定した。
[Tensile strength (TS) and uniform elongation (uEl)]
The tensile strength (TS) and uniform elongation (uEl) were measured by taking a JIS No. 5 test piece from a direction in which the longitudinal direction of the test piece was parallel to the rolling direction perpendicular to the rolling direction of the steel plate (C direction) and conducting a tensile test in accordance with JIS Z 2241:2022.

[穴広げ率(λ)]
 穴広げ率(λ)は以下のようにして決定した。まず、鋼板から幅100mm×長さ100mmの試験片を採取し、ポンチ径:10mm及びダイス径:10.25~11.5mm(クリアランス12.5%)の打ち抜き工具を用いて打ち抜き穴(初期穴:穴径d0=10mm)を作製した。次いで、かえり(バリ)がダイ側となるようにし、頂角60°の円錐ポンチにて板厚を貫通する割れが発生するまで初期穴を押し広げ、割れ発生時の穴径d1mmを測定して、下記式にて各試験片の穴広げ率λ(%)を求めた。この穴広げ試験を3回実施し、それらの平均値を穴広げ率λとして決定した。
   λ=100×{(d1-d0)/d0}
[Hole expansion ratio (λ)]
The hole expansion ratio (λ) was determined as follows. First, a test piece having a width of 100 mm and a length of 100 mm was taken from the steel plate, and a punching tool having a punch diameter of 10 mm and a die diameter of 10.25 to 11.5 mm (clearance 12.5%) was used to make a punched hole (initial hole: hole diameter d0 = 10 mm). Next, the burr was placed on the die side, and the initial hole was pushed out with a conical punch having an apex angle of 60 ° until a crack penetrating the plate thickness occurred, and the hole diameter d1 mm at the time of the crack occurrence was measured, and the hole expansion ratio λ (%) of each test piece was calculated using the following formula. This hole expansion test was performed three times, and the average value was determined as the hole expansion ratio λ.
λ=100×{(d1-d0)/d0}

[降伏比(YR)]
 降伏比(YR)は、試験片の長手方向が鋼板の圧延直角方向と平行になる向き(C方向)からJIS5号試験片を採取し、JIS Z 2241:2022に準拠した引張試験を行うことで測定した引張強さ(TS)及び0.2%耐力に基づき、下記式により決定した。
  降伏比YR=0.2%耐力/引張強さTS×100
[Yield ratio (YR)]
The yield ratio (YR) was determined by the following formula based on the tensile strength (TS) and 0.2% proof stress measured by taking a JIS No. 5 test piece from a direction (C direction) in which the longitudinal direction of the test piece was parallel to the rolling direction perpendicular to the steel plate and conducting a tensile test in accordance with JIS Z 2241:2022.
Yield ratio YR = 0.2% yield strength / tensile strength TS x 100

[均一伸び(uEl)以降の加工軟化率の絶対値]
 均一伸び(uEl)以降の加工軟化率の絶対値は以下のようにして決定した。まず、真応力(MPa)をσ、真ひずみをεとし、均一伸びのときの真応力を真ひずみで微分したdσ0/dε0を算出した。次いで、均一伸びから真ひずみ量で0.005増加したときのdσ1/dε1を算出し、最後にこれらをもとに|dσ0/dε0-dσ1/dε1|/0.005を算出し、得られた値を加工軟化率の絶対値(MPa)として決定した。
[Absolute value of work softening rate after uniform elongation (uEl)]
The absolute value of the work softening rate after uniform elongation (uEl) was determined as follows. First, true stress (MPa) was defined as σ, true strain as ε, and dσ0 / dε0 was calculated by differentiating the true stress at uniform elongation with true strain. Next, dσ1 /dε1 was calculated when the true strain increased by 0.005 from the uniform elongation, and finally, | dσ0 / dε0 - dσ1 / dε1 |/0.005 was calculated based on these, and the obtained value was determined as the absolute value of the work softening rate (MPa).

 鋼板の引張強さ(TS)が1180MPa以上であり、均一伸び(uEl)が5.0%以上であり、穴広げ率(λ)が40%以上であり、降伏比(YR)が75%以上であり、かつ均一伸び以降の加工軟化率の絶対値が250000MPa以下である場合を、高強度でかつ高い均一伸び、穴広げ性及び降伏比を有するとともに、衝突時の荷重低下を抑制することができる鋼板として評価した。その結果を表4に示す。表4中の「フェライトの個数密度の差の最大値/Nαm」は、図1に示す6つの個数密度の差、すなわちNα1とNα4の差、Nα4とNα7の差、Nα2とNα5の差、Nα5とNα8の差、Nα3とNα6の差、及びNα6とNα9の差のうちの最大値をNαmで除した値を意味するものである。したがって、この値が0.60以下である場合には、「板厚方向に隣接する各分割領域におけるフェライトの個数密度の差が全てNαm×0.60以下」の要件を満たすことになる。また、表4に示す金属組織において、残部組織は、パーライト及び残留オーステナイトの少なくとも1種であった。 Steel plates with a tensile strength (TS) of 1180 MPa or more, a uniform elongation (uEl) of 5.0% or more, a hole expansion ratio (λ) of 40% or more, a yield ratio (YR) of 75% or more, and an absolute value of the work softening rate after uniform elongation of 250,000 MPa or less were evaluated as steel plates with high strength, high uniform elongation, hole expansion property, and yield ratio, and capable of suppressing load reduction during collision. The results are shown in Table 4. "Maximum difference in number density of ferrite/Nαm" in Table 4 means the maximum value of the six number density differences shown in Figure 1, i.e., the difference between Nα1 and Nα4, the difference between Nα4 and Nα7, the difference between Nα2 and Nα5, the difference between Nα5 and Nα8, the difference between Nα3 and Nα6, and the difference between Nα6 and Nα9, divided by Nαm. Therefore, if this value is 0.60 or less, the requirement that "the difference in number density of ferrite in each divided region adjacent in the plate thickness direction is all Nαm × 0.60 or less" is met. Also, in the metal structure shown in Table 4, the remaining structure was at least one of pearlite and retained austenite.

 表1~4を参照すると、比較例2は、熱間圧延工程における後段2段の直前2段の各圧延パスにおける圧延温度が低かったために、再結晶が十分に促進されず、部分的に未再結晶粒が残ってしまったと考えられる。その結果として、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができず、すなわちフェライトの個数密度の差の最大値/Nαmが0.60超となり、これに関連してuEl以降の加工軟化率の絶対値が250000MPa超となり、すなわちuEl以降の加工軟化が顕著となった。比較例3は、後段2段の直前2段の各圧延パスにおける圧延温度が高かったために、再結晶後のオーステナイト粒が粗大化し、オーステナイト粒界の数が減少してフェライトの核生成サイトが減少してしまったものと考えられる。その結果として、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができず、uEl以降の加工軟化率の絶対値が250000MPa超となった。比較例4は、後段2段の直前2段の各圧延パスにおける圧下率が低かったために、再結晶が十分に促進されず、部分的に未再結晶粒が残ってしまったと考えられる。その結果として、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができず、uEl以降の加工軟化率の絶対値が250000MPa超となった。比較例5は、後段2段の直前2段の各圧延パスにおける圧下率が高かったために、過度なひずみの導入に起因して扁平なオーステナイト粒が形成されてしまったと考えられる。その結果として、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができず、uEl以降の加工軟化率の絶対値が250000MPa超となった。比較例6は、後段2段の直前2段の圧延パス後800~910℃の冷却停止温度まで冷却する時間が0.20秒超であったために、再結晶後のオーステナイト粒の粒成長を十分に抑制することできなかったと考えられる。その結果として、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができず、uEl以降の加工軟化率の絶対値が250000MPa超となった。 Referring to Tables 1 to 4, it is considered that in Comparative Example 2, the rolling temperature in each of the two rolling passes immediately before the latter two passes in the hot rolling process was low, so that recrystallization was not sufficiently promoted and unrecrystallized grains remained partially. As a result, the number density of ferrite could not be sufficiently uniformed in the thickness direction in the finally obtained metal structure, that is, the maximum value of the difference in number density of ferrite/Nαm exceeded 0.60, and in connection with this, the absolute value of the work softening rate after uEl exceeded 250,000 MPa, that is, work softening after uEl became significant. In Comparative Example 3, the rolling temperature in each of the two rolling passes immediately before the latter two passes was high, so that the austenite grains after recrystallization became coarse, the number of austenite grain boundaries decreased, and the nucleation sites of ferrite decreased. As a result, the number density of ferrite could not be sufficiently uniformed in the thickness direction in the finally obtained metal structure, and the absolute value of the work softening rate after uEl exceeded 250,000 MPa. In Comparative Example 4, the reduction rate in each of the rolling passes immediately before the last two stages was low, so recrystallization was not sufficiently promoted, and unrecrystallized grains were partially left. As a result, the number density of ferrite in the finally obtained metal structure could not be sufficiently uniformed in the plate thickness direction, and the absolute value of the work softening rate after uEl exceeded 250,000 MPa. In Comparative Example 5, the reduction rate in each of the rolling passes immediately before the last two stages was high, so it is thought that flat austenite grains were formed due to the introduction of excessive strain. As a result, the number density of ferrite in the finally obtained metal structure could not be sufficiently uniformed in the plate thickness direction, and the absolute value of the work softening rate after uEl exceeded 250,000 MPa. In Comparative Example 6, the time required for cooling to a cooling stop temperature of 800 to 910 ° C. after the rolling passes immediately before the last two stages was more than 0.20 seconds, so it is thought that the grain growth of austenite grains after recrystallization could not be sufficiently suppressed. As a result, the number density of ferrite in the final metal structure could not be sufficiently uniform in the thickness direction, and the absolute value of the work softening rate after uEl exceeded 250,000 MPa.

 比較例7は、後段2段の圧延パスとその直前2段の圧延パスとの間の冷却における冷却停止温度が低かったために、最終的に得られる金属組織においてフェライトが多く生成してしまった。その結果として、Ti析出物に起因する析出強化によってもフェライトとマルテンサイトとの硬度差を十分に低減することができず、λが低下した。比較例8は、後段2段の圧延パスとその直前2段の圧延パスとの間の冷却における冷却停止温度が高かったために、再結晶後のオーステナイト粒の粒成長を十分に抑制することできなかったと考えられる。その結果として、最終的に得られる金属組織においてフェライトの個数密度を板厚方向に十分に均一化することができず、uEl以降の加工軟化率の絶対値が250000MPa超となった。比較例9は、後段2段の各圧延パスの圧下率が低かったために、その後の冷却工程におけるフェライト変態の駆動力を十分に高めることができなかったと考えられる。その結果として、最終的に得られる金属組織において所望のフェライト面積率を達成することができず、uElが低下した。比較例10は、後段2段の各圧延パスの圧下率が高かったために、その後の冷却工程におけるフェライト変態の駆動力が大きくなりすぎてしまったと考えられる。その結果として、最終的に得られる金属組織においてフェライトが多く生成してしまい、Ti析出物に起因する析出強化によってもフェライトとマルテンサイトとの硬度差を十分に低減することができず、λが低下した。比較例11は、冷却工程における空冷までの水冷時間が長かったために、フェライトが比較的多く生成してしまった。その結果として、同様にλが低下した。比較例12は、空冷温度が低かったために、ベイナイトが比較的多く生成してしまい、uElが低下した。比較例13は、空冷温度が高かったために、フェライト変態を十分に促進させることができず、uElが低下した。比較例14は、空冷時間が短かったために、同様にフェライト変態を十分に促進させることができず、uElが低下した。比較例15は、空冷時間が長かったために、フェライトが比較的多く生成してしまい、λが低下した。比較例16は、空冷後50℃以下までの水冷時間が長かったために、ベイナイトが多く生成し、uElが低下した。 In Comparative Example 7, the cooling stop temperature in the cooling between the last two rolling passes and the two immediately preceding rolling passes was low, so a large amount of ferrite was generated in the final metal structure. As a result, the hardness difference between ferrite and martensite could not be sufficiently reduced even by precipitation strengthening due to Ti precipitates, and λ decreased. In Comparative Example 8, the cooling stop temperature in the cooling between the last two rolling passes and the two immediately preceding rolling passes was high, so it is considered that the grain growth of austenite grains after recrystallization could not be sufficiently suppressed. As a result, the number density of ferrite could not be sufficiently uniformed in the plate thickness direction in the final metal structure, and the absolute value of the work softening rate after uEl exceeded 250,000 MPa. In Comparative Example 9, the reduction rate of each rolling pass in the last two stages was low, so it is considered that the driving force of ferrite transformation in the subsequent cooling process could not be sufficiently increased. As a result, the desired ferrite area ratio could not be achieved in the final metal structure, and uEl decreased. In Comparative Example 10, the rolling reduction rate of each rolling pass in the latter two stages was high, so it is considered that the driving force of the ferrite transformation in the subsequent cooling process became too large. As a result, a large amount of ferrite was generated in the finally obtained metal structure, and the hardness difference between ferrite and martensite could not be sufficiently reduced even by precipitation strengthening due to Ti precipitates, and λ decreased. In Comparative Example 11, the water cooling time until air cooling in the cooling process was long, so a relatively large amount of ferrite was generated. As a result, λ also decreased. In Comparative Example 12, the air cooling temperature was low, so a relatively large amount of bainite was generated, and uEl decreased. In Comparative Example 13, the air cooling temperature was high, so the ferrite transformation could not be sufficiently promoted, and uEl decreased. In Comparative Example 14, the air cooling time was short, so the ferrite transformation could not be sufficiently promoted, and uEl decreased. In Comparative Example 15, the air cooling time was long, so a relatively large amount of ferrite was generated, and λ decreased. In Comparative Example 16, the time required for water cooling to 50°C or less after air cooling was long, so a lot of bainite was produced and uEl decreased.

 比較例44は、Ti含有量が低かったために、Ti析出物による析出強化を十分に作用させることができなかったと考えられる。その結果として、TSが低下した。比較例45は、Ti含有量が高かったために粗大な炭化物等が生成したものと考えられる。その結果として、鋼板の加工性が低下し、λが低下した。比較例46は、Nb含有量が低かったためにTSが低下した。比較例47は、Nb含有量が高かったために粗大な炭化物等が生成したものと考えられる。その結果として、鋼板の加工性が低下し、λが低下した。 In Comparative Example 44, the Ti content was low, which is believed to have prevented sufficient precipitation strengthening by Ti precipitates. As a result, TS decreased. In Comparative Example 45, the Ti content was high, which is believed to have caused coarse carbides and the like to form. As a result, the workability of the steel sheet decreased and λ decreased. In Comparative Example 46, the Nb content was low, which is believed to have caused TS decreased. In Comparative Example 47, the Nb content was high, which is believed to have caused coarse carbides and the like to form. As a result, the workability of the steel sheet decreased and λ decreased.

 これとは対照的に、全ての発明例に係る鋼板において、所定の化学組成を有し、さらに製造方法における各条件を適切に制御することで、金属組織が、面積%で、フェライト:10~40%、マルテンサイト:60~90%、及びベイナイト:0~10%であり、板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差が全てNαm×0.60以下である鋼板を得ることができた。また、その結果として、引張強さが1180MPa以上の高強度であるにもかかわらず、高い均一伸び、穴広げ性及び降伏比を有するとともに、均一伸び以降の加工軟化率の絶対値を確実に250000MPa以下に低減することができた。 In contrast, in all of the steel sheets according to the invention examples, a steel sheet with a predetermined chemical composition and with appropriately controlled manufacturing conditions has a metal structure with, in terms of area percentages, ferrite: 10-40%, martensite: 60-90%, and bainite: 0-10%. When a 150 μm x 150 μm region at 1/4 of the plate thickness position on a cross section perpendicular to the plate surface is equally divided into nine regions, the number density of ferrite is calculated in each divided region, and the average value is taken as Nαm, a steel sheet can be obtained in which the difference in number density of ferrite in adjacent divided regions in the plate thickness direction is all Nαm x 0.60 or less. As a result, despite a high tensile strength of 1180 MPa or more, the steel sheet has high uniform elongation, hole expandability, and yield ratio, and the absolute value of the work softening rate after uniform elongation can be reliably reduced to 250,000 MPa or less.

Claims (7)

 化学組成が、質量%で、
 C:0.060~0.300%、
 Si:0.30~1.50%、
 Mn:1.00~2.70%、
 P:0.100%以下、
 S:0.0300%以下、
 sol.Al:0.001~0.500%、
 O:0.0100%以下、
 N:0.0070%以下、
 Ti:0.070~0.170%、
 Nb:0.001~1.000%、
 B:0~0.0030%、
 Cr:0~0.70%、
 Mo:0~0.12%、
 Cu:0~0.40%、
 Ni:0~0.30%、
 V:0~0.300%、
 Sn:0~0.040%、
 As:0~0.100%、
 Zr:0~0.050%、
 Ca:0~0.0010%、
 Mg:0~0.0010%、
 Bi:0~0.010%、
 Co:0~0.010%、
 W:0~0.100%、
 Zn:0~0.010%、
 REM:0~0.0100%、並びに
 残部:Fe及び不純物であり、
 金属組織が、面積%で、
 フェライト:10~40%、
 マルテンサイト:60~90%、
 ベイナイト:0~10%、並びに
 パーライト及び残留オーステナイトの少なくとも1種:合計で0~5%であり、
 板面に垂直な断面の板厚1/4位置における150μm×150μmの領域を均等に9分割し、各分割領域でフェライトの個数密度を算出し、それらの平均値をNαmとした場合に、板厚方向に隣接する各分割領域におけるフェライトの個数密度の差が全てNαm×0.60以下であることを特徴とする、鋼板。
The chemical composition, in mass%, is
C: 0.060-0.300%,
Si: 0.30-1.50%,
Mn: 1.00-2.70%,
P: 0.100% or less,
S: 0.0300% or less,
sol. Al: 0.001 to 0.500%,
O: 0.0100% or less,
N: 0.0070% or less,
Ti: 0.070 to 0.170%,
Nb: 0.001-1.000%,
B: 0 to 0.0030%,
Cr: 0-0.70%,
Mo: 0 to 0.12%,
Cu: 0 to 0.40%,
Ni: 0 to 0.30%,
V: 0-0.300%,
Sn: 0 to 0.040%,
As: 0 to 0.100%,
Zr: 0 to 0.050%,
Ca: 0-0.0010%,
Mg: 0 to 0.0010%,
Bi: 0 to 0.010%,
Co: 0 to 0.010%,
W: 0-0.100%,
Zn: 0 to 0.010%,
REM: 0 to 0.0100%, and the balance: Fe and impurities;
The metal structure is, in area percent,
Ferrite: 10-40%,
Martensite: 60-90%,
Bainite: 0 to 10%, and at least one of pearlite and retained austenite: 0 to 5% in total;
A steel plate characterized in that, when a 150 μm x 150 μm region at 1/4 of the plate thickness position on a cross section perpendicular to the plate surface is equally divided into nine, the number density of ferrite is calculated in each divided region, and the average value of these is taken as Nαm, the difference in number density of ferrite in each divided region adjacent to each other in the plate thickness direction is all Nαm x 0.60 or less.
 前記化学組成が、質量%で、
 B:0.0001~0.0030%、
 Cr:0.001~0.70%、
 Mo:0.001~0.12%、
 Cu:0.001~0.40%、
 Ni:0.001~0.30%、
 V:0.001~0.300%、
 Sn:0.001~0.040%、
 As:0.001~0.100%、
 Zr:0.001~0.050%、
 Ca:0.0001~0.0010%、
 Mg:0.0001~0.0010%、
 Bi:0.001~0.010%、
 Co:0.001~0.010%、
 W:0.001~0.100%、
 Zn:0.001~0.010%、及び
 REM:0.0001~0.0100%
のうち少なくとも1種を含むことを特徴とする、請求項1に記載の鋼板。
The chemical composition, in mass%,
B: 0.0001 to 0.0030%,
Cr: 0.001-0.70%,
Mo: 0.001-0.12%,
Cu: 0.001-0.40%,
Ni: 0.001 to 0.30%,
V: 0.001-0.300%,
Sn: 0.001 to 0.040%,
As: 0.001 to 0.100%,
Zr: 0.001 to 0.050%,
Ca: 0.0001 to 0.0010%,
Mg: 0.0001 to 0.0010%,
Bi: 0.001 to 0.010%,
Co: 0.001 to 0.010%,
W: 0.001-0.100%,
Zn: 0.001 to 0.010%, and REM: 0.0001 to 0.0100%
The steel sheet according to claim 1, characterized in that it contains at least one of the following:
 Nαmが0.050個/μm2以上であることを特徴とする、請求項1又は2に記載の鋼板。 The steel sheet according to claim 1 or 2, characterized in that Nαm is 0.050 pieces/μm 2 or more.  1180MPa以上の引張強さを有することを特徴とする、請求項1~3のいずれか1項に記載の鋼板。 The steel plate according to any one of claims 1 to 3, characterized in that it has a tensile strength of 1180 MPa or more.  1.0~8.0mmの板厚を有することを特徴とする、請求項1~4のいずれか1項に記載の鋼板。 The steel plate according to any one of claims 1 to 4, characterized in that it has a plate thickness of 1.0 to 8.0 mm.  請求項1~5のいずれか1項に記載の鋼板を含むことを特徴とする、部品。 A part comprising the steel plate according to any one of claims 1 to 5.  請求項1又は2に記載の化学組成を有するスラブを加熱し、1180~1350℃の温度で6000秒以上保持することを含む加熱工程、
 前記スラブを4基以上の圧延スタンドからなるタンデム圧延機を用いて仕上げ圧延することを含み、下記(a)~(c)の条件を満足する熱間圧延工程、
  (a)後段2段の直前2段の各圧延パスにおける圧延温度が960~1080℃であり、前記各圧延パスにおける圧下率が30~50%であること、
  (b)前記後段2段の直前2段の圧延パス後0.20秒以内に圧延材を800~910℃の冷却停止温度まで冷却すること、及び
  (c)後段2段の各圧延パスにおける圧下率が10~40%であること
 仕上げ圧延された鋼板を水冷し、水冷開始から4.0秒以内に600~750℃の温度域まで冷却し、次いで前記温度域にて2.0~8.0秒の空冷を実施し、空冷後13秒以内に前記鋼板を50℃以下まで水冷することを含む冷却工程
を含む、鋼板の製造方法。
A heating step comprising heating a slab having the chemical composition according to claim 1 or 2 and holding it at a temperature of 1180 to 1350°C for 6000 seconds or more;
A hot rolling process including finish rolling the slab using a tandem rolling mill having four or more rolling stands, the hot rolling process satisfying the following conditions (a) to (c):
(a) the rolling temperature in each of the rolling passes in the two stages immediately preceding the latter two stages is 960 to 1080°C, and the rolling reduction in each of the rolling passes is 30 to 50%;
(b) cooling the rolled material to a cooling stop temperature of 800 to 910°C within 0.20 seconds after the rolling passes of the two rolling passes immediately preceding the latter two rolling passes; and (c) a rolling reduction rate in each rolling pass of the latter two rolling passes is 10 to 40%. A method for producing a steel plate, comprising a cooling step including: water-cooling the finish-rolled steel plate, cooling it to a temperature range of 600 to 750°C within 4.0 seconds from the start of water cooling, then air-cooling it in said temperature range for 2.0 to 8.0 seconds, and water-cooling the steel plate to 50°C or less within 13 seconds after air-cooling.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019088104A1 (en) * 2017-10-30 2019-05-09 新日鐵住金株式会社 Hot-rolled steel sheet and manufacturing method therefor
WO2019103121A1 (en) * 2017-11-24 2019-05-31 日本製鉄株式会社 Hot-rolled steel sheet and manufacturing method therefor
WO2020195605A1 (en) * 2019-03-26 2020-10-01 日本製鉄株式会社 Steel sheet, method for manufacturing same and plated steel sheet

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019088104A1 (en) * 2017-10-30 2019-05-09 新日鐵住金株式会社 Hot-rolled steel sheet and manufacturing method therefor
WO2019103121A1 (en) * 2017-11-24 2019-05-31 日本製鉄株式会社 Hot-rolled steel sheet and manufacturing method therefor
WO2020195605A1 (en) * 2019-03-26 2020-10-01 日本製鉄株式会社 Steel sheet, method for manufacturing same and plated steel sheet

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