WO2025032268A1 - Prefabricated element for construction and associated method - Google Patents
Prefabricated element for construction and associated method Download PDFInfo
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- WO2025032268A1 WO2025032268A1 PCT/ES2024/000016 ES2024000016W WO2025032268A1 WO 2025032268 A1 WO2025032268 A1 WO 2025032268A1 ES 2024000016 W ES2024000016 W ES 2024000016W WO 2025032268 A1 WO2025032268 A1 WO 2025032268A1
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- WO
- WIPO (PCT)
- Prior art keywords
- aggregate
- prefabricated
- prefabricated element
- calcium sulphate
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators or shrinkage compensating agents
- C04B22/06—Oxides, Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/04—Producing shaped prefabricated articles from the material by tamping or ramming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/08—Producing shaped prefabricated articles from the material by vibrating or jolting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/08—Producing shaped prefabricated articles from the material by vibrating or jolting
- B28B1/10—Producing shaped prefabricated articles from the material by vibrating or jolting and applying pressure otherwise than by the use of presses
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/04—Carboxylic acids; Salts, anhydrides or esters thereof
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/04—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
Definitions
- the present patent application aims to protect a prefabricated element for construction comprising at least one binder and at least one aggregate, where the binder is gypsum, and the aggregate is based on calcium sulphate plus a retarding additive. It also aims at a method of manufacturing said prefabricated element for construction, with the steps of i) preparation of an aggregate based on calcium sulphate; ii) homogeneous mixing of a gypsum binder, the aggregate based on calcium sulphate and water; iii) shaping of the prefabricated element by means of vibro compression, incorporating notable innovations and advantages.
- patent SU645607A discloses a construction block made from gypsum aggregates and a PVC coating. Specifically, a manufacturing process for elementary gypsum-based construction material is described, which has the general shape of a rectangular prism, where the prepared gypsum block is embedded in a compact or light polyvinyl chloride profile, with a strictly defined section, and is cut to the desired length. Said gypsum block, thus profiled and made, is covered in its two free ends, by means of two bottoms of the same plastic material, of dimensions substantially equal to the straight section of the profile and welded at its ends.
- patent RU1774935C describes a method of manufacturing products based on gypsum and concrete, from the mixture of gypsum binders and gypsum aggregates, where the gypsum binder is mixed with recycled gypsum aggregates and other additives. They can also be mixed, however, with cement. And in order to increase resistance to water and frost, it includes mixing dosed construction gypsum and water, placing the resulting mixture in a mould, followed by a stage of suction, stripping and drying.
- the present invention aims to define a new prefabricated element, as well as its manufacturing method, following a vibro compression system, using gypsum as raw material as a binder, and aggregates based on calcium sulphate.
- This procedure is preferably intended for the manufacture of prefabricated elements, which covers the entire base of prefabricated elements by vibrocompression obtained using the traditional system of cement plus aggregates; blocks, vaults, curbs, paving stones, caissons, prefabricated elements in general, using calcium sulphate as a base with a formulation based on gypsum with retardant additives, and different proportions of aggregates or mineral fillers, previously manufactured from calcium sulphate itself.
- the aim is therefore to achieve a semi-dry mix, i.e. a plaster with a low contribution of hydration water, which reduces the mixing water, while using retarding and fluidifying additives.
- a mix is understood as a low hydration mass.
- the quantity of water required to be added to the hemihydrate to convert it into a dihydrate is of the order of 186 g of water per 1000 g of gypsum. This quantity does not allow any workability unless the gypsum is already partially hydrated.
- the gypsum to be used is extended to any hemihydrated type, and makes high dehydration temperatures unnecessary, since it is not necessary to exceed 160“C. In this new material, it is also extended to ao alpha type gypsum, white gypsum, and plasters.
- the aggregate is passed through a sieve to remove the coarse aggregates, which can be used by using a hammer mill with a sieve grid at the outlet to reduce the particle size to a maximum of 5-8 mm.
- This particle size is determined by the walls of the piece to be manufactured according to the mould of the vibrocompression machine.
- the extraction of gypsum involves a protocol that depends on how the material is found in nature, according to different qualities and forms.
- the extracted material is taken to a first phase of coarse grinding that is carried out with crushers or hammer mills.
- the size of the particles requires a second process of crushing or grinding to obtain a finer size, less than 10 mm.
- not all the rocks extracted have the same quality, and the aggregate must be classified before using it as a filler material in the second phase described below.
- Second phase of the process - Mixing aggregates with gypsum The aggregate is added to the gypsum according to a defined percentage.
- the water is increased up to a total of 210-240g for every 1000g of gypsum, and can reach up to 300g of water depending on the quality of the gypsum.
- either the water or the gypsum plus aggregate mixture must be added.
- the prefabricated element of the present invention contains aggregates based on calcium sulphate, prepared from rapid setting and a low contribution of water in the water/gypsum ratio, and a subsequent elimination of very large and very small particles, by filtering, dehydration, respectively, for their subsequent use.
- both the binder and the aggregates are based on calcium sulphate, using for manufacturing a vibrocompression process, with dry pouring, so the amount of water used is less than in pouring by casting.
- a prefabricated element is obtained with a process that consumes less energy, less water, and reduces CO2 emissions.
- the prefabricated element, being manufactured with aggregates based on calcium sulphate has thermal, acoustic, or fire resistance properties, greater than traditional concrete or ceramics.
- the prefabricated element for construction comprises at least one binder and at least one aggregate, where the binder is gypsum, and the aggregate is based on calcium sulphate plus a retarding additive.
- the prefabricated element may be understood as, but is not limited to, curbs, paving stones, bricks, vaults, blocks, presenting a compressive strength of between 14 and 20 N/mm 2 .
- the retarding additive or retarder
- procedures can be established, depending on the dispersion and size. of manufactured aggregates, as well as their granulometric classification, such as the Bolomey or Fuller method.
- the use of gypsum with mineral aggregates means a reduction in CO2 emissions, with the achievement of better thermal, acoustic or fire resistance properties, surpassing those of traditional concrete or ceramics.
- the invention changes the concept of using gypsum as a pouring element to that of dry pouring.
- the advantage of this new material and the construction piece is that it does not require the use of cement, with the consequent environmental advantage of reducing the latter by gypsum, since in the manufacture of a piece a very significant lesser manufacturing energy is used compared to conventional materials that comprise, for example, cement.
- gypsum is an element considered ideal for the circular economy, since it is 100% reusable.
- the weight of the binder is between 40% and 70% of the weight of the prefabricated element, which translates into a weight of 400g to 700g of the total 1000g of the prefabricated element, thus presenting optimized properties in terms of mechanical and thermal resistance.
- the increase in mechanical compressive strength, taking cast black plaster as a reference is 2N/ mm and can reach values of up to 20N/mm2, which represents an increase of 1000%.
- the weight of the aggregate is between 30% and 60% of the weight of the prefabricated element, which translates into a weight of 300 g to 600 g of the mixture out of the total of 1000 g of the prefabricated element, thus presenting optimized properties in terms of mechanical and thermal resistance.
- the coefficient of thermal variation X (kcal/hm K or W/m a . a C) is reduced by more than 30%.
- the binder is one of the group of black plaster, white plaster, plaster or alpha plaster, which provides a degree of flexibility to the mixture, with alternatives of possible constituent materials.
- the aggregate is one of the group of prefabricated aggregate, recycled aggregate, gypsum aggregate directly from the quarry without cooking treatment, or a mixture of prefabricated aggregate with recycled aggregate, which also provides a degree of flexibility to the mixture, with alternatives of possible constituent materials.
- recycled aggregates which may include gypsum, as well as aggregates made from ceramics, such as in the specific case of arlite or perlite.
- the different types of aggregates are focused on different applications, depending on their quality, as well as the content or mixture of said aggregates.
- Recycled aggregates are understood to be those that are the result of the treatment of inorganic materials that have previously been used in construction. Therefore, they are construction and demolition waste.
- the type of aggregate used is also determined by the particle size fraction sought in the final mixture, preferably a fine aggregate of no more than 8 mm, that is, sand or gravel, discarding gravel and ballast.
- Recycled aggregates from concrete are basically obtained from foundations, building structures, prefabricated elements, etc.
- the use of aggregates from asphalt agglomerate layers and other recycled aggregates from clean ceramic waste and aggregates from mixtures is also contemplated.
- Aggregates from concrete are the most suitable due to their mechanical properties, although aggregates from clean ceramic waste and aggregates from mixtures can be chosen. Its maximum quantity is up to 70%, also depending on the quality of the plaster and its purity.
- the prefabricated aggregate for the prefabricated element for construction comprises a granulometry of i) maximum size of 10 mm, with a presence of between 1% and 5%; i ⁇ ) size between 3-5 mm, with a presence of between 75% and 88%; iii) size between 0.2-0.05mm, with a presence of between 10% and 20%; iv) size between 0.02- 0.005mm, with a presence of between 1% and 5%; and further comprises between 17.36% and 23.08% of water of the weight of the prefabricated element and between 0.01% and 0.2% of additive of the weight of the prefabricated element, where the additive is based on a polycarboxylic acid.
- This granulometry is defined according to the Attemberg classification, thus presenting optimized properties in terms of mechanical and thermal resistance, in line with what was mentioned above.
- the first phase involves the prefabrication of aggregates based on a material based on gypsum or calcium sulphate with very low hydration.
- the characteristics of the prefabricated aggregate are those of an incompressible material with low water absorption, due to a closed capillary structure. This is achieved through rapid setting and a low water contribution in the water/gypsum ratio.
- the second phase of the manufacturing process to obtain the prefabricated element consists of obtaining a homogeneous mixture of the aggregates with the rest of the gypsum matrix. Due to the low water absorption, the amount of water needed for the mixture will vary, although the final water in this step is estimated between 210-300g for every 1000g of gypsum. In the case of plaster, this percentage varies due to the better properties of the same compared to construction plaster. The percentage of hydration could be higher, depending on the purity and degree of grinding, reaching a contribution that can exceed 300 grams, that is, 250-350 g for every 1000 g of plaster.
- a general dosage of the material comprises a) 400 - 700 g of gypsum, which may be black gypsum, white gypsum, plaster of Paris or gypsum; b) 300 - 700 g of aggregate, which may be precast aggregate based on calcium sulphate, gypsum aggregate selected from quarry extraction, recycled aggregate or a mixture of precast gypsum aggregate with recycled aggregate; c) 210 - 300 g of water; d) 0.1 - 2 g of water additive based on polycarboxylic acids.
- the polycarboxylic acid is citric acid or citric acid with silicon dioxide, and also a melamine compound and/or salts, for example citric acid with a melamine base and/or salts, all with the aim of adding a retarding additive that delays setting.
- the recycled aggregate comprises a granulometry of i) maximum size of 10 mm, with a presence of between 1% and 8%: ii) size between 3-5 mm, with a presence of between 68% and 88%; lii) size between 0.2-0.05mm, with a presence of between 8% and 21%; iv) between 0.02-0.005mm, with a presence of between 1% and 6%.
- This recycled aggregate has the advantage of being more environmentally sustainable.
- the prefabricated aggregate can be based on a single particle size distribution of i) maximum size of 10 mm, with a presence of between 0% and 10 %; ii) size between 3-5 mm, with a presence of between 0% and 100 %; iii) size between 0.2-0.05 mm, with a presence of between 0% and 100 %; iv) size between 0.02-0.005 mm, with a presence of between 1% and 10 %; , and also comprises between 17.36% and 23.08% of water by weight of the prefabricated element and between 0.01% and 0.2% of additive by weight of the prefabricated element, where the additive is based on a polycarboxylic acid, a methamine compound and/or salts, thus presenting optimized properties in terms of mechanical and thermal resistance. Specifically, the increase in compressive strength can reach 700% (from 2 N/mm ⁇ to 14 N/mm ⁇ ), with thermal properties also improving by 20% depending on the fraction used.
- the aggregate comprises a proportion of up to 30% of arlite or perite, plus prefabricated aggregate, given that recycled aggregates can be added.
- the proportion of prefabricated aggregate supplied can be replaced by a fraction of said recycled aggregate.
- the gypsum matrix admits up to a maximum of 70% of aggregate in the matrix without counting the water, although these aggregates reduce the properties of calcium sulphate, therefore, it is considered that a reasonable fraction can be 10%-40% of recycled aggregate with respect to 100% of the aggregate, or of arlite or perite.
- fractions or granulometry of these recycled aggregates they preferably have the proportions of: a) 10 mm gravel in 1 - 8 %; b) fine gravel 5-3 mm in 68 - 88 %; c) fine sand 0.2-0.05 in 8 - 21 %; d) silt 0.02-0.005 in 1 - 6 %. being aggregates from crushed or concrete waste, from clean ceramic waste or aggregates from a mixture of both.
- the present invention also relates to a method of manufacturing a prefabricated element for construction, which comprises the steps of: i) preparing an aggregate based on calcium sulphate; ii) homogeneous mixing of a gypsum binder, the aggregate based on calcium sulphate and water; iii) shaping the prefabricated element by means of vibro compression, such that a prefabricated element is obtained that is suitably shaped as described above.
- vibrocompression in gypsum and/or calcium sulphate significantly reduces handling time when compared to vibrocompression in concrete. It also does not require a curing chamber or the addition of additional water.
- the manufactured aggregate is added to the gypsum for subsequent vibrocompression, since vibration eliminates part of the air in the mixture and the cavities, the vibration process being a fundamental part of the matrix fixing process, which consists of homogenising said aggregates.
- the method of manufacturing prefabricated elements for construction involves the addition of a water additive based on a polycarboxylic acid or silicon dioxide.
- the preparation of a mixture comprising an aggregate based on calcium sulphate, water and additive and comprising a part of aggregates, recycled aggregates, quarry aggregates, ahite or perlite, and comprises the steps of: i.1) mixing the calcium sulphate with water, additive and aggregates; i.2) kneading said mixture of calcium sulphate with water, additive and aggregates in a rotary horizontal mixer until obtaining calcium sulphate grains of homogeneous size less than 8 mm; i.3) pouring the mixture into a vibro compression machine to obtain the prefabricated elements, so that the prefabricated elements obtained with said process have a compressive strength greater than between 14 and 20 N/mm ?
- the horizontal mixer can be a rotary mixer with blades or pickaxes, and that there is a screening stage to remove coarse aggregates, i.e., diameters greater than Bmm. It should be noted that different manufacturing processes can be used to obtain these aggregates. For example, with a horizontal mixer with paddles or pickaxes, or simply planetary type mixing machines. In the first case, a higher quality of aggregates is achieved, since the plaster, once in the vat, is sprayed with water, previously added with a setting retarder.
- the rotating blades continuously mix, forming balls or grains of homogeneous size and diameters less than 7 mm.
- the initial quantity of water is set at 185 ⁇ 10 g per 1000 g of gypsum.
- the balls or grains are not usually homogeneous and a subsequent screening is necessary to eliminate the coarse fraction.
- polycarboxylic acids for example, with citric acid, this is set between 0.1-2 g per 1000 g of gypsum to be mixed.
- the preparation of an aggregate based on calcium sulphate comprises a prior stage of obtaining treated water for mixing, where the treated water comprises a setting retarder, so that the mixing water already includes said component.
- the preparation of a calcium sulphate-based aggregate comprises the following steps: i.1) mixing the calcium sulphate with water and additive; i.2) pulverizing the mixture of calcium sulphate with water and additive in a rotary horizontal mixer until obtaining a calcium sulphate grain of homogeneous size; i.3) sieving the calcium sulphate aggregate with a diameter less than 8 mm; i.4) grinding the calcium sulphate grains with a diameter greater than 10 mm in a fragmentation mill; i.5) dehydration treatment of the calcium sulphate.
- the horizontal mixer can be a rotary mixer with blades or pickaxes. That screening involves removing aggregates with a thickness greater than desired, in this case with diameters greater than 8 mm. That the grinding of the grains, or gravel, of aggregate in a fragmentation mill is to eliminate the largest particles, and to reduce the granulometry to a maximum of 5-8 mm, and that they can be reused in smaller fractions. And that the dehydration treatment of calcium sulphate is to eliminate the smallest particles, to be reused again in the production of the aggregate.
- the aggregates obtained with the previous procedure have a shore C hardness of 98-100, a humidity absorption of less than 0.1 -0.5% and a compressive strength greater than 20 N/mm 2 .
- the filler material requires screening and/or sifting to remove silt and fine sand smaller than 0.1 mm, as well as gravel exceeding 7 or 8 mm in average particle diameter.
- the larger particles can be subjected to a fragmentation mill to be reused in smaller fractions, and the fine particles can be subjected to a calcium sulphate dehydration process to be reused again in the production of the aggregate.
- 100% of the gypsum is used, which is quite an achievement, something that is not usually achieved in the known industrial manufacturing processes of construction materials.
- the amount of water is between 14.89% and 17.01% of the weight of the prefabricated element, thus presenting optimized properties in terms of mechanical and thermal resistance.
- the increase in compressive strength can reach up to 1000% (from 2 N/mm 2 to 20 N/mm z ), also improving thermal properties by up to 30%, depending on the type of part manufactured.
- FIG. 1 View of various prefabricated elements for construction, in accordance with the present invention.
- FIG. 2- View of a container with the mixture of various materials according to the manufacturing method of the prefabricated element, in accordance with the present invention
- FIG. 3- View of a container with the resulting grain-shaped aggregate according to the manufacturing method of the prefabricated element, in accordance with the present invention
- FIG. 4- View of a container filled with aggregate as well as the raw material obtained according to the manufacturing method of the prefabricated element, in accordance with the present invention
- FIG. 5 Perspective view of a mixing machine, according to the present invention.
- FIG. 6- Perspective view of a mill that receives the aggregate and transforms it into grain, in accordance with the present invention
- FIG. 8 View of the various elements that make up the manufacturing method of the prefabricated element, in accordance with the present invention.
- Figure 1 shows a view of several prefabricated elements (1) for construction, forming a wall.
- Figure 2 shows a view of a container with the mixture of various materials according to the manufacturing method of the prefabricated element (1), specifically an aggregate (3) with a retarder (9), together with a binder (2) with a gypsum base (21), to which water (4) is added with at least one additive (5).
- Figure 3 shows a view of a container with the result of an aggregate (3) in the form of grain (6) according to the manufacturing method of the prefabricated element (1).
- Figure 4 shows a view of a container filled with aggregate (3) as well as the raw material from which it is obtained according to the manufacturing method of the prefabricated element (1).
- Figure 5 shows a perspective view of a mixing machine (7).
- Figure 6 shows a perspective view of a mill (8) that receives the aggregate (3) and transforms it into grain (6).
- Figure 7 shows a view of the addition of a retarder (9) to water (4) mixed with aggregate (3) based on calcium sulphate (31).
- Figure 8 shows a view of the various elements that make up the manufacturing method of the prefabricated element (1), consisting of a binder (2) with a gypsum base (21), on the other hand an aggregate (3), to which water (4) is added with some additive (5), preferably a retarder (9), with the help of a mixing machine (7) and a mill (8). with the functionalities and according to the stages and phases described above.
- polycarboxylic acid e.g. critical acid
- polycarboxylic acid e.g. critical acid
- polycarboxylic acid for example, critical acid.
- the prefabricated element (1) for construction comprises at least one binder (2) and at least one aggregate (3), where the binder (2) is gypsum (21), and the aggregate (3) is based on calcium sulphate (31) plus a retarder additive (5) (9).
- the weight of the binder (2) is between 40% and 70% of the weight of the prefabricated element (1).
- the weight of the aggregate (3) is between 30% and 60% of the weight of the prefabricated element (1).
- the binder (2) is one of the group of black gypsum (21), white gypsum (21), plaster or alpha gypsum (21).
- the aggregate (3) is one of the group of prefabricated aggregate (3), recycled aggregate (3), gypsum aggregate (3) directly from the quarry without cooking treatment, or a mixture of prefabricated aggregate (3) with recycled aggregate (3).
- the maximum quantity is between 10% and 40% of the 100% of the aggregate (3), 600g would be binder (2), i.e. 60%, and 400g of prefabricated aggregate (3), i.e. 40%, out of a total of 1000g.
- the maximum quantity would be up to 70% of the 100% of the aggregate (3), 600g would be binder (2), and 280g of recycled aggregates (3), together with 120g of prefabricated aggregates (3), out of a total of 1000g.
- the prefabricated aggregate (3) comprises a granulometry of: i) maximum size of 10 mm, with a presence of between 1% and 5%; ii) size between 3-5 mm, with a presence of between 75% and 88%; iii) size between 0.2-0.05mm, with a presence of between 10% and 20%; iv) size between 0.02-0.005mm, with a presence of between 1% and 5%; , and further comprises between 17.36% and 23.08% of water of the weight of the prefabricated element (1) and between 0.01% and 0.2% of additive of the weight of the prefabricated element (1).
- the additive (5) is based on a polycarboxylic acid.
- prefabricated element (1) 600g would be binder (2), 400g of prefabricated aggregates (3), that is, 40%, out of a total of 1000g, with 5% of these aggregates (3) being of a size smaller than 10mm, 80% of a size of 3-5mm, 10% of a size between 0.2-0.05, 5% of a size of 0.002-0.005.
- the contribution of between 17.36% and 23.08% of water (4) of the weight of the prefabricated element (1) corresponds to between 210g and 300g of water (4).
- 1000g of gypsum (21) plus additional aggregate (3) reaching a final composition of between 1210 and 1300g.
- additive (5) of the weight of the prefabricated element (1), on the 1000g of gypsum (21) plus aggregate (3) represents between 0.1 and 2g of additive (5).
- polycarboxylic acid is citric acid or citric acid with silicon dioxide, and alternatively citric acid based on melamine and/or salts.
- the recycled aggregate (3) comprises a granulometry of: i) maximum size of 10 mm, with a presence of between 1% and 8%; ii) size between 3-5 mm, with a presence of between 68% and 88%; iil) size between 0.2-0.05mm, with a presence of between 8% and 21%; iv) between 0.02-0.005mm, with a presence of between 1% and 6%.
- the prefabricated aggregate (3) can be based on a single granulometry of: i) maximum size of 10 mm, with a presence of between 0% and 10 %; ii) size between 3-5 mm, with a presence of between 0% and 100 %; iii) size between 0.2-0.05 mm, with a presence of between 0% and 100 %; iv) size between 0.02-0.005 mm, with a presence of between 1% and 10 %; and further comprises between 17.36% and 23.08% of water (4) of the weight of the prefabricated element (1) and between 0.01% and 0.2% of additive (5) of the weight of the prefabricated element (1), where the additive (5) is based on a polycarboxylic acid, a melamine compound and/or salts.
- a prefabricated element (1) can have 600g of binder (2), 400g of prefabricated aggregates (3), 40% of which is over 1000g, and 100% of these aggregates (3) being between 3-5mm in size.
- a prefabricated element (1) has 600g of binder (2), 400g of prefabricated aggregates (3), that is, 40% of 1000g, with 240g, that is, 60% of aggregates (3) of size between 3-5mm, and 160g, that is, 40% of aggregates (3) of size between 0.2-0.05.
- the preferred percentages of 17.36% and 23.08% of water (4) of the weight of the prefabricated element (1) correspond to 210g and 300g of water (4), with 1000g of gypsum (21) plus additional aggregate (3), going to a final composition of a weight of between 1210d and 1300g. From the above, we have percentages between 0.01% and 0.2% of additive (5) of the weight of the prefabricated element (1), on the 1000g of plaster (21) plus aggregate (3), which represents 0.1-2g of additive (5)
- the aggregate (3) comprises a proportion of up to 30% of arlite or perite, plus prefabricated aggregate (3).
- the maximum quantity is between 10% and 40% with respect to 100% of the aggregate (3).
- the arlite aggregates it has up to 70% with respect to 100% of the aggregate (3).
- the present invention also relates, as shown in Figure 8, to a method of manufacturing a prefabricated element (1) for construction, which comprises the steps of: i) preparing an aggregate (3) based on calcium sulphate (31); ii) homogeneous mixing of a binder (2) of gypsum (21), the aggregate (3) based on calcium sulphate (31) and water (4); forming of the prefabricated element (1) by means of vibro compression.
- prefabricated aggregates (3) of calcium sulphate (31) are used as for the raw material.
- the method of manufacturing the prefabricated element (1) for construction comprises the addition of a water additive (5) (4) based on a polycarboxylic acid, or with silicon dioxide.
- the method of manufacturing a prefabricated element (1) for construction comprises the preparation of a mixture comprising an aggregate (3) based on calcium sulphate (31), water (4) and additive (5) and comprising a portion of aggregates (3), recycled aggregates (3), quarry aggregates (3), arlite or perlite, and comprises the steps of: 1) mixing the calcium sulphate (31) with water (4), additive (5) and aggregates (3); 2) kneading said mixture of calcium sulphate (31) with water (4), additive (5) and aggregates (3) in a horizontal rotary mixer (7) until obtaining grains (6) of calcium sulphate (31) of homogeneous size less than 8 mm; i.3) pouring the mixture into a vibro compression machine to obtain the prefabricated elements (1).
- the preparation of an aggregate (3) based on calcium sulphate (31) comprises a prior stage of obtaining treated water (4) for mixing, where the treated water (4) comprises a setting retarder (9).
- the preparation of an aggregate (3) based on calcium sulphate (31) comprises the following steps: i.1) mixing the calcium sulphate (31) with water (4) and additive (5); i.2) pulverizing the mixture of calcium sulphate (31) with water (4) and additive (5) in a horizontal rotary mixer (7) until obtaining a grain (6) of calcium sulphate (31) of homogeneous size; i.3) sieving the aggregate (3) of calcium sulphate (31) with a diameter less than 8 mm; i.4) grinding the grains (6) of calcium sulphate (31) with a diameter greater than 10 mm in a fragmentation mill (8); i.5) dehydration treatment of the calcium sulphate (31).
- the amount of water (4) is between 14.89% and 17.01% of the weight of the prefabricated element (1). Specifically, between 175g and 205g of water (4), which, with the additional 1000g of gypsum (21) plus aggregate (3), the final composition would end up having between 1175 and 1205g. It should be added that to obtain these aggregates (3) different manufacturing procedures can be chosen. For example, a mixer (7) horizontal paddle mixers or pickaxes, or simply planetary type mixing machines. In the first case, the most interesting for the quality of the aggregates (3), the gypsum (21) once in the vat is subjected to a spray of water (4), previously added with a setting retarder (9).
- the rotating paddles mix continuously forming balls or grains (6) of homogeneous size and diameters less than 7mm.
- the initial quantity of water (4) is set at 185120 g for every 1000 g of gypsum (21), resulting in a weight of 1175 g of mix (1000 g + 175 g), 14.89% of mix, and for 1205 g (1000 + 205 g), 17.01% of mix.
- the balls or grains (6) are not homogeneous, and a subsequent screening is necessary to eliminate the coarse fraction.
- water (4) with polycarboxylic acids for example, with citric acid, this is set between 0.1-2g for every 1000g of gypsum (21) to be mixed.
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Abstract
Description
DESCRIPCIÓN DESCRIPTION
ELEMENTO PREFABRICADO PARA LA CONSTRUCCIÓN Y MÉTODO ASOCIADO PREFABRICATED ELEMENT FOR CONSTRUCTION AND ASSOCIATED METHOD
OBJETO DE LA INVENCIÓN OBJECT OF THE INVENTION
La presente solicitud de patente tiene por objeto proteger un elemento prefabricado para la construcción que comprende ai menos un aglomerante y al menos un árido, donde el aglomerante es yeso, y el árido está basado en sulfato calcico más un aditivo retardador. También tiene como objeto un método de fabricación de dicho elemento prefabricado para la construcción, con las etapas de i) preparación de un árido basado en sulfato cálcico; ií) mezclado homogéneo de un aglomerante de yeso, del árido basado en sulfato cálcico y de agua; íii) conformado del elemento prefabricado por medio de vibro compresión, incorporando notables innovaciones y ventajas. The present patent application aims to protect a prefabricated element for construction comprising at least one binder and at least one aggregate, where the binder is gypsum, and the aggregate is based on calcium sulphate plus a retarding additive. It also aims at a method of manufacturing said prefabricated element for construction, with the steps of i) preparation of an aggregate based on calcium sulphate; ii) homogeneous mixing of a gypsum binder, the aggregate based on calcium sulphate and water; iii) shaping of the prefabricated element by means of vibro compression, incorporating notable innovations and advantages.
ANTECEDENTES DE LA INVENCIÓN BACKGROUND OF THE INVENTION
Actualmente, los desarrollos de fabricación a base de sulfato de calcio, como pueden ser escayolas, yeso moreno de construcción o negro, yeso blanco, anhidrita, etc . se basan en el sistema de vertido por colada. Esta forma de trabajo ha demostrado ser eficiente para ciertas aplicaciones, por ejemplo, para la fabricación de falsos techos de escayola, realización de piezas decorativas, etc. Dicha forma de trabajo, requiere de moldes específicos que pueden ser de distintos materiales, asi como de tiempos de fraguado a veces largos que hacen que el rendimiento en la fabricación sea lento Además, el resultado obtenido, debido a la cantidad de agua de amasado necesaria para conseguir la pasta fluida, hace que el elemento fabricado tenga unas propiedades mecánicas frágiles, siendo el material resultante poroso, blando, de fácil permeabilidad al agua, etc. Currently, calcium sulphate-based manufacturing developments, such as plaster, brown or black construction plaster, white plaster, anhydrite, etc., are based on the pouring system. This way of working has proven to be efficient for certain applications, for example, for the manufacture of false plaster ceilings, the creation of decorative pieces, etc. This way of working requires specific moulds that can be made of different materials, as well as sometimes long setting times that make manufacturing performance slow. In addition, the result obtained, due to the quantity of kneading water necessary to obtain the fluid paste, causes the manufactured element to have fragile mechanical properties, the resulting material being porous, soft, easily permeable to water, etc.
Un documento ilustrativo de lo que es conocido en el estado de la técnica, sería lo descrito en la patente SU645607A, en la que se divulga un bloque de construcción fabricado a partir de agregados de yeso y un recubrimiento de PVC. En concreto se describe un proceso de fabricación de material elemental de construcción con base de yeso, que tiene la forma general de un prisma rectangular, donde el bloque de yeso preparado se embebe en un perfil de policloruro de vinilo compacto o ligero, de sección estrictamente definida, recortándose a la longitud deseada. Dicho bloque de yeso así perfilado y realizado queda revestido en sus dos extremos libres, mediante dos fondos del mismo material plástico, de dimensiones sustancíalmente iguales a la sección recta de! perfilado y soldado en sus extremos. An illustrative document of what is known in the state of the art would be that described in patent SU645607A, which discloses a construction block made from gypsum aggregates and a PVC coating. Specifically, a manufacturing process for elementary gypsum-based construction material is described, which has the general shape of a rectangular prism, where the prepared gypsum block is embedded in a compact or light polyvinyl chloride profile, with a strictly defined section, and is cut to the desired length. Said gypsum block, thus profiled and made, is covered in its two free ends, by means of two bottoms of the same plastic material, of dimensions substantially equal to the straight section of the profile and welded at its ends.
Por otro lado es conocido, del estado de la técnica, lo descrito en la patente RU1774935C un método de fabricación de productos basados en yeso y hormigón, a partir de la mezcla de aglomerantes de yeso y agregados de yeso, donde el aglomerante de yeso se mezcla con agregados de yeso reciclado y otros aditivos. También se pueden mezclar, no obstante, con cemento. Y con el fin de aumentar la resistencia al agua y a las heladas, incluye mezclar yeso de construcción dosificado y agua, colocar la mezcla resultante en un molde, seguido de una etapa de aspiración, decapado y secado. On the other hand, it is known from the state of the art that patent RU1774935C describes a method of manufacturing products based on gypsum and concrete, from the mixture of gypsum binders and gypsum aggregates, where the gypsum binder is mixed with recycled gypsum aggregates and other additives. They can also be mixed, however, with cement. And in order to increase resistance to water and frost, it includes mixing dosed construction gypsum and water, placing the resulting mixture in a mould, followed by a stage of suction, stripping and drying.
Así, y a la vista de todo lo anterior, se aprecia aún una necesidad de obtener un nuevo material para el sector de la construcción, aportando mejores prestaciones de eficiencia energética, reduzca en su producción las emisiones de CO2, y también que exista la opción o posibilidad del empleo de materiales reciclados y adicciones, evitando finalmente ia necesidad de utilizar cemento a la hora conformar una pieza prefabricada. Thus, and in view of all the above, there is still a need to obtain a new material for the construction sector, providing better energy efficiency, reducing CO2 emissions in its production, and also providing the option or possibility of using recycled materials and additives, ultimately avoiding the need to use cement when forming a prefabricated piece.
DESCRIPCIÓN DE LA INVENCIÓN DESCRIPTION OF THE INVENTION
La presente invención tiene como el objeto el definir un nuevo elemento prefabricado, asi como su método de fabricación, siguiendo un sistema de vibro compresión, empleando como materia prima el yeso como aglomerante, y áridos con base en sulfato cálcico. The present invention aims to define a new prefabricated element, as well as its manufacturing method, following a vibro compression system, using gypsum as raw material as a binder, and aggregates based on calcium sulphate.
Dicho procedimiento está destinado de forma preferente para la fabricación de elementos prefabricados, que abarca toda la base de prefabricados por vibro compresión que se obtienen mediante el sistema tradicional de cemento más áridos; bloques, bovedillas, bordillos, adoquines, casetones, prefabricados en general, empleando como base el sulfato cálcico con una formulación a base de yeso aditivado con retardantes, y distintas proporciones de agregados o carga de minerales, previamente fabricados a partir del propio sulfato cálcico. This procedure is preferably intended for the manufacture of prefabricated elements, which covers the entire base of prefabricated elements by vibrocompression obtained using the traditional system of cement plus aggregates; blocks, vaults, curbs, paving stones, caissons, prefabricated elements in general, using calcium sulphate as a base with a formulation based on gypsum with retardant additives, and different proportions of aggregates or mineral fillers, previously manufactured from calcium sulphate itself.
Se trata por tanto de llegar a una mezcla semi seca, es decir, un yeso con baja aportación de agua de hidratación. lo cual reduce el agua de amasado, utilizando por otro lado el uso de aditivos retardantes y fluidificantes. Precisar que por mezcla se entiende una masa de baja hidratación. La cantidad de agua necesaria a aportar al hemihidrato para convertirse en dihidrato es del orden de 186 g de agua por 1000 g de yeso. Dicha cantidad no permite trabajabilidad alguna salvo que el yeso ya esté parcialmente hidratado. Así, partimos sobre una base de reducir el agua de portación a un minimo de unos 200±10 gramos de agua por cada 1000 g de yeso para ese fin. El yeso a emplear se amplía a cualquier tipo hemihidratado, y hace que no sea necesario de altas temperaturas de deshidratación, dado que no es necesario superar los 160“C. En este nuevo material se amplía también a los yesos tipo a o alfa, yeso blanco, y las escayolas. The aim is therefore to achieve a semi-dry mix, i.e. a plaster with a low contribution of hydration water, which reduces the mixing water, while using retarding and fluidifying additives. It should be noted that a mix is understood as a low hydration mass. The quantity of water required to be added to the hemihydrate to convert it into a dihydrate is of the order of 186 g of water per 1000 g of gypsum. This quantity does not allow any workability unless the gypsum is already partially hydrated. Thus, we start from a basis of reducing the carrier water to a minimum of about 200±10 grams of water per 1000 g of gypsum for this purpose. The gypsum to be used is extended to any hemihydrated type, and makes high dehydration temperatures unnecessary, since it is not necessary to exceed 160“C. In this new material, it is also extended to ao alpha type gypsum, white gypsum, and plasters.
En la presente invención se definen dos fases cuya cantidad de agua, partiendo del minimo indicado, es variable según la fase del proceso que se describe a continuación: In the present invention two phases are defined, the quantity of water of which, starting from the minimum indicated, varies according to the phase of the process described below:
I) Primera fase del proceso - Fabricación de árido de yeso: Para ello se necesita la consecución de un árido como base del desarrollo. A partir de sulfato cálcico, se fabrican áridos como base del sistema de fabricación por vibro compresión, con el yeso como materia base principal. Para dicha fabricación, el agua se reduce a 185±10 g de agua por cada 1000 g de yeso, añadiendo al agua de amasado o al propio yeso, la base de retardo necesaria, opcionalmente ácido cítrico (poli carboxílico) y/o ácido crítico con dióxido de silicio. Para el sistema de amasado es factible el uso de planetaria, u otro sistema de amasado que forme los aglomerados del llamado árido de yeso. I) First phase of the process - Manufacture of gypsum aggregate: For this, it is necessary to obtain an aggregate as a basis for development. From calcium sulphate, aggregates are manufactured as a basis for the vibrocompression manufacturing system, with gypsum as the main base material. For this manufacture, the water is reduced to 185±10 g of water per 1000 g of gypsum, adding to the mixing water or to the gypsum itself, the necessary retarding base, optionally citric acid (polycarboxylic) and/or critical acid with silicon dioxide. For the mixing system, the use of a planetary mixer or another mixing system that forms the agglomerates of the so-called gypsum aggregate is feasible.
Una vez fabricado el árido, se pasa por un tamiz para retirar aquellos áridos gruesos, que se pueden aprovechar empleando un molino de martillos con rejilla de tamizado en la salida para reducir la granulometría a un máximo de 5-8mm. Esta granulometría está condicionada por las paredes de la pieza a fabricar de acuerdo con el molde de la máquina de vibro compresión. Once the aggregate has been manufactured, it is passed through a sieve to remove the coarse aggregates, which can be used by using a hammer mill with a sieve grid at the outlet to reduce the particle size to a maximum of 5-8 mm. This particle size is determined by the walls of the piece to be manufactured according to the mould of the vibrocompression machine.
Al respecto de la obtención del árido de yeso triturado sin cocción, cabe mencionar que la extracción de yeso implica de un protocolo que depende de cómo se encuentra el material en la naturaleza, según distintas calidades y formas. El material extraído se lleva a una primera fase de molienda gruesa que se realiza con machacadoras o molinos de martillos. El tamaño de las partículas requiere de un segundo proceso de machaqueo o molienda para conseguir un tamaño más fino, menor de 10mm. Por otra parte, no todas las rocas extraídas tienen la misma calidad, y el árido debe ser clasificado antes de emplearlo como material de aporte en la segunda fase que se describe a continuación. II) Segunda fase del proceso - Mezcla de áridos con yeso: Se añade el árido al yeso de acuerdo con un porcentaje definido. Para el amasado, por ejemplo empleando una planetaria, el agua se incrementa hasta un total de 210-240g por cada 1000g de yeso, podiendo llegar hasta los 300g de agua en función de la calidad del yeso. E igualmente debe adítivarse o el agua, o la mezcla de yeso más árido. Regarding the production of crushed gypsum aggregate without cooking, it is worth mentioning that the extraction of gypsum involves a protocol that depends on how the material is found in nature, according to different qualities and forms. The extracted material is taken to a first phase of coarse grinding that is carried out with crushers or hammer mills. The size of the particles requires a second process of crushing or grinding to obtain a finer size, less than 10 mm. On the other hand, not all the rocks extracted have the same quality, and the aggregate must be classified before using it as a filler material in the second phase described below. II) Second phase of the process - Mixing aggregates with gypsum: The aggregate is added to the gypsum according to a defined percentage. For mixing, for example using a planetary mixer, the water is increased up to a total of 210-240g for every 1000g of gypsum, and can reach up to 300g of water depending on the quality of the gypsum. Likewise, either the water or the gypsum plus aggregate mixture must be added.
III) Tercera fase del proceso - Vertido en la máquina de vibro compresión: Se conforman las piezas según el molde empelado, dando paso a un secado natural de entre 24 y 72 horas, en función de la humedad relativa del ambiente, si bien a los 10-20 minutos ya puede ser paletizado, de modo que se reduce considerablemente el espacio empleado para la fabricación. III) Third phase of the process - Pouring into the vibrocompression machine: The pieces are shaped according to the mould used, giving way to a natural drying period of between 24 and 72 hours, depending on the relative humidity of the environment, although after 10-20 minutes it can be palletised, thus considerably reducing the space used for manufacturing.
A la vista de lo anterior se considera diferencial con todo lo conocido en el estado de la técnica, que el elemento prefabricado de la presente invención contiene áridos basados el sulfato calcico, preparados a partir del fraguado rápido y una baja aportación de agua en la relación agua/yeso, y una posterior eliminación de las partículas muy grandes y muy pequeñas, mediante filtrado, deshidratación, respectivamente, para su posterior aprovechamiento. Asi. tanto el aglomerante como los áridos están basados en sulfato calcico, utilizándose para la fabricación la un procedimiento de vibro comprensión, con vertido en seco, por lo que la cantidad de agua utilizada es menor que en el vertido por colada. De este modo se consigue un elemento prefabricado con un procedimiento que consume menos energía, menos agua, y se reducen las emisiones de CO?. Por otro lado, el elemento prefabricado, por ser fabricado con agregados basados en sulfato calcico, presenta unas propiedades térmicas, acústicas, o de resistencia al fuego, mayores que el hormigón tradicional o la cerámica. In view of the above, it is considered to be different from everything known in the state of the art, that the prefabricated element of the present invention contains aggregates based on calcium sulphate, prepared from rapid setting and a low contribution of water in the water/gypsum ratio, and a subsequent elimination of very large and very small particles, by filtering, dehydration, respectively, for their subsequent use. Thus, both the binder and the aggregates are based on calcium sulphate, using for manufacturing a vibrocompression process, with dry pouring, so the amount of water used is less than in pouring by casting. In this way, a prefabricated element is obtained with a process that consumes less energy, less water, and reduces CO2 emissions. On the other hand, the prefabricated element, being manufactured with aggregates based on calcium sulphate, has thermal, acoustic, or fire resistance properties, greater than traditional concrete or ceramics.
Más detalladamente, ei elemento prefabricado para la construcción comprende al menos un aglomerante y al menos un árido, donde el aglomerante es yeso, y ei árido está basado en sulfato cálcico más un aditivo retardador. Como elemento prefabricado puede entenderse, de modo no limitativo, bordillos, adoquines, ladrillos, bovedillas, bloques, presentando una resistencia a la compresión de entre 14 y 20 N/mm2. In more detail, the prefabricated element for construction comprises at least one binder and at least one aggregate, where the binder is gypsum, and the aggregate is based on calcium sulphate plus a retarding additive. The prefabricated element may be understood as, but is not limited to, curbs, paving stones, bricks, vaults, blocks, presenting a compressive strength of between 14 and 20 N/mm 2 .
Cabe mencionar que el aditivo retardador, o retardante, puede emplearse mezclado en el agua final, si bien también puede añadirse en seco. Para ajustar la dosificación, sobre todo cuando se añadan áridos reciclados o cuando la fabricación de áridos de yeso no sea homogénea, se pueden establecer procedimientos, en función de la dispersión y del tamaño de áridos fabricados, asi como su clasificación granulométrica, como el método Bolomey o Fuller. It should be noted that the retarding additive, or retarder, can be used mixed in the final water, although it can also be added dry. To adjust the dosage, especially when recycled aggregates are added or when the manufacture of gypsum aggregates is not homogeneous, procedures can be established, depending on the dispersion and size. of manufactured aggregates, as well as their granulometric classification, such as the Bolomey or Fuller method.
Subrayar que el empleo de yesos con agregados minerales supone una reducción de las emisiones de CO2 en su empleo, con la obtención de mejores propiedades térmicas, acústicas, o de resistencia al fuego, superando las del hormigón tradicional o la cerámica. Así pues la invención cambia el concepto del uso del yeso como elemento de vertido por colada, por el de vertido seco. La ventaja de este nuevo material y de la pieza constructiva, es que no requiere que se utilice cemento con ia consiguiente ventaja medioambiental al reducir este último por yeso, dado que en la fabricación de una pieza se emplea una menor energía de fabricación muy significativa comparada con los materiales convencionales que comprenden, por ejemplo, cemento. Además, el yeso es un elemento considerado ideal para la economía circular, pues es reutilizable al 100%. It should be noted that the use of gypsum with mineral aggregates means a reduction in CO2 emissions, with the achievement of better thermal, acoustic or fire resistance properties, surpassing those of traditional concrete or ceramics. Thus, the invention changes the concept of using gypsum as a pouring element to that of dry pouring. The advantage of this new material and the construction piece is that it does not require the use of cement, with the consequent environmental advantage of reducing the latter by gypsum, since in the manufacture of a piece a very significant lesser manufacturing energy is used compared to conventional materials that comprise, for example, cement. In addition, gypsum is an element considered ideal for the circular economy, since it is 100% reusable.
Añadir que el uso del árido a base de sulfato cálcico permite Integrar en la matriz sin modificar las propiedades que cualifican al yeso, sin merma de sus propiedades físicas como son la transmisión de calor, resistencia al fuego, etc. Y una vez mezclado con un yeso de baja hidratación, y una vez vibrado, se consigue reducir la presión de prensado, en las paredes del molde, siendo que dichos áridos son elementos incompresibles. It should be added that the use of calcium sulphate-based aggregate allows it to be integrated into the matrix without modifying the properties that qualify the plaster, without reducing its physical properties such as heat transmission, fire resistance, etc. And once mixed with a low hydration plaster, and once vibrated, it is possible to reduce the pressing pressure on the walls of the mould, given that said aggregates are incompressible elements.
Preferentemente, el peso del aglomerante está entre el 40% y el 70% del peso del eiemento prefabricado, io que se traduce en un peso de 400g a 700g del total de 1000g del elementa prefabricado, presentando así unas propiedades optimizadas en cuanto a resistencia mecánica y térmica. En concreto, el incremento de la resistencia mecánica a la compresión, tomando como referencia del yeso negro en colada, es de 2N/mmz pudiendo llegar hasta valores de 20N/mm2, io que supone un incremento del 1000%. Preferably, the weight of the binder is between 40% and 70% of the weight of the prefabricated element, which translates into a weight of 400g to 700g of the total 1000g of the prefabricated element, thus presenting optimized properties in terms of mechanical and thermal resistance. Specifically, the increase in mechanical compressive strength, taking cast black plaster as a reference, is 2N/ mm and can reach values of up to 20N/mm2, which represents an increase of 1000%.
Complementariamente, el peso del árido está entre ei 30% y el 60% del peso dei elemento prefabricado, lo que se traduce en un peso de 300g a 600 g de la mezcla del total de 1000g del elemento prefabricado, presentando así unas propiedades optimizadas en cuanto a resistencia mecánica y térmica. En concreto, ei coeficiente de variación térmica X (kcal/h m K o W/ma.aC) se reduce en más de un 30% Opcionalmente, el aglomerante es uno dei grupo de yeso negro, yeso blanco, escayola o yeso alfa, lo cual aporta un grado de fiexibilidad a la mezcla, con alternativas de posibles materiales integrantes. In addition, the weight of the aggregate is between 30% and 60% of the weight of the prefabricated element, which translates into a weight of 300 g to 600 g of the mixture out of the total of 1000 g of the prefabricated element, thus presenting optimized properties in terms of mechanical and thermal resistance. Specifically, the coefficient of thermal variation X (kcal/hm K or W/m a . a C) is reduced by more than 30%. Optionally, the binder is one of the group of black plaster, white plaster, plaster or alpha plaster, which provides a degree of flexibility to the mixture, with alternatives of possible constituent materials.
Adicionalmente, el árido es uno del grupo de árido prefabricado, árido reciclado, árido de yeso directamente de cantera sin tratamiento de cocción, o una mezcla de árido prefabricado con árido reciclado, lo cual también aporta un grado de fiexibilidad a la mezcla, con alternativas de posibles materiales integrantes. Additionally, the aggregate is one of the group of prefabricated aggregate, recycled aggregate, gypsum aggregate directly from the quarry without cooking treatment, or a mixture of prefabricated aggregate with recycled aggregate, which also provides a degree of flexibility to the mixture, with alternatives of possible constituent materials.
Mencionar que es por tanto posible mezclar con una parte adicional de áridos reciclados, que pueden comprender yeso, además de áridos fabricados a partir de cerámica, como el caso concreto de la arlita, o la perlita. Los distintos tipos de áridos están enfocados a distintas aplicaciones, en función de la calidad de los mismos, así como del contenido o mezcla de dichos áridos. Por áridos reciclados se ha de entender aquellos que son resultado del tratamiento de los materiales inorgánicos que previamente se han utilizado en la construcción. Por tanto, son residuos de construcción y demolición. It should be noted that it is therefore possible to mix with an additional portion of recycled aggregates, which may include gypsum, as well as aggregates made from ceramics, such as in the specific case of arlite or perlite. The different types of aggregates are focused on different applications, depending on their quality, as well as the content or mixture of said aggregates. Recycled aggregates are understood to be those that are the result of the treatment of inorganic materials that have previously been used in construction. Therefore, they are construction and demolition waste.
El tipo de árido utilizado también viene dado por la fracción granuiométrica que se busca en la mezcla final, debiendo ser preferentemente un árido fino de no más de 8mm, es decir, arena, o gravínes, descartándose la grava y la zahorra. Los áridos reciclados procedentes de hormigón, se obtienen básicamente de las cimentaciones, estructuras de edificios, prefabricados, etc. También se contempla el uso de áridos procedentes de capas de aglomerado asfáltico, y de otros áridos reciclados procedentes de residuos cerámicos limpios, y los áridos procedentes de mezclas. Los áridos procedentes del hormigón son los más idóneos, por sus propiedades mecánicas, si bien pueden escogerse áridos procedentes de residuos cerámicos limpios, y los áridos procedentes de mezclas. Su cantidad máxima viene a ser de hasta un 70%, en función también de la calidad del yeso, y de la pureza del mismo. The type of aggregate used is also determined by the particle size fraction sought in the final mixture, preferably a fine aggregate of no more than 8 mm, that is, sand or gravel, discarding gravel and ballast. Recycled aggregates from concrete are basically obtained from foundations, building structures, prefabricated elements, etc. The use of aggregates from asphalt agglomerate layers and other recycled aggregates from clean ceramic waste and aggregates from mixtures is also contemplated. Aggregates from concrete are the most suitable due to their mechanical properties, although aggregates from clean ceramic waste and aggregates from mixtures can be chosen. Its maximum quantity is up to 70%, also depending on the quality of the plaster and its purity.
Más específicamente, el árido prefabricado para el elemento prefabricado para la construcción comprende una granulometría de i) tamaño máximo de 10 mm, con una presencia de entre el 1 % y el 5 %; i¡) tamaño entre 3-5 mm, con una presencia de entre el 75% y el 88 %; iii) tamaño entre 0.2-0.05mm, con una presencia de entre el 10% y el 20 %; iv) tamaño entre 0.02- 0.005mm, con una presencia de entre ei 1% y el 5 %;. y comprende además entre el 17,36% y el 23,08% de agua del peso del elementa prefabricado y entre el 0,01% y el 0,2% de aditivo del peso del elemento prefabricado, donde el aditivo está basado en un ácido poii carboxílico Se define dicha granulometria según la clasificación Attemberg, presentando así unas propiedades optimizadas en cuanto a resistencia mecánica y térmica, en la linea de lo mencionado anteriormente. More specifically, the prefabricated aggregate for the prefabricated element for construction comprises a granulometry of i) maximum size of 10 mm, with a presence of between 1% and 5%; i¡) size between 3-5 mm, with a presence of between 75% and 88%; iii) size between 0.2-0.05mm, with a presence of between 10% and 20%; iv) size between 0.02- 0.005mm, with a presence of between 1% and 5%; and further comprises between 17.36% and 23.08% of water of the weight of the prefabricated element and between 0.01% and 0.2% of additive of the weight of the prefabricated element, where the additive is based on a polycarboxylic acid. This granulometry is defined according to the Attemberg classification, thus presenting optimized properties in terms of mechanical and thermal resistance, in line with what was mentioned above.
Subrayar que en una primera fase se produce la prefabricación de áridos basados en un material basado en yeso o sulfato calcio de muy baja hidratación. Las características del árido prefabricado son las de un material incompresible y de baja absorción de agua, debido a una estructura capilar cerrada. Esto se consigue mediante un fraguado rápido y una baja aportación de agua en ia relación agua/yeso. It should be noted that the first phase involves the prefabrication of aggregates based on a material based on gypsum or calcium sulphate with very low hydration. The characteristics of the prefabricated aggregate are those of an incompressible material with low water absorption, due to a closed capillary structure. This is achieved through rapid setting and a low water contribution in the water/gypsum ratio.
La segunda fase del proceso de fabricación para conseguir el elemento prefabricado, consiste en obtener una mezcla homogénea de los áridos con el resto de la matriz de yeso. Debido a la poca absorción de agua, la cantidad de agua que se necesita para la mezcla será variable, aunque el agua final en este paso se estima entre 210-300g por cada 1000g de yeso. En el caso de escayolas, este porcentaje varía por las mejores propiedades de las mismas comparadas con el yeso de construcción. El porcentaje de hidratación podría ser superior, en función de la pureza y grado de molido, llegando a una aportación que puede superar los 300 gramos, es decir, 250-350 g por cada 1000 g de escayola. The second phase of the manufacturing process to obtain the prefabricated element consists of obtaining a homogeneous mixture of the aggregates with the rest of the gypsum matrix. Due to the low water absorption, the amount of water needed for the mixture will vary, although the final water in this step is estimated between 210-300g for every 1000g of gypsum. In the case of plaster, this percentage varies due to the better properties of the same compared to construction plaster. The percentage of hydration could be higher, depending on the purity and degree of grinding, reaching a contribution that can exceed 300 grams, that is, 250-350 g for every 1000 g of plaster.
A modo de resumen general del material del elemento prefabricado, una dosificación general del material comprende a) 400 - 700 g de yeso, podiendo ser yeso negro, yeso blanco, escayola o yeso o; b) 300 - 700 g de árido, pudiendo ser árido prefabricado basado en sulfato calcico, árido de yeso seleccionado de la extracción de la cantera, árido reciclado o una mezcla de árido prefabricado de yeso con árido reciclado; c) 210 - 300 g de agua; d) 0,1 - 2 g de aditivo de agua basado en ácidos poli carboxílicos. As a general summary of the precast element material, a general dosage of the material comprises a) 400 - 700 g of gypsum, which may be black gypsum, white gypsum, plaster of Paris or gypsum; b) 300 - 700 g of aggregate, which may be precast aggregate based on calcium sulphate, gypsum aggregate selected from quarry extraction, recycled aggregate or a mixture of precast gypsum aggregate with recycled aggregate; c) 210 - 300 g of water; d) 0.1 - 2 g of water additive based on polycarboxylic acids.
Preferentemente, ei ácido poli carboxíiico es ácido cítrico o ácido cítrico con dióxido de silicio, y también un compuesto de melamina y/o saies. por ejemplo ácido cítrico con base de rnelamina y/o sales, todo ello al objeto de añadir un aditivo retardador que retarde el fraguado. Preferably, the polycarboxylic acid is citric acid or citric acid with silicon dioxide, and also a melamine compound and/or salts, for example citric acid with a melamine base and/or salts, all with the aim of adding a retarding additive that delays setting.
En una realización preferida de la invención, el árido reciclado comprende una granulometria de i) tamaño máximo de 10 mm, con una presencia de entre el 1% y el 8%: ii) tamaño entre 3-5 mm, con una presencia de entre el 68% y el 88%; lii) tamaño entre 0.2 0.05mm, con una presencia de entre el 8% y el 21%; iv) entre 0.02-0.005mm, con una presencia de entre el 1% y el 6%. Dicho árido reciclado conlleva la ventaja de presentar una mayor sostenibilidad medioambiental. In a preferred embodiment of the invention, the recycled aggregate comprises a granulometry of i) maximum size of 10 mm, with a presence of between 1% and 8%: ii) size between 3-5 mm, with a presence of between 68% and 88%; lii) size between 0.2-0.05mm, with a presence of between 8% and 21%; iv) between 0.02-0.005mm, with a presence of between 1% and 6%. This recycled aggregate has the advantage of being more environmentally sustainable.
Complementariamente, el árido prefabricado se puede basar en una sola granulometrla de i) tamaño máximo de 10 mm, con una presencia de entre el 0% y el 10 %; ii) tamaño entre 3-5 mm, con una presencia de entre el 0% y el 100 %; iii) tamaño entre 0.2-0.05mm, con una presencia de entre el 0% y ai 100 %; ív) tamaño entre 0.02-0.005mm, con una presencia de entre ei 1% y el 10 %; , y comprende además entre el 17,36% y el 23,08% de agua del peso del elemento prefabricado y entre el 0,01% y el 0,2% de aditivo del peso del elemento prefabricado, donde ei aditivo está basado en un ácido poli carboxllico, en un compuesto de meiamina y/o sales, presentando asi unas propiedades optimizadas en cuanto a resistencia mecánica y térmica. En concreto, el incremento de ia resistencia a la compresión puede llegar a ser del 700% (de 2N/mmí a 14N/mm¿), mejorándose también las propiedades térmicas en un 20% dependiendo de la fracción empleada. Additionally, the prefabricated aggregate can be based on a single particle size distribution of i) maximum size of 10 mm, with a presence of between 0% and 10 %; ii) size between 3-5 mm, with a presence of between 0% and 100 %; iii) size between 0.2-0.05 mm, with a presence of between 0% and 100 %; iv) size between 0.02-0.005 mm, with a presence of between 1% and 10 %; , and also comprises between 17.36% and 23.08% of water by weight of the prefabricated element and between 0.01% and 0.2% of additive by weight of the prefabricated element, where the additive is based on a polycarboxylic acid, a methamine compound and/or salts, thus presenting optimized properties in terms of mechanical and thermal resistance. Specifically, the increase in compressive strength can reach 700% (from 2 N/mm í to 14 N/mm ¿ ), with thermal properties also improving by 20% depending on the fraction used.
Por otro lado, el árido comprende una proporción hasta del 30% de arlita o periita, más árido prefabricado, dado que se pueden añadir áridos reciclados. Asi, la proporción aportada de árido prefabricado puede sustituirse por una fracción de dicho árido reciclado. La matriz de yeso admite hasta un 70% máximo de árido en la matriz sin contar el agua, si bien, estos áridos merman las propiedades del sulfato calcico, por tanto, se considera que una fracción razonable puede ser de un 10%-40% de árido reciclado respecto del 100% del árido, o de arlita o periita. On the other hand, the aggregate comprises a proportion of up to 30% of arlite or perite, plus prefabricated aggregate, given that recycled aggregates can be added. Thus, the proportion of prefabricated aggregate supplied can be replaced by a fraction of said recycled aggregate. The gypsum matrix admits up to a maximum of 70% of aggregate in the matrix without counting the water, although these aggregates reduce the properties of calcium sulphate, therefore, it is considered that a reasonable fraction can be 10%-40% of recycled aggregate with respect to 100% of the aggregate, or of arlite or perite.
En cuanto a las fracciones o granulometrla de esos áridos reciclados, preferentemente tienen ias proporciones de: a) grava 10 mm en un 1 - 8 %; b) grava fina 5-3 mm en un 68 - 88 %; c) arena fina 0.2-0.05 en un 8 - 21 %; d) limos 0.02-0.005 en un 1 - 6 %. siendo áridos procedentes del triturado o residuos de hormigón, procedentes de residuos cerámicos limpios o los áridos procedentes de una mezcla de ambos. As for the fractions or granulometry of these recycled aggregates, they preferably have the proportions of: a) 10 mm gravel in 1 - 8 %; b) fine gravel 5-3 mm in 68 - 88 %; c) fine sand 0.2-0.05 in 8 - 21 %; d) silt 0.02-0.005 in 1 - 6 %. being aggregates from crushed or concrete waste, from clean ceramic waste or aggregates from a mixture of both.
Es también objeto de la presente invención un método de fabricación de elemento prefabricado para la construcción, que comprende las etapas de: i) preparación de un árido basado en sulfato calcico; ¡i) mezclado homogéneo de un aglomerante de yeso, del árido basado en sulfato cálcico y de agua; iii) conformado del elemento prefabricado por medio de vibro compresión, de manera que se liega a un elemento prefabricado adecuadamente conformado según lo descrito anteriormente. Señalar que la vibro compresión en yeso y/o sulfato cálcico reduce significativamente tiempo de manejo, si se compara con la vibro compresión de hormigón. Tampoco necesita cámara de curado o adición de agua adicional. Precisar que el árido fabricado se añade al yeso para una posterior vibro compresión, dado que el vibrado elimina parte dei aire de la mezcla y las oquedades, siendo el proceso de vibrado una parte fundamental del proceso de fijación de la matriz, que consiste en la homogenización de dichos áridos. The present invention also relates to a method of manufacturing a prefabricated element for construction, which comprises the steps of: i) preparing an aggregate based on calcium sulphate; ii) homogeneous mixing of a gypsum binder, the aggregate based on calcium sulphate and water; iii) shaping the prefabricated element by means of vibro compression, such that a prefabricated element is obtained that is suitably shaped as described above. It should be noted that vibrocompression in gypsum and/or calcium sulphate significantly reduces handling time when compared to vibrocompression in concrete. It also does not require a curing chamber or the addition of additional water. It should be noted that the manufactured aggregate is added to the gypsum for subsequent vibrocompression, since vibration eliminates part of the air in the mixture and the cavities, the vibration process being a fundamental part of the matrix fixing process, which consists of homogenising said aggregates.
Mencionar por otro lado que, tras pruebas realizadas en laboratorio, al tratar de obtener piezas en moldes, sometidas a un proceso de compresión, dicha compresión implica en la matriz un aumento considerable de la presión lateral; es decir, perpendicular la presión de empuje de la mezcla sobre el molde. Esta presión, impide o dificulta enormemente el desmoldeo posterior, e impide la posibilidad de obtener paredes finas, es decir, de entre 0,5-20 mm, complicándose la fabricación en piezas cuya altura en la dirección de la compresión superen los 150 mm. La incorporación del árido de yeso solventa este problema haciendo factible la fabricación de elementos prefabricados, empleando la presión y la vibro compresión. It should also be mentioned that, after laboratory tests, when trying to obtain parts in moulds subjected to a compression process, said compression implies a considerable increase in lateral pressure on the matrix; that is, perpendicular to the pressure pushing the mixture on the mould. This pressure prevents or greatly hinders subsequent demoulding, and prevents the possibility of obtaining thin walls, that is, between 0.5-20 mm, complicating the manufacture of parts whose height in the compression direction exceeds 150 mm. The incorporation of gypsum aggregate solves this problem, making it feasible to manufacture prefabricated elements, using pressure and vibrocompression.
Subrayar que el método de fabricación de elemento prefabricado para ia construcción comprende la adición de un aditivo de agua basado en un ácido poli carboxílico o con dióxido de silicio. It should be noted that the method of manufacturing prefabricated elements for construction involves the addition of a water additive based on a polycarboxylic acid or silicon dioxide.
En una realización preferida de la invención del método de fabricación de elemento prefabricado para la construcción, la preparación de una mezcla que comprende un árido basado en sulfato cálcico, agua y aditivo y que comprende una parte de áridos, áridos reciclados, áridos de cantera, ahita o perlita, y comprende las etapas de: i.1) mezclado del sulfato cálcico con agua, aditivo y áridos: i.2) amasado de dicha mezcla de sulfato calcico con agua, aditivo y áridos en una mezcladora horizontal rotativa hasta la obtención de granos de sulfato cálcico de tamaño homogéneo menor de 8mm; i.3) vertido de la mezcla en una máquina de vibro compresión para obtención de los elementos prefabricados, de modo que ios elementos prefabricados obtenidos con dicho procedimiento presentan una y una resistencia a la compresión superior entre 14 y 20 N/mm?. Precisar que la mezcladora horizontal puede ser una rotativa de palas o picazas, que hay una etapa de tamizado para retirar aquellos áridos gruesos, es decir, diámetros mayores a Bmm. Precisar que para la obtención de estos áridos se puede optar por distintos procedimientos de fabricación. Por ejemplo, con una mezcladora horizontal de palas o picazas, o simplemente máquinas de mezclado del tipo planetaria. En el primer caso, se llega a una mayor calidad de los áridos, pues el yeso, una vez en la cuba, se somete a un pulverizado del agua, previamente aditivada con un retardador del fraguado. In a preferred embodiment of the invention of the method of manufacturing prefabricated elements for construction, the preparation of a mixture comprising an aggregate based on calcium sulphate, water and additive and comprising a part of aggregates, recycled aggregates, quarry aggregates, ahite or perlite, and comprises the steps of: i.1) mixing the calcium sulphate with water, additive and aggregates; i.2) kneading said mixture of calcium sulphate with water, additive and aggregates in a rotary horizontal mixer until obtaining calcium sulphate grains of homogeneous size less than 8 mm; i.3) pouring the mixture into a vibro compression machine to obtain the prefabricated elements, so that the prefabricated elements obtained with said process have a compressive strength greater than between 14 and 20 N/mm ? . Please note that the horizontal mixer can be a rotary mixer with blades or pickaxes, and that there is a screening stage to remove coarse aggregates, i.e., diameters greater than Bmm. It should be noted that different manufacturing processes can be used to obtain these aggregates. For example, with a horizontal mixer with paddles or pickaxes, or simply planetary type mixing machines. In the first case, a higher quality of aggregates is achieved, since the plaster, once in the vat, is sprayed with water, previously added with a setting retarder.
Las palas rotativas van mezclando en continúo formando bolas o granos de tamaño homogéneo y diámetros menores de 7mm. La cantidad de agua inicial se fija en 185±10 g por cada 1000 g de yeso. Para el caso de la maquina planetaria, las bolas o granos no suelen ser homogéneas y es necesario un cribado posterior para eliminar la fracción gruesa. En el caso de aditivar el agua con ácidos poli carboxílicos, por ejemplo, con el ácido cítrico, este se fija entre 0,1- 2g por cada 1000g de yeso a mezclar. The rotating blades continuously mix, forming balls or grains of homogeneous size and diameters less than 7 mm. The initial quantity of water is set at 185±10 g per 1000 g of gypsum. In the case of the planetary machine, the balls or grains are not usually homogeneous and a subsequent screening is necessary to eliminate the coarse fraction. In the case of adding polycarboxylic acids to the water, for example, with citric acid, this is set between 0.1-2 g per 1000 g of gypsum to be mixed.
Adicionalmente, la preparación de un árido basado en sulfato cálcico comprende una etapa previa de obtención de agua tratada para el mezclado, donde el agua tratada comprende un retardador del fraguado, de modo que el agua de mezcla ya incluye dicho componente. Additionally, the preparation of an aggregate based on calcium sulphate comprises a prior stage of obtaining treated water for mixing, where the treated water comprises a setting retarder, so that the mixing water already includes said component.
Complementariamente, la preparación de un árido basado en sulfato calcico comprende las etapas de: i.1 ) mezclado del sulfato cálcico con agua y aditivo; i.2) pulverizado de la mezcla de sulfato cálcico con agua y aditivo en una mezcladora horizontal rotativa hasta la obtención de un grano de sulfato cálcico de tamaño homogéneo; i.3) tamizado del árido de sulfato cálcico de diámetro menor a 8mm; i.4) molienda de los granos de sulfato cálcico de diámetro mayor a 10mm en un molino de fragmentación; i.5) tratamiento de deshidratación dei sulfato cálcico. Additionally, the preparation of a calcium sulphate-based aggregate comprises the following steps: i.1) mixing the calcium sulphate with water and additive; i.2) pulverizing the mixture of calcium sulphate with water and additive in a rotary horizontal mixer until obtaining a calcium sulphate grain of homogeneous size; i.3) sieving the calcium sulphate aggregate with a diameter less than 8 mm; i.4) grinding the calcium sulphate grains with a diameter greater than 10 mm in a fragmentation mill; i.5) dehydration treatment of the calcium sulphate.
Precisar que en este caso la mezcladora horizontai puede ser rotativa de palas o picazas. Que el tamizado implica la retirada de áridos de un grosor mayor al deseado, en este caso de diámetros mayores a 8mm. Que la molienda de los granos, o gravas, de árido en un molino de fragmentación es para eliminar las partículas más grandes, y para reducir la granulometría a un máximo de 5-8mm, y que puedan ser reutilizadas en fracciones más pequeñas. Y que el tratamiento de deshidratación del sulfate cálcico es para eliminar las partículas más pequeñas, para ser reutilizadas de nuevo en ia realización del árido. Y que los áridos obtenidos con el procedimiento anterior presentan una dureza shore C de 98-100, una absorción de humedad inferior al 0.1 -0,5% y una resistencia a la compresión superior a los 20 N/mm2. Señalar también que, para la realización de las piezas vibro comprimidas, el material de aporte requiere de un tamizado y/o cribado donde se eliminen los limos y la arena fina menor de 0.1 mm, así como la grava que exceda de los 7, 8 mm de diámetro de partícula promedio. En este sentido, las partículas más grandes, pueden someterse a un molino de fragmentación para ser reutilizadas en fracciones más pequeñas, y las finas, se pueden someter a un proceso de deshidratación del sulfato cálcico para ser reutilizadas de nuevo en la realización del árido. Así pues se llega a un aprovechamiento del 100 % del yeso, lo cual es todo logro, a lo que no se suele llegar en los procesos conocidos de fabricación industrial de materiales constructivos. It should be noted that in this case the horizontal mixer can be a rotary mixer with blades or pickaxes. That screening involves removing aggregates with a thickness greater than desired, in this case with diameters greater than 8 mm. That the grinding of the grains, or gravel, of aggregate in a fragmentation mill is to eliminate the largest particles, and to reduce the granulometry to a maximum of 5-8 mm, and that they can be reused in smaller fractions. And that the dehydration treatment of calcium sulphate is to eliminate the smallest particles, to be reused again in the production of the aggregate. And that the aggregates obtained with the previous procedure have a shore C hardness of 98-100, a humidity absorption of less than 0.1 -0.5% and a compressive strength greater than 20 N/mm 2 . It should also be noted that, in order to produce vibro-compressed pieces, the filler material requires screening and/or sifting to remove silt and fine sand smaller than 0.1 mm, as well as gravel exceeding 7 or 8 mm in average particle diameter. In this sense, the larger particles can be subjected to a fragmentation mill to be reused in smaller fractions, and the fine particles can be subjected to a calcium sulphate dehydration process to be reused again in the production of the aggregate. Thus, 100% of the gypsum is used, which is quite an achievement, something that is not usually achieved in the known industrial manufacturing processes of construction materials.
Más concretamente, la cantidad de agua es de entre 14,89% al 17,01% del peso del elemento prefabricado, presentando así unas propiedades optimizadas en cuanto a resistencia mecánica y térmica. En concreto, el incremento de la resistencia a la compresión puede llegar a ser hasta del 1000% (de 2N/mm2 a 20N/mmz), mejorándose también las propiedades térmicas hasta en un 30%, en función del tipo de pieza fabricada. More specifically, the amount of water is between 14.89% and 17.01% of the weight of the prefabricated element, thus presenting optimized properties in terms of mechanical and thermal resistance. Specifically, the increase in compressive strength can reach up to 1000% (from 2 N/mm 2 to 20 N/mm z ), also improving thermal properties by up to 30%, depending on the type of part manufactured.
En los dibujos adjuntos se muestra, a titulo de ejemplo no limitativo, un elemento prefabricado para la construcción, y método asociado, constituido de acuerdo con la invención. Otras características y ventajas de dicho un elemento prefabricado para la construcción, y método asociado, objeto de la presente invención, resultarán evidentes a partir de la descripción de una realización preferida, pero no exclusiva, que se ilustra a modo de ejemplo no limitativo en los dibujos que se acompañan. The attached drawings show, by way of non-limiting example, a prefabricated element for construction, and associated method, constituted in accordance with the invention. Other characteristics and advantages of said prefabricated element for construction, and associated method, object of the present invention, will be evident from the description of a preferred, but not exclusive, embodiment, which is illustrated by way of non-limiting example in the attached drawings.
BREVE DESCRIPCIÓN DE LOS DIBUJOS BRIEF DESCRIPTION OF THE DRAWINGS
Figura 1- Vista de varios elementos prefabricados para la construcción, de acuerdo con la presente invención; Figure 1- View of various prefabricated elements for construction, in accordance with the present invention;
Figura 2- Vista de un recipiente con la mezcla varios materiales según el método de fabricación del elemento prefabricado, de acuerdo con la presente invención; Figure 2- View of a container with the mixture of various materials according to the manufacturing method of the prefabricated element, in accordance with the present invention;
Figura 3- Vista de un recipiente con el resultado de árido en forma de grano según el método de fabricación del elemento prefabricado, de acuerdo con la presente invención; Figure 3- View of a container with the resulting grain-shaped aggregate according to the manufacturing method of the prefabricated element, in accordance with the present invention;
Figura 4- Vista de un contenedor lleno de árido así como la materia prima de ia que se obtiene según el método de fabricación del elemento prefabricado, de acuerdo con la presente invención; Figure 4- View of a container filled with aggregate as well as the raw material obtained according to the manufacturing method of the prefabricated element, in accordance with the present invention;
Figura 5- Vista en perspectiva de una máquina mezcladora, de acuerdo con la presente invención; Figure 5- Perspective view of a mixing machine, according to the present invention;
Figura 6- Vísta en perspectiva de un molino que recibe el árido y los transforma en grano, de acuerdo con la presente invención; Figure 6- Perspective view of a mill that receives the aggregate and transforms it into grain, in accordance with the present invention;
Figura 7- Vista de la adición de un retardador sobre agua mezclada con árido con base de sulfato cálcico, de acuerdo con la presente invención; Figure 7- View of the addition of a retarder on water mixed with calcium sulphate-based aggregate, in accordance with the present invention;
Figura 8- Vista de los varios elementos que integran el método de fabricación del elemento prefabricado, de acuerdo con la presente invención; Figure 8- View of the various elements that make up the manufacturing method of the prefabricated element, in accordance with the present invention;
DESCRIPCIÓN DE UNA REALIZACIÓN PREFERENTE DESCRIPTION OF A PREFERRED EMBODIMENT
A ia vista de las mencionadas figuras y, de acuerdo con la numeración adoptada, se puede observar en ellas un ejemplo de realización preferente de la invención, comprendiendo las partes y elementos que se indican y describen en detalle a continuación. In view of the aforementioned figures and, in accordance with the numbering adopted, one can observe in them a preferred embodiment of the invention, comprising the parts and elements that are indicated and described in detail below.
En la figura 1 se puede observar una vista de varios elementos prefabricados (1) para la construcción, conformando una pared o muro. Figure 1 shows a view of several prefabricated elements (1) for construction, forming a wall.
En la figura 2 se puede observar una vista de un recipiente con la mezcla varios materiales según el método de fabricación del elemento prefabricado (1), en concreto de un árido (3) con un retardador (9), junto con un aglomerante (2) con base de yeso (21 ), a la que se añade agua (4) con al menos un aditivo (5). En la figura 3 se puede observar una vista de un recipiente con el resultado de un árido (3) en forma de grano (6) según el método de fabricación del elemento prefabricado (1 ). Figure 2 shows a view of a container with the mixture of various materials according to the manufacturing method of the prefabricated element (1), specifically an aggregate (3) with a retarder (9), together with a binder (2) with a gypsum base (21), to which water (4) is added with at least one additive (5). Figure 3 shows a view of a container with the result of an aggregate (3) in the form of grain (6) according to the manufacturing method of the prefabricated element (1).
En la figura 4 se puede observar una vista de un contenedor lleno de árido (3) asi como la materia prima de la que se obtiene según el método de fabricación del elemento prefabricado (1). Figure 4 shows a view of a container filled with aggregate (3) as well as the raw material from which it is obtained according to the manufacturing method of the prefabricated element (1).
En la figura 5 se puede observar una vísta en perspectiva de una máquina mezcladora (7). Figure 5 shows a perspective view of a mixing machine (7).
En la figura 6 se puede observar una vista en perspectiva de un molino (8) que recibe el árido (3) y los transforma en grano (6). Figure 6 shows a perspective view of a mill (8) that receives the aggregate (3) and transforms it into grain (6).
En la figura 7 se puede observar una vista de la adición de un retardador (9) sobre agua (4) mezclada con árido (3) con base de sulfato calcico (31 ). Figure 7 shows a view of the addition of a retarder (9) to water (4) mixed with aggregate (3) based on calcium sulphate (31).
En la figura 8 se puede observar una vísta de los varios elementos que integran el método de fabricación del elemento prefabricado ( 1 ), constituidos por un aglomerante (2) con base de yeso (21), por otro lado un árido (3), a lo que se añade agua (4) con algún aditivo (5), preferentemente un retardador (9), con el concurso de una máquina mezcladora (7) y de un molino (8). con las funcionalidades y según las etapas y fases descritas anteriormente. Figure 8 shows a view of the various elements that make up the manufacturing method of the prefabricated element (1), consisting of a binder (2) with a gypsum base (21), on the other hand an aggregate (3), to which water (4) is added with some additive (5), preferably a retarder (9), with the help of a mixing machine (7) and a mill (8). with the functionalities and according to the stages and phases described above.
De modo ilustrativo, y no limitativo, se exponer a continuación cuatro ejemplos de realización de la invención, que darían lugar a un elemento prefabricado (1) con las propiedades y prestaciones más arriba explicadas: By way of illustration, and not limitation, four examples of the invention are set out below, which would give rise to a prefabricated element (1) with the properties and features explained above:
Ejemplo 1 : Example 1:
700 g de yeso negro, yeso blanco, escayola o yeso a 700 g of black plaster, white plaster, plaster of paris or plaster of paris
300 g de árido prefabricado 300 g of prefabricated aggregate
- 240 g de agua - 240 g of water
- 1 g de ácido poli carboxílico, por ejemplo, ácido critico - 1 g of polycarboxylic acid, e.g. critical acid
Ejemplo 2: Example 2:
- 400 g de yeso negro, yeso blanco, escayola o yeso a - 400 g of black plaster, white plaster, plaster of paris or plaster of paris
- 600 g de árido prefabricado/árido seleccionado de cantera de yeso - 600 g of prefabricated aggregate/selected aggregate from gypsum quarry
- 240 g de agua - 1 g de ácido poli carboxílico, por ejemplo, ácido crítico - 240 g of water - 1 g of polycarboxylic acid, e.g. critical acid
Ejemplo 3: Example 3:
- 700 g de yeso negro, yeso blanco, escayola o yeso α - 700 g of black plaster, white plaster, plaster of paris or α plaster
- 240 g de árido prefabricado/árido seleccionado de cantera de yeso - 240 g of prefabricated aggregate/selected aggregate from gypsum quarry
- 60 g de áridos reciclados y/o arlita - 60 g of recycled aggregates and/or arlite
- 240 g de agua - 240 g of water
- 1 g de ácido poli carboxílico, por ejemplo, ácido crítico - 1 g of polycarboxylic acid, e.g. critical acid
Ejemplo 4: Example 4:
- 400 g de yeso negro, yeso blanco, escayola o yeso o - 400 g of black plaster, white plaster, plaster of paris or plaster of paris
- 480 g de árido prefabricado/árido seleccionado de cantera de yeso - 480 g of prefabricated aggregate/selected aggregate from gypsum quarry
- 120 g de áridos reciclados y/o arlita - 120 g of recycled aggregates and/or arlite
•• 240 g de agua •• 240 g of water
- 1 g de ácido poli carboxílico, por ejemplo, ácido critico. - 1 g of polycarboxylic acid, for example, critical acid.
Más en particular, tal y como se observa en las figuras 2 y 8, el elemento prefabricado (1 ) para la construcción comprende al menos un aglomerante (2) y al menos un árido (3), donde el aglomerante (2) es yeso (21 ), y el árido (3) está basado en sulfato calcico (31) más un aditivo (5) retardador (9). More particularly, as seen in Figures 2 and 8, the prefabricated element (1) for construction comprises at least one binder (2) and at least one aggregate (3), where the binder (2) is gypsum (21), and the aggregate (3) is based on calcium sulphate (31) plus a retarder additive (5) (9).
Preferentemente, tal y como se observa en las figuras 1 y 2, el peso del aglomerante (2) está entre el 40% y el 70% del peso del elemento prefabricado (1). Preferably, as seen in figures 1 and 2, the weight of the binder (2) is between 40% and 70% of the weight of the prefabricated element (1).
Complementariamente, tal y como se observa en las figuras 1 y 2, el peso del árido (3) está entre el 30% y el 60% del peso del elemento prefabricado (1 ). Additionally, as can be seen in figures 1 and 2, the weight of the aggregate (3) is between 30% and 60% of the weight of the prefabricated element (1).
Cabe señalar que, tal y como se observa en las figuras 1 y 2, el aglomerante (2) es uno del grupo de yeso (21 ) negro, yeso (21) blanco, escayola o yeso (21 ) alfa. It should be noted that, as seen in Figures 1 and 2, the binder (2) is one of the group of black gypsum (21), white gypsum (21), plaster or alpha gypsum (21).
Por otro lado, tal y como se observa en las figuras 3 y 4, el árido (3) es uno del grupo de árido (3) prefabricado, árido (3) reciclado, árido (3) de yeso directamente de cantera sin tratamiento de cocción, o una mezcla de árido (3) prefabricado con árido (3) reciclado. Precisar a modo de ejemplo que, en una realización preferida de la invención, en cuanto al árido (3) reciclado, la cantidad máxima está entre el 10% y el 40% respecto dei 100% del árido (3), 600g serían de aglomerante (2), es decir el 60%, y 400g de árido (3) prefabricado, es decir el 40%, sobre un total de 1000g. En cuanto a los áridos (3) procedentes de mezclas, ia cantidad máxima seria de hasta un 70% respecto del 100% dei árido (3), 600g serian de aglomerante (2), y 280g de áridos reciclados (3), junto a 120g de áridos (3) prefabricados, sobre un total de 1000g. On the other hand, as can be seen in figures 3 and 4, the aggregate (3) is one of the group of prefabricated aggregate (3), recycled aggregate (3), gypsum aggregate (3) directly from the quarry without cooking treatment, or a mixture of prefabricated aggregate (3) with recycled aggregate (3). As an example, it can be stated that in a preferred embodiment of the invention, as regards the recycled aggregate (3), the maximum quantity is between 10% and 40% of the 100% of the aggregate (3), 600g would be binder (2), i.e. 60%, and 400g of prefabricated aggregate (3), i.e. 40%, out of a total of 1000g. As regards the aggregates (3) from mixtures, the maximum quantity would be up to 70% of the 100% of the aggregate (3), 600g would be binder (2), and 280g of recycled aggregates (3), together with 120g of prefabricated aggregates (3), out of a total of 1000g.
Según otro aspecto de la invención, tal y como se observa en las figuras 3 y 4, el árido (3) prefabricado comprende una granulometría de: i) tamaño máximo de 10 mm, con una presencia de entre el 1% y el 5 %; ii) tamaño entre 3-5 mm, con una presencia de entre el 75% y el 88 %; iii) tamaño entre 0.2-0.05mm, con una presencia de entre el 10% y el 20 %; iv) tamaño entre 0.02-0.005mm, con una presencia de entre el 1% y el 5 %; , y comprende además entre el 17,36% y el 23,08% de agua del peso del elemento prefabricado (1) y entre el 0,01% y el 0,2% de aditivo del peso del elemento prefabricado (1). donde el aditivo (5) está basado en un ácido poli carboxiiico. According to another aspect of the invention, as seen in Figures 3 and 4, the prefabricated aggregate (3) comprises a granulometry of: i) maximum size of 10 mm, with a presence of between 1% and 5%; ii) size between 3-5 mm, with a presence of between 75% and 88%; iii) size between 0.2-0.05mm, with a presence of between 10% and 20%; iv) size between 0.02-0.005mm, with a presence of between 1% and 5%; , and further comprises between 17.36% and 23.08% of water of the weight of the prefabricated element (1) and between 0.01% and 0.2% of additive of the weight of the prefabricated element (1). where the additive (5) is based on a polycarboxylic acid.
Precisar a modo de ejemplo que, en una realización preferida de la invención, en cuanto al elemento prefabricado (1), 600g serian de aglomerante (2), 400g de áridos (3) prefabricados, es decir, un 40%, sobre un total de 1000g, siendo el 5% de esos áridos (3) de tamaño menor 10mm, 80% de tamaño 3-5mm, 10% de tamaño entre 0.2-0.05, 5% de tamaño 0.002-0.005. Cabe mencionar que el aporte de entre el 17.36% y el 23,08% de agua (4) del peso del elemento prefabricado (1), corresponden a entre 210g y 300g de agua (4). con 1000g de yeso (21) más árido (3) adicionales, yendo a una composición final de entre 1210 y 1300g. Adicionalmente, entre el 0,01% y el 0,2% de aditivo (5) del peso del elemento prefabricado (1), sobre los 1000g de yeso (21) más árido (3), supone entre 0,1 y 2g de aditivo (5). It should be noted, as an example, that in a preferred embodiment of the invention, as regards the prefabricated element (1), 600g would be binder (2), 400g of prefabricated aggregates (3), that is, 40%, out of a total of 1000g, with 5% of these aggregates (3) being of a size smaller than 10mm, 80% of a size of 3-5mm, 10% of a size between 0.2-0.05, 5% of a size of 0.002-0.005. It should be mentioned that the contribution of between 17.36% and 23.08% of water (4) of the weight of the prefabricated element (1), corresponds to between 210g and 300g of water (4). with 1000g of gypsum (21) plus additional aggregate (3), reaching a final composition of between 1210 and 1300g. Additionally, between 0.01% and 0.2% of additive (5) of the weight of the prefabricated element (1), on the 1000g of gypsum (21) plus aggregate (3), represents between 0.1 and 2g of additive (5).
Más en detalle, tal y como se observa en la figura 2. el ácido poli carboxiiico es ácido cítrico o ácido cítrico con dióxido de silicio, y alternativamente ácido cítrico con base de melamina y/o sales In more detail, as shown in Figure 2, polycarboxylic acid is citric acid or citric acid with silicon dioxide, and alternatively citric acid based on melamine and/or salts.
Cabe mencionar que, tal y como se observa en las figuras 3 y 4. el árido (3) reciclado comprende una granulometrla de: i) tamaño máximo de 10 mm, con una presencia de entre el 1 % y el 8%; ii) tamaño entre 3-5 mm, con una presencia de entre el 68% y el 88%; iil) tamaño entre 0.2-0.05mm, con una presencia de entre el 8% y el 21%; iv) entre 0.02-0.005mm, con una presencia de entre el 1% y el 6%. It is worth mentioning that, as can be seen in figures 3 and 4, the recycled aggregate (3) comprises a granulometry of: i) maximum size of 10 mm, with a presence of between 1% and 8%; ii) size between 3-5 mm, with a presence of between 68% and 88%; iil) size between 0.2-0.05mm, with a presence of between 8% and 21%; iv) between 0.02-0.005mm, with a presence of between 1% and 6%.
Opcionalmente, tal y como se observa en las figuras 3 y 4. el árido (3) prefabricado se puede basar en una sola granulometría de: i) tamaño máximo de 10 mm, con una presencia de entre el 0% y el 10 %; ii) tamaño entre 3-5 mm, con una presencia de entre el 0% y el 100 %; iii) tamaño entre 0.2-0.05mm, con una presencia de entre el 0% y el 100 %; iv) tamaño entre 0.02-0.005mm, con una presencia de entre el 1% y el 10 %; y comprende además entre el 17,36% y el 23,08% de agua (4) del peso del elemento prefabricado (1) y entre el 0,01% y el 0,2% de aditivo (5) del peso del elemento prefabricado (1), donde el aditivo (5) está basado en un ácido poli carboxilico, en un compuesto de melamina y/o sales. Optionally, as seen in figures 3 and 4, the prefabricated aggregate (3) can be based on a single granulometry of: i) maximum size of 10 mm, with a presence of between 0% and 10 %; ii) size between 3-5 mm, with a presence of between 0% and 100 %; iii) size between 0.2-0.05 mm, with a presence of between 0% and 100 %; iv) size between 0.02-0.005 mm, with a presence of between 1% and 10 %; and further comprises between 17.36% and 23.08% of water (4) of the weight of the prefabricated element (1) and between 0.01% and 0.2% of additive (5) of the weight of the prefabricated element (1), where the additive (5) is based on a polycarboxylic acid, a melamine compound and/or salts.
Concretamente, un elemento prefabricado (1) puede contar con 600g de aglomerante (2), 400g de áridos (3) prefabricados, siendo un 40% sobre 1000g, y siendo el 100% de esos áridos (3) de tamaño entre 3-5mm. Alternativamente, un elemento prefabricado (1) cuenta con 600g de aglomerante (2), 400g de áridos (3) prefabricados, es decir, un 40% sobre 1000g, habiendo 240g, es decir un 60% de áridos (3) de tamaño entre 3-5mm, y 160g, es decir un 40% de áridos (3) de tamaño entre 0.2-0.05 Cabe precisar que los porcentajes preferentes del 17,36% y el 23,08% de agua (4) del peso del elemento prefabricado (1), corresponden a 210g y 300g de agua (4), con 1000g de yeso (21) más árido (3) adicionales, yendo a una composición final de un peso de entre 1210d y 1300g. De lo anterior, se cuenta con los porcentajes de entre el 0,01% y el 0.2% de aditivo (5) del peso del elemento prefabricado (1), sobre los 1000g de yeso (21) más árido (3), lo que supone 0,1-2g de aditivo (5) Specifically, a prefabricated element (1) can have 600g of binder (2), 400g of prefabricated aggregates (3), 40% of which is over 1000g, and 100% of these aggregates (3) being between 3-5mm in size. Alternatively, a prefabricated element (1) has 600g of binder (2), 400g of prefabricated aggregates (3), that is, 40% of 1000g, with 240g, that is, 60% of aggregates (3) of size between 3-5mm, and 160g, that is, 40% of aggregates (3) of size between 0.2-0.05. It should be noted that the preferred percentages of 17.36% and 23.08% of water (4) of the weight of the prefabricated element (1), correspond to 210g and 300g of water (4), with 1000g of gypsum (21) plus additional aggregate (3), going to a final composition of a weight of between 1210d and 1300g. From the above, we have percentages between 0.01% and 0.2% of additive (5) of the weight of the prefabricated element (1), on the 1000g of plaster (21) plus aggregate (3), which represents 0.1-2g of additive (5)
En una realización preferida de la invención, tal y como se observa en las figuras 3 y 4, el árido (3) comprende una proporción hasta del 30% de arlita o periita, más árido (3) prefabricado. Asi, en cuanto ai árido (3) reciclado, la cantidad máxima está entre el 10% y el 40% respecto del 100% del árido (3). Y en cuanto a los áridos de ariita, cuenta con hasta un 70% respecto del 100% del árido (3). In a preferred embodiment of the invention, as shown in Figures 3 and 4, the aggregate (3) comprises a proportion of up to 30% of arlite or perite, plus prefabricated aggregate (3). Thus, as regards the recycled aggregate (3), the maximum quantity is between 10% and 40% with respect to 100% of the aggregate (3). And as regards the arlite aggregates, it has up to 70% with respect to 100% of the aggregate (3).
Es también objeto de la presente invención, tal y como se observa en la figura 8, un método de fabricación de elemento prefabricado (1 ) para la construcción, que comprende las etapas de: i) preparación de un árido (3) basado en sulfato cálcico (31 ); ii) mezclado homogéneo de un aglomerante (2) de yeso (21), del árido (3) basado en sulfato cálcico (31) y de agua (4); ¡ii) conformado del elemento prefabricado (1 ) por medio de vibro compresión. Así, en cuanto a la materia prima se utilizan áridos (3) prefabricados de sulfato cálcico (31 ). The present invention also relates, as shown in Figure 8, to a method of manufacturing a prefabricated element (1) for construction, which comprises the steps of: i) preparing an aggregate (3) based on calcium sulphate (31); ii) homogeneous mixing of a binder (2) of gypsum (21), the aggregate (3) based on calcium sulphate (31) and water (4); forming of the prefabricated element (1) by means of vibro compression. Thus, as for the raw material, prefabricated aggregates (3) of calcium sulphate (31) are used.
Preferentemente, tal y como se observa en la figura 2, el método de fabricación de elemento prefabricado (1) para la construcción, comprende la adición de un aditivo (5) de agua (4) basado en un ácido poli carboxílico, o con dióxido de silicio. Preferably, as seen in Figure 2, the method of manufacturing the prefabricated element (1) for construction, comprises the addition of a water additive (5) (4) based on a polycarboxylic acid, or with silicon dioxide.
Cabe señalar que, tal y como se observa en la figura 8, el método de fabricación de elemento prefabricado (1) para la construcción, comprende la preparación de una mezcla que comprende un árido (3) basado en sulfato cálcico (31), agua (4) y aditivo (5) y que comprende una parte de áridos (3), áridos (3) reciclados, áridos (3) de cantera, arlita o perlita. y comprende las etapas de: í.1) mezclado del sulfato cálcico (31) con agua (4), aditivo (5) y áridos (3); ¡.2) amasado de dicha mezcla de sulfato cálcico (31) con agua (4). aditivo (5) y áridos (3) en una mezcladora (7) horizontal rotativa hasta la obtención de granos (6) de sulfato cálcico (31) de tamaño homogéneo menor de 8mm; i.3) vertido de la mezcla en una máquina de vibro compresión para obtención de los elementos prefabricados (1). It should be noted that, as seen in figure 8, the method of manufacturing a prefabricated element (1) for construction, comprises the preparation of a mixture comprising an aggregate (3) based on calcium sulphate (31), water (4) and additive (5) and comprising a portion of aggregates (3), recycled aggregates (3), quarry aggregates (3), arlite or perlite, and comprises the steps of: 1) mixing the calcium sulphate (31) with water (4), additive (5) and aggregates (3); 2) kneading said mixture of calcium sulphate (31) with water (4), additive (5) and aggregates (3) in a horizontal rotary mixer (7) until obtaining grains (6) of calcium sulphate (31) of homogeneous size less than 8 mm; i.3) pouring the mixture into a vibro compression machine to obtain the prefabricated elements (1).
Adicionalmente, tal y como se observa en las figuras 2 y 7, la preparación de un árido (3) basado en sulfato cálcico (31) comprende una etapa previa de obtención de agua (4) tratada para ei mezclado, donde el agua (4) tratada comprende un retardador (9) del fraguado. Additionally, as seen in figures 2 and 7, the preparation of an aggregate (3) based on calcium sulphate (31) comprises a prior stage of obtaining treated water (4) for mixing, where the treated water (4) comprises a setting retarder (9).
Complementariamente, tal y como se observa en la figura 8, la preparación de un árido (3) basado en sulfato cálcico (31 ) comprende las etapas de: i.1 ) mezclado del sulfato cálcico (31 ) con agua (4) y aditivo (5); i.2) pulverizado de la mezcla de sulfato cálcico (31 ) con agua (4) y aditivo (5) en una mezcladora (7) horizontal rotativa hasta la obtención de un grano (6) de sulfato calcico (31) de tamaño homogéneo; i.3) tamizado del árido (3) de sulfato cálcico (31) de diámetro menor a 8mm; i.4) molienda de ios granos (6) de sulfato calcico (31 ) de diámetro mayor a 10mm en un molino (8) de fragmentación; ¡.5) tratamiento de deshidratación del sulfato cálcico (31 ) Additionally, as shown in Figure 8, the preparation of an aggregate (3) based on calcium sulphate (31) comprises the following steps: i.1) mixing the calcium sulphate (31) with water (4) and additive (5); i.2) pulverizing the mixture of calcium sulphate (31) with water (4) and additive (5) in a horizontal rotary mixer (7) until obtaining a grain (6) of calcium sulphate (31) of homogeneous size; i.3) sieving the aggregate (3) of calcium sulphate (31) with a diameter less than 8 mm; i.4) grinding the grains (6) of calcium sulphate (31) with a diameter greater than 10 mm in a fragmentation mill (8); i.5) dehydration treatment of the calcium sulphate (31).
Más específicamente, tai y como se observa en las figuras 2 y 7, la cantidad de agua (4) es de entre 14,89% al 17,01% del peso del elemento prefabricado (1). En concreto de entre 175g y 205g de agua (4), que, con los 1000g de yeso (21) más árido (3) adicionales, la composición final acabaría teniendo entre 1175 y 1205g. Añadir que para la obtención de estos áridos (3) se puede optar por distintos procedimientos de fabricación. Por ejemplo, una mezcladora (7) horizontal de palas o picazas, o simplemente máquinas de mezclado del tipo planetaria. En el primer caso, el más interesante por la calidad de los áridos (3), el yeso (21 ) una vez en la cuba se somete a un pulverizado del agua (4), previamente aditivada con un retardador (9) del fraguado. Las palas rotativas van mezclando en continúo formando bolas o granos (6) de tamaño homogéneo y diámetros menores de 7mm. La cantidad de agua (4) inicial se fija en 185120 g por cada 1000 g de yeso (21), dando lugar a un peso de 1175g de mezcla (1000g+175g), un 14,89% de mezcla, y para 1205g (l000+205g), un 17,01% de mezcla. More specifically, as can be seen in figures 2 and 7, the amount of water (4) is between 14.89% and 17.01% of the weight of the prefabricated element (1). Specifically, between 175g and 205g of water (4), which, with the additional 1000g of gypsum (21) plus aggregate (3), the final composition would end up having between 1175 and 1205g. It should be added that to obtain these aggregates (3) different manufacturing procedures can be chosen. For example, a mixer (7) horizontal paddle mixers or pickaxes, or simply planetary type mixing machines. In the first case, the most interesting for the quality of the aggregates (3), the gypsum (21) once in the vat is subjected to a spray of water (4), previously added with a setting retarder (9). The rotating paddles mix continuously forming balls or grains (6) of homogeneous size and diameters less than 7mm. The initial quantity of water (4) is set at 185120 g for every 1000 g of gypsum (21), resulting in a weight of 1175 g of mix (1000 g + 175 g), 14.89% of mix, and for 1205 g (1000 + 205 g), 17.01% of mix.
Para el caso de la máquina planetaria, las bolas o granos (6) no son homogéneos, y se hace necesario un cribado posterior para eliminar la fracción gruesa. En el caso de aditivar el agua (4) con ácidos poli carboxllicos, por ejemplo, con el ácido cítrico, este se fija entre 0,1- 2g por cada 1000g de yeso (21) a mezclar. In the case of the planetary machine, the balls or grains (6) are not homogeneous, and a subsequent screening is necessary to eliminate the coarse fraction. In the case of adding water (4) with polycarboxylic acids, for example, with citric acid, this is set between 0.1-2g for every 1000g of gypsum (21) to be mixed.
Los detalles, las formas, las dimensiones y demás elementos accesorios, asi como los componentes empleados en la implementación del elemento prefabricado (1) para la construcción, y método asociado, podrán ser convenientemente sustituidos por otros que sean técnicamente equivalentes, y no se aparten de la esencialidad de la invención ni del ámbito definido por las reivindicaciones que se incluyen a continuación de la siguiente lista. The details, shapes, dimensions and other accessory elements, as well as the components used in the implementation of the prefabricated element (1) for construction, and associated method, may be conveniently replaced by others that are technically equivalent, and do not deviate from the essence of the invention or the scope defined by the claims included below the following list.
Lista referencias numéricas: List of numerical references:
1 elemento prefabricado 1 prefabricated element
2 aglomerante 2 binder
21 yeso 21 plaster
3 árido 3 arid
31 sulfato calcico 31 calcium sulfate
4 agua 4 water
5 aditivo 5 additive
6 grano 6 grain
7 mezcladora 7 mixer
8 molino 8 mill
9 retardador 9 retarder
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES202300065A ES2997118B2 (en) | 2023-08-07 | 2023-08-07 | PREFABRICATED CONSTRUCTION ELEMENT AND ASSOCIATED METHOD |
| ESP-202300065 | 2023-08-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2025032268A1 true WO2025032268A1 (en) | 2025-02-13 |
Family
ID=94534075
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/ES2024/000016 Pending WO2025032268A1 (en) | 2023-08-07 | 2024-08-02 | Prefabricated element for construction and associated method |
Country Status (3)
| Country | Link |
|---|---|
| AR (1) | AR133467A1 (en) |
| ES (1) | ES2997118B2 (en) |
| WO (1) | WO2025032268A1 (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7514644A (en) * | 1974-12-17 | 1976-06-21 | Maurice Toulas | BUILDING MATERIAL AND THE MANUFACTURING METHOD FOR THIS. |
| SU688468A1 (en) * | 1978-05-30 | 1979-09-30 | Томский инженерно-строительный институт | Method of producing gypsum articles |
| SU1339025A1 (en) * | 1984-07-26 | 1987-09-23 | Латвийский Научно-Исследовательский И Экспериментально-Технологический Институт Строительства | Method of producing decorative construction articles |
| SU1774935A3 (en) * | 1990-12-20 | 1992-11-07 | ||
| RU2190522C1 (en) * | 2001-09-03 | 2002-10-10 | Козаченко Андрей Викторович | Method and form for manufacture of interior-lining gypsum products |
| CN114014620A (en) * | 2021-10-29 | 2022-02-08 | 河北睿索固废工程技术研究院有限公司 | Lightweight aggregate and preparation method and application thereof |
-
2023
- 2023-08-07 ES ES202300065A patent/ES2997118B2/en active Active
-
2024
- 2024-08-02 WO PCT/ES2024/000016 patent/WO2025032268A1/en active Pending
- 2024-08-05 AR ARP240102073A patent/AR133467A1/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7514644A (en) * | 1974-12-17 | 1976-06-21 | Maurice Toulas | BUILDING MATERIAL AND THE MANUFACTURING METHOD FOR THIS. |
| SU688468A1 (en) * | 1978-05-30 | 1979-09-30 | Томский инженерно-строительный институт | Method of producing gypsum articles |
| SU1339025A1 (en) * | 1984-07-26 | 1987-09-23 | Латвийский Научно-Исследовательский И Экспериментально-Технологический Институт Строительства | Method of producing decorative construction articles |
| SU1774935A3 (en) * | 1990-12-20 | 1992-11-07 | ||
| RU2190522C1 (en) * | 2001-09-03 | 2002-10-10 | Козаченко Андрей Викторович | Method and form for manufacture of interior-lining gypsum products |
| CN114014620A (en) * | 2021-10-29 | 2022-02-08 | 河北睿索固废工程技术研究院有限公司 | Lightweight aggregate and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2997118A1 (en) | 2025-02-14 |
| AR133467A1 (en) | 2025-10-01 |
| ES2997118B2 (en) | 2025-11-03 |
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